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Transcript of Ch27
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Philip DuttonUniversity of Windsor, Canada
N9B 3P4
Prentice-Hall © 2002
General ChemistryPrinciples and Modern Applications
Petrucci • Harwood • Herring
8th Edition
Chapter 27: Organic Chemistry
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 2 of 75
Contents
27-1 Organic Compounds and Structures: An Overview
27-2 Alkanes
27-3 Alkenes and Alkynes
27-4 Aromatic Hydrocarbons
27-5 Alcohols, Phenols, and Ethers
27-6 Aldehydes and Ketones
27-7 Carboxylic Acids and Their Derivatives
27-8 Amines
27-9 Heterocyclic Compounds
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 3 of 75
Contents
27-10 Nomenclature of Stereoisomers in Organic Compounds
27-11 An Introduction to Substitution Reactions at sp3 Hybridized Carbon Atoms
27-12 Synthesis of Organic Compounds
27-13 Polymerization Reactions
Focus On Natural and Synthetic Dyes
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27-1 Organic Compounds and Structures: An Overview
• Hydrocarbons – the simplest organic compounds.• Simplest hydrocarbon is methane.
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Ethane
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Skeletal Isomerism
Prentice Hall © 2002 General Chemistry: Chapter 27 Slide 5 of
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 7 of 75
Simplified Drawings of Organic Structures
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 8 of 75
Nomenclature
• Select the longest continuous carbon chain.– This determines the base name.
• Consider each branch and name similarly except change the name from –ane to –yl.
• Number the C atoms so that substituents have the lowest possible number.
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 9 of 75
Nomenclature
• Name each substituent according to its identity and the number of the C atom to which it is attached.– Use di, tri, tetra as appropriate.
• Separate numbers from one another by commas.• List substituents alphabetically by name.
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 10 of 75
Table 27.1. Some Common Alkyl Groups
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Positional Isomerism
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 12 of 75
Fun
ctio
nal G
roup
s
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27-2 Alkanes
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Conformations
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Ring Structures
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Ring Strain
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Cyclohexane Conformations
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 18 of 75
Preparation of Alkanes
CH2=CH2 + H2 → CH3-CH3
Pt
Δ
2 CH3CH2Br + 2 Na → CH3CH2CH2CH3 + 2 NaBrpressure
Δ
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Reactions of Alkanes
Initiation: Cl-Cl → 2 Cl·
Propagation: H3C-H + Cl· → H3C· + HCl
H3C· + Cl2 → H3C-Cl + Cl·
Termination:
H3C· + Cl· → H3C-Cl
Cl· + Cl· → Cl-Cl
H3C· + H3C· → H3C-CH3
Δ or h
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 20 of 75
Combustion Reactions
C8H18(l) + O2(g) → 8 CO2(g) + 9 H2O(l)25
2
ΔH° = -5.48103 J
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Table 27.4 Principle Petroleum Fractions
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Octane Number
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27-3 Alkenes and Alkynes
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Geometric Isomerism
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Elimination Reaction
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Addition Reactions
Markovnikov rule
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Hydration Reaction
Addition is favored in dilute acid and elimination is favored in strong.
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Reduction of C=C
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27-4 Aromatic Hydrocarbons
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Characteristics of Aromatic Hydrocarbons
• Planar (flat) cyclic molecules.• Conjugated п systems (4n + 2)
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Prentice-Hall © 2002 General Chemistry: Chapter 27 Slide 31 of 75
Naming Aromatic Hydrocarbons
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Aromatic Substitution Reactions
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Aromatic Subsitution Reactions
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27-5 Alcohols, Phenols, and Ethers
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Preparation and Use of Alcohols
CO(g) + 2 H2(g) → CH3OH(g)350 °C
200 atmZnO, Cr2O3
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Preparation and Use of Alcohols
• Methanol.– 21st amongst industrial chemicals.
• Ethanol. – fermentation or by hydration of ethylene.
• Ehylene glycol.– High boiling point, soluble in water.
• Glycerin.
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Ethers
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Aldehydes and Ketones
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Preparation and Use
• Oxidation of alcohols.
• Extract from natural sources
• Acetone is extensively used as a solvent.
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Addition Reactions of the Carbonyl Group
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27-7 Carboxylic Acids and Their Derivatives
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Oxidation of Alcohols
CH3CH2OH + KMnO4 → CH3CO2-K+ → CH3CO2H
OH- H+
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Aromatic Acids
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Acetyl Group
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Esters
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Amides
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Resonance in Amides
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Reduction Reactions
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Amines
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Preparation of Amines
2 NH3 + CH3Br → CH3NH3+Br- + NH3 → CH3NH2 + NH4Br
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Basicity of Amines
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Ammonium Salts
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27-9 Heterocyclic Compounds
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27-10 Nomenclature of Stereoisomers in Organic Compounds
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Chirality
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The R,S System of Nomenclature
Substituent of higher atomic number takes precedence over one of lower atomic number:
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The R,S System of Nomenclature
If two substituents attached to the stereocenter have the same priority, proceed along the chains to the first point of difference:
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The R,S System of Nomenclature
Double and triple bonds count as if they were single and the atoms are duplicated or triplicated at the other end of the double or triple bond:
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The E,Z System of Nomenclature
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The E,Z System of Nomenclature
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27-11 An Introduction to Substitution Reactions at sp3 Hybridized Carbon
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SN2 Mechanism
Rate = k[OH-][CH3Cl]
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Inversion of Configuration
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SN1 Mechanism
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SN1 Mechanism
Rate = k [(CH3)3CCl]
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Racemic Products From SN1 Reactions
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27-12 Synthesis of Organic Compounds
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27-13 Polymerization Reactions
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Table 27.5 Some Polymers Produced by Chain-Reaction Polymerization
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Condensation Polymerization
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Table 27.6 Some Polymers Produced by Step Reaction Polymerization
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Stereospecific Polymers
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Focus On Natural and Synthetic Dyes
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Focus On Natural and Synthetic Dyes
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Chapter 27 Questions
Develop problem solving skills and base your strategy not on solutions to specific problems but on understanding.
Choose a variety of problems from the text as examples.
Practice good techniques and get coaching from people who have been here before.