Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of...
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![Page 1: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/1.jpg)
Background 1
• Critical levels of acidification and nutrient-N are still exceeded in many parts of Europe
• reductions in SO2 and NOx emissions have been achieved
• by 2010 NH3 is likely to be the largest contributor to acidifying and gaseous N emissions
![Page 2: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/2.jpg)
![Page 3: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/3.jpg)
![Page 4: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/4.jpg)
![Page 5: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/5.jpg)
![Page 6: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/6.jpg)
Background 2
• The UNECE resolved to apply a multi-effect multi-pollutant approach to prevent or minimise exceedance of critical loads or levels
• measures to reduce NH3 emissions are required under the 1999 protocol to the Convention on Long-Range Transboundary Air Pollution to abate Acidification, Eutrophication and ground-level O3
![Page 7: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/7.jpg)
Background 3
• Conscious of the need for a cost-effective regional approach to combatting air pollution that takes account of the variation in effects and abatement costs between countries
![Page 8: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/8.jpg)
Background 4
• Measures taken to reduce emissions of NOX and NHX should not, so far as possible, increase other emissions of reactive-N, including N2O
![Page 9: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/9.jpg)
Protocol requirements 1
• Countries have been given an emissions ceiling– from 4% reduction (France)– to 43% (Netherlands)
• with a 15% overall reduction for Europe
• and are required to apply, as a minimum the following control measures
![Page 10: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/10.jpg)
Protocol requirements 2
• To provide information to the general public
• make widely available information on NH3 abatement, including information on Good Agricultural Practice (GAP)
• encourage research into improvements to NH3 databases
• improve NH3 monitoring techniques
• quantify efficacy of NH3 control techniques for farms and their impacts on deposition
![Page 11: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/11.jpg)
Where does it come from?UK
0
20
40
60
80
100
120
140
160
Cattle Pigs Poultry Sheep Fertilizer Non-Ag
kg x 106
![Page 12: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/12.jpg)
Agricultural sources
0
10
20
30
40
50
60
cattle pigs poultry fur sheep fertilizers
UK DK
kg x 106
![Page 13: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/13.jpg)
Emissions at stages of manure management
0
5
10
15
20
25
30
35
40
45
Housing Yards Stores Spread Grazing
UKDK
%
![Page 14: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/14.jpg)
TAN flowTAN AT EXCRETION
TAN INTO STORAGE
TAN AT SPREADING
AMMONIA LOSSES FROM BUILDINGS
AMMONIA LOSSES FROM SPREADING
AMMONIA LOSSES FROM STORES
AMMONIA LOSSES FROM BUILDINGS
TAN AT EXCRETION
TAN INTO STORAGE
TAN AT SPREADING
AMMONIA LOSSES
FROM STORES
AMMONIA LOSSES FROM SPREADING
![Page 15: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/15.jpg)
Implications for abatement
• NH3 lost ‘upstream’, e.g. buildings and stores may be lost ‘downstream’ e.g. spreading, if no further measures taken.
• surface phenomenon– greatest emissions when SA/vol ratio large– buildings, spreading, less from stores– emissions largely cease when absorbed by soil
![Page 16: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/16.jpg)
Strategy 1
• Reduce emissions at final stage of manure management– Losses during spreading minimal
• 1% of total
• specific measures
• immobilize in litter
• rank according to cost-effectiveness
![Page 17: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/17.jpg)
Strategy 2
• Different strategy to nitrate (NO3), nitrous oxide (N2O)
• surface phenomenon
• reducing excess has limited effect
• need specific measures to reduce NH3
![Page 18: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/18.jpg)
Code of good agricultural practice- 6 sections
• N management
• feeding strategies
• spreading
• storage
• housing
• N fertilizers
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N management - balanced N application
• NH3 emissions arise before applied N enters pool of plant-available N
• balancing N inputs to crop needs has much less potl to reduce NH3 emissions than NO3
• specific abatement measures are needed to give large reductions in NH3 emissions
• adopting such measures will conserve N for crop uptake
![Page 20: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/20.jpg)
Livestock feeding strategies
• Ensure livestock not fed more protein than required
• reduces N excretion and hence NH3 emissions
• protein surplus largely excreted as urea or uric acid
• hence reducing protein input gives disproportionate decrease in NH3 losses
![Page 21: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/21.jpg)
SpreadingCategories
• 1 - Well researched, practical, quantitative data on their abatement efficiency
• 2 - promising, but research inadequate, or difficult to quantify efficiency. They may be used as part of an abatement strategy
• 3 - ineffective or are likely to be excluded on practical grounds
![Page 22: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/22.jpg)
Shallow injection - Slurry is placed in shallow (50-60 mm) open slots
Band spreading - Slurry applied in narrow bands by trailing hoses
Trailing Shoe - Sward is parted by the shoe and slurry applied to the soil
![Page 23: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/23.jpg)
Injection
• Deep injection inserts slurry beneath the surface– up to 95% reduction in emissions
• problems with – stones– damage to grass swards
• slot injection, more applicable, less damage– less effective, 60 - 70%
![Page 24: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/24.jpg)
![Page 25: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/25.jpg)
Band spreaders
• Reducing surface area reduces emissions– % losses less from large applicaton rates
• trailing shoe, mainly grassland– 40-70% reduction
• trailing hose, 10-50%
![Page 26: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/26.jpg)
![Page 27: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/27.jpg)
Field-scale studies
• Few studies using more than 1 technique– Malgeryd 1998, BS, TS, ShI– Mattila 1998, BS, I– Mulder and Huijsmans 1994, BS, TS, SlI/I– Misselbrook and Smith 2000, BS, TS, SlI
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Field-scale 2
• Some single comparisons have also been made– Pain and Misselbrook 1997, I– Sommer et al 1997, TH– Ferm et al 1999, TH– Bless et al 1991, TH
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Overall averages
Machine Arable Grassland
TH 31 (34) 32 (30)
TS 67 (70) 62 (62)
Sh/Sl I 72 (72)
I 70 (52)
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Category 1 - spreadingUNECE current
trailing hose 30 30trailing shoe 40 60injection – openslot
60 70
injection – closedslot
80 80
incorporation ofslurry or FYM
80-90 90-95
![Page 31: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/31.jpg)
Category 2 - spreading
• dilution of slurry– increased storage capacity– increased risk of run-off
• mechanical separation of slurry– emissions from solid fraction
• apply water after spreading
![Page 32: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/32.jpg)
Category 3 - spreading
• Acidifying slurry to pH 4-5– hazard of handling strong acids
– Increased N2O emissions
• additives e.g. salts of Ca, Mg, Al– quantities required too large
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Storage techniques
C1 solid roof, tentor lid
80
C2 natural crustformation
requiresstirring beforespreading
35-50
C2 floatingplastic cover
not well tested 60
C2 floating oil,leca cover
requiresstirring beforespreading
40
![Page 34: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/34.jpg)
![Page 35: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/35.jpg)
Ammonia emissions from cattle
0
50
100
150
200
250
Manure Grazing
TANNH3
![Page 36: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/36.jpg)
Extending the grazing season
• In principle large potential benefit
• Practice, not so clear– only part of day– do emissions continue from house?
• May make a small contribution
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Good housekeeping
• Spreading in evening
• Keeping yards clean
• Frequent scraping of cubicles
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Encourage FYM storage
• ‘fresh’ FYM 25% TAN, stored FYM 10%• Where does the TAN go during storage?
– Not much NH3
– N2O– N2
– Leaching– immobilization– ???
![Page 39: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/39.jpg)
Cost-curve output
Measure cost(£ x 106)
NH3 red(kg x 106)
cost(£ per kg)
immediate incorp FYM toarable land by disc
0.31 1.009 0.31
crust formation on lagoons 0.05 0.127 0.39immediate incorp slurry toarable land by disc
1.63 3.388 0.48
crust formation on slurry tanks 0.198 0.119 1.66application of slurry to grass bytrailing shoe
37.893 9.487 3.99
increased frequency of scrapingslurry from cubicle buildings
10.251 2.187 4.69
store all FYM 20.639 3.375 6.12
![Page 40: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/40.jpg)
Cost-curve dairy
0
20
40
60
80
100
120
0 10 20 30% NH3 reduction
£ x 106
![Page 41: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/41.jpg)
Feeding strategies
• Very effective for pigs (synthetic amino acids)– but expensive
• Less effective for poultry– and costs exceed profit margin
• Complex for ruminants– all grass– mixed forages
![Page 42: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/42.jpg)
Effect of fertilizer-N on autumn SMN (from Sylvester-Bradley & Chambers)
0
20
40
60
80
100
120
140
0 34 70 105 140 175 210 245
SMN (0-90) kg/ha
![Page 43: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/43.jpg)
0
20
40
60
80
100
120
140
0 34 70 105 140 175 210 245
SMN (0-90) kg/ha
![Page 44: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/44.jpg)
Background 1
• Critical levels of acidification and nutrient-N are still exceeded in many parts of Europe
• measures to reduce NH3 emissions are required under the protocol to the 1979 Convention on Long-Range Transboundary Air Pollution to abate Acidification, Eutrophication and ground-level O3
![Page 45: Background 1 Critical levels of acidification and nutrient- N are still exceeded in many parts of Europe reductions in SO 2 and NO x emissions have been.](https://reader035.fdocuments.us/reader035/viewer/2022062322/56649ed95503460f94be70c1/html5/thumbnails/45.jpg)
Background 2
• The UNECE resolved to apply a multi-effect multi-pollutant approach to prevent or minimise exceedance of critical loads or levels
• conscious of the need for a cost-effective regional approach to combatting air pollution that takes account of the variation in effects and abatement costs between countries