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ChemInform Abstract: Novel Sandwiched Intermetallic Selenoantimonates: Soft Synthesis and...
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1999 copper, Cu copper, Cu I 7400 04 - 031 Novel Sandwiched Intermetallic Selenoantimonates: Soft Synthesis and Characterization of Cu 2 SbSe 3 ·0.5en and Cu 2 SbSe 3 ·en. — Single crystals of the novel two-dimensional intermetallic copper selenoantimonates (V) and (VII) are obtained by soft solvothermal reactions. Both compounds crystallize in the monoclinic system, space group P2 1 /n with Z = 4 for (V) and space group Pn with Z = 2 for (VII). The structures consist of Cu 2 SbSe 3 layers separated by free ethylenediamine layers. The intermetallic layers are very similar in the two structures, but the solvent orientations are different. Both compounds contain Cu atoms with mixed valence and prove to be semiconductors. — (CHEN, Z.; DILKS, R. E.; WANG, R.-J.; LU, J. Y.; LI, J.; Chem. Mater. 10 (1998) 10, 3184-3188; Dep. Chem., Rutgers Univ., Camden, NJ 08102, USA; EN) 1
Transcript of ChemInform Abstract: Novel Sandwiched Intermetallic Selenoantimonates: Soft Synthesis and...
1999 copper, Cu
copper, CuI 7400
04 - 031Novel Sandwiched Intermetallic Selenoantimonates: Soft Synthesisand Characterization of Cu2SbSe3·0.5en and Cu2SbSe3·en. — Singlecrystals of the novel two-dimensional intermetallic copper selenoantimonates(V) and (VII) are obtained by soft solvothermal reactions. Both compoundscrystallize in the monoclinic system, space group P21/n with Z = 4 for (V)and space group Pn with Z = 2 for (VII). The structures consist of Cu2SbSe3layers separated by free ethylenediamine layers. The intermetallic layers arevery similar in the two structures, but the solvent orientations are different.Both compounds contain Cu atoms with mixed valence and prove to besemiconductors. — (CHEN, Z.; DILKS, R. E.; WANG, R.-J.; LU, J. Y.; LI, J.;Chem. Mater. 10 (1998) 10, 3184-3188; Dep. Chem., Rutgers Univ., Camden,NJ 08102, USA; EN)
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