ChemInform Abstract: The Elusive closo-Ge102- Zintl Ion: Finally “Captured” as a Ligand in the...

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ChemInform 2010, 41, issue 38 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Germanium I 4700 DOI: 10.1002/chin.201038014 The Elusive Zintl Ion: Finally "Captured" as a Ligand in the Com- plex [Ge10Mn(CO)4] 3- . — The Zintl ion is prepared by soft oxidation of and crystallized as compound (III). (III) crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD). The new cluster is a bicapped square antiprism, as expected for a closo-deltahedron of 10 atoms. — (RIOS, D.; SEVOV*, S. C.; Inorg. Chem. 49 (2010) 14, 6396-6398, DOI:10.1021/ic100877u ; Dep. Chem. Biochem., Univ. Notre Dame, Notre Dame, IN 46556, USA; Eng.) — Schramke 38- 014 c loso-Ge 2- 10 Ge 2- 10 Ge 4- 9

Transcript of ChemInform Abstract: The Elusive closo-Ge102- Zintl Ion: Finally “Captured” as a Ligand in the...

Page 1: ChemInform Abstract: The Elusive closo-Ge102- Zintl Ion: Finally “Captured” as a Ligand in the Complex [Ge10Mn(CO)4]3-.

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GermaniumI 4700 DOI: 10.1002/chin.201038014

The Elusive Zintl Ion: Finally "Captured" as a Ligand in the Com-plex [Ge10Mn(CO)4]3-. — The Zintl ion is prepared by soft oxidation of and crystallized as compound (III). (III) crystallizes in the monoclinic space group P21/n with Z = 4 (single crystal XRD). The new cluster is a bicapped square antiprism, as expected for a closo-deltahedron of 10 atoms. — (RIOS, D.; SEVOV*, S. C.; Inorg. Chem. 49 (2010) 14, 6396-6398, DOI:10.1021/ic100877u ; Dep. Chem. Biochem., Univ. Notre Dame, Notre Dame, IN 46556, USA; Eng.) — Schramke

38- 014 closo-Ge2-10

Ge2-10 Ge4-

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ChemInform 2010, 41, issue 38 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

METHODOLOGY Molecularstructuresenumeration and ......Koch et al. J Cheminform Page5of17 changing4bonds,sinceweaimtondminimaltransfor - mations.Letuscall a 13 and a 24 thetwofixedbonds,with

METHODOLOGY Molecularstructuresenumeration and ......Koch et al. J Cheminform Page5of17 changing4bonds,sinceweaimtondminimaltransfor - mations.Letuscall a 13 and a 24 thetwofixedbonds,with

Universities of Leeds, Sheffield and York ...eprints.whiterose.ac.uk/3752/1/Macropolyhedral_3752.pdfThe redox flexibility of transition-element centres allied with the closo-nido-arachno-etc

Universities of Leeds, Sheffield and York ...eprints.whiterose.ac.uk/3752/1/Macropolyhedral_3752.pdfThe redox flexibility of transition-element centres allied with the closo-nido-arachno-etc

Four Decades of Organic Chemistry of closo-Boranes: A Synthetic Toolbox for Constructing Liquid

Four Decades of Organic Chemistry of closo-Boranes: A Synthetic Toolbox for Constructing Liquid

Zintl Phases - University of Notre Damesevovlab/articles/SlaviChapter.pdf · and Woltersdorf, 1935), ... Since the Zintl phases usually contain alkali or alkaline-earth metals and

Zintl Phases - University of Notre Damesevovlab/articles/SlaviChapter.pdf · and Woltersdorf, 1935), ... Since the Zintl phases usually contain alkali or alkaline-earth metals and

Enhanced Stability of the Carba-closo-dodecaborate Anion ... · electrolyte, a concept for which computational and exper-imental correlations are reported for lithium salts in aprotic

Enhanced Stability of the Carba-closo-dodecaborate Anion ... · electrolyte, a concept for which computational and exper-imental correlations are reported for lithium salts in aprotic

Zintl -Based Materials For Thermoelectrics

Zintl -Based Materials For Thermoelectrics

Statistical principle-based approach for gene and protein ... · Lai et al. J Cheminform Page 2 of 9 tobiologicaldatabaserecords.Intheabovecases,“A2A” isasubtypeof“adenosinereceptor”.erefore“A2A

Statistical principle-based approach for gene and protein ... · Lai et al. J Cheminform Page 2 of 9 tobiologicaldatabaserecords.Intheabovecases,“A2A” isasubtypeof“adenosinereceptor”.erefore“A2A

Diazotization of the Amino Acid [closo-1-CB H -1-COOH-6-NH ... · its pK a was estimated at 18.1, which is lower by 3.7 than pK a for the 10-amino analogue [closo-1-CB 9 H -10-NH

Diazotization of the Amino Acid [closo-1-CB H -1-COOH-6-NH ... · its pK a was estimated at 18.1, which is lower by 3.7 than pK a for the 10-amino analogue [closo-1-CB 9 H -10-NH

Four Decades of Organic Chemistry of closo-Boranes: A Synthetic ...

Four Decades of Organic Chemistry of closo-Boranes: A Synthetic ...

Four Decades of Organic Chemistry of closo-Boranes: A ... · The synthesis of the first organic derivatives of closo-dodecaborate (1, Fig. 1) and closo-decaborate 7 in 1962 (ref.1)

Four Decades of Organic Chemistry of closo-Boranes: A ... · The synthesis of the first organic derivatives of closo-dodecaborate (1, Fig. 1) and closo-decaborate 7 in 1962 (ref.1)

ChemInform RxnFinder

ChemInform RxnFinder

2.6 Deltahedral Zintl Ions of Tin: Synthesis, Structure ...sevovlab/articles/c02-6-1.pdf · 2.6 Deltahedral Zintl Ions of Tin: Synthesis, Structure, and Reactivity Slavi C. Sevov

2.6 Deltahedral Zintl Ions of Tin: Synthesis, Structure ...sevovlab/articles/c02-6-1.pdf · 2.6 Deltahedral Zintl Ions of Tin: Synthesis, Structure, and Reactivity Slavi C. Sevov

Heteroatomic Deltahedral Zintl Ions of Group 14 and their ...sevovlab/articles/ESMS2009.pdf · Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation Miriam M. Gillett-Kunnath,

Heteroatomic Deltahedral Zintl Ions of Group 14 and their ...sevovlab/articles/ESMS2009.pdf · Heteroatomic Deltahedral Zintl Ions of Group 14 and their Alkenylation Miriam M. Gillett-Kunnath,

Investigations of Electronic Interactions Between closo ...Hammett value of σ p = +0.05 (ref.6).Spectroscopic studies demonstrated a rather moderate effect of the 12-vertex closo-borane

Investigations of Electronic Interactions Between closo ...Hammett value of σ p = +0.05 (ref.6).Spectroscopic studies demonstrated a rather moderate effect of the 12-vertex closo-borane

RESEARCHARTICLE OpAccess ......Jiangiet al. J Cheminform Pagej2jofj26 playerindrugabsorption,distribution,metabolism, excretion,andtoxicity(ADMET)[5, 6],andhasalsobeen ...

RESEARCHARTICLE OpAccess ......Jiangiet al. J Cheminform Pagej2jofj26 playerindrugabsorption,distribution,metabolism, excretion,andtoxicity(ADMET)[5, 6],andhasalsobeen ...

Synthesis and Reactivity of [closo-1-CB H -1-N ]: Functional ......9-1-N 2]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB 9} Cluster Bryan Ringstrand, Piotr

Synthesis and Reactivity of [closo-1-CB H -1-N ]: Functional ......9-1-N 2]: Functional Group Interconversion at the Carbon Vertex of the {closo-1-CB 9} Cluster Bryan Ringstrand, Piotr

RESEARCHARTICLE LargescalecomparisonofQSAR … · 2020. 3. 19. · Boscet al. J Cheminform Page3of16 Dta preparation Compoundstructureswereextractedfromthedatabase inSMILESformatandusingRDKit(version2017_09_01)

RESEARCHARTICLE LargescalecomparisonofQSAR … · 2020. 3. 19. · Boscet al. J Cheminform Page3of16 Dta preparation Compoundstructureswereextractedfromthedatabase inSMILESformatandusingRDKit(version2017_09_01)

Revisiting the Zintl-Klemm Concept for 2Ag3Te5-Type ...

Revisiting the Zintl-Klemm Concept for 2Ag3Te5-Type ...

Thermochemistry of icosahedral closo-dicarboranes: A composite ab initio … · 1 Thermochemistry of icosahedral closo-dicarboranes: A composite ab initio quantum-chemical perspective

Thermochemistry of icosahedral closo-dicarboranes: A composite ab initio … · 1 Thermochemistry of icosahedral closo-dicarboranes: A composite ab initio quantum-chemical perspective

The Photofragmentation Processes of the closo-Carborane and the

The Photofragmentation Processes of the closo-Carborane and the