ChemInform Abstract: Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aromatic...

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ChemInform 2011, 42, issue 01 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Polyphenylalkane derivatives Q 0720 DOI: 10.1002/chin.201124088 Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aro- matic Aldehydes: Selectively Generation Biaryls and Diarylketones. — Novel rhodium-catalyzed oxidative decarbonylative homocoupling of aryl aldehydes (I) in the presence of triphenylphosphine affords biaryls (II) as main products and diaryl ketones as by-products. However, the reaction in the presence of dppe leads selectively to di- arylketones (III). — (YANG, L.; ZENG, T.; SHUAI, Q.; GUO, X.; LI*, C.-J.; Chem. Commun. (Cambridge) 47 (2011) 7, 2161-2163, http://dx.doi.org/10.1039/c0cc04921b ; Dep. Chem., McGill Univ., Montreal, Que. H3A 2K6, Can.; Eng.) — R. Staver 24- 088

Transcript of ChemInform Abstract: Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aromatic...

Page 1: ChemInform Abstract: Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aromatic Aldehydes: Selectively Generation Biaryls and Diarylketones.

Polyphenylalkane derivativesQ 0720 DOI: 10.1002/chin.201124088

Phosphine Ligand Triggered Oxidative Decarbonylative Homocoupling of Aro-matic Aldehydes: Selectively Generation Biaryls and Diarylketones. — Novel rhodium-catalyzed oxidative decarbonylative homocoupling of aryl aldehydes (I) in the presence of triphenylphosphine affords biaryls (II) as main products and diaryl ketones as by-products. However, the reaction in the presence of dppe leads selectively to di-arylketones (III). — (YANG, L.; ZENG, T.; SHUAI, Q.; GUO, X.; LI*, C.-J.; Chem. Commun. (Cambridge) 47 (2011) 7, 2161-2163, http://dx.doi.org/10.1039/c0cc04921b ; Dep. Chem., McGill Univ., Montreal, Que. H3A 2K6, Can.; Eng.) — R. Staver

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ChemInform 2011, 42, issue 01 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

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