Chapter 17 Notes - PC\|MAC

10
4/10/14 1 Slide 1 of 34 © Copyright Pearson Prentice Hall > The Flow of Energy—Heat and Work Energy Transformations Heat (q) is energy that transfers from one object to another because of a temperature difference between them. Heat always flows from a warmer object to a cooler object. 17.1 Slide 2 of 34 © Copyright Pearson Prentice Hall > The Flow of Energy—Heat and Work Energy Transformations Thermochemistry is the study of energy changes that occur during chemical reactions and changes in state. The energy stored in the chemical bonds of a substance is called chemical potential energy. 17.1 Slide 3 of 34 © Copyright Pearson Prentice Hall > The Flow of Energy—Heat and Work Energy Transformations When fuel is burned in a car engine, chemical potential energy is released and is used to do work. 17.1

Transcript of Chapter 17 Notes - PC\|MAC

Page 1: Chapter 17 Notes - PC\|MAC

4/10/14

1

Slide 1 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Energy Transformations

Heat (q) is energy that transfers from one object to another because of a temperature difference between them.

Heat always flows from a warmer object to a cooler object.

17.1

Slide 2 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Energy Transformations

Thermochemistry is the study of energy changes that occur during chemical reactions and changes in state.

The energy stored in the chemical bonds of a substance is called chemical potential energy.

17.1

Slide 3 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Energy Transformations

When fuel is burned in a car engine, chemical potential energy is released and is used to do work.

17.1

Page 2: Chapter 17 Notes - PC\|MAC

4/10/14

2

Slide 4 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Exothermic and Endothermic Processes

The law of conservation of energy states that in any chemical or physical process, energy is neither created nor destroyed.

17.1

Slide 5 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Exothermic and Endothermic Processes

In an endothermic process, the system gains heat as the surroundings cool down.

In an exothermic process, the system loses heat as the surroundings heat up.

17.1

© Copyright Pearson Prentice Hall

Slide 6 of 34

Practice Problems for Conceptual Problem 17.1

Page 3: Chapter 17 Notes - PC\|MAC

4/10/14

3

© Copyright Pearson Prentice Hall

Slide 7 of 34

Practice Problems

Heat flows from the system (parafin) to the surroundings (air). The process is exothermic.

Slide 8 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Heat Capacity and Specific Heat

Water releases a lot of heat as it cools. During freezing weather, farmers protect citrus crops by spraying them with water.

17.1

Slide 9 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Units for Measuring Heat Flow

Heat flow is measured in two common units, the calorie and the joule.

The energy in food is usually expressed in Calories.

17.1

Page 4: Chapter 17 Notes - PC\|MAC

4/10/14

4

Slide 10 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Heat Capacity and Specific Heat

The amount of heat needed to increase the temperature of an object exactly 1°C is the heat capacity of that object.

The heat capacity of an object depends on both its mass and its chemical composition.

17.1

Slide 11 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Heat Capacity and Specific Heat

The specific heat capacity, or simply the specific heat, of a substance is the amount of heat it takes to raise the temperature of 1 g of the substance 1°C.

17.1

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 12 of 34

End Show

17.1

Page 5: Chapter 17 Notes - PC\|MAC

4/10/14

5

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 13 of 34

End Show

17.1

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 14 of 34

End Show

17.1

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 15 of 34

End Show

17.1

Page 6: Chapter 17 Notes - PC\|MAC

4/10/14

6

Slide 16 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Heat Capacity and Specific Heat

Because it is mostly water, the filling of a hot apple pie is much more likely to burn your tongue than the crust.

17.1

Slide 17 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Calorimetry

Calorimetry - the precise measurement of the heat flow into or out of a system for chemical and physical processes.

17.2

Slide 18 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Calorimetry

In Calorimetry:

heat released by system = heat absorbed by surroundings

Conversely:

heat absorbed by system = heat released by surroundings

17.2

Page 7: Chapter 17 Notes - PC\|MAC

4/10/14

7

Slide 19 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Calorimetry

Enthalpy (H) - the heat content of a system at constant pressure.

17.2

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 20 of 34

End Show

17.2

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 21 of 34

End Show

17.2

Page 8: Chapter 17 Notes - PC\|MAC

4/10/14

8

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 22 of 34

End Show

17.2

Slide 23 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Thermochemical Equations

Thermochemical Equation – a chemical equation that includes the enthalpy change.

17.2

Slide 24 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Thermochemical Equations

Heat of reaction - the enthalpy change for the chemical equation exactly as it is written.

17.2

Page 9: Chapter 17 Notes - PC\|MAC

4/10/14

9

Slide 25 of 34

© Copyright Pearson Prentice Hall

>The Flow of Energy—Heat and Work Thermochemical Equations

Heat of combustion - the heat of reaction for the complete burning of one mole of a substance.

17.2

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 26 of 34

End Show

17.3

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 27 of 34

End Show

17.3

Page 10: Chapter 17 Notes - PC\|MAC

4/10/14

10

© Copyright Pearson Prentice Hall

SAMPLE PROBLEM

Slide 28 of 34

End Show

17.3