CENTRAL COASTBLUE ADVANCED TREATMENT …€¦ · CENTRAL COASTBLUE ADVANCED TREATMENT DEMONSTRATION...
Transcript of CENTRAL COASTBLUE ADVANCED TREATMENT …€¦ · CENTRAL COASTBLUE ADVANCED TREATMENT DEMONSTRATION...
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CENTRAL COAST BLUE
ADVANCED TREATMENT DEMONSTRATION
FACILITY
One Community. One Water. One Future.
July 23, 2018
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The motivation: extreme drought in California
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The Players @ Pismo Beach Demonstration Facility
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Central Coast Blue Utilizes shared infrastructure
for common benefit
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PAGE 14
Lasting Water
Independence
5 Agencies
Managing water collaboratively and holistically
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2018 20222019 2021
Preliminary Design, Technology
Piloting,
Environmental Review &
**Community Connection**
Operations Begins (Phase 1)
Groundbreaking (Phase 2)
Closer to Water Independence
Construction Kick Off
(Phase 1) Preliminary
Design (Phase 2)
Phase I Design and Permitting
Advanced Treatment Design;
Test InjectionWell
2016 –current
Extensive and
thorough
planning and
collaboration
2020
Complete Phase I Design
and Permitting
Central Coast Blue Design Process and Stage
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Pismo Beach (Central Coast Blue) Demonstration Facility
7
• Technical details– MF: 4 PALL UNA MF elements
– RO: 8” DOW ECO-PRO 400 and 4” DOW BW30XFRLE-4040
– RO Recovery: 75-80%
– 2 RO stages, flux: 11-13.4 gfd; 10-11.2 gfd
– Permeate flow rate: 30-35 gpm
– Evoqua UV/AOP system, chemical-free
– Two Phase Testing to compare RO Operation Process
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IDE Sponsored Pilot Plant
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Pismo Beach Demonstration Facility Goals
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1. Compare IDE’s ECO-FAT technology vs. conventional FAT
2. Tangible public outreach and educational tool, first on the central coast
3. Evaluate process data for the Central Coast Blue design team
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Stage III:Standard RO
Stage I:Chloramination
No NDMA Formation
No membrane oxidation
Conventional FAT vs. ECO REUSE process
NH3 HOCl
Stage II:UF/MF
WWTP effluent
Stage IV:UV/AOP
No UVT Reduction
CEB &CIP Longer intervalsBetween CIP
NaCl
- Sequential cleaning of RO membranes by DOHS
- Conservation
Fe
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DORO RO
DOHS is Direct Osmosis High
Salinity Flush Provides:
• Backwash
• Scouring
• Bacteria Dehydration
Eco Reuse Cleaning Process:
DOHS – Direct OsmosisHigh Salinity
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Reject
POr 3 bar
Feed
ProductPOp 0.1 bar
PGr 12bar
PGp 1 bar
NDPRO = PGr-POr-PGp+PopNDPRO = 12 – 3 - 1 + 0.1 = +8.1 bar
NDP
DOHS Normal RO Process
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POr 3bar
SalineSolution
bar Feed
Product
PGr 12 bar
PGp 1barPop 0.1 barN
DP30
NDPRO = PGr-POr-PGp+PopNDPRO = 12 - 3 - 1 + 0.1 = + 8.1 barNDP DO (FO) = 12 - 100 - 1 + 0.1 = - 88.9 bar
DOHS – Direct (Forward) Osmosis High Salinity
“osmotic backwash”
Reject
USA Pat.7,658,852; Australia Pat. 2005254337; Singapore Pat. 153812 Israel Pat. 169882 GB Pat. 1414263.2 GB PCT/IB2015/055665
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USA Pat.7,658,852; Australia Pat. 2005254337; Singapore Pat. 153812 Israel Pat. GB 1414263.2 GB 1501243.8 Pat Pending
FeedN
aC
l
Vy
Vx
Vy
Vx
Vy
Vx
X
Y
Permeate
› Shear force increase along the feed-brine spacer
Vx on last membrane is 3 times higher than normal
› Vy diminishes proportionally:
Eco Reuse Cleaning Process:
DOHS – Direct Osmosis High Salinity
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Turbidity levels increase in brine after DOHS, indicates that biofouling is reduced
DOHS Effect on Removal of Fouling
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DOHS: Frequent removal of particles before a strong
van-der Waals interaction is created with the surface
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Draw Solution 100
DOHS: Osmotic Dehydration of Bacteria
USA Pat.7,658,852; Australia Pat. 2005254337; Singapore Pat. 153812 Israel Pat. 169882 GB Pat. 1414263.2 GB PCT/IB2015/055665
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Visualization of FO Backwash
18
Visualization test made by: Emily Tow, from in MIT Lab
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DOW membrane, two years in operation
under DOHS conditions.
Test conducted in DOW Water and Process Solution
Element Evaluation Lab
After two years of operation membrane show performance as new membrane from the box
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› 20
DO-HS Membrane Cleaning is absolutely safe for RO and NF membranes.
It is approved by all leading RO membrane manufactures.
Hydranautics Technical Bulletin: TSB107 Foulants and Cleaning
Procedures for composite polyamide RO Membrane Elements
(ESPA, ESNA, CPA, LFC, NANO and SWC)
http://www.membranes.com/docs/tsb/tsb107.pdf
Page 15
USA Pat.7,658,852; Australia Pat. 2005254337; Singapore Pat. 153812 Israel Pat. Patent GB 2519880
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21
www.membrane-recovery.com
Plant Name Country Plant type
Capacity on which
DO-HS actually
operated
Beginning of
DO-HS Operation
Fertilizers and Chemicals Ltd “Deshanim-1” Israel BWRO 624 GPM May-05
Fertilizers and Chemicals Ltd “Deshanim-2” Israel BWRO 367 GPM Oct-08
Kibbutz Ma’agan Michael “Blue & Green RO Plant” Israel BWRO 267 GPM Oct-05
Kibbutz Ma’agan Michael “Maagan Htpala RO plant” Israel BWRO 1505 GPM Apr-06
Haifa Chemicals Ltd Industrial waste water RO plant Israel IWWRO 220 GPM Feb-09
Carmel Olefins Ltd, Industrial waste water RO plant Israel IWWRO 1981 GPM Feb-11
GE Water Mobile RO Plant USA BWRO 250 GPM Apr-11
City of Ontario CHINO USA BWRO 307 GPM Mar-12
Newton Energy Center USA BWRO 300 GPM Oct-11
Kranji PUB Singapore Singapore WWRO 1468 GPM May-12
Turtle Bay SWRO Cyprus Cyprus SWRO 128 GPM Jun-08
Anticline Disposal LLC USA WWRO RO-1 156 GPM September 2012
Anticline Disposal LLC USA WWRO RO-2 137 GPM July 2013
REFERENCE LISTInstallations of DO-HS Membrane Cleaning Technology
in Commercial Operation
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Eco Reuse Phase: Microfiltration Performance
No Fe 53.5 ppm Fe2.5
ppm0
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Eco Reuse Phase: MF – Stable Specific Flux (with Fe dosage)
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RO Results: Good Specific Flux and Recovery with DOHS and Conservation
Recovery of ~80% proven in
DOHS/Conservation Mode
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40
45
50
55
60
65
70
75
80
85
02/09 02/19 03/01 03/11 03/21 03/31 04/10 04/20 04/30 05/10
Re
cove
ry (
%)
Total 1st Stage 2nd Stage
Eco Reuse Phase: RO Recovery 75% to 80%
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Eco Reuse Phase: Water Quality Results
•Acetaminophen •Atenolol •Caffeine •Carbamazepine •DEET •Fluoxetine •Gemfibrozil •Ibuprofen •Meprobamate •N-Nitrosodimethylamine •N-Nitrosomorpholine •Naproxen •Perfluorobutane sulfonate
•Perfluorobutanoic acid •Perfluorodecanesulfonate •Perfluorodecanoic acid •Perfluoroheptanoic acid •Perfluorohexane sulfonate •Perfluorohexanoic acid •Perfluorononanoic acid •Perfluorooctane sulfonate •Perfluorooctanoic acid •Perfluoropentanoic acid •Primidone
• Sucralose •Sulfamethoxazole •TCEP •Triclocarban •Triclosan •Trimethoprim
–30 CECS tested – 25 detected in secondary effluent, only 1 detected in the finished water – Sucralose 28 ng/L (3 log removal)
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Marc
hB
oard
Meeti
ng
_V1.p
pt/
25
Eco Reuse Phase: UV AOP
• Less NDMA means less UV dose to meet 10 ng/L standard (maybe none?)
• UV AOP still needed for 0.5-log 1,4- dioxane destruction (but at what dose?)
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Terminal Island Collimated Beam Test
(0.5-log removal of 1,4-D is about 1,200 mJ/cm2.)
SCVWD Collimated Beam Test
More Examples UVT Impact on UV Intensity and Efficiency in RO Permeate
00.20.40.60.8
11.21.4
0 500 1000 1500 2000
LRV
1,4
-Dio
xan
e
Measured UV Dose [mJ/cm2]
2 mg/L 4 mg/L Field 2 mg/L Field 4 mg/L
0
0.2
0.4
0.6
0.8
1
1.2
1.4
0 500 1000 1500 2000
LRV
1,4
-Dio
xan
e
UV Dose (mJ/cm2)
4 mg/L H2O2 6 mg/L H2O2 2 mg/L NaOCl 4 mg/L NaOCl 6 mg/L NaOCl
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Eco Reuse Phase: Water Quality Results
ParameterSecondary
Effluent
RO Feed
(MF Effluent)
RO
Permeate
TOC [mg/L] 12.5 10.5 ND<0.3
Total Strontium [mg/L] 0.38 0.35 ND<0.01
Electrical Conductivity [S/cm] 1,460 - 33
UVT [%] - ~56% >100%
>1.54 LRV
>1.54 LRV
>1.65 LRV
• RO Permeate UVT >100%. Lack of chloramines has important positive impact
• Conventional RO systems with chloramines have 98% UVT (new membranes) and 96% UVT
(old membranes).
• Typical design UVT for UV AOP is 96% UVT
• …this difference in UVT has a large impact on efficiency
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Eco Reuse Phase: Dose Capacity
Parameter Secondary Effluent [ng/L] Finished Water [ng/L]
NDMA 2.5 1.8
NMOR 2.3 0.81
No NDMA Means…
• Typical UV Dose for NDMA
Removal~1,000 mJ/cm2
• UV dose for 6-log adenovirus is 276
mJ/cm2
• So, what dose is needed for ½-log
1,4 Dioxane?
• If dose value is ~500mJ/cm2, there will be
substantial UV AOP savings
• Testing completed 5/23
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UVT Impact on UV Intensity and Efficiency
4% change in UVT results
in 20% greater UV intensity
UVI as function of UVT UVI design range
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• Stable MF and RO performance during Chloramine Free Operation
• DOHS is Effective preventive maintenance mechanism
• High specific flux
• High UVT (almost 100%) – major Lower CAPEX and OPEX savings
• MF and RO membranes intact (maintained integrity)
• Chloramine free! (no NDMA formation)
• Simpler process
• EQUALS LOWER COST OF WATER
Demonstration Facility Results: Eco Reuse Phase
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Pismo Beach Demo Site - for public outreach
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Questions/Discussion
Thanks and Credit to:
• City of Pismo Beach: Eric, Russ, Justin, Steve, Hailie, Bob, Lauren
• IDE, WSC, Carollo staff• Pall and Evoqua
Steve Wait