ChemInform Abstract: Hexamethyldisilazane (HMDS) Promotes Highly Efficient Oxidative Coupling of...

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2002 polysulfides polysulfides (benzene compounds) Q 0575 24 - 101 Hexamethyldisilazane (HMDS) Promotes Highly Efficient Oxida- tive Coupling of Thiols by DMSO under Nearly Neutral Reaction Conditions. A reagent combination of DMSO and HMDS permits the convenient oxidation of thiols to their disulfides. The neutrality of the reaction medium opens a potential use of acid sensitive substrates. — (KARIMI, BABAK; ZAREYEE, DARYOUSH; Synlett (2002) 2, 346-348; Dep. Chem., Inst. Adv. Stud. Basic Sci., Gava Zang, Zanjan, Iran; EN) 1

Transcript of ChemInform Abstract: Hexamethyldisilazane (HMDS) Promotes Highly Efficient Oxidative Coupling of...

Page 1: ChemInform Abstract: Hexamethyldisilazane (HMDS) Promotes Highly Efficient Oxidative Coupling of Thiols by DMSO under Nearly Neutral Reaction Conditions.

2002 polysulfides

polysulfides (benzene compounds)Q 0575

24 - 101Hexamethyldisilazane (HMDS) Promotes Highly Efficient Oxida-tive Coupling of Thiols by DMSO under Nearly Neutral ReactionConditions. — A reagent combination of DMSO and HMDS permits theconvenient oxidation of thiols to their disulfides. The neutrality of the reactionmedium opens a potential use of acid sensitive substrates. — (KARIMI,BABAK; ZAREYEE, DARYOUSH; Synlett (2002) 2, 346-348; Dep. Chem.,Inst. Adv. Stud. Basic Sci., Gava Zang, Zanjan, Iran; EN)

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