BASF Surfactants b.pdf
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A g g r e g a t e C o n d i t i o n @ R T A c t i v e M a t t e r [ % ] S o d i u m s u l f a t e [ % ] S o d i u m C h l o r i d e [ % ] p H v a l u e Features and Benefits Texapon ® EHS * Na-2-Ethylhexyl sulfate (iso-C8) liquid 42.5 - 49.0 0 - 2 0 - 0.5 10.0 - 11.5 2) Disponil ® ALS 33 NH4-lauryl sulfate (C8/14) liquid 32.0 - 34.0 0 - 7 a) 0 - 1.5 a) 6.0 - 7.0 5) Disponil ® SDS 15 Na-n-dodecyl sulfate (C12) liquid 14.5 - 15.5 0 - 0.8 0 - 0.3 8.0 - 9.0 1) Disponil ® SDS 30 Na-n-dodecyl sulfate (C12) liquid 29.0 - 31.0 0 - 1.0 0 - 0.1 7.5 - 8.5 5) Disponil ® SDS G Na-n-dodecyl sulfate (C12) granules 95.0 - 99.0 0 - 2.5 0 - 1.0 8.5 - 10.5 2) Disponil ® TLS 42 Triethanolami n l auryl sulfate (C12/14) liquid 40.0 - 43.0 0 - 3.0 b) 0 - 1.0 b) 7.2 - 7.5 5) Disponil ® SLS 103 Na-lauryl sul fate (C12/16) liquid 27.5 - 28.5 0 - 1.0 0 - 0.1 7.5 - 8.5 5) Disponil ® SLSK 30 Na-lauryl sulfate (C12/18) paste like 28.0 - 30.0 0 - 2.0 0 - 1.0 10.5 - 11.5 5) Disponil ® OCS 27 Na-oleyl-cetyl sulfate (C16/18') solid 26.0 - 28.0 0 - 0.6 0 - 0.3 8.3 - 11.5 5) * characteristic foaming behavior Disponil ® LDBS 19 linear Dodecyl benzene sulfonate, Na-salt liquid 18.5 - 19.5 0 - 1.0 0 - 0.1 7.0 - 8.5 5) Disponil ® LDBS 25 linear Dodecyl benzene sulfonate, Na-salt liquid 24.5 - 25.5 0 - 1.0 0 - 0.1 7.0 - 8.5 5) Disponil ® LDBS 55 linear Dodecyl benzene sulfonate, Na-salt paste like 54.0 - 56.0 0 - 1.0 - 9.0 - 10.0 3) Disponil ® FES 27 Fatty alcohol ether sulfate, Na-salt (2 EO) liquid 26.5 - 27.5 0 - 0.5 0 - 0.1 6.4 - 7.5 5) Disponil ® FES 32 Fatty alcohol ether sulfate, Na-salt (4 EO) liquid 30.0 - 32.0 0 - 0.8 - 7.0 - 8.5 5) Disponil ® FES 430 Fatty alcohol ether sulfate, Na-salt (8 EO) liquid 28.0 - 30.0 0 - 0.8 - 7.0 - 8.5 5) Disponil ® FES 993 Fatty alcohol ether sulfate, Na-salt (12 EO) liquid 29.0 - 31.0 0 - 0.8 - 7.0 - 8.5 5) Disponil ® BES 20 iso-Tridecyl alcohol ether sulfate, Na-salt (20 EO) liquid 28.0 - 30.0 0 - 1.0 - 7.0 - 8.5 5) Disponil ® FES 77 Fatty alcohol ether sulfate, Na-salt (30 EO) liquid 32.0 - 34.0 0 - 0.8 - 7.0 - 8.5 5) Disponil ® FES 61 Fatty alcohol ether sulfate, Na-salt (50 EO) liquid 31.0 - 33.0 0 - 0.8 - 7.0 - 8.5 5) Emuphor ® FES 30 Fatty alcohol ehter sulfate, Na-salt (30 EO) liquid 30.0 - 34.0 max. 1.5 - 7.5 - 9.0 Disponil ® AES 48 Nonyl phenol ether sulfate, Ammonium salt (4 EO) liquid 68.0 - 71.0 - - 6.0 - 7.5 Disponil ® AES 60 Nonyl phenol ether sul fate, Na-sal t (10 EO) liqui d 34.0 - 36.0 0 - 1.0 - 7.0 - 8.5 5) Disponil ® AES 25 Nonyl phenol ether sul fate, Na-sal t (25 EO) liqui d 31.0 - 33.0 0 - 0.5 - 7.0 - 9.0 1) Emulphor ® NPS 25 Nonyl phenol ether sulfate, Na-salt (25 EO) liquid 28.5 - 32.5 0 - 0.3 - 7.0 - 9.0 Emulphor ® OPS 25 Octyl phenol ether sulfate, Na-salt (25 EO) liquid ~ 34 0 - 2.0 - 7.0 - 9.0 Disponil ® SUS 87Special Sulfosucci nic aci d monoester, Di-Na-salt liquid 28.0 - 32.0 0 - 1.0 - 5.0 - 6.0 5) - suitable for manufacturing of small particle latices (hydrosols) Disponil ® SUS IC 875 Di-isooctyl-sulfosuccinate, Na-salt (iso-C8) liquid 73.0 - 76.0 0 - 1.0 - 5.5 - 7.5 5) Lutensit ® A-BO Di-isooctyl-sulfosuccinate, Na-salt (iso-C8) liqui d ~ 60 - 5.5 - 7.0 Disponil ® SUS IC 10 Di-isodecyl-sulfosuccinate, Na-salt ( iso-C10) liquid 63.0 - 6 6.0 0 - 1 .0 - 6.0 - 8.0 5) Hydropalat ® 885 * Modified Di-isooctyl sulfosuccinate (i so-C8) liqui d 83.0 - 86.0 0 - 1.0 - 5.5 - 7.5 2) Hydropalat ® 886 * Modified Di-isooctyl sulfosuccinate (i so-C8) liqui d 84.0 - 87.0 0 - 1.0 - 5.5 - 7.5 5) Hydropalat ® 88 * Di-isodecyl-sulfosuccinate, Na-salt ( iso-C10) liquid 48.0 - 5 1.0 0 - 1 .0 - 5.0 - 7.0 5) Disponil ® ODSLS Di-Na-Sulfosuccinamate (C18') partly crystallized 34.0 - 36.5 - - 7.5 - 9.5 4) - characteristic foaming behavior Disponil ® FEP 6300 Alkyl poly glycol ether phospate, acid form (3 EO) paste, liquid >98 - - <2.5 Disponil ® AEP 5300 Alkyl phenol e ther phosphate, acid ester (10 EO) liquid ~ 100 - - - Hydropalat ® 7003 Fatty alcohol ether phosphate, aci d ester (12 EO) liqui d 29.0 - 31.0 - - 1.0 - 3.0 5) - Corrosion protection - VAc-homo polymers Disponil ® OXS 970 Di-hydroxy stearic acid, NH4-salt partly crystallized 49.0 - 51.0 - - 8.5 - 9.0 5) - suitable for micro-suspension PVC Disponil ® OSS 50 KS Di-K-oleic acid sulfonate (C18') liquid 49.0 - 53.0 0 - 3.0 c) - 6.0 - 7.0 5) a) Ammonium sulfate/chloride b) Triethanol amine sulfate/chloride c) P otassium sulfate 1) as in 4) 5% in demi. water Revised date: March 12, 2012 2) 1% in de mi. w at er 5) 10 % in d emi. water 3) 3% in demi. water High Performance Surfactants for Emulsion Polymerization - alternatives to APEO-sulfates - improved stabilization properties in the latex over alkyl sulfates - lower ethoxylated products more suitable for all acrylics - medium ethoxylated products more suitable for styrene acrylics, mulsifiers for alkyd resins - higher ethoxylated products more suitable for VAc's, emulsifiers for alkyd resins. Ani oni c su rfac tant s Typical Technical Data Description Product Name Alk yl Su lfat es - basic surfactants - excellent particle size control - foaming agents, e.g. for carpet back ing, textile - suitable for all types of monomers, styrene acrylics, pure acrylics, E-PVC Alk yl-ar yl Su lfo nates - basic surfactants - especially for seed latex - stable against hydrolysis - suitable for all types of monomers, commonly use in E-PVC and NB Latex Alk yl Et hers ulf ates - based on Alkylphen ol ethoxylates (APEO's) - highly efficient wetting agents - strong reduction of dynamic surface tension - recommended as post add f or PSA-applications - applicable for viscosity adjustment of PVC-paste * product is free of volatile organic solvents Alk ylp heno l Et hers ulf ates Sulfosuccinates / Sulfossuccinamates - based on Alkylphenol ethoxylates (APEO'S). Alternatives see Disponil FES typ es Phosphoric Acid Esters Soaps
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Transcript of BASF Surfactants b.pdf
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Features and Benefits
Texapon EHS * Na-2-Ethylhexyl sulfate (iso-C8) liquid 42.5 - 49.0 0 - 2 0 - 0.5 10.0 - 11.5 2)
Disponil ALS 33 NH4-lauryl sulfate (C8/14) liquid 32.0 - 34.0 0 - 7 a) 0 - 1.5 a) 6.0 - 7.0 5)
Disponil SDS 15 Na-n-dodecyl sulfate (C12) liquid 14.5 - 15.5 0 - 0.8 0 - 0.3 8.0 - 9.0 1)
Disponil SDS 30 Na-n-dodecyl sulfate (C12) liquid 29.0 - 31.0 0 - 1.0 0 - 0.1 7.5 - 8.5 5)
Disponil SDS G Na-n-dodecyl sulfate (C12) granules 95.0 - 99.0 0 - 2.5 0 - 1.0 8.5 - 10.5 2)
Disponil TLS 42 Triethanolamin lauryl sulfate (C12/14) liquid 40.0 - 43.0 0 - 3.0 b) 0 - 1.0 b) 7.2 - 7.5 5)
Disponil SLS 103 Na-lauryl sulfate (C12/16) liquid 27.5 - 28.5 0 - 1.0 0 - 0.1 7.5 - 8.5 5)
Disponil SLSK 30 Na-lauryl sulfate (C12/18) paste like 28.0 - 30.0 0 - 2.0 0 - 1.0 10.5 - 11.5 5)
Disponil OCS 27 Na-oleyl-cetyl sulfate (C16/18') solid 26.0 - 28.0 0 - 0.6 0 - 0.3 8.3 - 11.5 5)
* characteristic foaming behavior
Disponil LDBS 19 linear Dodecyl benzene sulfonate, Na-salt liquid 18.5 - 19.5 0 - 1.0 0 - 0.1 7.0 - 8.5 5)
Disponil LDBS 25 linear Dodecyl benzene sulfonate, Na-salt liquid 24.5 - 25.5 0 - 1.0 0 - 0.1 7.0 - 8.5 5)
Disponil LDBS 55 linear Dodecyl benzene sulfonate, Na-salt paste like 54.0 - 56.0 0 - 1.0 - 9.0 - 10.0 3)
Disponil FES 27 Fatty alcohol ether sulfate, Na-salt (2 EO) liquid 26.5 - 27.5 0 - 0.5 0 - 0.1 6.4 - 7.5 5)
Disponil FES 32 Fatty alcohol ether sulfate, Na-salt (4 EO) liquid 30.0 - 32.0 0 - 0.8 - 7.0 - 8.5 5)
Disponil FES 430 Fatty alcohol ether sulfate, Na-salt (8 EO) liquid 28.0 - 30.0 0 - 0.8 - 7.0 - 8.5 5)
Disponil FES 993 Fatty alcohol ether sulfate, Na-salt (12 EO) liquid 29.0 - 31.0 0 - 0.8 - 7.0 - 8.5 5)
Disponil BES 20 iso-Tridecyl alcohol ether sulfate, Na-salt (20 EO) liquid 28.0 - 30.0 0 - 1.0 - 7.0 - 8.5 5)
Disponil FES 77 Fatty alcohol ether sulfate, Na-salt (30 EO) liquid 32.0 - 34.0 0 - 0.8 - 7.0 - 8.5 5)
Disponil FES 61 Fatty alcohol ether sulfate, Na-salt (50 EO) liquid 31.0 - 33.0 0 - 0.8 - 7.0 - 8.5 5)
Emuphor FES 30 Fatty alcohol ehter sulfate, Na-salt (30 EO) liquid 30.0 - 34.0 max. 1.5 - 7.5 - 9.0
Disponil AES 48 Nonyl phenol ether sulfate, Ammonium salt (4 EO) liquid 68.0 - 71.0 - - 6.0 - 7.5
Disponil AES 60 Nonyl phenol ether sulfate, Na-salt (10 EO) liquid 34.0 - 36.0 0 - 1.0 - 7.0 - 8.5 5)
Disponil AES 25 Nonyl phenol ether sulfate, Na-salt (25 EO) liquid 31.0 - 33.0 0 - 0.5 - 7.0 - 9.0 1)
Emulphor NPS 25 Nonyl phenol ether sulfate, Na-salt (25 EO) liquid 28.5 - 32.5 0 - 0.3 - 7.0 - 9.0
Emulphor OPS 25 Octyl phenol ether sulfate, Na-salt (25 EO) liquid ~ 34 0 - 2.0 - 7.0 - 9.0
Disponil SUS 87Special
Sulfosuccinic acid monoester, Di-Na-salt liquid 28.0 - 32.0 0 - 1.0 - 5.0 - 6.0 5)- suitable for manufacturing of small particle latices (hydrosols)
Disponil SUS IC 875 Di-isooctyl-sulfosuccinate, Na-salt (iso-C8) liquid 73.0 - 76.0 0 - 1.0 - 5.5 - 7.5 5)
Lutensit A-BO Di-isooctyl-sulfosuccinate, Na-salt (iso-C8) liquid ~ 60 - 5.5 - 7.0
Disponil SUS IC 10 Di-isodecyl-sulfosuccinate, Na-salt (iso-C10) liquid 63.0 - 66.0 0 - 1.0 - 6.0 - 8.0 5)
Hydropalat 885 * Modified Di-isooctyl sulfosuccinate (iso-C8) liquid 83.0 - 86.0 0 - 1.0 - 5.5 - 7.5 2)
Hydropalat 886 * Modified Di-isooctyl sulfosuccinate (iso-C8) liquid 84.0 - 87.0 0 - 1.0 - 5.5 - 7.5 5)
Hydropalat 88 * Di-isodecyl-sulfosuccinate, Na-salt (iso-C10) liquid 48.0 - 51.0 0 - 1.0 - 5.0 - 7.0 5)
Disponil ODSLS Di-Na-Sulfosuccinamate (C18')partly
crystallized 34.0 - 36.5 - - 7.5 - 9.5 4) - characteristic foaming behavior
Disponil FEP 6300 Alkyl polyglycol ether phospate, acid form (3 EO) paste, liquid >98 - -
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Disponil LS 500 Fatty alcohol ethoxylate (C12/14) (50 EO) solid flakes 99.5 - 100.0 6.0 - 7.0 1) 43 - 47 18.4
Lutensol AT 11 Fatty alcohol ethoxylate (C16/18) (11 EO) solid 100.0 5.0 - 8.0 - 13
Lutensol AT 18 Fatty alcohol ethoxylate (C16/18) (18 EO) solid 100.0 5.0 - 8.1 - 15
Lutensol AT 25 Fatty alcohol ethoxylate (C16/18) (25 EO)powder/ flakes 100.0 5.0 - 8.0 - 16
Disponil TA 400 Fatty alcohol ethoxylate (C16/18) (40 EO) solid 99.0 - 100.0 6.0 - 7.5 1) 42 - 47 17.4
Lutensol AT 50 Fatty alcohol ethoxylate (C16/18) (50 EO)powder/ flakes 100.0 5.0 - 8.0 19
Disponil OC 5 Oleyl-cetyl ethoxylate (C16/18') (5 EO)partly
crystallized 98.0 - 100.0 6.5 - 7.5 1) 10 - 20 9.5
Disponil OC 25 Oleyl-cetyl ethoxylate (C16/18') (25 EO) solid 99.5 - 100.0 6.0 - 7.5 1) ~ 40 16.5
Modified Fatty Alcohol Ethoxylates
Disponil A 1080 mod. Fatty alcohol ethoxylates (10 EO) liquid 79.0 - 81.0 6.0 - 7.5 1) < 10 14
Disponil A 1580 mod. Fatty alcohol ethoxylates (15 EO) liquid 79.0 - 81.0 6.0 - 7.5 1) < 15 15
Disponil A 3065 mod. Fatty alcohol ethoxylates (30 EO) liquid 64.0 - 66.0 6.0 - 7.5 1) < 10 16.5
Disponil A 4065 mod. Fatty alcohol ethoxylates (40 EO) liquid 64.0 - 66.0 6.0 - 7.5 1) < 15 16.5
Disponil AFX 9580 mod. Fatty alcohol ethoxylates (9.5 EO) liquid 79.0 - 81.0 6.0 - 7.5 1) < 10 13.7
Disponil AFX 1080 mod. Fatty alcohol ethoxylates (10 EO) liquid 79.0 - 81.0 6.0 - 7.5 2) < 10 14.5
Disponil AFX 2075 mod. Fatty alcohol ethoxylates (20 EO) liquid 74.0 - 76.0 6.0 - 7.5 2) < 15 17
Disponil AFX 3070 mod. Fatty alcohol ethoxylates (30 EO) liquid 69.0 - 71.0 6.0 - 7.5 2) < 15 17.5
Disponil AFX 4030 mod. Fatty alcohol ethoxylates (40 EO) liquid 29.0 - 31.0 6.0 - 7.5 2) < 5 18
Alkylphenol Ethoxylates
Letensol AP 9 Alkyl Phenol Polyglycolether (9 EO) liquid >99 5.0 - 8.0 - 13
Letensol AP 10 Alkyl Phenol Polyglycolether (10 EO) liquid >99 5.0 - 8.0 - 13.5
Lutensol AP 14 Alkyl Phenol Polyglycolether (14 EO) liquid >99 5.0 - 8.0 - 14.5
Lutensol AP 20 Alkyl Phenol Polyglycolether (20 EO) paste >99 5.0 - 8.0 - 16
Disponil OP 4070 Octyl phenol ethoxylate (40 EO) liquid 69.0 - 71.0 6.0 - 7.5 2) < 5 17.9
Disponil NP 2080 Nonyl phenol ethoxylate (20 EO) liquid 79.0 - 81.0 6.0 - 7.0 2) < 5 16
Emulan OP25 Octyl phenol ethoxylates (25 EO) paste >99 5.0 - 8.0 - -
Disponil NP 3070 Nonyl phenol ethoxylate (30 EO) liquid 69.0 - 71.0 6.0 - 7.0 2) < 0 17.2
Lutensol TO 8 C13 - Oxo alcohol Ethoxylate (8 EO) liquid >99.0 5.0 - 8.0 - 13
Lutensol TO 10 C13 - Oxo alcohol Ethoxylate (10 EO) pastes >99.0 5.0 - 8.0 - 13.5
Lutensol TO 12 C13 - Oxo alcohol Ethoxylate (12 EO) solid >99.0 5.0 - 8.0 - 14.5
Lutensol TO 15 C13 - Oxo alcohol Ethoxylate (15 EO) solid >99.0 5.0 - 8.0 - 15.5
Emulan TO 2080 C13 - Oxo alcohol Ethoxylate (20 EO) liquid 80 5.0 - 8.0 - 16
Emulan TO 3070 C13 - Oxo alcohol Ethoxylate (30 EO) liquid 70 5.0 - 8.0 - 17
Emulan TO 4070 C13 - Oxo alcohol Ethoxylate (40 EO) liquid 70 5.0 - 8.0 - 18
Disponil APG 215 Alkyl polyglycosid (C8/C10) liquid 62.0 - 65.0 11.5 - 12.5 3) - -
Disponil APG 425 Alkyl polyglycosid (C8/14) liquid 48.0 - 52.0 7.0 - 9.5 4) - -
Disponil APG 600 Alkyl polyglycosid (C12/14) liquid 50.0 - 53.0 11.5 - 12.5 3) - -
Pluronic PE 3100 PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 1000g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 3500 PO/EO-Blockpolymer (ca.50 EO, molar mass ca. 1900g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 4300 PO/EO-Blockpolymer (ca.30 EO, molar mass ca. 1750g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 6100 PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 2000g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 6120 PO/EO-Blockpolymer (ca.12 EO, molar mass ca. 2100g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 6200 PO/EO-Blockpolymer (ca.20 EO, molar mass ca. 2450g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 6400 PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 2900g/mol) liquid >99.0 6.0 - 8.0 - -
Pluronic PE 6800 PO/EO-Blockpolymer (ca.80 EO, molar mass ca. 8000g/mol) powder >99.0 5.0 - 8.0 - -
Pluronic PE 8100 PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 2600g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 9200 PO/EO-Blockpolymer (ca.20 EO, molar mass ca. 3650g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 9400 PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 4600g/mol) solid >99.0 5.0 - 8.0 - -
Pluronic PE 10100 PO/EO-Blockpolymer (ca.10 EO, molar mass ca. 3500g/mol) liquid >99.0 4.0 - 8.0 - -
Pluronic PE 10300 PO/EO-Blockpolymer (ca.30 EO, molar mass ca. 4950g/mol) paste >99.0 5.0 - 8.0 - -
- alternatives to alkylphenol ethoxylates (APEO's)- co-emulsifiers for improvement of stabilization properties- emulsifiers for alkyd resins
Fatty Alcohol Ethoxylates
Alkyl Polyglycosides
Description
Alkyl Polyglycolether
Typical Technical Data
pluronic PE 6100, PE6200, PE 6400, PE 6800- Low foam genration emulsifiers (depending on ratio EO/PO and interactions with anionic surfactants present in the latex formulation) - provide latexs with high stability high shear stabilityhigh elctrolytic stabilityhigh freeze-thaw stability -low water sensitivity (depending on ratio EO/PO and interactions with anionic surfactants present in the latex formulation)
-100% renewable base surfactant
Nonionic surfactants
- basic non-ionic surfactans- alternative to Alkylphenol ethoxylate (APEO)- co-emulsifiers to impeove stabilization properties
- alternatives to alkylphenol ethoxylates (APEO's)- co-emulsifiers for improvement of stabilization properties- emulsifiers for alkyd resins
- basic non-ionic surfactants- alternatives to Alkylphenol ethoxylates (APEO's)- emulsifiers for alkyd resins
EO/PO Block Copolymers
- based on alkylphenol ethoxylates - (APEO's) (Alternatives see, modified and non-modified fatty alcohol ethoxylates)
Product Name
High Performance Surfactants for Emulsion Polymerization
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Pluronic PE 10400 PO/EO-Blockpolymer (ca.40 EO, molar mass ca. 5900g/mol) solid >99.0 5.0 - 8.0 - -
Pluronic PE 10500 PO/EO-Blockpolymer (ca.50 EO, molar mass ca. 6500g/mol) solid >99.0 5.0 - 8.0 - -1) 1% in 0,03% KCl-solution 2) 10% in 0,03% KCl-solution 3) 10% in 15% IPA-dilution 4) 20% in 15% IPA-dilution
Revised date: March 12, 2012
