C I FINAL REPORT Gc i final report g r h field data acquisition t i for _ design of contaminated...
98
C I FINAL REPORT G r H FIELD DATA ACQUISITION t I FOR _ DESIGN OF CONTAMINATED GROUNDWATER 0 I EXTRACTION AND TREATMENT SYSTEM C VOLUME HI - APPENDICES B THROUGH E HELEVA LANDFILL SITE LEHIGH COUNTY, PENNSYLVANIA EPA WORK ASSIGNMENT NUMBER 37-08-3N59 CONTRACT NUMBER 68-W8-0037 C r I NUS PROJECT NUMBER 0224 C • SEPTEMBER 1989 Ut-j ftR30U526
Transcript of C I FINAL REPORT Gc i final report g r h field data acquisition t i for _ design of contaminated...
C I FINAL REPORTG
r H FIELD DATA ACQUISITIONt I FOR
_ DESIGN OF CONTAMINATED GROUNDWATER0 I EXTRACTION AND TREATMENT SYSTEM
C
VOLUME HI - APPENDICES B THROUGH E
HELEVA LANDFILL SITELEHIGH COUNTY, PENNSYLVANIA
EPA WORK ASSIGNMENT NUMBER 37-08-3N59CONTRACT NUMBER 68-W8-0037
Cr I NUS PROJECT NUMBER 0224
C• SEPTEMBER 1989
Ut-j
ftR30U526
FINAL REPORTFIELD DATA ACQUISITION
FORDESIGN OF CONTAMINATED GROUNDWATEREXTRACTION AND TREATMENT SYSTEM
VOLUME III - APPENDICES B THROUGH E
HELEVA LANDFILL SITELEHIGH COUNTY, PENNSYLVANIA
EPA WORK ASSIGNMENTNUMBER 37-08-3N59
CONTRACT NUMBER 68-W8-0037
NUS PROJECT NUMBER 0224
r! SEPTEMBER 1989
DISCLOSURE STATEMENT
This document contains proprietary information. The information furnished in this document shallnot be disclosed in whole or in part for any purpose other than to evaluate such information inaccordance with the terms of Contract Number 68-W8-0037.
TABLE OF CONTENTS
B MONITORING WELL BORING LOGS AND WELL CONSTRUCTION DIAGRAMS
C GROUNDWATER SAMPLE CHEMICAL ANALYTICAL RESULTS
D SOIL BORING LOGS AND LOAD BEARING CAPACITY CALCULATIONS
E EXTRACTION RATE AND WELL SPACING CALCULATIONS
F PREDICTION OF FLUSHING REQUIREMENTS FOR GROUNDWATER REMEDIATION
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APPENDIX F
PREDICTION OF FLUSHING REQUIREMENTSFOR GROUNDWATER REMEDIATION
This section provides the assumptions and equations used in the mass balance calculation forpredicting the approximate number of pore volumes to be flushed during the remediation of thegroundwater contamination in the bedrock aquifer beneath the Heleva Landfill Site.
Pore Volume Requirementi -
Based on distribution of contaminants between fractured bedrock and groundwater, and a model ofcontact between fractured rock and groundwater, the rate of contaminant removal from the aquifercan be calculated.
Assumptions used in the model are:
• Fractured rock/groundwater equilibrium• Distribution coefficients used are valid• The contact model is as follows:
- Saturated bedrock is 0.99 solids, 0.01 water- Water is completely drained- Fresh (uncontaminated) water is used to resaturate bedrock
TCE was selected as a first cut contaminant. Any contaminant with a portion coefficient less than TCEwill be removed at a higher rate.
Kd = Distribution coefficientKoc = Partition coefficient: for TCE = 126TOC = Total Organic carbon: for bedrock = 0.02%Cw = Concentration of contaminant in pore water = 148,000yg/l = 148,000ppbCs = Concentration of contaminant on solid: for bedrock
R33891 F-1 _ _ « *,. . f . -»ft&3{H»6i7
Kd = (126) (0.0002) = 0.025Cs = (Kd)(Cw)
Mass Balance on Contaminant
Total mass = mass in groundwater and mass on bedrock= Cw(densityofwater)(porosity) + Cs(density of rock)(1-porosity)= Cw(1x10-9l/yg)(0.01) + Cs(2.6x10-9 l/yg)( 1-0.01)
TM = Cw(1 x10-H yg/l) + Cs(2.57x 10-9 yg/l)
At time t = n, when n is 1 pore volume:
TAf,n = C (10~"J + C (2.57xlO~9w,n* ' • "v
When water is removed:
TMJ_,=|C )( 2.57xlO~a ) = (C . . )( 10'11 ) + ( C . , 2.57xl(Tn-r l -9 '11 ~9
Since:
Then:
C - \ K . Cs,n \ d
K,C (2.57xlO~9 = C IO~U + K.C )( 2.57x IO"9d
And:
C ., )( 10~U) + {K,}{ C J.1 )f 2.57x10 ~9ii "Vt + lM / \ dj\ w,n+l"C 2.57xlO~ =w,n **
R33891 F'2 R O O A J C t OAft3Qi*6 I 8
Cu,)J(2.57xlO-9) =
«v*+ 2.57xlO-9)(V)J\ d.)
2.57 If.d
0.01+1)12.57
To relate this to the original concentration:
Solving for n, the number of pore volumes to be flushed:
w,n
w,o( I \In
Inw,o
In0.01 ) 4-1 Kd )( 2.57
C ,Ji2.57xlO-9
R33891 F-3
AR30U619
The following is a printout of this calculation solving for n, using the above assumptions andcalculations.
R33891 F-4
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