2) BREATHER VALVES

I BASIC FUNCTION

The breather valve also known as pressure/vacuum relief valve is a protective device mounted on the top of a fixed roof atmospheric storage tank. Its primary function is to conserve the loss of storage tank content when the tank is in out-breathing mode. The purpose & selection of breather valve is mainly to control the in-breathing and out-breathing of storage tank by protecting the tank under over pressurization and vacuum and possible rupture or imploding

The storage tank needs a suitable size vent (fixed or controlled venting) to achieve in-breathing and out-breathing cycles during loading or unloading operations. The inbreathing of storage tank is due to the pump in of fluid to storage tank and condensing of vapour part of storage tank at lower ambient temperature. This develops a vacuum in the tank if fixed vent nozzles is under sized or controlled venting is in close mode till preset value. The out-breathing process is an opposite phenomenon to inbreathing and it takes place when the tank is loaded and evaporation of liquid due to higher atmosphere temperature. This phenomenon develops over pressure in tank if vent nozzle is under sized or controlled venting in close mode till preset value. The pressure and vacuum developed in the tank shall be within the design values allowable by a code and function of pressure / vacuum relief valve is to conserve the vapour loss by opening and closing within the set values to safeguard the tank design parameters.

a) Emergency Vent Valve

The pressure/vacuum relief valve is meant to take care of normal in-breathing and out-breathing functions. The minimum ambient temperature is a geographical phenomenon and can be estimated based on local metriological data for sizing the vent nozzles. However, maximum temperature is a function of storage tank exposure temperature due to external fire in an area in vicinity of storage tank or flashes due to chemical reaction within the tank.

In such a situation to cope up with the rate of evaporation of liquid stored in the storage tank based on worst wetted surface area of tank would call for an emergency vent valve which is pressure set at a value slightly higher than breather valve to work as stand by device under emergency situation when breather valve cannot control the rise in pressure of tank. The emergency vent valve maintains the positive pressure in the tank within allowable design parameters. Hence emergency vent valve can be termed as emergency pressure relief valve.

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COMP REF: BREATHER VALVES.DOC

b) Pressure or Vacuum Relief Valve

Pressure and vacuum relief valve is a composite unit to encounter the over pressure/vacuum condition within storage tank with single unit. However it is feasible to achieve two independent units one to control pressure and other to control vacuum and can be procured as pressure or vacuum relief valve. The basic function of each unit is identical to composite unit under respective area of work.

c) Gauge Hatch

This has similar function as emergency vent valve as far as construction features are concerned. However, this is recommended as a standby measure on top of storage tank to carry out manaul measurement of tank level with a metallic tape where conventional float and tape type level instrument is out of action.

d) Tank Blanketing Valve

The function of automatic tank blanketing valve is to maintain the constant pressure in the vapour space of storage tank when tank is under unloading mode or vapour under condensation due to low ambient temperature. Under both these pheonomena vacuums is developed within the tank and this will allow the inert gas to automatically enter the tank in vapour space and maintain the tank vapour space pressure. The advantage of this unit is to minimise the tank content to get vapourised due to loss in tank level while unloading and due to increase in ambient temperature.

e) Pilot Operated Relief Valve

The pilot operated relief valve is designed to provide safe, dependable and accurate low pressure and/or vacuum protection. Full flow is attained with no more than 10% over-pressure. This reduces the need of high over pressure design requirements which save products and prevents high fugitive emissions. Blowdown may be adjusted to the requirements between 0% to 20% of set pressure. Properly adjusted pilot operated relief valve is bubble tight upto 95% of set pressure.

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f) Air operated relief valve

Air operated relief valve is used to replace weight loaded & pilot operated valves in severe applications where polymerization & crystallization may take place & plug as well as corrode the control orifice. The air operated valve increases valve efficiency & reduces evaporation losses. The pressure switch coupled with a solenoid valve & using instrument air instead of corrosive product vapour provides a bubble tight seal. Additionally the use of clean air greatly reduces the maintenance time compared to the pilot operated valve. By using air operated valve remote sensing is provided by the pressure switch. The valve provides greater conservation due to minimum product loss.

II ADVANTAGE OF PRESURE/VACUUM RELIEF VALVE (EVAPORATION LOSSES)

Saving in cost of content lost in form of vapour Protects tank from over pressure or vacuum condition Protection under fire hazard Atmospheric corrosion of area in vicinity Control the emissions to atmosphere

1) Purpose

In reality properly sized opening on the tank roof protects the tank from rupture or imploading. However, it constantly outbreath and inbreath and during outbreathing cycle it losses the vapour to atmosphere and possesses constant fire hazard. This can be prevented by installation of pressure/vacuum relief valve. Cost of loss of vapour totally out weighs the cost of breather valve.

a) Calculating the tank content loss during outbreathing

- 20 feet dia and above

Ly = TPY ( P )68 D 1.73 H 0.51 T 0.50 FP

1000 14.7 – PLy = The outbreathing loss in barrels per year

TPY = Turn overs per year

P = The true vapour pressure at bulk liquid temperature in Lbs/in2 abs

D = Tank diameter in feet

H = The average outage in feet

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T = Average daily ambient temperature change

FP = Paint Factor

- Small dia tanks

Ly = TPY ( P )68 D 1.73 H 0.51 T 0.50 FP C 1000 14.7-P

b) API’s Estimated Breathing Loss Table

Tank Dia x Ht in feet

Nominal Tank Capacity barrels

Breathing Loss BBLS/Year saved using Pr Relief Valve

Estimated losses with Pressure Relief Valve

Estimated losses with open vent

30’ x 40’ 5000 154 235 8142.5’ x 40’ 10,000 297 441 14460’ x 30’ 20,000 570 825 255

100’ x 40’ 55,000 1382 2000 618

Due to the above statement breather valve is also termed as conservation vent valve.

c) Basic fire protection mode with usage of breather valve

- Observes close tank principle within set pressures on pressure and vacuum side hence vapours have no access to external fire source and to allow combustion

- Breather valve discharge to atmosphere is with positive pressure and the velocity of the relieving vapour is higher than flame speed hence protects the tank content from external fire source

- Over rich vapour mixture within tank due to equilibrium being reached in a closed tank, the vapours are too rich to burn. However when emptying the tank due to inbreathing of air and oxygen in air, the vapour mixture is

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susceptible to ignite hence flame arrestor shall be installed to protect the tank content

- In case of intermittent inbreathing the escape of vapour from tank to atmosphere do not exist hence it is always in safe mode.

d) Reduced Corrosion

- They help in reduction in overall corrosion in a plant due to controlled emmision of vapour

e) Recommendation

- Pressure/vacuum valves are recommended by API 2000 for use on atmospheric storage tanks in which the hydrocarbon with a flash point below 100o F is stored. OSHA recommends that tank storing Class I liquids shall be equipped with venting device which shall be normally closed except over set pressure or vacuum conditions. Generally speaking the majority of the regulatory bodies dealing with tank safety such as API, NFPA, OSHA insurance companies etc insist installations of these devices on flammable liquid storage tanks

III HOW PRESSURE/VACUUM RELIEF VALVES FUNCTION

The atmospheric storage tanks are designed for storage of liquid hydrocarbon at operating conditions close to atmospheric pressure and temperature conditions. The tanks are designed in such a way to overcome the routine over pressure and vacuum conditions prevailing in a tank due to loading, unloading operation and thermal expansion and contraction of liquid due to change in ambient temperature during the day and in a year. This kind of storage tanks are ideal and economical for storage of large quantity of liquid hydrocarbon and expensive chemicals in liquid form. These tanks are designed as per API 650 with conical reinforced roof with weak roof to shell design criteria and this is the criteria which imposes the restriction on over pressure and vacuum requirements beyond which the tank may rupture or implod and the main failure link is shell to roof joint. The normal range of design parameters for such tanks is (+) 150 MM WG & (-) 75 mm WG with respect to atmospheric pressure. The emissions of vapour from storage tanks is due to variations in vapour space within tank due to change in liquid level and variation in ambient temperature and its effect on wetted surface area of storage tanks.

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The breather valves are installed to reduce the continuous vapour loss to atmosphere through fixed vent nozzle to achieve the controlled losses with the set operating range of breather valve within the design pressure and vacuum parameters employed for the storage tanks. The saving in vapour loss is due to intermittent operation of breather valve. In order to accommodate large volumes at low set pressure these valves have ports that are greater in area compared to area of inlet port or nozzle provided on tank. The low setting values necessitates weight loading valve instead of spring loaded valve.

Because of weight loaded concept a pressure / vacuum valve requires approx 100% overset pressure in order to reach full opening of the valve. However, while deciding on a set pressure the maximum allowable working pressure MAWP should be at least twice of the required set pressure to obtain optimum flow. If the MAWPis less than 100% above the required set pressure then the valve shall be larger in size than normally required. The possibility of valve chatter and accelerated seat and diaphragm wear will exist if less than 20% over pressure is allowed. A pressure / vacuum valve is not same as high pressure safety valve and should not be sized at 10% to 20% over pressure.

Spring Loaded Valves

The small capacity storage tanks can be designed with dome roof instead of conical reinforced roof as per API 620. These tanks can be designed for higher range of pressure and vacuum conditioning w.r.t. atmospheric pressure. Say +2000 WG and –400 MM WG. This kind of storage tanks provides higher vapour conservations by opting out for spring loaded breather valves.

- When weight loaded valve becomes too massive then it can be replaced by compact design of spring loaded breather valve

- Most helpful where installation space is a constraint

IV SIZING OF PRESSURE / VACUUM RELIEF VALVES(AS PER API 2000)

A) BASIS

The following parameters need to be considered while sizing the pressure/vacuum relief valve :

1 Normal Relief : The sum of the vapour displacement resulting from filling + thermal outbreathing from storage tank or emptying + thermal inbreathing of storage tank

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2 Emergency Relief : Thermal outbreathing due to exposure of storage tank to external fire

B) Pressure / Vacuum Relief Valve Settings (As per API 2521)

Pressure/Vacuum valves on atmospheric pressure fixed roof tanks are usually set at ½ oz/in2 (22 mm WG) pressure or vacuum. Test data indicates that an increase of 1oz/in2 in the pressure set point over ½ oz/in2 reduces breathing losses by approximately 7%. However, the test data indicates that each additional increase of 1oz/in2 in pressure set point reduces the breathing losses in progressively smaller increments.

C) Pressure / Vacuum Relief Valve Settings (As per API 2513)

The pressure and vacuum setting of breather valves are directed by the structural characteristics of the tank and should be within safe operating limits. A certain amount of pressure and vacuum beyond this setting is necessary to overcome pressure drop in order to obtain required flow. Proper size and settings can be best determined by reference to API 2000.

D) Breather Valve Capacity Calculation

Q = A d2 2 x P x 9.805 x 3600 x E4 K x La

a = Volumetric flow M3/hr

d = Diameter of valve Meter

P = Total differential pressure

Set pressure + over pressure

Pressure mm H20

Vacuum mm H20

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K = Head loss co-efficient of valve (Refer Table 1)

Pressure & Vacuum

La = Density of air at valve test 1.2217 kg/m3

E = Overpressure correction factor ___________i) = Dead weight loaded valves 3 Over-pressure pressure & Set-pressure vacuum ___________ii) = Spring loaded valves 3 Over-pressure pressure & Set-pressure vacuum

E Breather valve size calculation _____________________

d = Q

16.05 x P x 2826 x E K

For units refer point (D) above

F To convert mass flow to equivalent volumetric air flow

Q = Ma x Tg Ta Mg x Wg

La

Q = Volumetric air flow = M3 /hr at 1.221 7 kg/m3 air

Density @ 293 o K

Wg = Mass flow rate kg/hr

Ma = Molecular wt of air 29

Ta = Absolute temperature of air o K (273 + o C)

Mg = Molecular wt of fluid

Tg = Absolute temp of process fluid o K (273 + o C)

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La = Density of air at valve test 1.2217 kg/m 3

G Venting requirements in accordance with API 2000

1 To determine volumetric air flow requirements as per API 2000

a) Outbreathing (SCFH air) due to hydrocarbon movement requirements

= 6.0 or 12.0 x barrels/hr filling + thermal requirements as per Table 1

12.0 for flash point of oil below 100o F

6.0 for flash point of oil at 100o F and above

b) Inbreathing (SCFH air) due to

Oil movement requirements = 5.6 x barrels/hr emptying + thermalRequirements as per Table 1.

Example :

Tank Size : 100 ft dia x 60 ft high (cap 84000 barrels)

Tank contents : Gasoline (Flash Point 50o F)

Filling rate : 6100 barrels/hr

Emptying rate : 3200 barrels/hr

- Outbreathing = 12 x 6100 + 53500 = 126,700 ScFH

Inbreathing = 56 x 3200 + 53500 = 71,420 ScFH

Tank capacity = Vertical storage tank (Barrels)

Where Df = Dia in feet, Dm = Dia in Metres

Barrels = 0.14 D f 2 x height in feet

Barrels = 4.944 Dm2 x height in metres

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c) Emergency Venting

The volumetric air flow requirements for emergency venting as per API 2000 for any specific liquid may be determined by the following formula :

Cubic feet of free air per hour = V x 1337 T L M 520

V = Cubic feet of free air from Table 2

L = Latent heat of vapourisation in BTU

M = Molecular Weight

T = Temp of Relief Valve in degree rankine

v) a) Broad specification for pressure & vacuum relief valve

- Size range 50 to 300 mm- Pressure range 25 to 2000 mm wg- Vacuum range 25 to 250 mm WG- Body material – Aluminium, cast iron, cast steel, stainless steel,

- PALLETS : OPERATING RANGE- PTFE, 35 to 100 mm

Aluminium 50 to 250 mmstainless steel 100 to 2000 mmwith soft insert of PTFE, Neoprene or viton

aluminium Seats : Stainless Steel

- Allowable leakage rateLit/hr

40 to 100 mm 1.13100 to 150 1.69150 to 200 2.25200 to 250 2.83

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b) Broad specification for emergency vent valve

- Size range : 200 mm to 750 mm- Pressure range : 100 mm to 250 mm WG and above- Body material : carbon steel, stainless steel- Seat : Stainless steel or Hastalloy “C”- Cover : Valve pellet PTFE diaphragm + soft nitrile rubber backing ring- Blowdown Rate : 20 to 25%- Over Pressure : Max 50% over set pressure to minimize leakage

VI FLAME ARRESTOR & BREATHER VALVE ASSEMBLIES

A flame arrstor is a safety device installed on a nozzle on top of a storage tank when the flash point of the stored product is lower than the possible tank temperature. A majority of the cases a vent to atmosphere pressure/vacuum valve is installed on top of the flame arrestor to achieve the safe storage of tank content and minimum emission of vapour to atmosphere. Even in order to control the emission to the atmosphere the flame arrestor and breather valve assembly mounted on the tank can be hooked up to flare, incinerator or thermal oxidiser.

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