CHAPTER 2 MATTER & MINERALSsite.iugaza.edu.ps/mabualtayef/files/02-Matter-and...Ionic bonding oAtoms...
Transcript of CHAPTER 2 MATTER & MINERALSsite.iugaza.edu.ps/mabualtayef/files/02-Matter-and...Ionic bonding oAtoms...
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CHAPTER 2
MATTER & MINERALS
Associate Professor Mazen AbualtayefCivil and Environmental Engineering Department
Islamic University of Gaza, PalestineThe materials are mostly adapted from the presentation of Stan & Cindy Hatfield
ECIV 3302
Engineering Geology
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Minerals: Building Blocks of Rocks
• By definition a mineral is
oNaturally occurring
oInorganic solid
oOrdered internal molecular structure
oDefinite chemical composition
• Rock
oA solid aggregate of minerals
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Composition of Minerals
• ElementsoBasic building blocks of minerals
oOver 115 are known (92 naturally occurring)
oA group of the same kind of atoms is called an element
• Atoms
oSmallest particles of matter
oRetains all the characteristics of an element
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Composition of Minerals• Atomic structure
oCentral region called the nucleus Consists of protons (+ charges) and neutrons (0 charges)
oElectrons (- charges)
Negatively charged particles that surround the nucleus
Located in discrete energy levels called shells
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Composition of Minerals
• Chemical bonding
Formation of a compound by combining two or more elements and three types:
a. Ionic bonding
oAtoms gain or lose outermost electrons to form ions
oIonic compounds consist of an orderly arrangement of oppositely charged ions
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Halite (NaCl) – An example of ionic bonding
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Composition of Minerals
b. Covalent bondingoAtoms share electrons
to achieve electrical
neutrality
oGenerally stronger
than ionic bonds
oBoth ionic and
covalent bonds
typically occur in the
same compound7
Diamonds are made of pure carbon and its
the hardest substance.
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Composition of Minerals
c. Metallic bondingoElectrons are free to migrate among
atoms
oWeaker and less common than other
bonds
• IsotopesoMass number = sum of neutrons +
protons in an atom
oAtoms of same element with
different # of neutrons
o Isotope = atom that exhibits
variation in its mass number8
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Structure of Minerals• Minerals consist of an orderly array of atoms
chemically bonded to form a particular crystalline
structure
• Internal atomic arrangement in ionic compounds
is determined by ionic size
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Physical Properties of Minerals
• Primary diagnostic propertiesoDetermined by observation or
performing a simple testoSeveral physical properties are used
to identify hand samples of minerals
• Crystal formoExternal expression of a mineral’s
internal structureoOften interrupted due to
competition for space and rapid loss of heat
A garnet crystal
Cubic crystals of pyrite
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Physical Properties of Minerals
• Luster
o Appearance of a mineral in
reflected light
o Two basic categories
Metallic
Nonmetallic
o Other descriptive terms
include vitreous, silky, or
earthyGalena (PbS) displays metallic luster
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Physical Properties of Minerals
• Color
o Generally unreliable
for mineral
identification
o Often highly
variable due to slight
changes in mineral
chemistry
o Exotic colorations of
certain minerals
produce gemstonesQuartz (SiO2) exhibits a variety of colors
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• Streak
oColor of a mineral in its powdered form
Physical Properties of Minerals
Mohs scale of hardness
Streak is obtained on an unglazed porcelain plate
• Hardness
oResistance of a mineral to abrasion or scratching
oAll minerals are compared to a standard scale called the Mohs scale of hardness
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•Cleavage
oTendency to break along
planes of weak bonding
oProduces flat, shiny
surfaces
oDescribed by resulting
geometric shapes Number of planes
Angles between
adjacent planes
Physical Properties of Minerals
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Fluorite, halite, and calcite all exhibit perfect cleavage
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• Fracture
o Absence of cleavage
when a mineral is broken
• Specific Gravity
o Weight of a mineral /
weight of an equal
volume of water
o Average value = 2.7
Physical Properties of Minerals
Conchoidal Fracture
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• Other properties
o Magnetism
o Reaction to hydrochloric acid
o Malleability
o Double refraction
o Taste
o Smell
o Elasticity
Physical Properties of Minerals
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Mineral Groups
• Nearly 4000 minerals have been named
• Rock-forming mineralsoCommon minerals that
make up most of the rocks of Earth’s crust
oOnly a few dozen members
oComposed mainly of the 8 elements that make up over 98% of the continental crust
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• Silicates
oMost important mineral group Comprise most rock-forming
minerals
Very abundant due to large % of silicon and oxygen in Earth’s crust
o Basic building block is the
silicon-oxygen tetrahedron Four oxygen ions surrounding
a much smaller silicon ion
Two illustrations of the
Si–O tetrahedron
Mineral Groups
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• Joining silicate structures
Mineral Groups
Single tetrahedra are
linked together to form
various structures: Isolated tetrahedra (a)
Tetrahedra pairs (b)
Ring structures (c)
Single and double chain
structures (d)
Sheet or layered
structures (f)
Complex 3-dimensional
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• Common silicate mineralso Light silicates: Feldspar group
Most common mineral group
Exhibit two directions of perfect cleavage at 90 degrees
Orthoclase (potassium feldspar) and Plagioclase (sodium
and calcium feldspar) are the two most common members
Mineral Groups
Potassium feldspar Plagioclase feldspar
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Mineral Groups
• Common silicate mineralso Light silicates: Quartz
Only common silicate composed
entirely of oxygen & silicon
Hard and resistant to weathering
Conchoidal fracture
Often forms hexagonal crystals
o Light silicates: Muscovite Common member of the mica
family
Excellent cleavage in one direction
Produces the “glimmering”
brilliance often seen in beach sand
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Mineral Groups
• Common silicate mineralso Light silicates: Clay minerals
Clay is a general term used to describe a variety of complex minerals
Clay minerals all have a sheet or layered structure
Most originate as products of chemical weathering
o Dark silicates: Olivine group High temperature Fe-Mg silicates Individual tetrahedra linked together
by iron and magnesium ions Forms small, rounded crystals with no
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Mineral Groups• Common silicate mineralso Dark silicates: Pyroxene group
Single chain structures involving iron and magnesium
Two distinctive cleavages at nearly 90 degrees
Augite is the most common mineral in pyroxene group
Hornblende amphibole
o Dark silicates: Amphibole group Double chain structures involving a variety of ions
Two perfect cleavages exhibiting angles of 124 and 56 degrees
Hornblende is the most common mineral in amphibole group
Cleavage angles for augite and hornblende
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Mineral Groups
• Important non-silicate
mineralso Typically divided into
classes based on
anions
o Comprise only 8% of
Earth’s crust
o Often occur as
constituents in
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Mineral Groups
• Important non-silicate mineralso Carbonates
Primary constituents in limestone and dolostone
Calcite (CaCO3) and dolomite CaMg(CO3)2 are the two most important carbonate minerals
o Many non-silicate minerals have economic value
o Examples Hematite (oxide mined for iron ore) Halite (halide mined for salt) Sphalerite (sulfide mined for zinc ore) Native copper (native element mined
for copper)
Native copper
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