ChemInform Abstract: First Total Synthesis and Absolute Configuration of...
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2001 terpenes terpenes U 0200 28 - 181 First Total Synthesis and Absolute Configuration of (-)-13-Hydroxy- 11,12-epoxy-neocembrene. — The enantioselective synthesis of the naturally occurring cembranoid (I) is achieved via a macro-olefination strategy employing titanium-mediated Mc Murry coupling as a key step from (S)-(+)- carvone. The absolute configuration of the epoxy ring is determined as (11S, 12S). — (ZHANG, TAO; LIU, ZUOSHENG; LI, YULIN; Synthesis (2001) 3, 393-398; Natl. Lab. Appl. Org. Chem., Lanzhou Univ., Lanzhou 730000, Peop. Rep. China; EN) 1
Transcript of ChemInform Abstract: First Total Synthesis and Absolute Configuration of...
2001 terpenes
terpenesU 0200
28 - 181First Total Synthesis and Absolute Configuration of (-)-13-Hydroxy-11,12-epoxy-neocembrene. — The enantioselective synthesis of thenaturally occurring cembranoid (I) is achieved via a macro-olefination strategyemploying titanium-mediated Mc Murry coupling as a key step from (S)-(+)-carvone. The absolute configuration of the epoxy ring is determined as (11S,12S). — (ZHANG, TAO; LIU, ZUOSHENG; LI, YULIN; Synthesis (2001) 3,393-398; Natl. Lab. Appl. Org. Chem., Lanzhou Univ., Lanzhou 730000, Peop.Rep. China; EN)
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