Asymmetric Hydrogenation of Imines Catalyzed by Iridium Complexes with Phosphine—Phosphite...

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Page 1: Asymmetric Hydrogenation of Imines Catalyzed by Iridium Complexes with Phosphine—Phosphite Ligands: Importance of Backbone Flexibility.

2005 Enantioselective syntheses

Enantioselective synthesesO 0031 Asymmetric Hydrogenation of Imines Catalyzed by Iridium Complexes with

Phosphine—Phosphite Ligands: Importance of Backbone Flexibility. — Chiral phosphine-phospites provide an alternative class of ligands for the iridium catalyzed enantioselective hydrogenation of imines. — (VARGAS, S.; RUBIO, M.; SUAREZ, A.; PIZZANO*, A.; Tetrahedron Lett. 46 (2005) 12, 2049-2052; Inst. Invest. Quim., CSIC, Univ. Sevilla, E-41092 Sevilla, Spain; Eng.) — D. Singer

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