Chapter 4: Carbon Do Now: How many bonds can carbon form?
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Transcript of Chapter 4: Carbon Do Now: How many bonds can carbon form?
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Chapter 4: Carbon
Do Now:
How many bonds can carbon form?
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Carbon (The Backbone of life)• Body consists of carbon based
compounds (ex: proteins, lipids, carbohydrates, DNA)
• Carbon can form up to 4 bonds• Most frequent partners are O, H, N• Carbon chains form the skeleton of most
organic molecules
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Fig. 4-4
Hydrogen(valence = 1)
Oxygen(valence = 2)
Nitrogen(valence = 3)
Carbon(valence = 4)
H O N C
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Organic Chemistry• The study of compounds that contain
carbon
• Most contain Hydrogen atoms as well as carbon.
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• Carbon can form 4 covalant bonds with a variety of atoms
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Hydrocarbons • Organic molecules consisting of only
carbon and hydrogen
• Non-polar molecules (fats)
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Carbon Skeletons
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Isomers• Molecules with same molecular formula
but different structures (shapes) – different chemical properties– different biological functions
6 carbons
6 carbons
6 carbons
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Fig. 4-7
Pentane
(a) Structural isomers
(b) Geometric isomers
2-methyl butane
cis isomer: The two Xs areon the same side.
trans isomer: The two Xs areon opposite sides.
(c) Enantiomers
L isomer D isomer
Structural: different covalent arrangement
Geometric: same covalent arrangements, different spatial arrangements
Enantiomers: isomers that are mirror images
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Isomers- Form affects function• Structural differences create important
functional significance– medicines
• L-version active• but not D-version
– sometimes withtragic results…
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Form affects function• Thalidomide
– prescribed to pregnant women in 50s & 60s – reduced morning sickness, but…– stereoisomer caused severe birth defects
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Fig. 4-8
Drug
Ibuprofen
Albuterol
Condition
Pain;inflammation
Asthma
EffectiveEnantiomer
S-Ibuprofen
R-Albuterol
R-Ibuprofen
S-Albuterol
IneffectiveEnantiomer
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Functional groups• Parts of organic molecules that are
involved in chemical reactions– give organic molecules distinctive properties
hydroxyl amino
carbonyl sulfhydryl
carboxyl phosphate
• Affect reactivity– makes hydrocarbons hydrophilic – increase solubility in water
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Hydroxyl• –OH
– organic compounds with OH = alcohols – names typically end in -ol
• ethanol
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Carbonyl• C=O
– O double bonded to C
• if C=O at end molecule = aldehyde
• if C=O in middle of molecule = ketone
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Carboxyl • –COOH
– C double bonded to O & single bonded to OH group• compounds with COOH = acids
– fatty acids– amino acids
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Amino• -NH2
– N attached to 2 H• compounds with NH2 = amines
– amino acids
• NH2 acts as base
– ammonia picks up H+ from solution
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Sulfhydryl • –SH
– S bonded to H• compounds with SH = thiols
• SH groups stabilize the structure of proteins
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Phosphate • –PO4
– P bound to 4 O
• connects to C through an O
• lots of O = lots of negative charge– highly reactive
• transfers energy between organic molecules – ATP
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Look at the difference• Basic structure of male & female hormones is
identical– identical carbon skeleton – attachment of different functional groups– interact with different targets in the body
• different effects
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Diversity of molecules
• Substitute other atoms or groups around the carbon– ethane vs. ethanol
• H replaced by an hydroxyl group (–OH)
• nonpolar vs. polar
• gas vs. liquid
• biological effects!
ethane (C2H6) ethanol (C2H5OH)