Chapter 4 – History of the Atom - coleman general...
Transcript of Chapter 4 – History of the Atom - coleman general...
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Chapter 4 – History of the Atom
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Democritus 460 – 370 BC
n The first to propose the idea of an atom n Indivisible n Indestructible n Atom comes from the Greek
word atomos, which means “indestructible”
n Everything is made of them
This is my globe. His name is Globey.
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First Concept of an Atom
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Unfortunately… n Aristotle: opposed
Democritus and said all matter is a combo of n Earth n Air n Fire
n Water
n Why? Because Democritus had no proof.
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What about this
Democritus fellow?
Oh, don’t listen
to him, he cray-cray!
Some dude (Plato?) Aristotle
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I may be crazy, but I’m right! Time
will tell.
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Evidence for a new Atomic Theory:
1. Law of conservation of mass (matter): Mass is neither created or destroyed in a chemical reaction.
2. The law of Definite proportions: Chemical
compounds always have the same proportion of elements no matter how much of that compound you have.
2. Example: water is always 2 parts Hydrogen to 1 part Oxygen
3. The law of Multiple proportions: When two elements form compounds the ratio of their masses always form small whole numbers.
Example: Carbon and Oxygen combine to form CO or CO2, but never C0.5O1
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John Dalton 1766-1844 n Dalton’s Atomic Theory of Matter:
n Each element is composed of extremely small particles called atoms that are cannot be divided
n All the atoms of a given element are identical to each other, but they differ from those of any other element
n Atoms are neither created nor destroyed in any chemical reaction, just rearranged
n Atoms bond together to form compounds. A given compound always has the same relative numbers and kinds of atoms.
Do you like my fancy pants? You do? They’re called nickers.
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JJ Thompson 1856-1940
• Discovered electron 1897 – Cathode Ray Experiment
• Electrons are negatively charged
particles in an atom.
I’m not Teddy Roosevelt.
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The Cathode Ray Tube Experiment
video
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• Plum Pudding model 1904
• Electrons in a soup of positive charges
• Discovered isotopes 1913
Very interesting, there seems to be both positive and negative forces working
within an atom.
I really need a girlfriend.
JJ Thompson 1871-1937
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Plum Pudding Model
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Robert Millikan n In 1909 Robert Millikan
measured the exact electronic charge and mass of an electron in his Oil Drop Experiment.
How did I come up with this device? MAGIC, that’s how.
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The Oil Drop Experiment n Millikan concluded that:
• The mass of an electron is 9.10939 x 10-28 g
• Which is 1840
times smaller than that of the Proton n The electronic
charge on an electron is 1.60 x 10-19 C
• The relative charge on an electron is -1 (relative to a proton which is +1) video
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Ernest Rutherford 1871-1937
n Nuclear Model 1910 n Gold Foil Experiment
I’m kinda cool. No, really. Do you want to see my foil collection?
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Gold Foil Experiment • Alpha particles scatter from the gold foil.
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Rutherford’s Model (cont)
n Rutherford concluded that… n The Atom is mostly empty space n Has a region called the nucleus that…
n … is positively charged n … contains most of the mass of the atom
n The electrons are very small and orbit the nucleus in fixed paths.
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Rutheford’s Model (cont) This model is called the Nuclear Atom or
Nuclear Model
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• If we drew the atom to scale and made protons and neutrons a centimeter in diameter, then the electrons would be less than the diameter of a hair and the entire atom's diameter would be greater than the length of thirty football fields!
• 99.999999999999% of an atom's volume is just empty space!
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“Discovery” of Proton
n If there are negative charges in the atom, there must be positive charges balancing them out = PROTONS
n Ernest Rutherford gets credit for the proton because he named it.
n Moseley discovered atomic number
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Discovery of the Neutron
n In 1932, the English physicist James Chadwick (1891–1974) confirmed the existence of yet another subatomic particle: the neutron.
n Neutrons: n Located in nucleus with proton n Have no charge n mass nearly equal to a proton.
NEUTRon. Because It’s NEUTRAL, you see. Neutral… get it?
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Niels Bohr 1885-1962 n Planetary Model 1913
n Nucleus surrounded by orbiting electrons at different energy levels
n Electrons have definite orbits
n Utilized Planck’s Quantum Energy theory
n Worked on the Manhattan Project (US atomic bomb)
I’m not bohring. Get it? BOHRing?... I’ll just be over here exciting electrons…
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Bohr Model for Nitrogen
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Ernst Schrödinger 1887-1961
n Quantum Mechanical Model 1926 n Schrodinger: Used math to
describe the likely hood that an electron will be found in a particular place. (probability) n Electrons do not follow a fixed path. n Electrons are in electron clouds
called “orbitals”. n The denser parts of the clouds are
where they are more likely to be found.
Can I borrow your cat for a bit?
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Quantum Mechanical Theory
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n Uncertainty Principle: n You cannot know the location
and the momentum of an electron at the same time. n You cannot know exactly where
an electron will be. n Just where it might be based on
probability.
Werner Heisenberg 1901-1976
I don’t know how fast I’m going but I know where I am.
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Quantum Model of the Atom
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400 BC 1803 1904 1910 1913 1926
Niels Bohr
J J Thomson
Democratus
John Dalton
Schroedinger / Heisenberg
Ernest Rutherford
Atomic Theory