ChemInform Abstract: Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes.

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ChemInform 2010, 41, issue 51 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Epoxidation O 0218 DOI: 10.1002/chin.201051035 Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes. — An improved method is presented for the Fe-catalyzed epoxidation of olefins. High chemoselectivity is achieved using a catalytic complex of FeCl3, H2-pydic and a novel formamidine lig- and. The method is effective for styrene derivatives (I) and conjugated dienes like (V). — (SCHROEDER, K.; ENTHALER, S.; JOIN, B.; JUNGE, K.; BELLER*, M.; Adv. Synth. Catal. 352 (2010) 10, 1771-1778, DOI:10.1002/adsc.201000091 ; Leibniz-Inst. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mischke 51- 035

Transcript of ChemInform Abstract: Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes.

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EpoxidationO 0218 DOI: 10.1002/chin.201051035

Iron-Catalyzed Epoxidation of Aromatic Olefins and 1,3-Dienes. — An improved method is presented for the Fe-catalyzed epoxidation of olefins. High chemoselectivity is achieved using a catalytic complex of FeCl3, H2-pydic and a novel formamidine lig-and. The method is effective for styrene derivatives (I) and conjugated dienes like (V). — (SCHROEDER, K.; ENTHALER, S.; JOIN, B.; JUNGE, K.; BELLER*, M.; Adv. Synth. Catal. 352 (2010) 10, 1771-1778, DOI:10.1002/adsc.201000091 ; Leibniz-Inst. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mischke

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ChemInform 2010, 41, issue 51 © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim