ChemInform Abstract: Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for...

1
ChemInform 2009, 40, issue 05 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Benzopyran derivatives R 0350 Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for One-Pot Synthesis of Benzopyrones and Bicyclic Spiro Ketones. — A variety of substituted diynones is converted to polycyclic benzoisochromenes or spirocyclic prod- ucts catalyzed by PtCl2 or AuCl(PPh3)/AgOTf. When diynals (I) are used as substrates, the corresponding benzoisochromenes are obtained, while the gold-catalyzed reaction does not deliver any satisfactory results. — (DAS, A.; CHANG, H.-K.; YANG, C.-H.; LIU*, R.-S.; Org. Lett. 10 (2008) 18, 4061-4064; Dep. Chem., Natl. Tsing Hua Univ., Hsinchu 30043, Taiwan; Eng.) — R. Steudel 05- 139

Transcript of ChemInform Abstract: Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for...

www.cheminform.wiley-vch.de

Benzopyran derivativesR 0350 Platinum- and Gold-Catalyzed Hydrative Carbocyclization of Oxo Diynes for

One-Pot Synthesis of Benzopyrones and Bicyclic Spiro Ketones. — A variety of substituted diynones is converted to polycyclic benzoisochromenes or spirocyclic prod-ucts catalyzed by PtCl2 or AuCl(PPh3)/AgOTf. When diynals (I) are used as substrates, the corresponding benzoisochromenes are obtained, while the gold-catalyzed reaction does not deliver any satisfactory results. — (DAS, A.; CHANG, H.-K.; YANG, C.-H.; LIU*, R.-S.; Org. Lett. 10 (2008) 18, 4061-4064; Dep. Chem., Natl. Tsing Hua Univ., Hsinchu 30043, Taiwan; Eng.) — R. Steudel

05- 139

ChemInform 2009, 40, issue 05 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim