C–C C R–OH - · PDF filecarbon is present in most foods? ... presence of carbon....

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24.1 (and heating food substances lab) What evidence do we have that carbon is present in most foods? When most foods are heated they turn black. This indicates the presence of carbon. Why is the term “organic” chemistry misleading? It suggests that all organic compounds come from living things. Organic compounds may be synthetic or may arise without life. Which compounds are inorganic and which are organic? Inorganic: the oxides of carbon (CO, CO 2 ), the bicarbonates (containing the HCO 3 - ion, such as NaHCO 3 ), and carbonates of metal ions (compounds containing the CO 3 2- ion, such as Na 2 CO 3 ). All other carbon-containing compounds are organic. Give examples of organic compounds. Plastics, synthetic and natural fibers (like cotton and wood), most drugs, perfumes, petroleum products, carbohydrates, fats and oils, proteins, vitamins, hair, cell membranes and cell components, etc. Define functional group. The name for the part of an organic molecule where most chemical reactions occur. Draw the characteristic structural feature of these functional groups: Alkanes C–C Alkenes C=C Alkynes CC Aromatics or or C C C C C C H H H H H H (all the same) Alcohols R–OH Aldehydes C O (H)R H Ketones C O R R' Carboxylic acids C O (H)R OH Also symbolized as COOH Esters C O (H)R O R' Also symbolized as COOC Ethers R–O–R’ Amines N R'' R R' or ' N H R R or N H R H (3 possibilities) Amides C O (H)R N R''(H) R'(H) Why are compounds classified according to functional groups? Because compounds with similar functional groups undergo similar reactions (we only have to know a few general reactions). How does the presence of functional groups influence the boiling point and the solubility of molecules? The more polar the group, the higher the boiling point and the greater the solubility in water. For example CH 3 –O–CH 3 has a lower boiling point and lower solubility in water than CH 3 CH 2 –OH (the electro- negativity difference between C and O is 1.0 versus 1.4 for H and O). Draw a hydroxyl group –OH Draw a carbonyl group C O R R Draw a carboxyl group C O OH R You should know the rules for naming hydrocarbons (see handout)

Transcript of C–C C R–OH - · PDF filecarbon is present in most foods? ... presence of carbon....

Page 1: C–C C R–OH - · PDF filecarbon is present in most foods? ... presence of carbon. ... carbohydrates, fats and oils, proteins, vitamins, hair, cell membranes and cell components,

24.1 (and heating food substances lab) What evidence do we have that carbon is present in most foods?

When most foods are heated they turn black. This indicates the presence of carbon.

Why is the term “organic” chemistry misleading?

It suggests that all organic compounds come from living things. Organic compounds may be synthetic or may arise without life.

Which compounds are inorganic and which are organic?

Inorganic: the oxides of carbon (CO, CO2), the bicarbonates (containing the HCO3

- ion, such as NaHCO3), and carbonates of metal ions (compounds containing the CO3

2- ion, such as Na2CO3). All other carbon-containing compounds are organic.

Give examples of organic compounds.

Plastics, synthetic and natural fibers (like cotton and wood), most drugs, perfumes, petroleum products, carbohydrates, fats and oils, proteins, vitamins, hair, cell membranes and cell components, etc.

Define functional group. The name for the part of an organic molecule where most chemical reactions occur.

Draw the characteristic structural feature of these functional groups: Alkanes C–C Alkenes C=C Alkynes C≡C Aromatics

or or

C

C

C

C

C

C

H

H

H

H

H

H

(all the same) Alcohols R–OH Aldehydes

C

O

(H)R H Ketones

C

O

R R' Carboxylic acids

C

O

(H)R OH Also symbolized as COOH Esters

C

O

(H)R O R' Also symbolized as COOC Ethers R–O–R’ Amines

N

R''

R R' or 'N

H

R R or N

H

R H (3 possibilities) Amides

C

O

(H)R N

R''(H)

R'(H) Why are compounds classified according to functional groups?

Because compounds with similar functional groups undergo similar reactions (we only have to know a few general reactions).

How does the presence of functional groups influence the boiling point and the solubility of molecules?

The more polar the group, the higher the boiling point and the greater the solubility in water. For example CH3–O–CH3 has a lower boiling point and lower solubility in water than CH3CH2–OH (the electro-negativity difference between C and O is 1.0 versus 1.4 for H and O).

Draw a hydroxyl group –OH Draw a carbonyl group

C

O

RR Draw a carboxyl group

C

O

OHR You should know the rules for naming hydrocarbons (see handout)