ChemInform Abstract: KCuMIVF7 (MIV: Zr4+, Hf4+), a New Type of Structure.
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2000 structure structure (solids and liquids) D 2000 49 - 002 KCuM IV F 7 (M IV : Zr 4+ , Hf 4+ ), a New Type of Structure. — The title compounds are prepared by heating mixtures of KF, CuF 2 , and ZrF 4 or HfF 4 , respectively (gold tube, 700 ◦ C, 3 weeks). KCuZrF 7 and KCuHfF 7 are isotypic and crystallize in the orthorhombic space group Cmcm with Z = 8, as revealed by single crystal XRD. Cu 2+ is coordinated by six F - ions forming a distorted octahedron. Zr 4+ is surrounded by eight F - forming a distorted cubic antiprism. The coordination number of potassium is 10. The CuF 6 octahedra and the ZrF 8 antiprisms both form chains along the [001] direction which are connected to layers perpendicular to [100] by sharing edges. — (KRAUS, M.; MUELLER, B. G.; Z. Anorg. Allg. Chem. 626 (2000) 9, 1929-1933; Inst. Anorg. Anal. Chem., Justus-Liebig-Univ., D-35392 Giessen, Germany; DE) 1
Transcript of ChemInform Abstract: KCuMIVF7 (MIV: Zr4+, Hf4+), a New Type of Structure.
2000 structure
structure (solids and liquids)D 2000
49 - 002KCuMIV F7 (MIV : Zr4+, Hf4+), a New Type of Structure. — Thetitle compounds are prepared by heating mixtures of KF, CuF2, and ZrF4 orHfF4, respectively (gold tube, 700 ◦C, 3 weeks). KCuZrF7 and KCuHfF7 areisotypic and crystallize in the orthorhombic space group Cmcm with Z = 8, asrevealed by single crystal XRD. Cu2+ is coordinated by six F− ions forming adistorted octahedron. Zr4+ is surrounded by eight F− forming a distorted cubicantiprism. The coordination number of potassium is 10. The CuF6 octahedraand the ZrF8 antiprisms both form chains along the [001] direction which areconnected to layers perpendicular to [100] by sharing edges. — (KRAUS,M.; MUELLER, B. G.; Z. Anorg. Allg. Chem. 626 (2000) 9, 1929-1933; Inst.Anorg. Anal. Chem., Justus-Liebig-Univ., D-35392 Giessen, Germany; DE)
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