Ch 6 The Periodic Table And Periodic Law Short2
Transcript of Ch 6 The Periodic Table And Periodic Law Short2
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Chapter 6The Periodic Table
The how and whyThe how and why
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History 1829 German J. W. Dobereiner
Grouped elements into triads
• Three elements with similar properties
• Properties followed a pattern
• The same element was in the middle of all trends
Not all elements had triads
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History Russian scientist Dmitri Mendeleev
taught chemistry in terms of properties
Mid 1800 – atomic masses of elements were known
Wrote down the elements in order of increasing mass
Found a pattern of repeating properties
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Mendeleev’s Table Grouped elements in columns by similar
properties in order of increasing atomic mass
Found some inconsistencies - felt that the properties were more important than the mass, so switched order.
Found some gaps Must be undiscovered elements Predicted their properties before they
were found
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The Modern Table Elements are still grouped by properties Similar properties are in the same
column Periodic Law- When the elements are
arranged by increasing atomic number, there is a periodic repetition of their chemical and physical properties.
Order is in increasing atomic number
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Horizontal rows are called periods There are 7 periods
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Vertical columns are called groups. Elements are placed in columns by
similar properties. Also called families
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1A
2A 3A 4A 5A 6A7A
8A0
The elements in the A groups are called the representative elements
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1A 2A
3A 4A 5A 6A 7A
8A
3B 4B 5B 6B 7B 8B 8B 8B 1B 2B
1 2
13 14 15 16 17
18
3 4 5 6 7 8 9 10 11 12
IA IIA
IIIB
IVB
VB
VIB
VII
B
VII
IB
IIIA
IVA
VA
VIA
VII
A
VII
IA
IB IIB
Other Systems
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Metals
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Metals Luster – shiny. Ductile – drawn into wires. Malleable – hammered into sheets. Conductors of heat and electricity.
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Transition metals The Group B
elements
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Non-metals Dull Brittle Nonconductors
- insulators
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Metalloids or Semimetals Properties of both Semiconductors
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These are called the inner transition elements and they belong here
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Group 1A are the alkali metals Group 2A are the alkaline earth metals
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Group 7A is called the Halogens Group 8A are the noble gases
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Alkali metals all end in s1
Alkaline earth metals all end in s2
really have to include He but it fits better later
He has the properties of the noble gases
s2s1 S- block
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Transition Metals -d block
d1 d2 d3s1
d5 d5 d6 d7 d8s1
d10 d10
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The P-block p1 p2 p3 p4 p5 p6
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F - block inner transition elements
f1 f5f2 f3 f4
f6 f7 f8 f9 f10 f11 f12 f14
f13
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Each row (or period) is the energy level for s and p orbitals
1
2
3
4
5
6
7
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d orbitals fill up after previous energy level so first d is 3d even though it’s in row 4
1
2
3
4
5
6
7
3d
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f orbitals start filling at 4f
1
2
3
4
5
6
7 4f
5f
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Writing Electron configurations the easy way
Yes there is a shorthandYes there is a shorthand
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Electron Configurations repeat The shape of the periodic table is a
representation of this repetition. When we get to the end of the row
the outermost energy level is full. This is the basis for our shorthand
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The Shorthand Write the symbol of the noble gas
before the element in brackets [ ] Then the rest of the electrons. Aluminum - full configuration 1s22s22p63s23p1
Ne is 1s22s22p6
so Al is [Ne] 3s23p1
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More examples Ge = 1s22s22p63s23p63d104s24p2
Ge = [Ar] 4s23d104p2
Ge = [Ar] 3d104s24p2
Hf=1s22s22p63s23p64s23d104p64f14
4d105s25p65d26s2
Hf=[Xe]6s24f145d2
Hf=[Xe]4f145d26s2
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The Shorthand
Sn- 50 electrons
The noble gas before it is Kr
[ Kr ]
Takes care of 36
Next 5s2
5s2
Then 4d10
4d10Finally 5p2
5p2
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Electron configurations and groups Representative elements have s and
p orbitals as last filled
• Group number = number of electrons in highest energy level
Transition metals- d orbitals Inner transition- f orbitals Noble gases s and p orbitals full
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Part 3Periodic trends
Identifying the patterns
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What we will investigate Atomic size
• how big the atoms are Ionization energy
• How much energy to remove an electron
Electronegativity• The attraction for the electron in a
compound Ionic size
• How big ions are
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What we will look for Periodic trends-
• How those 4 things vary as you go across a period
Group trends
• How those 4 things vary as you go down a group
Why?
• Explain why they vary
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The why first The positive nucleus pulls on
electrons Periodic trends – as you go across a
period• The charge on the nucleus gets
bigger• The outermost electrons are in the
same energy level• So the outermost electrons are pulled
stronger
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The why first The positive nucleus pulls on
electrons Group Trends
• As you go down a group–You add energy levels
–Outermost electrons not as attracted by the nucleus
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Atomic Size
Atomic Radius = half the distance between two nuclei of molecule
}Radius
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Trends in Atomic Size Influenced by two factors
• Energy Level– Higher energy level is further away
• Charge on nucleus– More charge pulls electrons in closer
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Group trends As we go down a
group
• Each atom has another energy level
• So the atoms get bigger
HLi
Na
K
Rb
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Periodic Trends As you go across a period the radius
gets smaller.
• More nuclear charge
• Pulls outermost electrons closer
Na Mg Al Si P S Cl Ar
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Ionization Energy The amount of energy required to
completely remove an electron from a gaseous atom.
Removing one electron makes a +1 ion
The energy required is called the first ionization energy
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Ionization Energy The second ionization energy is the
energy required to remove the second electron
• Always greater than first IE The third IE is the energy required to
remove a third electron
• Greater than 1st or 2nd IE
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Symbol First Second ThirdHHeLiBeBCNO F Ne
1312 2731 520 900 800 1086 1402 1314 1681 2080
5247 7297 1757 2430 2352 2857 3391 3375 3963
1181014840 3569 4619 4577 5301 6045 6276
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What determines IE The greater the nuclear charge the
greater IE.
Filled and half filled orbitals have lower energy, so achieving them is easier, lower IE
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Group trends As you go down a group first IE
decreases because of
• The outer electron is less attracted
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Periodic trends All the atoms in the same period
• Have Increasing nuclear charge– So IE generally increases from left to right.
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Ionic Size Cations are positive ions Cations form by losing electrons Cations are smaller than the atom
they come from Metals form cations
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Ionic size Anions are negative ions Anions form by gaining electrons Anions are bigger than the atom they
come from Nonmetals form anions
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Electronegativity
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Electronegativity The tendency for an atom to attract
electrons to itself when it is chemically combined with another element.
How “greedy” Big electronegativity means it pulls
the electron toward it.
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Group Trend The further down a group
• The more electrons an atom has.
• Less attraction for electrons
• Low electronegativity.
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Periodic Trend Metals - left end Low nuclear charge Low attraction Low electronegativity Right end - nonmetals High nuclear charge Large attraction High electronegativity Not noble gases- no compounds
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Ionization energy, electronegativity
INCREASE
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Atomic size increases,
Ionic size increases
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Nuclear Charge
Ene
rgy
Leve
ls
& S
hiel
ding