ARALDITE 2015 GB RESIN - RS Components...

SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006

ARALDITE® 2015 GB RESIN

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Revision Date:

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SDS Number: 400001015909

Date of last issue: 18.11.2016 Date of first issue: 07.04.2016

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

: ARALDITE® 2015 GB RESIN

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Adhesives

1.3 Details of the supplier of the safety data sheet

Company : Huntsman Advanced Materials (Europe)BVBA Address : Everslaan 45

3078 Everberg Belgium

Telephone : +41 61 299 20 41 Telefax : +41 61 299 20 40 E-mail address of person responsible for the SDS

: [email protected]

1.4 Emergency telephone number

Emergency telephone number : EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Skin irritation, Category 2

H315: Causes skin irritation.

Serious eye damage, Category 1

H318: Causes serious eye damage.

Skin sensitisation, Category 1

H317: May cause an allergic skin reaction.

Chronic aquatic toxicity, Category 2

H411: Toxic to aquatic life with long lasting effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)



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Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

: Prevention: P261 Avoid breathing mist or vapours. P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face

protection. Response: P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously

with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention.

P362 + P364 Take off contaminated clothing and wash it before reuse.

Hazardous components which must be listed on the label:

Bisphenol A epoxy resin Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol Butanedioldiglycidyl ether

Additional Labelling:

EUH205 Contains epoxy constituents. May produce an allergic reaction.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components

Chemical name CAS-No. EC-No. Index-No.

Classification Concentration



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Registration number (% w/w)

4,4'-Isopropylidenediphenol, oligomeric reaction products with 1-chloro-2,3-epoxypropane

25068-38-6 500-033-5 603-074-00-8 01-2119456619-26

Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317 Aquatic Chronic 2; H411

30 - 60

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol

9003-36-5 500-006-8 01-2119454392-40

Skin Irrit. 2; H315 Skin Sens. 1; H317 Aquatic Chronic 2; H411

13 - 30

1,4-Bis(2,3-epoxypropoxy)butane

2425-79-8 219-371-7 603-072-00-7 01-2119494060-45

Acute Tox. 4; H302 Acute Tox. 4; H332 Acute Tox. 4; H312 Skin Irrit. 2; H315 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Chronic 3; H412

3 - 7

bisphenol A - epoxy resins, number average MW >700 - <1100

25068-38-6 Polymer

Skin Irrit. 2; H315 Eye Irrit. 2; H319 Skin Sens. 1; H317

3 - 7

2-[[3-Hydroxy-2,2-bis[[(1-oxoallyl)oxy]methyl]propoxy]methyl]-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl diacrylate

60506-81-2 262-270-8 -

Eye Irrit. 2; H319 1 - 3

Hydroquinone 123-31-9 204-617-8 604-005-00-4 -

Acute Tox. 4; H302 Eye Dam. 1; H318 Skin Sens. 1; H317 Muta. 2; H341 Carc. 2; H351 Aquatic Acute 1; H400 Aquatic Chronic 1; H410

< 0,1

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

: Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.

If inhaled

: If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician.

In case of skin contact

: If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes.

In case of eye contact

: Immediately flush eye(s) with plenty of water. Remove contact lenses.



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Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed

: Keep respiratory tract clear. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

Hazardous combustion products

: No data is available on the product itself.

5.3 Advice for firefighters

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

Specific extinguishing methods


Further information

: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions

: Use personal protective equipment.

6.2 Environmental precautions



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Environmental precautions

: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

None

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

: Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Hygiene measures

: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Electrical installations / working materials must comply with the technological safety standards.

Recommended storage temperature

: 2 - 40 °C

Other data

: No decomposition if stored and applied as directed.



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7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

1,4-dihydroxybenzene

123-31-9 TWA 0,5 mg/m3 GB EH40

Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health effects

Value

Bisphenol A epoxy resin

Workers Dermal Systemic effects, Short-term exposure

8,33 mg/kg bw/day

Workers Inhalation Systemic effects, Short-term exposure

12,25 mg/m3

Workers Dermal Systemic effects, Long-term exposure

8,33 mg/kg bw/day

Workers Inhalation Systemic effects, Long-term exposure

12,25 mg/m3

Consumers Dermal Systemic effects, Short-term exposure

3,571 mg/kg bw/day

Consumers Oral Systemic effects, Short-term exposure

0,75 mg/kg bw/day

Consumers Dermal Systemic effects, Long-term exposure

3,571 mg/kg bw/day

Consumers Oral Systemic effects, Long-term exposure

0,75 mg/kg bw/day

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value

Bisphenol A epoxy resin Fresh water 0,006 mg/l

Remarks: Assessment Factors

Marine water 0,0006 mg/l

Assessment Factors

Freshwater - intermittent 0,018 mg/l

Assessment Factors

Fresh water sediment 0,996 mg/kg

Equilibrium method



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Marine sediment 0,0996 mg/kg

Equilibrium method

Soil 0,196 mg/kg

Equilibrium method

Sewage treatment plant 10 mg/l

Assessment Factors

Secondary Poisoning 11 mg/kg

Fresh water 0,006 mg/l

Assessment Factors


Assessment Factors

Freshwater - intermittent 0,018 mg/l

Assessment Factors


Equilibrium method


Equilibrium method

Soil 0,196 mg/kg

Equilibrium method


Assessment Factors


Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol

Fresh water 0,003 mg/l

Assessment Factors


Assessment Factors

Intermittent use/release 0,0254 mg/l

Assessment Factors


Equilibrium method


Equilibrium method

Soil 0,237 mg/kg



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Equilibrium method


Assessment Factors

Siloxanes and Silicones, di-Me, reaction products with silica

Fresh water sediment > 100 mg/kg

Assessment Factors

Soil 23 mg/kg

Assessment Factors

8.2 Exposure controls

Engineering measures

Effective exhaust ventilation system

Personal protective equipment

Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.

Hand protectionMaterial : butyl-rubber Material : Ethyl Vinyl Alcohol Laminate (EVAL) Break through time : > 8 h Material : Nitrile rubber Material : Neoprene gloves Break through time : 10 - 480 min Remarks

: The suitability for a specific workplace should be discussed with the producers of the protective gloves. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : paste



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Colour

: beige

Odour

: slight

Odour Threshold


pH

: ca. 6 - 7 (25 °C) Concentration: 500 g/l

Freezing point


Melting point

No data is available on the product itself.

Boiling point

: > 200 °C

Flash point

: > 150 °C Method: Pensky-Martens closed cup, closed cup

Evaporation rate


Flammability (solid, gas)


Burning rate


Upper explosion limit


Lower explosion limit


Vapour pressure

: < 0,002 hPa (20 °C)

Relative vapour density


Relative density


Density

: 1,4 g/cm3 (25 °C)

Solubility(ies) Water solubility

: practically insoluble (20 °C)

Solubility in other solvents


Partition coefficient: n-octanol/water


Auto-ignition temperature


Decomposition temperature

: > 200 °C

Viscosity Viscosity, dynamic

: thixotropic



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Explosive properties


Oxidizing properties


9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

No decomposition if stored and applied as directed.

10.2 Chemical stability


10.3 Possibility of hazardous reactions

Hazardous reactions


10.4 Conditions to avoid

Conditions to avoid

: No data available

10.5 Incompatible materials

Materials to avoid

: Strong acids and strong bases Strong oxidizing agents

10.6 Hazardous decomposition products

Carbon oxides Burning produces noxious and toxic fumes.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity - Product

: Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method

Acute inhalation toxicity - Product

: Acute toxicity estimate : > 20 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method

Acute dermal toxicity - Product

: Acute toxicity estimate : > 2 000 mg/kg Method: Calculation method

Acute toxicity (other routes of administration)

: No data available



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Skin corrosion/irritation

Components:

Bisphenol A epoxy resin: Species: Rabbit Assessment: Mild skin irritant Method: OECD Test Guideline 404 Result: Irritating to skin. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Species: Rabbit Method: OECD Test Guideline 404 Result: Irritating to skin. Butanedioldiglycidyl ether: Species: Rabbit Method: OECD Test Guideline 404 Result: Skin irritation 1,4-dihydroxybenzene: Species: Rabbit Assessment: No skin irritation Result: No skin irritation

Serious eye damage/eye irritation

Components:

Bisphenol A epoxy resin: Species: Rabbit Assessment: Mild eye irritant Method: OECD Test Guideline 405 Result: Irritating to eyes. Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Species: Rabbit Method: OECD Test Guideline 405 Result: No eye irritation Butanedioldiglycidyl ether: Species: Rabbit Method: OECD Test Guideline 405 Result: Risk of serious damage to eyes. dipentaerythritol pentaacrylate: Result: Eye irritation 1,4-dihydroxybenzene: Assessment: Risk of serious damage to eyes. Result: Risk of serious damage to eyes.

Respiratory or skin sensitisation

Product:

Remarks: Causes sensitisation.



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Assessment: No data available

Germ cell mutagenicity

Components:

Bisphenol A epoxy resin: Genotoxicity in vitro

: Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive

: Concentration: 0 - 5000 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: positive

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Genotoxicity in vitro




Butanedioldiglycidyl ether: Genotoxicity in vitro


: Concentration: 1 - 100 µg/L Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: positive

bisphenol A - epoxy resins, number average MW >700 - <1100: Genotoxicity in vitro




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1,4-dihydroxybenzene: Genotoxicity in vitro

: Metabolic activation: with and without metabolic activation Result: positive

: Test Type: Ames test Test species: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative GLP: yes

: Test Type: Chromosome aberration test in vitro Test species: Human lymphocytes Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative GLP: yes

: Test Type: Chromosome aberration test in vitro Test species: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: positive

Components:

Bisphenol A epoxy resin: Genotoxicity in vivo

: Cell type: Germ Application Route: Oral Method: OECD Test Guideline 478 Result: negative

Cell type: Somatic Application Route: Oral Dose: 0 - 5000 mg/kg Method: OPPTS 870.5395 Result: negative

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Genotoxicity in vivo

: Cell type: Somatic Application Route: Oral Exposure time: 48 h



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Dose: 2000 mg/kg Method: OECD Test Guideline 474 Result: negative

Cell type: Somatic Application Route: Oral Dose: 2000 mg/kg Method: OECD Test Guideline 486 Result: negative

Butanedioldiglycidyl ether: Genotoxicity in vivo

: Test Type: In vivo micronucleus test Test species: Mouse Cell type: Somatic Application Route: Oral Exposure time: 4 d Dose: 187.5 - 750 mg/kg Method: OECD Test Guideline 474 Result: negative

Test Type: unscheduled DNA synthesis assay Test species: Rat Cell type: Liver cells Application Route: Oral Method: OECD Test Guideline 486 Result: negative

bisphenol A - epoxy resins, number average MW >700 - <1100: Genotoxicity in vivo

: Cell type: Germ Application Route: Oral Method: OECD Test Guideline 478 Result: negative

Cell type: Somatic Application Route: Oral Dose: 0 - 5000 mg/kg Method: OPPTS 870.5395 Result: negative

1,4-dihydroxybenzene: Genotoxicity in vivo

: Application Route: Intraperitoneal injection Method: OECD Test Guideline 483 Result: positive

Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: positive



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Application Route: Oral Exposure time: 10 Weeks Method: OECD Test Guideline 478 Result: negative

Components:

Bisphenol A epoxy resin: Germ cell mutagenicity- Assessment

: Weight of evidence does not support classification as a germ cell mutagen.

Butanedioldiglycidyl ether: Germ cell mutagenicity- Assessment

: Weight of evidence does not support classification as a germ cell mutagen.

bisphenol A - epoxy resins, number average MW >700 - <1100: Germ cell mutagenicity- Assessment

: Animal testing did not show any mutagenic effects.

1,4-dihydroxybenzene: Germ cell mutagenicity- Assessment

: In vitro tests showed mutagenic effects

Germ cell mutagenicity- Assessment

: No data available

Carcinogenicity

Components:

Bisphenol A epoxy resin: Species: Rat, (male and female) Application Route: Oral Exposure time: 24 month(s) Dose: 15 mg/kg Frequency of Treatment: 7 days/week Method: OECD Test Guideline 453 Result: negative Species: Mouse, (male) Application Route: Dermal Exposure time: 24 month(s) Dose: 0.1 mg/kg Frequency of Treatment: 3 days/week Method: OECD Test Guideline 453 Result: negative Species: Rat, (female)



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Application Route: Dermal Exposure time: 24 month(s) Dose: 1 mg/kg Frequency of Treatment: 5 days/week Method: OECD Test Guideline 453 Result: negative bisphenol A - epoxy resins, number average MW >700 - <1100: Species: Rat, (male and female) Application Route: Oral Exposure time: 24 month(s) Dose: 15 mg/kg Frequency of Treatment: 7 daily Method: OECD Test Guideline 453 Result: negative Species: Mouse, (male) Application Route: Dermal Exposure time: 24 month(s) Dose: .1 mg/kg Frequency of Treatment: 3 daily Method: OECD Test Guideline 453 Result: negative Species: Rat, (female) Application Route: Dermal Exposure time: 24 month(s) Dose: 1 mg/kg Frequency of Treatment: 5 daily Method: OECD Test Guideline 453 Result: negative 1,4-dihydroxybenzene: Species: Rat Application Route: Oral Exposure time: 103 weeks Frequency of Treatment: 5 daily Method: OECD Test Guideline 453 Result: positive Species: Mouse Application Route: Oral Exposure time: 103 weeks Frequency of Treatment: 5 daily Method: OECD Test Guideline 453 Result: positive

Components:

bisphenol A - epoxy resins, number average MW >700 - <1100: Carcinogenicity - Assessment

: Animal testing did not show any carcinogenic effects.

1,4-dihydroxybenzene:



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Carcinogenicity - Assessment

: Limited evidence of carcinogenicity in animal studies

Reproductive toxicity

Components:

Bisphenol A epoxy resin: Effects on fertility : Test Type: Two-generation study

Species: Rat, male and female Application Route: Oral Dose: >750 milligram per kilogram General Toxicity - Parent: No-observed-effect level: 540 mg/kg body weight General Toxicity F1: No-observed-effect level: 540 mg/kg body weight Symptoms: No adverse effects Method: OECD Test Guideline 416 Result: No effects on fertility and early embryonic development were detected.

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Species: Rat, male and female

Application Route: Oral Method: OECD Test Guideline 416 Result: No effects on fertility and early embryonic development were detected.

bisphenol A - epoxy resins, number average MW >700 - <1100: Species: Rat, male and female


1,4-dihydroxybenzene: Species: Rat

Application Route: Oral Method: EPA OTS 798.4100

Components:

Bisphenol A epoxy resin: Effects on foetal development

: Species: Rabbit, female Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 30 mg/kg body weight Method: Other guidelines Result: No teratogenic effects Species: Rabbit, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 60 mg/kg body weight Method: OECD Test Guideline 414



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Result: No teratogenic effects Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 180 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol:

Species: Rabbit, female Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 30 mg/kg body weight Result: No teratogenic effects

bisphenol A - epoxy resins, number average MW >700 - <1100:

Species: Rabbit, female Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 30 mg/kg body weight Method: Other guidelines Result: No teratogenic effects Species: Rabbit, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 60 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 180 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects


Species: Rat Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 100 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects Species: Rabbit Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 25 mg/kg body weight Method: EPA OTS 798.4900 Result: No teratogenic effects



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Components:

bisphenol A - epoxy resins, number average MW >700 - <1100: Reproductive toxicity - Assessment

: No evidence of adverse effects on sexual function and fertility, or on development, based on animal experiments.

STOT - single exposure

No data available

STOT - repeated exposure

No data available

Repeated dose toxicity

Components:

Bisphenol A epoxy resin: Species: Rat, male and female NOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 14 WeeksNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male and female NOEL: 10 mg/kg Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity Species: Mouse, male NOAEL: 100 mg/kg Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 3 d Method: Subchronic toxicity Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Species: Rat, male and female NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 13 WeeksNumber of exposures: 7 d Method: Subchronic toxicity Butanedioldiglycidyl ether: Species: Rat, male and female NOAEL: 200 mg/kg Application Route: Ingestion Exposure time: 28 dNumber of exposures: 7 d Method: Subacute toxicity bisphenol A - epoxy resins, number average MW >700 - <1100: Species: Rat, male and female NOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 14 WeeksNumber of exposures: 7 d



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Method: Subchronic toxicity Species: Rat, male and female NOEL: 10 mg/kg Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity 1,4-dihydroxybenzene: Species: Mouse LOAEL: 100 Application Route: Ingestion Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity Species: Rat LOAEL: 100 Application Route: Ingestion Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity Species: Rat NOAEL: 109,6 Application Route: Skin contact Exposure time: 13 WeeksNumber of exposures: 5 d Method: Subchronic toxicity Repeated dose toxicity - Assessment

: No data available

Aspiration toxicity

No data available

Experience with human exposure

General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available

Ingestion: No data available



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Toxicology, Metabolism, Distribution

No data available

Neurological effects

No data available

Further information


SECTION 12: Ecological information

12.1 Toxicity

Components:

Bisphenol A epoxy resin:

Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 1,5 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 203

Toxicity to daphnia and other aquatic invertebrates

: EC50 (Daphnia magna (Water flea)): 2,7 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water

Toxicity to algae

: EC50 (Selenastrum capricornutum (green algae)): 9,4 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: EPA-660/3-75-009

Toxicity to microorganisms

: IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: NOEC: 0,3 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211


Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 0,55 mg/l Exposure time: 96 h Test Type: semi-static test



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Test substance: Fresh water Method: OECD Test Guideline 203


: EC50 (Daphnia magna (Water flea)): 1,6 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202

Toxicity to algae

: EC50 (Selenastrum capricornutum (green algae)): 1,8 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201

M-Factor (Acute aquatic toxicity)

: 1


: IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water


: NOEC: 0,3 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 211

Ecotoxicology Assessment Acute aquatic toxicity

: This product has no known ecotoxicological effects.

Chronic aquatic toxicity

: Toxic to aquatic life with long lasting effects.

Butanedioldiglycidyl ether:

Toxicity to fish

: LC50 (Brachydanio rerio (zebrafish)): 24 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 203


: EC50 (Daphnia magna (Water flea)): 75 mg/l Exposure time: 24 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 202

Toxicity to algae

: EL50 : > 160 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201



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: IC50 (activated sludge): > 100 mg/l Exposure time: 3 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 209


Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 0,638 mg/l Exposure time: 96 h Test Type: flow-through test Method: OECD Test Guideline 203


: EC50 (Daphnia magna (Water flea)): 0,134 mg/l Exposure time: 48 h Test Type: semi-static test Method: OECD Test Guideline 202 GLP: yes

Toxicity to algae

: ErC50 (Selenastrum capricornutum (green algae)): 0,33 mg/l Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 GLP: yes


: 10


: IC50 (activated sludge): 71 mg/l Exposure time: 2 h GLP:


: NOEC: 0,0057 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Method: OECD Test Guideline 211 GLP: yes

12.2 Persistence and degradability

Components:

Bisphenol A epoxy resin:

Biodegradability

: Inoculum: Sewage (STP effluent) Concentration: 20 mg/l Result: Not readily biodegradable. Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301F

Stability in water

: Degradation half life (DT50): 4,83 d (25 °C) pH: 4 Method: OECD Test Guideline 111 Remarks: Fresh water



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Degradation half life (DT50): 7,1 d (25 °C) pH: 9 Method: OECD Test Guideline 111 Remarks: Fresh water



Biodegradability

: Inoculum: activated sludge Concentration: 3 mg/l Result: Not readily biodegradable. Biodegradation: ca. 0 % Exposure time: 28 d Method: Directive 67/548/EEC Annex V, C.4.E.


Biodegradability

: Inoculum: activated sludge Concentration: 20 mg/l Result: Not readily biodegradable. Biodegradation: 43 % Exposure time: 28 d Method: OECD Test Guideline 301F

bisphenol A - epoxy resins, number average MW >700 - <1100:

Biodegradability

: Inoculum: Sewage (STP effluent) Concentration: 20 mg/l Result: Not readily biodegradable. Biodegradation: 5 % Exposure time: 28 d Method: OECD Test Guideline 301F

Stability in water

: Degradation half life (DT50): 4,83 d (25 °C) pH: 4 Method: OECD Test Guideline 111 Remarks: Fresh water




Biodegradability

: Test Type: aerobic Inoculum: activated sludge



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Concentration: 100 mg/l Result: Readily biodegradable. Biodegradation: 70 % Exposure time: 14 d Method: OECD Test Guideline 301C

12.3 Bioaccumulative potential

Components:

Bisphenol A epoxy resin: Bioaccumulation

: Bioconcentration factor (BCF): 31 Remarks: Does not bioaccumulate.


: log Pow: 3,242 (25 °C) pH: 7,1 Method: OECD Test Guideline 117

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Bioaccumulation

: Species: Fish Bioconcentration factor (BCF): 150 Remarks: Does not bioaccumulate.


: log Pow: 2,7 - 3,6 Method: OECD Test Guideline 117

Butanedioldiglycidyl ether: Partition coefficient: n-octanol/water

: log Pow: -0,269 (25 °C) pH: 6,7 Method: OECD Test Guideline 117

bisphenol A - epoxy resins, number average MW >700 - <1100: Bioaccumulation

: Species: Fish Bioconcentration factor (BCF): 31 Remarks: Does not bioaccumulate.

1,4-dihydroxybenzene: Bioaccumulation

: Bioconcentration factor (BCF): 3,16


: log Pow: 0,59

12.4 Mobility in soil

Components:

Bisphenol A epoxy resin: Distribution among environmental compartments

: Koc: 445

Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol: Distribution among environmental compartments

: Koc: 4460 Method: OECD Test Guideline 121




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Distribution among environmental compartments

: Koc: 12,59 Method: OECD Test Guideline 121

bisphenol A - epoxy resins, number average MW >700 - <1100: Distribution among environmental compartments

: Koc: 445

12.5 Results of PBT and vPvB assessment

Product:

Assessment

: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher..

12.6 Other adverse effects

Product:

Additional ecological information

: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Toxic to aquatic life with long lasting effects.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.

SECTION 14: Transport information

IATA 14.1 UN number : UN 3082

14.2 UN proper shipping name

: Environmentally hazardous substance, liquid, n.o.s.

(BISPHENOL A EPOXY RESIN, BISPHENOL F EPOXY RESIN)

14.3 Transport hazard class(es)

: 9

14.4 Packing group : III

Labels : Miscellaneous

Packing instruction (cargo aircraft)

: 964



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Packing instruction (passenger aircraft)

: 964

IMDG 14.1 UN number : UN 3082


: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.



: 9

14.4 Packing group : III Labels : 9 EmS Code : F-A, S-F 14.5 Environmental hazards Marine pollutant : yes

ADR 14.1 UN number : UN 3082





: 9

14.4 Packing group : III Labels : 9 14.5 Environmental hazards Environmentally hazardous : yes

RID 14.1 UN number : UN 3082





: 9

14.4 Packing group : III Labels : 9 14.5 Environmental hazards Environmentally hazardous : yes

Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACH - Candidate List of Substances of Very High : This product does not contain



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Concern for Authorisation (Article 59).

substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57).

Other regulations:

Take note of Directive 94/33/EC on the protection of young people at work or stricter national regulations, where applicable.

The components of this product are reported in the following inventories:

DSL

: This product contains one or several components listed in the Canadian NDSL.

AICS

: On the inventory, or in compliance with the inventory

NZIoC


ENCS

: Not in compliance with the inventory

KECI


PICCS


IECSC


TCSI


TSCA


Inventories

AICS (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (United States of America (USA))

15.2 Chemical safety assessment

SECTION 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed. H312 : Harmful in contact with skin. H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H318 : Causes serious eye damage.



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H319 : Causes serious eye irritation. H332 : Harmful if inhaled. H341 : Suspected of causing genetic defects. H351 : Suspected of causing cancer. H400 : Very toxic to aquatic life. H410 : Very toxic to aquatic life with long lasting effects. H411 : Toxic to aquatic life with long lasting effects. H412 : Harmful to aquatic life with long lasting effects.

Full text of other abbreviations

Acute Tox. : Acute toxicity Aquatic Acute : Acute aquatic toxicity Aquatic Chronic : Chronic aquatic toxicity Carc. : Carcinogenicity Eye Dam. : Serious eye damage Eye Irrit. : Eye irritation Muta. : Germ cell mutagenicity Skin Irrit. : Skin irritation Skin Sens. : Skin sensitisation

Further information

Classification of the mixture: Classification procedure:

Skin Irrit. 2 H315 Calculation method

Eye Dam. 1 H318 Calculation method

Skin Sens. 1 H317 Calculation method

Aquatic Chronic 2 H411 Calculation method

While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.



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NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.


ARALDITE® 2015 GB HARDENER

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SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name

: ARALDITE® 2015 GB HARDENER

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture

: Hardener

1.3 Details of the supplier of the safety data sheet

Company : Huntsman Advanced Materials (Europe)BVBA Address : Everslaan 45

3078 Everberg Belgium

Telephone : +41 61 299 20 41 Telefax : +41 61 299 20 40 E-mail address of person responsible for the SDS

: [email protected]

1.4 Emergency telephone number

Emergency telephone number : EUROPE: +32 35 75 1234 France ORFILA: +33(0)145425959 ASIA: +65 6336-6011 China: +86 20 39377888 +86 532 83889090 India: + 91 22 42 87 5333 Australia: 1800 786 152 New Zealand: 0800 767 437 USA: +1/800/424.9300

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture


Acute toxicity, Category 4

H332: Harmful if inhaled.

Skin corrosion, Category 1B

H314: Causes severe skin burns and eye damage.

Skin sensitisation, Category 1

H317: May cause an allergic skin reaction.

Chronic aquatic toxicity, Category 2

H411: Toxic to aquatic life with long lasting effects.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)



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Hazard pictograms

:

Signal word

: Danger

Hazard statements

: H332 Harmful if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects.

Precautionary statements

: Prevention: P261 Avoid breathing mist or vapours. P280 Wear protective gloves/ protective clothing/

eye protection/ face protection. P273 Avoid release to the environment. Response: P301 IF SWALLOWED: P310 Immediately call a POISON

CENTER/doctor. P331 Do NOT induce vomiting. P303 + P361 + P353 + P310 IF ON SKIN (or hair): Take off

immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER/doctor.

P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.

Hazardous components which must be listed on the label:

2-propenenitrile polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated Diethylenetriamine Aminoethylpiperazine 2,4,6-tris(dimethylaminomethyl)phenol

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.2 Mixtures

Hazardous components



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Chemical name CAS-No. EC-No. Registration number


Concentration

(% w/w)

2-Propenenitrile, polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated

68683-29-4

Skin Sens. 1; H317 Skin Irrit. 2; H315

13 - 30

Bis(isopropyl)naphthalene 38640-62-9 254-052-6 -

Asp. Tox. 1; H304 Aquatic Chronic 1; H410

7 - 13

2,2'-Iminodi(ethylamine) 111-40-0 203-865-4 01-2119473793-27

Acute Tox. 4; H302 Acute Tox. 2; H330 Acute Tox. 4; H312 Skin Corr. 1B; H314 Eye Dam. 1; H318 Skin Sens. 1; H317 STOT SE 3; H335

3 - 7

2-Piperazin-1-ylethylamine 140-31-8 205-411-0 01-2119471486-30

Acute Tox. 4; H302 Acute Tox. 3; H311 Skin Corr. 1B; H314 Eye Dam. 1; H318 Skin Sens. 1; H317 Aquatic Chronic 3; H412

1 - 3

2,4,6-Tris(dimethylaminomethyl)phenol

90-72-2 202-013-9 01-2119560597-27

Acute Tox. 4; H302 Skin Corr. 1C; H314 Eye Dam. 1; H318 Aquatic Chronic 3; H412 Skin Sens. 1B; H317

1 - 3

4,4'-Isopropylidenediphenol 80-05-7 201-245-8 01-2119457856-23

Eye Dam. 1; H318 Skin Sens. 1; H317 Repr. 2; H361f STOT SE 3; H335 Aquatic Chronic 2; H411

0.1 - 1

Amines, polyethylenepoly-, triethylenetetramine fraction

90640-67-8 01-2119487919-13

Acute Tox. 4; H302 Acute Tox. 4; H312 Skin Corr. 1B; H314 Skin Sens. 1; H317 Aquatic Chronic 3; H412

0.1 - 1

For explanation of abbreviations see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice

: Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended.



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If inhaled

: Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice.

In case of skin contact

: Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty. If on skin, rinse well with water. If on clothes, remove clothes.

In case of eye contact

: Small amounts splashed into eyes can cause irreversible tissue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist.

If swallowed

: Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital.

4.2 Most important symptoms and effects, both acute and delayed

None known.

4.3 Indication of any immediate medical attention and special treatment needed

Treatment

: Symptomatic and supportive therapy as needed. Following severe exposure medical follow-up should be monitored for at least 48 hours.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media

: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

: High volume water jet

5.2 Special hazards arising from the substance or mixture

Specific hazards during : Do not allow run-off from fire fighting to enter drains or water



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firefighting

courses.

Hazardous combustion products


5.3 Advice for firefighters

Special protective equipment for firefighters

: Wear self-contained breathing apparatus for firefighting if necessary.

Specific extinguishing methods


Further information

: Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions

: Use personal protective equipment. Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions

: Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up

: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

None

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

: Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms.



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To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Persons susceptible to skin sensitisation problems or asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Hygiene measures

: When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Keep container tightly closed in a dry and well-ventilated place. Observe label precautions. Electrical installations / working materials must comply with the technological safety standards.

Other data


7.3 Specific end use(s)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Occupational Exposure Limits

Components CAS-No. Value type (Form of exposure)

Control parameters Basis

Diethylenetriamine 111-40-0 TWA 1 ppm 4.3 mg/m3

GB EH40

Further information Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity., Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used

4,4'-isopropylidenediphenol

80-05-7 TWA (inhalable dust)

10 mg/m3 GB EH40

Further information Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used

TWA (inhalable dust)

10 mg/m3 2009/161/EU

Further information Indicative

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health effects

Value

Diethylenetriamine Workers Inhalation Systemic effects, Short-term exposure

92.1 mg/m3



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Workers Inhalation Local effects, Short-term exposure

2.6 mg/m3


11.4 mg/kg bw/day


15.4 mg/m3

Workers Dermal Local effects, Long-term exposure

1.1 mg/cm2

Workers Inhalation Local effects, Long-term exposure

0.87 mg/m3

Consumers Oral Local effects, Short-term exposure

4.88 mg/kg bw/day

Consumers Inhalation Systemic effects, Short-term exposure

27.5 mg/m3


4.88 mg/kg bw/day

Consumers Inhalation Systemic effects, Long-term exposure

4.6 mg/m3

naphthalene, bis(1-methylethyl)-


30 mg/m3


4.3 mg/kg bw/day


7.4 mg/m3


2.1 mg/kg bw/day


2.1 mg/kg bw/day

Aminoethylpiperazine Workers Dermal Systemic effects, Short-term exposure

20 mg/kg bw/day

Workers Dermal Local effects, Short-term exposure

0.04 mg/cm2


3.3 mg/kg bw/day


3.6 mg/m3


0.006 mg/cm2


1.7 mg/kg bw/day


5.3 mg/m3


0.3 mg/kg bw/day

Consumers Dermal Local effects, Short-term exposure

0.02 mg/cm2

Consumers Dermal Systemic effects, 10 mg/kg



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Short-term exposure bw/day


0.9 mg/m3


1.5 mg/kg bw/day

Workers Inhalation Systemic effects, Short-term exposure

21.4 mg/m3

Consumers Dermal Local effects, Long-term exposure

0.003 mg/cm2

2,4,6-tris(dimethylaminomethyl)phenol


0.31 mg/m3

triethylenetetramine Workers Inhalation Systemic effects, Short-term exposure

5380 mg/m3


0.57 mg/kg bw/day


1 mg/m3


0.028 mg/m3

Consumers Dermal Systemic effects, Short-term exposure

8 mg/kg bw/day


1600 mg/m3


20 mg/kg bw/day


1 mg/cm2


0.25 mg/kg bw/day


0.29 mg/m3


0.41 mg/kg bw/day

Consumers Dermal Local effects, Long-term exposure

0.43 mg/cm2

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value

Diethylenetriamine Fresh water 0.56 mg/l

Remarks: Assessment Factors

Marine water 0.056 mg/l

Assessment Factors

Fresh water sediment 1072 mg/kg

Equilibrium method



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Marine sediment 107.2 mg/kg

Equilibrium method

Soil 7.97 mg/kg

Equilibrium method, Assessment Factors

Freshwater - intermittent 0.32 mg/l

Assessment Factors

naphthalene, bis(1-methylethyl)- Fresh water 0.26 µg/l

Assessment Factors

Marine water 0.026 µg/l

Assessment Factors

Sewage treatment plant 0.15 mg/l

Assessment Factors

Fresh water sediment 0.94 mg/kg

Equilibrium method


Equilibrium method

Soil 0.1872 mg/kg

Equilibrium method


Assessment Factors

Aminoethylpiperazine Fresh water 0.058 mg/l

Assessment Factors


Assessment Factors


Assessment Factors

Fresh water sediment 215 mg/kg

Equilibrium method


Equilibrium method

Soil 42.9 mg/kg

Equilibrium method


Assessment Factors



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2,4,6-tris(dimethylaminomethyl)phenol

Fresh water 0.084 mg/l

Assessment Factors


Assessment Factors


Assessment Factors


Assessment Factors

triethylenetetramine Fresh water 190 µg/l

Assessment Factors

Fresh water sediment 95.9 mg/kg

Equilibrium method

Marine water 38 µg/l

Assessment Factors

Freshwater - intermittent 200 µg/l

Assessment Factors


Equilibrium method

Soil 19.1 mg/kg

Equilibrium method


Assessment Factors

Secondary Poisoning 0.18 mg/kg

Assessment Factors

8.2 Exposure controls

Engineering measures

Effective exhaust ventilation system

Personal protective equipment

Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems.

Hand protectionMaterial : butyl-rubber Material : Ethyl Vinyl Alcohol Laminate (EVAL) Break through time : > 8 h



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Material : Nitrile rubber Break through time : 10 - 480 min Remarks

: The suitability for a specific workplace should be discussed with the producers of the protective gloves. Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).

Skin and body protection : Impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Respiratory protection : Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines.

Filter type : Combined particulates and organic vapour type (A-P)

No personal respiratory protective equipment normally required.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance

: paste

Colour

: light cream

Odour

: amine-like

Boiling point

: > 200 °C

Flash point

: > 100 °C Method: Pensky-Martens closed cup, closed cup

Vapour pressure

: < 0.49 hPa (20 °C)

Density

: 1.4 g/cm3 (25 °C)

Solubility(ies) Water solubility

: practically insoluble (20 °C)

Decomposition temperature

: > 200 °C

Viscosity Viscosity, dynamic

: thixotropic



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9.2 Other information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity


10.2 Chemical stability


10.3 Possibility of hazardous reactions

Hazardous reactions


10.4 Conditions to avoid

Conditions to avoid

: No data available

10.5 Incompatible materials

Materials to avoid

: Strong acids and strong bases Strong oxidizing agents

10.6 Hazardous decomposition products

Burning produces noxious and toxic fumes. Carbon oxides Nitrogen oxides (NOx)

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity - Product

: Acute toxicity estimate : > 2,000 mg/kg Method: Calculation method

Acute inhalation toxicity - Product

: Acute toxicity estimate : 3.12 mg/l Exposure time: 4 h Test atmosphere: dust/mist Method: Calculation method

Acute dermal toxicity - Product

: Acute toxicity estimate : > 2,000 mg/kg Method: Calculation method

Acute toxicity (other routes of administration)

: No data available

Skin corrosion/irritation

Components:



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2-propenenitrile polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated: Species: Rabbit Assessment: Moderate skin irritant Result: Irritating to skin. Diethylenetriamine: Species: Rabbit Result: Causes burns. Aminoethylpiperazine: Species: Rabbit Result: Causes burns. 2,4,6-tris(dimethylaminomethyl)phenol: Species: Rabbit Method: OECD Test Guideline 404 Result: Corrosive after 1 to 4 hours of exposure 4,4'-isopropylidenediphenol: Species: Rabbit Method: OECD Test Guideline 404 Result: No skin irritation Triethylenetetramine: Species: Rabbit Method: OECD Test Guideline 405 Result: Corrosive after 3 minutes to 1 hour of exposure

Serious eye damage/eye irritation

Product:

Remarks: May cause irreversible eye damage.

Respiratory or skin sensitisation

Components:

2-propenenitrile polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. naphthalene, bis(1-methylethyl)-: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: Does not cause skin sensitisation. Diethylenetriamine: Exposure routes: Skin Species: Mouse



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Method: OECD Test Guideline 429 Result: May cause sensitisation by skin contact. Remarks: Causes sensitisation. Exposure routes: Respiratory Tract Species: Mouse Result: Does not cause respiratory sensitisation. Aminoethylpiperazine: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. 2,4,6-tris(dimethylaminomethyl)phenol: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: negative Assessment: The product is a skin sensitiser, sub-category 1B. Result: The product is a skin sensitiser, sub-category 1B. 4,4'-isopropylidenediphenol: Exposure routes: Skin Species: Mouse Method: OECD Test Guideline 429 Result: Does not cause skin sensitisation. Exposure routes: Skin Species: Humans Assessment: May cause sensitisation by skin contact. Result: Causes sensitisation. Triethylenetetramine: Exposure routes: Skin Species: Guinea pig Method: OECD Test Guideline 406 Result: May cause sensitisation by skin contact. Assessment: No data available

Germ cell mutagenicity

Components:

naphthalene, bis(1-methylethyl)-: Genotoxicity in vitro

: Concentration: 92 mg/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative

: Concentration: 40 - 60 mg/ml



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Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative

Aminoethylpiperazine: Genotoxicity in vitro

: Concentration: 5000 ug/plate Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative

: Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative

: Metabolic activation: negative Method: OECD Test Guideline 482 Result: negative

2,4,6-tris(dimethylaminomethyl)phenol: Genotoxicity in vitro



: Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative

4,4'-isopropylidenediphenol: Genotoxicity in vitro

: Metabolic activation: with and without metabolic activation Result: negative

Triethylenetetramine: Genotoxicity in vitro

: Concentration: 0 - 200 µg/L Metabolic activation: negative Method: OECD Test Guideline 482 Result: negative

Components:



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naphthalene, bis(1-methylethyl)-: Genotoxicity in vivo

: Application Route: Intraperitoneal injection Dose: 1.92 g/kg Method: OECD Test Guideline 474 Result: negative

Diethylenetriamine: Genotoxicity in vivo

: Cell type: Somatic Application Route: Oral Dose: 85 - 850 mg/kg Method: OECD Test Guideline 474 Result: negative

Application Route: Oral Result: negative

Aminoethylpiperazine: Genotoxicity in vivo

: Application Route: Intraperitoneal injection Dose: 175 - 560 mg/kg Method: OECD Test Guideline 474 Result: negative

4,4'-isopropylidenediphenol: Genotoxicity in vivo

: Method: OECD Test Guideline 474 Result: negative

Triethylenetetramine: Genotoxicity in vivo

: Application Route: Intraperitoneal injection Dose: 0 - 600 mg/kg Method: OECD Test Guideline 474 Result: negative

Carcinogenicity

Components:

Diethylenetriamine: Species: Mouse, (male) Application Route: Dermal Dose: 56.3 mg/kg Frequency of Treatment: 3 daily Result: negative 4,4'-isopropylidenediphenol: Species: Rat, (male and female) Application Route: Oral Exposure time: 103 weeks Frequency of Treatment: 7 daily Result: negative



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Triethylenetetramine: Species: Mouse, (male) Application Route: Dermal Dose: 42 mg/kg Frequency of Treatment: 3 daily Method: OECD Test Guideline 451 Result: negative Carcinogenicity - Assessment

: No data available

Reproductive toxicity

Components:

Diethylenetriamine: Effects on fertility : Species: Rat, male and female

Application Route: Oral General Toxicity - Parent: No observed adverse effect level: 30 mg/kg wet weight Method: OECD Test Guideline 421

Aminoethylpiperazine: Species: Rat, male and female


2,4,6-tris(dimethylaminomethyl)phenol: Species: Rat, male and female

Application Route: Oral Method: OECD Test Guideline 422 Remarks: No significant adverse effects were reported

4,4'-isopropylidenediphenol: Species: Rat, male and female

Application Route: Oral Method: OECD Test Guideline 416 Result: Embryotoxic effects and adverse effects on the offspring were detected.

Components:

naphthalene, bis(1-methylethyl)-: Effects on foetal development

: Species: Rat, female Application Route: Oral General Toxicity Maternal: Lowest observed adverse effect level: 250 mg/kg body weight Method: Directive 67/548/EEC, Annex V, B.31. Result: No teratogenic effects

Diethylenetriamine: Species: Rat



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Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 100 mg/kg body weight Method: OECD Test Guideline 421

Aminoethylpiperazine:

Species: Rat, male and female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: 224 - 285 mg/kg body weight Method: OECD Test Guideline 422 Result: No teratogenic effects

4,4'-isopropylidenediphenol:

Species: Rat, female Application Route: Oral General Toxicity Maternal: No observed adverse effect level: < 160 mg/kg body weight Method: OECD Test Guideline 416 Result: No teratogenic effects

Triethylenetetramine:

Species: Rat Application Route: Oral General Toxicity Maternal: No observed adverse effect level: > 750 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects Species: Rabbit Application Route: Dermal General Toxicity Maternal: No observed adverse effect level: 125 mg/kg body weight Method: OECD Test Guideline 414 Result: No teratogenic effects

Components:

4,4'-isopropylidenediphenol: Reproductive toxicity - Assessment

: Some evidence of adverse effects on sexual function and fertility, and/or on development, based on animal experiments.

STOT - single exposure

Components:

Diethylenetriamine: Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. 4,4'-isopropylidenediphenol: Assessment: The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with respiratory tract irritation.



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STOT - repeated exposure

No data available

Repeated dose toxicity

Components:

naphthalene, bis(1-methylethyl)-: Species: Rat, male and female NOAEL: 170 mg/kg Application Route: Ingestion Exposure time: 4,320 hNumber of exposures: 7 d Method: Subchronic toxicity Diethylenetriamine: Species: Rat, male and female : 70 - 80 Application Route: Ingestion Test atmosphere: vapour Exposure time: 360 hNumber of exposures: 7 d Method: Subchronic toxicity Species: Rat, male and female NOAEL: 114 Application Route: Skin contact Exposure time: 9,600 hNumber of exposures: 6 d Method: Chronic toxicity Aminoethylpiperazine: Species: Rat, male and female NOAEL: 151 - 285 Application Route: Ingestion Exposure time: 672 hMethod: Subacute toxicity Species: Rat, male and female NOAEL: > 1000 Application Route: Skin contact Exposure time: 696 hNumber of exposures: 5 d Method: Subacute toxicity 2,4,6-tris(dimethylaminomethyl)phenol: Species: Rat, male and female NOEL: 15 mg/kg Application Route: Ingestion Exposure time: 1,032 hNumber of exposures: 7 d Method: Subacute toxicity 4,4'-isopropylidenediphenol: Species: Dog, male and female : 75 mg/kg, 10 Application Route: Ingestion Test atmosphere: dust/mist Exposure time: 2,160 hNumber of exposures: 7 d



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Method: Subchronic toxicity Species: Rat, male and female LOAEL: 600 mg/kg Application Route: Ingestion Exposure time: 672 hNumber of exposures: 7 d Method: Subchronic toxicity Triethylenetetramine: Species: Rat, male and female NOAEL: 50 mg/kg Application Route: Ingestion Exposure time: 26 WeeksNumber of exposures: 7 d Method: Subchronic toxicity Repeated dose toxicity - Assessment

: No data available

Aspiration toxicity

No data available

Experience with human exposure

General Information: No data available

Inhalation: No data available

Skin contact: No data available

Eye contact: No data available


Toxicology, Metabolism, Distribution

No data available

Neurological effects

No data available

Further information




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SECTION 12: Ecological information

12.1 Toxicity

Components:

2-propenenitrile polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated:


: EC50 (Daphnia magna (Water flea)): 1,000 mg/l Exposure time: 48 h Method: OECD Test Guideline 202

Toxicity to algae

: EC50 (No information available.): > 1,000 mg/l Exposure time: 72 h Method: OECD Test Guideline 201

naphthalene, bis(1-methylethyl)-:

Toxicity to fish

: LC50 : > 0.5 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1. Remarks: Aquatic toxicity is unlikely due to low solubility.


: EC50 : > 0.16 mg/l Exposure time: 48 h Test Type: static test Test substance: Marine water Method: OECD Test Guideline 202 Remarks: Aquatic toxicity is unlikely due to low solubility.

EL50 (Daphnia magna (Water flea)): 1.7 mg/l Exposure time: 48 h Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 202

Toxicity to algae

: NOECr (Desmodesmus subspicatus (Scenedesmus subspicatus)): ca. 0.15 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Remarks: Aquatic toxicity is unlikely due to low solubility.


: 1


: NOEC: 0.013 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water



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Method: OECD Test Guideline 202

Diethylenetriamine:

Toxicity to fish

: LC50 : 430 mg/l Exposure time: 96 h Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.1.


: EC50 (Daphnia magna (Water flea)): 32 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water

Toxicity to algae

: EbC50 (Selenastrum capricornutum (green algae)): 1,164 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201

Toxicity to fish (Chronic toxicity)

: NOEC: 10 mg/l Exposure time: 28 d Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 210


: NOEC: 5.6 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.20

Toxicity to soil dwelling organisms

: EC50: > 1,000 mg/kg Exposure time: 56 d Species: Eisenia fetida (earthworms) Method: OECD Test Guideline 222




Toxicity to fish

: LC50 : 2,190 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water


: EC50 (Daphnia magna (Water flea)): 58 mg/l Exposure time: 48 h Test Type: static test



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Method: OECD Test Guideline 202 Remarks: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Toxicity to algae

: EC50 (Selenastrum capricornutum (green algae)): > 1,000 mg/l Exposure time: 72 h Test substance: Fresh water Method: OECD Test Guideline 201

2,4,6-tris(dimethylaminomethyl)phenol:

Toxicity to fish

: LC50 (Cyprinus carpio (Carp)): 175 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water


: LC50 : 718 mg/l Exposure time: 96 h Test Type: static test Test substance: Marine water

Toxicity to algae

: ErC50 (Desmodesmus subspicatus (Scenedesmus subspicatus)): 84 mg/l Exposure time: 72 h Test Type: static test Test substance: Fresh water Method: OECD Test Guideline 201

Ecotoxicology Assessment Chronic aquatic toxicity



Toxicity to fish

: LC50 (Oncorhynchus mykiss (rainbow trout)): 7.5 mg/l Exposure time: 96 h


: EC50 : 3.9 - 10.2 mg/l Exposure time: 48 h

(Ceriodaphnia dubia (Water flea)):

Toxicity to algae

: EC50 (Selenastrum capricornutum (green algae)): 2.5 - 3.1 mg/l Exposure time: 96 h

Toxicity to fish (Chronic toxicity)

: NOEC: 0.016 mg/l Exposure time: 444 d Species: Pimephales promelas (fathead minnow) Test Type: flow-through test Test substance: Fresh water Method: EPA OPPTS 850.1500 Remarks: Toxic to aquatic organisms.

Ecotoxicology Assessment



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Chronic aquatic toxicity

: Toxic to aquatic life with long lasting effects.


Toxicity to fish

: LC50 (Pimephales promelas (fathead minnow)): 330 mg/l Exposure time: 96 h Test Type: static test Test substance: Fresh water Method: EPA OTS 797.1400


: EC50 (Daphnia magna (Water flea)): 31.1 mg/l Exposure time: 48 h Test Type: static test Test substance: Fresh water Method: Directive 67/548/EEC, Annex V, C.2.

Toxicity to algae

: ErC50 (Selenastrum capricornutum (green algae)): 20 mg/l Exposure time: 72 h Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 201

Toxicity to bacteria

: EC50 (activated sludge): 800 mg/l Exposure time: 0.5 h Test Type: static test Test substance: Fresh water


: EC10: 1.9 mg/l Exposure time: 21 d Species: Daphnia magna (Water flea) Test Type: semi-static test Test substance: Fresh water Method: OECD Test Guideline 202



12.2 Persistence and degradability

Components:

2-propenenitrile polymer with 1,3-butadiene, 1-cyano-1-methyl-4-oxo-4-[[2-(1-piperazinyl)ethyl]amino]butyl-terminated:

Biodegradability

: Result: Not readily biodegradable.

naphthalene, bis(1-methylethyl)-:

Biodegradability

: Inoculum: activated sludge Concentration: 0.2 mg/l Result: Not readily biodegradable. Biodegradation: 30 - 35 % Exposure time: 56 d Method: OECD Test Guideline 310

Diethylenetriamine:

Biodegradability : Inoculum: activated sludge



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Result: Readily biodegradable Biodegradation: 87 % Exposure time: 21 d Method: OECD Test Guideline 301D

Photodegradation

: Test Type: Air Rate constant: 500000 Degradation (direct photolysis): 50 %


Biodegradability

: Inoculum: activated sludge Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 28 d Method: OECD Test Guideline 301F

Biochemical Oxygen Demand (BOD)

: 5 mg/l Incubation time: 5 d

Chemical Oxygen Demand (COD)

: 560 mg/l

Photodegradation

: Test Type: Air Degradation (direct photolysis): 50 %

Test Type: Water

2,4,6-tris(dimethylaminomethyl)phenol:

Biodegradability

: Inoculum: activated sludge Concentration: 2 mg/l Result: Not readily biodegradable. Biodegradation: 4 % Exposure time: 28 d Method: OECD Test Guideline 301D


Biodegradability

: Result: Not readily biodegradable. Biodegradation: 1 - 2 % Exposure time: 28 d


Biodegradability

: Inoculum: activated sludge Result: Not readily biodegradable. Biodegradation: 0 % Exposure time: 162 d Method: OECD Test Guideline 301D

Inoculum: activated sludge Result: Not readily biodegradable. Biodegradation: 20 % Exposure time: 84 d Method: OECD Test Guideline 302 A



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12.3 Bioaccumulative potential

Components:

naphthalene, bis(1-methylethyl)-: Bioaccumulation

: Species: Cyprinus carpio (Carp) Exposure time: 60 d Bioconcentration factor (BCF): 770 - 6,400 Test substance: Fresh water Method: flow-through test


: log Pow: 6.081 Method: QSAR

Diethylenetriamine: Bioaccumulation

: Species: Cyprinus carpio (Carp) Exposure time: 42 d Bioconcentration factor (BCF): 0.3 - 6.3 Test substance: Fresh water Method: flow-through test Remarks: Bioaccumulation is unlikely.


: log Pow: -1.58 (20 °C) pH: 7

Aminoethylpiperazine: Bioaccumulation

: Species: Fish Remarks: Does not bioaccumulate.


: log Pow: -1.48 (20 °C)

2,4,6-tris(dimethylaminomethyl)phenol: Partition coefficient: n-octanol/water

: log Pow: 0.219 (21.5 °C) Method: OPPTS 830.7550

Triethylenetetramine: Partition coefficient: n-octanol/water

: log Pow: -2.65 (20 °C) Method: OECD Test Guideline 117

12.4 Mobility in soil

Components:

naphthalene, bis(1-methylethyl)-: Distribution among environmental compartments

: Koc: 36108Method: QSAR

Diethylenetriamine: Distribution among environmental compartments

: Koc: 19111

Aminoethylpiperazine: Distribution among environmental compartments

: Koc: ca. 37000



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Triethylenetetramine: Distribution among environmental compartments

: Koc: 1584.9 - 5012Method: OECD Test Guideline 106

12.5 Results of PBT and vPvB assessment

Product:

Assessment

: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher..

12.6 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Send to a licensed waste management company.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers.

SECTION 14: Transport information

IATA 14.1 UN number : UN 2735


: Polyamines, liquid, corrosive, n.o.s.

(DIETHYLENE TRIAMINE, DIISOPROPYLNAPHTHALENE)


: 8

14.4 Packing group : II

Labels : Corrosive

Packing instruction (cargo aircraft)

: 855

Packing instruction (passenger aircraft)

: 851

IMDG 14.1 UN number : UN 2735


: POLYAMINES, LIQUID, CORROSIVE, N.O.S.


14.3 Transport hazard : 8



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class(es) 14.4 Packing group : II Labels : 8 EmS Code : F-A, S-B 14.5 Environmental hazards Marine pollutant : yes

ADR 14.1 UN number : UN 2735





: 8

14.4 Packing group : II Labels : 8 14.5 Environmental hazards Marine pollutant : no

RID 14.1 UN number : UN 2735





: 8

14.4 Packing group : II Labels : 8 14.5 Environmental hazards Marine pollutant : no

Transport in bulk according to Annex II of Marpol and the IBC Code

Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59).

: Not applicable

REACH - List of substances subject to authorisation (Annex XIV)

: Not applicable

The components of this product are reported in the following inventories:

TSCA

: On TSCA Inventory

DSL

: All components of this product are on the Canadian DSL



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AICS


NZIoC


ENCS


KECI


PICCS


IECSC


Inventories

AICS (Australia), DSL (Canada), IECSC (China), ENCS (Japan), KECI (Korea), NZIOC (New Zealand), PICCS (Philippines), TSCA (United States of America)

15.2 Chemical safety assessment

SECTION 16: Other information

Full text of H-Statements

H302 : Harmful if swallowed. H304 : May be fatal if swallowed and enters airways. H311 : Toxic in contact with skin. H312 : Harmful in contact with skin. H314 : Causes severe skin burns and eye damage. H315 : Causes skin irritation. H317 : May cause an allergic skin reaction. H318 : Causes serious eye damage. H330 : Fatal if inhaled. H335 : May cause respiratory irritation. H361f : Suspected of damaging fertility. H410 : Very toxic to aquatic life with long lasting effects. H411 : Toxic to aquatic life with long lasting effects. H412 : Harmful to aquatic life with long lasting effects.

Full text of other abbreviations

Acute Tox. : Acute toxicity Aquatic Chronic : Chronic aquatic toxicity Asp. Tox. : Aspiration hazard Eye Dam. : Serious eye damage Repr. : Reproductive toxicity Skin Corr. : Skin corrosion Skin Irrit. : Skin irritation Skin Sens. : Skin sensitisation



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STOT SE : Specific target organ toxicity - single exposure

Further information

While the information and recommendations in this publication are to the best of our knowledge, information and belief accurate at the date of publication, NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY, EXPRESS OR OTHERWISE.

IN ALL CASES, IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.

THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION. WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION, NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.

Hazards, toxicity and behaviour of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes. Such hazards, toxicity and behaviour should be determined by the user and made known to handlers, processors and end users.

The trademarks above are the property of Huntsman Corporation or an affiliate thereof.

NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.

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