ChemInform Abstract: Stereoselective Hydrocoupling of [(1R)-exo]-3-exo-(Diphenylmethyl)bornyl...

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2002 polyphenylalkane derivatives polyphenylalkane derivatives Q 0720 12 - 129 Stereoselective Hydrocoupling of [(1R)-exo]-3-exo- (Diphenylmethyl)bornyl Cinnamates by Electroreduction. — The chiral auxiliary (I) is effective for the stereoselective hydrocoupling of its cinnamates by electroreduction. From the resulting hydrodimers (VII) the diaryldiols (IX) and diesters (XI) are synthesized in good enantioselectivity. — (KISE, NAOKI; IWASAKI, KEISUKE; TOKIEDA, NAOHIKO; UEDA, NASUO; Org. Lett. 3 (2001) 21, 3241-3244; Dep. Biotechnol., Fac. Eng., Tottori Univ., Koyama, Tottori 680, Japan; EN) 1

Transcript of ChemInform Abstract: Stereoselective Hydrocoupling of [(1R)-exo]-3-exo-(Diphenylmethyl)bornyl...

Page 1: ChemInform Abstract: Stereoselective Hydrocoupling of [(1R)-exo]-3-exo-(Diphenylmethyl)bornyl Cinnamates by Electroreduction.

2002 polyphenylalkane derivatives

polyphenylalkane derivativesQ 0720

12 - 129Stereoselective Hydrocoupling of [(1R)-exo]-3-exo-(Diphenylmethyl)bornyl Cinnamates by Electroreduction. —The chiral auxiliary (I) is effective for the stereoselective hydrocoupling of itscinnamates by electroreduction. From the resulting hydrodimers (VII) thediaryldiols (IX) and diesters (XI) are synthesized in good enantioselectivity.— (KISE, NAOKI; IWASAKI, KEISUKE; TOKIEDA, NAOHIKO; UEDA,NASUO; Org. Lett. 3 (2001) 21, 3241-3244; Dep. Biotechnol., Fac. Eng.,Tottori Univ., Koyama, Tottori 680, Japan; EN)

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