ChemInform Abstract: One-Step Entry to P,O- and P,N-Type Heterocyclic Tertiary Phosphine Ligands and...

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ChemInform 2011, 42, issue 45 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Polyphenyl derivatives Q 0700 DOI: 10.1002/chin.201145079 One-Step Entry to P,O- and P,N-Type Heterocyclic Tertiary Phosphine Ligands and Application in Suzuki—Miyaura Cross-Coupling Reactions. — Furanylphos- phine ligand FPL is efficiently used for the coupling of various aryl iodides and bro- mides with phenylboronic acid (II), low yields are observed for aryl chlorides. For a wide range of electron-deficient, electron-rich and ortho-substituted chlorobenzene derivatives better results are achieved using pyridine ligand PPL. — (ULLAH, E.; MCNULTY*, J.; KENNEDY, C.; ROBERTSON, A.; Org. Biomol. Chem. 9 (2011) 12, 4421-4424, http://dx.doi.org/10.1039/c1ob05426k ; Dep. Chem., McMaster Univ., Hamilton, Ont. L8S 4M1, Can.; Eng.) — S. Adam 45- 079

Transcript of ChemInform Abstract: One-Step Entry to P,O- and P,N-Type Heterocyclic Tertiary Phosphine Ligands and...

Page 1: ChemInform Abstract: One-Step Entry to P,O- and P,N-Type Heterocyclic Tertiary Phosphine Ligands and Application in Suzuki—Miyaura Cross-Coupling Reactions.

Polyphenyl derivativesQ 0700 DOI: 10.1002/chin.201145079

One-Step Entry to P,O- and P,N-Type Heterocyclic Tertiary Phosphine Ligands and Application in Suzuki—Miyaura Cross-Coupling Reactions. — Furanylphos-phine ligand FPL is efficiently used for the coupling of various aryl iodides and bro-mides with phenylboronic acid (II), low yields are observed for aryl chlorides. For a wide range of electron-deficient, electron-rich and ortho-substituted chlorobenzene derivatives better results are achieved using pyridine ligand PPL. — (ULLAH, E.; MCNULTY*, J.; KENNEDY, C.; ROBERTSON, A.; Org. Biomol. Chem. 9 (2011) 12, 4421-4424, http://dx.doi.org/10.1039/c1ob05426k ; Dep. Chem., McMaster Univ., Hamilton, Ont. L8S 4M1, Can.; Eng.) — S. Adam

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ChemInform 2011, 42, issue 45 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim