Boston Seeds - TOXIC TO AQUATIC ORGANISMS, …sowing/pla ntin g) Grassland 6.0 6.0 per year 5 days...

DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label.All instructions within this section must be read carefully in order to obtain safeand successful use of this product.

IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/ INDUSTRIAL/FORESTRY/AQUATIC HERBICIDE

Maximum Maximum Crops/Situations Individual Dose Total Dose Latest Time of (litres of (litres of Application product per ha) product per ha) Wheat, durum wheat, barley, 4.0 4.0 per crop 7 days before harvest oats, combining pea, field bean Wheat, barley, oats, combining 1.5 1.5 per crop Pre-emergence and vining pea, field bean, oilseed rape, mustard, linseed, sugar beet, swede, turnip, bulb onion, leek Oilseed rape, linseed 4.0 4.0 per crop 14 days before harvest Mustard 4.0 4.0 per crop 8 days before harvest EITHER 4.0 4.0 per year 5 days before drilling or Stubbles of all edible crops, planting of following crop stubbles of all non-edible crops OR 1.5 1.5 per year 2 days before drilling or planting of following crop or 24 hours before cultivating All edible and non-edible 5.0 5.0 per year – crops (destruction prior to sowing/planting) Grassland 6.0 6.0 per year 5 days before harvest, grazing or drilling Hard surfaces, natural 5.0 – – surfaces not intended to bear vegetation, permeable surfaces overlying soil, enclosed waters, open waters, land immediately adjacent to aquatic areas Green cover on land not 6.0 6.0 per year 24 hours before cultivation being used for crop production Amenity vegetation 5.0 – – Apple, pear 5.0 5.0 per year After harvest but before green cluster stage Plum, cherry, damson 5.0 5.0 per year After harvest but before white bud stage Forestry, forest nursery – 10.0 – – weed control Forestry, forest nursery – 2ml per 10cm – – chemical thinning by diameter (or less) injection of tree Forestry, forest nursery – 200ml/litre – – stump applications of water (20% solution of product in water)

IMPORTANT INFORMATION continued OTHER SPECIFIC RESTRICTIONS: Users must consult the appropriate water regulatory body (Environmental ProtectionAgency/Scottish Environmental Protection Agency) before using this product to controlaquatic weeds. The maximum concentration of glyphosate in the water must not exceed

0.2 ppm or such lower concentration as the appropriate water regulatory body may require. The dose applied to green cover on land not being used for crop production must not exceed 6.0 litres of product per ha per year. When applying through rotary atomisers, the spray droplet spectrum must be of a minimum Volume Median Diameter (VMD) of 200 microns. Weedwipers may be used in any crop where the wiper or chemical does not touch the growing crop. The maximum concentrations used must not exceed a 1:2 dilution with water in a Weed wiper mini or a 1:1 dilution with water in other wipers. The maximum individual dose must not exceed 22.5 g/litre glyphosate for hydraulic knapsack sprayers. For stump applications, the maximum concentration must not exceed 200 ml product made up to a total volume of 1 litre with water (20% solution). READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

GENERAL INFORMATIONRosate 36 is a soluble concentrate herbicide, containing the active ingredient glyphosate, forthe control of most species of emerged annual and perennial grass and broad-leaved weeds.It is adsorbed by the weed foliage and translocated to the growing points in the roots and tothe underground rhizomes/stolons of perennial weeds. Best results are obtained from applicationsmade under good growing conditions (adequate soil moisture and warm/humid conditions),when the weeds are actively growing and at the recommended growth stages for treatment.After application, glyphosate is strongly adsorbed onto the soil particles and becomes practicallyimmobilized within the soil. As a result, it has no further herbicidal activity and it is subsequentlybroken down by microbial activity. New crops can be sown or planted at very short intervalsafter application.

WARNINGS AND RESTRICTIONSTAKE EXTREME CARE TO AVOID SPRAY DRIFT to avoid severe damage or complete destruction of plants outside the target area.DO NOT APPLY under windy conditions.DO NOT MIX, STORE, USE OR APPLY IN GALVANISED OR UNLINED STEEL CONTAINERSOR SPRAY TANKS.DO NOT allow the spray mixture to stand in the tank for a long period and make sure spraytanks are well vented.FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVED ORBURIED PRIOR TO GRAZING OR CUTTING FOR FEED when applications are made to foliagewhich will be subsequently fed to stock in any way. For use on hard surfaces, apply this product carefully. Ensure spraying takes place only whenweeds are actively growing (normally March to October) and is confined only to visible weedsincluding those in the 30cm swath covering the kerb edge and road gulley – do not overspraydrains. At least 6 hours are required for the spray to become rainfast and taken up by the foliage after application. For maximum efficacy, it is preferable that at least 24 hours elapsebefore any rainfall occurs after application. Do not apply where the target weeds are senescingnaturally or if they are under stress, particularly from drought, high temperatures or frost, asthey may be poorly controlled under these conditions. Weed control will take longer when weedsare growing slowly. Do not cultivate BEFORE application. After application, Rosate 36 takes several days to fully translocate through the plant. For this reason, do not make applications of fertiliser, lime, manure or other pesticides for at least 5days before or after application. Do not tank-mix with any other product except with a suitableauthorised adjuvant where specifically recommended on this label. After application, largeconcentrations of decaying foliage, roots, or rhizomes/stolons should be dispersed or buriedby thorough cultivation before crop drilling. Trace amounts of Rosate 36 remaining in thesprayer after use can cause damage to other crops subsequently treated with the sameequipment. Immediately after use thoroughly clean the sprayer and all equipment as detailedin the section “SPRAYER DECONTAMINATION”.

212

A soluble concentrate herbicide containing 360 g/ litre glyphosate acid present as 480 g/ litre (41.5% w/ w) isopropylamine salt and polyoxyethyleneamine surfactant.A foliar-applied, translocated herbicide for the control of annual and perennial weeds in a range of agricultural, horticultural, forestry, industrial, amenity and aquatic situations.

Rosate 36 – contains 480 g/litre (41.5% w/w) glyphosate isopropylamine salt andpolyoxyethyleneamine.

TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATICENVIRONMENTKEEP OUT OF THE REACH OF CHILDRENKEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFSWHEN USING DO NOT EAT, DRINK OR SMOKEUSE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATIONTHIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY

To avoid risks to man and the environment, comply with the instructions for use.DANGEROUS FOR

THE ENVIRONMENT

Approval Holder and Marketing CompanyAlbaugh Europe Sàrl, World Trade Center Lausanne, Avenue Gratta-Paille 2, 1018 Lausanne, SwitzerlandTel: + 41 21 799 9130 Fax: + 41 21 799 9139

MAPP 14459

The Control of Substances Hazardous to Health (COSHH) Regulations may apply to the use of this product at work.

IMPORTANT INFORMATIONFOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/INDUSTRIAL/FORESTRY/AQUATIC HERBICIDE.Crops: Wheat, durum wheat, barley, oats, oilseed rape, combining pea, mustard, field bean, linseed, sugar beet, swede, turnip, bulb onion, leek, stubbles of all crops, grassland, hard surfaces, natural surfaces not intended to bear vegetation, permeable surfaces overlying soil, all edible and non-edible crops (destruction of established vegetation prior to sowing or planting), green cover on land not being used for production, apple, pear, plum, cherry, damson, enclosed waters, open waters, land immediately adjacent to aquatic areas, forestry and forest nursery (weed control and chemical thinning by stump application and injection).Maximum Individual Dose per hectare, Maximum Total Dose per hectare, ) See underMaximum Number of Treatments, Latest Time of Application, Other Specific Restrictions: ) “Directions for Use”READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FORUSING PLANT PROTECTION PRODUCTS.

SAFETY PRECAUTIONSOperator protectionEngineering control of operator exposure must be used where reasonably practicable in addition tothe following personal protective equipment:WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate and when handlingcontaminated surfaces.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES ANDRUBBER BOOTS when using hand-held sprayers and hand-held rotary atomisers.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES,RUBBER BOOTS AND FACE PROTECTION (FACESHIELD) when using weedwiper equipment,making cut-stump treatments and using stem injection equipment.However, engineering controls may replace personal protective equipment if a COSHH assessment

shows they provide an equal or higher standard of protection.WASH CONCENTRATE from skin or eyes immediately.DO NOT BREATHE SPRAY.WASH HANDS AND EXPOSED SKIN before eating and drinking and after work.WASH ALL PROTECTIVE CLOTHING thoroughly after use, especially the insides of gloves.Environmental protectionDo not contaminate water with the product or its container, except when used as directed.Do not clean application equipment near surface water. Avoid contamination via drains fromfarmyards and roads.Storage and disposalKEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manuallyrinsing three times. Add washings to sprayer at time of filling and dispose of the container safely.

For advice on medical emergencies, fires, spillages or chemical hazards, telephone: 01235 239 670 (24 hour)

H

Albaugh Europe is a trading style of Albaugh Europe Sàrl and Albaugh UK Ltd.

PROTECT FROM FROST

ROSATE 36 20L LEAF ENG MONSANTO_AlbEU-UK_Rosate 36 MAPP 14459_LB_5-20L_CR_MS_23-07-13 23/07/2013 16:09

DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label.All instructions within this section must be read carefully in order to obtain safeand successful use of this product.

IMPORTANT INFORMATION FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/ INDUSTRIAL/FORESTRY/AQUATIC HERBICIDE

Maximum Maximum Crops/Situations Individual Dose Total Dose Latest Time of (litres of (litres of Application product per ha) product per ha) Wheat, durum wheat, barley, 4.0 4.0 per crop 7 days before harvest oats, combining pea, field bean Wheat, barley, oats, combining 1.5 1.5 per crop Pre-emergence and vining pea, field bean, oilseed rape, mustard, linseed, sugar beet, swede, turnip, bulb onion, leek Oilseed rape, linseed 4.0 4.0 per crop 14 days before harvest Mustard 4.0 4.0 per crop 8 days before harvest EITHER 4.0 4.0 per year 5 days before drilling or Stubbles of all edible crops, planting of following crop stubbles of all non-edible crops OR 1.5 1.5 per year 2 days before drilling or planting of following crop or 24 hours before cultivating All edible and non-edible 5.0 5.0 per year – crops (destruction prior to sowing/planting) Grassland 6.0 6.0 per year 5 days before harvest, grazing or drilling Hard surfaces, natural 5.0 – – surfaces not intended to bear vegetation, permeable surfaces overlying soil, enclosed waters, open waters, land immediately adjacent to aquatic areas Green cover on land not 6.0 6.0 per year 24 hours before cultivation being used for crop production Amenity vegetation 5.0 – – Apple, pear 5.0 5.0 per year After harvest but before green cluster stage Plum, cherry, damson 5.0 5.0 per year After harvest but before white bud stage Forestry, forest nursery – 10.0 – – weed control Forestry, forest nursery – 2ml per 10cm – – chemical thinning by diameter (or less) injection of tree Forestry, forest nursery – 200ml/litre – – stump applications of water (20% solution of product in water)

IMPORTANT INFORMATION continued OTHER SPECIFIC RESTRICTIONS: Users must consult the appropriate water regulatory body (Environmental ProtectionAgency/Scottish Environmental Protection Agency) before using this product to controlaquatic weeds. The maximum concentration of glyphosate in the water must not exceed

0.2 ppm or such lower concentration as the appropriate water regulatory body may require. The dose applied to green cover on land not being used for crop production must not exceed 6.0 litres of product per ha per year. When applying through rotary atomisers, the spray droplet spectrum must be of a minimum Volume Median Diameter (VMD) of 200 microns. Weedwipers may be used in any crop where the wiper or chemical does not touch the growing crop. The maximum concentrations used must not exceed a 1:2 dilution with water in a Weed wiper mini or a 1:1 dilution with water in other wipers. The maximum individual dose must not exceed 22.5 g/litre glyphosate for hydraulic knapsack sprayers. For stump applications, the maximum concentration must not exceed 200 ml product made up to a total volume of 1 litre with water (20% solution). READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

GENERAL INFORMATIONRosate 36 is a soluble concentrate herbicide, containing the active ingredient glyphosate, forthe control of most species of emerged annual and perennial grass and broad-leaved weeds.It is adsorbed by the weed foliage and translocated to the growing points in the roots and tothe underground rhizomes/stolons of perennial weeds. Best results are obtained from applicationsmade under good growing conditions (adequate soil moisture and warm/humid conditions),when the weeds are actively growing and at the recommended growth stages for treatment.After application, glyphosate is strongly adsorbed onto the soil particles and becomes practicallyimmobilized within the soil. As a result, it has no further herbicidal activity and it is subsequentlybroken down by microbial activity. New crops can be sown or planted at very short intervalsafter application.

WARNINGS AND RESTRICTIONSTAKE EXTREME CARE TO AVOID SPRAY DRIFT to avoid severe damage or complete destruction of plants outside the target area.DO NOT APPLY under windy conditions.DO NOT MIX, STORE, USE OR APPLY IN GALVANISED OR UNLINED STEEL CONTAINERSOR SPRAY TANKS.DO NOT allow the spray mixture to stand in the tank for a long period and make sure spraytanks are well vented.FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVED ORBURIED PRIOR TO GRAZING OR CUTTING FOR FEED when applications are made to foliagewhich will be subsequently fed to stock in any way. For use on hard surfaces, apply this product carefully. Ensure spraying takes place only whenweeds are actively growing (normally March to October) and is confined only to visible weedsincluding those in the 30cm swath covering the kerb edge and road gulley – do not overspraydrains. At least 6 hours are required for the spray to become rainfast and taken up by the foliage after application. For maximum efficacy, it is preferable that at least 24 hours elapsebefore any rainfall occurs after application. Do not apply where the target weeds are senescingnaturally or if they are under stress, particularly from drought, high temperatures or frost, asthey may be poorly controlled under these conditions. Weed control will take longer when weedsare growing slowly. Do not cultivate BEFORE application. After application, Rosate 36 takes several days to fully translocate through the plant. For this reason, do not make applications of fertiliser, lime, manure or other pesticides for at least 5days before or after application. Do not tank-mix with any other product except with a suitableauthorised adjuvant where specifically recommended on this label. After application, largeconcentrations of decaying foliage, roots, or rhizomes/stolons should be dispersed or buriedby thorough cultivation before crop drilling. Trace amounts of Rosate 36 remaining in thesprayer after use can cause damage to other crops subsequently treated with the sameequipment. Immediately after use thoroughly clean the sprayer and all equipment as detailedin the section “SPRAYER DECONTAMINATION”.

212

A soluble concentrate herbicide containing 360 g/ litre glyphosate acid present as 480 g/ litre (41.5% w/ w) isopropylamine salt and polyoxyethyleneamine surfactant.A foliar-applied, translocated herbicide for the control of annual and perennial weeds in a range of agricultural, horticultural, forestry, industrial, amenity and aquatic situations.

Rosate 36 – contains 480 g/litre (41.5% w/w) glyphosate isopropylamine salt andpolyoxyethyleneamine.

TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG-TERM ADVERSE EFFECTS IN THE AQUATICENVIRONMENTKEEP OUT OF THE REACH OF CHILDRENKEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFSWHEN USING DO NOT EAT, DRINK OR SMOKEUSE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATIONTHIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY

To avoid risks to man and the environment, comply with the instructions for use.DANGEROUS FOR

THE ENVIRONMENT

Approval Holder and Marketing CompanyAlbaugh Europe Sàrl, World Trade Center Lausanne, Avenue Gratta-Paille 2, 1018 Lausanne, SwitzerlandTel: + 41 21 799 9130 Fax: + 41 21 799 9139

MAPP 14459

The Control of Substances Hazardous to Health (COSHH) Regulations may apply to the use of this product at work.

IMPORTANT INFORMATIONFOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL/INDUSTRIAL/FORESTRY/AQUATIC HERBICIDE.Crops: Wheat, durum wheat, barley, oats, oilseed rape, combining pea, mustard, field bean, linseed, sugar beet, swede, turnip, bulb onion, leek, stubbles of all crops, grassland, hard surfaces, natural surfaces not intended to bear vegetation, permeable surfaces overlying soil, all edible and non-edible crops (destruction of established vegetation prior to sowing or planting), green cover on land not being used for production, apple, pear, plum, cherry, damson, enclosed waters, open waters, land immediately adjacent to aquatic areas, forestry and forest nursery (weed control and chemical thinning by stump application and injection).Maximum Individual Dose per hectare, Maximum Total Dose per hectare, ) See underMaximum Number of Treatments, Latest Time of Application, Other Specific Restrictions: ) “Directions for Use”READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FORUSING PLANT PROTECTION PRODUCTS.

SAFETY PRECAUTIONSOperator protectionEngineering control of operator exposure must be used where reasonably practicable in addition tothe following personal protective equipment:WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate and when handlingcontaminated surfaces.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES ANDRUBBER BOOTS when using hand-held sprayers and hand-held rotary atomisers.WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS), SUITABLE PROTECTIVE GLOVES,RUBBER BOOTS AND FACE PROTECTION (FACESHIELD) when using weedwiper equipment,making cut-stump treatments and using stem injection equipment.However, engineering controls may replace personal protective equipment if a COSHH assessment

shows they provide an equal or higher standard of protection.WASH CONCENTRATE from skin or eyes immediately.DO NOT BREATHE SPRAY.WASH HANDS AND EXPOSED SKIN before eating and drinking and after work.WASH ALL PROTECTIVE CLOTHING thoroughly after use, especially the insides of gloves.Environmental protectionDo not contaminate water with the product or its container, except when used as directed.Do not clean application equipment near surface water. Avoid contamination via drains fromfarmyards and roads.Storage and disposalKEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manuallyrinsing three times. Add washings to sprayer at time of filling and dispose of the container safely.

For advice on medical emergencies, fires, spillages or chemical hazards, telephone: 01235 239 670 (24 hour)

H

Albaugh Europe is a trading style of Albaugh Europe Sàrl and Albaugh UK Ltd.

PROTECT FROM FROST

ROSATE 36 20L LEAF ENG MONSANTO_AlbEU-UK_Rosate 36 MAPP 14459_LB_5-20L_CR_MS_23-07-13 23/07/2013 16:09 Page 1

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TRANSFORMATION PROCESSESEffects on brewing and baking have not been established. Consult grain merchant or processorbefore use.

WEEDS CONTROLLEDRosate 36 controls most species of emerged annual and perennial grass and broad-leavedweeds. After application the active ingredient is translocated from the treated foliage to theroots and other underground parts of perennial plants. Weeds are most susceptible to Rosate 36when they are actively growing under warm, humid conditions with adequate soil moisture.Poor control will occur if application is made to weeds that are subject to natural senescenceor if their growth is held back by dry conditions, waterlogging, high temperatures or frost.Weed control can also be reduced if these conditions occur soon after application. Any othersituation that restricts uptake into the plant (e.g., a covering of dust on the foliage from wind-blown soil) will reduce levels of weed control. It is important that weeds are actively growing and at the correct growth stages at the time ofapplication, otherwise re-growth can occur and will require subsequent re-treatment.Symptoms of weed control are usually seen within 7 – 10 days after application but it maytake longer under poor growing conditions. Treated foliage usually shows a gradual wilting andloss of vigour followed by a slight reddening then yellowing followed by plant death. Symptomsare usually seen on grass weeds before becoming apparent on broad-leaved weeds.Complete death and deterioration of the weed foliage and root system may take up to 4 weeksor longer under poor growing conditions. For application rates of Rosate 36 of 2.0 litres per ha or less, in certain situations it isrecommended to add a suitable authorised adjuvant. Do not use an adjuvant when applyingthrough a rotary atomiser sprayer.

Annual WeedsFor best results annual weeds must be growing actively at the time of application. Annualgrass weeds should have at least 5 cm of emerged leaf length and broad-leaved weedsshould have at least 2 fully expanded true leaves. When used for the control of green cover on land not being used for production, annualgrasses such as Black-grass and Brome grasses should be treated either at full ear emergenceor before stem elongation. Treatments made during the stem elongation phase of annualgrasses may result in poor weed control and require a further application.

Perennial WeedsFor best results perennial broad-leaved weeds must be treated when they are actively growing(they are most susceptible around the time of flowering). Perennial grass weeds must have developed an actively growing fully emerged foliage whenthe application is made. For Common couch the tillering stage (when the growth of new rhizomesstarts) is the most susceptible growth stage. This is usually when there are 4 – 5 leaves, eachabout 10 – 15 cm in length.The action of Rosate 36 on the control of Nettles is slow and it does not give an acceptablelevel of control of Horsetails (Equisetum arvense) from a single application.

FOLLOWING CROPSAfter application, glyphosate is strongly adsorbed by the soil particles and subsequently brokendown by microbial activity. Once absorbed onto the soil, Rosate 36 has no further herbicidalactivity and crops can be sown or drilled at specified intervals after application. However, a slightcheck to crop growth can occur if seeds of the newly planted crop germinate within the residualmat of dying and decaying weed foliage, roots, or rhizomes/stolons. Direct drilled crops areparticularly susceptible. Cultivate the ground thoroughly to disperse or bury the decaying organicmatter remaining after application. Loose or fluffy soils/seedbeds should be consolidated and anormal programme of fertiliser and crop protection treatments should be applied as appropriateto the new crop, particularly where this follows destruction of grassland.Trees and shrubs may be planted 7 days after application. Grass may be sown 14 days after application.All other crops may be sown or planted 2 days after application.

RESISTANCE MANAGEMENTThere is low risk for the development of weed resistance to Rosate 36. Strains of some annual weeds (e.g., Black-grass, Wild oats and Italian Ryegrass) have developedresistance to herbicides which may lead to poor control. A strategy for preventing and managingsuch resistance should be adopted. This should include integrating herbicides with a programme

of cultural control measures. Guidelines have been produced by the Weed Resistance ActionGroup and copies are available from the HGCA, CPA, your distributor or crop adviser. Implementa weed resistance strategy based on Good Agricultural Practice and including the following:Follow the label recommendations.Adopt complementary weed control practices.Minimise the risk of spreading weed infestations.Implement good spraying practice to maintain effective weed control.Use the correct spray nozzles to maximise coverage.Apply only under appropriate weather conditions.Monitor herbicide performance and report any unexpected results to Albaugh Europe Sàrl.

APPLICATIONBefore use, make sure the spraying equipment is cleaned from any previous use and that it iscalibrated to apply the recommended spray volume and pressure. This is particularly importantwhen using low-volume applications. After use, make sure the sprayer and all equipment isthoroughly cleaned as detailed in the section “SPRAYER DECONTAMINATION”.Do not store, mix or use in unlined or galvanized steel tanks or equipment.Spray immediately after mixing, do not allow the mixture to stand for long periods in the spraytank and ensure that tanks are well ventilated.

Tractor-mounted or Trailed SprayersBefore use, make sure the sprayer is cleaned from any previous use and calibrated to applythe recommended spray volume and pressure. Make sure all the sprayer nozzles are performingequally and that the spray boom is set at the correct height above the target weeds. This isparticularly important when making pre-harvest applications to a crop.Unless a different water volume is specified under “Crop Recommendations”, apply in 80 – 250litres of water per hectare as a MEDIUM or COARSE spray (BCPC) and with a spray pressureof 1.5 – 2.5 bars using suitable 80° or 110° nozzles. For best results and to reduce the risk ofspray drift, use a spray pressure within this range. The preferred application volume is normallybetween 200 – 250 litres per ha but this can be reduced with the use of appropriate low volumenozzles, adjusting spray pressure and tractor ground speed (tractor speed will typically needto be set to 4 – 9 kph). Do not allow the spray boom to bounce or yaw, this is particularlyimportant for pre-harvest applications. Ensure that the water volume selected gives a goodeven spray cover of the target weeds.Half fill the sprayer tank with clean water and begin gentle agitation. To avoid the mixingoperation resulting in excessive foaming, do not use agitation from the top of the tank. Addthe required quantity of product into the sprayer tank and allow to disperse fully. Rinse thecontainers thoroughly by using an integrated pressure rinsing device or manually rinsing threetimes. Add the washings to the sprayer and continue agitation whilst topping up the tank withwater to the required level. Continue agitation until the mix is sprayed out. The use of a de-foamingproduct may be necessary.Spray immediately after mixing, do not allow the mixture to stand. If a tank-mix with an authorisedadjuvant is being used, add to the sprayer tank separately, and follow any specific instructionson the order of mixing.

Knapsack SprayersKnapsack sprayers may be used for spot or directed applications, for example to land not intendedto bear vegetation, orchards, non-crop areas and in forest and farm forestry. Apply in 100 – 300 litres of water per hectare as a MEDIUM or COARSE spray (BCPC). Forwater volumes in the range of 100 – 150 litres of water per ha, it will be necessary to fit lowvolume spray nozzle(s).Example spray dilution calculation: to apply 5.0 litres per ha of Rosate 36 in a water volume of200 litres per ha in a sprayer tank of capacity 5 litres, add 125 ml of Rosate 36 to 4.88 litres ofwater in the sprayer tank. This volume of diluted spray will cover an area of 250 m2. Do notmake up a spray solution of a greater quantity than required for the area to be treated. Ensurean even spray coverage with an even walking speed during application.Half fill the sprayer tank with clean water. Add the required quantity of product into the sprayertank and allow to disperse fully. Rinse the containers thoroughly by using an integrated pressurerinsing device or manually rinsing three times. Add the washings to the sprayer and top up thetank with water to the required level and mix thoroughly by agitating the tank. Spray immediatelyafter mixing, do not allow the mixture to stand. If a tank-mix with an authorised adjuvant isbeing used, add to the sprayer tank separately, and follow any specific instructions on theorder of mixing.


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Rotary Atomiser SprayersApply through a rotary atomizer sprayer using a minimum water volume of 40 litres per ha and aspray droplet spectrum of a minimum Volume Median Diameter (VMD) of 200 microns and up to300 microns. This corresponds to a MEDIUM or COARSE spray (BCPC). The tractor forwardspeed will typically be in the range of 4 – 9 kph but it must be calibrated in the field to apply thecorrect spray volume. Use a spray bout marker to avoid overlapping spray bouts.Do not tank-mix Rosate 36 with any adjuvant when applying through Rotary Atomiser Sprayers.

Hand-held WeedwipersFor use only in orchards and non-crop situations. Use a concentration of 1 part of Rosate 36to 2 parts of water. Do not exceed this maximum concentration and add a dye (water-based) ifnecessary.

Tractor-mounted WeedwipersTractor-mounted weedwipers may be used in grassland and arable crops for the control ofWeed beet, Sugar beet bolters and other tall weeds growing above the crop. DO NOT USE WEEDWIPERS IN SOFT FRUIT CROPS.WEEDS THAT ARE NOT ACTIVELY GROWING WILL NOT BE CONTROLLED.KEEP STOCK OUT of treated areas for 7 days.THE FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVEDOR BURIED PRIOR TO GRAZING OR CUTTING FOR FEED. To ensure that application does not result in crop damage, the weeds should always be atleast 10 cm taller than the crop vegetation and a distance of 5 cm must be maintained betweenthe top of the crop vegetation and the wiper. The optimum weed height for treatment is 10 cmabove the height of the crop vegetation. If the weed vegetation is dense, it will be necessary to make two passes of the wiper fromopposite directions of the tractor travel. Weeds growing from below the wiped area will needsubsequent applications.To minimize weed seed return to the soil, application should be made prior to weed seedmaturity. For sugar beet bolters, apply a programme of three applications with an interval oftwo weeks between applications starting in early July to early August.Use a concentration of 1 part of Rosate 36 to 1 part of water. Do not exceed this maximumconcentration. Under very hot or dry conditions it may be necessary to reduce the concentrationto 1 part of Rosate 36 to 2 parts of water. For best results, ensure that the wiping surface isimpregnated with the herbicide solution at all times but does not drip. Clean the wiping ropesas required during the working day to ensure that flow rate to the wiping surface is maintainedat full rate at all times. The maximum recommended forward speed is 5 kph or less.

CROP RECOMMENDATIONSPre-harvest Treatment in Arable CropsRosate 36 can be applied as a pre-harvest treatment for the control of weeds in certainrecommended arable crops prior to harvest for the control of a range of perennial and annualgrass and broad-leaved weeds. DO NOT TREAT CROPS GROWN FOR SEED.Consult the processor before use on any crop intended for processing.

Wheat (including Durum Wheat), Barley and OatsApply when the moisture of the youngest grains in the ear is below 30% and not less than 7days before harvest. Make an accurate measurement of seed moisture immediately prior toapplication.DO NOT TREAT CROPS GROWN FOR SEED.To minimise crop damage, apply using a high-clearance tractor fitted with narrow wheels andcrop dividers.Do not use straw from a treated crop as a horticultural mulch. Straw from a treated crop maybe used for any other purpose.After harvest, straw may be chopped, incorporated or removed according to normal practiceand the land can be cultivated normally after harvest and straw disposal.For best results if dull weather conditions occur after application, allow up to 14 days betweenapplication and harvest.

Certain broad-leaved weeds (Annual nettle, Rosebay willow-herb, Redshank, Pale persicaria andKnotgrass) are not susceptible at rates of 1.5 l/ha or less. For application rates of Rosate 36 of2.0 litres per ha or less, in certain situations it is recommended to add a suitable authorised adjuvant.Do not use an adjuvant when applying through a rotary atomiser sprayer.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy and/or weed foliage is dense. Alternativelyapply in a minimum of 40 litres of water per ha using a rotary atomiser sprayer ensuring thatthe spray droplet spectrum is in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.

Weed Species/Situation Application rate – Litres product/hectare

Common couch – up to 25 shoots/m2 2.0*

Common couch 25 – 75 shoots/m2 3.0

Common couch – over 75 shoots/m2 in direct drilled crops 4.0 Perennial broad-leaved weeds and other perennial grasses

Annual grasses, cereal stems, cereal leaves plus reduction 1.0* of green material in the crop (harvest management aid)

Annual broad-leaved weeds plus reduction of green 1.5* material in the crop (harvest management aid)

*For application rates of Rosate 36 of 2.0 litres per ha or less, it is recommended in certainsituations to add a suitable authorised adjuvant. Do not use an adjuvant when applyingthrough a rotary atomiser sprayer.

Oilseed Rape and MustardApply when the moisture of the grains (crop seeds) is below 30% and at the timing as indicatedbelow. Make an accurate measurement of seed moisture immediately prior to application.Oilseed Rape: 14 – 21 days before harvest. Observe the latest time of application of 14 days before harvest.Mustard: 8 – 10 days before harvest. Observe the latest time of application of 8 days before harvest.DO NOT TREAT CROPS GROWN FOR SEED.To minimise crop damage, apply using a high-clearance tractor fitted with narrow wheels andcrop dividers. After harvest, straw may be chopped, incorporated or removed according to normal practiceand the land can be cultivated normally after harvest and straw disposal.Uneven crop maturity may occur from applications made to crops under stress due to drought,disease or excessive heat.Do not treat patches or areas of the crop that are late maturing due to any cause (e.g.,waterlogging or pigeon damage).Do not treat crops that have a significant number of secondary re-growth shoots.Apply in 100 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy and/or weed foliage is dense. Do not apply with a rotary atomiser sprayer. Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.


Common couch – up to 75 shoots/m2

Annual weeds 3.0 Crop destruction before direct combine harvesting (harvest management aid)

Common couch – over 75 shoots/m2 4.0 Perennial broad-leaved weeds and other perennial grasses

11

Likely routes of exposure and related long and short termsymptoms and health effects:Inhalation: There is a low risk of exposure by inhalation. Short-term symptoms and effects:Possible slight nasal irritation and discharge.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Eye contact: There is a risk of exposure by eye contact.Short-term symptoms and effects:Possible slight transitory redness and swelling.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Skin contact: There is a risk of exposure by skin contact.Short-term symptoms and effects:Possible slight transitory redness.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Ingestion: There is a very low risk of accidental exposure by ingestion.Short-term symptoms and effects:Possible mild gastrointestinal effects.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.

12. ECOLOGICAL INFORMATIONAll the information and data contained in this section are derived fromdata on similar mixtures.12.1 ToxicityAcute ToxicityLC50 fish, Oncorhynchus mykiss (96h): 8.2 mg/lEC50 aquatic inverterbrates, Daphnia magna (48h): 11.0 mg/lErC50 algae, Selenastrum capricornutum (72h): 8.0 mg/lLD50 birds, Mallard duck: >5620 mg/kgHoney bees:LD50 oral, Apis mellifera (48h): >395 µg/beeLD50 contact, Apis mellifera (48h): >338 µg/bee12.2 Persistence and degradability: Not readily biodegradable12.3 Bioaccumulative potential: No significant potential forbioaccumulation12.4 Mobility in soil: Not readily mobile, binds strongly to soil12.5 Results of PBT and vPvB assessment: No PBT or vPvBassessments have been carried out on the mixture; please refer to 12.1,12.2 & 12.3.12.6 Other adverse effects: Not determined.12.7 Additional Information: None.13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methodsDisposal of waste product, contaminated packaging materials and anyexcess diluted spray should be in accordance with ‘The HazardousWaste (England and Wales) Regulations 2005’ and any other applicablelocal or national legislation (for guidance refer to the MAFF/HSE“Pesticides: Code of Practice for the Safe Use of Pesticides on Farmsand Holdings”). For the handling and management of accidental release,follow the information given under Section 6 and 7.14. TRANSPORT INFORMATION14.1 UN number: UN 308214.2 UN Proper shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains N-(phosphonomethyl)glycine, compound with 2-propylamine(1:1) and tallow alkylamine ethoxylate)

14.3 Transport hazard class(es): 914.4 Packing group: III14.5 Environmental hazards:Land transport ADR/RID - Environmentally Hazardous: YesMaritime transport IMDG - Marine pollutant: Yes14.6 Special Precautions for User:Land transport ADR/RID - Tunnel restriction code: E14.7 Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Code: IBC Code: IBC0315. REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislationspecific for the substance or mixture:EU RegulationsREGULATION (EC) No 1107/2009 of The European Parliament and ofthe Council of 21 October 2009 concerning the placing of plantprotection products on the market and repealing Council Directives79/117/EEC and 91/414/EEC. Council Directive 67/548/EEC of 27 June1967 on the approximation of laws, regulations and administrativeprovisions relating to the classification, packaging and labelling ofdangerous substances.DIRECTIVE 1999/45/EC of the European Parliament and of the Councilof 31 May 1999 concerning the approximation of the laws, regulationsand administrative provisions of the Member States relating to theclassification, packaging and labelling of dangerous preparations.REGULATION (EC) No 1272/2008 of the European Parliament and of theCouncil of 16 December 2008 on classification, labelling and packagingof substances and mixtures, amending and repealing Directives67/548/EEC and 1999/45/EC, and amending Regulation (EC) No1907/2006.REGULATION (EC) No 1907/2006 of the European Parliament and of theCouncil of 18 December 2006 concerning the Registration, Evaluation,Authorisation and Restriction of Chemicals (REACH), establishing aEuropean Chemicals Agency, amending Directive 1999/45/EC andrepealing Council Regulation (EEC) No 793/93 and CommissionRegulation (EC) No 1488/94 as well as Council Directive 76/769/EECand Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010amending Regulation (EC) No 1907/2006 of the European Parliamentand of the Council on the Registration, Evaluation, Authorisation andRestriction of Chemicals (REACH)National Regulations/legislation:The Chemicals (Hazard Information & Packaging for Supply) Regulations2009 (CHIP 4). Health and Safety at Work etc. Act 1974, as amended,the Control of Substances Hazardous to Health Regulations 1999(COSHH), as amended.15.2 Chemical Safety AssessmentNo Chemical Safety Assessment under Regulation (EC) 1907/2006 isrequired and has not been carried out.

16. OTHER INFORMATIONa) Indication of changes:The numbering system identifying new versions and/or revisions of thisSDS is incremental. An increment by an integer number identifies theissue of a new version requiring provision of updates according toArticle 31(9) of REACH, while an increment by a decimal identifies minorchanges such as typographical errors, text improvements and/orformatting. Revisions indicated by a decimal point do not affect the riskmanagement measures or information on hazards, do not refer torestrictions imposed and/or to authorisations granted or refused.The paragraphs where changes have been made are indicated by thesymbol ‘!’ in the margin.

b) Abbreviations and acronyms:N: Dangerous for the environment.Xn: Harmful.c) Key literature references and sources for data:Albaugh Europe SàrlECHA Guidance on the compilation of safety data sheets (Version 1.1,December 2011)d) Classification and procedure used to derive the classification formixtures according to Regulation (EC) 1272/2008 [CLP]Not Applicablee) Relevant R-phrases, H-statements and precautionary statementsnot written out in full under Sections 2 to 15:R22 Harmful if swallowed.R41 Risk of serious damage to eyes.R50 Very toxic to aquatic organisms.R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.

H302 Harmful if swallowedH318 Causes serious eye damageH400 Very toxic to aquatic lifeH411 Toxic to aquatic life with long lasting effectsf) Training advice:General occupational hygiene training recommended.g) Further information:The information and recommendations in this publication are, to thebest of our knowledge, information and belief, accurate at the date ofpublication. Nothing herein is to be construed as a warranty, expressedor implied. In all cases it is the responsibility of the user to determine theapplicability of such information or the suitability of any products fortheir own particular purpose.

This Material Safety Data Sheet was compiled by Albaugh Europe Sàrl([email protected]) in compliance with Regulation (EC)1907/2006 as amended by 453/2010.


5

Combining Pea, Field BeansApply when the moisture of the grains (crop seeds) is below 30% and at least 7 days beforeharvest. Make an accurate measurement of seed moisture prior to application. Observe thelatest time of application of 7 days before harvest.DO NOT TREAT CROPS GROWN FOR SEED.Apply using a high-clearance tractor fitted with narrow wheels and crop dividers to minimisecrop damage.Not for use as a crop desiccant treatment.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy is dense. Alternatively apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns. Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.


Common couch – up to 75 shoots/m2 3.0


LinseedApply when the moisture of the grains (crop seeds) is below 30% and at least 14 days beforeharvest. Make an accurate measurement of seed moisture prior to application. The seed podswill usually be brown, the seeds light brown, and the plant leaves and stems yellow-green togreen in colour.An interval of up to 4 weeks may be required before the crop can be harvested by direct combining.Weeds may not be susceptible from applications made in the autumn – see “Weed Control”.DO NOT TREAT CROPS GROWN FOR SEED.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy is dense. Do not apply with a rotary atomiser sprayer.Select the correct application rate according to the weed species to be treated, weed population or situation as in the table below.



Common couch – over 75 shoots/m2 4.0

Perennial broad-leaved weeds and other perennial grasses 4.0

Crop destruction before direct combine harvesting 3.0 (harvest management aid)

Treatment of Stubbles of all Crops or Cultivated Land prior to Sowing or Planting anyCrop except Orchards (see Separate Section “Orchards”)Control of Common Couch, other Perennial Grasses and Volunteer Potatoes (Autumn) inStubbles of all CropsRosate 36 can be applied to the stubbles of all crops in the autumn or spring for the control ofCommon Couch, other perennial grasses and volunteer potatoes, prior to cultivation and sowingor planting of any crop.The ground must not be cultivated prior to application. Leave an interval of at least 5 days before and after application. Volunteer potatoes (autumn application only) must have a significant amount of top growth atapplication.For spring applications allow a minimum of 21 days of weed growth prior to application. Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a higher

volume within this range where the crop canopy is dense. Alternatively, apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed population or situation as in the table below.



Common couch – over 75 shoots/m2

Other perennial grasses 4.0 Volunteer potatoes – autumn treatment only

Control of Volunteer Cereals, Annual Grasses and Annual Broad-leaved Weeds in Stubblesof all Crops or on already Cultivated Land prior to Sowing or Planting any Crop. Rosate 36 can be applied to the stubbles of all crops prior to cultivation or to already cultivatedland in the autumn or spring for the control of Volunteer cereals, annual grasses and annualbroad-leaved weeds prior to cultivation and sowing or planting of any crop.Land may be cultivated after an interval of at least 24 hours has elapsed after application.Land can be direct drilled after an interval of at least 2 days has elapsed after application.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a higher volumewithin this range where the crop canopy is dense. Alternatively, apply in a minimum of 40 litres ofwater per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrum is in therange of a Volume Median Diameter (VMD) of 200 – 300 microns.Apply Rosate 36 at 1.5 litres per ha and for best results add a suitable authorised adjuvant. Donot use an adjuvant when applying through a rotary atomiser sprayer.

Destruction of Established Grassland with Weed Control prior to Re-seeding, Planting orSowingRosate 36 can be used for the destruction of established grassland and weeds present in thesward prior to re-seeding, planting or sowing new grassland or any other crop. Apply to grass re-growth after grazing or cutting. Alternatively, apply before grazing or cuttingbetween June – October to grassland 30 – 60 cm high that is not dense and before maturityof grass seeds.Grassland crops can be used in the normal manner after 5 days have elapsed after application,including grazing by or feeding to cattle, dairy cows or sheep. THE FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVEDOR BURIED PRIOR TO GRAZING OR CUTTING FOR FEED.Following removal of the grass crop, normal cultivations may be carried out in preparation forplanting or sowing the following crop.DO NOT APPLY any fertiliser or lime application prior to application of Rosate 36.Apply in 150 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the grass canopy or weed foliage is dense.Do not apply with a rotary atomiser sprayer.Select the correct application rate according to the grassland situation to be treated as in thetable below and according to the rate required for the control of the least susceptible weedspecies present in the sward – see “Grassland Weed Control” below.


Short rotation Rye-grass containing annual weeds 3.0

Grass leys 2-4 years old containing perennial grass weeds 4.0

Longer term grass leys 4-7 years old containing 5.0 perennial broad-leaved weeds

Permanent pasture 6.0

controllable, provide sufficient ventilation and control the release at itssource.6.1.2 For emergency respondersClothing conforming to EN469.6.2 Environmental precautionsUse appropriate containment to avoid environmental contamination.Control the release at its source. Contain the spill to prevent it fromspreading, contaminating soil or entering sewage and drainage systemsor any body of water. Inform the local water company if the releaseenters drains and the Environment Agency (England and Wales), theScottish Environmental Protection Agency (Scotland) or the Environmentand Heritage Service (Northern Ireland) if it enters surface or groundwaters. 6.3 Methods and material for containment and cleaning upFor containmentClean up spills immediately and place in a compatible disposalcontainer. Contain spill by diking with earth, sand or absorbent materialand place into a compatible marked disposal container.For cleaning upScrub area with a hard water detergent. Soak up wash liquid withadditional absorbent material and place into a compatible markeddisposal container. Seal container and arrange for disposal.Other information: Not Applicable6.4 Reference to other sectionsRefer to Section 8 for personal protective equipment and to Section 13for disposal instructions.

7. HANDLING AND STORAGE7.1 Precautions for safe handlingObtain special instructions before use. Do not handle until all safetyprecautions have been read and understood. Provide suitable ventilationin the areas where the product is stored and used. Contaminated workclothing should not be allowed out of the workplace. Avoid all contactby mouth, with eyes and skin. Wear personal protective equipment asspecified in Section 8. When using, do not eat, drink or smoke. Removecontaminated clothing and protective equipment before meals and afterwork. Wash hands and exposed skin before meals and after work. Washall protective clothing thoroughly after use, especially the insides of gloves.7.2 Conditions for safe storage, including any incompatibilitiesThe mixture is stable under normal ambient conditions. Keep in originalcontainer, in a dry, cool and safe place. Store in a locked, suitable store.Keep away from any source of ignition. Keep out of the reach of childrenand unauthorised personnel. Keep away from food, drink and animalfeeding stuffs. 7.3 Specific end use(s)Herbicide for professional use as directed by the product label, everyother use is hazardous.

8. EXPOSURE CONTROL/PERSONAL PROTECTION8.1 Control ParametersOccupational Exposure limit valuesNo occupational Exposure limit values have been set for the mixture orits components.Information on monitoring procedures: None available.8.2 Exposure controls8.2.1 Appropriate engineering controlsEngineering controls and appropriate work processes must be used toeliminate or reduce worker and environmental exposure in the areaswhere the substance is handled, transported, loaded, unloaded, storedand used. These measures must be adequate for the extent of theactual risk. Provide adequate local exhaust ventilation. Use specializedtransfer systems if available.

8.2.2 Personal protection equipmentEye and face protectionAvoid contact with eyes. If there is a significant potential for contact,wear suitable eye and face protection (EN 166).Skin protection:Hand protection: Wear suitable protective gloves against chemicals (EN374 part 1, 2, 3). Nitrile rubber min. 0.5mm thick and 300mm long glovesare the ones proven to be the most suitable according to tests onpesticide products. Wash the gloves thoroughly after each use,especially the insides. Replace gloves if damaged and before exceedingthe breakthrough time.Body protection: Avoid contact with skin. If there is a significantpotential for contact, wear suitable coveralls (ISO 13982-1, Type 5, EN13034, Type 6).Other skin protection: None specified.Respiratory protection: No special requirement when used asrecommended. If a risk assessment shows that engineering controls donot provide adequate respiratory protection to exposure to sprayparticles, wear particle filtering half mask (EN 149) or half maskconnected to particle filter (EN 140 + 143).8.2.3 Environmental exposure controlsImplement all applicable local and community environmental protectionlegislation. Refer to Section 15. Use appropriate containment to avoidenvironmental contamination. Do not empty into drains. Do notcontaminate water with the product or used container. Do not cleanapplication equipment near surface water. Avoid contamination viadrains from farmyards and roads. Refer to Section 12 and 13.

9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesa) Appearance: Liquid

Colour: Amberb) Odour: Faint aminec) Odour threshold: Not determined – not required under all

applicable pesticide legislation.d) pH: 5.07 undiluted formulation

4.7 (1% dilution in water)e) Melting point/

freezing point: Not applicable – the mixture is a liquid at ambient temperature and must be protected from frost

f) Initial boiling point and boiling range: Approximately 100 °C

g) Flash point: None – the mixture is water-basedh) Evaporation rate: Not available - not required under all

applicable pesticide legislation.i) Flammability (solid, gas): Not applicable (liquid)j) Upper/lower flammability

or explosive limits: Not applicable – the mixture is water-based

k) Vapour pressure: No significant volatility – the mixture is water-based

l) Vapour density: Not applicable - not required under all applicable pesticide legislation.

m) Density: 1.175 g/cm3 at 20°Cn) Solubility(ies)

Solubility (water): Completely soluble in watero) Partition coefficient: n-octanol/water:

Glifosate, acido: Log Po/w<-3,2 (25 °C, pH valore: 5-9)p) Auto-ignition temperature: >400 °C

Minimum Ignition Temperature: Not available

Minimum Ignition Energy: Not availableq) Decomposition temperature: Glyphosate acid: 199.1 °Cr) Viscosity: 67.6 mPa.s at 20°C, 27.3 mPa.s at 40°Cs) Explosive properties: Explosion hazard: not explosive.t) Oxidising properties: Not an oxidising agent.9.2 Other informationSurface tension: 36.8 mNmFlammability (in contact with water): Not flammable

10. STABILITY AND REACTIVITY10.1 ReactivityNon-reactive when stored in original container under normal conditionsof storage and use. 10.2 Chemical stabilityStable when stored in original container under normal conditions ofstorage and use.10.3 Possibility of hazardous reactionsNo hazardous reactions when stored in original container under normalconditions of storage and use. Reacts with strong bases and strongoxidising substances, galvanised steel and unlined mild steel with therelease of hydrogen, a highly flammable gas that may explode. 10.4 Conditions to avoidContact with galvanised steel and unlined mild steel, strong bases andstrong oxidising substances. Do not store in proximity of sources ofignition and direct sunlight.10.5 Incompatible materialsGalvanised steel and unlined mild steel. Avoid contact with strong basesand strong oxidising substances.10.6 Hazardous decomposition productsDuring decomposition evolves toxic fumes including nitrogen oxides,carbon oxides and phosphorus oxides.

11. TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects11.1.1 Substances: Non applicabile.11.1.2 MixturesAll the data contained in this section are derived from actual test data onthe mixture unless otherwise stated.

a) Acute toxicity:LD50 oral, rat: >5000 mg/kg bwLD50 dermal, rabbit: >5000 mg/kg bwLC50 inhalation, rat: >5.12 mg/l

b) Irritation:Skin: Slight irritant (not classified as a skin irritant under Directive 1999/45/EC)Eye: Mild eye irritant (not classified as an eye irritant under Directive 1999/45/EC)

c) Corrosivity: Not classified as corrosive on the basis of skin and eye irritation studies

d) Sensitisation: The product is not classified as a respiratory or skin sensitizer in animal studies

e) Repeated dose toxicity: Not classified as hazardous for repeated dose toxicity on the basis of mixture component information

f) Carcinogenicity: Not classified as carcinogenic on the basis of mixture component information

g) Mutagenicity: Not classified as mutagenic on the basis of mixture component information

h) Toxicity for reproduction: Not classified as a reproductive toxicant on the basis of mixture component information

10


6

Grassland Weed ControlThe following weeds are controlled at 3.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Annual meadow-grass Meadow FescueCommon chickweed Meadow FoxtailCommon mouse-ear Rough meadow-grassDock seedlings Speedwell sppItalian rye-grass Timothy grassMayweed speciesThe following weeds are controlled at 4.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Black bent Creeping soft-grassBroad-leaved dock Curled dockCock’s foot Perennial rye-grassCommon bent PlantainsCommon couch Soft bromeCreeping bent Yorkshire fogThe following weeds are controlled at 5.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Bracken (at full frond expansion) Red cloverCommon sorrel SedgesCommon nettle Sheep’s sorrelCreeping buttercup Soft rushCreeping thistle Spear thistleDaisy Tufted hair-grassDwarf thistle YarrowPerennial sow-thistleThe following weeds are controlled at 6.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Common ragwort Nardus (Mat grass)Hard rush Red fescueHeath rush Sheep’s fescueJointed rush White clover *Molinia (Purple moor-grass) Yellow rattle*For best results against White clover, cut in June and spray 4 weeks later. Hard Surfaces, Natural Surfaces not intended to bear Vegetation, Permeable SurfacesOverlying SoilApply in 80 – 400 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the weed foliage is dense. Alternatively, apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns. Rosate 36 may beused for the control of unwanted vegetation in non-crop areas such as roadsides, paths, hardsurfaces and along fence lines, walls and similar situations in amenity and industrial areas.People, domestic pets and wildlife do not need to be excluded from the treated area. However,to avoid direct transfer of the wet spray onto desired vegetation, it is advisable not to walk inthe treated area until the spray is dry on the foliage. Apply this product carefully. Ensurespraying takes place only when weeds are actively growing (normally March to October) and isconfined only to visible weeds including those in the 30cm swath covering the kerb edge androad gulley – do not overspray drains. DO NOT USE IN OR ALONGSIDE HEDGEROWS.DO NOT USE UNDER GLASS OR POLYTHENE.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below. Weed Species/Situation Application rate – Litres product/hectare Annual weeds 1.5* Perennial grass and perennial broad-leaved weeds 5.0

*For application rates of Rosate 36 of 2.0 litres per ha or less, it is recommended in certain situationsto add a suitable authorised adjuvant. Do not use an adjuvant when applying through a rotaryatomiser sprayer.

Enclosed Waters, Land immediately adjacent to Aquatic Areas and Open WatersRosate 36 may be used for the control of dense infestations only of emerged and floatingweeds in enclosed waters, open waters and on land immediately adjacent to aquatic areas,e.g. reservoirs, irrigation ditches, water courses and waterways. Before use read the official code of practice “Guidelines for the Use of Herbicides on Weeds inor near Watercourses and Lakes” obtainable from: Department of the Environment and Rural Affairs (DEFRA publications, Tel: 08459 556000);Rural Affairs Department, Scottish Executive;Department of Agriculture and Rural Development for Northern Ireland;National Assembly for Wales Agriculture Department.The following legislation may apply to the use of Rosate 36 for the control of weeds in enclosedwaters, open waters and on land immediately adjacent to aquatic areas:Water Act 1989Water Resources Act 1991Control of Pollution Act 1974Northern Ireland Water Resources Act 1992Control of Pollution and Local Government (Northern Ireland) Order 1978Consult the appropriate water regulatory body (Environmental Protection Agency/ScottishEnvironmental Protection Agency) before using this product to control aquatic weeds. Themaximum concentration of glyphosate in the water must not exceed 0.2ppm or such lowerconcentration as the appropriate water regulatory body may require. Rosate 36 may be used iffish are present in the water provided it is used in strict accordance with theserecommendations.For the control of dense infestations of emerged reeds, soft-rush, bulrush, bent-grass,creeping-grass, canary-grass, sweet-grass, whorl-grass and water-cress, apply 5.0 litres perhectare in 250 litres of water per ha using a hydraulic nozzle sprayer or a hand-held sprayer.For most species, treat actively growing plants during August – September. Best resultsagainst water-cress are obtained from spraying in June. Treat bulrush in late July.For the control of dense infestations of floating white water-lily and yellow water-lily, apply 6.0litres per ha in 100 – 200 litres of water per ha using a hydraulic nozzle sprayer or a hand-heldsprayer. Treat actively growing floating weeds during July – August.For best results, use a boat-mounted or tractor-mounted sprayer with a maximum spray pressureof 2.0 bar.When using a boat-mounted sprayer, minimise the forward speed to as low as possible so asto cause minimum wake and disturbance of the floating weed foliage. Even under ideal applicationconditions, some leaves may be disturbed by the boat or wash prior to full absorption of thespray and require a further application 2 – 3 weeks later. In flowing water, make the applicationagainst the direction of the water current. When using a tractor-mounted sprayer do not exceeda forward speed of 8 kph.

OrchardsRosate 36 may be used on land that is to be planted to orchard (top fruit) or in establishedorchards.

Land to be planted to Orchard with Top Fruit TreesApply in 200 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the weed foliage is dense. Alternatively apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.

9

ROSATE 36SAFETY DATA SHEET according to Regulation (EC) 453/2010

Version 1 UK Issue date: 07/05/20131. IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY1.1 Product identifierTrade nameRosate 361.2 Relevant identified uses of the mixture and uses advised against1.2.1 Relevant identified usesFor professional use only as anagricultural/horticultural/industrial/forestry/aquatic herbicide.1.2.2 Uses advised againstDo not use for any other purpose.1.3 Details of the supplier of the safety data sheetAlbaugh Europe SàrlWorld Trade Center Lausanne, Avenue Gratta-Paille, 21018 Lausanne, SwitzerlandTelephone: + 41 21 799 9130Fax: + 41 21 799 9139E-mail: [email protected]: www.albaugheurope.eu1.4 Emergency telephone numberFor advice on medical emergencies, fires or major spills: +44 (0) 1235239 670Available: 24hTime Zone: GMTLanguage(s) of phone service: All EU languages UK National Poisons Information Service: +44 (0)121 507 4123 (Forhealth professionals only)Available: 24hTime Zone: GMTLanguage(s) of phone service: English2. HAZARDS IDENTIFICATION2.1 Classification of the substance or mixtureClassification according to Regulation (EC) no. 1272/2008[CLP/GHS]This product has not yet been classified under Regulation (EC) no.1272/2008 [CLP/GHS]Classification according to Directive 67/548/EEC or 1999/45/ECN; R51/53: Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.Additional informationFor abbreviations, refer to Section 16.2.2 Label elementsLabelling according to Directive 67/548/EEC or 1999/45/ECHazard pictograms

DANGEROUS FOR THE ENVIRONMENTIndication of danger:Dangerous for the environmentRisk phrases:R51/53: Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.Safety advice:S2: Keep out of reach of children.S13: Keep away from food, drink and animal feeding stuffs.S20/21: When using do not eat, drink or smoke.S35: This material and its container must be disposed of in a safe way.

S57: Use appropriate containment to avoid environmentalcontamination.2.3 Other hazardsNone known3. COMPOSITION / INFORMATION ON INGREDIENTS3.1 SubstancesNot relevant3.2 MixturesDescription of the mixture:Mixture of glyphosate isopropylamine salt and co-formulants.• Chemical Name: N-(phosphonomethyl) glycine, compound with 2- propylamine (1:1) CAS-No.: 38641-94-0 EC-No.: 254-056-8 Index No. - Concentration (W/W): 41.5 % 67/548/EEC Classification: N; R51/53 CLP (Reg. 1272/2008) Classification: Hazardous to the aquatic environment, Chronic hazard, Cat2, H411• Chemical Name: Tallow alkylamine ethoxylate CAS-No.: 61791-26-2 EC-No.: - Index No. - Concentration (W/W): 15.5 % 67/548/EEC Classification: Xn; R22, R41, N; R50 CLP (Reg. 1272/2008) Classification: Acute Toxicity, oral, Cat4, H302 Serious Eye Damage, Cat1, H318, Hazardous to the aquatic environment, Acute hazard, Cat1, H400• Chemical Name: Other ingredients CAS-No.: - EC-No.: - Index No. - Concentration (W/W): to 100% 67/548/EEC Classification: Not classified CLP (Reg. 1272/2008) Classification: Not classifiedAdditional informationFor full text of R- and H-phrases, see Section 16.4. FIRST AID MEASURES4.1 Description of first aid measuresGeneral notes:If symptoms occur after exposure to this product, seek medicalattention immediately and show the product label or this SDS. Removeto fresh air and keep at rest. Do not allow smoking or eating. Take off allcontaminated clothing and footwear. Following inhalation:Remove to fresh air and keep at rest in half-upright position. Seekmedical attention immediately.Following skin contact:Remove all contaminated clothing. Wash skin with soap and rinse withplenty of water. Seek medical attention if irritation arises. Wash clothesbefore re-use.Following eye contact:Immediately rinse with water. Holding eyes open, continue rinsing for 15minutes at least. Remove contact lenses as soon as possible. Seekmedical attention immediately.Following ingestion:If swallowed, DO NOT INDUCE VOMITING: seek medical adviceimmediately and show this container or label. Remove any residuesfrom mouth and rinse it with plenty of water. Offer the casualty 1 or 2glasses of water to drink. Never give anything by mouth to anunconscious person.Self-protection of first aiderPersonal protective equipment for first aid responders is recommended

according to potential for exposure (refer to Section 8).Notes for the doctor:No specific antidote. Treat symptomatically (decontamination, vitalfunctions). Call a Poison Centre immediately for treatment advice. Incase of ingestion gastric lavage may be necessary (with proper laryngealcontrol). Before emptying the stomach, assess the potential dangerarising from lung aspiration against the product toxicity. Report toAlbaugh Europe Sàrl any unusual symptoms occurring after exposureby any route.4.2 Most important symptoms and effects, both acute and delayedFollowing inhalation:Possible slight nasal irritation and discharge. No delayed effectsexpected.Following skin contact:Possible slight transitory redness. No delayed effects expected.Following eye contact:Possible slight transitory redness and swelling. No delayed effectsexpected.Following ingestion:Possible mild gastrointestinal effects. No significant delayed effectsexpected.4.3 Indication of immediate medical attention and special treatmentneededNo need to provide any special means/medicinal products forimmediate treatment at the workplace, no specific antidote available.

5. FIRE FIGHTING MEASURES5.1 Extinguishing mediaSuitable extinguishing media:Carbon dioxide, water spray, alcohol-resistant foam, dry chemical forsmall fires, alcohol-resistant foam or water spray for large fires.Unsuitable extinguishing media:Solid water jet.5.2 Special hazards arising from the mixtureHazardous combustion productsEvolves toxic and corrosive fumes in fire including nitrogen oxides,carbon oxides and phosphorus oxides.5.3 Advice for fire-fightersClothing conforming to EN469 should be sufficient to deal with firesinvolving the mixture. However, a Self-Contained Breathing Apparatus(SCBA) may be required if there is a potential for exposure tocombustion fumes.5.4 Additional informationProvide storage and work areas with suitable fire extinguishers.Call the Fire Brigade at once to deal with all fires involving pesticidesunless the fire is small and immediately controllable. Spray unopenedcontainers with a mist spray to keep cool. If without risk, remove intactcontainers from exposure to fire. Contain fire-fighting water, bunding ifnecessary with sand or earth. Do not allow contamination of publicdrains or surface or ground waters. Dispose of fire debris andcontaminated water as advised in the MAFF/HSE “Pesticides: Code ofPractice for the Safe Use of Pesticides on Farms and Holdings”.

6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergencyprocedures6.1.1 For non-emergency personnelProtective equipment: Remove immediately any contaminated clothing.Wear prescribed personal protective equipment to prevent contact witheyes and skin. A Self-Contained Breathing Apparatus (SCBA) may berequired if there is an elevated risk for exposure.Emergency procedures: Call the emergency services if the release is notimmediately controllable. If the release is localized and immediately


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Weed Species Situation Application rate – Litres product/hectare Perennial grasses and In stubbles of arable crops 4.0 broad-leaved weeds In pasture land 5.0

All top fruit crops may be planted after 7 days have elapsed after treatment.

Established Apple, Pear, Plum, Damson and Cherry OrchardsApply in 200 – 400 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the weed foliage is dense. Do not apply with a rotary atomisersprayer. Timing: apply after trees have lost their leaves in the autumn, but before the green cluster stagein apples and pears, and before the white bud stage in plums, cherries and damsons.Do not use until after trees have been established for 2 years.Avoid spray coming into contact with tree branches and tree trunks at a height of over 30 cmabove the ground.Do not make more than 1 application per year.

Weed Species/Situation Application rate – Litres product/hectare Perennial grasses and broad-leaved weeds 5.0 Root suckers – apply in late spring only

Wheat, Barley, Oats, Oilseed Rape, Combining Pea, Field Bean, Mustard, Linseed, SugarBeet, Swede, Turnip, Bulb Onion and LeekRosate 36 may be used as a post-sowing, pre-crop emergence treatment for the control ofvolunteer cereals and annual weeds on land planted with wheat, barley, oats, oilseed rape,combining pea, field bean, mustard, linseed, sugar beet, swede, turnip, bulb onion and leek.APPLICATION MUST BE MADE PRIOR TO ANY CROP EMERGENCE. Apply 1.5 litres per ha of Rosate 36 in 80 – 250 litres of water per ha by means of a hydraulicnozzle sprayer. Alternatively, apply in a minimum of 40 litres of water per ha using a rotaryatomiser sprayer ensuring that the spray droplet spectrum is in the range of a Volume MedianDiameter (VMD) of 200 – 300 microns.

Green Cover on Land not being used for Crop ProductionRosate 36 may be used on land not being used for crop production (“set-aside”) for the controlof perennial and annual grass and broad-leaved weeds before or during removal from production.Before use on land temporarily removed from production, make sure that any applicationcomplies with any rules and stipulations under grant programmes or other managementconsiderations.Do not top cut or cultivate immediately prior to application.For the control of perennial weeds, allow at least 21 days of growth in the spring prior to applicationand at least 5 days after application prior to drilling or cultivating. For the control of annualweeds, allow at least 24 hours after application prior to cultivating. Do not direct drill afterapplication to set-aside.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the foliage is dense. Alternatively, apply in a minimum of 40litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns. Application can alsobe made using tractor-mounted weed-wiper equipment.Select the correct application rate according to the weeds present as in the table below:

Weed Species/Situation Application rate – Litres product/hectare Common couch – up to 75 shoots/m2 3.0


Perennial broad-leaved weeds 4.0 and other perennial grasses

Annual weeds – application in early Autumn or Spring 1.5

Annual weeds – application in late Spring or Summer 3.0

Forestry and Forest NurseryRosate 36 may be used for pre-planting site preparation, weed control in established plantingsand for chemical thinning by stump applications and direct injection.

Weed Control – Pre-planting Site PreparationRosate 36 may be used for the control of arable and grassland weeds in arable land, grasslandareas and land to be re-planted prior to planting. Do not plant trees until at least 7 days haveelapsed after application.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer.Use the higher volume within this recommended range where the weed foliage is dense.Alternatively, apply in a minimum of 40 litres of water per ha using a rotary atomiser sprayerensuring that the spray droplet spectrum is in the range of a Volume Median Diameter (VMD)of 200 – 300 microns.Apply 4.0 litres per ha for the control arable weeds and at 5.0 litres per ha for the control ofgrassland weeds.

Weed Control – Post-planting Directed ApplicationsRosate 36 may be used for weed control around conifers and deciduous trees as a directedspray application using a hand-held sprayer.Apply using a 2.0% spray concentration with a knapsack sprayer fitted with a tree guard. Forexample, in a knapsack sprayer with a 5.0 litre tank, use 100 ml of Rosate 36 in 5.0 litres of water.For all directed spray applications made during the growing season, a tree guard must be fittedto avoid damage to the trees.Apply to Bracken when the tips of the fronds are fully unfurled but prior to senescence.Apply to Heather during the period from late August to the end of September.For Rhododendron, cut the coppice back and treat when it is over 1 metre in height. Apply thespray to just before the point of run-off.All other woody weeds from June to August should be treated before leaf senescence hasstarted but after new growth of the crop has hardened off. Select the application rate per ha according to the target weeds to be controlled as in the following table:


Woody weeds including Ash, Beech, Bracken, Brambles, 3.0 Hazel, Oak, Sycamore and Willow

Annual and perennial grass and broad-leaved weeds 4.0 Heather on peat soils

Heather on mineral soils 6.0

Rhododendron 10.0 #

# The rate can be reduced to 8.0 litres per ha if a suitable authorised adjuvant is added.

Weed Control – Overall post-planting Application in the Dormant SeasonRosate 36 may be applied as an overall application to certain conifer species in the dormantseason for the control of grass weeds, Bracken, Brambles, Beech and Birch.DO NOT MAKE AN OVERALL APPLICATION TO CHRISTMAS TREES OR OTHER SPECIESGROWN FOR ORNAMENTAL PURPOSES.Apply in 200 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – usea higher volume within this range where the weed foliage is dense. Alternatively, apply usinghand-held equipment. Rosate 36 may be safely applied as an overall spray to the species listed below, providingthey are fully dormant and that leader shoot growth has hardened off. Corsican pine Norway spruceDouglas fir (do not apply in Spring) Scots pineLawson cypress Sitka spruceLodgepole pine Western red cedarNoble fir (do not apply in Spring)

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The actual time of leader shoot growth becoming fully hardened off can vary considerablyaccording to location and season. It can range from late July until October or later.To avoid damage to lammas growth, direct the spray away from the leaders. It is recommendedto make a trial application to a small area of trees to check crop safety under local conditionsbefore wide-scale application in following years. Select the application rate per ha according to the target weeds to be controlled as in thetable below. These reduced application rates are specifically for use in Forestry. Poor weedcontrol may occur if they are used in other situations.


Grass weeds in lowland areas 1.5

Grass weeds in upland areas 2.0 Bracken, Beech and Birch

Brambles 3.0

Chemical Thinning by Stump ApplicationApplication rate:Deciduous trees: Apply a dilution of 1 part of Rosate 36 to 9 parts of water (10% solution).Coniferous trees: Apply a dilution of 1 parts of Rosate 36 to 4 parts of water (20% solution).A suitable water based dye can be added to the dilution in order to mark treated stumps.Apply the diluted solution to the rim of the freshly cut tree surface, apply liberally to saturatethe surface. Apply with a spot gun, paintbrush or specially adapted clearing saw. Apply to cutstumps as soon as possible after cutting, only during the period between November to April andbefore the start of active sap flow in spring or early summer. Do not make channels, trenches orholes in the cut stump and fill with dilution. Do not use undiluted product.

Chemical Thinning by Injection of Tree StemsRosate 36 may be used for chemical thinning by direct injection into tree stems of all coniferousand deciduous tree species.Make a notch cut with an axe in the tree stem and apply 2.0 ml of undiluted Rosate 36 into thenotch. For trees up to 10 cm in diameter, make one cut, in trees over 10 cm diameter, maketwo or three cuts. Do not apply to trees in the period of active sap flow in spring/early summer.

SPRAYER DECONTAMINATIONTrace amounts of Rosate 36 remaining in the sprayer after use can cause damage to othercrops subsequently treated with the same equipment. Immediately after use, thoroughly cleanthe sprayer and all equipment with a proprietary detergent cleaner.It is essential that all nozzles, filters, tubing, strainers, pumps and the spray tank are thoroughlycleaned after use to avoid the risk of damage to crops subsequently treated with the sameequipment.

COMPATIBILITYRosate 36 can be tank-mixed with a suitable authorised adjuvant and other products specifiedon the Albaugh Europe Sàrl approved compatibility list. An up-to-date copy can be obtainedfrom your distributor or directly from Albaugh Europe Sàrl (Tel: +44 (0) 20 3551 2580, email:[email protected]).

COMPANY ADVISORY INFORMATIONThis section is not part of the Product Label under the Control of Pesticides Regulations1986. It provides additional advice on product use at the discretion of the applicant.

TERMS AND CONDITIONS OF SUPPLY, SALE AND USEMany factors can affect or influence the activity of this product, including, but not limited to:weather and soil conditions, crop variety, treatment timing, water volume, application rates,spraying techniques, crop rotation, regional factors, and the occurrence and development ofstrains resistant to the active ingredient. Under certain circumstances, changes in activity or

crop damage can occur. The manufacturer or supplier is unable to accept any liability in thesecircumstances. All goods supplied by us are of a high grade and we believe them to be suitablefor the purpose for which we expressly supply them: but as we cannot exercise any controlover their mixing, use or application which may affect the performance of the goods all conditionsand warranties statutory or otherwise as to the quality or fitness for any purpose of our goodsare excluded and no responsibility will be accepted by us for any damage or injury whatsoeverarising from their storage, handling, application or use. These conditions cannot be varied byour staff, our agents or the re-sellers of the product whether or not they supervise or assist inthe use of such goods.

AlbEU-UK_Rosate 36 MAPP 14459_LB_5-20L_CR_MS_23-07-13


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Grassland Weed ControlThe following weeds are controlled at 3.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Annual meadow-grass Meadow FescueCommon chickweed Meadow FoxtailCommon mouse-ear Rough meadow-grassDock seedlings Speedwell sppItalian rye-grass Timothy grassMayweed speciesThe following weeds are controlled at 4.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Black bent Creeping soft-grassBroad-leaved dock Curled dockCock’s foot Perennial rye-grassCommon bent PlantainsCommon couch Soft bromeCreeping bent Yorkshire fogThe following weeds are controlled at 5.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Bracken (at full frond expansion) Red cloverCommon sorrel SedgesCommon nettle Sheep’s sorrelCreeping buttercup Soft rushCreeping thistle Spear thistleDaisy Tufted hair-grassDwarf thistle YarrowPerennial sow-thistleThe following weeds are controlled at 6.0 litres per ha under good growing conditions fromapplications made for grassland destruction: Common ragwort Nardus (Mat grass)Hard rush Red fescueHeath rush Sheep’s fescueJointed rush White clover *Molinia (Purple moor-grass) Yellow rattle*For best results against White clover, cut in June and spray 4 weeks later. Hard Surfaces, Natural Surfaces not intended to bear Vegetation, Permeable SurfacesOverlying SoilApply in 80 – 400 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the weed foliage is dense. Alternatively, apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns. Rosate 36 may beused for the control of unwanted vegetation in non-crop areas such as roadsides, paths, hardsurfaces and along fence lines, walls and similar situations in amenity and industrial areas.People, domestic pets and wildlife do not need to be excluded from the treated area. However,to avoid direct transfer of the wet spray onto desired vegetation, it is advisable not to walk inthe treated area until the spray is dry on the foliage. Apply this product carefully. Ensurespraying takes place only when weeds are actively growing (normally March to October) and isconfined only to visible weeds including those in the 30cm swath covering the kerb edge androad gulley – do not overspray drains. DO NOT USE IN OR ALONGSIDE HEDGEROWS.DO NOT USE UNDER GLASS OR POLYTHENE.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below. Weed Species/Situation Application rate – Litres product/hectare Annual weeds 1.5* Perennial grass and perennial broad-leaved weeds 5.0

*For application rates of Rosate 36 of 2.0 litres per ha or less, it is recommended in certain situationsto add a suitable authorised adjuvant. Do not use an adjuvant when applying through a rotaryatomiser sprayer.

Enclosed Waters, Land immediately adjacent to Aquatic Areas and Open WatersRosate 36 may be used for the control of dense infestations only of emerged and floatingweeds in enclosed waters, open waters and on land immediately adjacent to aquatic areas,e.g. reservoirs, irrigation ditches, water courses and waterways. Before use read the official code of practice “Guidelines for the Use of Herbicides on Weeds inor near Watercourses and Lakes” obtainable from: Department of the Environment and Rural Affairs (DEFRA publications, Tel: 08459 556000);Rural Affairs Department, Scottish Executive;Department of Agriculture and Rural Development for Northern Ireland;National Assembly for Wales Agriculture Department.The following legislation may apply to the use of Rosate 36 for the control of weeds in enclosedwaters, open waters and on land immediately adjacent to aquatic areas:Water Act 1989Water Resources Act 1991Control of Pollution Act 1974Northern Ireland Water Resources Act 1992Control of Pollution and Local Government (Northern Ireland) Order 1978Consult the appropriate water regulatory body (Environmental Protection Agency/ScottishEnvironmental Protection Agency) before using this product to control aquatic weeds. Themaximum concentration of glyphosate in the water must not exceed 0.2ppm or such lowerconcentration as the appropriate water regulatory body may require. Rosate 36 may be used iffish are present in the water provided it is used in strict accordance with theserecommendations.For the control of dense infestations of emerged reeds, soft-rush, bulrush, bent-grass,creeping-grass, canary-grass, sweet-grass, whorl-grass and water-cress, apply 5.0 litres perhectare in 250 litres of water per ha using a hydraulic nozzle sprayer or a hand-held sprayer.For most species, treat actively growing plants during August – September. Best resultsagainst water-cress are obtained from spraying in June. Treat bulrush in late July.For the control of dense infestations of floating white water-lily and yellow water-lily, apply 6.0litres per ha in 100 – 200 litres of water per ha using a hydraulic nozzle sprayer or a hand-heldsprayer. Treat actively growing floating weeds during July – August.For best results, use a boat-mounted or tractor-mounted sprayer with a maximum spray pressureof 2.0 bar.When using a boat-mounted sprayer, minimise the forward speed to as low as possible so asto cause minimum wake and disturbance of the floating weed foliage. Even under ideal applicationconditions, some leaves may be disturbed by the boat or wash prior to full absorption of thespray and require a further application 2 – 3 weeks later. In flowing water, make the applicationagainst the direction of the water current. When using a tractor-mounted sprayer do not exceeda forward speed of 8 kph.

OrchardsRosate 36 may be used on land that is to be planted to orchard (top fruit) or in establishedorchards.

Land to be planted to Orchard with Top Fruit TreesApply in 200 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the weed foliage is dense. Alternatively apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.

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ROSATE 36SAFETY DATA SHEET according to Regulation (EC) 453/2010

Version 1 UK Issue date: 07/05/20131. IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY1.1 Product identifierTrade nameRosate 361.2 Relevant identified uses of the mixture and uses advised against1.2.1 Relevant identified usesFor professional use only as anagricultural/horticultural/industrial/forestry/aquatic herbicide.1.2.2 Uses advised againstDo not use for any other purpose.1.3 Details of the supplier of the safety data sheetAlbaugh Europe SàrlWorld Trade Center Lausanne, Avenue Gratta-Paille, 21018 Lausanne, SwitzerlandTelephone: + 41 21 799 9130Fax: + 41 21 799 9139E-mail: [email protected]: www.albaugheurope.eu1.4 Emergency telephone numberFor advice on medical emergencies, fires or major spills: +44 (0) 1235239 670Available: 24hTime Zone: GMTLanguage(s) of phone service: All EU languages UK National Poisons Information Service: +44 (0)121 507 4123 (Forhealth professionals only)Available: 24hTime Zone: GMTLanguage(s) of phone service: English2. HAZARDS IDENTIFICATION2.1 Classification of the substance or mixtureClassification according to Regulation (EC) no. 1272/2008[CLP/GHS]This product has not yet been classified under Regulation (EC) no.1272/2008 [CLP/GHS]Classification according to Directive 67/548/EEC or 1999/45/ECN; R51/53: Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.Additional informationFor abbreviations, refer to Section 16.2.2 Label elementsLabelling according to Directive 67/548/EEC or 1999/45/ECHazard pictograms

DANGEROUS FOR THE ENVIRONMENTIndication of danger:Dangerous for the environmentRisk phrases:R51/53: Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.Safety advice:S2: Keep out of reach of children.S13: Keep away from food, drink and animal feeding stuffs.S20/21: When using do not eat, drink or smoke.S35: This material and its container must be disposed of in a safe way.

S57: Use appropriate containment to avoid environmentalcontamination.2.3 Other hazardsNone known3. COMPOSITION / INFORMATION ON INGREDIENTS3.1 SubstancesNot relevant3.2 MixturesDescription of the mixture:Mixture of glyphosate isopropylamine salt and co-formulants.• Chemical Name: N-(phosphonomethyl) glycine, compound with 2- propylamine (1:1) CAS-No.: 38641-94-0 EC-No.: 254-056-8 Index No. - Concentration (W/W): 41.5 % 67/548/EEC Classification: N; R51/53 CLP (Reg. 1272/2008) Classification: Hazardous to the aquatic environment, Chronic hazard, Cat2, H411• Chemical Name: Tallow alkylamine ethoxylate CAS-No.: 61791-26-2 EC-No.: - Index No. - Concentration (W/W): 15.5 % 67/548/EEC Classification: Xn; R22, R41, N; R50 CLP (Reg. 1272/2008) Classification: Acute Toxicity, oral, Cat4, H302 Serious Eye Damage, Cat1, H318, Hazardous to the aquatic environment, Acute hazard, Cat1, H400• Chemical Name: Other ingredients CAS-No.: - EC-No.: - Index No. - Concentration (W/W): to 100% 67/548/EEC Classification: Not classified CLP (Reg. 1272/2008) Classification: Not classifiedAdditional informationFor full text of R- and H-phrases, see Section 16.4. FIRST AID MEASURES4.1 Description of first aid measuresGeneral notes:If symptoms occur after exposure to this product, seek medicalattention immediately and show the product label or this SDS. Removeto fresh air and keep at rest. Do not allow smoking or eating. Take off allcontaminated clothing and footwear. Following inhalation:Remove to fresh air and keep at rest in half-upright position. Seekmedical attention immediately.Following skin contact:Remove all contaminated clothing. Wash skin with soap and rinse withplenty of water. Seek medical attention if irritation arises. Wash clothesbefore re-use.Following eye contact:Immediately rinse with water. Holding eyes open, continue rinsing for 15minutes at least. Remove contact lenses as soon as possible. Seekmedical attention immediately.Following ingestion:If swallowed, DO NOT INDUCE VOMITING: seek medical adviceimmediately and show this container or label. Remove any residuesfrom mouth and rinse it with plenty of water. Offer the casualty 1 or 2glasses of water to drink. Never give anything by mouth to anunconscious person.Self-protection of first aiderPersonal protective equipment for first aid responders is recommended

according to potential for exposure (refer to Section 8).Notes for the doctor:No specific antidote. Treat symptomatically (decontamination, vitalfunctions). Call a Poison Centre immediately for treatment advice. Incase of ingestion gastric lavage may be necessary (with proper laryngealcontrol). Before emptying the stomach, assess the potential dangerarising from lung aspiration against the product toxicity. Report toAlbaugh Europe Sàrl any unusual symptoms occurring after exposureby any route.4.2 Most important symptoms and effects, both acute and delayedFollowing inhalation:Possible slight nasal irritation and discharge. No delayed effectsexpected.Following skin contact:Possible slight transitory redness. No delayed effects expected.Following eye contact:Possible slight transitory redness and swelling. No delayed effectsexpected.Following ingestion:Possible mild gastrointestinal effects. No significant delayed effectsexpected.4.3 Indication of immediate medical attention and special treatmentneededNo need to provide any special means/medicinal products forimmediate treatment at the workplace, no specific antidote available.

5. FIRE FIGHTING MEASURES5.1 Extinguishing mediaSuitable extinguishing media:Carbon dioxide, water spray, alcohol-resistant foam, dry chemical forsmall fires, alcohol-resistant foam or water spray for large fires.Unsuitable extinguishing media:Solid water jet.5.2 Special hazards arising from the mixtureHazardous combustion productsEvolves toxic and corrosive fumes in fire including nitrogen oxides,carbon oxides and phosphorus oxides.5.3 Advice for fire-fightersClothing conforming to EN469 should be sufficient to deal with firesinvolving the mixture. However, a Self-Contained Breathing Apparatus(SCBA) may be required if there is a potential for exposure tocombustion fumes.5.4 Additional informationProvide storage and work areas with suitable fire extinguishers.Call the Fire Brigade at once to deal with all fires involving pesticidesunless the fire is small and immediately controllable. Spray unopenedcontainers with a mist spray to keep cool. If without risk, remove intactcontainers from exposure to fire. Contain fire-fighting water, bunding ifnecessary with sand or earth. Do not allow contamination of publicdrains or surface or ground waters. Dispose of fire debris andcontaminated water as advised in the MAFF/HSE “Pesticides: Code ofPractice for the Safe Use of Pesticides on Farms and Holdings”.

6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergencyprocedures6.1.1 For non-emergency personnelProtective equipment: Remove immediately any contaminated clothing.Wear prescribed personal protective equipment to prevent contact witheyes and skin. A Self-Contained Breathing Apparatus (SCBA) may berequired if there is an elevated risk for exposure.Emergency procedures: Call the emergency services if the release is notimmediately controllable. If the release is localized and immediately


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Combining Pea, Field BeansApply when the moisture of the grains (crop seeds) is below 30% and at least 7 days beforeharvest. Make an accurate measurement of seed moisture prior to application. Observe thelatest time of application of 7 days before harvest.DO NOT TREAT CROPS GROWN FOR SEED.Apply using a high-clearance tractor fitted with narrow wheels and crop dividers to minimisecrop damage.Not for use as a crop desiccant treatment.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy is dense. Alternatively apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns. Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.




LinseedApply when the moisture of the grains (crop seeds) is below 30% and at least 14 days beforeharvest. Make an accurate measurement of seed moisture prior to application. The seed podswill usually be brown, the seeds light brown, and the plant leaves and stems yellow-green togreen in colour.An interval of up to 4 weeks may be required before the crop can be harvested by direct combining.Weeds may not be susceptible from applications made in the autumn – see “Weed Control”.DO NOT TREAT CROPS GROWN FOR SEED.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy is dense. Do not apply with a rotary atomiser sprayer.Select the correct application rate according to the weed species to be treated, weed population or situation as in the table below.




Perennial broad-leaved weeds and other perennial grasses 4.0

Crop destruction before direct combine harvesting 3.0 (harvest management aid)

Treatment of Stubbles of all Crops or Cultivated Land prior to Sowing or Planting anyCrop except Orchards (see Separate Section “Orchards”)Control of Common Couch, other Perennial Grasses and Volunteer Potatoes (Autumn) inStubbles of all CropsRosate 36 can be applied to the stubbles of all crops in the autumn or spring for the control ofCommon Couch, other perennial grasses and volunteer potatoes, prior to cultivation and sowingor planting of any crop.The ground must not be cultivated prior to application. Leave an interval of at least 5 days before and after application. Volunteer potatoes (autumn application only) must have a significant amount of top growth atapplication.For spring applications allow a minimum of 21 days of weed growth prior to application. Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a higher

volume within this range where the crop canopy is dense. Alternatively, apply in a minimum of40 litres of water per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrumis in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed population or situation as in the table below.



Common couch – over 75 shoots/m2

Other perennial grasses 4.0 Volunteer potatoes – autumn treatment only

Control of Volunteer Cereals, Annual Grasses and Annual Broad-leaved Weeds in Stubblesof all Crops or on already Cultivated Land prior to Sowing or Planting any Crop. Rosate 36 can be applied to the stubbles of all crops prior to cultivation or to already cultivatedland in the autumn or spring for the control of Volunteer cereals, annual grasses and annualbroad-leaved weeds prior to cultivation and sowing or planting of any crop.Land may be cultivated after an interval of at least 24 hours has elapsed after application.Land can be direct drilled after an interval of at least 2 days has elapsed after application.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a higher volumewithin this range where the crop canopy is dense. Alternatively, apply in a minimum of 40 litres ofwater per ha using a rotary atomiser sprayer ensuring that the spray droplet spectrum is in therange of a Volume Median Diameter (VMD) of 200 – 300 microns.Apply Rosate 36 at 1.5 litres per ha and for best results add a suitable authorised adjuvant. Donot use an adjuvant when applying through a rotary atomiser sprayer.

Destruction of Established Grassland with Weed Control prior to Re-seeding, Planting orSowingRosate 36 can be used for the destruction of established grassland and weeds present in thesward prior to re-seeding, planting or sowing new grassland or any other crop. Apply to grass re-growth after grazing or cutting. Alternatively, apply before grazing or cuttingbetween June – October to grassland 30 – 60 cm high that is not dense and before maturityof grass seeds.Grassland crops can be used in the normal manner after 5 days have elapsed after application,including grazing by or feeding to cattle, dairy cows or sheep. THE FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVEDOR BURIED PRIOR TO GRAZING OR CUTTING FOR FEED.Following removal of the grass crop, normal cultivations may be carried out in preparation forplanting or sowing the following crop.DO NOT APPLY any fertiliser or lime application prior to application of Rosate 36.Apply in 150 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the grass canopy or weed foliage is dense.Do not apply with a rotary atomiser sprayer.Select the correct application rate according to the grassland situation to be treated as in thetable below and according to the rate required for the control of the least susceptible weedspecies present in the sward – see “Grassland Weed Control” below.


Short rotation Rye-grass containing annual weeds 3.0

Grass leys 2-4 years old containing perennial grass weeds 4.0

Longer term grass leys 4-7 years old containing 5.0 perennial broad-leaved weeds

Permanent pasture 6.0

controllable, provide sufficient ventilation and control the release at itssource.6.1.2 For emergency respondersClothing conforming to EN469.6.2 Environmental precautionsUse appropriate containment to avoid environmental contamination.Control the release at its source. Contain the spill to prevent it fromspreading, contaminating soil or entering sewage and drainage systemsor any body of water. Inform the local water company if the releaseenters drains and the Environment Agency (England and Wales), theScottish Environmental Protection Agency (Scotland) or the Environmentand Heritage Service (Northern Ireland) if it enters surface or groundwaters. 6.3 Methods and material for containment and cleaning upFor containmentClean up spills immediately and place in a compatible disposalcontainer. Contain spill by diking with earth, sand or absorbent materialand place into a compatible marked disposal container.For cleaning upScrub area with a hard water detergent. Soak up wash liquid withadditional absorbent material and place into a compatible markeddisposal container. Seal container and arrange for disposal.Other information: Not Applicable6.4 Reference to other sectionsRefer to Section 8 for personal protective equipment and to Section 13for disposal instructions.

7. HANDLING AND STORAGE7.1 Precautions for safe handlingObtain special instructions before use. Do not handle until all safetyprecautions have been read and understood. Provide suitable ventilationin the areas where the product is stored and used. Contaminated workclothing should not be allowed out of the workplace. Avoid all contactby mouth, with eyes and skin. Wear personal protective equipment asspecified in Section 8. When using, do not eat, drink or smoke. Removecontaminated clothing and protective equipment before meals and afterwork. Wash hands and exposed skin before meals and after work. Washall protective clothing thoroughly after use, especially the insides of gloves.7.2 Conditions for safe storage, including any incompatibilitiesThe mixture is stable under normal ambient conditions. Keep in originalcontainer, in a dry, cool and safe place. Store in a locked, suitable store.Keep away from any source of ignition. Keep out of the reach of childrenand unauthorised personnel. Keep away from food, drink and animalfeeding stuffs. 7.3 Specific end use(s)Herbicide for professional use as directed by the product label, everyother use is hazardous.

8. EXPOSURE CONTROL/PERSONAL PROTECTION8.1 Control ParametersOccupational Exposure limit valuesNo occupational Exposure limit values have been set for the mixture orits components.Information on monitoring procedures: None available.8.2 Exposure controls8.2.1 Appropriate engineering controlsEngineering controls and appropriate work processes must be used toeliminate or reduce worker and environmental exposure in the areaswhere the substance is handled, transported, loaded, unloaded, storedand used. These measures must be adequate for the extent of theactual risk. Provide adequate local exhaust ventilation. Use specializedtransfer systems if available.

8.2.2 Personal protection equipmentEye and face protectionAvoid contact with eyes. If there is a significant potential for contact,wear suitable eye and face protection (EN 166).Skin protection:Hand protection: Wear suitable protective gloves against chemicals (EN374 part 1, 2, 3). Nitrile rubber min. 0.5mm thick and 300mm long glovesare the ones proven to be the most suitable according to tests onpesticide products. Wash the gloves thoroughly after each use,especially the insides. Replace gloves if damaged and before exceedingthe breakthrough time.Body protection: Avoid contact with skin. If there is a significantpotential for contact, wear suitable coveralls (ISO 13982-1, Type 5, EN13034, Type 6).Other skin protection: None specified.Respiratory protection: No special requirement when used asrecommended. If a risk assessment shows that engineering controls donot provide adequate respiratory protection to exposure to sprayparticles, wear particle filtering half mask (EN 149) or half maskconnected to particle filter (EN 140 + 143).8.2.3 Environmental exposure controlsImplement all applicable local and community environmental protectionlegislation. Refer to Section 15. Use appropriate containment to avoidenvironmental contamination. Do not empty into drains. Do notcontaminate water with the product or used container. Do not cleanapplication equipment near surface water. Avoid contamination viadrains from farmyards and roads. Refer to Section 12 and 13.

9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesa) Appearance: Liquid

Colour: Amberb) Odour: Faint aminec) Odour threshold: Not determined – not required under all

applicable pesticide legislation.d) pH: 5.07 undiluted formulation

4.7 (1% dilution in water)e) Melting point/

freezing point: Not applicable – the mixture is a liquid at ambient temperature and must be protected from frost

f) Initial boiling point and boiling range: Approximately 100 °C

g) Flash point: None – the mixture is water-basedh) Evaporation rate: Not available - not required under all

applicable pesticide legislation.i) Flammability (solid, gas): Not applicable (liquid)j) Upper/lower flammability

or explosive limits: Not applicable – the mixture is water-based

k) Vapour pressure: No significant volatility – the mixture is water-based

l) Vapour density: Not applicable - not required under all applicable pesticide legislation.

m) Density: 1.175 g/cm3 at 20°Cn) Solubility(ies)

Solubility (water): Completely soluble in watero) Partition coefficient: n-octanol/water:

Glifosate, acido: Log Po/w<-3,2 (25 °C, pH valore: 5-9)p) Auto-ignition temperature: >400 °C

Minimum Ignition Temperature: Not available

Minimum Ignition Energy: Not availableq) Decomposition temperature: Glyphosate acid: 199.1 °Cr) Viscosity: 67.6 mPa.s at 20°C, 27.3 mPa.s at 40°Cs) Explosive properties: Explosion hazard: not explosive.t) Oxidising properties: Not an oxidising agent.9.2 Other informationSurface tension: 36.8 mNmFlammability (in contact with water): Not flammable

10. STABILITY AND REACTIVITY10.1 ReactivityNon-reactive when stored in original container under normal conditionsof storage and use. 10.2 Chemical stabilityStable when stored in original container under normal conditions ofstorage and use.10.3 Possibility of hazardous reactionsNo hazardous reactions when stored in original container under normalconditions of storage and use. Reacts with strong bases and strongoxidising substances, galvanised steel and unlined mild steel with therelease of hydrogen, a highly flammable gas that may explode. 10.4 Conditions to avoidContact with galvanised steel and unlined mild steel, strong bases andstrong oxidising substances. Do not store in proximity of sources ofignition and direct sunlight.10.5 Incompatible materialsGalvanised steel and unlined mild steel. Avoid contact with strong basesand strong oxidising substances.10.6 Hazardous decomposition productsDuring decomposition evolves toxic fumes including nitrogen oxides,carbon oxides and phosphorus oxides.

11. TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects11.1.1 Substances: Non applicabile.11.1.2 MixturesAll the data contained in this section are derived from actual test data onthe mixture unless otherwise stated.

a) Acute toxicity:LD50 oral, rat: >5000 mg/kg bwLD50 dermal, rabbit: >5000 mg/kg bwLC50 inhalation, rat: >5.12 mg/l

b) Irritation:Skin: Slight irritant (not classified as a skin irritant under Directive 1999/45/EC)Eye: Mild eye irritant (not classified as an eye irritant under Directive 1999/45/EC)

c) Corrosivity: Not classified as corrosive on the basis of skin and eye irritation studies

d) Sensitisation: The product is not classified as a respiratory or skin sensitizer in animal studies

e) Repeated dose toxicity: Not classified as hazardous for repeated dose toxicity on the basis of mixture component information

f) Carcinogenicity: Not classified as carcinogenic on the basis of mixture component information

g) Mutagenicity: Not classified as mutagenic on the basis of mixture component information

h) Toxicity for reproduction: Not classified as a reproductive toxicant on the basis of mixture component information

10


4

Rotary Atomiser SprayersApply through a rotary atomizer sprayer using a minimum water volume of 40 litres per ha and aspray droplet spectrum of a minimum Volume Median Diameter (VMD) of 200 microns and up to300 microns. This corresponds to a MEDIUM or COARSE spray (BCPC). The tractor forwardspeed will typically be in the range of 4 – 9 kph but it must be calibrated in the field to apply thecorrect spray volume. Use a spray bout marker to avoid overlapping spray bouts.Do not tank-mix Rosate 36 with any adjuvant when applying through Rotary Atomiser Sprayers.

Hand-held WeedwipersFor use only in orchards and non-crop situations. Use a concentration of 1 part of Rosate 36to 2 parts of water. Do not exceed this maximum concentration and add a dye (water-based) ifnecessary.

Tractor-mounted WeedwipersTractor-mounted weedwipers may be used in grassland and arable crops for the control ofWeed beet, Sugar beet bolters and other tall weeds growing above the crop. DO NOT USE WEEDWIPERS IN SOFT FRUIT CROPS.WEEDS THAT ARE NOT ACTIVELY GROWING WILL NOT BE CONTROLLED.KEEP STOCK OUT of treated areas for 7 days.THE FOLIAGE OF ANY POISONOUS WEEDS (SUCH AS RAGWORT) MUST BE REMOVEDOR BURIED PRIOR TO GRAZING OR CUTTING FOR FEED. To ensure that application does not result in crop damage, the weeds should always be atleast 10 cm taller than the crop vegetation and a distance of 5 cm must be maintained betweenthe top of the crop vegetation and the wiper. The optimum weed height for treatment is 10 cmabove the height of the crop vegetation. If the weed vegetation is dense, it will be necessary to make two passes of the wiper fromopposite directions of the tractor travel. Weeds growing from below the wiped area will needsubsequent applications.To minimize weed seed return to the soil, application should be made prior to weed seedmaturity. For sugar beet bolters, apply a programme of three applications with an interval oftwo weeks between applications starting in early July to early August.Use a concentration of 1 part of Rosate 36 to 1 part of water. Do not exceed this maximumconcentration. Under very hot or dry conditions it may be necessary to reduce the concentrationto 1 part of Rosate 36 to 2 parts of water. For best results, ensure that the wiping surface isimpregnated with the herbicide solution at all times but does not drip. Clean the wiping ropesas required during the working day to ensure that flow rate to the wiping surface is maintainedat full rate at all times. The maximum recommended forward speed is 5 kph or less.

CROP RECOMMENDATIONSPre-harvest Treatment in Arable CropsRosate 36 can be applied as a pre-harvest treatment for the control of weeds in certainrecommended arable crops prior to harvest for the control of a range of perennial and annualgrass and broad-leaved weeds. DO NOT TREAT CROPS GROWN FOR SEED.Consult the processor before use on any crop intended for processing.

Wheat (including Durum Wheat), Barley and OatsApply when the moisture of the youngest grains in the ear is below 30% and not less than 7days before harvest. Make an accurate measurement of seed moisture immediately prior toapplication.DO NOT TREAT CROPS GROWN FOR SEED.To minimise crop damage, apply using a high-clearance tractor fitted with narrow wheels andcrop dividers.Do not use straw from a treated crop as a horticultural mulch. Straw from a treated crop maybe used for any other purpose.After harvest, straw may be chopped, incorporated or removed according to normal practiceand the land can be cultivated normally after harvest and straw disposal.For best results if dull weather conditions occur after application, allow up to 14 days betweenapplication and harvest.

Certain broad-leaved weeds (Annual nettle, Rosebay willow-herb, Redshank, Pale persicaria andKnotgrass) are not susceptible at rates of 1.5 l/ha or less. For application rates of Rosate 36 of2.0 litres per ha or less, in certain situations it is recommended to add a suitable authorised adjuvant.Do not use an adjuvant when applying through a rotary atomiser sprayer.Apply in 80 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy and/or weed foliage is dense. Alternativelyapply in a minimum of 40 litres of water per ha using a rotary atomiser sprayer ensuring thatthe spray droplet spectrum is in the range of a Volume Median Diameter (VMD) of 200 – 300 microns.Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.


Common couch – up to 25 shoots/m2 2.0*

Common couch 25 – 75 shoots/m2 3.0

Common couch – over 75 shoots/m2 in direct drilled crops 4.0 Perennial broad-leaved weeds and other perennial grasses

Annual grasses, cereal stems, cereal leaves plus reduction 1.0* of green material in the crop (harvest management aid)

Annual broad-leaved weeds plus reduction of green 1.5* material in the crop (harvest management aid)

*For application rates of Rosate 36 of 2.0 litres per ha or less, it is recommended in certainsituations to add a suitable authorised adjuvant. Do not use an adjuvant when applyingthrough a rotary atomiser sprayer.

Oilseed Rape and MustardApply when the moisture of the grains (crop seeds) is below 30% and at the timing as indicatedbelow. Make an accurate measurement of seed moisture immediately prior to application.Oilseed Rape: 14 – 21 days before harvest. Observe the latest time of application of 14 days before harvest.Mustard: 8 – 10 days before harvest. Observe the latest time of application of 8 days before harvest.DO NOT TREAT CROPS GROWN FOR SEED.To minimise crop damage, apply using a high-clearance tractor fitted with narrow wheels andcrop dividers. After harvest, straw may be chopped, incorporated or removed according to normal practiceand the land can be cultivated normally after harvest and straw disposal.Uneven crop maturity may occur from applications made to crops under stress due to drought,disease or excessive heat.Do not treat patches or areas of the crop that are late maturing due to any cause (e.g.,waterlogging or pigeon damage).Do not treat crops that have a significant number of secondary re-growth shoots.Apply in 100 – 250 litres of water per ha by means of a hydraulic nozzle sprayer – use a highervolume within this range where the crop canopy and/or weed foliage is dense. Do not apply with a rotary atomiser sprayer. Select the correct application rate according to the weed species to be treated, weed populationor situation as in the table below.


Common couch – up to 75 shoots/m2

Annual weeds 3.0 Crop destruction before direct combine harvesting (harvest management aid)


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Likely routes of exposure and related long and short termsymptoms and health effects:Inhalation: There is a low risk of exposure by inhalation. Short-term symptoms and effects:Possible slight nasal irritation and discharge.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Eye contact: There is a risk of exposure by eye contact.Short-term symptoms and effects:Possible slight transitory redness and swelling.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Skin contact: There is a risk of exposure by skin contact.Short-term symptoms and effects:Possible slight transitory redness.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.Ingestion: There is a very low risk of accidental exposure by ingestion.Short-term symptoms and effects:Possible mild gastrointestinal effects.Long-term symptoms and effects:No evidence of long-term effects after prolonged or repeated exposure.

12. ECOLOGICAL INFORMATIONAll the information and data contained in this section are derived fromdata on similar mixtures.12.1 ToxicityAcute ToxicityLC50 fish, Oncorhynchus mykiss (96h): 8.2 mg/lEC50 aquatic inverterbrates, Daphnia magna (48h): 11.0 mg/lErC50 algae, Selenastrum capricornutum (72h): 8.0 mg/lLD50 birds, Mallard duck: >5620 mg/kgHoney bees:LD50 oral, Apis mellifera (48h): >395 µg/beeLD50 contact, Apis mellifera (48h): >338 µg/bee12.2 Persistence and degradability: Not readily biodegradable12.3 Bioaccumulative potential: No significant potential forbioaccumulation12.4 Mobility in soil: Not readily mobile, binds strongly to soil12.5 Results of PBT and vPvB assessment: No PBT or vPvBassessments have been carried out on the mixture; please refer to 12.1,12.2 & 12.3.12.6 Other adverse effects: Not determined.12.7 Additional Information: None.13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methodsDisposal of waste product, contaminated packaging materials and anyexcess diluted spray should be in accordance with ‘The HazardousWaste (England and Wales) Regulations 2005’ and any other applicablelocal or national legislation (for guidance refer to the MAFF/HSE“Pesticides: Code of Practice for the Safe Use of Pesticides on Farmsand Holdings”). For the handling and management of accidental release,follow the information given under Section 6 and 7.14. TRANSPORT INFORMATION14.1 UN number: UN 308214.2 UN Proper shipping name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains N-(phosphonomethyl)glycine, compound with 2-propylamine(1:1) and tallow alkylamine ethoxylate)

14.3 Transport hazard class(es): 914.4 Packing group: III14.5 Environmental hazards:Land transport ADR/RID - Environmentally Hazardous: YesMaritime transport IMDG - Marine pollutant: Yes14.6 Special Precautions for User:Land transport ADR/RID - Tunnel restriction code: E14.7 Transport in bulk according to Annex II of MARPOL 73/78 andthe IBC Code: IBC Code: IBC0315. REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislationspecific for the substance or mixture:EU RegulationsREGULATION (EC) No 1107/2009 of The European Parliament and ofthe Council of 21 October 2009 concerning the placing of plantprotection products on the market and repealing Council Directives79/117/EEC and 91/414/EEC. Council Directive 67/548/EEC of 27 June1967 on the approximation of laws, regulations and administrativeprovisions relating to the classification, packaging and labelling ofdangerous substances.DIRECTIVE 1999/45/EC of the European Parliament and of the Councilof 31 May 1999 concerning the approximation of the laws, regulationsand administrative provisions of the Member States relating to theclassification, packaging and labelling of dangerous preparations.REGULATION (EC) No 1272/2008 of the European Parliament and of theCouncil of 16 December 2008 on classification, labelling and packagingof substances and mixtures, amending and repealing Directives67/548/EEC and 1999/45/EC, and amending Regulation (EC) No1907/2006.REGULATION (EC) No 1907/2006 of the European Parliament and of theCouncil of 18 December 2006 concerning the Registration, Evaluation,Authorisation and Restriction of Chemicals (REACH), establishing aEuropean Chemicals Agency, amending Directive 1999/45/EC andrepealing Council Regulation (EEC) No 793/93 and CommissionRegulation (EC) No 1488/94 as well as Council Directive 76/769/EECand Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and2000/21/EC, including amendments.COMMISSION REGULATION (EU) No 453/2010 of 20 May 2010amending Regulation (EC) No 1907/2006 of the European Parliamentand of the Council on the Registration, Evaluation, Authorisation andRestriction of Chemicals (REACH)National Regulations/legislation:The Chemicals (Hazard Information & Packaging for Supply) Regulations2009 (CHIP 4). Health and Safety at Work etc. Act 1974, as amended,the Control of Substances Hazardous to Health Regulations 1999(COSHH), as amended.15.2 Chemical Safety AssessmentNo Chemical Safety Assessment under Regulation (EC) 1907/2006 isrequired and has not been carried out.

16. OTHER INFORMATIONa) Indication of changes:The numbering system identifying new versions and/or revisions of thisSDS is incremental. An increment by an integer number identifies theissue of a new version requiring provision of updates according toArticle 31(9) of REACH, while an increment by a decimal identifies minorchanges such as typographical errors, text improvements and/orformatting. Revisions indicated by a decimal point do not affect the riskmanagement measures or information on hazards, do not refer torestrictions imposed and/or to authorisations granted or refused.The paragraphs where changes have been made are indicated by thesymbol ‘!’ in the margin.

b) Abbreviations and acronyms:N: Dangerous for the environment.Xn: Harmful.c) Key literature references and sources for data:Albaugh Europe SàrlECHA Guidance on the compilation of safety data sheets (Version 1.1,December 2011)d) Classification and procedure used to derive the classification formixtures according to Regulation (EC) 1272/2008 [CLP]Not Applicablee) Relevant R-phrases, H-statements and precautionary statementsnot written out in full under Sections 2 to 15:R22 Harmful if swallowed.R41 Risk of serious damage to eyes.R50 Very toxic to aquatic organisms.R51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.

H302 Harmful if swallowedH318 Causes serious eye damageH400 Very toxic to aquatic lifeH411 Toxic to aquatic life with long lasting effectsf) Training advice:General occupational hygiene training recommended.g) Further information:The information and recommendations in this publication are, to thebest of our knowledge, information and belief, accurate at the date ofpublication. Nothing herein is to be construed as a warranty, expressedor implied. In all cases it is the responsibility of the user to determine theapplicability of such information or the suitability of any products fortheir own particular purpose.

This Material Safety Data Sheet was compiled by Albaugh Europe Sàrl([email protected]) in compliance with Regulation (EC)1907/2006 as amended by 453/2010.


Boston Seeds - TOXIC TO AQUATIC ORGANISMS, …sowing/pla ntin g) Grassland 6.0 6.0 per year 5 days...

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Transcript of Boston Seeds - TOXIC TO AQUATIC ORGANISMS, …sowing/pla ntin g) Grassland 6.0 6.0 per year 5 days...