Chemical Safety on the Job

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Chemical Safety on the Job GLOBALLY HARMONIZED 11-2011

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GLOBALLY HARMONIZED. Chemical Safety on the Job. 11-2011. Why HAZCOM ???. Synthron. Dermatitis. Global Harmonization. Adopted 4-26-2012 New MSDS (New name SDS Safety Data Sheet. 1. Standardized format and information 2. 16 Sections - PowerPoint PPT Presentation

Transcript of Chemical Safety on the Job

Page 1: Chemical Safety on the Job

Chemical Safety on the Job

GLOBALLY HARMONIZED

11-2011

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Why HAZCOM ???

Synthron

Dermatitis

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March 20, 2012US Department of Labor's OSHA revises Hazard Communication StandardRegulation protects workers from dangerous chemicals,helps American businesses compete worldwideWASHINGTON –

To better protect workers from hazardous chemicals, the U.S. Department of Labor's Occupational Safety and Health Administration has revised its Hazard Communication Standard, aligning it with the United Nations' global chemical labeling system. The new standard, once implemented, will prevent an estimated 43 deaths and result in an estimated $475.2 million in enhanced productivity for U.S. businesses each year.

"Exposure to hazardous chemicals is one of the most serious dangers facing American workers today," said Secretary of Labor Hilda L. Solis. "Revising OSHA's Hazard Communication Standard will improve the quality, consistency and clarity of hazard information that workers receive, making it safer for workers to do their jobs and easier for employers to stay competitive in the global marketplace."

The Hazard Communication Standard, being revised to align with the United Nations' Globally Harmonized System of Classification and Labeling of Chemicals, will be fully implemented in 2016 and benefit workers by reducing confusion about chemical hazards in the workplace, facilitating safety training and improving understanding of hazards, especially for low literacy workers. OSHA's standard will classify chemicals according to their health and physical hazards, and establish consistent labels and safety data sheets for all chemicals made in the United States and imported from abroad.

The revised standard also is expected to prevent an estimated 585 injuries and illnesses annually. It will reduce trade barriers and result in estimated annualized benefits in productivity improvements for American businesses that regularly handle, store and use hazardous chemicals, as well as cost savings of $32.2 million for American businesses that periodically update safety data sheets and labels for chemicals covered under the standard.

"OSHA's 1983 Hazard Communication Standard gave workers the right to know. As one participant expressed during our rulemaking process, this update will give them the right to understand, as well," said Assistant Secretary of Labor for Occupational Safety and Health Dr. David Michaels.

During the transition period to the effective completion dates noted in the standard, chemical manufacturers, importers, distributors and employers may comply with either 29 Code of Federal Regulations 1910.1200 (the final standard), the current standard or both.

The final rule revising the standard is available at http://s.dol.gov/P1*.

Further information for workers, employers and downstream users of hazardous chemicals can be reviewed at OSHA's Hazard Communication Safety and Health topics at http://www.osha.gov/dsg/hazcom/index.html, which includes links to OSHA's revised Hazard Communication Standard and guidance materials such as Q and A's, OSHA fact sheet and Quick Cards.

Under the Occupational Safety and Health Act of 1970, employers are responsible for providing safe and healthful workplaces for their employees. OSHA's role is to ensure these conditions for America's working men and women by setting and enforcing standards, and providing training, education and assistance. For more information, visit http://www.osha.gov.

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The standard that gave workers the right to know, now gives them

the right to understand. Safety & Health Topics Page: Hazard Communication

Labeling Safety Data Sheets Pictograms Effective Dates

Highlights: HCS / GHS Final Rule

Federal Register: The Final Rule was filed on March 20th at the Office of the Federal Register and available for viewing on their Public Electronic Inspection Desk. The Federal Register published the final rule on March 26, 2012. The effective date of the final rule is 60 days after the date of publication.

Federal Register [PDF, 52 MB] Comparison of Existing and Revised HCS

Side-by-side Redline Strikeout of the Regulatory Text

Press Release: US Department of Labor's OSHA publishes final rule to update the Hazard Communication Standard (HCS)

Guidance OSHA Briefs [PDF 263 KB] Fact Sheet Quick Cards

"Exposure to hazardous chemicals is one of the most serious threats facing American workers today," said U.S. Secretary of Labor Hilda Solis. "Revising OSHA's Hazard Communication standard will improve the quality and consistency of hazard information, making it safer for workers to do their jobs and easier for employers to stay competitive."

The Hazard Communication Standard (HCS) is now aligned with the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). This update to the Hazard Communication Standard (HCS) will provide a common and coherent approach to classifying chemicals and communicating hazard information on labels and safety data sheets. Once implemented, the revised standard will improve the quality and consistency of hazard information in the workplace, making it safer for workers by providing easily understandable information on appropriate handling and safe use of hazardous chemicals. This update will also help reduce trade barriers and result in productivity improvements for American businesses that regularly handle, store, and use hazardous chemicals while providing cost savings for American businesses that periodically update safety data sheets and labels for chemicals covered under the hazard communication standard.

Hazard Communication Standard In order to ensure chemical safety in the workplace, information about the

identities and hazards of the chemicals must be available and understandable to workers. OSHA's Hazard Communication Standard (HCS) requires the development and dissemination of such information:

Chemical manufacturers and importers are required to evaluate the hazards of the chemicals they produce or import, and prepare labels and safety data sheets to convey the hazard information to their downstream customers;

All employers with hazardous chemicals in their workplaces must have labels and safety data sheets for their exposed workers, and train them to handle the chemicals appropriately.

Major changes to the Hazard Communication Standard Hazard classification: Provides specific criteria for classification of health and physical hazards, as well as classification of

mixtures. Labels: Chemical manufacturers and importers will be required to provide a label that includes a harmonized signal word,

pictogram, and hazard statement for each hazard class and category. Precautionary statements must also be provided. Safety Data Sheets: Will now have a specified 16-section format. Information and training: Employers are required to train workers by December 1, 2013 on the new labels elements and

safety data sheets format to facilitate recognition and understanding.

Dr. David Michaels discusses the publication of the Final Rule for

Hazard Communication [Video | Statement]

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Global Harmonization

• Adopted 4-26-2012• New MSDS (New name SDS Safety Data

Sheet.1. Standardized format and information2. 16 Sections 3. Pictograph use and ease of interpretation so it can be used worldwide.

• New labels (2), using pictographs, signal words and hazard statement.

Primarily affects companies that make MSDS.

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Global Benefits of Harmonization

– Countries, international organizations, chemical producers and users of chemicals all benefit.• Enhance protection of humans and

environment.• Facilitate international trade in

chemicals.• Reduce need for testing and

evaluation.• Assist countries and international

organizations to ensure the sound management of chemicals.

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Effective Completion Date Requirement(s) Who

December 1, 2013 Train employees on the new label elements and safety data

sheet (SDS) format.

Employers

June 1, 2015*

December 1, 2015

Compliance with all modified provisions of this final rule,

except: The Distributor shall not ship

containers labeled by the chemical manufacturer or

importer unless it is a GHS label

Chemical manufacturers, importers, distributors and employers

June 1, 2016 Update alternative workplace labeling and hazard

communication program as necessary, and provide

additional employee training for newly identified physical or

health hazards.

Employers

Transition Period to the effective completion dates noted above

May comply with either 29 CFR 1910.1200 (the final standard), or the current standard, or both

Chemical manufacturers, importers, distributors, and employers

Effective Dates

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Chemical Classification

• Test method neutral• Tiered approach for MIXTURE

classification– Classify based on data for actual

mixture– If data unavail use bridging to estimate

based on ingredient information

GHS classifies based on both Physical and Health Hazards…Environmental Hazards are also classified and labeled.

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Hazards of Chemicals…• There are 2 basic types of

chemical hazards– Physical Hazards– Health HazardsAs well as EnvironmentalHazards

• The first rule of Chemical safety is…• "Know what you are working • with and how to protect yourself • and others“

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Chemicals can enter the body through:

• your lungs if you breath fumes, mists or dust

• your skin if liquid or dust touches or spills on you or splashes in your eyes

• your mouth if you eat after handling chemicals

• accidental swallowing of a chemical

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HCS Physical Hazards…• Chemicals are classified as having

Physical Hazards if they are Explosive Compressed Gas Combustible Liquids Flammable Unstable Water Reactive Oxidizers

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GHS Physical Hazards• Explosives• Flammable

aerosols• Gasses under

pressure• Self reactive

substances• Pyrophoric liquids• Self heating

substances• Organic peroxides• Substances which

on water contact give flammable gasses

• Oxidizing solids

• Flammable gasses• Oxidizing gases• Flammable liquids• Flammable solids• Pyrophoric solids• Oxidizing liquids• Corrosive to metals

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Chemicals with Physical Hazards…

• Used only by trained employees

• Stored in a safe manner

• Never mixed with other chemicals unless by an approved procedure

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HCS Health Hazards• Chemicals are classified as being a

health hazard if they:Can cause cancerAre poisonous (toxic)Cause harm to your skin, internal

organs, or nervous systemAre corrosive - such as acidsCause allergic reactions after

repeated exposure

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Health Effects…

• Some chemicals affect specific organs such as your kidneys, liver, reproductive or nervous system.

THESE ORGANS ARE CALLED TARGET ORGANS…

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GHS Health Hazards• Acute toxicity (LD50’s

and LC 50’s)• Skin corrosion/

irritation• Serious eye damage/

eye irritation• Respiratory and skin

sensitizer• Germ cell

mutagenicity

• Reproductive toxicity• Carcinogenicity• Specific target organ

toxicity (STOT) single exposure

• Specific target organ toxicity (STOT) repeated exposure

• Aspiration hazard

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Current Flammable/ Combustible Classifications

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Labeling Comparison

OSHARequirements • Must contain: - identity of hazardous chemicals, - name/ address of responsible party, - appropriate hazard warnings. • • Exposure calculations not

permitted in determining whether a hazard must appear on a label.

• If there is potential for exposure, (other than in minute, trace or very small quantities), the hazard must be included when well-substantiated1.

GHSRequirements• Must contain: - product identifier, - name, address, telephone of responsible party - chemical identity - hazard pictograms, signal words, hazard statement, and precautionary information (precautionary information is not standardized yet).

• For labels,Hazard symbols, signal words, and hazard statements standardized assigned to each hazard category These standardized elements should not be subject to variation, and should appear on the GHS label.

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Labeling Comparison

OSHA

• Label Verbiage - No requirements for specific text if appropriate hazard warnings included. • • permits graphics:

pictures, symbols, or combination thereof on a label or other appropriate form which convey the specific physical or health hazard(s), including target organ effects, of the chemical(s) in the container(s)

• Hazards are considered for exposures under normal conditions of use or in foreseeable emergencies.

GHS

• Label Verbiage • • Each hazard has a

category, or set of categories, with corresponding pictograms, signal words, hazard and precautionary statements.

• • Displays all the hazard statements associated with the product/chemical.

• • “May be harmful if inhaled” is an example of a hazard warning. Provides guidance on using precautionary statements.

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Labeling ComparisonOSHA

• Signal Words American National Standards Institute's (ANSI) Standard Z129.1 provides much useful information for employers regarding product labels and is generally very helpful in complying with the HCS. ANSI recommends Caution, Warning, and Danger, in order of increasing severity. • Chronic Health Effects

Labeling Well substantiated chronic health hazards - for example, carcinogenicity, reproductive toxicity, or developmental toxicity – as well as target organ effects must be stated on the label. • Guidance ANSI Z129.1 standard, adherence is not required by law

GHS• Signal Words • GHS uses Warning and

Danger only. • Comprehensibility • The aim of harmonized

system is to present information in a manner audience can easily understand.

• Chronic Health Effects Labeling

• GHS has classification criteria for chronic health endpoints and standard statements for those hazard categories. "May cause damage to the liver through prolonged or repeated exposure by inhalation” is an example of a standard chronic health effect statement.

• Guidance • GHS is labeling requirement

for those countries/regions which adopt the GHS.

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Labeling ComparisonOSHA

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GHS

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In House LabelsAlternative labeling systems such as the National Fire Protection Association (NFPA) 704 Hazard Rating and the Hazardous Material Information System (HMIS) are permitted for workplace containers. However, the information supplied on these labels must be consistent with the revised HCS, e.g., no conflicting hazard warnings or pictograms.

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Uniform Labels…

• Pictures may be used to identify hazards and required protection

• This Information may also be on the Manufacturer’s label

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