Chapter: 3 Water

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Copyright © 2005 Pearson Education, Inc. publishing as Benjamin Cummings Chapter: 3 Wate

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Chapter: 3 Water. Figure 3.1. Water: A Molecule That Supports All of Life. 3/4 of the Earth’s surface Abundance is the main reason the Earth is habitable.  –. +. Hydrogen bonds. H.  –. +. H. +.  –.  –. +. Figure 3.2. Polar Nature of Water. Oxygen Highly electro negative - PowerPoint PPT Presentation

Transcript of Chapter: 3 Water

Page 1: Chapter: 3 Water

Copyright © 2005 Pearson Education, Inc. publishing as Benjamin Cummings

Chapter: 3 Water

Page 2: Chapter: 3 Water

Copyright © 2005 Pearson Education, Inc. publishing as Benjamin Cummings

Water: A Molecule That Supports All of Life

• 3/4 of the Earth’s surface

• Abundance is the main reason the Earth is habitable

Figure 3.1

Page 3: Chapter: 3 Water

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Hydrogenbonds

+

+

H

H+

+

– –

Figure 3.2

Polar Nature of Water• Oxygen Highly electro negative• Polarity of water molecules

Hydrogen bonds between molecules

Page 4: Chapter: 3 Water

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Properties of Water

• Cohesion: Capillary Action

• High Specific Heat: Moderation of Temperature

• Ice Floats

• Universal Solvent

Page 5: Chapter: 3 Water

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Cohesion

• Bonding to neighboring molecules

• Due to hydrogen bonding

Hydrogenbonds

+

+

H

H+

+

Figure 3.2

Page 6: Chapter: 3 Water

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Cohesion

• Transpiration pull water up through the microscopic vessels of plants

Water conducting cells

100 µmFigure 3.3

Page 7: Chapter: 3 Water

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Cohesion

• Surface tension

Figure 3.4

Page 8: Chapter: 3 Water

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Water moderates air temperature

• Absorbs heat from air that is warmer and releasing the stored heat to air that is cooler

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Water High Specific Heat

• Amount of heat absorbed or lost to change its temperature

hydrogen bonds

• Evaporative Cooling: Sweat

Page 10: Chapter: 3 Water

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Ice Floats

• Hydrogen bonds in ice

– More “ordered” than in liquid water less dense

Liquid waterHydrogen bonds

constantly break and re-form

IceHydrogen bonds are stable

Hydrogen bond

Figure 3.5

Page 11: Chapter: 3 Water

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Ice Floats

Water is most dense at 4 deg. C•Because ice floats in water life can exist under the frozen surfaces of lakes and polar seas

1.0g/cm3= liquid0.9g/cm3= ice

Page 12: Chapter: 3 Water

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Solvent of Life

• Polar regions of water molecule interact with ionic compounds

Negative oxygen regions

of polar water molecules are attracted to sodium

cations (Na+).+

+

+

+Cl –

Na+Positive hydrogen regions

of water molecules cling to chloride anions

(Cl–).

++

+

+

–Na+

Cl–

Figure 3.6

Page 14: Chapter: 3 Water

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Solute Concentration

• Molecular Mass: Sum of the masses of all the atom in a molecule

• Avogadro's Numbe: 6.0 x 10-23 Daltons= 1g

• Molar Mass: molecular mass x Avogadro’s # (usually on chemical label) (moles)

• Molarity : The number of moles of solute per litter of solution.

Page 15: Chapter: 3 Water

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Examples

• If you have 5 M of a solute in 2.5 L of solution what is the molarity of the solution?

• The Concentration of a solute in blood is 1.3 x10-10 M. How many molecules of this solute would be in a liter of blood?

Page 16: Chapter: 3 Water

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What is pH?

Hydronium concentration in water is 10-7. pH is –log of H+ concentrationAcids increase H+ concentrationBases reduce H+ concentrationAcidic = Higher H+

Basic = Higher OH-

Page 17: Chapter: 3 Water

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pH scale

Incr

easi

ngly

Aci

dic

[H+ ]

> [O

H– ]

Incr

easi

ngly

Bas

ic[H

+ ] <

[OH

– ]

Neutral[H+] = [OH–]

Oven cleaner

0

1

2

3

4

5

6

7

8

9

10

11

12

13

14

pH Scale

Battery acid

Digestive (stomach) juice, lemon juiceVinegar, beer, wine,colaTomato juice

Black coffee RainwaterUrine

Pure waterHuman blood

Seawater

Milk of magnesia

Household ammonia

Household bleach

Figure 3.8

Page 18: Chapter: 3 Water

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Buffers

• Minimize changes in pH

• Carbonic acid in the blood

Page 19: Chapter: 3 Water

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http://www.youtube.com/watch?v=V3NCeSlYQWQ&feature=player_detailpage

Chapter 4: Carbon Compounds

A fat molecule