ChemInform Abstract: Anion-Molecule Approaches to Non-Kekule Molecules: The Radical Anion of...

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1997 intermediates intermediates (and their reactions) O 0190 03 - 094 Anion-Molecule Approaches to Non-Kekule Molecules: The Radical Anion of Cyclopentadienylidenetrimethylenemethane and Deriva- tives. The gas-phase ion-molecule reaction of the fulvene (I) with the atomic oxygen radical anion generates the title radical anion which is characterized by photoelectron spectroscopic experiments and reactivity studies. It is shown that the derivative can react as a radical as well as an anion. (ZHAO, J.; DOWD, P.; GRABOWSKI, J. J.; J. Am. Chem. Soc. 118 (1996) 37, 8871-8874; Dep. Chem., Univ. Pittsburgh, Pittsburgh, PA 15260, USA; EN) 1

Transcript of ChemInform Abstract: Anion-Molecule Approaches to Non-Kekule Molecules: The Radical Anion of...

1997 intermediates

intermediates (and their reactions)O 0190

03 - 094Anion-Molecule Approaches to Non-Kekule Molecules: The RadicalAnion of Cyclopentadienylidenetrimethylenemethane and Deriva-tives. — The gas-phase ion-molecule reaction of the fulvene (I) withthe atomic oxygen radical anion generates the title radical anion which ischaracterized by photoelectron spectroscopic experiments and reactivity studies.It is shown that the derivative can react as a radical as well as an anion. —(ZHAO, J.; DOWD, P.; GRABOWSKI, J. J.; J. Am. Chem. Soc. 118 (1996)37, 8871-8874; Dep. Chem., Univ. Pittsburgh, Pittsburgh, PA 15260, USA;EN)

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