Modern Theories of Acids & Bases The Arrhenius and Bronsted-Lowry Theories.
Bronsted Lowry Acid Base. Bronsted and Lowry An ACID donates a proton (loses an H+) An ACID donates...
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Transcript of Bronsted Lowry Acid Base. Bronsted and Lowry An ACID donates a proton (loses an H+) An ACID donates...
Bronsted Lowry
Acid Base
Bronsted and Lowry
An ACID donates a proton (loses an H+)
A BASE accepts a proton (gains an H+)
Conjugate Acid Base Pairs
When an acid loses its hydrogen, it becomes a base (as it is able to gain a hydrogen again)
This is known as a conjugate base
At the same time, when a base gains a hydrogen in a reaction, it becomes a conjugate acid
Weak acids are found on pages 8 and 9 in your data booklet. The conjugate base formula for each acid is directly right to the acid formula. Each conjugate is the result of a loss of 1 hydrogen.
It is important to note that acids and bases may be noted as salts (ionic compounds)
When this occurs, you must dissociate the ions and allow the demonstration of the proton transfer (omit the spectator ions)
Example
Potassium hydrogen sulfate and sodium acetate are mixed in aqueous solution
Strong acids form Weak Bases
A strong acid will have a conjugate base that is weak
Strong acids lose its proton easily (and therefore will not accept a hydrogen easily)
A weaker acid will have a stronger conjugate base
Weak acids hold their protons more (and therefore will easily accept a hydrogen)
Kw = KaKb
Kw is the equilibrium constant for water (1.0 x 10-14)
Ka is the equilibrium constant for acids and can be found on page 8 and 9 in the data booklet
Kb is the equilibrium constant for bases and will have to be calculated using Kw = KaKb
Acid Reactions
HA + H2O H3O+ + A-
Base Reactions
Amphiprotic Substances
An amphiprotic substance is a chemical species that can donate or accept a proton
Substance must contain a hydrogen to donate
Substance must be able to accept a hydrogen (usually have a negative charge)
Reactions Favor if the weak acid has a higher Ka
than the conjugate acid in the same equation, the reaction will proceed in the forward direction and favor the products
if the weak acid has a lower Ka than the conjugate acid, the reaction will proceed in the reverse direction and favor the reactants
Example
Write the Bronsted-Lowry equation for the reaction between acetic acid and sodium sulfate. Label the conjugate acid base pairs and comment on whether the products or reactants are favored:
Example 2
Write the Bronsted-Lowry equation for the reaction between lactic acid and potassium hydrogen carbonate. Label the conjugate acid base pairs and comment on whether the products or reactants are favored:
C2H5OCOOH(aq) + HCO31-(aq) C2H5OCOO1-(aq) +
H2CO3(aq)
acid base conj. Base conj. Acid
K = [H2CO3(aq)][C2H5OCOO1-(aq)]
[C2H5OCOOH(aq)][HCO31-(aq)]
Favors products!
Kacid = 1.4x104 Kconjacid = 4.5x10-7