ChemInform Abstract: Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7-...

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1997 stereochemistry stereochemistry (general, optical resolution) O 0030 48 - 026 Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7- phosphabicyclo(2.2.1)heptanes, and Their Application in Highly Enantioselective Pd-Catalyzed Allylic Alkylations. The Pd- catalyzed alkylation in the presence of the novel phosphine ( IVa) proceeds with excellent enantioselectivity. — (CHEN, Z.; JIANG, Q.; ZHU, G.; XIAO, D.; CAO, P.; GUO, C.; ZHANG, X.; J. Org. Chem. 62 (1997) 13, 4521-4523; Dep. Chem., Pa. State Univ., University Park, PA 16802, USA; EN) 1

Transcript of ChemInform Abstract: Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7-...

Page 1: ChemInform Abstract: Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7- phosphabicyclo(2.2.1)heptanes, and Their Application in Highly Enantioselective Pd-Catalyzed

1997 stereochemistry

stereochemistry (general, optical resolution)O 0030

48 - 026Syntheses of Novel Chiral Monophosphines, 2,5-Dialkyl-7-phenyl-7-phosphabicyclo(2.2.1)heptanes, and Their Application in HighlyEnantioselective Pd-Catalyzed Allylic Alkylations. — The Pd-catalyzed alkylation in the presence of the novel phosphine ( IVa) proceeds withexcellent enantioselectivity. — (CHEN, Z.; JIANG, Q.; ZHU, G.; XIAO, D.;CAO, P.; GUO, C.; ZHANG, X.; J. Org. Chem. 62 (1997) 13, 4521-4523; Dep.Chem., Pa. State Univ., University Park, PA 16802, USA; EN)

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