Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of...

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Chemical Weathering

Transcript of Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of...

Page 1: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering

Page 2: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering

Page 3: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction  

Page 4: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview:

Decomposition alters minerals into more stable minerals or substances at the earth’s surface.

Page 5: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction

Page 6: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction

an element loses electrons to an Oxygen ion

Page 7: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction

an element loses electrons to an Oxygen ion

2Fe2++ 4HCO3 -1 + 1/2O2 + 2H20 >>>> Fe2O3 + 4H2CO3

Page 8: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction

an element loses electrons to an Oxygen ion

2Fe2++ 4HCO3 -1 + 1/2O2 + 2H20 >>>> Fe2O3 + 4H2CO3

Ferrous bicarbonate ferric carbonic acid Iron Iron

Page 9: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution

Page 10: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution

The process of chemical weathering by which earth material passes into solution by removal of its atoms.

Page 11: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution

The process of chemical weathering by which earth material passes into solution by removal of its atoms.

Most well-known:

CO2 + H2O = H2CO3

Carbon dioxide water carbonic acid

Page 12: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution

The process of chemical weathering by which earth material passes into solution by removal of its atoms.

Most well-known:

CO2 + H2O = H2CO3

Carbon dioxide water carbonic acid

CaCO3 + H2CO3 = Ca+ + HCO3-

Limestone + carbonic acid = calcium ions + bicarbonate

Page 13: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution

The process of chemical weathering by which earth material passes into solution by removal of its atoms.

Most well-known: Limestone + water + carbonic acid = calcium ions + CO2 + bicarbonate

pH controls solubility….

Page 14: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis

Describes the reaction between minerals and hydrogen“converting primary minerals into secondary minerals”

Page 15: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis

Describes the reaction between minerals and hydrogen“converting primary minerals into secondary minerals” 2 KAlSi3O8 + 2H+ + 9H2O >>>> H4Al2Si2O9 + 4H4SiO4 + 2K+

orthoclase kaolinite silica acid

Page 16: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange

involves the substitution of ions in solution for those held by mineral grains.

 

Page 17: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Cation exchange capacity (CEC): the capability for absorbing cations

“High Base Saturation”…..the % of exchange sites occupied by cationsother than H+.”

In acid soils, H+ replaces the cations; but in basic soils, H+ replace by cations.

Page 18: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview

Page 19: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview * Mobility of cations

(Ca+2, Mg2+, Na+) > K+ > Fe2+ > Si4+ > Ti 4+> Fe 3+> Al 3

Page 20: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview * Mobility of cations

(Ca+2, Mg2+, Na+) > K+ > Fe2+ > Si4+ > Ti 4+> Fe 3+> Al 3

* All related to the ionic potentialvalence (z) / ionic radius

Page 21: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Page 22: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Page 23: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

valence (z) / ionic radiusvery mobile = less than 3very immobile + greater than 9.5

 

Page 24: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview B. Leaching“The separation, selective removal, or dissolving out of soluble constituents from a rock by the natural action of percolating water”

Page 25: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview B. Leaching“The separation, selective removal, or dissolving out of soluble constituents from a rock by the natural action of percolating water”

The process is dependent on CLIMATE and SOIL PROPERTIES

Page 26: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview B. Leaching C. pH

Page 27: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview B. Leaching C. pH

* The mobility of ions is controlled by pH

Page 28: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

pH controls solubility….

Page 29: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Page 30: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering III. Mobility A. Overview B. Leaching C. pH D. Fixation/Retardation

Page 31: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

 III. Mobility A. Overview B. Leaching C. pH D. Fixation/Retardation E. Chelation  

Page 32: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical WeatheringIV. Degree and Rate of Decomposition A. Mineral Stability

Page 33: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Page 34: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical Weathering 

I. Introduction II. Process of Decomposition A. Overview: B. Oxidation and Reduction C. Solution D. Hydrolysis E. Ion Exchange III. Mobility A. Overview B. Leaching C. pH D. Fixation/Redardation E. Chelation IV. Degree and Rate of Decomposition A. Mineral Stability B. Secondary Minerals

Page 35: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.
Page 36: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.

Chemical WeatheringIV. Degree and Rate of Decomposition A. Mineral Stability B. Secondary Minerals C. Estimates based on chemical analysis 

Page 37: Chemical Weathering. I. Introduction Chemical Weathering I. Introduction II. Process of Decomposition A. Overview: Decomposition alters minerals into.