ChemInform Abstract: Gold-Catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers Using...

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ChemInform 2009, 40, issue 46 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Carboxylic acid esters Q 0530 Gold-Catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers Using Molecular Oxygen. Simultaneous Degradation of C—H and Single and Triple Carbon—Carbon Bonds under Ambient Conditions. — The oxidation of alkynyl ethers in the presence of a gold catalyst proceeds with simultaneous cleavage of C—H, C—C, and C≡C bonds to afford esters (II) and (V). — (DAS, A.; CHAUDHURI, R.; LIU*, R.-S.; Chem. Commun. (Cambridge) 2009, 27, 4046-4048; Dep. Chem., Natl. Tsing Hua Univ., Hsinchu 30043, Taiwan; Eng.) — R. Staver 46- 080

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Carboxylic acid estersQ 0530 Gold-Catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers Using

Molecular Oxygen. Simultaneous Degradation of C—H and Single and Triple Carbon—Carbon Bonds under Ambient Conditions. — The oxidation of alkynyl ethers in the presence of a gold catalyst proceeds with simultaneous cleavage of C—H, C—C, and C≡C bonds to afford esters (II) and (V). — (DAS, A.; CHAUDHURI, R.; LIU*, R.-S.; Chem. Commun. (Cambridge) 2009, 27, 4046-4048; Dep. Chem., Natl. Tsing Hua Univ., Hsinchu 30043, Taiwan; Eng.) — R. Staver

46- 080

ChemInform 2009, 40, issue 46 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Supporting Information - Royal Society of Chemistry · S1 Supporting Information Gold-catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers using Molecular Oxygen. Simultaneous

Supporting Information - Royal Society of Chemistry · S1 Supporting Information Gold-catalyzed Oxidative Cleavage of Aryl-Substituted Alkynyl Ethers using Molecular Oxygen. Simultaneous

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Jacobsen asymmetric epoxidation of olefins R = aryl, alkenyl, alkynyl R’ = bulky group Metal complexes of porphyrins, salens, phthlocyanins catalyze the.

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