ChemInform Abstract: Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to...
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ChemInform 2011, 42, issue 49 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Praseodymium I 3000 DOI: 10.1002/chin.201149014 Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic— -Organic Hybrid Chains and Layers. — The crystal structures of compounds (III), (IV), and (V) are determined by single crystal XRD. (III) crystallizes in the hexagonal space group R3m with Z = 3. The structure contains a nearly perfect Td-symmetric [Pr4Sb12O18Cl17] 5- anionic nanocluster. (IV) crystallizes in the monoclinic space group P2 1 /c with Z = 4. The anionic clusters in (IV) are interconnected by the isophthalic acid ligands to form zigzag chains. (V) crystallizes in the monoclinic space group C2/c with Z = 4. Each [Pr4Sb12O18Cl 11] + cluster links to four adjacent clusters through four tere- phthalic acid ligands forming a two-dimensional wavelike layer. — (HU, B.; FENG, M.-L.; LI, J.-R.; LIN, Q.-P.; HUANG*, X.-Y.; Angew. Chem., Int. Ed. 50 (2011) 35, 8110-8113, http://dx.doi.org/10.1002/anie.201103127 ; State Key Lab. Struct. Chem., Fujian Inst. Res. Struct. Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop. Rep. China; Eng.) — W. Pewestorf 49- 014
Transcript of ChemInform Abstract: Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to...
PraseodymiumI 3000 DOI: 10.1002/chin.201149014
Lanthanide Antimony Oxohalides: From Discrete Nanoclusters to Inorganic—-Organic Hybrid Chains and Layers. — The crystal structures of compounds (III), (IV), and (V) are determined by single crystal XRD. (III) crystallizes in the hexagonal space group R3m with Z = 3. The structure contains a nearly perfect Td-symmetric [Pr4Sb12O18Cl17]
5- anionic nanocluster. (IV) crystallizes in the monoclinic space group P21/c with Z = 4. The anionic clusters in (IV) are interconnected by the isophthalic acid ligands to form zigzag chains. (V) crystallizes in the monoclinic space group C2/c with Z = 4. Each [Pr4Sb12O18Cl11]
+ cluster links to four adjacent clusters through four tere-phthalic acid ligands forming a two-dimensional wavelike layer. — (HU, B.; FENG, M.-L.; LI, J.-R.; LIN, Q.-P.; HUANG*, X.-Y.; Angew. Chem., Int. Ed. 50 (2011) 35, 8110-8113, http://dx.doi.org/10.1002/anie.201103127 ; State Key Lab. Struct. Chem., Fujian Inst. Res. Struct. Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop. Rep. China; Eng.) — W. Pewestorf
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ChemInform 2011, 42, issue 49 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
