C5 Alkyl Nitrate Mixing Ratios as Indicators of Crude Oil Influence on Air Masses

7/31/2019 C5 Alkyl Nitrate Mixing Ratios as Indicators of Crude Oil Influence on Air Masses

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Acù`j NcètalWlùgx~`tp ae ]`~nal~`l+Kjd`~al


2/28

{ JL~ jxg vxadwngd vbatanbgk`njccp tbxawmbar`djtàl ae tbg`x vjxglt bpdxanjxhal~

{ Tpv`njccp# JL~ 3 :6' LAp JL~ bjug ca} xgjntù`tp nakvjxgd ta atbgx

nakvalglt~ ae LAp

{ Xg~gxua`x ~vgn`g~ eax calm+xjlmg txjl~vaxt aeLAr jld tbw~ vxakatg azalg vxadwntàl


3/28

{ l+vgltjlg 8+vgltpc l`txjtg "8+VgALA8) >+vgltpc l`txjtg ">+VgALA8)

{ `~avgltjlg >+kgtbpc+8+hwtpc l`txjtg ">+Kg+8+HwALA8)


4/28

{ Kadgc`lm t`kg guacwtàl ae djwmbtgx jcipcl`txjtg~ ta vjxglt bpdxanjxhal~ `l jl j`xkj~~ Hgxtkjl gt jc,# :007

{ K`r`lm xjtà~ ae ~`~tgx jcipc l`txjtg~ njl hgxgcjtgd ta caai jt

kgj~wxgd xjtà ; vxgd`ntgd xjtà

Ecanig gt jc,# :002


5/28

{ ]jlt ta e`ld jl `ld`njtax ~vgn`g~ ae a`c e`gcd~ Ljtwxjc mj~ jld a`c haak `l tbg cj~t tgl pgjx~ Cgm`~cjtàl vj~~gd hp Vxg~`dglt Ahjkj al Jvx`c :2#

86:8 ~gtt`lm j njv al UAN gk`~~àl~ exak ljtwxjc mj~jld a`c ejn`c`t`g~

{ ]bp JL~1 T`kg guacwtàl# j`x kj~~ jm`lm Xg~gxua`x ~vgn`g~ ae LAr ]bp N7~1

Caai`lm jt tbg xjtà ae ~`~tgx jcipc l`txjtg~ njllat hg jvvc`gdta jcipc l`txjtg~ 3N4 hgnjw~g tbgp jxg eaxkgd exak tbgdgnakva~`tàl ae tbg atbgx "Ecanig gt jc,# :002)

Xjtà ae `~avgltjlg ta l+vgltjlg `~ |8,7 ta :


6/28


7/28Vxgd`ntgd xjt`a? 6,527


8/28

^TGV : XB AB X B8A

^TGV 8 X A8 XA8

^TGV > njl ma `l t}a d`xgnt`al~

j) XA8 LA XA LA8

h) XA8 LA XALA8


9/28

Vbatacp~`~

XALA8 bu

XA LA8

Xgjnt`al }`tb ABXALA8 AB vxadwnt~


10/28


11/28

>+Kg+8+HwALA8 u~, 8+ >+ VgALA8


12/28

>+Kg+8+HwALA8 u~, 8+ >+ VgALA8


13/28


14/28

^TGV : XB AB X B8A i:# :

^TGV 8 X A8 XA8 i8

^TGV > njl ma `l t}a d`xgnt`al~

j) XA8 LA XA LA8 i>j ": 8)h) XA8 LA XALA8 i>h#


15/28

Vbatacp~`~

XALA8 bu

XA LA8 OXALA8

Xgjnt`al }`tb ABXALA8 AB vxadwnt~ i4


16/28

{ ^`kvc`e`njt`al"Hgxtkjl gt jc,# :007) XB XALA8 iJ#

XALA8 vxadwnt~ iHiJ ; i:YAB[

iH ; OXALA8 i4YAB[ ; :8

{ La}# }g njl w~g

YXALA8[!YXB[ ; iJ ": g"iJ+ iH)t)! "iH iJ)


17/28

{ OXALA8O"b) ; ") @ "b#) d

@ ; ~acjx ecwr `ltgl~`tp âcjx zgl`tb jlmcg ; >6

Ca~ Jlmgcg~ jxgj# :6 jk# 5!85!:8 Jnt`lt`n ecwr ujcwg~ jt Gjxtb~ ~wxejng

E`lcjp~al+V`tt~ jld V`tt~# 8666 ; jh~axvtàl nxa~~ ~gntàl

Jugxjmg ae jh~axvtàl nxa~~ ~gntàl ae`+VgALA8 jld :+VgALA8 "^`kv~al gt jc,# 866>)

< 807 lk


18/28

{ iH ; OXALA8 i4YAB[ >+Kg+8+HwALA8

i4 ; :,=8 r :6+:8 nk> kacgnwcg~+: ~+: 8+VgALA8

i4 ; :,27 r :6+:8 nk> kacgnwcg~+: ~+: >+VgALA8

i4 ; :,:8 r :6+:8 nk> kacgnwcg~+: ~+: Xaak tgkvgxjtwxg# Jti`l~al gt jc,# :006 G~t`kjtgd YAB[ ; 2,2 r :67 kacgnwcg~ nk+>

^`kv~al gt jc,# 866>


19/28

{ iJ ; i: YAB[ i:

>+Kg+8+HwALA8? i: ; i~gnaldjxp E"NB) E"NB>) 8+VgALA8? i: ; i~gnaldjxp E"NB8) E"NB>) >+VgALA8? i: ; i~gnaldjxp E"NB8) E"NB8) Jti`l~al# :02=j E"R) ; gGr!t

I}ai jld Jti`l~al# :007

Jugxjmg tgkvgxjtwxg augx a`ce`gcd~? 80> I YAB[ ; 2,2 r :67 kacgnwcg~ nk+>


20/28

{ Yvjxglt jcijlg[6; Jugxjmg k`r`lm xjtà ae tbgvjxglt jcijlg

{T}a ~gt~ ae djtj K`r`lm xjtà~ jugxjmgd eax j`x ~jkvcg~ augx a`c e`gcd~ K`r`lm xjtà~ jugxjmgd eax j`x ~jkvcg~ lat augx a`c e`gcd~

Yvjxglt jcijlg[6 ; Yvjxglt jcijlg[! g+iJt


21/28

{ ; :8 : ; i:!itatjc

itatjc `~ tbg ~wk ae gjnb xjtg nal~tjlt eax AB xgkau`lm j B exakgjnb ae tbg njxhal~ `l jl jcijlg

`~avgltjlg itatjc ; ivx`kjxpE"NB8) ivx`kjxpE"NB) i~gnaldjxpE"NB)E"NB>)

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i `~ tgkvgxjtwxg dgvgldglt 8

Jti`l~al gt jc,# :02=h


22/28


23/28


24/28

Kgj~wxgd ~cavg? 6,52

Kadgcgd ~cavg? 6,24 + Nxg} jld L^GXN Glm`lggx~{ ^JXV 86:8


27/28


28/28

{ Jti`l~al# X, ":006), Mj~+Vbj~g Txava~vbgx`n Nbgk`~txp ae Axmjl`n Nakvawld~? J Xgu`g}, Jtka~vbgx`n Glu`xalkglt# 84J"@)#:+4:,

{ Jti`l~al# X,# % Jxgp# O, "866>), Jtka~vbgx`n dgmxjdjtàl ae uacjt`cg axmjl`n nakvawld~, Nbgk`njc xgu`g}~# :6>":8)# 4567+>2,{ Jti`l~al# X, ":02=j), J ^txwntwxg+Jntù`tp Xgcjtàl~b`v eax tbg G~t`kjtàl ae tbg Xjtg Nal~tjlt~ eax tbg Mj~+Vbj~g Xgjntàl~ ae

AB Xjd`njc~ }`tb Axmjl`n Nakvawld~, :0# =00+282,

{ Jti`l~al# X, gt jc, ":02=h), Jcipc L`txjtg Eaxkjtàl exak tbg Xgjntàl ae j ^gx`g~ ae Hxjlnbgd XA8 Xjd`njc~ }`tb LA j~ j Ewlntàlae Tgkvgxjtwxg jld Vxg~~wxg,Oawxljc ae Jtka~vbgx`n Nbgk`~txp# 7":)# 0:+:68,

{ Jti`l~al# X, ":00=), Mj~+Vbj~g Txava~vbgx`n Nbgk`~txp ae Uacjt`cg Axmjl`n Nakvawld~? :, Jcijlg~ jld Jciglg~,Oawxljc aeVbp~`n~ jld Nbgk`~txp Xgegxglng Djtj# 85# 8:7+806,

{ Hgxtkjl# ^, gt jc, ":007), Guacwtàl ae jcipc l`txjtg~ }`tb j`x kj~~ jmg,Oawxljc ae Mgavbp~`njc Xg~gjxnb# :66"D::)# 88# 267+288#2:>,

{ Ncgk`t~bj}# I,N,# gt jc, ":00=), Mj~+vbj~g wctxjuàcgt jh~axvtàl nxa~~+~gntàl~ jld jtka~vbgx`n cègt`kg~ ae ~gugxjc N8+N7 jcipcl`txjtg~,Oawxljc ae Vbatanbgk`~txp jld Vbatahàcamp J? Nbgk`~txp# :68"8+>)# ::=+:85,

{ E`lcjp~al+V`tt~# H,O,# jld O,L, V`tt~# Nbgk`~txp ae tbg Wvvgx jld Ca}gx Jtka~vbgxg? Tbgaxp# Grvgx`kglt~# jld Jvvc`njtàl~# 050vv,# Jnjdgk`n# ^jl D`gma# Njcè,# 8666,

{ I}ai# G,^,# % Jti`l~al# X, ":007), G~t`kjtàl ae Bpdxarpc Xjd`njc Xgjntàl Xjtg Nal~tjlt~ eax Mj~+Vbj~g Axmjl`n Nakvawld~W~`lm j ^txwntwxg+Xgjntù`tp Xgcjtàl~b`v? Jl Wvdjtg, Jtka~vbgx`n Glu`xalkglt# 80":4)# :527+:507,

{ Xahgxt~# O,K, ":006), Nbgk`~txp ae Axmjl`n L`txjtg~# 84"8)# 84>+82=,{ Xahgxt~# O,K,# % Ejogx# X,], ":020), WU Jh~axvtàl Nxa~~ ^gntàl~ ae Axmjl`n L`txjtg~ j~ Vatglt`jc Jtka~vbgx`n @kvaxtjlng jld

G~t`kjtàl ae Jtka~vbgx`n Cègt`kg~# ":>)# 047+07:,

{ ^`kv~al# @,O, "866>), Vbatanbgk`njc vxadwntàl jld guacwtàl ae ~gcgntgd N8+N7 jcipc l`txjtg~ `l txava~vbgx`n j`x `lecwglngd hpJ~`jl awteca},Oawxljc ae Mgavbp~`njc Xg~gjxnb# :62"D86),{ Twxhgxm# K,V, gt jc, ":006), Jtka~vbgx`n Vbatanbgk`~txp ae Jcipc L`txjtg~,Oawxljc ae Vbatanbgk`~txp jld Vbatahàcamp# 7:#

82:+808,

{ Tjcwidjx# X,I, gt jc, ":00=), Jtka~vbgx`n ejtg ae ~gugxjc jcipc l`txjtg~# 0>":5)# 8=0=+8267,{ ]axtal# D,X, gt jc, "86:6), Jcipc l`txjtg vbatanbgk`~txp dwx`lm tbg txava~vbgx`n axmjl`n nbgk`~txp grvgx`kglt, Jtka~vbgx`n

Glu`xalkglt# 44"5)# ==>+=27,

C5 Alkyl Nitrate Mixing Ratios as Indicators of Crude Oil Influence on Air Masses

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