bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing...

21

Transcript of bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing...

Page 1: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.
Page 2: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.
Page 3: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.
Page 4: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.
Page 5: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

1 / 2 Project: 649 - MEW, 2016 July (2016/K/05523)

Summary no.: 345927/1; 05.08.2016.

Certificate validity check

SUMMARY

Customer: BIOKÖR Technológiai és Környezetvédelmi Kft.

1089 Budapest, Bláthy Ottó utca 41.

Project: 649 - MEW, 2016 July (2016/K/05523)

Summary no.: 345927/1

Beginning of analysis: 29.07.2016. End of analysis: 05.08.2016.

In the case of samples not taken by the laboratory, results refer only to the samples delivered to the laboratory.

The report shall not be reproduced except in full without the written approval of WESSLING Hungary Ltd.

Page 6: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

2 / 2 Project: 649 - MEW, 2016 July (2016/K/05523)

Summary no.: 345927/1; 05.08.2016.

Determination of Tributyltin*

Sample type: Surface water EN ISO 17353

Sample ID Tributyltin

µg/L

QL

µg/L

MS004 <0.00005 0.00005

MS006 0.00031±0.00003 0.00005

MS010 <0.00005 0.00005

MS011 <0.00005 0.00005

MS012 <0.00005 0.00005

* The test was performed by the organization recognized by DAkkS under registration no. D-PL-14162-01-00 WESSLING GmbH Oppin. 05.08.2016.

This test report was generated from a validated system and is valid without a signature.

Filep Zoltán Laboratóriumvezető

Page 7: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

1 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Certificate validity check

INVESTIGATION REPORT

Customer: BIOKÖR Technológiai és Környezetvédelmi Kft.

1089 Budapest, Bláthy Ottó utca 41.

Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1 Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015.

Beginning of analysis: 29.07.2016. End of analysis: 31.08.2016.

In the case of samples not taken by the laboratory, results refer only to the samples delivered to the laboratory.

The report shall not be reproduced except in full without the written approval of WESSLING Hungary Ltd.

Page 8: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

2 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

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Page 9: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

3 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Co

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006

Page 10: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

4 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Co

mm

ent

Sam

plin

g o

rgan

izat

ion

Inst

itute

of O

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y, B

ulga

rian

Aca

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Inst

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Inst

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Acc

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Acc

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Acc

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Acc

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Coo

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Coo

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Con

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Coo

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Con

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Typ

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1 l a

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Qu

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1000

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1000

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40 c

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1000

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1000

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1000

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1000

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1000

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1000

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1000

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3

1000

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50 c

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1000

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3

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Sam

ple

cod

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0002

0738

49

0002

0738

51

0002

0738

52

0002

1076

87

0002

6631

24

0001

6697

35

0002

0738

97

0002

0738

98

0002

0738

99

0002

0739

00

0002

0739

01

0002

1106

91

0002

6631

25

0001

6698

24

0002

0739

10

0002

0739

11

0002

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12

0002

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13

0002

1077

09

0002

6631

26

0001

6698

06

Sam

ple

typ

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Sur

face

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Sur

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Sur

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Sur

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Sur

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Sur

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Dat

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18/0

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MS

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007

MS

007

MS

007

MS

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MS

008

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MS

008

MS

008

MS

008

MS

008

MS

009

Page 11: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

5 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Co

mm

ent

Sam

plin

g o

rgan

izat

ion

Inst

itute

of O

cean

olog

y, B

ulga

rian

Aca

dem

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Acc

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Acc

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Acc

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Typ

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A v

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40 c

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1000

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1000

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1000

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1000

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0002

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0002

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61

0002

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62

0002

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63

0002

0739

65

0002

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66

0002

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0002

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0001

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0002

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0002

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0002

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0002

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0002

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53

0002

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0002

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0002

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0002

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0002

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0002

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Sam

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MS

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MS

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MS

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Page 12: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

6 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Co

mm

ent

Sam

plin

g o

rgan

izat

ion

Inst

itute

of O

cean

olog

y, B

ulga

rian

Aca

dem

y of

Sci

ence

s (I

O-B

AS

)

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of O

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Page 13: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

7 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Co

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Page 14: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

8 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of TOC Sample type: Surface water

(1) MSZ EN 1484:1998

Sample ID TOC 1

mg/dm3

MS001 <1

MS002 3 ± 0.3

MS003 3 ± 0.3

MS004 2 ± 0.2

MS005 2 ± 0.2

MS006 3 ± 0.3

MS007 1 ± 0.1

MS008 1 ± 0.1

MS009 1 ± 0.1

MS010 2 ± 0.2

MS011 <1

MS012 2 ± 0.2

MS013 <1

MS102 <1

MS104 <1

MS105 1 ± 0.1

MS110 2 ± 0.2

MS111 3 ± 0.3

MSRev1 2 ± 0.2

MSRev2 3 ± 0.3

MSRev3 2 ± 0.2

MSRev4 4 ± 0.4

MSRev5 <1

MSRev6 1 ± 0.1

MSRev7 2 ± 0.2

Instruments: Shimadzu TOC-L TNM-L CSN; UV/VIS Evolution300

Determination of hexavalent chromium Sample type: Surface water

(1) MSZ EN ISO 18412:2007 (2) MSZ ISO 11083:2003

Component Unit Sample ID

MS004

Chromium(VI) 1, 2 g/dm3 <0.5

Instruments: HP-6890-GCMS_03-5973

Page 15: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

9 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of dissolved element content (1/2) Sample type: Surface water

(1) MSZ EN ISO 17294-2:2005 (2) EPA Method 200.8:1999

Component Unit Sample ID

MS001 MS002 MS003 MS004

Aluminium (dissolved) 1 g/dm3 <3 <3 <3 <3 Arsenic (dissolved) 1 g/dm3 <3 <3 <3 <3 Cadmium (dissolved) 1 g/dm3 <0.06 <0.06 <0.06 <0.06

Cobalt (dissolved) 1 g/dm3 <1 <1 <1 <1

Copper (dissolved) 1 g/dm3 <1 <1 <1 <1

Chromium (dissolved) 1 g/dm3 - - - 0.45 ± 0.02

Mercury (dissolved) 2 g/dm3 0.027 ±0.003 0.029 ±0.003 0.026 ±0.003 <0.015

Lithium (dissolved) 1 g/dm3 51 ± 0.5 57 ± 0.6 56.0 ± 0.5 49 ± 0.5

Nickel (dissolved) 1 g/dm3 <1 <1 <1 <1

Lead (dissolved) 1 g/dm3 <0.3 <0.3 <0.3 <0.3

Zinc (dissolved) 1 g/dm3 <12 <12 <12 <12

Component Unit Sample ID

MS006 MS007 MS008 MS010

Aluminium (dissolved) 1 g/dm3 <3 <3 <3 <3 Arsenic (dissolved) 1 g/dm3 <3 <3 <3 <3 Cadmium (dissolved) 1 g/dm3 <0.06 <0.06 <0.06 <0.06

Cobalt (dissolved) 1 g/dm3 <1 <1 <1 <1

Copper (dissolved) 1 g/dm3 <1 <1 <1 <1

Mercury (dissolved) 2 g/dm3 0.030 ±0.003 <0.015 <0.015 <0.015

Lithium (dissolved) 1 g/dm3 52.5 ± 0.5 46.8 ± 0.5 49.3 ± 0.5 44.2 ± 0.4

Nickel (dissolved) 1 g/dm3 <1 <1 <1 <1

Lead (dissolved) 1 g/dm3 <0.3 <0.3 <0.3 <0.3

Zinc (dissolved) 1 g/dm3 <12 <12 <12 <12

Component Unit Sample ID Quantitation limit

µg/dm3 MS011 MS012 MS013 MS102

Aluminium (dissolved) 1 g/dm3 <3 <3 <3 - 3

Arsenic (dissolved) 1 g/dm3 <3 <3 <3 - 3

Cadmium (dissolved) 1 g/dm3 <0.06 <0.06 <0.06 0.08 ±0.01 0.06

Cobalt (dissolved) 1 g/dm3 <1 <1 <1 - 1

Copper (dissolved) 1 g/dm3 <1 <1 <1 - 1

Mercury (dissolved) 2 g/dm3 <0.015 <0.015 <0.015 - 0.015

Lithium (dissolved) 1 g/dm3 43.3 ± 0.2 50.9 ± 0.5 52.0 ± 0.4 - 5

Nickel (dissolved) 1 g/dm3 <2.5 <2.5 <2.5 - 2.5

Lead (dissolved) 1 g/dm3 <0.3 <0.3 <0.3 - 0.3

Zinc (dissolved) 1 g/dm3 <12 <12 <12 - 12

Instruments: PE FIMS-400 Hg-AAS 02

Page 16: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

10 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of dissolved element content (2/2) Sample type: Surface water

(1) MSZ EN ISO 17294-2:2005

Component Unit Sample ID

MS104 MS105 MS109 MS110

Cadmium (dissolved 1 g/dm3 <0.06 <0.06 <0.06 <0.06

Nickel (dissolved) 1 g/dm3 - - - <2.5

Component Unit Sample ID Quantitation limit

µg/dm3 MS111 MS112

Cadmium (dissolved) 1 g/dm3 0.17 ± 0.03 <0.06 0.06

Nickel (dissolved) 1 g/dm3 - <2.5 2.5

Instruments: PE FIMS-400 Hg-AAS 02

Determination of polychlorinated biphenyls (PCB) (1/2) Sample type: Surface water

(1) MSZ 1484-11:2003

Component Unit Sample ID

MS001 MS002 MS003 MS004

PCB 28 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 52 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 101 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 118 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 153 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 138 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 180 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

Sum of PCB (7) (a) 1 g/dm3 - - - -

Component Unit Sample ID

MS006 MS007 MS010 MS011

PCB 28 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 52 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 101 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 118 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 153 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 138 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

PCB 180 1 g/dm3 <0.0001 <0.0001 <0.0001 <0.0001

Sum of PCB (7) (a) 1 g/dm3 - - - -

(a) Mathematical sum of individual components. Instruments: HP-6890-GCMS_03-5973

Page 17: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

11 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of polychlorinated biphenyls (PCB) (2/2) Sample type: Surface water

(1) MSZ 1484-11:2003

Component Unit Sample ID

MS012 MS013

PCB 28 1 g/dm3 <0.0001 <0.0001

PCB 52 1 g/dm3 <0.0001 <0.0001

PCB 101 1 g/dm3 <0.0001 <0.0001

PCB 118 1 g/dm3 <0.0001 <0.0001

PCB 153 1 g/dm3 <0.0001 <0.0001

PCB 138 1 g/dm3 <0.0001 <0.0001

PCB 180 1 g/dm3 <0.0001 <0.0001

Sum of PCB (7) (a) 1 g/dm3 - -

(a) Mathematical sum of individual components. Instruments: HP-6890-GCMS_03-5973

Determination of Octyl-phenols Sample type: Surface water

(1) MSZ EN ISO 18857-1:2007

Sample ID

4-(1,1,3,3-Tetrametilbutil)-phenol 1

g/dm3

4-Octylphenol 1

g/dm3

MS001 <0.003 <0.003

MS002 <0.003 <0.003

MS003 <0.003 <0.003

MS004 <0.003 <0.003

MS006 <0.003 <0.003

MS007 <0.003 <0.003

MS008 <0.003 <0.003

MS010 <0.003 <0.003

MS011 <0.003 <0.003

MS012 <0.003 <0.003

MS013 <0.003 <0.003

Instruments: HP-7890B-GCMS_15-5973

Page 18: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

12 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of Hexachlorobenzene Sample type: Surface water

(1) MSZ 1484-8:2004

Sample ID Hexachlorobenzene 1

g/dm3

MS001 <0.01

MS002 <0.01

MS003 <0.01

MS004 <0.01

MS006 <0.01

MS007 <0.01

MS008 <0.01

MS010 <0.01

MS011 <0.01

MS012 <0.01

MS013 <0.01

Instruments: HP-6890-GCMS_03-5973

Determination of Pentachlorobenzene Sample type: Surface water

(1) MSZ 1484-8:2004

Sample ID Pentachlorobenzene 1

g/dm3

MS001 <0.0002

MS002 <0.0002

MS003 <0.0002

MS004 <0.0002

MS006 <0.0002

MS007 <0.0002

MS008 <0.0002

MS010 <0.0002

MS011 <0.0002

MS012 <0.0002

MS013 <0.0002

Instruments: HP-6890-GCMS_03-5973

Page 19: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

13 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of Bisphenol-A Sample type: Surface water

(1) EPA Method 1694:2007

Sample ID Bisphenol-A 1

g/dm3

MS001 <0.1

MS002 <0.1

MS003 <0.1

MS004 <0.1

MS006 <0.1

MS007 <0.1

MS008 <0.1

MS010 <0.1

MS011 <0.1

MS012 <0.1

Instruments: LC-MS06

Determination of Phthalates Sample type: Surface water

(1) EPA Method 8270D:2007

Sample ID Bis(2-ethylhexyl)-phthalate 1

g/dm3

MS001 0.4 ±0.04

MS002 0.3 ±0.03

MS003 0.8±0.08

MS004 0.4±0.04

MS006 0.8±0.08

MS007 0.4±0.04

MS008 0.1±0.01

MS010 0.5±0.05

MS011 0.9±0.09

MS012 0.4±0.04

MS013 0.3±0.03

Instruments: HP-6890-GCMS_03-5973

Determination of Atrazine Sample type: Surface water

(1) WBSE-47:2010

Component Unit Sample ID

MS001 MS006 MS010

Atrazine 1 g/dm3 <0.01 <0.01 <0.01

Instruments: HP-6890-GCMS_14-5973

Page 20: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

14 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of terbutryn Sample type: Surface water

(1) WBSE-47:2010

Sample ID Terbutryn 1

g/dm3

MS003 <0.001

MS004 <0.001

MS007 <0.001

MS008 <0.001

MS010 <0.001

MS011 <0.001

MS012 <0.001

Instruments: HP-6890-GCMS_14-5973

Determination of Phthalates Sample type: Surface water

(1) EPA Method 8270D:2007

Component Unit Sample ID

MS006

Di-n-butyl-phthalate 1 g/dm3 0.2±0.02

Instruments: HP-6890-GCMS_03-5973

Determination of Phthalates Sample type: Surface water

(1) EPA Method 8270D:2007

Component Unit Sample ID

MS006 MS007

Diethyl-phthalate 1 g/dm3 <0.1 <0.1

Instruments: HP-6890-GCMS_03-5973

Determination of Hexachlorobutadiene Sample type: Surface water

(1) MSZ 1484-5:1998 7.3. section

Component Unit Sample ID

MS003 MS004 MS012

Hexachlorobutadiene 1 g/dm3 <0.1 <0.1 <0.1

Instruments: HP-6890-GCMS_09-5975

Page 21: bgodc.io-bas.bgbgodc.io-bas.bg/documents/2016/Protocols_PSSP_TOC_July_2016.pdf · Testing laboratory accredited by NAT under reg. no. NAT-1-1398/2015. Beginning of analysis: 29.07.2016.

Környezetanalitikai Laboratórium

WESSLING Hungary Kft. H-1047 Budapest, Fóti út 56. H-1325 Budapest, Újpest Pf. 211. Tel./ Fax: (+36-1) 872 3600, (+36-1) 872 3800 www.wessling.hu

Testing laboratory accredited by NAT under Reg. Nr.: NAT-1-1398/2015.

15 / 15 Project: 649 - MEW, 2016 July (2016/K/05523)

Report no.: 352068/1; 01.09.2016.

Determination of Pesticides Sample type: Surface water

(1) WBSE-47:2010

Component Unit Sample ID

MS001 MS002 MS003 MS004

2,4'-DDD 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4'-DDE 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4'-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4’-DDD and 2,4’-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

DDT/DDD/DDE (5) (a) 1 g/dm3 - - - -

Component Unit Sample ID

MS006 MS007 MS008 MS010

2,4'-DDD 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4'-DDE 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4'-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

4,4’-DDD and 2,4’-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002 <0.0002

DDT/DDD/DDE (5) (a) 1 g/dm3 - - - -

Component Unit Sample ID

MS011 MS012 MS013

2,4'-DDD 1 g/dm3 <0.0002 <0.0002 <0.0002

4,4'-DDE 1 g/dm3 <0.0002 <0.0002 <0.0002

4,4'-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002

4,4’-DDD and 2,4’-DDT 1 g/dm3 <0.0002 <0.0002 <0.0002

DDT/DDD/DDE (5) (a) 1 g/dm3 - - -

(a) Mathematical sum of individual components. Instruments: HP-6890-GCMS_14-5973 01.09.2016.

Validált rendszerből generált vizsgálati jegyzőkönyv, amely aláírás nélkül is hiteles.

Filep Zoltán Laboratóriumvezető