Chapter - Chemical Bonding And Molecular Structure - … · Chapterwise Previous year Qs 27 CHAPTER...

Chapterwise Previous year Qs

27

CHAPTER

CHEMICAL BONDING AND

MOLECULAR STRUCTURE

1. The angle between the overlapping of one s-

orbital and one p-orbital is [1988] (a) 180 °

(b) 120 °

(c) 109° , 28'

(d) 120° , 60°

ANS: (A)

2. Equilateral shape has [1988] (a) sp hybridisation (b) sp2 hybridisation (c) sp3 hybridisaiton (d) sp3 hybridisation Ans: (b) 3. Which of the following molecule does not have a linear arrangement of atoms? (a) H2 S (b) C2H2 (c) BeH2 (d) CO2

Ans: (a)

4. Which of the following does not apply to

metallic bond? (a) Overlapping valence orbitals (b) Mobile valency electrons (c) Delocalized electrons (d) Highly directed bonds. Ans: (d) 5. In which one of the following molecules the central atom said to adopt sp2 hybridization? (a) BeF2 (b) BF3 (c) C2H2 (d) NH3

Ans: (b)

6. H2O has a non zero dipole moment while

BeF2 has zero dipole moment because (a) H2O molecule is linear while BeF2 is bent (b) BeF2 molecule is linear while H2O is bent (c) Fluorine has more electronegativity than oxygen (d) Beryllium has more electronegativity than oxygen.

Ans: (b) 7. Among LiCl, BeCl2 BCl3 and CCl4, the covalent bond character follows the order (a) LiCl < BeCl2 > BCl3 > CCl4 (b) BeCl2 < BCl3 < CCl4 < LiCl (c) LiCl < BeCl2 < BCl3 < CCl4 (d) LiCl > BeCl2 > BCl3 > CCl4

Ans: (c)

8. Which statement is NOTcorrect?

(a) Asigma bond is weaker than a S-bond. (b) Asigma bond is stronger than a S-bond. (c) Adouble bond is stronger than a single bond. (d) Adouble bond is shorter than a single bond. Ans: (a) 9. Which one shows maximum hydrogen bonding? (a) H2O (b) H2 Se (c) H2 S (d) HF. Ans: (d)

10. Linear combination of two hybridized

orbitals belonging to two atoms and each having one electron leads to a (a) Sigma bond (b) Double bond (c) Co-ordinate covalent bond (d) Pi bond. Ans: (a) 11. Which one of the following formulae does not correctly represent the bonding capacities of the two atoms involved?

(a)

(b)

(c)

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(d) Ans: (d) 12. In compound X, all the bond angles are exactly 109°28 ; X is (a) Chloromethane (b) Carbon tetrachloride (c) Iodoform (d) Chloroform. Ans: (d)

13. Which of the following bonds will be most

polar? (a) N– Cl (b) O– F (c) N– F (d) N– N Ans: (c) 14. Which one of the following has the shortest carbon carbon bond length? (a) Benzene (b) Ethene (c) Ethyne (d) Ethane Ans: (c) 15. Which structure is linear? (a) SO2 (b) CO2 (c) CO3-2

(d) SO4-2

Ans: (b)

16. Strongest hydrogen bond is shown by

(a) Water (b) Ammonia (c) Hydrogen fluoride (d) Hydrogen sulphide. Ans: (c) 17. Which of the following statements is not correct? (a) Double bond is shorter than a single bond (b) Sigma bond is weaker than a S(pi) bond (c) Double bond is stronger than a single bond (d) Covalent bond is stronger than hydrogen bond. Ans: (b) 18. Among the following which compound will show the highest lattice energy? (a) KF

(b) NaF (c) CsF (d) RbF Ans: (b) 19. Which one of the following is the correct order of interactions? (a) Covalent < hydrogen bonding < vander Waals < dipole-dipole (b) vander Waals < hydrogen bonding < dipole < covalent (c) vander Waals < dipole-dipole < hydrogen bonding < covalent (d) Dipole-dipole < vander Waals < hydrogen bonding < covalent. Ans: (b) 20. Strongest bond is in between (a) CsF (b) NaCl (c) Both (d) none of the above Ans: (a) 21. Mark the incorrect statement in the following (a) The bond order in the species O2, O2 + and O2 – decreases as O2+ > O2> O2- (b) The bond energy in a diatomic molecule always increases when an electron is lost (c) Electrons in antibonding M.O. contribute to repulsion between two atoms. (d) With increase in bond order, bond length decreases and bond strength increases. Ans: (b) 22. The weakest among the following types of bonds is (a) ionic (b) covalent (c) metallic (d) H–bond. Ans: (d) 23. Which of the following does not have a tetrahedral structure? (a) BH– 4

(b) BH3 (c) BH+4 (d) H2O Ans: (b)

24. Which of the following pairs will form the

most stable ionic bond? (a) Na and Cl


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(b) Mg and F (c) Li and F (d) Na and F Ans: (b) 25. Among the following orbital bonds, the angle is minimum between (a) sp3 bonds (b) px and py orbitals (c) H– O– Hin water (d) sp bonds. Ans: (b) 26. Linus Pauling received the Nobel Prize for his work on (a) atomic structure (b) photosynthesis (c) chemical bonds (d) thermodynamics Ans: (c) 27. The boiling point of p-nitrophenol is higher than that of o-nitrophenol because (a) NO2 group at p-position behave in a different way from that at o-position. (b) intramolecular hydrogen bonding exists in p-nitrophenol (c) there is intermolecular hydrogen bonding in p-nitrophenol (d) p-nitrophenol has a higher molecular weight than o-nitrophenol. Ans: (c) 28. The distance between the two adjacent carbon atoms is largest in (a) benzene (b) ethene (c) butane (d) ethyne Ans: (c) 29. Which of the following species is paramagnetic? (a) O22- (b) NO (c) CO (d) CN– Ans: (b) 30. The BCl3 is a planar molecule whereas NCl3 is pyramidal because (a) B-Cl bond is more polar than N-Cl bond (b) N-Cl bond is more covalent than B-Cl bond (c) nitrogen atom is smaller than boron atom (d) BCl3 has no lone pair but NCl3 has a lone pair of electrons

Ans: (d) 31. The correct order of the O–Obond length in O2, H2O2 and O3 is (a) O2>O3>H2O2 (b) O3>H2O2>O2 (c) O2> H2O2> O3 (d) H2O2> O3> O2 Ans: (d)

32.

(a) 0

(b) 1

(c) 2

(d) 3

Ans: (d)

33.

(a)

(b)

(c)

(d)

Ans: (c)

34. Which of the following compounds has a 3-

centre bond? (a) Diborane (b) Carbon dioxide (c) Boron trifluroide (d) Ammonia Ans: (a) 35. The low density of ice compared to water is due to (a) hydrogen-bonding interactions (b) dipole-dipole interactions (c) dipole-induced dipole interactions (d) induced dipole-induced dipole interactions Ans: (a) 36. The cylindrical shape of an alkyne is due to the fact that it has

(a)

(b)

(c)


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(d) Ans: (d) 37. N2 and O2 are converted into monocations, N2

+ and O2+ respectively. Which of the following

statements is wrong? (a) In N2, the N—Nbond weakens (b) In O2, the O—Obond order increases (c) In O2, paramagnetism decreases (d) N2

+ becomes diamagnetic Ans: (b) 38. The AsF5 molecule is trigonal bipyramidal. The hybrid orbitals used by the As atom for bonding are

(a)

(b)

(c)

(d) Ans: (c) 39. The number of anti-bonding electron pairs in O2-2 molecular ion on the basis of molecular orbital theory is, (Atomic number of Ois 8) (a) 5

(b) 2

(c) 3

(d) 4

Ans: (d)

40. Among the following which one is not

paramagnetic? [Atomic numbers: Be = 4, Ne = 10, As = 33, Cl = 17] (a) Cl– (b) Be+ (c) Ne+ 2

(d) As+ Ans: (a) 41. In PO43– ion, the formal charge on each oxygen atom and P—O bond order respectively are (a) –0.75, 0.6

(b) – 0.75, 1.0 (c) – 0.75, 1.25

(d) –3, 1.25

Ans: (c)

42. Which of the following molecules is planar?

(a) SF4 (b) XeF4 (c) NF3 (d) SiF4

Ans: (b)

43.

(a) bonding is 100% ionic in both the molecules (b) ABhas more ionic bond character than CD (c) ABhas lesser ionic bond character than CD (d) bonding is nearly covalent in both the molecules Ans: (c) 44. Which one of the following arrangements represents the increasing bond orders of the given species? (a) NO+ < NO< NO– < O2 – (b) O2 – < NO– < NO<NO+ (c) NO– < O2 – < NO< NO+ (d) NO< NO+ < O2 – < NO– Ans: (b) 45. Which one of the following has the pyramidal shape? (a) CO3 2 – (b) SO3 (c) BF3 (d) PF3

Ans: (d)

46. Which one of the following molecules will

form a linear polymeric structure due to hydrogen bonding? (a) NH3 (b) H2O (c) HCl (d) HF Ans: (d) 47. Among the following the electron deficient compound is: (a) BCl3 (b) CCl4 (c) PCl5 (d) BeCl2 Ans: (a)



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48. The relationship between the dissociation

energy of N2 and N2+ is:

(a) Dissociation energy of N2 + > dissociation energy of N2 (b) Dissociation energy of N2 = dissociation energy of N2

+

(c) Dissociation energy of N2 > dissociation energy of N2

+

(d) Dissociation energy of N2 can either be lower or higher than the dissociation energy of N2

+

Ans: (c)

49. Cation and anion combines in a crystal to

form following type of compound. (a) ionic (b) metallic (c) covalent (d) dipole-dipole Ans: (a) 50.

(a) NO2- (b) NO3- (c) 3 PO43- (d) 2 CO32-

Ans: (c)

51. In which of the following the bond angle is

maximum? (a) NH3 (b) SCl2 (c) NH4

+

(d) PCl3

Ans: (c)

52. Which of the following two are

isostructural? (a) NH3, BF3 (b) PCl5, ICl5 (c) XeF2, IF2 – (d) CO3 –2, SO3 –2

Ans: (c)

53. Main axis of a diatomic molecule is z,

molecular orbital px and py overlap to form which of the following orbital?

(a) (b)

(c)

(d) Ans: (a) 54.

(a) Electron density on Xwill increase and on Hwill decrease (b) In both electron density will decrease (c) In both electron density will increase (d) Electron density will decrease on Xand will increase on H Ans: (a) 55.

(a) NO3– (b) SO32– (c) BO33– (d) CO32– Ans: (b) 56. In NO3– ion number of bond pair and lone pair of electrons on nitrogen atom respectively are (a) 2, 2

(b) 3, 1 (c) 1, 3

(d) 4, 0

Ans: (d)

57. Which of the following statements is not

correct for sigma and pi-bonds formed between two carbon atoms? (a) Sigma-bond determines the direction between carbon atoms but a pi-bond has no primary effect in this regard (b) Sigma-bond is stronger than a pi-bond (c) Bond energies of sigma- and pi-bonds are of the order of 264 kJ/mol and 347 kJ/mol, respectively (d) Free rotation of atoms about a sigma-bond is allowed but not in case of a pi-bond Ans: (c) 58. Among the following the pair in which the two species are not isostructural is

(a)

(b)

(c)

(d) Ans: (a)


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59.

(a) three (b) two (c) six (d) four Ans: (a) 60. H2Ois dipolar, whereas BeF2 is not. It is because (a) the electronegativity of F is greater than that of O (b) H2O involves hydrogen bonding whereas BeF2 is a discrete molecule (c) H2O is linear and BeF2 is angular (d) H2O is angular and BeF2 is linear Ans: (d) 61.

(a)

(b)

(c)

(d) Ans: (a) 62. In BrF3 molecule, the lone pairs occupy equatorial positions to minimize (a) lone pair - bond pair repulsion only (b) bond pair - bond pair repulsion only (c) lone pair - lone pair repulsion and lone pair - bond pair repulsion (d) lone pair - lone pair repulsion only Ans: (c) 63. Which of the following is the electron deficient molecule? (a) C2H6 (b) B2H6 (c) SiH4 (d) PH3 Ans: (b)

64. The correct sequence of increasing covalent

character is represented by (a) LiCl < NaCl < BeCl2 (b) BeCl2 < LiCl < NaCl (c) NaCl < LiCl < BeCl2

(d) BeCl2 < NaCl < LiCl Ans: (c) 65. Which of the following molecules has trigonal planar geometry? (a) BF3 (b) NH3 (c) PCl3 (d) IF3

Ans: (a)

66. Which of the following would have a

permanent dipole moment? (a) SiF4 (b) SF4 (c) XeF4 (d) BF3

Ans: (b)

67. Which of the following is not a correct

statement? (a) The canonical structures have no real existence (b) Every AB5 molecule does in fact have square pyramidal structure (c) Multiple bonds are always shorter than corresponding single bonds (d) The electron-deficient molecules can act as Lewis acids Ans: (b) 68. The number of unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is (a) 3

(b) 4

(c) 1

(d) 2

Ans: (d)

69. In which of the following molecules all the

bonds are not equal? (a) BF3 (b) AlF3 (c) NF3 (d) ClF3

Ans: (d)



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70. The electronegativity difference between

Nand Fis greater than that between Nand Hyet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D) . This is because (a) in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions (b) in NH3 as well as NF3 the atomic dipole and bond dipole are in opposite directions (c) in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these are in the same direction (d) in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction Ans: (a) 71. Which of the following species has a linear shape? (a) SO2 (b) NO2

+ (c) O3 (d) NO2– Ans: (b) 72. Which of the following is not isostructural with SiCl4? (a) SO4 2 – (b) PO4 3 – (c) NH4 +

(d) SCl4

Ans: (d)

73. In which of the following pairs, the two

species are iso-structure? (a) SO3 2 – and NO3 – (b) BF3 an NF3 (c) BrO3 – and XeO3 (d) SF4 and XeF4

Ans: (c)

74. The correct order of C–O bond length

among CO, CO32- , CO2 is (a) CO< CO3 2 – < CO2 (b) CO3 2 – < CO2 < CO (c) CO< CO2 < CO3 2 – (d) CO2 < CO3 2 – < CO Ans: (c) 75. The angular shape of ozone molecule (O3) consists of: (a) 1 sigma and 2 pi bonds (b) 2 sigma and 2 pi bonds (c) 1 sigma and 1 pi bonds

(d) 2 sigma and 1 pi bonds Ans: (d) 76. The correct order of increasing bond angles in the following triatomic species is:

(a)

(b)

(c)

(d)

Ans: (b)

77. Four diatomic species are listed below in

different sequences. Which of these presents the correct order of their increasing bond order?

(a)

(b)

(c)

(d)

Ans: (d)

78. What is the dominant intermolecular force

or bond that must be overcome in converting liquid CH3OH to a gas? (a) Dipole-dipole interaction (b) Covalent bonds (c) London dispersion force (d) Hydrogen bonding Ans: (d) 79.

(a) NH2- and H2O (b) NO2- and H2O (c) BF3 and NO2- (d) NO2- and NH2- Ans: (c)

80. In which of the following pairs of

molecules/ ions, the central atoms have sp2 hybridization? (a) NO2- and NH3 (b) BF3 and NO2- (c) NH2- and HO2 (d) BF3 and NH2-

Ans: (b)

81. In which one of the following species the

central atom has the type of hybridization which


34

is not the same as that present in the other three? (a) SF4 (b) I3- (c) SbCl52– (d) PCl5

Ans: (c)

82. Some of the properties of the two species,

NO3- and H3O+ are described below. Which one of them is correct? (a) Similar in hybridization for the central atom with different structures. (b) Dissimilar in hybridization for the central atom with different structures. (c) isostructural with same hybridization for the central atom. (d) Isostructural with different hybridization for the central atom. Ans: (b) 83. In which of the following molecules the central atom does not have sp3 hybridization? (a) NH4+ (b) CH4 (c) SF4 (d) BF4–

Ans: (b)

84. Considering the state of hybridization of

carbon atoms, find out the molecule among the following which is linear?

(a)

(b)

(c)

(d)

Ans: (b)

85.

(a)

(b)

(c)

(d) Ans: (a)

86. Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?

(a)

(b)

(c)

(d) Ans: (d) 87. Bond order of 1.5 is shown by: (a) O2+ (b) O2- (c) O22- (d) O2

Ans: (b)

88. Which of the following species contains

three bond pairs and one lone pair around the central atom? (a) H2O (b) BF3 (c) NH2-

(d) PCI3

Ans: (a)

89. The pair of species with the same bond

order is: (a) O22–, B2 (b) O2+, NO+ (c) NO, CO (d) N2, O2

Ans: (a)

90. During change of O2 to O2- ion, the electron

adds on which one of the following orbitals?

(a)

(b)

(c) (d) Ans: (a) 91. Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them:

(a)

(b)

(c)

(d)


35

Ans: (d)

92. Which of the following is electron -

deficient? (a) (SiH3) 2

(b) (BH3) 2

(c) PH3 (d) (CH3) 2

Ans: (b)

93.

(a) H2O (b) SO2 (c) NO2 (d) CO2

Ans: (a)

94. Which of the following is paramagnetic?

(a) O2– (b) CN– (c) NO+ (d) CO Ans: (a) 95. XeF2 is isostructural with: (a) ICl2 – (b) SbCl3 (c) BaCl2 (d) TeF2

Ans: (a)

96. In which of the following pair both the

species have sp3 hybridization? (a) H2 S, BF3 (b) SiF4, BeH2 (c) NF3, H2O (d) NF3, BF3

Ans: (c)

97. The pair of species that has the same bond

order in the following is: (a) O2, B2 (b) CO, NO+ (c) NO–, CN– (d) O2, N2

Ans: (b)

98. In which of the following ionisation

processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic?

(a)

(b)

(c)

(d) Ans: (d) 99.

(a)

(b)

(c)

(d) Ans: (d)

1.

2.

3.

4.

5.

6.

7.


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8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

24.

25.


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26.

27.

28.

29.

30.

31.

32.

33.

34.

35.

36.

37.

38.


38

39.

40.

41.

42.

43.


39

44.

45.

46.

47.

48.

49.

50.

51.

52.

53.

54.


40

55.

56.

57.

58.

59.

60.

61.

62.


41

63.

64.

65.

66.

67.

68.

69.

70.


42

71.

72.

73.

74.

75.

76.

77. 78.


43

79.

80.

81.

82.

83.

84.

85.

86.

87. 88.

89.


44

90.

91.

92.

93.

94.

95.

96.

97.

98.


45

99.

Chapter - Chemical Bonding And Molecular Structure - … · Chapterwise Previous year Qs 27 CHAPTER...

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