ChemInform Abstract: Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System...

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ChemInform 2009, 40, issue 39 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim www.cheminform.wiley-vch.de Oxirane derivatives R 0030 Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System for Epoxidation of Olefins with Hydrogen Peroxide. — An improved Fe—N-arylimidazole catalytic system is developed for the epoxidation of a wide range of aromatic and aliphatic olefins with hydrogen peroxide. In general, high chemoselec- tivity is achieved. The reaction mechanism is discussed in detail. — (SCHROEDER, K.; ENTHALER, S.; BITTERLICH, B.; SCHULZ, T.; SPANNENBERG, A.; TSE, M. K.; JUNGE, K.; BELLER*, M.; Chem. Eur. J. 15 (2009) 22, 5471-5481; Leibniz-Inst. Org. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mischke 39- 099

Transcript of ChemInform Abstract: Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System...

Page 1: ChemInform Abstract: Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System for Epoxidation of Olefins with Hydrogen Peroxide.

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Oxirane derivativesR 0030 Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst

System for Epoxidation of Olefins with Hydrogen Peroxide. — An improved Fe—N-arylimidazole catalytic system is developed for the epoxidation of a wide range of aromatic and aliphatic olefins with hydrogen peroxide. In general, high chemoselec-tivity is achieved. The reaction mechanism is discussed in detail. — (SCHROEDER, K.; ENTHALER, S.; BITTERLICH, B.; SCHULZ, T.; SPANNENBERG, A.; TSE, M. K.; JUNGE, K.; BELLER*, M.; Chem. Eur. J. 15 (2009) 22, 5471-5481; Leibniz-Inst. Org. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mischke

39- 099

ChemInform 2009, 40, issue 39 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim