ChemInform Abstract: Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System...
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![Page 1: ChemInform Abstract: Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst System for Epoxidation of Olefins with Hydrogen Peroxide.](https://reader035.fdocuments.us/reader035/viewer/2022080306/575003d51a28ab11489b56af/html5/thumbnails/1.jpg)
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Oxirane derivativesR 0030 Design and Mechanistic Studies on a Biomimetic Iron—Imidazole Catalyst
System for Epoxidation of Olefins with Hydrogen Peroxide. — An improved Fe—N-arylimidazole catalytic system is developed for the epoxidation of a wide range of aromatic and aliphatic olefins with hydrogen peroxide. In general, high chemoselec-tivity is achieved. The reaction mechanism is discussed in detail. — (SCHROEDER, K.; ENTHALER, S.; BITTERLICH, B.; SCHULZ, T.; SPANNENBERG, A.; TSE, M. K.; JUNGE, K.; BELLER*, M.; Chem. Eur. J. 15 (2009) 22, 5471-5481; Leibniz-Inst. Org. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mischke
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ChemInform 2009, 40, issue 39 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim