ChemInform Abstract: A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen...

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ChemInform 2011, 42, issue 21 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Oxirane derivatives R 0030 DOI: 10.1002/chin.201121096 A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature. — A novel method is developed using air as the oxidant. In- terestingly, both trans- and cis-olefins give only trans epoxides (II) as the products. — (SCHROEDER, K.; JOIN, B.; AMALI, A. J.; JUNGE, K.; RIBAS, X.; COSTAS, M.; BELLER*, M.; Angew. Chem., Int. Ed. 50 (2011) 6, 1425-1429, http://dx.doi.org/10.1002/anie.201004623 ; Leibniz-Inst. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mais 21- 096

Transcript of ChemInform Abstract: A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen...

Page 1: ChemInform Abstract: A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature.

Oxirane derivativesR 0030 DOI: 10.1002/chin.201121096

A Biomimetic Iron Catalyst for the Epoxidation of Olefins with Molecular Oxygen at Room Temperature. — A novel method is developed using air as the oxidant. In-terestingly, both trans- and cis-olefins give only trans epoxides (II) as the products. — (SCHROEDER, K.; JOIN, B.; AMALI, A. J.; JUNGE, K.; RIBAS, X.; COSTAS, M.; BELLER*, M.; Angew. Chem., Int. Ed. 50 (2011) 6, 1425-1429, http://dx.doi.org/10.1002/anie.201004623 ; Leibniz-Inst. Katal., Univ. Rostock, D-18059 Rostock, Germany; Eng.) — Mais

21- 096

ChemInform 2011, 42, issue 21 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim