ChemInform Abstract: Self-Assembly of Three-Dimensional Nanostructured Antimony.

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ChemInform 2009, 40, issue 10 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Nanotechnology V 1505 Self-Assembly of Three-Dimensional Nanostructured Antimony. — Three-dimen- sional nanostructured antimony is synthesized by immerging an anodically oxidized Cu sheet into a SbCl3/Bu4NBF4/DMSO solution at room temperature. The samples are characterized by FE-SEM, XRD, and HRTEM. The Sb nanocages are constructed from Sb single crystal nanowires and exhibit a regular fourteen-faced polyhedron shape. The average diameter of the Sb nanowires ranges from 5 to 8 nm. A growth mechanism is discussed. Three-dimensional nanostructured Sb may be a good system for studying the electronic conduction and transport properties, and quantum confinement effects. — (LIU*, P.; ZHONG, K.; LIANG, C.; YANG, Q.; TONG, Y.; LI, G.; HOPE, G. A.; Chem. Mater. 20 (2008) 24, 7532-7538; Sch. Chem. Chem. Eng., Sun Yat-Sen Univ., Guangzhou 510275, Peop. Rep. China; Eng.) — W. Pewestorf 10- 215

Transcript of ChemInform Abstract: Self-Assembly of Three-Dimensional Nanostructured Antimony.

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NanotechnologyV 1505 Self-Assembly of Three-Dimensional Nanostructured Antimony. — Three-dimen-

sional nanostructured antimony is synthesized by immerging an anodically oxidized Cu sheet into a SbCl3/Bu4NBF4/DMSO solution at room temperature. The samples are characterized by FE-SEM, XRD, and HRTEM. The Sb nanocages are constructed from Sb single crystal nanowires and exhibit a regular fourteen-faced polyhedron shape. The average diameter of the Sb nanowires ranges from 5 to 8 nm. A growth mechanism is discussed. Three-dimensional nanostructured Sb may be a good system for studying the electronic conduction and transport properties, and quantum confinement effects. — (LIU*, P.; ZHONG, K.; LIANG, C.; YANG, Q.; TONG, Y.; LI, G.; HOPE, G. A.; Chem. Mater. 20 (2008) 24, 7532-7538; Sch. Chem. Chem. Eng., Sun Yat-Sen Univ., Guangzhou 510275, Peop. Rep. China; Eng.) — W. Pewestorf

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ChemInform 2009, 40, issue 10 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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