Beth Powell Business Platform Leader Hazardous Materials Performance Packaging.
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Transcript of Beth Powell Business Platform Leader Hazardous Materials Performance Packaging.
Beth PowellBusiness Platform Leader
www.newpig.com/shalegas
Hazardous Materials Performance Packaging
Disclaimers
This presentation is for general guidance only and must not be
used to determine compliance with 49 CFR Parts 100-185.
This presentation does not satisfy the Training Requirements
(49 CFR 172.704) for hazmat employees.
If you need this training, please contact your nearest
Safety-Kleen branch.
Basic Necessities
Package It
Placard It Mark It
Label It
49 CFR Part 172-173
Hazardous Materials Table
A list of all the proper shipping names that can be used to describe hazardous material for
transportation in the U.S.
Do not assume a substance is not hazardous if you do not find it listed in the HMT
HMT
Exceptions Non-bulk BulkPassenger
aircraft/railCargo
aircraft only(1) (2) (3) (4) (5) (6) (7) (8A) (8B) (8C) (9A) (9B)
D Diesel fuel 3 NA1993 III None 144, B1, IB3, T4, TP1, TP29
150 203 242 60 L 220 L
I Diesel fuel 3 UN1202 III 3 144, B1, IB3, T2, TP1
150 203 242 60 L 220 L
D G Hazardous waste, solid, n.o.s. 9 NA3077 III 9 B54, IB8, IP2, T1, TP33
155 213 240 No limit No limit
D G Hazardous waste, liquid, n.o.s. 9 NA3082 III 9 IB3, T2, TP1 155 203 241 No limit No limit
Hydrogen chloride, anhydrous 2.3 UN1050 2.3, 8 3, N86, N89 None 304 None Forbidden Forbidden
Shale oil 3 UN1288 II 3 IB2, T4, TP1, TP8
150 202 242 5 L 60 L
Shale oil 3 UN1288 I 3 T11, TP1, TP8, TP27
None 201 243 1 L 30 L
Shale oil 3 UN1288 III 3 B1, IB3, T2, TP1 150 203 242 60 L 220 L
A, W Rags, oily 4.2 UN1856 III 4.2 151 213 240 Forbidden Forbidden
A, I, W Textile waste, wet 4.2 UN1857 III 4.2 151 213 240 Forbidden Forbidden
Symbols PGIdentification
NumbersHazard class or Division
Hazardous materials descriptions and proper shipping names
Special Provisions (§
172.102)Label Codes
(8)
Packaging (§ 173.***)
(9)Quantity Limitations (see §§
173.27 and 175.75)
Hazardous Materials Table
http://www.phmsa.dot.gov/staticfiles/PHMSA/DownloadableFiles/Files/Hazmat/Hazmat%20Table.xls
Columns 1 & 2
Column 1 – Symbols Column 2 – Proper Shipping Names
– Roman type
– Supplemented by “punctuation marks” or words in italics
– Options indicated by “or”
– Singular or plural
– Upper or lower case
+ Fixes the proper shipping name
A Air
D Domestic
G Generic or n.o.s.
I International
W Water
Column 3 – Hazard Class
1. Explosive
2. Gases
3. Flammable and Combustible Liquids
4. Flammable Solids
5. Oxidizers and Organic Peroxides
6. Poisons & Infectious Substances
7. Radioactive
8. Corrosive
9. Miscellaneous
Columns 4 & 5
Column 4 – Identification Number for each proper shipping name.
– A four digit number preceded by “NA” for North America or “UN” for United Nations
Column 5 – Packing Group I, II, III, if assigned.
– Performance testing includes drop, leak-proofness, hydrostatic pressure, stacking and vibration
Packing Group (PG):
PG I – Greatest Danger
PG II – Moderate Danger
PG III – Minor Danger
Columns 6 & 7
Column 6 – Label Codes– Indicates the primary hazard label– Indicate subsidiary hazard labels
Column 7 – Special Provisions (§172.102)– Includes packaging provisions, prohibitions and exceptions
Transported By:A – AirH – HighwayR – RailW – Water
Transported In:B – BulkN – Non-BulkT – IntermodalTP – Portable Tanks
Columns 8, 9 & 10
Column 8 – Packaging Authorizations (§173.***)
– Exceptions (8A)
– Non-bulk specification packaging (8B)
– Bulk specification packaging (8C)
Column 9 – Quantity Limitations – Passenger Aircraft/Rail (9A)
– Cargo Aircraft Only (9B)
Column 10 – Vessel Stowage Requirements– Cargo and passenger vessels (10A)
– Specific hazardous materials (10B)
Packaging
Why is it Important?
1) First Line of Defense
• To the handler
• To the carrier
• To the environment
2) Accidents in Transit
• Public safety
• Emergency response
3) Gets there in one piece!
Packaging Selection Steps
1. Identify the Hazardous Material
2. Determine the Packing Group (Column 5)
3. Understand Special Provisions (Column 7)
– You must always check!
4. Identify the Packaging Exceptions (Column 8A)
– Exceptions are relief from the more stringent packaging requirements
5. Determine Bulk or Non-Bulk (Column 8B or 8C)
– Look up the 173.*** for the approved packaging
6. Understand Packaging ID Codes
Bulk vs. Non-Bulk
BulkLiquid
(>119 gal)
Solid (>882 lbs and capacity > 119 gal)
Gas (Water capacity > 1000 lbs)
Non-BulkLiquid
(≤119 gal)
Solid (≤ 882 lbs and capacity ≤ 119 gal)
Gas (Water capacity ≤ 1000 lbs)
Non-Bulk Packaging Codes
Type of Container
1=Drum
2=Wooden Barrel
3=Jerrican
4=Box
5=Bag
6=Composite Packaging
7=Pressure Receptacle
Material of ConstructionA=Steel B=Aluminum C=Natural Wood D=Plywood F=Reconstituted Wood G=Fiberboard H=Plastic L=Textile M=Paper, Multi-Wall N=Metal other than Steel
or Aluminum P=Glass, Porcelain, or
Stoneware
Category within Type
1=Closed Head
2=Open Head
Examples:
1A1 is a closed-head steel drum
1H2 is an open-head plastic drum
T = Used to denote a Salvage Drum which has been tested for leakproofness using water as the test media
IBC Packaging Codes
Type of Container
11=Rigid, designed for solids, loaded or unloaded by gravity
21=Rigid, designed for solids, loaded or unloaded under pressure > 10 kPa
13=Flexible, designed for solids, loaded or unloaded by gravity
31=Rigid, designed for liquids, loaded or unloaded by gravity
Material of ConstructionA=Steel
B=Aluminum
C=Natural Wood
D=Plywood
F=Reconstituted Wood
G=Fiberboard
H=Plastic
L=Textile
M=Paper, Multi-Wall
N=Metal other than Steel
or Aluminum
P=Glass, Porcelain, or
Stoneware
Category within TypeComposite IBC
1=Rigid inner receptacle
2=Flexible inner receptacle
Flexible IBC
1=Uncoated without liner
2=Coated without liner
3=Uncoated with liner
4=Coated with liner
Example: 13H4 is a flexible IBC made from coated plastic and includes a liner
Second Set of Manufacturer’s Markings
Performance LevelX=Meets PG I, II and III tests
Y=Meets PG II and III tests
Z=Meets PG III tests
Specific Gravity• Weight of a liquid compared to
weight of water• For packages intended to hold
liquids without inner containers
OR
Gross Weight (Kilograms)• 1 lb = 0.454 kg• For packages intended to hold
solids or inner containers
Examples:
1A1/Y1.8 is rated for Packing Groups II or III liquids with a specific gravity up to 1.8
1H2/X100 is rated for Packing Groups I, II or III solids up to 100 kg in weight
Last Set of Manufacturer’s Markings
Test Pressure (Kilopascals)
Maximum hydrostatic pressure
for packages intended to hold
liquids
OR
SolidsFor packaging containing
solids or inner packaging
Year of Manufacture
Then…
Country of ManufacturePlace where the package was
manufactured and marked
Then…
Name/Symbol of Manufacturer
Examples:
1A1/Y1.8/250/07/USA/M439 was tested up to 250 kPa, manufactured in 2007, made in the USA and approved by M4269
1H2/X100/S/10/USA/M4339 was rated for solids, manufactured in 2010, made in the USA and approved by M4339
All TogetherTest Pressure For liquids (kPa)
OR
Solids
Performance Level
X=Meets PG I, II and III tests
Y=Meets PG II and III tests
Z=Meets PG III tests
Type
1=Drum
2=Wooden Barrel
3=Jerrican
4=Box
5=Bag
6=Composite
Packaging
7=Pressure
Receptacle
Material A=Steel B=Aluminum C=Natural Wood D=Plywood F=Reconstituted Wood G=Fiberboard H=Plastic L=Textile M=Paper, Multi-Wall N=Metal other than Steel or Aluminum P=Glass, Porcelain, orStoneware
Category
1=Closed Head
2=Open Head
T = Salvage Drum which hasbeen tested forleakproofness
Specific GravityFor liquids
OR
Gross WeightFor solids (kg)
1 A 1/ Y 1.8/ 250
1 A 2/ X 120/ S
1 A 2/ Y 1.8/ 150
1 H 1/ Y 1.8/ 100
1 H 2/ Y 6/ S
1 H 2T/ X 100 S
Salvage Drums
Used when packages of hazardous materials are damaged,
defective or found leaking.
Must have sufficient cushioning and absorbent to prevent
excessive movement and eliminate any free liquid at time
drum is closed.
Marking Placement
Steel open and closed head drums MUST be marked with the
UN number permanently embossed on the bottom.
Plastic drums MUST be UN marked (embossed) on the side or
the bottom. If labels are also used they must be durable.