APPENDIX 8.1-1 Baseline Data Collection and Results...APPENDIX 8.1-1 Baseline Data Collection and...
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APPENDIX 8.1-1 Baseline Data Collection and Results
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1.0 INTRODUCTION
A baseline sampling program that included both terrestrial and aquatic components was completed for the WesPac
Tilbury Marine Jetty Project (the Project). The terrestrial component was completed on 31 July 2015, and the
aquatic component was completed on 16 and 23June 2015. The Project site is located along the South Arm of the
Fraser River in Delta, BC (Figure 1).
The purpose of the baseline sampling program is to provide site-specific chemistry results that will be used to
estimate baseline exposure concentrations as a part of the Human Health assessment.
The baseline sampling program was designed to be consistent with a country foods guidance document prepared
for Health Canada (Golder 2005). The baseline sampling program was designed to collect country foods that are
consumed by people in the Local and Regional Assessment Areas (LAA and RAA). The targeted country foods
were berries in the terrestrial environment, and fish in the freshwater environment.
The fish tissue chemistry data collected as part of the baseline sampling program is used to evaluate risks related
to the fish consumption pathway. Consumption of shellfish was not considered an operable pathway as shellfish
were not present in the South Arm of the Fraser River within the Study Area and were not observed during the
baseline sampling program. In addition, shellfish areas along the outer estuary are closed to shellfish harvesting
(Department of Fisheries and Oceans 2018).
Fifteen (15) sites located within the LAA and RAA were selected for berry and soil sampling. The terrestrial
sampling locations were selected based on input from the Musqueam Aboriginal assistant and areas people use
for recreational purposes (e.g., parks, campsites). Fish samples were collected from the intertidal shoreline on the
Fraser River adjacent to Tilbury Island in front of the WesPac Project Site.
2.0 FIELD SAMPLING AND ANALYSIS METHODS
2.1 Terrestrial Baseline Sampling
Golder field personnel, accompanied by a Musqueam Aboriginal assistant, conducted sampling on 31 July 2015.
Sampling locations were accessed on foot. Co-located soil and berries were collected in accordance with Golder
(2005). Co-located soil samples were collected adjacent to where the berries were sampled. A summary of the
collection methodology is presented below.
2.1.1 Sampling Methods
At each collection site, the following sampling methods were utilized:
Photographs were taken including: the surrounding area and ground cover; soil in the sample jar, the berry
sample in the collection bag (e.g., Ziploc bag); and, the entire plant including leaves and branches (see
photographs in Attachment 1).
Berry samples were handpicked, avoiding the inclusion of any soil or debris. Berry samples were placed in
clean, labelled Ziploc bags, and were placed on ice in coolers until they could be frozen. Frozen berry samples
were then submitted to the lab for analysis.
Surficial soil samples (top 15 cm) were collected at the base of the plant sampled for berries using a stainless
steel trowel, removing the top layer of litter/fibre and humus. The collected soils were placed in a stainless
APPENDIX 8.1-1 Baseline Data Collection and Results
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steel bowl and mixed to create a homogenous sample. The soil sample was then placed in clean, labelled
glass jars. Samples were stored on ice in a cooler and transported to the lab for analysis.
A plant and soil identification form was completed at each site and included date, sample #, photo numbers,
location, growing environment, vegetation type, soil type, soil depth, and field notes.
The following quality assurance measures were taken:
Cross-contamination during sample collection was minimized by wearing disposable nitrile gloves, which were
changed between each sample. Stainless steel equipment (i.e., trowels) were washed with decontamination
soap and rinsed with distilled water between sample collection sites.
Duplicate soil and berry samples were collected at sampling locations 15-Tilbury-1 and 15-Tilbury-8 to assess
reproducibility (see Section 3.2).
The sampling locations where the soil and berries were collected are provided in Table 1 and shown on Figure 2.
Table 1: Soil and Berry Sample Locations
Location Sampling Date UTM Coordinates
Zone Easting Northing
15-Tilbury-1 31-July-2015 10 U 496628 5439875
15-Tilbury-2 31-July-2015 10 U 497452 5440294
15-Tilbury-3 31-July-2015 10 U 497499 5441935
15-Tilbury-4 31-July-2015 10 U 497489 5443381
15-Tilbury-5 31-July-2015 10 U 497098 5442905
15-Tilbury-6 31-July-2015 10 U 496916 5442596
15-Tilbury-7 31-July-2015 10 U 495207 5440970
15-Tilbury-8 31-July-2015 10 U 495911 5441523
15-Tilbury-9 31-July-2015 10 U 494339 5439938
15-Tilbury-10 31-July-2015 10 U 496630 5443756
15-Tilbury-11 31-July-2015 10 U 497151 5444057
15-Tilbury-12 31-July-2015 10 U 493006 5440846
15-Tilbury-13 31-July-2015 10 U 491330 5439918
15-Tilbury-14 31-July-2015 10 U 491508 5440086
15-Tilbury-15 31-July-2015 10 U 485782 5441569
Table 2 summarizes the type of berries and soil collected, and the surrounding growing environment at each
sampling location.
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Table 2: Terrestrial Baseline Sampling Program Summary
Vegetation Sample ID
Soil Sample ID Berry Type Soil Depth (cm)
Soil Type
Growing Environment (%)
Trees Shrubs Grass Moss/ Lichen
Rock/ Bare Ground
15-Tilbury-B-1 15-Tilbury-S-1 Rubus armeniacus (Himalayan blackberry)
0 - 5 fine sandy loam/organic 0 70 30 0 0
15-Tilbury-B-2 15-Tilbury-S-2 Rubus armeniacus (himalayan blackberry)
0 - 5 fine sandy loam/organic 0 35 60 0 5
15-Tilbury -B-3 15-Tilbury-S-3 Rubus armeniacus (himalayan blackberry)
0 - 5 silty/rocks throughout 0 20 80 0 0
15-Tilbury-B-4 15-Tilbury-S-4 Rubus armeniacus (himalayan blackberry)
0 - 5 gravely sand/organic 50 20 0 0 30
15-Tilbury-B-5 15-Tilbury-S-5 Rubus armeniacus (himalayan blackberry)
0 - 5 gravely sand 40 20 10 0 30
15-Tilbury-B-6 15-Tilbury-S-6 Rubus armeniacus (himalayan blackberry)
0 - 5 sand 40 20 10 0 30
15-Tilbury-B-7 15-Tilbury-S-7 Rubus armeniacus (himalayan blackberry)
0 - 5 fine sandy loam/organic 30 50 10 0 10
15-Tilbury-B-8 15-Tilbury-S-8 Rubus armeniacus (himalayan blackberry)
0 - 5 gravely sand/organic 30 40 30 0 0
15-Tilbury -B-9 15-Tilbury-S-9 Rubus armeniacus (himalayan blackberry)
0 - 5 sand 20 50 30 0 0
15-Tilbury-B-10 15-Tilbury-S-10 Rubus armeniacus (himalayan blackberry) 0 - 5 sand 0 60 20 0 20
15-Tilbury-B-11 15-Tilbury-S-11 Rubus armeniacus (himalayan blackberry) 0 - 5 sand 40 40 0 0 0
15-Tilbury-B-12 15-Tilbury-S-12 Rubus armeniacus (himalayan blackberry) 5 - 10 silty sand/organic 50 20 20 0 10
15-Tilbury-B-13 15-Tilbury-S-13 Rubus armeniacus (himalayan blackberry) 0 - 10 dry silty sand/organic 50 20 25 0 5
15-Tilbury-B-14 15-Tilbury-S-14 Rubus armeniacus (himalayan blackberry) 0 - 5 dry silty sand/organic 40 40 20 0 0
15-Tilbury-B-15 15-Tilbury-S-15 Rubus armeniacus (himalayan blackberry) 0 - 5
Fine sand with clay throughout
10 30 50 0 10
Notes: % = percent; cm = centimeter.
APPENDIX 8.1-1 Baseline Data Collection and Results
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2.1.2 Analysis Methods
Soil and berry samples were submitted to ALS Environmental (ALS; Burnaby, BC) for chemistry analysis.
Soil samples (15 samples plus 2 duplicate samples) were analyzed for:
pH (1:2 H2O extract);
Moisture content (drying/gravimetric);
Metals in soil (Collision/Reaction Cell-ICPMS [inductively coupled plasma mass spectrometry]) including
mercury (Cold Vapour Atomic Fluorescence Spectroscopy [CVAFS]); and,
Polycyclic aromatic hydrocarbons (rotary extraction).
Berry samples (15 samples plus 2 duplicate sample) were analyzed for:
Moisture content (drying/gravimetric);
Metals in tissue (CRC-ICPMS and inductively coupled plasma – optical emissions spectrophotometry
[ICPOES]) including silver (CRC-ICPMS) and mercury (CVAFS); and
Polycyclic aromatic hydrocarbons – low level.
Soil concentrations were compared to applicable guidelines and the results are presented in Appendix 8.1-2. There
are no standards or guidelines available for vegetation.
2.2 Aquatic Baseline Sampling
2.2.1 Sampling Methods
Golder field personnel conducted aquatic baseline sampling between 16 June and 23 June 2015 by. Sampling
locations were accessed by foot. Golder set ten baited minnow traps over two periods in the areas of the intertidal
foreshore that were wetted between the 2.3 and 3.0 m above-sea-level (ASL) tidal cycle. Results of the minnow
trapping are provided in Table 3.
Table 3: Minnow Trapping Results and Sampling Locations
Location Sampling Date Species Life Stage Catch (n)
MT-1 set at approximately 10U 497223 5443132
17-June-2015 Northern pikeminnow
(Pyychocheilus oregonensis)
Juvenile 1
MT-3 set at approximately 10U 497233 5443177
17-June-2015 Prickly sculpin (Cottus asper) Adult 1
MT-5
set at approximately 10U 497255 5443200
17-June-2015 Prickly sculpin (Cottus asper) Adult 2
MT-5 23-June-2015 Peamouth chub
(Mylocheilus caurinus) Adult 1
MT-5 23-June-2015 Sculpin
(Cottus sp.) Adult 2
APPENDIX 8.1-1 Baseline Data Collection and Results
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In addition to the minnow trapping activities, Golder conducted beach seining activities at five locations along the
intertidal foreshore in the wetted areas above 2.3 m ASL. Results of the beach seining activities are provided in
Table 4.
Table 4: Beach Seining Results and Sampling Locations
Location Sampling Date Species Life Stage Catch (n)
S-1
sampled at approximately 10U 497261 5443212
17-June-2015 Chum Salmon
(Oncorhynchus keta) Fry 32
S-1 17-June-2015 Pink Salmon
(Oncorhynchus gorbuscha)
Fry 9
S-1 17-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 5
S-2
sampled at approximately 10U 497264 5443234
17-June-2015 Chinook Salmon (Oncorhynchus tshawytscha)
Fry 1
S-2 17-June-2015 Chum Salmon
(Oncorhynchus keta) Fry 5
S-2 17-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 2
S-3 sampled at approximately 10U 497219 5443135
17-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 1
S-4 sampled at approximately 10U 497227 5443170
17-June-2015 Sculpin
(Cottus sp.) Juvenile 2
S-5
sampled at approximately 10U 497315 5443296
17-June-2015 Peamouth chub
(Mylocheilus caurinus) Adult 1
S-5 17-June-2015 Redside shiner (Richardsonius
balteatus) Adult 9
S-5 17-June-2015 Sculpin
(Cottus sp.) Juvenile 7
S-5 17-June-2015 Speckled sanddab
(Citharichthys stigmaeus)
Fry 1
S-1
sampled at approximately 10U 497261 5443212
23-June-2015 Chum Salmon
(Oncorhynchus keta) Fry 3
S-1 23-June-2015 Minnow sp.
(Cyprindae sp.) Fry 10
S-1 23-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 13
S-2
sampled at approximately 10U 497264 5443234
23-June-2015 Chum Salmon
(Oncorhynchus keta) Fry 2
S-2 23-June-2015 Minnow sp.
(Cyprindae sp.) Fry 17
S-2 23-June-2015 Northern pikeminnow
(Ptychocheilus oregonensis)
Fry 1
APPENDIX 8.1-1 Baseline Data Collection and Results
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Location Sampling Date Species Life Stage Catch (n)
S-2 23-June-2015 Starry flounder
(Platichthys stellatus) Fry 1
S-2 23-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 1
S-3 sampled at approximately 10U 497219 5443135
23-June-2015 Minnow sp.
(Cyprindae sp.) Fry 5
S-5
sampled at approximately 10U 497315 5443296
23-June-2015 Chum salmon
(Oncorhynchus keta) Fry 1
S-5 23-June-2015 Minnow sp.
(Cyprindae sp.) Fry 1
S-5 23-June-2015 Sculpin
(Cottus sp.) Juvenile 1
S-5 23-June-2015 Stickleback sp.
(Gasterosteus sp.) Fry 4
Fish sampled were intended for documentation of fish species present at the Site. A limited number of sculpin
(Cottus sp.) were retained from the sampling effort and submitted for analysis of metals content. Samples
submitted included adult Prickly Sculpin (Cottus asper) caught in minnow trap 3 (MT-2-CC-01), and from minnow
trap 5 (MT-5-CC-01 and MT-5-CC) as well as juvenile sculpin (unidentified species) from beach seining locations
4 and 5(S-4-CC-01, S-4-CC-02, S-5-CC-01 and S-5-CC-02). Sculpin were chosen for analysis over the other fish
species collected because the tissue chemistry would likely be the most representative of exposure to the Site.
Sculpin are generally catadromous, whereby reproductive adults migrate from a fresh water environment to an
estuarine environment to spawn, then the adults and the reared young return to a fresh water environment
(McPhail and McPhail 2007; Krejsa 1967). Specifically, adult Prickly Sculpin in British Columbia generally spawn
between April and late June with the male sculpin guarding the nest for approximately 16 days until the egg mass
has hatched (McPhail and McPhail 2007). As a result, the adult Prickly Sculpin and the juvenile sculpin retained
for analysis would have likely lived out a portion of their lifecycle in or near the Site.
2.2.2 Analysis Methods
Fish samples were submitted to ALS (Burnaby, BC) for chemistry analysis. In some instances, the individual fish
samples were not large enough to obtain appropriate detection limits. As such, sample S-4-CC-01, S-5-CC-02, S-
4-CC-02 and MT-5-CC-02 were composited and analyzed as one sample. Detection limits were also elevated for
the other samples analyzed except for sample MT-2-CC-01 (which had sufficient tissue weight). In total, three fish
samples, MT-2-CC-01, S-5-CC-02, MT-5-CC-01, and a composite sample were analyzed. Fish samples (3
samples plus 1 composite) were analyzed for:
Moisture (drying/gravimetric);
Metals in tissue (CRC-ICPMS and ICPOES) including silver (CRC-ICPMS) and mercury (CVAFS); and
Polycyclic aromatic hydrocarbons – low level.
APPENDIX 8.1-1 Baseline Data Collection and Results
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The glass jar containing sample MT-2-CC-01 was received broken after being shipped from ALS Burnaby to ALS
Kelso. Therefore, sample MT-2-CC-01 was not analyzed for PAHs.
Fish concentrations were compared to applicable guidelines and the results are presented in Appendix 8.1-2 for
informational purposes.
2.3 Quality Assurance/Quality Control
2.3.1 Field
For field quality assurance/quality control (QA/QC) purposes, two duplicate samples of berries and two duplicate
samples of soil were collected. The location where the duplicates were collected was chosen randomly and based
on sample availability during the field program. Sample duplicates are collected to provide an indication of natural
sample variation and the reproducibility results from within the same sample plot or plant. For duplicate media
samples, the sampling mass collected was doubled using the same sample procedures outlined above.
2.3.2 Laboratory
In addition to field duplicate QA/QC procedures, analyses conducted by ALS followed appropriate laboratory
QA/QC procedures. Each analytical method and standard sample has control limits that must be met to verify the
results for both the standard materials and the unknown samples submitted. These results were reported with
each laboratory data summary report. Laboratory QA/QC included analysis of method blanks, laboratory control
samples, matrix spikes, and reference materials to assess precision and accuracy of analyses. All laboratory
duplicate samples were analyzed for the suite of analytes listed in Section 2.1.2. Laboratory data QA/QC reports
were reviewed upon receipt to confirm that the laboratory data quality objectives (DQOs) had been met and that
the applicable QA/QC information had been reported.
3.0 RESULTS
3.1 Analytical results
The results of the baseline soil, vegetation and fish sampling program are presented in Attachment 2. The results
for soils are presented in Tables 2-1 and 2-2 for metals and PAHs, respectively. The results of the baseline
vegetation sampling program are presented in Tables 2-3 and 2-4 for metals and PAHs, respectively. The results
of the fish sampling program are presented in Tables 2-5 and 2-6 for metals and PAHs, respectively.
3.2 Quality Assurance/Quality Control
3.2.1 Field
For soil, the duplicate was a sample that was blended and divided into two equal portions, each of which is
analyzed in the same manner. For berries, duplicate collection involves collecting two separate samples of the
same tissue type from the same location.
APPENDIX 8.1-1 Baseline Data Collection and Results
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The comparison of the results of a duplicate pair are often expressed as Relative Percent Difference (RPD). The
RPD is an indicator of sample heterogeneity. Lower RPD numbers indicate that samples are homogeneous. The
formula for calculating the RPD is provided below:
𝑅𝑃𝐷 𝑎𝑏𝑠 𝑆𝑎𝑚𝑝𝑙𝑒 𝐷𝑢𝑝
𝑀𝑒𝑎𝑛 𝑥 100
Where:
RPD is the relative percent difference;
abs (Sample - Dup) is the absolute value of the original sample minus the duplicate sample; and
Mean is the average of the two samples.
RPDs were not calculated if concentrations were not detected in one or both of the duplicate sample pairs.
Variability in sample results can be introduced in the field and laboratory. Generally, higher variability is accepted
from field duplicates compared to laboratory duplicates. Field duplicate variability of 30% to 50% (RPD) is common
for soil and could also be expected for berries. However, because berry duplicates are not true “split” samples,
variability could also be higher. Laboratory duplicate variability is generally less than field duplicate variability since
fewer steps are involved and RPDs of 20% may be expected.
The BC Ministry of Environment and Climate Change Strategy (2015) considers a RPD of 20% to be acceptable
for duplicate soil samples. A RPD value of more than 30% was used for berries as tissues are inherently subject
to greater heterogeneity than abiotic media (Golder 2005). Duplicate samples that have larger variation indicate
high sample variability, which can be due to natural sample heterogeneity.
Soil Duplicate QA/QC
The duplicate analyses for soil samples are provided in Tables B-7 for metals and B-8 for PAHs. The RPD was
greater than 20% for the following parameters: arsenic, chromium, anthracene, benz(a)anthracene
benzo(a)pyrene, benzo(b)fluoranthene, benzo(b+j+k)fluoranthene, benzo(g,h,i)perylene, benzo(k)fluoranthene,
fluoranthene, indeno(1,2,3-c,d)pyrene, phenanthrene and pyrene. Duplicate variability is likely attributed to the
natural heterogeneity of soils. Most natural soils are highly variable and rarely homogeneous. Although this
variability could affect the precision of the individual results, selection of the duplicate samples was random,
meaning that there would be no systematic bias in results due to the variability.
Although RPD results for PAHs in soil were high (96 to 163%), the higher, more conservative, parent
concentrations were used in the risk assessment to identify constituents of potential concern in soil. Therefore,
variability in soil concentrations does not affect the results of the risk assessment.
Berry Duplicate QA/QC
The duplicate sample analyses for berry samples are provided in Tables B-9 (metals) and B-10 (PAHs). The RPD
was greater than 30% in one or more sets of duplicate samples for the following: aluminum, barium, cadmium,
copper, molybdenum, tin and zinc. The RPD results for PAHs were below the RPD limit. The observed duplicate
variability is likely attributed to heterogeneity internally in plant tissues or to the adherence of dust or soil on plant
APPENDIX 8.1-1 Baseline Data Collection and Results
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surfaces. Although this variability could affect the precision of the individual results, selection of the duplicate
samples was random, meaning that there would be no systematic bias in results due to the variability.
Fish QA/QC
Duplicate samples were not collected for fish tissues. Fish are mobile, and collection of duplicates is not considered
appropriate for evaluating field sample variability and reproducibility. Fish tissues were submitted to ALS, which is
accredited by the Canadian Association for Laboratory Accreditation. ALS analyzed laboratory duplicates, method
blanks, and reference materials to assess precision and accuracy (see Section 3.2.2 for a discussion on laboratory
QA/QC results).
3.2.2 Laboratory
Laboratory data reports for samples collected during field sampling are provided in Attachment 3. The following
data quality issues were identified in the ALS laboratory reports:
Soil
Detection limits were elevated for several parameters due to required dilution, sample matrix effects and
co-eluting interference.
The laboratory may need to dilute samples to account for the following: 1) when the analyst suspects that
concentrations are outside the calibration range of the instrument, 2) when the sample has high dissolved
solids or electrical conductivity. In such cases, the detection limit is adjusted to account for dilution.
Some tests are impacted by either chemical factors or physical factors (colour, turbidity) that make it
impossible to get a valid measurement of the sample “as submitted”. In such cases, the sample may be
diluted to a level that the impact is mitigated. This dilution triggers a corresponding detection limit increase.
Co-elution occurs when chemicals come off the instrument column at the same time, creating matrix
interference. The resulting chromatogram may have some “background”, making it difficult to identify the
analyte with confidence. Therefore, the detection limits were raised to account for the background.
Berries
Detection limits were elevated for benzo(a)pyrene due to matrix interference. The resulting chromatogram
may have some “background”, making it difficult to identify the polycyclic aromatic hydrocarbon with
confidence. Therefore, the detection limits were raised to account for the background.
The results reported for acenaphthene in several samples may contain a slight bias due to matrix interference.
The acenaphthene results for the samples affected by matrix interference may be biased high and may be
more conservative than those without matrix interference.
Fish
The upper control criterion was exceeded by 1% for the fluoranthene surrogate in the sample method blank.
The upper control criterion error is associated with a potential slightly high bias.
APPENDIX 8.1-1 Baseline Data Collection and Results
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4.0 CONCLUSIONS
The purpose of the baseline sampling program was to determine the baseline concentrations of metals in
vegetation, soil and fish within the project area. Based on a review of the methods, detection limits and QA/QC
where applicable, the data are considered suitable for inclusion in the Human Health assessment.
5.0 CLOSURE
This appendix has been prepared in support of Section 8.1 (Human Health) of the EAC Application being prepared
for the WesPac Tilbury Project under the joint review of the British Columbia Environmental Assessment Office
and the Canadian Environmental Assessment Agency. This appendix should be read in conjunction with
Section 8.1 (Human Health). Any use which a third party makes of this Appendix, or any reliance on or decisions
made based on it, are the responsibility of such third parties. Golder Associates Ltd. accepts no responsibility for
damages, if any, suffered by any third party as a result of decisions made or actions based on this appendix.
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APPENDIX 8.1-1 Baseline Data Collection and Results
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6.0 REFERENCES
BC Ministry of Environment and Climate Change Strategy. 2015, Contaminated Sites – Q&As. Available at:
https://www2.gov.bc.ca/assets/gov/environment/air-land-water/site-remediation/docs/contaminated-
sites/cs_q-a.pdf. Accessed March 2018.
Department of Fisheries and Oceans. 2018. Shellfish harvesting openings and closures. Pacific Region, Area 29.
Available at: http://www.dfo-mpo.gc.ca/shellfish-mollusques/closures-fermetures-eng.htm. Accessed
August 2018.
Golder. 2005. Guidance for Including Country Foods in Human Health Assessments for Federal Contaminated
Sites. HECS-SEP-BC/Yukon/05/06-01. Submitted to Health Canada. Burnaby, BC.
McPhail JD and DL McPhail. 2007. The Freshwater Fishes of British Columbia. 620pp. The University of Alberta
Press. Ring House 2, Edmonton, Alberta, Canada.
Krejsa RJ. 1967. The Systematics of the Prickly Sculpin, Coitus asper Richardson, a Polytypic Species. Part II.
Studies on the Life History, with Especial Reference to Migration. Pacific Science, Vol. XXI, July 1967, pp.
414-422.
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WESTHAMISLAND
SHADYISLAND
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BARBERISLAND
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SAMPLE LOCATIONS FOR THE HUMAN HEALTH BASELINESAMPLING PROGRAM
TILBURY MARINE JETTYDELTA, B.C.
WESPAC MIDSTREAM - VANCOUVER LLC
1. INDIAN RESERVES AND MUNICIPAL BOUNDARIES OBTAINED BY B.C. MINISTRY OFFORESTS, LANDS AND NATURAL RESOURCE OPERATIONS.2. RAILWAY, WATER, FOREST, PARKS, WATERCOURSE AND RESIDENTIAL AREA DATAOBTAINED FROM CANVEC © DEPARTMENT OF NATURAL RESOURCES CANADA. ALLRIGHTS RESERVED.3. TOPO BASEMAP © ESRI AND ITS LICENSORS. ALL RIGHTS RESERVED.PROJECTION: UTM ZONE 10; DATUM: NAD 83
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15-Tilbury-5
15-Tilbury-6
15-Tilbury-10
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1:20,000 METRESSCALE
ATTACHMENT 1 Photos
1
Photo 1: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-1, July 2015.
Photo 2: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-2, July 2015.
Photo 3: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-3, July 2015.
ATTACHMENT 1 Photos
2
Photo 4: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-4, July 2015.
Photo 5: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-5, July 2015.
Photo 6: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-6, July 2015.
ATTACHMENT 1 Photos
3
Photo 7: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-7, July 2015.
Photo 8: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-8, July 2015.
Photo 9: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-9, July 2015.
ATTACHMENT 1 Photos
4
Photo 10: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-10, July 2015.
Photo 11: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-11, July 2015.
Photo 12: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-12, July 2015.
ATTACHMENT 1 Photos
5
Photo 13: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-13, July 2015.
Photo 14: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-14, July 2015.
Photo 15: Soil and berries (Himalayan blackberry) collected at 15-Tilbury-15, July 2015.
Appendix 8.1-1Attachment 2
Table 2-1: Soil Analytical Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location Farm Land Farm Land Farm Land Farm LandDyke East of Project Site
Dyke West of Project Site
Dyke West of Project Site
Deas Park Deas Park Deas Park
Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FDPhysical ParametersMoisture % 13.5 13.7 10.4 15.4 4.03 4.27 5.62 6.33 7.53 6.66pH pH units 6.02 6.02 6.16 5.80 6.40 6.76 6.27 6.54 6.43 6.52Organic CarbonTotal Organic Carbon % 3.03 2.99 2.28 2.37 0.97 0.54 1.23 4.79 2.03 2.07MetalsAluminum (Al) mg/kg 21400 21100 11300 16000 16300 15700 8540 10400 10400 10000Antimony (Sb) mg/kg 0.72 0.71 0.39 0.98 0.54 <0.10 0.29 0.28 0.22 0.22Arsenic (As) mg/kg 8.84 9.21 4.19 6.550 5.65 1.88 3.73 2.62 5.38 3.45Barium (Ba) mg/kg 146 133 070 084 059 086 055 051 046 044Beryllium (Be) mg/kg 0.47 0.47 0.23 0.29 0.23 0.31 0.19 0.18 0.17 0.15Bismuth (Bi) mg/kg <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20 0.68 <0.20 <0.20Boron (B) mg/kg <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.0 10.3 <5.0 <5.0Cadmium (Cd) mg/kg 0.49 0.50 0.179 0.350 0.27 0.029 0.09 0.28 0.16 0.14Chromium (Cr) mg/kg 50.90 50.30 29.1 35.10 23.8 04.8 29.80 25.4 39.3 20.6Cobalt (Co) mg/kg 13.40 13.90 8.32 11.30 10.90 5.35 8.01 9.20 08.0 07.9Copper (Cu) mg/kg 42.80 42.30 26.4 44.00 41.70 03.9 15.8 44.90 22.1 19.2Iron (Fe) mg/kg 29600 29600 20100 27700 29300 17500 17600 18600 19400 18200Lead (Pb) mg/kg 25.4 23.9 20.8 65.8 10.0 01.3 05.9 04.9 03.5 03.4Lithium (Li) mg/kg 19.7 19.9 09.4 14.3 14.7 <2.0 7.6 6.4 07.6 07.0Manganese (Mn) mg/kg 0337 0339 310 432 504 370 327 378 364 348Mercury (Hg) mg/kg 0.073 0.077 0.0256 0.032 0.0114 <0.0050 0.0267 0.0350 0.0257 0.0255Molybdenum (Mo) mg/kg 1.75 1.92 0.87 1.26 0.77 0.87 0.46 0.46 0.45 0.45Nickel (Ni) mg/kg 43.10 43.80 21.5 27.50 18.5 04.1 30.1 26.8 23.7 22.4Selenium (Se) mg/kg 0.48 0.47 <0.20 0.28 0.38 <0.20 <0.20 <0.20 <0.20 <0.20Silver (Ag) mg/kg <0.10 <0.10 <0.10 0.11 0.10 <0.10 <0.10 <0.10 <0.10 <0.10Strontium (Sr) mg/kg 44.1 42.1 33.2 33.6 34.7 74.6 31.8 43.7 32.1 28.7Thallium (Tl) mg/kg 0.138 0.130 0.064 0.076 0.060 <0.050 0.057 0.055 <0.050 <0.050Tin (Sn) mg/kg <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0 <2.0Uranium (U) mg/kg 2.290 2.310 0.573 0.662 0.340 0.660 0.31 0.299 0.273 0.247Vanadium (V) mg/kg 69.30 68.70 47.5 66.20 72.5 24.4 40.5 43.2 48.7 45.5Zinc (Zn) mg/kg 129.0 125.0 131 116.0 90.1 032 037 069 047 045Notes:
Units
< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate.
O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-1 Soil Metals] Golder Associates Page 1 of 2
Appendix 8.1-1Attachment 2
Table 2-1: Soil Analytical Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location
Sample IDDate SampledQA/QCPhysical ParametersMoisture %pH pH unitsOrganic CarbonTotal Organic Carbon %MetalsAluminum (Al) mg/kgAntimony (Sb) mg/kgArsenic (As) mg/kgBarium (Ba) mg/kgBeryllium (Be) mg/kgBismuth (Bi) mg/kgBoron (B) mg/kgCadmium (Cd) mg/kgChromium (Cr) mg/kgCobalt (Co) mg/kgCopper (Cu) mg/kgIron (Fe) mg/kgLead (Pb) mg/kgLithium (Li) mg/kgManganese (Mn) mg/kgMercury (Hg) mg/kgMolybdenum (Mo) mg/kgNickel (Ni) mg/kgSelenium (Se) mg/kgSilver (Ag) mg/kgStrontium (Sr) mg/kgThallium (Tl) mg/kgTin (Sn) mg/kgUranium (U) mg/kgVanadium (V) mg/kgZinc (Zn) mg/kgNotes:
Units
< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate.
Boat LaunchDyke North of Project Site
Dyke North of Project Site
Park near Fraser River,
Richmond
South-Dyke Park
Finn Slough Gary Point
15-Tilbury-S-9 15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-1531-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015
- - - - - - -
3.24 8.30 8.91 27.0 11.0 6.32 13.56.61 7.57 7.89 6.71 6.73 6.37 4.87
0.38 2.95 1.51 3.50 4.28 1.46 1.87
09250 12400 8720 14700 13400 15300 173000.21 1.27 1.34 0.70 0.59 0.47 0.503.49 6.48 16.40 8.23 6.03 4.06 7.76046 070 048 110 79.8 059 67.70.20 0.26 0.16 0.35 0.31 0.22 0.29
<0.20 <0.20 <0.20 <0.20 <0.20 <0.20 <0.20<5.0 <5.0 <5.0 <5.0 <5.0 <5.0 <5.00.091 0.24 0.469 0.414 0.271 0.31 0.13632.3 28.7 17.8 42.8 35.7 26.2 49.18.28 8.59 5.24 13.90 12.10 10.40 8.1814.10 29.9 21.8 35.20 32.70 42.0 35.3020300 22100 15300 29100 25000 27100 321004.47 26.20 33.70 93.70 14.20 36.70 19.9007.3 11.0 05.5 14.8 14.0 14.5 17.1341 294 0314 533 347 499 224
0.0480 0.0611 0.0519 0.0823 0.0633 0.0296 0.06740.37 1.05 0.95 1.04 1.04 0.66 1.3532.8 24.2 15.5 43.4 38.0 18.2 28.5
<0.20 <0.20 <0.20 0.48 0.28 0.34 0.39<0.10 <0.10 0.11 0.10 <0.10 0.10 0.1125.2 47.9 149.0 057 46.0 34.4 40.3
<0.050 0.067 <0.050 0.103 0.084 <0.050 0.105<2.0 <2.0 6 <2.0 <2.0 <2.0 <2.00.297 0.717 1.060 1.230 0.878 0.37 1.0849.8 49.0 30.0 55.0 50.6 73.0 65.642.6 85.6 96.6 129.0 87.1 089 67.7
O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-1 Soil Metals] Golder Associates Page 2 of 2
Appendix 8.1-1Attachment 2
Table 2-2: Soil Analytical Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location Farm Land Farm Land Farm Land Farm LandDyke East of Project Site
Dyke West of Project Site
Dyke West of Project Site
Deas Park Deas Park Deas Park Boat Launch
Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-S-9Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD -Polycyclic Aromatic HydrocarbonsAcenaphthene mg/kg 0.017 <0.013 0.039 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Acenaphthylene mg/kg 0.019 0.016 <0.010 0.0107 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Anthracene mg/kg 0.0603 0.012 0.0632 0.0065 <0.0040 <0.0070 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040Benz(a)anthracene mg/kg 0.173 0.025 0.121 0.017 <0.010 <0.020 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(a)pyrene mg/kg 0.311 0.075 0.217 0.024 <0.010 0.024 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(b)fluoranthene mg/kg 0.572 0.133 0.413 0.041 0.011 0.070 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(b+j+k)fluoranthene mg/kg 0.809 0.196 0.585 0.055 <0.015 0.096 <0.015 <0.015 <0.015 <0.015 <0.015Benzo(g,h,i)perylene mg/kg 0.221 0.078 0.175 0.020 <0.010 0.012 <0.010 <0.010 <0.010 <0.010 <0.010Benzo(k)fluoranthene mg/kg 0.237 0.063 0.172 0.014 <0.010 0.026 <0.010 <0.010 <0.010 <0.010 <0.010Chrysene mg/kg 0.269 <0.070 <0.30 0.032 <0.010 0.064 <0.010 <0.010 <0.010 <0.010 <0.010Dibenz(a,h)anthracene mg/kg <0.040 <0.020 <0.040 0.0055 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050Fluoranthene mg/kg 0.586 0.073 0.398 0.031 0.016 0.056 <0.010 <0.010 <0.010 <0.010 <0.010Fluorene mg/kg 0.028 <0.025 0.035 <0.010 <0.010 <0.010 <0.010 <0.020 <0.010 <0.010 <0.010Indeno(1,2,3-c,d)pyrene mg/kg 0.221 0.060 0.139 0.019 <0.010 0.015 <0.010 <0.010 <0.010 <0.010 <0.0102-Methylnaphthalene mg/kg <0.020 <0.025 <0.020 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Naphthalene mg/kg <0.020 <0.025 0.023 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Phenanthrene mg/kg 0.40 0.041 0.397 0.028 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Pyrene mg/kg 0.481 0.073 0.352 0.033 0.013 0.058 <0.010 <0.010 <0.010 <0.010 <0.010B(a)P Total Potency Equivalent mg/kg 0.456 0.114 0.325 0.039 <0.020 0.039 <0.020 <0.020 <0.020 <0.020 <0.020
Notes:
Units
< = not measured above the laboratory detection limit; B(a)P = benzo(a)pyrene; mg/kg = milligram per kilogram.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate.
O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-2 Soil PAH] Golder Associates Page 1 of 2
Appendix 8.1-1Attachment 2
Table 2-2: Soil Analytical Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location
Sample IDDate SampledQA/QCPolycyclic Aromatic HydrocarbonsAcenaphthene mg/kgAcenaphthylene mg/kgAnthracene mg/kgBenz(a)anthracene mg/kgBenzo(a)pyrene mg/kgBenzo(b)fluoranthene mg/kgBenzo(b+j+k)fluoranthene mg/kgBenzo(g,h,i)perylene mg/kgBenzo(k)fluoranthene mg/kgChrysene mg/kgDibenz(a,h)anthracene mg/kgFluoranthene mg/kgFluorene mg/kgIndeno(1,2,3-c,d)pyrene mg/kg2-Methylnaphthalene mg/kgNaphthalene mg/kgPhenanthrene mg/kgPyrene mg/kgB(a)P Total Potency Equivalent mg/kgNotes:
Units
< = not measured above the laboratory detection limit; B(a)P = benzo(a)pyrene; mg/kg = milligram per kilogram.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate.
Dyke North of Project Site
Dyke North of Project Site
Park near Fraser River,
Richmond
South-Dyke Park
Finn Slough Gary Point
15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-1531-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015
- - - - - -
0.024 0.0123 <0.0050 <0.010 <0.0050 <0.00500.029 0.0097 0.0076 0.027 <0.0050 0.00960.078 0.0364 0.0088 0.0218 0.0058 0.00670.212 0.099 0.034 0.058 <0.010 0.0240.4 0.084 0.037 0.104 <0.010 0.027
0.554 0.122 0.051 0.17 0.030 0.0460.809 0.173 0.072 0.243 0.030 0.0650.251 0.054 0.021 0.068 0.013 0.0160.255 0.051 0.021 0.074 <0.010 0.0190.274 0.135 0.054 0.091 <0.030 0.041
<0.040 0.0127 0.0056 <0.020 <0.0050 <0.00500.476 0.197 0.073 0.116 0.020 0.0650.028 0.015 <0.010 <0.020 <0.010 <0.0100.219 0.059 0.024 0.059 <0.010 0.02
<0.025 0.012 <0.010 <0.020 <0.010 <0.010<0.025 0.011 0.011 <0.020 <0.010 <0.0100.332 0.180 0.038 0.056 0.010 0.0400.613 0.207 0.077 0.129 0.019 0.060.55 0.132 0.056 0.152 <0.020 0.041
O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-2 Soil PAH] Golder Associates Page 2 of 2
Appendix 8.1-1Attachment 2
Table 2-3: Vegetation Analytical Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location Farm Land Farm Land Farm Land Farm LandDyke East of Project Site
Dyke West of Project Site
Dyke West of Project Site
Deas Park Deas Park Deas Park Boat LaunchDyke North of Project Site
Dyke North of Project Site
Park near Fraser River,
Richmond
South-Dyke Park
Finn Slough Gary Point
Sample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-2 15-Tilbury-B-3 15-Tilbury-B-4 15-Tilbury-B-5 15-Tilbury-B-6 15-Tilbury-B-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-B-9 15-Tilbury-B-10 15-Tilbury-B-11 15-Tilbury-B-12 15-Tilbury-B-13 15-Tilbury-B-14 15-Tilbury-B-15Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD - - - - - - -Physical ParametersMoisture % 86.8 85.6 84.4 87.4 83.0 83.9 85.5 82.9 87.6 84.6 86.4 84.2 78.9 87.2 85.6 86.2 87.0MetalsAluminum (Al) mg/kg 29.7 42.8 10.7 20.8 29.8 11.8 18.6 14.5 3.7 5 7.6 26.8 55 12.8 15.3 9.9 17Aluminum (Al) mg/kg wwt 3.94 6.16 1.67 2.62 5.06 1.9 2.71 2.49 0.46 0.76 1.04 4.23 11.6 1.63 2.21 1.37 2.22Antimony (Sb) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 0.014 0.014 <0.010 <0.010 <0.010 <0.010Antimony (Sb) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 0.0022 0.003 <0.0020 <0.0020 <0.0020 <0.0020Arsenic (As) mg/kg <0.020 0.025 <0.020 0.021 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 0.026 0.051 0.036 <0.020 <0.020 <0.020Arsenic (As) mg/kg wwt <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 <0.0040 0.0041 0.0107 0.0046 <0.0040 <0.0040 <0.0040Barium (Ba) mg/kg 12.3 7.58 7.43 21.8 4.16 4.01 7.76 2.46 3.53 3.93 4.38 2.17 1.91 4.37 2.19 14.5 3Barium (Ba) mg/kg wwt 1.64 1.09 1.16 2.75 0.706 0.646 1.13 0.422 0.437 0.604 0.594 0.342 0.404 0.557 0.317 2 0.391Beryllium (Be) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Beryllium (Be) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Bismuth (Bi) mg/kg <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Bismuth (Bi) mg/kg wwt <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Boron (B) mg/kg 18.6 14.3 12.4 13.5 11.1 11.5 13.1 12.5 18.9 15.4 13.7 12.6 10.4 17.1 13.4 15 19.7Boron (B) mg/kg wwt 2.46 2.05 1.92 1.7 1.88 1.84 1.9 2.15 2.33 2.37 1.86 1.98 2.2 2.18 1.94 2.07 2.57Cadmium (Cd) mg/kg 0.0709 0.0514 0.0408 0.128 0.0228 0.0159 0.0185 0.0505 0.0214 0.035 0.0138 0.0092 0.0208 0.034 0.0197 0.146 0.0801Cadmium (Cd) mg/kg wwt 0.0094 0.0074 0.0064 0.0161 0.0039 0.0026 0.0027 0.0087 0.0026 0.0054 0.0019 0.0015 0.0044 0.0043 0.0028 0.0202 0.0105Chromium (Cr) mg/kg 0.076 0.089 <0.050 0.063 0.056 <0.050 0.054 <0.050 <0.050 <0.050 <0.050 0.062 0.078 0.068 <0.050 <0.050 <0.050Chromium (Cr) mg/kg wwt 0.01 0.013 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 0.016 <0.010 <0.010 <0.010 <0.010Cobalt (Co) mg/kg 0.11 0.13 0.032 0.152 0.047 0.029 0.074 0.039 <0.020 <0.020 0.03 0.047 0.046 0.07 0.072 1.03 0.425Cobalt (Co) mg/kg wwt 0.0145 0.0188 0.005 0.0192 0.008 0.0047 0.0108 0.0068 <0.0040 <0.0040 0.004 0.0075 0.0098 0.0089 0.0104 0.142 0.0554Copper (Cu) mg/kg 10.6 10 8.16 7.12 5.04 5.6 5.64 6.68 8.19 9.32 8.47 7.01 7.42 7.65 6.11 8.04 12.1Copper (Cu) mg/kg wwt 1.4 1.44 1.27 0.898 0.855 0.902 0.82 1.14 1.01 1.43 1.15 1.11 1.57 0.975 0.882 1.11 1.58Iron (Fe) mg/kg 53.9 64.1 27.4 40.6 46.1 37.1 43.9 34 38 35.5 35.7 45 75 29 34.1 29.5 50.8Iron (Fe) mg/kg wwt 7.15 9.22 4.26 5.12 7.82 5.97 6.39 5.82 4.7 5.46 4.85 7.1 15.9 3.7 4.93 4.07 6.63Lead (Pb) mg/kg 0.029 0.035 <0.020 0.042 0.047 0.032 0.038 <0.020 <0.020 <0.020 <0.020 0.044 0.27 <0.020 0.029 0.026 0.031Lead (Pb) mg/kg wwt <0.0040 0.0051 <0.0040 0.0052 0.008 0.0051 0.0055 <0.0040 <0.0040 <0.0040 <0.0040 0.0069 0.0571 <0.0040 0.0041 <0.0040 0.0041Lithium (Li) mg/kg <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 <0.50Lithium (Li) mg/kg wwt <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10Manganese (Mn) mg/kg 22.6 18.7 10.5 66.3 20.5 29.7 44.9 22.3 19.1 17.9 17.7 9.93 13 13 12 64.7 40.9Manganese (Mn) mg/kg wwt 2.99 2.69 1.64 8.37 3.48 4.78 6.53 3.81 2.36 2.76 2.41 1.57 2.75 1.66 1.74 8.94 5.34Mercury (Hg) mg/kg 0.0059 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0052 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0052 0.0063Mercury (Hg) mg/kg wwt <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010Molybdenum (Mo) mg/kg 0.54 0.601 0.462 0.159 0.207 0.115 0.35 0.161 0.759 0.317 0.342 0.599 0.427 0.542 0.27 0.217 0.147Molybdenum (Mo) mg/kg wwt 0.0716 0.0864 0.0719 0.0201 0.0351 0.0185 0.0509 0.0275 0.0939 0.0488 0.0464 0.0945 0.0902 0.0692 0.0389 0.03 0.0192Nickel (Ni) mg/kg 2.07 1.88 1.31 4.63 1.69 2.05 3.8 2.18 1.5 1.39 1.33 0.62 0.74 2.23 2.56 6.48 6.67Nickel (Ni) mg/kg wwt 0.275 0.27 0.204 0.585 0.287 0.329 0.553 0.374 0.186 0.214 0.181 0.097 0.155 0.284 0.37 0.896 0.87Selenium (Se) mg/kg <0.050 <0.050 <0.050 <0.050 0.051 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050 <0.050Selenium (Se) mg/kg wwt <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010 <0.010Silver (Ag) mg/kg <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 <0.0050 0.0055 <0.0050Silver (Ag) mg/kg wwt <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010 <0.0010Strontium (Sr) mg/kg 15.9 11.7 11.7 16.5 11.5 11.5 14 6.08 11 11.2 11.1 8.34 6.24 21 7.72 20.8 10.1Strontium (Sr) mg/kg wwt 2.11 1.68 1.82 2.09 1.96 1.86 2.03 1.04 1.36 1.73 1.51 1.32 1.32 2.67 1.11 2.87 1.32Thallium (Tl) mg/kg <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020Thallium (Tl) mg/kg wwt <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040Tin (Sn) mg/kg 0.52 0.77 0.33 0.42 0.37 0.84 0.83 0.43 0.94 0.61 0.33 0.47 0.42 0.73 1.21 0.53 0.59Tin (Sn) mg/kg wwt 0.069 0.111 0.052 0.052 0.063 0.135 0.121 0.073 0.117 0.094 0.045 0.075 0.088 0.093 0.175 0.073 0.077Uranium (U) mg/kg <0.0020 0.0024 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 <0.0020 0.0033 <0.0020 <0.0020 <0.0020 <0.0020Uranium (U) mg/kg wwt <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 <0.00040 0.00069 <0.00040 <0.00040 <0.00040 <0.00040Vanadium (V) mg/kg <0.10 0.1 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.11 <0.10 <0.10 <0.10 <0.10Vanadium (V) mg/kg wwt <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 <0.020 0.023 <0.020 <0.020 <0.020 <0.020Zinc (Zn) mg/kg 18.4 14.8 18.3 13.4 10.2 11.4 10.7 13.8 15 17 15.3 10.4 13.4 12.5 11.9 14.6 23.8Zinc (Zn) mg/kg wwt 2.44 2.12 2.86 1.69 1.73 1.84 1.55 2.36 1.86 2.62 2.08 1.65 2.83 1.59 1.72 2.01 3.11Notes:
Units
< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate
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Appendix 8.1-1Attachment 2
Table 2-4: Vegetation Analytical Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
2018-10-05 13-1422-0049
Sample Location Farm Land Farm Land Farm Land Farm LandDyke East of Project Site
Dyke West of Project Site
Dyke West of Project Site
Deas Park Deas Park Deas Park Boat LaunchDyke North of Project Site
Dyke North of Project Site
Park near Fraser River,
Richmond
South-Dyke Park
Finn Slough Gary Point
Sample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-2 15-Tilbury-S-3 15-Tilbury-S-4 15-Tilbury-S-5 15-Tilbury-S-6 15-Tilbury-S-7 15-Tilbury-S-8 15-Tilbury-S-8D 15-Tilbury-S-9 15-Tilbury-S-10 15-Tilbury-S-11 15-Tilbury-S-12 15-Tilbury-S-13 15-Tilbury-S-14 15-Tilbury-S-15Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD - - - - - FDA FD - - - - - - -Physical ParametersMoisture % 86.8 85.6 84.4 87.4 83.0 83.9 85.5 82.9 87.6 84.6 86.4 84.2 78.9 87.2 85.6 86.2 87.0Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 0.57 0.63 <0.50 <0.49 <0.50 <0.49 <0.51 0.71 <0.50 <0.50 0.58
Acenaphthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 3.9 3.7 <4.0 <3.2 <3.7 <3.1 <2.5 5.5 <3.5 <3.7 4.4Acenaphthylene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Acenaphthylene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benz(a)anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benz(a)anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(a)pyrene µg/kg wwt <11 <17 <16 <14 <20 <15 <16 <18 <12 <20 <13 <15 <21 <21 <15 <18 <17Benzo(a)pyrene µg/kg <83 <120 <99 <110 <120 <88 <120 <110 <96 <130 <96 <94 <98 <160 <110 <130 <130Benzo(b)fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(b)fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(g,h,i)perylene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(g,h,i)perylene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Benzo(k)fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Benzo(k)fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Chrysene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Chrysene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Dibenz(a,h)anthracene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Dibenz(a,h)anthracene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Dibenzofuran µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Dibenzofuran µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.8Fluoranthene µg/kg wwt <0.50 <0.50 <0.50 <0.48 0.79 0.89 0.5 0.56 0.57 0.56 <0.50 0.58 0.96 1.7 <0.50 0.96 1.8Fluoranthene µg/kg <3.8 <3.5 <3.3 <3.9 4.6 5.5 4.3 3.3 4.6 3.6 <3.7 3.7 4.6 13 <3.5 6.9 14Fluorene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 0.86 <0.50 0.63 0.55Fluorene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 6.7 <3.5 4.6 4.2Indeno(1,2,3-cd)pyrene µg/kg wwt <0.50 <0.50 <0.50 <0.48 <0.49 <0.50 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 <0.51 <0.49 <0.50 <0.50 <0.49Indeno(1,2,3-cd)pyrene µg/kg <3.8 <3.5 <3.3 <3.9 <2.9 <3.1 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 <2.5 <3.8 <3.5 <3.7 <3.82-Methylnaphthalene µg/kg wwt <1.0 <1.0 <1.0 <0.96 <0.97 <1.0 <0.99 <1.0 <0.99 <0.98 <1.0 <0.98 <1.1 <0.97 <0.99 <1.0 <0.972-Methylnaphthalene µg/kg <7.6 <7.0 <6.5 <7.7 <5.7 <6.2 <6.9 <5.8 <8.0 <6.4 <7.4 <6.2 <4.9 <7.6 <6.9 <7.3 <7.5Naphthalene µg/kg wwt <1.0 <1.0 <1.0 <0.96 <0.97 <1.0 <0.99 <1.0 <0.99 <0.98 <1.0 <0.98 <1.1 <0.97 <0.99 <1.0 <0.97Naphthalene µg/kg <7.6 <7.0 <6.5 <7.7 <5.7 <6.2 <6.9 <5.8 <8.0 <6.4 <7.4 <6.2 <4.9 <7.6 <6.9 <7.3 <7.5Phenanthrene µg/kg wwt 0.78 0.8 0.9 1.2 2 2.1 1.8 1.3 1.3 1.3 0.75 1.5 2.4 3.9 1.2 3.5 3.8Phenanthrene µg/kg 5.9 5.6 5.8 9.6 12 13 12 7.8 10 8.7 5.5 9.4 11 31 8.5 26 29Pyrene µg/kg wwt <0.50 <0.50 <0.50 <0.48 0.51 0.74 <0.50 <0.50 <0.50 <0.49 <0.50 <0.49 0.65 0.72 <0.50 <0.50 0.77Pyrene µg/kg <3.8 <3.5 <3.3 <3.9 3 4.6 <3.5 <2.9 <4.0 <3.2 <3.7 <3.1 3.1 5.6 <3.5 <3.7 5.9Notes:
Units
< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.
QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicate
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-5: Fish Analytical Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample ID MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE *Date Sampled 17-Jun-2015 17-Jun-2015 17-Jun-2015 17-Jun-2015
Physical ParametersMoisture % 73.4 78.0 76.3 75.6
MetalsAluminum (Al) mg/kg 161 64 473 241Aluminum (Al) mg/kg wwt 42.9 14.1 112 58.7Antimony (Sb) mg/kg 0.014 <0.010 0.017 0.016Antimony (Sb) mg/kg wwt 0.0038 0.0021 0.0041 0.0039Arsenic (As) mg/kg 0.601 0.594 0.862 1.01Arsenic (As) mg/kg wwt 0.16 0.13 0.205 0.246Barium (Ba) mg/kg 6.45 7.49 6.49 8.21Barium (Ba) mg/kg wwt 1.72 1.64 1.54 2Beryllium (Be) mg/kg <0.010 <0.010 <0.010 <0.010Beryllium (Be) mg/kg wwt <0.0020 <0.0020 0.0021 <0.0020Bismuth (Bi) mg/kg <0.010 <0.010 <0.010 <0.010Bismuth (Bi) mg/kg wwt 0.0022 <0.0020 <0.0020 <0.0020Boron (B) mg/kg <1.0 <1.0 <1.0 <1.0Boron (B) mg/kg wwt <0.20 <0.20 <0.20 <0.20Cadmium (Cd) mg/kg 0.0569 0.0872 0.122 0.109Cadmium (Cd) mg/kg wwt 0.0151 0.0191 0.029 0.0265Chromium (Cr) mg/kg 0.344 0.158 0.801 0.653Chromium (Cr) mg/kg wwt 0.092 0.035 0.19 0.159Cobalt (Co) mg/kg 0.215 0.212 0.43 0.395Cobalt (Co) mg/kg wwt 0.0571 0.0466 0.102 0.0963Copper (Cu) mg/kg 3.29 2.81 3.7 3.17Copper (Cu) mg/kg wwt 0.877 0.616 0.878 0.773Iron (Fe) mg/kg 277 141 931 483Iron (Fe) mg/kg wwt 73.6 30.9 221 118Lead (Pb) mg/kg 0.252 0.228 2.32 0.179Lead (Pb) mg/kg wwt 0.0671 0.05 0.55 0.0437Lithium (Li) mg/kg <0.50 <0.50 <0.50 <0.50Lithium (Li) mg/kg wwt <0.10 <0.10 <0.10 <0.10Manganese (Mn) mg/kg 24 11.5 23.3 33.3Manganese (Mn) mg/kg wwt 6.38 2.52 5.53 8.13Mercury (Hg) mg/kg 0.106 0.223 0.157 0.0948Mercury (Hg) mg/kg wwt 0.0282 0.0489 0.0373 0.0231Molybdenum (Mo) mg/kg 0.116 0.057 0.089 0.116Molybdenum (Mo) mg/kg wwt 0.0308 0.0125 0.0211 0.0282Nickel (Ni) mg/kg 0.51 0.26 1.29 0.81Nickel (Ni) mg/kg wwt 0.135 0.057 0.305 0.198Selenium (Se) mg/kg 1.62 2.41 1.85 1.91Selenium (Se) mg/kg wwt 0.432 0.53 0.44 0.465Silver (Ag) mg/kg <0.0050 <0.0050 0.0075 <0.0050Silver (Ag) mg/kg wwt 0.0012 <0.0010 0.0018 0.0012Strontium (Sr) mg/kg 80 104 115 89.5Strontium (Sr) mg/kg wwt 21.3 22.9 27.3 21.8Thallium (Tl) mg/kg 0.0408 0.0449 0.0449 0.0342Thallium (Tl) mg/kg wwt 0.0109 0.00985 0.0107 0.00833Tin (Sn) mg/kg <0.10 0.15 0.18 0.22Tin (Sn) mg/kg wwt 0.024 0.032 0.042 0.053Uranium (U) mg/kg 0.0275 0.0175 0.0479 0.0323Uranium (U) mg/kg wwt 0.00732 0.00384 0.0114 0.00788Vanadium (V) mg/kg 0.65 0.8 2.27 1.21Vanadium (V) mg/kg wwt 0.174 0.176 0.54 0.295Zinc (Zn) mg/kg 64.7 70.3 67 79.8Zinc (Zn) mg/kg wwt 17.2 15.4 15.9 19.5Notes:< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.
*composite of samples S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-CC-02
Units
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-6: Fish Analytical Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample ID S-5-CC-02 MT-5-CC-01 COMPOSITE *Date Sampled 17-Jun-2015 17-Jun-2015 17-Jun-2015QA/QCPhysical ParametersMoisture % 78.0 76.3 75.6Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt 1.8 3.1 1.9Acenaphthene µg/kg 8 13 7.6Acenaphthylene µg/kg wwt 1.1 0.93 1.4Acenaphthylene µg/kg 5.2 3.9 5.8Anthracene µg/kg wwt 0.52 0.49 0.91Anthracene µg/kg 2.3 2.1 3.7Benz(a)anthracene µg/kg wwt 1.5 1.2 1.9Benz(a)anthracene µg/kg 7 4.2 7.6Benzo(a)pyrene µg/kg wwt 1.1 <0.55 <0.96Benzo(a)pyrene µg/kg 4.9 <2.4 <4.0Benzo(b)fluoranthene µg/kg wwt 1.5 <0.50 <0.86Benzo(b)fluoranthene µg/kg 6.7 <2.1 <3.6Benzo(g,h,i)perylene µg/kg wwt 2.6 <0.66 <1.2Benzo(g,h,i)perylene µg/kg 12 <2.8 <4.7Benzo(k)fluoranthene µg/kg wwt 0.83 <0.33 <0.58Benzo(k)fluoranthene µg/kg 3.8 <1.4 <2.4Chrysene µg/kg wwt 0.86 1 <0.60Chrysene µg/kg 3.9 >1.5 <2.5Dibenz(a,h)anthracene µg/kg wwt <0.81 <0.65 <1.2Dibenz(a,h)anthracene µg/kg <3.7 <2.8 <4.6Dibenzofuran µg/kg wwt 1.9 2.3 1.6Dibenzofuran µg/kg 8.4 9.5 6.6Fluoranthene µg/kg wwt 2.3 2.1 2.8Fluoranthene µg/kg 10 8.9 11Fluorene µg/kg wwt 4.7 5.1 5.3Fluorene µg/kg 22 21 22Indeno(1,2,3-cd)pyrene µg/kg wwt 1.3 <0.66 <1.2Indeno(1,2,3-cd)pyrene µg/kg 6 <2.8 <4.72-Methylnaphthalene µg/kg wwt 1.4 1.9 1.62-Methylnaphthalene µg/kg 6.6 8.2 6.4Naphthalene µg/kg wwt 2.2 2.7 2.9Naphthalene µg/kg 10 11 12Phenanthrene µg/kg wwt 5.2 5.8 5.2Phenanthrene µg/kg 24 24 21Pyrene µg/kg wwt 1.4 1.2 1.3Pyrene µg/kg 6.3 5.1 5.2
Notes:
Units
< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-7: Soil QA/QC Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 13.5 13.7 0.25 1% 7.53 6.66 0.25 12%pH pH units 6.02 6.02 0.10 0% 6.43 6.52 0.10 1%Organic CarbonTotal Organic Carbon % 3.03 2.99 0.10 1% 2.03 2.07 0.10 2%MetalsAluminum (Al) mg/kg 21400 21100 50 1% 10400 10000 50 4%Antimony (Sb) mg/kg 0.72 0.71 0.1 1% 0.22 0.22 0.1 NCArsenic (As) mg/kg 8.84 9.21 0.1 4% 5.38 3.45 0.1 44%Barium (Ba) mg/kg 146 133 0.5 9% 45.9 44.3 0.5 4%Beryllium (Be) mg/kg 0.47 0.47 0.1 NC 0.17 0.15 0.1 NCBismuth (Bi) mg/kg <0.20 <0.20 0.2 NC <0.20 <0.20 0.2 NCBoron (B) mg/kg <5.0 <5.0 5 NC <5.0 <5.0 5 NCCadmium (Cd) mg/kg 0.49 0.503 0.02 3% 0.162 0.144 0.02 12%Chromium (Cr) mg/kg 50.9 50.3 0.5 1% 39.3 20.6 0.5 62%Cobalt (Co) mg/kg 13.4 13.9 0.1 4% 7.95 7.94 0.1 0%Copper (Cu) mg/kg 42.8 42.3 0.5 1% 22.1 19.2 0.5 14%Iron (Fe) mg/kg 29600 29600 50 0% 19400 18200 50 6%Lead (Pb) mg/kg 25.4 23.9 0.5 6% 3.54 3.35 0.5 6%Lithium (Li) mg/kg 19.7 19.9 2 1% 7.6 7 2 NCManganese (Mn) mg/kg 337 339 1 1% 364 348 1 4%Mercury (Hg) mg/kg 0.0725 0.0772 0.005 6% 0.0257 0.0255 0.005 1%Molybdenum (Mo) mg/kg 1.75 1.92 0.1 9% 0.45 0.45 0.1 NCNickel (Ni) mg/kg 43.1 43.8 0.5 2% 23.7 22.4 0.5 6%Selenium (Se) mg/kg 0.48 0.47 0.2 NC <0.20 <0.20 0.2 NCSilver (Ag) mg/kg <0.10 <0.10 0.1 NC <0.10 <0.10 0.1 NCStrontium (Sr) mg/kg 44.1 42.1 0.5 5% 32.1 28.7 0.5 11%Thallium (Tl) mg/kg 0.138 0.13 0.05 NC <0.050 <0.050 0.05 NCTin (Sn) mg/kg <2.0 <2.0 2 NC <2.0 <2.0 2 NCUranium (U) mg/kg 2.29 2.31 0.05 1% 0.273 0.247 0.05 10%Vanadium (V) mg/kg 69.3 68.7 0.2 1% 48.7 45.5 0.2 7%Zinc (Zn) mg/kg 129 125 2 3% 46.6 45 2 3%Notes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated
Value = exceeds 20%
UnitsMethod
Detection Limit
Relative Percent Difference
(%)
Method Detection Limit
Relative Percent Difference
(%)
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-8: Soil QA/QC Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-S-1 15-Tilbury-S-1D 15-Tilbury-S-8 15-Tilbury-S-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPolycyclic Aromatic HydrocarbonsAcenaphthene mg/kg 0.017 <0.013 0.01 NC <0.0050 <0.0050 0.005 NCAcenaphthylene mg/kg 0.019 0.016 0.01 NC <0.0050 <0.0050 0.005 NCAnthracene mg/kg 0.0603 0.012 0.008 134% <0.0040 <0.0040 0.004 NCBenz(a)anthracene mg/kg 0.173 0.025 0.02 149% <0.010 <0.010 0.01 NCBenzo(a)pyrene mg/kg 0.311 0.075 0.02 122% <0.010 <0.010 0.01 NCBenzo(b)fluoranthene mg/kg 0.572 0.133 0.02 125% <0.010 <0.010 0.01 NCBenzo(b+j+k)fluoranthene mg/kg 0.809 0.196 0.028 122% <0.015 <0.015 0.015 NCBenzo(g,h,i)perylene mg/kg 0.221 0.078 0.02 96% <0.010 <0.010 0.01 NCBenzo(k)fluoranthene mg/kg 0.237 0.063 0.02 116% <0.010 <0.010 0.01 NCChrysene mg/kg 0.269 <0.070 0.02 NC <0.010 <0.010 0.01 NCDibenz(a,h)anthracene mg/kg <0.040 <0.020 0.04 NC <0.0050 <0.0050 0.005 NCFluoranthene mg/kg 0.586 0.073 0.02 156% <0.010 <0.010 0.01 NCFluorene mg/kg 0.028 <0.025 0.02 NC <0.010 <0.010 0.01 NCIndeno(1,2,3-c,d)pyrene mg/kg 0.221 0.060 0.02 115% <0.010 <0.010 0.01 NC2-Methylnaphthalene mg/kg <0.020 <0.025 0.02 NC <0.010 <0.010 0.01 NCNaphthalene mg/kg <0.020 <0.025 0.02 NC <0.010 <0.010 0.01 NCPhenanthrene mg/kg 0.40 0.041 0.02 163% <0.010 <0.010 0.01 NCPyrene mg/kg 0.481 0.073 0.02 147% <0.010 <0.010 0.01 NCB(a)P Total Potency Equivalent mg/kg 0.456 0.114 0.028 120% <0.020 <0.020 0.02 NCNotes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; mg/kg = milligram per kilogram.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated
Value = exceeds 20%
Relative Percent Difference
(%)
Method Detection Limit
UnitsMethod
Detection Limit
Relative Percent Difference
(%)
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-9: Vegetation QA/QC Results - MetalsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample Location Farm Land Farm Land Deas Park Deas ParkSample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-8 15-Tilbury-B-8DDate Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 86.8 85.6 0.25 1% 87.6 84.6 0.25 3%Metals NCAluminum (Al) mg/kg 29.7 42.8 2 36% 3.7 5 2 NCAluminum (Al) mg/kg wwt 3.94 6.16 0.4 44% 0.46 0.76 0.4 NCAntimony (Sb) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCAntimony (Sb) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCArsenic (As) mg/kg <0.020 0.025 0.02 NC <0.020 <0.020 0.02 NCArsenic (As) mg/kg wwt <0.0040 <0.0040 0.004 NC <0.0040 <0.0040 0.004 NCBarium (Ba) mg/kg 12.3 7.58 0.05 47% 3.53 3.93 0.05 11%Barium (Ba) mg/kg wwt 1.64 1.09 0.01 40% 0.437 0.604 0.01 32%Beryllium (Be) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCBeryllium (Be) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCBismuth (Bi) mg/kg <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCBismuth (Bi) mg/kg wwt <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCBoron (B) mg/kg 18.6 14.3 1 26% 18.9 15.4 1 20%Boron (B) mg/kg wwt 2.46 2.05 0.2 18% 2.33 2.37 0.2 2%Cadmium (Cd) mg/kg 0.0709 0.0514 0.005 32% 0.0214 0.035 0.005 48%Cadmium (Cd) mg/kg wwt 0.0094 0.0074 0.001 24% 0.0026 0.0054 0.001 70%Chromium (Cr) mg/kg 0.076 0.089 0.05 NC <0.050 <0.050 0.05 NCChromium (Cr) mg/kg wwt 0.01 0.013 0.01 NC <0.010 <0.010 0.01 NCCobalt (Co) mg/kg 0.11 0.13 0.02 17% <0.020 <0.020 0.02 NCCobalt (Co) mg/kg wwt 0.0145 0.0188 0.004 NC <0.0040 <0.0040 0.004 NCCopper (Cu) mg/kg 10.6 10 0.1 6% 8.19 9.32 0.1 13%Copper (Cu) mg/kg wwt 1.4 1.44 0.02 3% 1.01 1.43 0.02 34%Iron (Fe) mg/kg 53.9 64.1 3 17% 38 35.5 3 7%Iron (Fe) mg/kg wwt 7.15 9.22 0.6 25% 4.7 5.46 0.6 15%Lead (Pb) mg/kg 0.029 0.035 0.02 NC <0.020 <0.020 0.02 NCLead (Pb) mg/kg wwt <0.0040 0.0051 0.004 NC <0.0040 <0.0040 0.004 NCLithium (Li) mg/kg <0.50 <0.50 0.5 NC <0.50 <0.50 0.5 NCLithium (Li) mg/kg wwt <0.10 <0.10 0.1 NC <0.10 <0.10 0.1 NCManganese (Mn) mg/kg 22.6 18.7 0.05 19% 19.1 17.9 0.05 6%Manganese (Mn) mg/kg wwt 2.99 2.69 0.01 11% 2.36 2.76 0.01 16%Mercury (Hg) mg/kg 0.0059 <0.0050 0.005 NC <0.0050 0.0052 0.005 NCMercury (Hg) mg/kg wwt <0.0010 <0.0010 0.001 NC <0.0010 <0.0010 0.001 NCMolybdenum (Mo) mg/kg 0.54 0.601 0.02 11% 0.759 0.317 0.02 82%Molybdenum (Mo) mg/kg wwt 0.0716 0.0864 0.004 19% 0.0939 0.0488 0.004 63%Nickel (Ni) mg/kg 2.07 1.88 0.2 10% 1.5 1.39 0.2 8%Nickel (Ni) mg/kg wwt 0.275 0.27 0.04 2% 0.186 0.214 0.04 14%Selenium (Se) mg/kg <0.050 <0.050 0.05 NC <0.050 <0.050 0.05 NCSelenium (Se) mg/kg wwt <0.010 <0.010 0.01 NC <0.010 <0.010 0.01 NCSilver (Ag) mg/kg <0.0050 <0.0050 0.005 NC <0.0050 <0.0050 0.005 NCSilver (Ag) mg/kg wwt <0.0010 <0.0010 0.001 NC <0.0010 <0.0010 0.001 NCStrontium (Sr) mg/kg 15.9 11.7 0.05 30% 11 11.2 0.05 2%Strontium (Sr) mg/kg wwt 2.11 1.68 0.01 23% 1.36 1.73 0.01 24%Thallium (Tl) mg/kg <0.0020 <0.0020 0.002 NC <0.0020 <0.0020 0.002 NCThallium (Tl) mg/kg wwt <0.00040 <0.00040 0.0004 NC <0.00040 <0.00040 0.0004 NCTin (Sn) mg/kg 0.52 0.77 0.1 39% 0.94 0.61 0.1 43%Tin (Sn) mg/kg wwt 0.069 0.111 0.02 47% 0.117 0.094 0.02 22%Uranium (U) mg/kg <0.0020 0.0024 0.002 NC <0.0020 <0.0020 0.002 NCUranium (U) mg/kg wwt <0.00040 <0.00040 0.0004 NC <0.00040 <0.00040 0.0004 NCVanadium (V) mg/kg <0.10 0.1 0.1 NC <0.10 <0.10 0.1 NCVanadium (V) mg/kg wwt <0.020 <0.020 0.02 NC <0.020 <0.020 0.02 NCZinc (Zn) mg/kg 18.4 14.8 0.5 22% 15 17 0.5 13%Zinc (Zn) mg/kg wwt 2.44 2.12 0.1 14% 1.86 2.62 0.1 34%Notes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; mg/kg = milligram per kilogram; ww = wet weight.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated
Value = exceeds 30%
UnitsMethod
Detection Limit
Relative Percent Difference
(%)
Method Detection Limit
Relative Percent Difference
(%)
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2018-10-05 Appendix 8.1-1Attachment 2
Table 2-10: Vegetation QA/QC Results - PAHsHuman Health Assessment
WesPac Tilbury Project, Delta, BC
13-1422-0049
Sample Location Farm Land Farm Land Deas Park Deas Park
Sample ID 15-Tilbury-B-1 15-Tilbury-B-1D 15-Tilbury-B-8 15-Tilbury-B-8D
Date Sampled 31-Jul-2015 31-Jul-2015 31-Jul-2015 31-Jul-2015QA/QC FDA FD FDA FDPhysical ParametersMoisture % 86.8 85.6 0.25 1% 87.6 84.6 0.25 3%Polycyclic Aromatic HydrocarbonsAcenaphthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAcenaphthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCAcenaphthylene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAcenaphthylene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCAnthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCAnthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenz(a)anthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenz(a)anthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(a)pyrene µg/kg wwt <11 <17 17 NC <12 <20 12 NCBenzo(a)pyrene µg/kg <83 <120 83 NC <96 <130 96 NCBenzo(b)fluoranthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(b)fluoranthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(g,h,i)perylene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(g,h,i)perylene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCBenzo(k)fluoranthene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCBenzo(k)fluoranthene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCChrysene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCChrysene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCDibenz(a,h)anthracene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCDibenz(a,h)anthracene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCDibenzofuran µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCDibenzofuran µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCFluoranthene µg/kg wwt <0.50 <0.50 0.50 NC 0.57 0.56 0.49 NCFluoranthene µg/kg <3.8 <3.5 3.5 NC 4.6 3.6 3.2 NCFluorene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCFluorene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCIndeno(1,2,3-cd)pyrene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCIndeno(1,2,3-cd)pyrene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NC2-Methylnaphthalene µg/kg wwt <1.0 <1.0 1.0 NC <0.99 <0.98 0.98 NC2-Methylnaphthalene µg/kg <7.6 <7.0 7.0 NC <8.0 <6.4 6.4 NCNaphthalene µg/kg wwt <1.0 <1.0 1.0 NC <0.99 <0.98 0.98 NCNaphthalene µg/kg <7.6 <7.0 7.0 NC <8.0 <6.4 6.4 NCPhenanthrene µg/kg wwt 0.78 0.8 0.50 NC 1.3 1.3 0.49 NCPhenanthrene µg/kg 5.9 5.6 3.5 NC 10 8.7 3.2 NCPyrene µg/kg wwt <0.50 <0.50 0.50 NC <0.50 <0.49 0.49 NCPyrene µg/kg <3.8 <3.5 3.5 NC <4.0 <3.2 3.2 NCNotes:Relative percent differences were not calculated for chemicals where one or more values were less than detection or if both values were within five times the method detection limit.< = not measured above the laboratory detection limit; % = percent; µg/kg = microgram per kilogram; ww = wet weight.QA/QC = quality assurance/quality control; FDA = field duplicate available; FD = field duplicateNC = not calculated
Value = exceeds 30%
UnitsMethod
Detection Limit
Relative Percent Difference
(%)
Method Detection Limit
Relative Percent Difference
(%)
O:\Final\2013\1422\13-1422-0049\1314220049-156-A-Rev0\ATT\Att 2\Att 2_Analytical Results.xlsx [B-10 RPD Veg PAH] Golder Associates Page 1 of 1
[This report shall not be reproduced except in full without the written authority of the Laboratory.]
18-JUN-15
Lab Work Order #: L1628885
Date Received:GOLDER ASSOCIATES LTD.
200-2920 Virtual WayVancouver BC V5M 0C4
ATTN: Audrey WagenaarFINAL 09-FEB-16 12:53 (MT)Report Date:
Version:
Certificate of Analysis
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company
____________________________________________
Amber Springer, B.ScAccount Manager
ADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
Client Phone: 604-297-2036
13-1422-0049/16000/16010Job Reference: NOT SUBMITTEDProject P.O. #:
10-034387C of C Numbers:Legal Site Desc:
09-FEB-16 12:53 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1628885 CONTD....
2PAGE of
Version: FINAL
5
TISSUE
Fish tissue Fish tissue Fish tissue Fish tissue17-JUN-15 17-JUN-15 17-JUN-15
MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE (S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-
CC-02)
L1628885-1 L1628885-4 L1628885-5 L1628885-8
% Moisture (%)
Aluminum (Al)-Total (mg/kg)
Aluminum (Al)-Total (mg/kg wwt)
Antimony (Sb)-Total (mg/kg)
Antimony (Sb)-Total (mg/kg wwt)
Arsenic (As)-Total (mg/kg)
Arsenic (As)-Total (mg/kg wwt)
Barium (Ba)-Total (mg/kg)
Barium (Ba)-Total (mg/kg wwt)
Beryllium (Be)-Total (mg/kg)
Beryllium (Be)-Total (mg/kg wwt)
Bismuth (Bi)-Total (mg/kg)
Bismuth (Bi)-Total (mg/kg wwt)
Boron (B)-Total (mg/kg)
Boron (B)-Total (mg/kg wwt)
Cadmium (Cd)-Total (mg/kg)
Cadmium (Cd)-Total (mg/kg wwt)
Chromium (Cr)-Total (mg/kg)
Chromium (Cr)-Total (mg/kg wwt)
Cobalt (Co)-Total (mg/kg)
Cobalt (Co)-Total (mg/kg wwt)
Copper (Cu)-Total (mg/kg)
Copper (Cu)-Total (mg/kg wwt)
Iron (Fe)-Total (mg/kg)
Iron (Fe)-Total (mg/kg wwt)
Lead (Pb)-Total (mg/kg)
Lead (Pb)-Total (mg/kg wwt)
Lithium (Li)-Total (mg/kg)
Lithium (Li)-Total (mg/kg wwt)
Manganese (Mn)-Total (mg/kg)
Manganese (Mn)-Total (mg/kg wwt)
Mercury (Hg)-Total (mg/kg)
Mercury (Hg)-Total (mg/kg wwt)
Molybdenum (Mo)-Total (mg/kg)
Molybdenum (Mo)-Total (mg/kg wwt)
Nickel (Ni)-Total (mg/kg)
Nickel (Ni)-Total (mg/kg wwt)
73.4 78.0 76.3 75.6
161 64.0 473 241
42.9 14.1 112 58.7
0.014 <0.010 0.017 0.016
0.0038 0.0021 0.0041 0.0039
0.601 0.594 0.862 1.01
0.160 0.130 0.205 0.246
6.45 7.49 6.49 8.21
1.72 1.64 1.54 2.00
<0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 0.0021 <0.0020
<0.010 <0.010 <0.010 <0.010
0.0022 <0.0020 <0.0020 <0.0020
<1.0 <1.0 <1.0 <1.0
<0.20 <0.20 <0.20 <0.20
0.0569 0.0872 0.122 0.109
0.0151 0.0191 0.0290 0.0265
0.344 0.158 0.801 0.653
0.092 0.035 0.190 0.159
0.215 0.212 0.430 0.395
0.0571 0.0466 0.102 0.0963
3.29 2.81 3.70 3.17
0.877 0.616 0.878 0.773
277 141 931 483
73.6 30.9 221 118
0.252 0.228 2.32 0.179
0.0671 0.0500 0.550 0.0437
<0.50 <0.50 <0.50 <0.50
<0.10 <0.10 <0.10 <0.10
24.0 11.5 23.3 33.3
6.38 2.52 5.53 8.13
0.106 0.223 0.157 0.0948
0.0282 0.0489 0.0373 0.0231
0.116 0.057 0.089 0.116
0.0308 0.0125 0.0211 0.0282
0.51 0.26 1.29 0.81
0.135 0.057 0.305 0.198
Physical Tests
Metals
09-FEB-16 12:53 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1628885 CONTD....
3PAGE of
Version: FINAL
5
TISSUE
Fish tissue Fish tissue Fish tissue Fish tissue17-JUN-15 17-JUN-15 17-JUN-15
MT-2-CC-01 S-5-CC-02 MT-5-CC-01 COMPOSITE (S-4-CC-01, S-5-CC-01, S-4-CC-02, MT-5-
CC-02)
L1628885-1 L1628885-4 L1628885-5 L1628885-8
Selenium (Se)-Total (mg/kg)
Selenium (Se)-Total (mg/kg wwt)
Silver (Ag)-Total (mg/kg)
Silver (Ag)-Total (mg/kg wwt)
Strontium (Sr)-Total (mg/kg)
Strontium (Sr)-Total (mg/kg wwt)
Thallium (Tl)-Total (mg/kg)
Thallium (Tl)-Total (mg/kg wwt)
Tin (Sn)-Total (mg/kg)
Tin (Sn)-Total (mg/kg wwt)
Uranium (U)-Total (mg/kg)
Uranium (U)-Total (mg/kg wwt)
Vanadium (V)-Total (mg/kg)
Vanadium (V)-Total (mg/kg wwt)
Zinc (Zn)-Total (mg/kg)
Zinc (Zn)-Total (mg/kg wwt)
1.62 2.41 1.85 1.91
0.432 0.530 0.440 0.465
<0.0050 <0.0050 0.0075 <0.0050
0.0012 <0.0010 0.0018 0.0012
80.0 104 115 89.5
21.3 22.9 27.3 21.8
0.0408 0.0449 0.0449 0.0342
0.0109 0.00985 0.0107 0.00833
<0.10 0.15 0.18 0.22
0.024 0.032 0.042 0.053
0.0275 0.0175 0.0479 0.0323
0.00732 0.00384 0.0114 0.00788
0.65 0.80 2.27 1.21
0.174 0.176 0.540 0.295
64.7 70.3 67.0 79.8
17.2 15.4 15.9 19.5
Metals
Reference Information 09-FEB-16 12:53 (MT)
L1628885 CONTD....
4PAGE of
AG-DRY-CCMS-N-VA
AG-WET-CCMS-N-VA
HG-DRY-CVAFS-N-VA
HG-WET-CVAFS-N-VA
MET-DRY-CCMS-N-VA
MET-WET-CCMS-N-VA
MOISTURE-TISS-VA
Silver in Tissue by CRC ICPMS (DRY)
Silver in Tissue by CRC ICPMS (WET)
Mercury in Tissue by CVAFS (DRY)
Mercury in Tissue by CVAFS (WET)
Metals in Tissue by CRC ICPMS (DRY)
Metals in Tissue by CRC ICPMS (WET)
% Moisture in Tissues
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Analysis is by atomic fluorescence spectrophotometry or atomic absorption spectrophotometry, adapted from US EPA Method 245.7.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Analysis is by atomic fluorescence spectrophotometry or atomic absorption spectrophotometry, adapted from US EPA Method 245.7.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This analysis is carried out gravimetrically by drying the sample at 105 C for a minimum of six hours.
ALS Test Code Test Description
Tissue
Tissue
Tissue
Tissue
Tissue
Tissue
Tissue
EPA 200.3/6020A
EPA 200.3/6020A
EPA 200.3, EPA 245.7
EPA 200.3, EPA 245.7
EPA 200.3/6020A
EPA 200.3/6020A
ASTM D2974-00 Method A
Method Reference**
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
Matrix
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location
Test Method References:
Chain of Custody Numbers:
10-034387
Version: FINAL
5
Reference Information 09-FEB-16 12:53 (MT)
L1628885 CONTD....
5PAGE of
GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.
Version: FINAL
5
Quality Control ReportPage 1 of
Client:
Contact:
GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Audrey Wagenaar
Report Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
AG-DRY-CCMS-N-VA
AG-WET-CCMS-N-VA
HG-DRY-CVAFS-N-VA
HG-WET-CVAFS-N-VA
Tissue
Tissue
Tissue
Tissue
R3328428
R3328428
R3328399
R3328398
Batch
Batch
Batch
Batch
CRM
DUP
LCS
MB
CRM
DUP
LCS
MB
CRM
DUP
LCS
MB
CRM
DUP
LCS
MB
WG2228293-3
WG2228293-2
WG2228293-4
WG2228293-1
WG2228293-3
WG2228293-2
WG2228293-4
WG2228293-1
WG2228293-3
WG2228293-2
WG2228293-4
WG2228293-1
WG2228293-3
WG2228293-2
WG2228293-4
WG2228293-1
VA-NIST-1566B
L1628885-1
VA-NIST-1566B
L1628885-1
VA-NIST-1566B
L1628885-1
VA-NIST-1566B
L1628885-1
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
103.3
<0.0050
85.8
<0.0050
103.3
0.0011
85.8
<0.0010
91.8
0.113
102.9
<0.0050
91.8
0.0300
102.9
<0.0010
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
10-DEC-15
N/A
14
6.3
6.3
40
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
mg/kg
%
mg/kg
%
mg/kg wwt
%
mg/kg wwt
%
mg/kg
%
mg/kg
%
mg/kg wwt
%
mg/kg wwt
0.005
0.001
0.005
0.001
RPD-NA<0.0050
0.0012
0.106
0.0282
8
Quality Control ReportPage 2 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA Tissue
R3328428BatchCRM
DUP
WG2228293-3
WG2228293-2
VA-NIST-1566B
L1628885-1
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
105.2
105.3
99.1
105.5
97.8
104.3
107.3
106.8
108.1
108.5
106.5
111.2
105.9
96.1
103.2
108.8
103.2
132
0.013
0.585
5.02
<0.010
<0.010
<1.0
0.0557
0.291
0.194
3.26
226
0.207
<0.50
19.4
0.111
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
20
11
2.7
25
N/A
N/A
N/A
2.2
17
10
1.2
20
20
N/A
21
4.0
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RPD-NA
RPD-NA
RPD-NA
RPD-NA
161
0.014
0.601
6.45
<0.010
<0.010
<1.0
0.0569
0.344
0.215
3.29
277
0.252
<0.50
24.0
0.116
8
Quality Control ReportPage 3 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA Tissue
R3328428BatchDUP
LCS
MB
WG2228293-2
WG2228293-4
WG2228293-1
L1628885-1Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
0.44
1.69
66.6
0.0315
<0.10
0.0231
0.54
61.1
101.1
99.8
96.9
98.4
93.0
97.9
92.4
96.2
98.1
98.8
98.5
95.5
97.0
93.1
99.7
97.4
98.9
99.0
95.4
97.5
98.0
95.7
101.3
95.0
<2.0
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
14
4.0
18
26
N/A
17
20
5.7
40
40
60
40
40
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg 2
RPD-NA
0.51
1.62
80.0
0.0408
<0.10
0.0275
0.65
64.7
8
Quality Control ReportPage 4 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA
MET-WET-CCMS-N-VA
Tissue
Tissue
R3328428
R3331853
R3328428
Batch
Batch
Batch
MB
CRM
CRM
WG2228293-1
WG2228293-3
WG2228293-3
VA-NIST-1566B
VA-NIST-1566B
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
<0.010
<0.020
<0.050
<0.010
<0.010
<1.0
<0.0050
<0.050
<0.020
<0.10
<3.0
<0.020
<0.50
<0.050
<0.020
<0.20
<0.050
<0.050
<0.0020
<0.10
<0.0020
<0.10
<0.50
0.012
105.2
105.3
99.1
105.5
97.8
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
11-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
0-0.018
70-130
70-130
70-130
70-130
70-130
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
0.01
0.02
0.05
0.01
0.01
1
0.005
0.05
0.02
0.1
3
0.02
0.5
0.05
0.02
0.2
0.05
0.05
0.002
0.1
0.002
0.1
0.5
8
Quality Control ReportPage 5 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA Tissue
R3328428BatchCRM
DUP
WG2228293-3
WG2228293-2
VA-NIST-1566B
L1628885-1
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
104.3
107.3
106.8
108.1
108.5
106.5
111.2
105.9
96.1
103.2
108.8
103.2
35.1
0.0034
0.156
1.34
<0.0020
<0.0020
<0.20
0.0148
0.077
0.0517
0.867
60.1
0.0551
<0.10
5.16
0.0296
0.117
0.450
17.7
0.00837
0.022
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
20
11
2.7
25
N/A
N/A
N/A
2.2
17
10
1.2
20
20
N/A
21
4.0
14
4.0
18
26
8.4
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
60
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
RPD-NA
RPD-NA
RPD-NA
RPD-NA
42.9
0.0038
0.160
1.72
<0.0020
0.0022
<0.20
0.0151
0.092
0.0571
0.877
73.6
0.0671
<0.10
6.38
0.0308
0.135
0.432
21.3
0.0109
0.024
8
Quality Control ReportPage 6 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA Tissue
R3328428BatchDUP
LCS
MB
WG2228293-2
WG2228293-4
WG2228293-1
L1628885-1Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
0.00615
0.143
16.3
101.1
99.8
96.9
98.4
93.0
97.9
92.4
96.2
98.1
98.8
98.5
95.5
97.0
93.1
99.7
97.4
98.9
99.0
95.4
97.5
98.0
95.7
101.3
95.0
<0.40
<0.0020
<0.0040
<0.010
<0.0020
<0.0020
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
17
20
5.7
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
mg/kg wwt
mg/kg wwt
mg/kg wwt
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
0.4
0.002
0.004
0.01
0.002
0.002
0.00732
0.174
17.2
8
Quality Control ReportPage 7 ofReport Date: 09-FEB-16Workorder: L1628885
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA
MOISTURE-TISS-VA
Tissue
Tissue
R3328428
R3331853
R3329162
Batch
Batch
Batch
MB
CRM
DUP
WG2228293-1
WG2228293-3
WG2230479-3
VA-NIST-1566B
L1628885-1
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Antimony (Sb)-Total
% Moisture
<0.20
<0.0010
<0.010
<0.0040
<0.020
<0.60
<0.0040
<0.10
<0.010
<0.0040
<0.040
<0.010
<0.010
<0.00040
<0.020
<0.00040
<0.020
<0.10
0.0118
74.8
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
09-DEC-15
11-DEC-15
11-DEC-151.9 20
0-0.0177
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
%
0.2
0.001
0.01
0.004
0.02
0.6
0.004
0.1
0.01
0.004
0.04
0.01
0.01
0.0004
0.02
0.0004
0.02
0.1
73.4
8
Quality Control ReportPage 8 ofReport Date: 09-FEB-16Workorder: L1628885
Sample Parameter Qualifier Definitions:
Description Qualifier
RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.
Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate
Legend:
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
Hold Time Exceedances:
All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
8
February 03, 2016 Analytical Report for Service Request No: K1600229
Ms. Amber SpringerALS Environmental - Canada8081 Lougheed HwyBurnaby, BC V5A 1W9
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.
For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory January 08, 2016
RE: L1628885
Dear Ms.Springer,
K1600229.
Please contact me if you have any questions. My extension is 3376. You may also contact me via email at [email protected].
Respectfully submitted,
ALS Group USA, Corp. dba ALS Environmental
Gregory Salata, Ph.D.Client Services Manager
ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626
+1 360 577 7222+1 360 636 1068
T :F :
ALS Environmental
www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
www.alsglobal.com
ALS Environmental
F :T :
+1 360 636 1068+1 360 577 7222
Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp
Table of Contents
RIGHT SOLUTIONS | RIGHT PARTNER
Acronyms
Qualifiers
State Certifications, Accreditations, And Licenses
Case Narrative
Chain of Custody
General Chemistry
Polynuclear Aromatic Hydrocarbons
Raw Data
Polynuclear Aromatic Hydrocarbons
ASTM American Society for Testing and Materials
A2LA American Association for Laboratory Accreditation
CARB California Air Resources Board
CAS Number Chemical Abstract Service registry Number
CFC Chlorofluorocarbon
CFU Colony-Forming Unit
DEC Department of Environmental Conservation
DEQ Department of Environmental Quality
DHS Department of Health Services
DOE Department of Ecology
DOH Department of Health
EPA U. S. Environmental Protection Agency
ELAP Environmental Laboratory Accreditation Program
GC Gas Chromatography
GC/MS Gas Chromatography/Mass Spectrometry
LOD Limit of Detection
LOQ Limit of Quantitation
LUFT Leaking Underground Fuel Tank
M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance
allowed in drinking water as established by the USEPA.
MDL Method Detection Limit
MPN Most Probable Number
MRL Method Reporting Limit
NA Not Applicable
NC Not Calculated
NCASI National Council of the Paper Industry for Air and Stream Improvement
ND Not Detected
NIOSH National Institute for Occupational Safety and Health
PQL Practical Quantitation Limit
RCRA Resource Conservation and Recovery Act
SIM Selected Ion Monitoring
TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or
equal to the MDL.
Acronyms
Inorganic Data Qualifiers
* The result is an outlier. See case narrative.
# The control limit criteria is not applicable. See case narrative.
B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.
E The result is an estimate amount because the value exceeded the instrument calibration range.
J The result is an estimated value.
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.
X See case narrative.
Q See case narrative. One or more quality control criteria was outside the limits.
H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.
Metals Data Qualifiers
# The control limit criteria is not applicable. See case narrative.
J The result is an estimated value.
E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.
M The duplicate injection precision was not met.
N The Matrix Spike sample recovery is not within control limits. See case narrative.
S The reported value was determined by the Method of Standard Additions (MSA).
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.
i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.
X See case narrative.
+ The correlation coefficient for the MSA is less than 0.995.
Q See case narrative. One or more quality control criteria was outside the limits.
Organic Data Qualifiers
* The result is an outlier. See case narrative.
# The control limit criteria is not applicable. See case narrative.
A A tentatively identified compound, a suspected aldol-condensation product.
B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.
C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.
D The reported result is from a dilution.
E The result is an estimated value.
J The result is an estimated value.
N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.
PThe GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.
X See case narrative.
Q See case narrative. One or more quality control criteria was outside the limits.
Additional Petroleum Hydrocarbon Specific Qualifiers
F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.
L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.
H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.
O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.
Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard.
Z The chromatographic fingerprint does not resemble a petroleum product.
Agency Web Site Number
Alaska DEC UST http://dec.alaska.gov/applications/eh/ehllabreports/USTLabs.aspx UST-040
Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339
Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637
California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795
DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L14-51
Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412
Hawaii DOH Not available -
Idaho DHWhttp://www.healthandwelfare.idaho.gov/Health/Labs/CertificationDrinkingWaterLabs/tabid/1833/Default.aspx -
ISO 17025 http://www.pjlabs.com/ L14-50
Louisiana DEQhttp://www.deq.louisiana.gov/portal/DIVISIONS/PublicParticipationandPermitSupport/LouisianaLaboratoryAccreditationProgram.aspx 03016
Maine DHS Not available WA01276
Michigan DEQ http://www.michigan.gov/deq/0,1607,7-135-3307_4131_4156---,00.html 9949
Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457
Montana DPHHS http://www.dphhs.mt.gov/publichealth/ CERT0047
Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276
New Jersey DEP http://www.nj.gov/dep/oqa/ WA005
North Carolina DWQ http://www.dwqlab.org/ 605
Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801
Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010
South Carolina DHEC http://www.scdhec.gov/environment/envserv/ 61002
Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427
Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544
Wisconsin DNR http://dnr.wi.gov/ 998386840
Wyoming (EPA Region 8) http://www.epa.gov/region8/water/dwhome/wyomingdi.html -
Kelso Laboratory Website www.alsglobal.com NA
ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.
Case Narrative
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
Approved by______________________________________________
ALS ENVIRONMENTAL
Client: ALS Environmental - Canada Service Request No.: K1600229 Project: L1628885 Date Received: 01/08/16Sample Matrix: Animal Tissue
Case Narrative
All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II validation deliverables including summary forms and all of the associated raw data for each of the analyses. When appropriate to the method, method blank results have been reported with each analytical test.
Sample Receipt
Four animal tissue samples were received for analysis at ALS Environmental on 01/08/16. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored frozen at –20ºC upon receipt at the laboratory.
Polynuclear Aromatic Hydrocarbons by EPA Method 8270
Surrogate Exceptions: The upper control criterion was exceeded by 1% for the surrogate Fluoranthene-d10 in sample Method Blank (MB) KWG1600316-3. The error associated with elevated recovery equates to a potential slight high bias. The result was flagged to indicate the issue. No further corrective action was taken.
No other anomalies associated with the analysis of these samples were observed.
Chain of Custody
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
f/11Ltoo2,1A L1628885
~...-. .... ,.., Enu&ronmental
Subcontract Request Form
Subcontract To:
ALS ENVIRONMENTAL- KELSO, WASHINGTON, USA 1317 S. 13TH AVE KELSO,WA 98626
NOTES: Please reference on final report and invoice: PO# L/628885
ALS requires QC data to be provided with your final results.
Please see enclosed
SAMPLE NUMBER
~ sample(s) in
ANALYTICAL REQUIRED
4. Container(s)
DATE SAMPLED
DUE DATE
L1628885-1 MT-2-CC-01 6/17/2015
Special Request- Kelso (SPECIAL REQUEST-KL 14) 12/17/2015
L1628885-4 S-5-CC-02 6/ 17/ 2015
Special Request- Kelso (SPECIAL REQUEST-KL 14) 12/17/2015
L1628885-5 MT-5-CC-01 6/ 17/ 2015
Special Request- Kelso (SPECIAL REQUEST-KL 14) 12/17/2015
L1628885-8 COMPOSITE
Special Request- Kelso (SPECIAL REQUEST-KL 14) 12/17/2015
Subcontract Info Contact:
Analysis and reporting info contact:
Walter Lin (604) 253-4188
Amber Springer, B.Sc 8081 LOUGHEED HWY SUITE 100 BURNABY,BC V5A 1W9
VANCOUVER
Priority Flag
Phone: (604) 253-4188 Email: [email protected]
Please email confirmation of receipt to: [email protected]
Shipped By: ______________ Date Shipped:
i ] 't/ll.c 1 OLJD Received By: '~'"' Date Received: Tl
Verified By: _______________ Date Verified:
Temperature:
Sample Integrity Issues:
Monday, December 21, 2015 11:42 AM Page 1 of 1
Client lfi..:J/:tt~ . ]Sf_,~ Opened· !jo7; ~= PC'Jdu_n-. role'£ 8,, ' ""~•KI6 f}Q;i,:Jq ="'if Unloaded~: 1~/x~/;~~~~+-~ J7 (f? By:~
Cooler Receipt and Preservation Form
1. Samples were received via? UPS DHL PDX Courier Hand Delivered
2. Samples were received in: (circle)
3. Were custody seals on coolers?
Box Envelope Other NA
y@ If yes, how many and where?
If present, were custody seals intact? y N If present, were they signed and dated? y N . ..
Rawr'<J>l, Corrected. Raw Corrected Corr •. · ThermOmeter Cooler/CDC I~ , .· Tracking Number CoolerT p COoler 'rem Tem.P-al~nk nm~·Biailk · Factor . ID N~ . · ...
• NA Filed
~.1' X", {C) ·-·· -· . c/ ;--)~'":~- P:::~N 1'?/RO Lfq I/) ~-
,, li
rylce ~
5. Were custody papers properly filled out (ink, signed, etc.)?
6. Did all bottles arrive in good condition (unbroken)? Indicate in the table below.
7. Were all sample labels complete (i.e analysis, preservation, etc.)?
8. Did all sample labels and tags agree with custody papers? Indicate major discrepancies in the table on page 2.
9. Were appropriate bottles/containers and volumes received for the tests indicated?
l 0. Were the pH-preserved bottles (see SMO GEN SOP) received at the appropriate pH? Indicate in the table below
ll. Were VOA vials received without headspace? Indicate in the table below.
Sam le ID on Bottle Sam le ID on COC Identified by:
.
N NA~ NA . · :_.; '*" NA · 'CJ (fiJ'
'{.!:./ N
NA <J2 NA C) @Y ~ y
-
N
N
N
N
Bottle Count Out of Head· Volume Reagent Lot Sample ID Bottle Type Temp space Broke pH Reagent added Number. Initials Time
L J {.P Z?SK:>S~3 ·( f ·zo~ X ' /ttl .<;aawLtd ~n7. X .
:Lf{g_1Xf&:5 -I aM.uJ:I-f' d /onrKt../1 'f: 'ianz ni"<J fMz0.& ru:rf i f1Ck7rtdualiO bulzkiGLarzyjJ "
1
)/-{- Jnr 1 (/ h1d ,_2412LIJ~cf ~--,]·--·-- l
Page~~of __
General Chemistry
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
K1600229ALS Environmental - Canada
L1628885
Polynuclear Aromatic Hydrocarbons
Cover Page - Organic Analysis Data Package
Client:
Project:
Service Request:
Date
Collected
Date
ReceivedLab CodeSample Name
ALS Group USA, Corp. dba ALS Environmental
K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02
K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01
K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite
Cover Page - Organic 1of1Page
RR185774SuperSet Reference:u:\Stealth\Crystal.rpt\FormSSum.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-002
ug/Kg
Wet
L1628885-4 S-5-CC-02
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
8.6 01/12/161 KWG160031601/25/160.40J2.2Naphthalene
8.6 01/12/161 KWG160031601/25/160.66J1.42-Methylnaphthalene
8.6 01/12/161 KWG160031601/25/160.49J1.1Acenaphthylene
8.6 01/12/161 KWG160031601/25/160.88J1.8Acenaphthene
8.6 01/12/161 KWG160031601/25/160.42J1.9Dibenzofuran
8.6 01/12/161 KWG160031601/25/160.50J4.7Fluorene
8.6 01/12/161 KWG160031601/25/160.21J5.2Phenanthrene
8.6 01/12/161 KWG160031601/25/160.31J0.52Anthracene
8.6 01/12/161 KWG160031601/25/160.56J2.3Fluoranthene
8.6 01/12/161 KWG160031601/25/160.30J1.4Pyrene
8.6 01/12/161 KWG160031601/25/160.52J1.5Benz(a)anthracene
8.6 01/12/161 KWG160031601/25/160.43J0.86Chrysene
8.6 01/12/161 KWG160031601/25/160.62J1.5Benzo(b)fluoranthene†
8.6 01/12/161 KWG160031601/25/160.42J0.83Benzo(k)fluoranthene
8.6 01/12/161 KWG160031601/25/160.69J1.1Benzo(a)pyrene
8.6 01/12/161 KWG160031601/25/160.83J1.3Indeno(1,2,3-cd)pyrene
8.6 01/12/161 KWG160031601/25/160.81UNDDibenz(a,h)anthracene
8.6 01/12/161 KWG160031601/25/160.83J2.6Benzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 AcceptableFluoranthene-d10 01/25/1699
39-111 AcceptableTerphenyl-d14 01/25/16102
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:0801/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-003
ug/Kg
Wet
L1628885-5 MT-5-CC-01
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 01/12/161 KWG160031601/25/160.32J2.7Naphthalene
6.9 01/12/161 KWG160031601/25/160.53J1.92-Methylnaphthalene
6.9 01/12/161 KWG160031601/25/160.39J0.93Acenaphthylene
6.9 01/12/161 KWG160031601/25/160.70J3.1Acenaphthene
6.9 01/12/161 KWG160031601/25/160.33J2.3Dibenzofuran
6.9 01/12/161 KWG160031601/25/160.40J5.1Fluorene
6.9 01/12/161 KWG160031601/25/160.17J5.8Phenanthrene
6.9 01/12/161 KWG160031601/25/160.25J0.49Anthracene
6.9 01/12/161 KWG160031601/25/160.44J2.1Fluoranthene
6.9 01/12/161 KWG160031601/25/160.24J1.2Pyrene
6.9 01/12/161 KWG160031601/25/160.42J1.0Benz(a)anthracene
6.9 01/12/161 KWG160031601/25/160.35UNDChrysene
6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†
6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene
6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene
6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene
6.9 01/12/161 KWG160031601/25/160.65UNDDibenz(a,h)anthracene
6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1682
41-100 AcceptableFluoranthene-d10 01/25/1693
39-111 AcceptableTerphenyl-d14 01/25/1694
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:1201/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-004
ug/Kg
Wet
L1628885-8 Composite
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
12 01/12/161 KWG160031601/25/160.55J2.9Naphthalene
12 01/12/161 KWG160031601/25/160.91J1.62-Methylnaphthalene
12 01/12/161 KWG160031601/25/160.67J1.4Acenaphthylene
12 01/12/161 KWG160031601/25/161.3J1.9Acenaphthene
12 01/12/161 KWG160031601/25/160.58J1.6Dibenzofuran
12 01/12/161 KWG160031601/25/160.70J5.3Fluorene
12 01/12/161 KWG160031601/25/160.29J5.2Phenanthrene
12 01/12/161 KWG160031601/25/160.43J0.91Anthracene
12 01/12/161 KWG160031601/25/160.77J2.8Fluoranthene
12 01/12/161 KWG160031601/25/160.41J1.3Pyrene
12 01/12/161 KWG160031601/25/160.72J1.9Benz(a)anthracene
12 01/12/161 KWG160031601/25/160.60UNDChrysene
12 01/12/161 KWG160031601/25/160.86UNDBenzo(b)fluoranthene†
12 01/12/161 KWG160031601/25/160.58UNDBenzo(k)fluoranthene
12 01/12/161 KWG160031601/25/160.96UNDBenzo(a)pyrene
12 01/12/161 KWG160031601/25/161.2UNDIndeno(1,2,3-cd)pyrene
12 01/12/161 KWG160031601/25/161.2UNDDibenz(a,h)anthracene
12 01/12/161 KWG160031601/25/161.2UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1683
41-100 AcceptableFluoranthene-d10 01/25/1698
39-111 AcceptableTerphenyl-d14 01/25/1696
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:1601/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
KWG1600316-3
ug/Kg
Wet
Method Blank
NA
NA
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 01/12/161 KWG160031601/25/160.32J1.1Naphthalene
6.9 01/12/161 KWG160031601/25/160.53UND2-Methylnaphthalene
6.9 01/12/161 KWG160031601/25/160.39UNDAcenaphthylene
6.9 01/12/161 KWG160031601/25/160.70UNDAcenaphthene
6.9 01/12/161 KWG160031601/25/160.33UNDDibenzofuran
6.9 01/12/161 KWG160031601/25/160.40UNDFluorene
6.9 01/12/161 KWG160031601/25/160.17J0.42Phenanthrene
6.9 01/12/161 KWG160031601/25/160.25UNDAnthracene
6.9 01/12/161 KWG160031601/25/160.44UNDFluoranthene
6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene
6.9 01/12/161 KWG160031601/25/160.42J0.81Benz(a)anthracene
6.9 01/12/161 KWG160031601/25/160.35UNDChrysene
6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†
6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene
6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene
6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene
6.9 01/12/161 KWG160031601/25/160.65UNDDibenz(a,h)anthracene
6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 Outside Control LimitsFluoranthene-d10 01/25/16101
39-111 AcceptableTerphenyl-d14 01/25/16110
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:2001/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
ALS Group USA, Corp. dba ALS Environmental
Extraction Method:
QA/QC Report
Surrogate Recovery Summary
ALS Environmental - Canada K1600229
Low
Animal tissue
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Units:
Level:
Sample Name Lab Code
Polynuclear Aromatic Hydrocarbons
EPA 3541
Analysis Method: 8270D SIM
Sur1 Sur2 Sur3
Percent
K1600229-002L1628885-4 S-5-CC-02 90 99 102
K1600229-003L1628885-5 MT-5-CC-01 82 93 94
K1600229-004L1628885-8 Composite 83 98 96
KWG1600316-3 *Method Blank 90 101 110
KWG1600316-1Lab Control Sample 86 95 92
KWG1600316-2Duplicate Lab Control Sample 82 90 88
Form 2A - OrganicPrinted: 01/29/2016 10:03:25 1 of 1
Surrogate Recovery Control Limits (%)
39-96
41-100
39-111
Fluorene-d10
Fluoranthene-d10
Terphenyl-d14
Results flagged with an asterisk (*) indicate values outside control criteria.
Page
Results flagged with a pound (#) indicate the control criteria is not applicable.
RR185774SuperSet Reference:
Sur1
Sur2
Sur3
=
=
=
u:\Stealth\Crystal.rpt\Form2.rpt
Lab Control Spike/Duplicate Lab Control Spike Summary
%Rec
Lab Control Spike
%Rec
Limits
Duplicate Lab Control Spike
%Rec RPD
RPD
Limit
QA/QC Report
Duplicate Lab Control Sample
KWG1600316-2
ALS Environmental - Canada K1600229
8270D SIM
ug/Kg
Wet
Lab Control Sample
KWG1600316-1
Polynuclear Aromatic Hydrocarbons
KWG1600316
Animal tissue
Low
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Extraction Method:
Analysis Method:
Units:
Basis:
Level:
Extraction Lot:
Analyte Name Result Result
ALS Group USA, Corp. dba ALS Environmental
Date Extracted:
Date Analyzed:
01/12/2016
01/25/2016
EPA 3541
Spike
Amount
Spike
Amount
43-102500 76 40Naphthalene 500 81 6403 379
43-114500 73 402-Methylnaphthalene 500 77 6387 365
53-100500 78 40Acenaphthylene 500 83 7416 388
52-101500 77 40Acenaphthene 500 83 8413 383
55-103500 79 40Dibenzofuran 500 82 4412 394
56-104500 77 40Fluorene 500 84 9419 385
54-100500 73 40Phenanthrene 500 79 9397 363
57-103500 83 40Anthracene 500 90 9451 413
55-108500 80 40Fluoranthene 500 87 9435 399
48-117500 79 40Pyrene 500 85 7425 394
55-105500 74 40Benz(a)anthracene 500 82 10411 370
58-112500 85 40Chrysene 500 92 8461 425
60-107500 83 40Benzo(b)fluoranthene 500 90 8452 417
58-115500 87 40Benzo(k)fluoranthene 500 95 9474 433
56-110500 75 40Benzo(a)pyrene 500 83 10413 376
50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296
52-112500 54 40Dibenz(a,h)anthracene 500 64 17319 268
56-117500 73 40Benzo(g,h,i)perylene 500 79 9397 365
Form 3C - OrganicPrinted: 01/29/2016 10:04:00 Page 1 of 1
Results flagged with an asterisk (*) indicate values outside control criteria.
RR185774SuperSet Reference:
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
u:\Stealth\Crystal.rpt\Form3DLC.rpt
Polynuclear Aromatic Hydrocarbons
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
K1600229ALS Environmental - Canada
L1628885
Polynuclear Aromatic Hydrocarbons
Cover Page - Organic Analysis Data Package
Client:
Project:
Service Request:
Date
Collected
Date
ReceivedLab CodeSample Name
ALS Group USA, Corp. dba ALS Environmental
K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02
K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01
K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite
Cover Page - Organic 1of1Page
RR185821SuperSet Reference:u:\Stealth\Crystal.rpt\FormSSum.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-002
ug/Kg
Dry
L1628885-4 S-5-CC-02
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
40 01/12/161 KWG160031601/25/161.8J10Naphthalene
40 01/12/161 KWG160031601/25/163.0J6.62-Methylnaphthalene
40 01/12/161 KWG160031601/25/162.2J5.2Acenaphthylene
40 01/12/161 KWG160031601/25/164.0J8.0Acenaphthene
40 01/12/161 KWG160031601/25/161.9J8.4Dibenzofuran
40 01/12/161 KWG160031601/25/162.3J22Fluorene
40 01/12/161 KWG160031601/25/160.94J24Phenanthrene
40 01/12/161 KWG160031601/25/161.5J2.3Anthracene
40 01/12/161 KWG160031601/25/162.6J10Fluoranthene
40 01/12/161 KWG160031601/25/161.4J6.3Pyrene
40 01/12/161 KWG160031601/25/162.4J7.0Benz(a)anthracene
40 01/12/161 KWG160031601/25/162.0J3.9Chrysene
40 01/12/161 KWG160031601/25/162.9J6.7Benzo(b)fluoranthene†
40 01/12/161 KWG160031601/25/161.9J3.8Benzo(k)fluoranthene
40 01/12/161 KWG160031601/25/163.2J4.9Benzo(a)pyrene
40 01/12/161 KWG160031601/25/163.8J6.0Indeno(1,2,3-cd)pyrene
40 01/12/161 KWG160031601/25/163.7UNDDibenz(a,h)anthracene
40 01/12/161 KWG160031601/25/163.8J12Benzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 AcceptableFluoranthene-d10 01/25/1699
39-111 AcceptableTerphenyl-d14 01/25/16102
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page17:34:0201/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185821u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-003
ug/Kg
Dry
L1628885-5 MT-5-CC-01
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
29 01/12/161 KWG160031601/25/161.4J11Naphthalene
29 01/12/161 KWG160031601/25/162.2J8.22-Methylnaphthalene
29 01/12/161 KWG160031601/25/161.7J3.9Acenaphthylene
29 01/12/161 KWG160031601/25/163.0J13Acenaphthene
29 01/12/161 KWG160031601/25/161.4J9.5Dibenzofuran
29 01/12/161 KWG160031601/25/161.7J21Fluorene
29 01/12/161 KWG160031601/25/160.70J24Phenanthrene
29 01/12/161 KWG160031601/25/161.1J2.1Anthracene
29 01/12/161 KWG160031601/25/161.9J8.9Fluoranthene
29 01/12/161 KWG160031601/25/160.99J5.1Pyrene
29 01/12/161 KWG160031601/25/161.8J4.2Benz(a)anthracene
29 01/12/161 KWG160031601/25/161.5UNDChrysene
29 01/12/161 KWG160031601/25/162.1UNDBenzo(b)fluoranthene†
29 01/12/161 KWG160031601/25/161.4UNDBenzo(k)fluoranthene
29 01/12/161 KWG160031601/25/162.4UNDBenzo(a)pyrene
29 01/12/161 KWG160031601/25/162.8UNDIndeno(1,2,3-cd)pyrene
29 01/12/161 KWG160031601/25/162.8UNDDibenz(a,h)anthracene
29 01/12/161 KWG160031601/25/162.8UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1682
41-100 AcceptableFluoranthene-d10 01/25/1693
39-111 AcceptableTerphenyl-d14 01/25/1694
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page17:34:0601/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185821u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-004
ug/Kg
Dry
L1628885-8 Composite
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
49 01/12/161 KWG160031601/25/162.3J12Naphthalene
49 01/12/161 KWG160031601/25/163.8J6.42-Methylnaphthalene
49 01/12/161 KWG160031601/25/162.8J5.8Acenaphthylene
49 01/12/161 KWG160031601/25/165.0J7.6Acenaphthene
49 01/12/161 KWG160031601/25/162.4J6.6Dibenzofuran
49 01/12/161 KWG160031601/25/162.9J22Fluorene
49 01/12/161 KWG160031601/25/161.2J21Phenanthrene
49 01/12/161 KWG160031601/25/161.8J3.7Anthracene
49 01/12/161 KWG160031601/25/163.2J11Fluoranthene
49 01/12/161 KWG160031601/25/161.7J5.2Pyrene
49 01/12/161 KWG160031601/25/163.0J7.6Benz(a)anthracene
49 01/12/161 KWG160031601/25/162.5UNDChrysene
49 01/12/161 KWG160031601/25/163.6UNDBenzo(b)fluoranthene†
49 01/12/161 KWG160031601/25/162.4UNDBenzo(k)fluoranthene
49 01/12/161 KWG160031601/25/164.0UNDBenzo(a)pyrene
49 01/12/161 KWG160031601/25/164.7UNDIndeno(1,2,3-cd)pyrene
49 01/12/161 KWG160031601/25/164.6UNDDibenz(a,h)anthracene
49 01/12/161 KWG160031601/25/164.7UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1683
41-100 AcceptableFluoranthene-d10 01/25/1698
39-111 AcceptableTerphenyl-d14 01/25/1696
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page17:34:1001/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185821u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
KWG1600316-3
ug/Kg
Dry
Method Blank
NA
NA
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 01/12/161 KWG160031601/25/160.32J1.1Naphthalene
6.9 01/12/161 KWG160031601/25/160.53UND2-Methylnaphthalene
6.9 01/12/161 KWG160031601/25/160.39UNDAcenaphthylene
6.9 01/12/161 KWG160031601/25/160.70UNDAcenaphthene
6.9 01/12/161 KWG160031601/25/160.33UNDDibenzofuran
6.9 01/12/161 KWG160031601/25/160.40UNDFluorene
6.9 01/12/161 KWG160031601/25/160.17J0.42Phenanthrene
6.9 01/12/161 KWG160031601/25/160.25UNDAnthracene
6.9 01/12/161 KWG160031601/25/160.44UNDFluoranthene
6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene
6.9 01/12/161 KWG160031601/25/160.42J0.81Benz(a)anthracene
6.9 01/12/161 KWG160031601/25/160.35UNDChrysene
6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†
6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene
6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene
6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene
6.9 01/12/161 KWG160031601/25/160.65UNDDibenz(a,h)anthracene
6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 Outside Control LimitsFluoranthene-d10 01/25/16101
39-111 AcceptableTerphenyl-d14 01/25/16110
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page17:34:1401/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185821u:\Stealth\Crystal.rpt\Form1mNew.rpt
ALS Group USA, Corp. dba ALS Environmental
Extraction Method:
QA/QC Report
Surrogate Recovery Summary
ALS Environmental - Canada K1600229
Low
Animal tissue
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Units:
Level:
Sample Name Lab Code
Polynuclear Aromatic Hydrocarbons
EPA 3541
Analysis Method: 8270D SIM
Sur1 Sur2 Sur3
Percent
K1600229-002L1628885-4 S-5-CC-02 90 99 102
K1600229-003L1628885-5 MT-5-CC-01 82 93 94
K1600229-004L1628885-8 Composite 83 98 96
KWG1600316-3 *Method Blank 90 101 110
KWG1600316-1Lab Control Sample 86 95 92
KWG1600316-2Duplicate Lab Control Sample 82 90 88
Form 2A - OrganicPrinted: 01/29/2016 17:34:19 1 of 1
Surrogate Recovery Control Limits (%)
39-96
41-100
39-111
Fluorene-d10
Fluoranthene-d10
Terphenyl-d14
Results flagged with an asterisk (*) indicate values outside control criteria.
Page
Results flagged with a pound (#) indicate the control criteria is not applicable.
RR185821SuperSet Reference:
Sur1
Sur2
Sur3
=
=
=
u:\Stealth\Crystal.rpt\Form2.rpt
Lab Control Spike/Duplicate Lab Control Spike Summary
%Rec
Lab Control Spike
%Rec
Limits
Duplicate Lab Control Spike
%Rec RPD
RPD
Limit
QA/QC Report
Duplicate Lab Control Sample
KWG1600316-2
ALS Environmental - Canada K1600229
8270D SIM
ug/Kg
Dry
Lab Control Sample
KWG1600316-1
Polynuclear Aromatic Hydrocarbons
KWG1600316
Animal tissue
Low
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Extraction Method:
Analysis Method:
Units:
Basis:
Level:
Extraction Lot:
Analyte Name Result Result
ALS Group USA, Corp. dba ALS Environmental
Date Extracted:
Date Analyzed:
01/12/2016
01/25/2016
EPA 3541
Spike
Amount
Spike
Amount
43-102500 76 40Naphthalene 500 81 6403 379
43-114500 73 402-Methylnaphthalene 500 77 6387 365
53-100500 78 40Acenaphthylene 500 83 7416 388
52-101500 77 40Acenaphthene 500 83 8413 383
55-103500 79 40Dibenzofuran 500 82 4412 394
56-104500 77 40Fluorene 500 84 9419 385
54-100500 73 40Phenanthrene 500 79 9397 363
57-103500 83 40Anthracene 500 90 9451 413
55-108500 80 40Fluoranthene 500 87 9435 399
48-117500 79 40Pyrene 500 85 7425 394
55-105500 74 40Benz(a)anthracene 500 82 10411 370
58-112500 85 40Chrysene 500 92 8461 425
60-107500 83 40Benzo(b)fluoranthene 500 90 8452 417
58-115500 87 40Benzo(k)fluoranthene 500 95 9474 433
56-110500 75 40Benzo(a)pyrene 500 83 10413 376
50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296
52-112500 54 40Dibenz(a,h)anthracene 500 64 17319 268
56-117500 73 40Benzo(g,h,i)perylene 500 79 9397 365
Form 3C - OrganicPrinted: 01/29/2016 17:34:47 Page 1 of 1
Results flagged with an asterisk (*) indicate values outside control criteria.
RR185821SuperSet Reference:
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
u:\Stealth\Crystal.rpt\Form3DLC.rpt
K1600229ALS Environmental - Canada
L1628885
Polynuclear Aromatic Hydrocarbons
Cover Page - Organic Analysis Data Package
Client:
Project:
Service Request:
Date
Collected
Date
ReceivedLab CodeSample Name
ALS Group USA, Corp. dba ALS Environmental
K1600229-002 06/17/2015 01/08/2016L1628885-4 S-5-CC-02
K1600229-003 06/17/2015 01/08/2016L1628885-5 MT-5-CC-01
K1600229-004 06/17/2015 01/08/2016L1628885-8 Composite
Cover Page - Organic 1of1Page
RR185774SuperSet Reference:u:\Stealth\Crystal.rpt\FormSSum.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-002
ug/Kg
Wet
L1628885-4 S-5-CC-02
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
8.6 01/12/161 KWG160031601/25/160.40J2.2Naphthalene
8.6 01/12/161 KWG160031601/25/160.66J1.42-Methylnaphthalene
8.6 01/12/161 KWG160031601/25/160.49J1.1Acenaphthylene
8.6 01/12/161 KWG160031601/25/160.88J1.8Acenaphthene
8.6 01/12/161 KWG160031601/25/160.42J1.9Dibenzofuran
8.6 01/12/161 KWG160031601/25/160.50J4.7Fluorene
8.6 01/12/161 KWG160031601/25/160.21J5.2Phenanthrene
8.6 01/12/161 KWG160031601/25/160.31J0.52Anthracene
8.6 01/12/161 KWG160031601/25/160.56J2.3Fluoranthene
8.6 01/12/161 KWG160031601/25/160.30J1.4Pyrene
8.6 01/12/161 KWG160031601/25/160.52J1.5Benz(a)anthracene
8.6 01/12/161 KWG160031601/25/160.43J0.86Chrysene
8.6 01/12/161 KWG160031601/25/160.62J1.5Benzo(b)fluoranthene†
8.6 01/12/161 KWG160031601/25/160.42J0.83Benzo(k)fluoranthene
8.6 01/12/161 KWG160031601/25/160.69J1.1Benzo(a)pyrene
8.6 01/12/161 KWG160031601/25/160.83J1.3Indeno(1,2,3-cd)pyrene
8.6 01/12/161 KWG160031601/25/160.81UNDDibenz(a,h)anthracene
8.6 01/12/161 KWG160031601/25/160.83J2.6Benzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 AcceptableFluoranthene-d10 01/25/1699
39-111 AcceptableTerphenyl-d14 01/25/16102
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:0801/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-003
ug/Kg
Wet
L1628885-5 MT-5-CC-01
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 01/12/161 KWG160031601/25/160.32J2.7Naphthalene
6.9 01/12/161 KWG160031601/25/160.53J1.92-Methylnaphthalene
6.9 01/12/161 KWG160031601/25/160.39J0.93Acenaphthylene
6.9 01/12/161 KWG160031601/25/160.70J3.1Acenaphthene
6.9 01/12/161 KWG160031601/25/160.33J2.3Dibenzofuran
6.9 01/12/161 KWG160031601/25/160.40J5.1Fluorene
6.9 01/12/161 KWG160031601/25/160.17J5.8Phenanthrene
6.9 01/12/161 KWG160031601/25/160.25J0.49Anthracene
6.9 01/12/161 KWG160031601/25/160.44J2.1Fluoranthene
6.9 01/12/161 KWG160031601/25/160.24J1.2Pyrene
6.9 01/12/161 KWG160031601/25/160.42J1.0Benz(a)anthracene
6.9 01/12/161 KWG160031601/25/160.35UNDChrysene
6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†
6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene
6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene
6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene
6.9 01/12/161 KWG160031601/25/160.65UNDDibenz(a,h)anthracene
6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1682
41-100 AcceptableFluoranthene-d10 01/25/1693
39-111 AcceptableTerphenyl-d14 01/25/1694
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:1201/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
K1600229-004
ug/Kg
Wet
L1628885-8 Composite
06/17/2015
01/08/2016
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
12 01/12/161 KWG160031601/25/160.55J2.9Naphthalene
12 01/12/161 KWG160031601/25/160.91J1.62-Methylnaphthalene
12 01/12/161 KWG160031601/25/160.67J1.4Acenaphthylene
12 01/12/161 KWG160031601/25/161.3J1.9Acenaphthene
12 01/12/161 KWG160031601/25/160.58J1.6Dibenzofuran
12 01/12/161 KWG160031601/25/160.70J5.3Fluorene
12 01/12/161 KWG160031601/25/160.29J5.2Phenanthrene
12 01/12/161 KWG160031601/25/160.43J0.91Anthracene
12 01/12/161 KWG160031601/25/160.77J2.8Fluoranthene
12 01/12/161 KWG160031601/25/160.41J1.3Pyrene
12 01/12/161 KWG160031601/25/160.72J1.9Benz(a)anthracene
12 01/12/161 KWG160031601/25/160.60UNDChrysene
12 01/12/161 KWG160031601/25/160.86UNDBenzo(b)fluoranthene†
12 01/12/161 KWG160031601/25/160.58UNDBenzo(k)fluoranthene
12 01/12/161 KWG160031601/25/160.96UNDBenzo(a)pyrene
12 01/12/161 KWG160031601/25/161.2UNDIndeno(1,2,3-cd)pyrene
12 01/12/161 KWG160031601/25/161.2UNDDibenz(a,h)anthracene
12 01/12/161 KWG160031601/25/161.2UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1683
41-100 AcceptableFluoranthene-d10 01/25/1698
39-111 AcceptableTerphenyl-d14 01/25/1696
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:1601/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
Analytical Results
ALS Environmental - Canada K1600229
KWG1600316-3
ug/Kg
Wet
Method Blank
NA
NA
L1628885
Animal tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMDLMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 01/12/161 KWG160031601/25/160.32J1.1Naphthalene
6.9 01/12/161 KWG160031601/25/160.53UND2-Methylnaphthalene
6.9 01/12/161 KWG160031601/25/160.39UNDAcenaphthylene
6.9 01/12/161 KWG160031601/25/160.70UNDAcenaphthene
6.9 01/12/161 KWG160031601/25/160.33UNDDibenzofuran
6.9 01/12/161 KWG160031601/25/160.40UNDFluorene
6.9 01/12/161 KWG160031601/25/160.17J0.42Phenanthrene
6.9 01/12/161 KWG160031601/25/160.25UNDAnthracene
6.9 01/12/161 KWG160031601/25/160.44UNDFluoranthene
6.9 01/12/161 KWG160031601/25/160.24J0.51Pyrene
6.9 01/12/161 KWG160031601/25/160.42J0.81Benz(a)anthracene
6.9 01/12/161 KWG160031601/25/160.35UNDChrysene
6.9 01/12/161 KWG160031601/25/160.50UNDBenzo(b)fluoranthene†
6.9 01/12/161 KWG160031601/25/160.33UNDBenzo(k)fluoranthene
6.9 01/12/161 KWG160031601/25/160.55UNDBenzo(a)pyrene
6.9 01/12/161 KWG160031601/25/160.66UNDIndeno(1,2,3-cd)pyrene
6.9 01/12/161 KWG160031601/25/160.65UNDDibenz(a,h)anthracene
6.9 01/12/161 KWG160031601/25/160.66UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 01/25/1690
41-100 Outside Control LimitsFluoranthene-d10 01/25/16101
39-111 AcceptableTerphenyl-d14 01/25/16110
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:03:2001/29/2016Printed: Form 1A - Organic
Merged SuperSet Reference: RR185774u:\Stealth\Crystal.rpt\Form1mNew.rpt
ALS Group USA, Corp. dba ALS Environmental
Extraction Method:
QA/QC Report
Surrogate Recovery Summary
ALS Environmental - Canada K1600229
Low
Animal tissue
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Units:
Level:
Sample Name Lab Code
Polynuclear Aromatic Hydrocarbons
EPA 3541
Analysis Method: 8270D SIM
Sur1 Sur2 Sur3
Percent
K1600229-002L1628885-4 S-5-CC-02 90 99 102
K1600229-003L1628885-5 MT-5-CC-01 82 93 94
K1600229-004L1628885-8 Composite 83 98 96
KWG1600316-3 *Method Blank 90 101 110
KWG1600316-1Lab Control Sample 86 95 92
KWG1600316-2Duplicate Lab Control Sample 82 90 88
Form 2A - OrganicPrinted: 01/29/2016 10:03:25 1 of 1
Surrogate Recovery Control Limits (%)
39-96
41-100
39-111
Fluorene-d10
Fluoranthene-d10
Terphenyl-d14
Results flagged with an asterisk (*) indicate values outside control criteria.
Page
Results flagged with a pound (#) indicate the control criteria is not applicable.
RR185774SuperSet Reference:
Sur1
Sur2
Sur3
=
=
=
u:\Stealth\Crystal.rpt\Form2.rpt
Lab Control Spike/Duplicate Lab Control Spike Summary
%Rec
Lab Control Spike
%Rec
Limits
Duplicate Lab Control Spike
%Rec RPD
RPD
Limit
QA/QC Report
Duplicate Lab Control Sample
KWG1600316-2
ALS Environmental - Canada K1600229
8270D SIM
ug/Kg
Wet
Lab Control Sample
KWG1600316-1
Polynuclear Aromatic Hydrocarbons
KWG1600316
Animal tissue
Low
L1628885
Client:
Project:
Sample Matrix:
Service Request:
Extraction Method:
Analysis Method:
Units:
Basis:
Level:
Extraction Lot:
Analyte Name Result Result
ALS Group USA, Corp. dba ALS Environmental
Date Extracted:
Date Analyzed:
01/12/2016
01/25/2016
EPA 3541
Spike
Amount
Spike
Amount
43-102500 76 40Naphthalene 500 81 6403 379
43-114500 73 402-Methylnaphthalene 500 77 6387 365
53-100500 78 40Acenaphthylene 500 83 7416 388
52-101500 77 40Acenaphthene 500 83 8413 383
55-103500 79 40Dibenzofuran 500 82 4412 394
56-104500 77 40Fluorene 500 84 9419 385
54-100500 73 40Phenanthrene 500 79 9397 363
57-103500 83 40Anthracene 500 90 9451 413
55-108500 80 40Fluoranthene 500 87 9435 399
48-117500 79 40Pyrene 500 85 7425 394
55-105500 74 40Benz(a)anthracene 500 82 10411 370
58-112500 85 40Chrysene 500 92 8461 425
60-107500 83 40Benzo(b)fluoranthene 500 90 8452 417
58-115500 87 40Benzo(k)fluoranthene 500 95 9474 433
56-110500 75 40Benzo(a)pyrene 500 83 10413 376
50-117500 59 40Indeno(1,2,3-cd)pyrene 500 67 13337 296
52-112500 54 40Dibenz(a,h)anthracene 500 64 17319 268
56-117500 73 40Benzo(g,h,i)perylene 500 79 9397 365
Form 3C - OrganicPrinted: 01/29/2016 10:04:00 Page 1 of 1
Results flagged with an asterisk (*) indicate values outside control criteria.
RR185774SuperSet Reference:
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
u:\Stealth\Crystal.rpt\Form3DLC.rpt
[This report shall not be reproduced except in full without the written authority of the Laboratory.]
31-JUL-15
Lab Work Order #: L1651409
Date Received:GOLDER ASSOCIATES LTD.
200-2920 Virtual WayVancouver BC V5M 0C4
ATTN: Ann-Marie NorrisFINAL REV. 201-DEC-15 16:59 (MT)Report Date:
Version:
Certificate of Analysis
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company
____________________________________________
Amber Springer, B.ScAccount Manager
ADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
Client Phone: 604-296-4200
1-DEC-2015 The list of reported Metals has been adjusted.Comments:
13/1422-0049/16000/16120Job Reference: NOT SUBMITTEDProject P.O. #:
14-475217, 14-475220C of C Numbers:Legal Site Desc:
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
2PAGE of
* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-1 15-TILBURY-S-2 15-TILBURY-S-1D 15-TILBURY-S-3 15-TILBURY-S-4
L1651409-1 L1651409-2 L1651409-3 L1651409-4 L1651409-5
Moisture (%)
pH (1:2 soil:water) (pH)
Total Organic Carbon (%)
Aluminum (Al) (mg/kg)
Antimony (Sb) (mg/kg)
Arsenic (As) (mg/kg)
Barium (Ba) (mg/kg)
Beryllium (Be) (mg/kg)
Bismuth (Bi) (mg/kg)
Boron (B) (mg/kg)
Cadmium (Cd) (mg/kg)
Chromium (Cr) (mg/kg)
Cobalt (Co) (mg/kg)
Copper (Cu) (mg/kg)
Iron (Fe) (mg/kg)
Lead (Pb) (mg/kg)
Lithium (Li) (mg/kg)
Manganese (Mn) (mg/kg)
Mercury (Hg) (mg/kg)
Molybdenum (Mo) (mg/kg)
Nickel (Ni) (mg/kg)
Selenium (Se) (mg/kg)
Silver (Ag) (mg/kg)
Strontium (Sr) (mg/kg)
Thallium (Tl) (mg/kg)
Tin (Sn) (mg/kg)
Uranium (U) (mg/kg)
Vanadium (V) (mg/kg)
Zinc (Zn) (mg/kg)
Acenaphthene (mg/kg)
Acenaphthylene (mg/kg)
Anthracene (mg/kg)
Benz(a)anthracene (mg/kg)
Benzo(a)pyrene (mg/kg)
Benzo(b)fluoranthene (mg/kg)
Benzo(b+j+k)fluoranthene (mg/kg)
13.5 10.4 13.7 15.4 4.03
6.02 6.16 6.02 5.80 6.40
3.03 2.28 2.99 2.37 0.97
21400 11300 21100 16000 16300
0.72 0.39 0.71 0.98 0.54
8.84 4.19 9.21 6.55 5.65
146 70.1 133 83.8 59.1
0.47 0.23 0.47 0.29 0.23
<0.20 <0.20 <0.20 <0.20 <0.20
<5.0 <5.0 <5.0 <5.0 <5.0
0.490 0.179 0.503 0.350 0.274
50.9 29.1 50.3 35.1 23.8
13.4 8.32 13.9 11.3 10.9
42.8 26.4 42.3 44.0 41.7
29600 20100 29600 27700 29300
25.4 20.8 23.9 65.8 9.99
19.7 9.4 19.9 14.3 14.7
337 310 339 432 504
0.0725 0.0256 0.0772 0.0322 0.0114
1.75 0.87 1.92 1.26 0.77
43.1 21.5 43.8 27.5 18.5
0.48 <0.20 0.47 0.28 0.38
<0.10 <0.10 <0.10 0.11 0.10
44.1 33.2 42.1 33.6 34.7
0.138 0.064 0.130 0.076 0.060
<2.0 <2.0 <2.0 <2.0 <2.0
2.29 0.573 2.31 0.662 0.340
69.3 47.5 68.7 66.2 72.5
129 131 125 116 90.1
0.017 0.039 <0.013 <0.0050 <0.0050
0.019 <0.010 0.016 0.0107 <0.0050
0.0603 0.0632 0.012 0.0065 <0.0040
0.173 0.121 0.025 0.017 <0.010
0.311 0.217 0.075 0.024 <0.010
0.572 0.413 0.133 0.041 0.011
0.809 0.585 0.196 0.055 <0.015
Physical Tests
Organic / Inorganic Carbon
Metals
Polycyclic Aromatic Hydrocarbons
DLA
DLA
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
3PAGE of
* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-5 15-TILBURY-S-6 15-TILBURY-S-7 15-TILBURY-S-8 15-TILBURY-S-9
L1651409-6 L1651409-7 L1651409-8 L1651409-9 L1651409-10
Moisture (%)
pH (1:2 soil:water) (pH)
Total Organic Carbon (%)
Aluminum (Al) (mg/kg)
Antimony (Sb) (mg/kg)
Arsenic (As) (mg/kg)
Barium (Ba) (mg/kg)
Beryllium (Be) (mg/kg)
Bismuth (Bi) (mg/kg)
Boron (B) (mg/kg)
Cadmium (Cd) (mg/kg)
Chromium (Cr) (mg/kg)
Cobalt (Co) (mg/kg)
Copper (Cu) (mg/kg)
Iron (Fe) (mg/kg)
Lead (Pb) (mg/kg)
Lithium (Li) (mg/kg)
Manganese (Mn) (mg/kg)
Mercury (Hg) (mg/kg)
Molybdenum (Mo) (mg/kg)
Nickel (Ni) (mg/kg)
Selenium (Se) (mg/kg)
Silver (Ag) (mg/kg)
Strontium (Sr) (mg/kg)
Thallium (Tl) (mg/kg)
Tin (Sn) (mg/kg)
Uranium (U) (mg/kg)
Vanadium (V) (mg/kg)
Zinc (Zn) (mg/kg)
Acenaphthene (mg/kg)
Acenaphthylene (mg/kg)
Anthracene (mg/kg)
Benz(a)anthracene (mg/kg)
Benzo(a)pyrene (mg/kg)
Benzo(b)fluoranthene (mg/kg)
Benzo(b+j+k)fluoranthene (mg/kg)
4.27 5.62 6.33 7.53 3.24
6.76 6.27 6.54 6.43 6.61
0.54 1.23 4.79 2.03 0.38
15700 8540 10400 10400 9250
<0.10 0.29 0.28 0.22 0.21
1.88 3.73 2.62 5.38 3.49
86.3 54.9 50.8 45.9 45.8
0.31 0.19 0.18 0.17 0.20
<0.20 <0.20 0.68 <0.20 <0.20
<5.0 <5.0 10.3 <5.0 <5.0
0.029 0.094 0.277 0.162 0.091
4.78 29.8 25.4 39.3 32.3
5.35 8.01 9.20 7.95 8.28
3.90 15.8 44.9 22.1 14.1
17500 17600 18600 19400 20300
1.33 5.85 4.93 3.54 4.47
<2.0 7.6 6.4 7.6 7.3
370 327 378 364 341
<0.0050 0.0267 0.0350 0.0257 0.0480
0.87 0.46 0.46 0.45 0.37
4.06 30.1 26.8 23.7 32.8
<0.20 <0.20 <0.20 <0.20 <0.20
<0.10 <0.10 <0.10 <0.10 <0.10
74.6 31.8 43.7 32.1 25.2
<0.050 0.057 0.055 <0.050 <0.050
<2.0 <2.0 <2.0 <2.0 <2.0
0.660 0.307 0.299 0.273 0.297
24.4 40.5 43.2 48.7 49.8
31.6 37.4 69.0 46.6 42.6
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0070 <0.0040 <0.0040 <0.0040 <0.0040
<0.020 <0.010 <0.010 <0.010 <0.010
0.024 <0.010 <0.010 <0.010 <0.010
0.070 <0.010 <0.010 <0.010 <0.010
0.096 <0.015 <0.015 <0.015 <0.015
Physical Tests
Organic / Inorganic Carbon
Metals
Polycyclic Aromatic Hydrocarbons
DLM
DLQ
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-10 15-TILBURY-S-11 15-TILBURY-S-8-D 15-TILBURY-S-12 15-TILBURY-S-13
L1651409-11 L1651409-12 L1651409-13 L1651409-14 L1651409-15
Moisture (%)
pH (1:2 soil:water) (pH)
Total Organic Carbon (%)
Aluminum (Al) (mg/kg)
Antimony (Sb) (mg/kg)
Arsenic (As) (mg/kg)
Barium (Ba) (mg/kg)
Beryllium (Be) (mg/kg)
Bismuth (Bi) (mg/kg)
Boron (B) (mg/kg)
Cadmium (Cd) (mg/kg)
Chromium (Cr) (mg/kg)
Cobalt (Co) (mg/kg)
Copper (Cu) (mg/kg)
Iron (Fe) (mg/kg)
Lead (Pb) (mg/kg)
Lithium (Li) (mg/kg)
Manganese (Mn) (mg/kg)
Mercury (Hg) (mg/kg)
Molybdenum (Mo) (mg/kg)
Nickel (Ni) (mg/kg)
Selenium (Se) (mg/kg)
Silver (Ag) (mg/kg)
Strontium (Sr) (mg/kg)
Thallium (Tl) (mg/kg)
Tin (Sn) (mg/kg)
Uranium (U) (mg/kg)
Vanadium (V) (mg/kg)
Zinc (Zn) (mg/kg)
Acenaphthene (mg/kg)
Acenaphthylene (mg/kg)
Anthracene (mg/kg)
Benz(a)anthracene (mg/kg)
Benzo(a)pyrene (mg/kg)
Benzo(b)fluoranthene (mg/kg)
Benzo(b+j+k)fluoranthene (mg/kg)
8.30 8.91 6.66 27.0 11.0
7.57 7.89 6.52 6.71 6.73
2.95 1.51 2.07 3.50 4.28
12400 8720 10000 14700 13400
1.27 1.34 0.22 0.70 0.59
6.48 16.4 3.45 8.23 6.03
69.7 47.8 44.3 110 79.8
0.26 0.16 0.15 0.35 0.31
<0.20 <0.20 <0.20 <0.20 <0.20
<5.0 <5.0 <5.0 <5.0 <5.0
0.236 0.469 0.144 0.414 0.271
28.7 17.8 20.6 42.8 35.7
8.59 5.24 7.94 13.9 12.1
29.9 21.8 19.2 35.2 32.7
22100 15300 18200 29100 25000
26.2 33.7 3.35 93.7 14.2
11.0 5.5 7.0 14.8 14.0
294 314 348 533 347
0.0611 0.0519 0.0255 0.0823 0.0633
1.05 0.95 0.45 1.04 1.04
24.2 15.5 22.4 43.4 38.0
<0.20 <0.20 <0.20 0.48 0.28
<0.10 0.11 <0.10 0.10 <0.10
47.9 149 28.7 57.3 46.0
0.067 <0.050 <0.050 0.103 0.084
<2.0 6.0 <2.0 <2.0 <2.0
0.717 1.06 0.247 1.23 0.878
49.0 30.0 45.5 55.0 50.6
85.6 96.6 45.0 129 87.1
0.024 0.0123 <0.0050 <0.0050 <0.010
0.029 0.0097 <0.0050 0.0076 0.027
0.078 0.0364 <0.0040 0.0088 0.0218
0.212 0.099 <0.010 0.034 0.058
0.400 0.084 <0.010 0.037 0.104
0.554 0.122 <0.010 0.051 0.170
0.809 0.173 <0.015 0.072 0.243
Physical Tests
Organic / Inorganic Carbon
Metals
Polycyclic Aromatic Hydrocarbons
DLA
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL31-JUL-15 31-JUL-15
15-TILBURY-S-14 15-TILBURY-S-15
L1651409-16 L1651409-17
Moisture (%)
pH (1:2 soil:water) (pH)
Total Organic Carbon (%)
Aluminum (Al) (mg/kg)
Antimony (Sb) (mg/kg)
Arsenic (As) (mg/kg)
Barium (Ba) (mg/kg)
Beryllium (Be) (mg/kg)
Bismuth (Bi) (mg/kg)
Boron (B) (mg/kg)
Cadmium (Cd) (mg/kg)
Chromium (Cr) (mg/kg)
Cobalt (Co) (mg/kg)
Copper (Cu) (mg/kg)
Iron (Fe) (mg/kg)
Lead (Pb) (mg/kg)
Lithium (Li) (mg/kg)
Manganese (Mn) (mg/kg)
Mercury (Hg) (mg/kg)
Molybdenum (Mo) (mg/kg)
Nickel (Ni) (mg/kg)
Selenium (Se) (mg/kg)
Silver (Ag) (mg/kg)
Strontium (Sr) (mg/kg)
Thallium (Tl) (mg/kg)
Tin (Sn) (mg/kg)
Uranium (U) (mg/kg)
Vanadium (V) (mg/kg)
Zinc (Zn) (mg/kg)
Acenaphthene (mg/kg)
Acenaphthylene (mg/kg)
Anthracene (mg/kg)
Benz(a)anthracene (mg/kg)
Benzo(a)pyrene (mg/kg)
Benzo(b)fluoranthene (mg/kg)
Benzo(b+j+k)fluoranthene (mg/kg)
6.32 13.5
6.37 4.87
1.46 1.87
15300 17300
0.47 0.50
4.06 7.76
58.7 67.7
0.22 0.29
<0.20 <0.20
<5.0 <5.0
0.305 0.136
26.2 49.1
10.4 8.18
42.0 35.3
27100 32100
36.7 19.9
14.5 17.1
499 224
0.0296 0.0674
0.66 1.35
18.2 28.5
0.34 0.39
0.10 0.11
34.4 40.3
<0.050 0.105
<2.0 <2.0
0.372 1.08
73.0 65.6
89.4 67.7
<0.0050 <0.0050
<0.0050 0.0096
0.0058 0.0067
<0.010 0.024
<0.010 0.027
0.030 0.046
0.030 0.065
Physical Tests
Organic / Inorganic Carbon
Metals
Polycyclic Aromatic Hydrocarbons
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-1 15-TILBURY-S-2 15-TILBURY-S-1D 15-TILBURY-S-3 15-TILBURY-S-4
L1651409-1 L1651409-2 L1651409-3 L1651409-4 L1651409-5
Benzo(g,h,i)perylene (mg/kg)
Benzo(k)fluoranthene (mg/kg)
Chrysene (mg/kg)
Dibenz(a,h)anthracene (mg/kg)
Fluoranthene (mg/kg)
Fluorene (mg/kg)
Indeno(1,2,3-c,d)pyrene (mg/kg)
2-Methylnaphthalene (mg/kg)
Naphthalene (mg/kg)
Phenanthrene (mg/kg)
Pyrene (mg/kg)
Surrogate: Acenaphthene d10 (%)
Surrogate: Chrysene d12 (%)
Surrogate: Naphthalene d8 (%)
Surrogate: Phenanthrene d10 (%)
B(a)P Total Potency Equivalent (mg/kg)
IACR (CCME) (mg/kg)
0.221 0.175 0.078 0.020 <0.010
0.237 0.172 0.063 0.014 <0.010
0.269 <0.30 <0.070 0.032 <0.010
<0.040 <0.040 <0.020 0.0055 <0.0050
0.586 0.398 0.073 0.031 0.016
0.028 0.035 <0.025 <0.010 <0.010
0.221 0.139 0.060 0.019 <0.010
<0.020 <0.020 <0.025 <0.010 <0.010
<0.020 0.023 <0.025 <0.010 <0.010
0.404 0.397 0.041 0.028 <0.010
0.481 0.352 0.073 0.033 0.013
100.9 123.9 100.2 94.5 97.1
79.3 103.6 80.9 97.5 111.3
76.0 94.8 78.1 84.1 91.8
98.5 120.9 96.2 100.9 111.6
0.456 0.325 0.114 0.039 <0.020
6.75 4.85 1.60 0.51 <0.15
Polycyclic Aromatic Hydrocarbons
DLM DLM
DLM DLM DLM
DLA
DLA DLA DLM
DLA DLA
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-5 15-TILBURY-S-6 15-TILBURY-S-7 15-TILBURY-S-8 15-TILBURY-S-9
L1651409-6 L1651409-7 L1651409-8 L1651409-9 L1651409-10
Benzo(g,h,i)perylene (mg/kg)
Benzo(k)fluoranthene (mg/kg)
Chrysene (mg/kg)
Dibenz(a,h)anthracene (mg/kg)
Fluoranthene (mg/kg)
Fluorene (mg/kg)
Indeno(1,2,3-c,d)pyrene (mg/kg)
2-Methylnaphthalene (mg/kg)
Naphthalene (mg/kg)
Phenanthrene (mg/kg)
Pyrene (mg/kg)
Surrogate: Acenaphthene d10 (%)
Surrogate: Chrysene d12 (%)
Surrogate: Naphthalene d8 (%)
Surrogate: Phenanthrene d10 (%)
B(a)P Total Potency Equivalent (mg/kg)
IACR (CCME) (mg/kg)
0.012 <0.010 <0.010 <0.010 <0.010
0.026 <0.010 <0.010 <0.010 <0.010
0.064 <0.010 <0.010 <0.010 <0.010
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
0.056 <0.010 <0.010 <0.010 <0.010
<0.010 <0.010 <0.020 <0.010 <0.010
0.015 <0.010 <0.010 <0.010 <0.010
<0.010 <0.010 <0.010 <0.010 <0.010
<0.010 <0.010 <0.010 <0.010 <0.010
<0.010 <0.010 <0.010 <0.010 <0.010
0.058 <0.010 <0.010 <0.010 <0.010
81.0 93.3 100.0 85.4 92.5
90.8 96.1 101.5 93.7 98.3
76.7 81.5 92.2 78.8 85.7
91.1 100.0 102.2 95.9 100.4
0.039 <0.020 <0.020 <0.020 <0.020
0.74 <0.15 <0.15 <0.15 <0.15
Polycyclic Aromatic Hydrocarbons
DLM
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL SOIL SOIL SOIL31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-S-10 15-TILBURY-S-11 15-TILBURY-S-8-D 15-TILBURY-S-12 15-TILBURY-S-13
L1651409-11 L1651409-12 L1651409-13 L1651409-14 L1651409-15
Benzo(g,h,i)perylene (mg/kg)
Benzo(k)fluoranthene (mg/kg)
Chrysene (mg/kg)
Dibenz(a,h)anthracene (mg/kg)
Fluoranthene (mg/kg)
Fluorene (mg/kg)
Indeno(1,2,3-c,d)pyrene (mg/kg)
2-Methylnaphthalene (mg/kg)
Naphthalene (mg/kg)
Phenanthrene (mg/kg)
Pyrene (mg/kg)
Surrogate: Acenaphthene d10 (%)
Surrogate: Chrysene d12 (%)
Surrogate: Naphthalene d8 (%)
Surrogate: Phenanthrene d10 (%)
B(a)P Total Potency Equivalent (mg/kg)
IACR (CCME) (mg/kg)
0.251 0.054 <0.010 0.021 0.068
0.255 0.051 <0.010 0.021 0.074
0.274 0.135 <0.010 0.054 0.091
<0.040 0.0127 <0.0050 0.0056 <0.020
0.476 0.197 <0.010 0.073 0.116
0.028 0.015 <0.010 <0.010 <0.020
0.219 0.059 <0.010 0.024 0.059
<0.025 0.012 <0.010 <0.010 <0.020
<0.025 0.011 <0.010 0.011 <0.020
0.332 0.180 <0.010 0.038 0.056
0.613 0.207 <0.010 0.077 0.129
97.6 94.4 82.8 89.6 92.2
80.9 99.4 88.3 97.6 77.6
75.8 86.5 77.3 84.0 70.4
92.7 100.7 91.7 100.4 89.9
0.550 0.132 <0.020 0.056 0.152
7.11 1.76 <0.15 0.72 2.10
Polycyclic Aromatic Hydrocarbons
DLM DLM
DLA
DLA DLA
DLA DLA
01-DEC-15 16:59 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651409 CONTD....
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* Please refer to the Reference Information section for an explanation of any qualifiers detected.
Version: FINAL REV. 2
11
SOIL
SOIL SOIL31-JUL-15 31-JUL-15
15-TILBURY-S-14 15-TILBURY-S-15
L1651409-16 L1651409-17
Benzo(g,h,i)perylene (mg/kg)
Benzo(k)fluoranthene (mg/kg)
Chrysene (mg/kg)
Dibenz(a,h)anthracene (mg/kg)
Fluoranthene (mg/kg)
Fluorene (mg/kg)
Indeno(1,2,3-c,d)pyrene (mg/kg)
2-Methylnaphthalene (mg/kg)
Naphthalene (mg/kg)
Phenanthrene (mg/kg)
Pyrene (mg/kg)
Surrogate: Acenaphthene d10 (%)
Surrogate: Chrysene d12 (%)
Surrogate: Naphthalene d8 (%)
Surrogate: Phenanthrene d10 (%)
B(a)P Total Potency Equivalent (mg/kg)
IACR (CCME) (mg/kg)
0.013 0.016
<0.010 0.019
<0.030 0.041
<0.0050 <0.0050
0.020 0.065
<0.010 <0.010
<0.010 0.020
<0.010 <0.010
<0.010 <0.010
0.010 0.040
0.019 0.060
93.7 81.9
93.9 90.3
84.4 74.8
99.3 93.6
<0.020 0.041
0.27 0.59
Polycyclic Aromatic Hydrocarbons
DLM
Reference Information
DLA
DLM
DLQ
Detection Limit adjusted for required dilution
Detection Limit Adjusted due to sample matrix effects.
Detection Limit raised due to co-eluting interference. GCMS qualifier ion ratio did not meet acceptance criteria.
Qualifiers for Individual Parameters Listed:
Description Qualifier
01-DEC-15 16:59 (MT)
L1651409 CONTD....
10PAGE of
C-TOT-ORG-LECO-SK
HG-200.2-CVAF-VA
MET-200.2-CCMS-VA
MOISTURE-VA
PAH-TMB-H/A-MS-VA
PH-1:2-VA
Organic Carbon by combustion method
Mercury in Soil by CVAFS
Metals in Soil by CRC ICPMS
Moisture content
PAH - Rotary Extraction (Hexane/Acetone)
pH in Soil (1:2 Soil:Water Extraction)
Total Organic Carbon (C-TOT-ORG-LECO-SK, C-TOT-ORG-SK)
Total C and inorganic C are determined on separate samples. The total C is determined by combustion and thermal conductivity detection, while inorganic C is determined by weight lass after addition of hydrochloric acid. Organic C is calculated by the difference between these two determinations.
Reference for Total C:Nelson, D.W. and Sommers, L.E. 1996. Total Carbon, organic carbon and organic matter. P. 961-1010 In: J.M. Bartels et al. (ed.) Methods of soil analysis: Part 3 Chemical methods. (3rd ed.) ASA and SSSA, Madison, WI. Book series no. 5
Reference for Inorganic C:Loeppert, R.H. and Suarez, D.L. 1996. Gravimetric Method for Loss of Carbon Dioxide. P. 455-456 In: J.M. Bartels et al. (ed.) Methods of soil analysis:Part 3 Chemical methods. (3rd ed.) ASA and SSSA, Madison, WI. Book series no. 5
Soil samples are digested with nitric and hydrochloric acids, followed by analysis by CVAFS.
Soil samples are digested with nitric and hydrochloric acids, followed by analysis by CRC ICPMS. Method Limitation: This method is not a total digestion technique. It is a very strong acid digestion that is intended to dissolve those metals that may be environmentally available. This method does not dissolve all silicate materials and may result in a partial extraction. depending on the sample matrix, for some metals, including, but not limited to Al, Ba, Be, Cr, Sr, Ti, Tl, and V.
This analysis is carried out gravimetrically by drying the sample at 105 C for a minimum of six hours.
This analysis is carried out using procedures adapted from "Test Methods for Evaluating Solid Waste" SW-846, Methods 3570 & 8270, published by the United States Environmental Protection Agency (EPA). The procedure uses a mechanical shaking technique to extract a subsample of the sediment/soil with a 1:1 mixture of hexane and acetone. The extract is then solvent exchanged to toluene. The final extract is analysed by capillary column gas chromatography with mass spectrometric detection (GC/MS). Surrogate recoveries may not be reported in cases where interferences fromthe sample matrix prevent accurate quantitation. Because the two isomers cannot be readily chromatographically separated, benzo(j)fluoranthene is reported as part of the benzo(b)fluoranthene parameter.
This analysis is carried out in accordance with procedures described in the pH, Electrometric in Soil and Sediment method - Section B Physical/Inorganic and Misc. Constituents, BC Environmental Laboratory Manual 2007. The procedure involves mixing the dried (at <60°C) and sieved(No. 10 / 2mm) sample with deionized/distilled water at a 1:2 ratio of sediment to water. The pH of the solution is then measured using a standard pH probe.
ALS Test Code Test Description
Soil
Soil
Soil
Soil
Soil
Soil
SSSA (1996) p. 973
EPA 200.2/1631E (mod)
EPA 200.2/6020A (mod)
ASTM D2974-00 Method A
EPA 3570/8270
BC WLAP METHOD: PH, ELECTROMETRIC, SOIL
Method Reference**
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
Matrix
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location
VA ALS ENVIRONMENTAL - VANCOUVER, BRITISH COLUMBIA, CANADA
Test Method References:
Chain of Custody Numbers:
14-475217 14-475220
Version: FINAL REV. 2
11
Reference Information 01-DEC-15 16:59 (MT)
L1651409 CONTD....
11PAGE of
GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.
Version: FINAL REV. 2
11
Quality Control ReportPage 1 of
Client:
Contact:
GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Ann-Marie Norris
Report Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
C-TOT-ORG-LECO-SK
HG-200.2-CVAF-VA
MET-200.2-CCMS-VA
Soil
Soil
Soil
R3243452
R3237942
R3239578
R3241321
Batch
Batch
Batch
Batch
DUP
IRM
MB
CRM
CRM
LCS
MB
CRM
CRM
DUP
LCS
MB
CRM
WG2143293-1
WG2143293-2
WG2143293-3
WG2141453-4
WG2141453-5
WG2141453-3
WG2141453-1
WG2141475-4
WG2141475-5
WG2141475-2
WG2141475-3
WG2141475-1
WG2141453-4
L1651409-10
08-109_SOIL
VA-NRC-STSD1
VA-NRC-PACS3
VA-NRC-STSD1
VA-NRC-PACS3
L1651409-13
VA-NRC-STSD1
Total Organic Carbon
Total Organic Carbon
Total Organic Carbon
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Mercury (Hg)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
0.40
0.92
<0.10
101.7
106.9
103.8
<0.0050
103.5
106.5
0.0252
93.9
<0.0050
102.9
91.1
101.1
90.2
104.4
104.0
117.5
10-AUG-15
10-AUG-15
10-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
6.5
1.1
30
40
0.77-1.43
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
mg/kg
%
%
mg/kg
%
mg/kg
%
%
%
%
%
%
%
0.1
0.005
0.005
0.38
0.0255
14
Quality Control ReportPage 2 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3241321BatchCRM
CRM
WG2141453-4
WG2141453-5
VA-NRC-STSD1
VA-NRC-PACS3
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
98.2
104.6
102.2
101.6
102.2
101.9
105.7
99.6
104.2
101.9
101.1
92.7
105.4
107.0
109.5
106.8
102.4
102.2
88.9
93.6
101.5
99.3
101.9
93.9
99.0
98.8
101.8
99.5
99.3
93.5
93.4
95.8
100.3
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
14
Quality Control ReportPage 3 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3241321BatchCRM
CRM
CRM
WG2141453-5
WG2141475-4
WG2141475-5
VA-NRC-PACS3
VA-NRC-STSD1
VA-NRC-PACS3
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
103.6
95.0
101.3
102.6
87.5
106.9
99.9
101.3
98.1
98.3
100.4
89.0
95.5
99.5
100.5
98.1
101.0
101.3
100.8
99.1
102.6
92.0
97.2
108.2
101.6
101.4
100.2
111.7
102.6
103.0
103.0
100.8
96.4
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
14
Quality Control ReportPage 4 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3241321BatchCRM
LCS
WG2141475-5
WG2141475-3
VA-NRC-PACS3Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
87.2
91.7
87.5
98.7
96.4
95.3
96.2
97.7
99.5
97.9
101.1
92.2
92.6
97.8
99.4
104.6
94.7
109.2
99.8
85.5
106.0
97.1
101.8
95.5
94.1
101.4
96.2
94.9
100.4
88.8
104.1
100.4
99.5
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
14
Quality Control ReportPage 5 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3241321BatchLCS
MB
WG2141475-3
WG2141453-1
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
98.7
109.2
104.2
90.5
100.9
109.0
100.2
102.6
93.5
112.4
101.9
102.5
105.9
102.0
97.1
<50
<0.10
<0.10
<0.50
<0.10
<0.20
<5.0
<0.020
<0.50
<0.10
<0.50
<50
<0.50
<2.0
<1.0
<0.10
<0.50
<0.20
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
50
0.1
0.1
0.5
0.1
0.2
5
0.02
0.5
0.1
0.5
50
0.5
2
1
0.1
0.5
0.2
14
Quality Control ReportPage 6 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3241321BatchMB
MB
WG2141453-1
WG2141475-1
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
<0.10
<0.50
<0.050
<2.0
<0.050
<0.20
<2.0
<50
<0.10
<0.10
<0.50
<0.10
<0.20
<5.0
<0.020
<0.50
<0.10
<0.50
<50
<0.50
<2.0
<1.0
<0.10
<0.50
<0.20
<0.10
<0.50
<0.050
<2.0
<0.050
<0.20
<2.0
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
04-AUG-15
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
0.1
0.5
0.05
2
0.05
0.2
2
50
0.1
0.1
0.5
0.1
0.2
5
0.02
0.5
0.1
0.5
50
0.5
2
1
0.1
0.5
0.2
0.1
0.5
0.05
2
0.05
0.2
2
14
Quality Control ReportPage 7 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3242322BatchCRM
CRM
WG2144236-4
WG2144236-5
VA-NRC-STSD1
VA-NRC-PACS3
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
108.9
107.9
106.7
99.7
101.4
104.2
111.4
102.5
108.4
104.8
103.5
105.7
106.5
91.4
101.0
115.3
106.1
108.2
106.5
120.4
104.7
110.8
113.1
105.5
104.2
93.2
89.9
98.2
93.9
96.4
95.4
96.8
95.8
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
14
Quality Control ReportPage 8 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3242322BatchCRM
DUP
WG2144236-5
WG2144236-2
VA-NRC-PACS3
L1651409-13
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
96.4
100.0
97.6
84.1
95.9
95.4
98.5
102.3
97.3
107.9
95.6
88.4
102.5
100.0
100.2
10800
0.19
3.21
43.9
0.16
<0.20
<5.0
0.138
20.3
7.80
21.5
19800
3.25
7.2
352
0.34
22.1
<0.20
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
7.8
13
7.1
0.8
4.0
N/A
N/A
4.0
1.2
1.7
11
8.3
3.2
1.7
1.1
28
1.0
N/A
40
30
30
40
30
30
30
30
30
30
30
30
40
30
30
40
30
30
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
RPD-NA
RPD-NA
RPD-NA
10000
0.22
3.45
44.3
0.15
<0.20
<5.0
0.144
20.6
7.94
19.2
18200
3.35
7.0
348
0.45
22.4
<0.20
14
Quality Control ReportPage 9 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA Soil
R3242322BatchDUP
LCS
MB
WG2144236-2
WG2144236-3
WG2144236-1
L1651409-13Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Aluminum (Al)
<0.10
29.0
<0.050
<2.0
0.219
50.9
44.5
103.3
101.3
97.7
100.2
93.1
98.5
84.9
104.0
100.9
100.1
97.5
102.8
102.7
83.4
100.8
104.7
100.3
99.7
97.9
109.3
97.0
97.9
101.4
106.0
97.4
<50
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
N/A
0.9
N/A
N/A
12
11
1.1
40
40
30
40
30
30
30
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg 50
RPD-NA
RPD-NA
RPD-NA
<0.10
28.7
<0.050
<2.0
0.247
45.5
45.0
14
Quality Control ReportPage 10 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-200.2-CCMS-VA
MOISTURE-VA
PAH-TMB-H/A-MS-VA
Soil
Soil
Soil
R3242322
R3237047
R3238630
Batch
Batch
Batch
MB
LCS
MB
IRM
WG2144236-1
WG2141467-2
WG2141467-1
WG2142525-4 ALS PAH1 RM
Antimony (Sb)
Arsenic (As)
Barium (Ba)
Beryllium (Be)
Bismuth (Bi)
Boron (B)
Cadmium (Cd)
Chromium (Cr)
Cobalt (Co)
Copper (Cu)
Iron (Fe)
Lead (Pb)
Lithium (Li)
Manganese (Mn)
Molybdenum (Mo)
Nickel (Ni)
Selenium (Se)
Silver (Ag)
Strontium (Sr)
Thallium (Tl)
Tin (Sn)
Uranium (U)
Vanadium (V)
Zinc (Zn)
Moisture
Moisture
Acenaphthene
Acenaphthylene
<0.10
<0.10
<0.50
<0.10
<0.20
<5.0
<0.020
<0.50
<0.10
<0.50
<50
<0.50
<2.0
<1.0
<0.10
<0.50
<0.20
<0.10
<0.50
<0.050
<2.0
<0.050
<0.20
<2.0
100.1
<0.25
103.5
122.7
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
07-AUG-15
01-AUG-15
01-AUG-15
05-AUG-15
05-AUG-15
90-110
60-130
60-130
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
0.1
0.1
0.5
0.1
0.2
5
0.02
0.5
0.1
0.5
50
0.5
2
1
0.1
0.5
0.2
0.1
0.5
0.05
2
0.05
0.2
2
0.25
14
Quality Control ReportPage 11 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
PAH-TMB-H/A-MS-VA Soil
R3238630BatchIRM
MB
WG2142525-4
WG2142525-1
ALS PAH1 RMAnthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Acenaphthene
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogate: Naphthalene d8
118.4
119.6
108.2
116.0
127.2
123.9
118.2
119.1
110.4
102.3
119.6
115.3
124.1
111.1
111.2
<0.0050
<0.0050
<0.0040
<0.010
<0.010
<0.010
<0.010
<0.010
<0.010
<0.0050
<0.010
<0.010
<0.010
<0.010
<0.010
<0.010
<0.010
85.5
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
50-130
60-130
60-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
0.005
0.005
0.004
0.01
0.01
0.01
0.01
0.01
0.01
0.005
0.01
0.01
0.01
0.01
0.01
0.01
0.01
50-130
14
Quality Control ReportPage 12 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
PAH-TMB-H/A-MS-VA Soil
R3238630
R3239587
Batch
Batch
MB
IRM
MB
WG2142525-1
WG2141464-4
WG2141464-1
ALS PAH1 RM
Surrogate: Acenaphthene d10
Surrogate: Phenanthrene d10
Surrogate: Chrysene d12
Acenaphthene
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(1,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Acenaphthene
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
85.9
85.7
94.0
89.3
111.0
107.9
102.4
104.3
119.3
88.7
120.9
116.7
100.9
115.2
90.7
97.5
113.4
119.3
95.5
112.7
<0.0050
<0.0050
<0.0040
<0.010
<0.010
<0.010
<0.010
<0.010
<0.010
<0.0050
<0.010
<0.010
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
60-130
50-130
60-130
60-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
60-130
60-130
60-130
0.005
0.005
0.004
0.01
0.01
0.01
0.01
0.01
0.01
0.005
0.01
0.01
14
Quality Control ReportPage 13 ofReport Date: 01-DEC-15Workorder: L1651409
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
PAH-TMB-H/A-MS-VA
PH-1:2-VA
Soil
Soil
R3239587
R3237899
Batch
Batch
MB
DUP
WG2141464-1
WG2141475-2 L1651409-13
Indeno(1,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Pyrene
Surrogate: Naphthalene d8
Surrogate: Acenaphthene d10
Surrogate: Phenanthrene d10
Surrogate: Chrysene d12
pH (1:2 soil:water)
<0.010
<0.010
<0.010
<0.010
<0.010
98.8
97.9
90.0
85.7
6.49
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
05-AUG-15
04-AUG-150.03 0.3
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
%
pH
0.01
0.01
0.01
0.01
0.01
50-130
60-130
60-130
60-130
J6.52
14
Quality Control ReportPage 14 ofReport Date: 01-DEC-15Workorder: L1651409
Sample Parameter Qualifier Definitions:
Description Qualifier
J
RPD-NA
Duplicate results and limits are expressed in terms of absolute difference.
Relative Percent Difference Not Available due to result(s) being less than detection limit.
Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate
Legend:
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
Hold Time Exceedances:
All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
14
[This report shall not be reproduced except in full without the written authority of the Laboratory.]
31-JUL-15
Lab Work Order #: L1651410
Date Received:GOLDER ASSOCIATES LTD.
200-2920 Virtual WayVancouver BC V5M 0C4
ATTN: Ann-Marie NorrisFINAL REV. 201-DEC-15 17:03 (MT)Report Date:
Version:
Certificate of Analysis
ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited Company
____________________________________________
Amber Springer, B.ScAccount Manager
ADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700
Client Phone: 604-298-6623
1-DEC-2015 The list of reported Metals has been adjusted.Comments:
13-1422-0049/16000/16120Job Reference: NOT SUBMITTEDProject P.O. #:
14-475218, 14-475219C of C Numbers:Legal Site Desc:
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
2PAGE of
Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-1 15-TILBURY-B-1D 15-TILBURY-B-2 15-TILBURY-B-3 15-TILBURY-B-4
L1651410-1 L1651410-2 L1651410-3 L1651410-4 L1651410-5
% Moisture (%)
Aluminum (Al)-Total (mg/kg)
Aluminum (Al)-Total (mg/kg wwt)
Antimony (Sb)-Total (mg/kg)
Antimony (Sb)-Total (mg/kg wwt)
Arsenic (As)-Total (mg/kg)
Arsenic (As)-Total (mg/kg wwt)
Barium (Ba)-Total (mg/kg)
Barium (Ba)-Total (mg/kg wwt)
Beryllium (Be)-Total (mg/kg)
Beryllium (Be)-Total (mg/kg wwt)
Bismuth (Bi)-Total (mg/kg)
Bismuth (Bi)-Total (mg/kg wwt)
Boron (B)-Total (mg/kg)
Boron (B)-Total (mg/kg wwt)
Cadmium (Cd)-Total (mg/kg)
Cadmium (Cd)-Total (mg/kg wwt)
Chromium (Cr)-Total (mg/kg)
Chromium (Cr)-Total (mg/kg wwt)
Cobalt (Co)-Total (mg/kg)
Cobalt (Co)-Total (mg/kg wwt)
Copper (Cu)-Total (mg/kg)
Copper (Cu)-Total (mg/kg wwt)
Iron (Fe)-Total (mg/kg)
Iron (Fe)-Total (mg/kg wwt)
Lead (Pb)-Total (mg/kg)
Lead (Pb)-Total (mg/kg wwt)
Lithium (Li)-Total (mg/kg)
Lithium (Li)-Total (mg/kg wwt)
Manganese (Mn)-Total (mg/kg)
Manganese (Mn)-Total (mg/kg wwt)
Mercury (Hg)-Total (mg/kg)
Mercury (Hg)-Total (mg/kg wwt)
Molybdenum (Mo)-Total (mg/kg)
Molybdenum (Mo)-Total (mg/kg wwt)
Nickel (Ni)-Total (mg/kg)
Nickel (Ni)-Total (mg/kg wwt)
86.8 85.6 84.4 87.4 83.0
29.7 42.8 10.7 20.8 29.8
3.94 6.16 1.67 2.62 5.06
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.020 0.025 <0.020 0.021 <0.020
<0.0040 <0.0040 <0.0040 <0.0040 <0.0040
12.3 7.58 7.43 21.8 4.16
1.64 1.09 1.16 2.75 0.706
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
18.6 14.3 12.4 13.5 11.1
2.46 2.05 1.92 1.70 1.88
0.0709 0.0514 0.0408 0.128 0.0228
0.0094 0.0074 0.0064 0.0161 0.0039
0.076 0.089 <0.050 0.063 0.056
0.010 0.013 <0.010 <0.010 <0.010
0.110 0.130 0.032 0.152 0.047
0.0145 0.0188 0.0050 0.0192 0.0080
10.6 10.0 8.16 7.12 5.04
1.40 1.44 1.27 0.898 0.855
53.9 64.1 27.4 40.6 46.1
7.15 9.22 4.26 5.12 7.82
0.029 0.035 <0.020 0.042 0.047
<0.0040 0.0051 <0.0040 0.0052 0.0080
<0.50 <0.50 <0.50 <0.50 <0.50
<0.10 <0.10 <0.10 <0.10 <0.10
22.6 18.7 10.5 66.3 20.5
2.99 2.69 1.64 8.37 3.48
0.0059 <0.0050 <0.0050 <0.0050 <0.0050
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
0.540 0.601 0.462 0.159 0.207
0.0716 0.0864 0.0719 0.0201 0.0351
2.07 1.88 1.31 4.63 1.69
0.275 0.270 0.204 0.585 0.287
Physical Tests
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
3PAGE of
Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-5 15-TILBURY-B-6 15-TILBURY-B-7 15-TILBURY-B-8 15-TILBURY-B-8D
L1651410-6 L1651410-7 L1651410-8 L1651410-9 L1651410-10
% Moisture (%)
Aluminum (Al)-Total (mg/kg)
Aluminum (Al)-Total (mg/kg wwt)
Antimony (Sb)-Total (mg/kg)
Antimony (Sb)-Total (mg/kg wwt)
Arsenic (As)-Total (mg/kg)
Arsenic (As)-Total (mg/kg wwt)
Barium (Ba)-Total (mg/kg)
Barium (Ba)-Total (mg/kg wwt)
Beryllium (Be)-Total (mg/kg)
Beryllium (Be)-Total (mg/kg wwt)
Bismuth (Bi)-Total (mg/kg)
Bismuth (Bi)-Total (mg/kg wwt)
Boron (B)-Total (mg/kg)
Boron (B)-Total (mg/kg wwt)
Cadmium (Cd)-Total (mg/kg)
Cadmium (Cd)-Total (mg/kg wwt)
Chromium (Cr)-Total (mg/kg)
Chromium (Cr)-Total (mg/kg wwt)
Cobalt (Co)-Total (mg/kg)
Cobalt (Co)-Total (mg/kg wwt)
Copper (Cu)-Total (mg/kg)
Copper (Cu)-Total (mg/kg wwt)
Iron (Fe)-Total (mg/kg)
Iron (Fe)-Total (mg/kg wwt)
Lead (Pb)-Total (mg/kg)
Lead (Pb)-Total (mg/kg wwt)
Lithium (Li)-Total (mg/kg)
Lithium (Li)-Total (mg/kg wwt)
Manganese (Mn)-Total (mg/kg)
Manganese (Mn)-Total (mg/kg wwt)
Mercury (Hg)-Total (mg/kg)
Mercury (Hg)-Total (mg/kg wwt)
Molybdenum (Mo)-Total (mg/kg)
Molybdenum (Mo)-Total (mg/kg wwt)
Nickel (Ni)-Total (mg/kg)
Nickel (Ni)-Total (mg/kg wwt)
83.9 85.5 82.9 87.6 84.6
11.8 18.6 14.5 3.7 5.0
1.90 2.71 2.49 0.46 0.76
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.020 <0.020 <0.020 <0.020 <0.020
<0.0040 <0.0040 <0.0040 <0.0040 <0.0040
4.01 7.76 2.46 3.53 3.93
0.646 1.13 0.422 0.437 0.604
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
11.5 13.1 12.5 18.9 15.4
1.84 1.90 2.15 2.33 2.37
0.0159 0.0185 0.0505 0.0214 0.0350
0.0026 0.0027 0.0087 0.0026 0.0054
<0.050 0.054 <0.050 <0.050 <0.050
<0.010 <0.010 <0.010 <0.010 <0.010
0.029 0.074 0.039 <0.020 <0.020
0.0047 0.0108 0.0068 <0.0040 <0.0040
5.60 5.64 6.68 8.19 9.32
0.902 0.820 1.14 1.01 1.43
37.1 43.9 34.0 38.0 35.5
5.97 6.39 5.82 4.70 5.46
0.032 0.038 <0.020 <0.020 <0.020
0.0051 0.0055 <0.0040 <0.0040 <0.0040
<0.50 <0.50 <0.50 <0.50 <0.50
<0.10 <0.10 <0.10 <0.10 <0.10
29.7 44.9 22.3 19.1 17.9
4.78 6.53 3.81 2.36 2.76
<0.0050 <0.0050 <0.0050 <0.0050 0.0052
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
0.115 0.350 0.161 0.759 0.317
0.0185 0.0509 0.0275 0.0939 0.0488
2.05 3.80 2.18 1.50 1.39
0.329 0.553 0.374 0.186 0.214
Physical Tests
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
4PAGE of
Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-9 15-TILBURY-B-10 15-TILBURY-B-11 15-TILBURY-B-12 15-TILBURY-B-13
L1651410-11 L1651410-12 L1651410-13 L1651410-14 L1651410-15
% Moisture (%)
Aluminum (Al)-Total (mg/kg)
Aluminum (Al)-Total (mg/kg wwt)
Antimony (Sb)-Total (mg/kg)
Antimony (Sb)-Total (mg/kg wwt)
Arsenic (As)-Total (mg/kg)
Arsenic (As)-Total (mg/kg wwt)
Barium (Ba)-Total (mg/kg)
Barium (Ba)-Total (mg/kg wwt)
Beryllium (Be)-Total (mg/kg)
Beryllium (Be)-Total (mg/kg wwt)
Bismuth (Bi)-Total (mg/kg)
Bismuth (Bi)-Total (mg/kg wwt)
Boron (B)-Total (mg/kg)
Boron (B)-Total (mg/kg wwt)
Cadmium (Cd)-Total (mg/kg)
Cadmium (Cd)-Total (mg/kg wwt)
Chromium (Cr)-Total (mg/kg)
Chromium (Cr)-Total (mg/kg wwt)
Cobalt (Co)-Total (mg/kg)
Cobalt (Co)-Total (mg/kg wwt)
Copper (Cu)-Total (mg/kg)
Copper (Cu)-Total (mg/kg wwt)
Iron (Fe)-Total (mg/kg)
Iron (Fe)-Total (mg/kg wwt)
Lead (Pb)-Total (mg/kg)
Lead (Pb)-Total (mg/kg wwt)
Lithium (Li)-Total (mg/kg)
Lithium (Li)-Total (mg/kg wwt)
Manganese (Mn)-Total (mg/kg)
Manganese (Mn)-Total (mg/kg wwt)
Mercury (Hg)-Total (mg/kg)
Mercury (Hg)-Total (mg/kg wwt)
Molybdenum (Mo)-Total (mg/kg)
Molybdenum (Mo)-Total (mg/kg wwt)
Nickel (Ni)-Total (mg/kg)
Nickel (Ni)-Total (mg/kg wwt)
86.4 84.2 78.9 87.2 85.6
7.6 26.8 55.0 12.8 15.3
1.04 4.23 11.6 1.63 2.21
<0.010 0.014 0.014 <0.010 <0.010
<0.0020 0.0022 0.0030 <0.0020 <0.0020
<0.020 0.026 0.051 0.036 <0.020
<0.0040 0.0041 0.0107 0.0046 <0.0040
4.38 2.17 1.91 4.37 2.19
0.594 0.342 0.404 0.557 0.317
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
13.7 12.6 10.4 17.1 13.4
1.86 1.98 2.20 2.18 1.94
0.0138 0.0092 0.0208 0.0340 0.0197
0.0019 0.0015 0.0044 0.0043 0.0028
<0.050 0.062 0.078 0.068 <0.050
<0.010 <0.010 0.016 <0.010 <0.010
0.030 0.047 0.046 0.070 0.072
0.0040 0.0075 0.0098 0.0089 0.0104
8.47 7.01 7.42 7.65 6.11
1.15 1.11 1.57 0.975 0.882
35.7 45.0 75.0 29.0 34.1
4.85 7.10 15.9 3.70 4.93
<0.020 0.044 0.270 <0.020 0.029
<0.0040 0.0069 0.0571 <0.0040 0.0041
<0.50 <0.50 <0.50 <0.50 <0.50
<0.10 <0.10 <0.10 <0.10 <0.10
17.7 9.93 13.0 13.0 12.0
2.41 1.57 2.75 1.66 1.74
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
0.342 0.599 0.427 0.542 0.270
0.0464 0.0945 0.0902 0.0692 0.0389
1.33 0.62 0.74 2.23 2.56
0.181 0.097 0.155 0.284 0.370
Physical Tests
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
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Version: FINAL REV. 2
11
TISSUE
Tissue Tissue31-JUL-15 31-JUL-15
15-TILBURY-B-14 15-TILBURY-B-15
L1651410-16 L1651410-17
% Moisture (%)
Aluminum (Al)-Total (mg/kg)
Aluminum (Al)-Total (mg/kg wwt)
Antimony (Sb)-Total (mg/kg)
Antimony (Sb)-Total (mg/kg wwt)
Arsenic (As)-Total (mg/kg)
Arsenic (As)-Total (mg/kg wwt)
Barium (Ba)-Total (mg/kg)
Barium (Ba)-Total (mg/kg wwt)
Beryllium (Be)-Total (mg/kg)
Beryllium (Be)-Total (mg/kg wwt)
Bismuth (Bi)-Total (mg/kg)
Bismuth (Bi)-Total (mg/kg wwt)
Boron (B)-Total (mg/kg)
Boron (B)-Total (mg/kg wwt)
Cadmium (Cd)-Total (mg/kg)
Cadmium (Cd)-Total (mg/kg wwt)
Chromium (Cr)-Total (mg/kg)
Chromium (Cr)-Total (mg/kg wwt)
Cobalt (Co)-Total (mg/kg)
Cobalt (Co)-Total (mg/kg wwt)
Copper (Cu)-Total (mg/kg)
Copper (Cu)-Total (mg/kg wwt)
Iron (Fe)-Total (mg/kg)
Iron (Fe)-Total (mg/kg wwt)
Lead (Pb)-Total (mg/kg)
Lead (Pb)-Total (mg/kg wwt)
Lithium (Li)-Total (mg/kg)
Lithium (Li)-Total (mg/kg wwt)
Manganese (Mn)-Total (mg/kg)
Manganese (Mn)-Total (mg/kg wwt)
Mercury (Hg)-Total (mg/kg)
Mercury (Hg)-Total (mg/kg wwt)
Molybdenum (Mo)-Total (mg/kg)
Molybdenum (Mo)-Total (mg/kg wwt)
Nickel (Ni)-Total (mg/kg)
Nickel (Ni)-Total (mg/kg wwt)
86.2 87.0
9.9 17.0
1.37 2.22
<0.010 <0.010
<0.0020 <0.0020
<0.020 <0.020
<0.0040 <0.0040
14.5 3.00
2.00 0.391
<0.010 <0.010
<0.0020 <0.0020
<0.010 <0.010
<0.0020 <0.0020
15.0 19.7
2.07 2.57
0.146 0.0801
0.0202 0.0105
<0.050 <0.050
<0.010 <0.010
1.03 0.425
0.142 0.0554
8.04 12.1
1.11 1.58
29.5 50.8
4.07 6.63
0.026 0.031
<0.0040 0.0041
<0.50 <0.50
<0.10 <0.10
64.7 40.9
8.94 5.34
0.0052 0.0063
<0.0010 <0.0010
0.217 0.147
0.0300 0.0192
6.48 6.67
0.896 0.870
Physical Tests
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
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Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-1 15-TILBURY-B-1D 15-TILBURY-B-2 15-TILBURY-B-3 15-TILBURY-B-4
L1651410-1 L1651410-2 L1651410-3 L1651410-4 L1651410-5
Selenium (Se)-Total (mg/kg)
Selenium (Se)-Total (mg/kg wwt)
Silver (Ag)-Total (mg/kg)
Silver (Ag)-Total (mg/kg wwt)
Strontium (Sr)-Total (mg/kg)
Strontium (Sr)-Total (mg/kg wwt)
Thallium (Tl)-Total (mg/kg)
Thallium (Tl)-Total (mg/kg wwt)
Tin (Sn)-Total (mg/kg)
Tin (Sn)-Total (mg/kg wwt)
Uranium (U)-Total (mg/kg)
Uranium (U)-Total (mg/kg wwt)
Vanadium (V)-Total (mg/kg)
Vanadium (V)-Total (mg/kg wwt)
Zinc (Zn)-Total (mg/kg)
Zinc (Zn)-Total (mg/kg wwt)
<0.050 <0.050 <0.050 <0.050 0.051
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
15.9 11.7 11.7 16.5 11.5
2.11 1.68 1.82 2.09 1.96
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.00040 <0.00040 <0.00040 <0.00040 <0.00040
0.52 0.77 0.33 0.42 0.37
0.069 0.111 0.052 0.052 0.063
<0.0020 0.0024 <0.0020 <0.0020 <0.0020
<0.00040 <0.00040 <0.00040 <0.00040 <0.00040
<0.10 0.10 <0.10 <0.10 <0.10
<0.020 <0.020 <0.020 <0.020 <0.020
18.4 14.8 18.3 13.4 10.2
2.44 2.12 2.86 1.69 1.73
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
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Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-5 15-TILBURY-B-6 15-TILBURY-B-7 15-TILBURY-B-8 15-TILBURY-B-8D
L1651410-6 L1651410-7 L1651410-8 L1651410-9 L1651410-10
Selenium (Se)-Total (mg/kg)
Selenium (Se)-Total (mg/kg wwt)
Silver (Ag)-Total (mg/kg)
Silver (Ag)-Total (mg/kg wwt)
Strontium (Sr)-Total (mg/kg)
Strontium (Sr)-Total (mg/kg wwt)
Thallium (Tl)-Total (mg/kg)
Thallium (Tl)-Total (mg/kg wwt)
Tin (Sn)-Total (mg/kg)
Tin (Sn)-Total (mg/kg wwt)
Uranium (U)-Total (mg/kg)
Uranium (U)-Total (mg/kg wwt)
Vanadium (V)-Total (mg/kg)
Vanadium (V)-Total (mg/kg wwt)
Zinc (Zn)-Total (mg/kg)
Zinc (Zn)-Total (mg/kg wwt)
<0.050 <0.050 <0.050 <0.050 <0.050
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
11.5 14.0 6.08 11.0 11.2
1.86 2.03 1.04 1.36 1.73
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.00040 <0.00040 <0.00040 <0.00040 <0.00040
0.84 0.83 0.43 0.94 0.61
0.135 0.121 0.073 0.117 0.094
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.00040 <0.00040 <0.00040 <0.00040 <0.00040
<0.10 <0.10 <0.10 <0.10 <0.10
<0.020 <0.020 <0.020 <0.020 <0.020
11.4 10.7 13.8 15.0 17.0
1.84 1.55 2.36 1.86 2.62
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
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Version: FINAL REV. 2
11
TISSUE
Tissue Tissue Tissue Tissue Tissue31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15 31-JUL-15
15-TILBURY-B-9 15-TILBURY-B-10 15-TILBURY-B-11 15-TILBURY-B-12 15-TILBURY-B-13
L1651410-11 L1651410-12 L1651410-13 L1651410-14 L1651410-15
Selenium (Se)-Total (mg/kg)
Selenium (Se)-Total (mg/kg wwt)
Silver (Ag)-Total (mg/kg)
Silver (Ag)-Total (mg/kg wwt)
Strontium (Sr)-Total (mg/kg)
Strontium (Sr)-Total (mg/kg wwt)
Thallium (Tl)-Total (mg/kg)
Thallium (Tl)-Total (mg/kg wwt)
Tin (Sn)-Total (mg/kg)
Tin (Sn)-Total (mg/kg wwt)
Uranium (U)-Total (mg/kg)
Uranium (U)-Total (mg/kg wwt)
Vanadium (V)-Total (mg/kg)
Vanadium (V)-Total (mg/kg wwt)
Zinc (Zn)-Total (mg/kg)
Zinc (Zn)-Total (mg/kg wwt)
<0.050 <0.050 <0.050 <0.050 <0.050
<0.010 <0.010 <0.010 <0.010 <0.010
<0.0050 <0.0050 <0.0050 <0.0050 <0.0050
<0.0010 <0.0010 <0.0010 <0.0010 <0.0010
11.1 8.34 6.24 21.0 7.72
1.51 1.32 1.32 2.67 1.11
<0.0020 <0.0020 <0.0020 <0.0020 <0.0020
<0.00040 <0.00040 <0.00040 <0.00040 <0.00040
0.33 0.47 0.42 0.73 1.21
0.045 0.075 0.088 0.093 0.175
<0.0020 <0.0020 0.0033 <0.0020 <0.0020
<0.00040 <0.00040 0.00069 <0.00040 <0.00040
<0.10 <0.10 0.11 <0.10 <0.10
<0.020 <0.020 0.023 <0.020 <0.020
15.3 10.4 13.4 12.5 11.9
2.08 1.65 2.83 1.59 1.72
Metals
01-DEC-15 17:03 (MT)
Sample ID Description
Client ID
Sampled Date
Grouping Analyte
Sampled Time
ALS ENVIRONMENTAL ANALYTICAL REPORT
L1651410 CONTD....
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Version: FINAL REV. 2
11
TISSUE
Tissue Tissue31-JUL-15 31-JUL-15
15-TILBURY-B-14 15-TILBURY-B-15
L1651410-16 L1651410-17
Selenium (Se)-Total (mg/kg)
Selenium (Se)-Total (mg/kg wwt)
Silver (Ag)-Total (mg/kg)
Silver (Ag)-Total (mg/kg wwt)
Strontium (Sr)-Total (mg/kg)
Strontium (Sr)-Total (mg/kg wwt)
Thallium (Tl)-Total (mg/kg)
Thallium (Tl)-Total (mg/kg wwt)
Tin (Sn)-Total (mg/kg)
Tin (Sn)-Total (mg/kg wwt)
Uranium (U)-Total (mg/kg)
Uranium (U)-Total (mg/kg wwt)
Vanadium (V)-Total (mg/kg)
Vanadium (V)-Total (mg/kg wwt)
Zinc (Zn)-Total (mg/kg)
Zinc (Zn)-Total (mg/kg wwt)
<0.050 <0.050
<0.010 <0.010
0.0055 <0.0050
<0.0010 <0.0010
20.8 10.1
2.87 1.32
<0.0020 <0.0020
<0.00040 <0.00040
0.53 0.59
0.073 0.077
<0.0020 <0.0020
<0.00040 <0.00040
<0.10 <0.10
<0.020 <0.020
14.6 23.8
2.01 3.11
Metals
Reference Information 01-DEC-15 17:03 (MT)
L1651410 CONTD....
10PAGE of
AG-DRY-CCMS-N-VA
AG-WET-CCMS-N-VA
HG-DRY-CVAFS-N-VA
HG-WET-CVAFS-N-VA
MET-DRY-CCMS-N-VA
MET-WET-CCMS-N-VA
MOISTURE-TISS-VA
Silver in Tissue by CRC ICPMS (DRY)
Silver in Tissue by CRC ICPMS (WET)
Mercury in Tissue by CVAFS (DRY)
Mercury in Tissue by CVAFS (WET)
Metals in Tissue by CRC ICPMS (DRY)
Metals in Tissue by CRC ICPMS (WET)
% Moisture in Tissues
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Analysis is by atomic fluorescence spectrophotometry or atomic absorption spectrophotometry, adapted from US EPA Method 245.7.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Analysis is by atomic fluorescence spectrophotometry or atomic absorption spectrophotometry, adapted from US EPA Method 245.7.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This method is conducted following British Columbia Lab Manual method "Metals in Animal Tissue and Vegetation (Biota) - Prescriptive". Tissue samples are homogenized and sub-sampled prior to hotblock digestion with nitric and hydrochloric acids, in combination with addition of hydrogen peroxide. Instrumental analysis is by collision cell inductively coupled plasma - mass spectrometry (modified from EPA Method 6020A).
Method Limitation: This method employs a strong acid/peroxide digestion, and is intended to provide a conservative estimate of bio-available metals. Near complete recoveries are achieved for most toxicologically important metals, but elements associated with recalcitrant minerals may be only partially recovered.
This analysis is carried out gravimetrically by drying the sample at 105 C for a minimum of six hours.
ALS Test Code Test Description
Tissue
Tissue
Tissue
Tissue
Tissue
Tissue
Tissue
EPA 200.3/6020A
EPA 200.3/6020A
EPA 200.3, EPA 245.7
EPA 200.3, EPA 245.7
EPA 200.3/6020A
EPA 200.3/6020A
ASTM D2974-00 Method A
Method Reference**
** ALS test methods may incorporate modifications from specified reference methods to improve performance.
Matrix
The last two letters of the above test code(s) indicate the laboratory that performed analytical analysis for that test. Refer to the list below:
Laboratory Definition Code Laboratory Location
Test Method References:
Chain of Custody Numbers:
14-475218 14-475219
Version: FINAL REV. 2
11
Reference Information 01-DEC-15 17:03 (MT)
L1651410 CONTD....
11PAGE of
GLOSSARY OF REPORT TERMSSurrogate - A compound that is similar in behaviour to target analyte(s), but that does not occur naturally in environmental samples. Forapplicable tests, surrogates are added to samples prior to analysis as a check on recovery.mg/kg - milligrams per kilogram based on dry weight of sample.mg/kg wwt - milligrams per kilogram based on wet weight of sample.mg/kg lwt - milligrams per kilogram based on lipid-adjusted weight of sample.mg/L - milligrams per litre.< - Less than.D.L. - The reported Detection Limit, also known as the Limit of Reporting (LOR).N/A - Result not available. Refer to qualifier code and definition for explanation.
Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.
Version: FINAL REV. 2
11
Quality Control ReportPage 1 of
Client:
Contact:
GOLDER ASSOCIATES LTD. 200-2920 Virtual Way Vancouver BC V5M 0C4Ann-Marie Norris
Report Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
AG-DRY-CCMS-N-VA
AG-WET-CCMS-N-VA
HG-DRY-CVAFS-N-VA
HG-WET-CVAFS-N-VA
Tissue
Tissue
Tissue
Tissue
R3252602
R3253959
R3252602
R3253959
R3253404
R3253402
Batch
Batch
Batch
Batch
Batch
Batch
CRM
MB
DUP
LCS
CRM
MB
DUP
LCS
CRM
CRM
DUP
LCS
MB
CRM
CRM
WG2154708-3
WG2154708-1
WG2154708-2
WG2154708-5
WG2154708-3
WG2154708-1
WG2154708-2
WG2154708-5
WG2154708-3
WG2154708-4
WG2154708-2
WG2154708-5
WG2154708-1
WG2154708-3
WG2154708-4
VA-NIST-1566B
L1651410-1
VA-NIST-1566B
L1651410-1
VA-NIST-1566B
VA-NIST-1547
L1651410-1
VA-NIST-1566B
VA-NIST-1547
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Silver (Ag)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
76.8
<0.0050
<0.0050
96.9
76.8
<0.0010
<0.0010
96.9
101.1
102.6
0.0054
104.4
<0.0050
101.1
102.6
24-AUG-15
24-AUG-15
25-AUG-15
25-AUG-15
24-AUG-15
24-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
N/A
N/A
9.4
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
mg/kg
mg/kg
%
%
mg/kg wwt
mg/kg wwt
%
%
%
mg/kg
%
mg/kg
%
%
0.005
0.001
0.005
RPD-NA
RPD-NA
<0.0050
<0.0010
0.0059
10
Quality Control ReportPage 2 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
HG-WET-CVAFS-N-VA
MET-DRY-CCMS-N-VA
Tissue
Tissue
R3253402
R3252602
Batch
Batch
DUP
LCS
MB
CRM
MB
WG2154708-2
WG2154708-5
WG2154708-1
WG2154708-3
WG2154708-1
L1651410-1
VA-NIST-1566B
Mercury (Hg)-Total
Mercury (Hg)-Total
Mercury (Hg)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
<0.0010
104.4
<0.0010
95.0
91.8
93.4
98.0
92.5
89.7
93.3
94.8
94.4
96.9
97.7
98.4
98.9
88.5
89.8
99.7
95.9
<2.0
<0.010
<0.020
<0.050
<0.010
<0.010
<1.0
<0.0050
<0.050
25-AUG-15
25-AUG-15
25-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
N/A 40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
mg/kg wwt
%
mg/kg wwt
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
0.001
2
0.01
0.02
0.05
0.01
0.01
1
0.005
0.05
RPD-NA<0.0010
10
Quality Control ReportPage 3 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA Tissue
R3252602
R3253274
Batch
Batch
MB
CRM
CRM
WG2154708-1
WG2154708-3
WG2154708-4
VA-NIST-1566B
VA-NIST-1547
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Antimony (Sb)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
<0.020
<0.10
<3.0
<0.020
<0.50
<0.050
<0.020
<0.20
<0.050
<0.050
<0.0020
<0.10
<0.0020
<0.10
<0.50
0.008
106.0
0.019
0.061
88.5
80.4
90.4
85.2
0.050
98.2
93.6
92.5
90.4
0.044
0.41
0.116
94.0
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
0-0.018
70-130
0.01-0.03
0.04-0.08
70-130
70-130
70-130
70-130
0.034-0.074
70-130
70-130
70-130
70-130
0.026-0.066
0.27-0.67
0.07-0.17
70-130
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
mg/kg
mg/kg
%
%
%
%
mg/kg
%
%
%
%
mg/kg
mg/kg
mg/kg
%
0.02
0.1
3
0.02
0.5
0.05
0.02
0.2
0.05
0.05
0.002
0.1
0.002
0.1
0.5
10
Quality Control ReportPage 4 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA Tissue
R3253274
R3253959
Batch
Batch
CRM
DUP
LCS
WG2154708-4
WG2154708-2
WG2154708-5
VA-NIST-1547
L1651410-1
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
101.2
0.10
85.7
0.25
102.0
33.2
<0.010
<0.020
12.3
<0.010
<0.010
18.1
0.0708
0.070
0.110
9.45
53.8
0.028
<0.50
21.6
0.471
2.03
<0.050
15.2
<0.0020
0.46
<0.0020
<0.10
17.4
99.6
101.9
100.9
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
11
N/A
N/A
0.5
N/A
N/A
2.4
0.2
7.3
0.1
11
0.3
5.4
N/A
4.4
14
2.2
N/A
4.9
N/A
12
N/A
N/A
5.5
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
60
40
40
40
40
40
70-130
0.01-0.21
70-130
0.17-0.37
70-130
70-130
70-130
70-130
%
mg/kg
%
mg/kg
%
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
%
%
%
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
29.7
<0.010
<0.020
12.3
<0.010
<0.010
18.6
0.0709
0.076
0.110
10.6
53.9
0.029
<0.50
22.6
0.540
2.07
<0.050
15.9
<0.0020
0.52
<0.0020
<0.10
18.4
10
Quality Control ReportPage 5 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-DRY-CCMS-N-VA
MET-WET-CCMS-N-VA
Tissue
Tissue
R3253959
R3252602
Batch
Batch
LCS
CRM
WG2154708-5
WG2154708-3 VA-NIST-1566B
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
102.1
100.7
98.5
93.7
100.0
99.6
98.9
96.9
95.4
98.0
100.9
100.6
101.0
99.9
103.0
95.8
96.6
101.3
97.5
101.3
92.4
95.0
91.8
93.4
98.0
92.5
89.7
93.3
94.8
94.4
96.9
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
10
Quality Control ReportPage 6 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA Tissue
R3252602BatchCRM
MB
WG2154708-3
WG2154708-1
VA-NIST-1566BMolybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
97.7
98.4
98.9
88.5
89.8
99.7
95.9
<0.40
<0.0020
<0.0040
<0.010
<0.0020
<0.0020
<0.20
<0.0010
<0.010
<0.0040
<0.020
<0.60
<0.0040
<0.10
<0.010
<0.0040
<0.040
<0.010
<0.010
<0.00040
<0.020
<0.00040
<0.020
<0.10
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
70-130
70-130
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%
%
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
0.4
0.002
0.004
0.01
0.002
0.002
0.2
0.001
0.01
0.004
0.02
0.6
0.004
0.1
0.01
0.004
0.04
0.01
0.01
0.0004
0.02
0.0004
0.02
0.1
10
Quality Control ReportPage 7 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA Tissue
R3253274
R3253959
Batch
Batch
CRM
CRM
DUP
WG2154708-3
WG2154708-4
WG2154708-2
VA-NIST-1566B
VA-NIST-1547
L1651410-1
Antimony (Sb)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
0.0078
106.0
0.0194
0.0610
88.5
80.4
90.4
85.2
0.0502
98.2
93.6
92.5
90.4
0.0443
0.414
0.116
94.0
101.2
0.100
85.7
0.251
102.0
4.40
<0.0020
<0.0040
1.63
<0.0020
<0.0020
2.40
0.0094
<0.010
0.0145
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
24-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
11
N/A
N/A
0.5
N/A
N/A
2.4
0.2
N/A
0.1
40
40
40
40
40
40
40
40
40
40
0-0.0177
70-130
0.01-0.03
0.04-0.08
70-130
70-130
70-130
70-130
0.0339-0.073
70-130
70-130
70-130
70-130
0.0264-0.066
0.273-0.673
0.07-0.17
70-130
70-130
0.008-0.208
70-130
0.165-0.365
70-130
mg/kg wwt
%
mg/kg wwt
mg/kg wwt
%
%
%
%
mg/kg wwt
%
%
%
%
mg/kg wwt
mg/kg wwt
mg/kg wwt
%
%
mg/kg wwt
%
mg/kg wwt
%
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
3.94
<0.0020
<0.0040
1.64
<0.0020
<0.0020
2.46
0.0094
0.010
0.0145
10
Quality Control ReportPage 8 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA Tissue
R3253959BatchDUP
LCS
WG2154708-2
WG2154708-5
L1651410-1Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
Aluminum (Al)-Total
Antimony (Sb)-Total
Arsenic (As)-Total
Barium (Ba)-Total
Beryllium (Be)-Total
Bismuth (Bi)-Total
Boron (B)-Total
Cadmium (Cd)-Total
Chromium (Cr)-Total
Cobalt (Co)-Total
Copper (Cu)-Total
Iron (Fe)-Total
Lead (Pb)-Total
Lithium (Li)-Total
Manganese (Mn)-Total
Molybdenum (Mo)-Total
Nickel (Ni)-Total
Selenium (Se)-Total
Strontium (Sr)-Total
1.25
7.12
<0.0040
<0.10
2.86
0.0624
0.269
<0.010
2.01
<0.00040
0.061
<0.00040
<0.020
2.31
99.6
101.9
100.9
102.1
100.7
98.5
93.7
100.0
99.6
98.9
96.9
95.4
98.0
100.9
100.6
101.0
99.9
103.0
95.8
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
11
0.3
N/A
N/A
4.4
14
2.2
N/A
4.9
N/A
12
N/A
N/A
5.5
40
40
40
40
40
40
40
40
60
40
40
40
40
40
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
70-130
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
mg/kg wwt
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
%
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
RPD-NA
1.40
7.15
<0.0040
<0.10
2.99
0.0716
0.275
<0.010
2.11
<0.00040
0.069
<0.00040
<0.020
2.44
10
Quality Control ReportPage 9 ofReport Date: 01-DEC-15Workorder: L1651410
Test Matrix Reference Result Qualifier Units RPD Limit Analyzed
MET-WET-CCMS-N-VA
MOISTURE-TISS-VA
Tissue
Tissue
R3253959
R3250930
Batch
Batch
LCS
DUP
WG2154708-5
WG2152817-1 L1651410-5
Thallium (Tl)-Total
Tin (Sn)-Total
Uranium (U)-Total
Vanadium (V)-Total
Zinc (Zn)-Total
% Moisture
96.6
101.3
97.5
101.3
92.4
83.6
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
25-AUG-15
19-AUG-150.6 20
70-130
70-130
70-130
70-130
70-130
%
%
%
%
%
%83.0
10
Quality Control ReportPage 10 ofReport Date: 01-DEC-15Workorder: L1651410
Sample Parameter Qualifier Definitions:
Description Qualifier
RPD-NA Relative Percent Difference Not Available due to result(s) being less than detection limit.
Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate
Legend:
The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.
Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.
Hold Time Exceedances:
All test results reported with this submission were conducted within ALS recommended hold times.
ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal government requirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by the US EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.
10
September 17, 2015 Analytical Report for Service Request No: K1509391
Ms. Amber SpringerALS Environmental - Canada8081 Lougheed HwyBurnaby, BC V5A 1W9
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. The test results meet requirements of the current NELAP standards, where applicable, and except as noted in the laboratory case narrative provided. For a specific list of NELAP-accredited analytes, refer to the certifications section at www.alsglobal.com. All results are intended to be considered in their entirety, and ALS Group USA Corp. dba ALS Environmental (ALS) is not responsible for use of less than the complete report. Results apply only to the items submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the report.
For your reference, these analyses have been assigned our service request numberEnclosed are the results of the sample(s) submitted to our laboratory August 26, 2015
RE: L1651410
Dear Ms.Springer,
K1509391.
Please contact me if you have any questions. My extension is 3293. You may also contact me via email at [email protected].
Respectfully submitted,
ALS Group USA, Corp. dba ALS Environmental
Shar Samy, Ph.D.Project Manager
ALS Group USA, Corp1317 South 13th AvenueKelso, WA 98626
+1 360 577 7222+1 360 636 1068
T :F :
ALS Environmental
www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNERPage 1 of 64
www.alsglobal.com
ALS Environmental
F :T :
+1 360 636 1068+1 360 577 7222
Kelso, WA 986261317 South 13th AvenueALS Group USA, Corp
Table of Contents
RIGHT SOLUTIONS | RIGHT PARTNER
Acronyms
Qualifiers
State Certifications, Accreditations, And Licenses
Case Narrative
Chain of Custody
General Chemistry
Polynuclear Aromatic Hydrocarbons
Polynuclear Aromatic Hydrocarbons
Page 2 of 64
ASTM American Society for Testing and Materials
A2LA American Association for Laboratory Accreditation
CARB California Air Resources Board
CAS Number Chemical Abstract Service registry Number
CFC Chlorofluorocarbon
CFU Colony-Forming Unit
DEC Department of Environmental Conservation
DEQ Department of Environmental Quality
DHS Department of Health Services
DOE Department of Ecology
DOH Department of Health
EPA U. S. Environmental Protection Agency
ELAP Environmental Laboratory Accreditation Program
GC Gas Chromatography
GC/MS Gas Chromatography/Mass Spectrometry
LOD Limit of Detection
LOQ Limit of Quantitation
LUFT Leaking Underground Fuel Tank
M ModifiedMCL Maximum Contaminant Level is the highest permissible concentration of a substance
allowed in drinking water as established by the USEPA.
MDL Method Detection Limit
MPN Most Probable Number
MRL Method Reporting Limit
NA Not Applicable
NC Not Calculated
NCASI National Council of the Paper Industry for Air and Stream Improvement
ND Not Detected
NIOSH National Institute for Occupational Safety and Health
PQL Practical Quantitation Limit
RCRA Resource Conservation and Recovery Act
SIM Selected Ion Monitoring
TPH Total Petroleum Hydrocarbonstr Trace level is the concentration of an analyte that is less than the PQL but greater than or
equal to the MDL.
Acronyms
Page 3 of 64
Inorganic Data Qualifiers
* The result is an outlier. See case narrative.
# The control limit criteria is not applicable. See case narrative.
B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.
E The result is an estimate amount because the value exceeded the instrument calibration range.
J The result is an estimated value.
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.
X See case narrative.
Q See case narrative. One or more quality control criteria was outside the limits.
H The holding time for this test is immediately following sample collection. The samples were analyzed as soon as possible afterreceipt by the laboratory.
Metals Data Qualifiers
# The control limit criteria is not applicable. See case narrative.
J The result is an estimated value.
E The percent difference for the serial dilution was greater than 10%, indicating a possible matrix interference in the sample.
M The duplicate injection precision was not met.
N The Matrix Spike sample recovery is not within control limits. See case narrative.
S The reported value was determined by the Method of Standard Additions (MSA).
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
W The post-digestion spike for furnace AA analysis is out of control limits, while sample absorbance is less than 50% of spike absorbance.
i The MRL/MDL or LOQ/LOD is elevated due to a matrix interference.
X See case narrative.
+ The correlation coefficient for the MSA is less than 0.995.
Q See case narrative. One or more quality control criteria was outside the limits.
Organic Data Qualifiers
* The result is an outlier. See case narrative.
# The control limit criteria is not applicable. See case narrative.
A A tentatively identified compound, a suspected aldol-condensation product.
B The analyte was found in the associated method blank at a level that is significant relative to the sample result as defined by the DOD or NELAC standards.
C The analyte was qualitatively confirmed using GC/MS techniques, pattern recognition, or by comparing to historical data.
D The reported result is from a dilution.
E The result is an estimated value.
J The result is an estimated value.
N The result is presumptive. The analyte was tentatively identified, but a confirmation analysis was not performed.
PThe GC or HPLC confirmation criteria was exceeded. The relative percent difference is greater than 40% between the two analytical results.
U The analyte was analyzed for, but was not detected ("Non-detect") at or above the MRL/MDL. DOD-QSM 4.2 definition : Analyte was not detected and is reported as less than the LOD or as defined by the project. The detection limit is adjusted for dilution.
i The MRL/MDL or LOQ/LOD is elevated due to a chromatographic interference.
X See case narrative.
Q See case narrative. One or more quality control criteria was outside the limits.
Additional Petroleum Hydrocarbon Specific Qualifiers
F The chromatographic fingerprint of the sample matches the elution pattern of the calibration standard.
L The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of lighter molecular weight constituents than the calibration standard.
H The chromatographic fingerprint of the sample resembles a petroleum product, but the elution pattern indicates the presence of a greater amount of heavier molecular weight constituents than the calibration standard.
O The chromatographic fingerprint of the sample resembles an oil, but does not match the calibration standard.
Y The chromatographic fingerprint of the sample resembles a petroleum product eluting in approximately the correct carbon range, but the elution pattern does not match the calibration standard.
Z The chromatographic fingerprint does not resemble a petroleum product.
Page 4 of 64
Agency Web Site Number
Alaska DEC UST http://dec.alaska.gov/applications/eh/ehllabreports/USTLabs.aspx UST-040
Arizona DHS http://www.azdhs.gov/lab/license/env.htm AZ0339
Arkansas - DEQ http://www.adeq.state.ar.us/techsvs/labcert.htm 88-0637
California DHS (ELAP) http://www.cdph.ca.gov/certlic/labs/Pages/ELAP.aspx 2795
DOD ELAP http://www.denix.osd.mil/edqw/Accreditation/AccreditedLabs.cfm L14-51
Florida DOH http://www.doh.state.fl.us/lab/EnvLabCert/WaterCert.htm E87412
Hawaii DOH Not available -
Idaho DHWhttp://www.healthandwelfare.idaho.gov/Health/Labs/CertificationDrinkingWaterLabs/tabid/1833/Default.aspx -
ISO 17025 http://www.pjlabs.com/ L14-50
Louisiana DEQhttp://www.deq.louisiana.gov/portal/DIVISIONS/PublicParticipationandPermitSupport/LouisianaLaboratoryAccreditationProgram.aspx 03016
Maine DHS Not available WA01276
Michigan DEQ http://www.michigan.gov/deq/0,1607,7-135-3307_4131_4156---,00.html 9949
Minnesota DOH http://www.health.state.mn.us/accreditation 053-999-457
Montana DPHHS http://www.dphhs.mt.gov/publichealth/ CERT0047
Nevada DEP http://ndep.nv.gov/bsdw/labservice.htm WA01276
New Jersey DEP http://www.nj.gov/dep/oqa/ WA005
North Carolina DWQ http://www.dwqlab.org/ 605
Oklahoma DEQ http://www.deq.state.ok.us/CSDnew/labcert.htm 9801
Oregon – DEQ (NELAP)http://public.health.oregon.gov/LaboratoryServices/EnvironmentalLaboratoryAccreditation/Pages/index.aspx WA100010
South Carolina DHEC http://www.scdhec.gov/environment/envserv/ 61002
Texas CEQ http://www.tceq.texas.gov/field/qa/env_lab_accreditation.html T104704427
Washington DOE http://www.ecy.wa.gov/programs/eap/labs/lab-accreditation.html C544
Wisconsin DNR http://dnr.wi.gov/ 998386840
Wyoming (EPA Region 8) http://www.epa.gov/region8/water/dwhome/wyomingdi.html -
Kelso Laboratory Website www.alsglobal.com NA
ALS Group USA Corp. dba ALS Environmental (ALS) - KelsoState Certifications, Accreditations, and Licenses
Analyses were performed according to our laboratory’s NELAP-approved quality assurance program. A complete listing of specific NELAP-certified analytes, can be found in the certification section at www.ALSGlobal.com or at the accreditation bodies web site.Please refer to the certification and/or accreditation body's web site if samples are submitted for compliance purposes. The states highlighted above, require the analysis be listed on the state certification if used for compliance purposes and if the method/anlayte is offered by that state.
Page 5 of 64
Case Narrative
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
Page 6 of 64
Approved by______________________________________________
ALS ENVIRONMENTAL Client: ALS Environmental - Canada Service Request No.: K1509391 Project: L1651410 Date Received: 08/26/15 Sample Matrix: Plant Tissue
Case Narrative All analyses were performed consistent with the quality assurance program of ALS Environmental. This report contains analytical results for samples designated for Tier II data deliverables. When appropriate to the method, method blank results have been reported with each analytical test. Surrogate recoveries have been reported for all applicable organic analyses. Additional quality control analyses reported herein include: Laboratory Control Sample (LCS), and Laboratory/Duplicate Laboratory Control Sample (LCS/DLCS). Sample Receipt Seventeen plant tissue samples were received for analysis at ALS Environmental on 08/26/15. The samples were received in good condition and consistent with the accompanying chain of custody form. The samples were stored frozen at –20ºC upon receipt at the laboratory. Polynuclear Aromatic Hydrocarbons by EPA Method 8270 Elevated Detection Limits: The detection limits were elevated for Benzo(a)pyrene in the field samples. The chromatogram indicated the presence of non-target background components. The results were flagged to indicate the matrix interference. Sample Notes and Discussion: The results reported for Acenaphthene in several samples may contain a slight bias. The chromatogram indicated the presence of non-target background components. The matrix interference may have resulted in a slight high bias in the affected samples. The results were flagged with “X” to indicate the issue. No other anomalies associated with the analysis of these samples were observed.
Page 7 of 64
Chain of Custody
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
Page 8 of 64
Polynuclear Aromatic Hydrocarbons
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
Page 12 of 64
K1509391ALS Environmental - Canada
L1651410
Polynuclear Aromatic Hydrocarbons
Cover Page - Organic Analysis Data Package
Client:
Project:
Service Request:
Date
Collected
Date
ReceivedLab CodeSample Name
ALS Group USA, Corp. dba ALS Environmental
K1509391-001 07/31/2015 08/26/2015L1651410-1 15-TILBURY-B-1
K1509391-002 07/31/2015 08/26/2015L1651410-2 15-TILBURY-B-1D
K1509391-003 07/31/2015 08/26/2015L1651410-3 15-TILBURY-B-2
K1509391-004 07/31/2015 08/26/2015L1651410-4 15-TILBURY-B-3
K1509391-005 07/31/2015 08/26/2015L1651410-5 15-TILBURY-B-4
K1509391-006 07/31/2015 08/26/2015L1651410-6 15-TILBURY-B-5
K1509391-007 07/31/2015 08/26/2015L1651410-7 15-TILBURY-B-6
K1509391-008 07/31/2015 08/26/2015L1651410-8 15-TILBURY-B-7
K1509391-009 07/31/2015 08/26/2015L1651410-9 15-TILBURY-B-8
K1509391-010 07/31/2015 08/26/2015L1651410-10 15-TILBURY-B-8D
K1509391-011 07/31/2015 08/26/2015L1651410-11 15-TILBURY-B-9
K1509391-012 07/31/2015 08/26/2015L1651410-12 15-TILBURY-B-10
K1509391-013 07/31/2015 08/26/2015L1651410-13 15-TILBURY-B-11
K1509391-014 07/31/2015 08/26/2015L1651410-14 15-TILBURY-B-12
K1509391-015 07/31/2015 08/26/2015L1651410-15 15-TILBURY-B-13
K1509391-016 07/31/2015 08/26/2015L1651410-16 15-TILBURY-B-14
K1509391-017 07/31/2015 08/26/2015L1651410-17 15-TILBURY-B-15
Cover Page - Organic 1of1Page
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Analytical Results
ALS Environmental - Canada K1509391
K1509391-001
ug/Kg
Wet
L1651410-1 15-TILBURY-B-1
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/150.78Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/15UNDFluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
11 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1563
41-100 AcceptableFluoranthene-d10 09/08/1575
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
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Analytical Results
ALS Environmental - Canada K1509391
K1509391-002
ug/Kg
Wet
L1651410-2 15-TILBURY-B-1D
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/150.80Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/15UNDFluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
17 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1563
41-100 AcceptableFluoranthene-d10 09/08/1574
39-111 AcceptableTerphenyl-d14 09/08/1561
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
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Analytical Results
ALS Environmental - Canada K1509391
K1509391-003
ug/Kg
Wet
L1651410-3 15-TILBURY-B-2
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/150.90Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/15UNDFluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
16 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1579
39-111 AcceptableTerphenyl-d14 09/08/1563
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
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Analytical Results
ALS Environmental - Canada K1509391
K1509391-004
ug/Kg
Wet
L1651410-4 15-TILBURY-B-3
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.96 09/02/151 KWG150812309/08/15UNDNaphthalene
0.96 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.48 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.48 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.48 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.48 09/02/151 KWG150812309/08/15UNDFluorene
0.48 09/02/151 KWG150812309/08/151.2Phenanthrene
0.48 09/02/151 KWG150812309/08/15UNDAnthracene
0.48 09/02/151 KWG150812309/08/15UNDFluoranthene
0.48 09/02/151 KWG150812309/08/15UNDPyrene
0.48 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.48 09/02/151 KWG150812309/08/15UNDChrysene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.48 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
14 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.48 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.48 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1567
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1559
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
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Analytical Results
ALS Environmental - Canada K1509391
K1509391-005
ug/Kg
Wet
L1651410-5 15-TILBURY-B-4
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.97 09/02/151 KWG150812309/08/15UNDNaphthalene
0.97 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.49 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.49 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.49 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.49 09/02/151 KWG150812309/08/15UNDFluorene
0.49 09/02/151 KWG150812309/08/152.0Phenanthrene
0.49 09/02/151 KWG150812309/08/15UNDAnthracene
0.49 09/02/151 KWG150812309/08/150.79Fluoranthene
0.49 09/02/151 KWG150812309/08/150.51Pyrene
0.49 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.49 09/02/151 KWG150812309/08/15UNDChrysene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.49 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
20 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.49 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.49 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1571
41-100 AcceptableFluoranthene-d10 09/08/1582
39-111 AcceptableTerphenyl-d14 09/08/1565
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:37:4309/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 18 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-006
ug/Kg
Wet
L1651410-6 15-TILBURY-B-5
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/152.1Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/150.89Fluoranthene
0.50 09/02/151 KWG150812309/08/150.74Pyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
15 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1560
41-100 AcceptableFluoranthene-d10 09/08/1571
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:37:4709/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 19 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-007
ug/Kg
Wet
L1651410-7 15-TILBURY-B-6
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.99 09/02/151 KWG150812309/08/15UNDNaphthalene
0.99 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15X0.57Acenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/151.8Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/150.62Fluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
16 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1570
41-100 AcceptableFluoranthene-d10 09/08/1580
39-111 AcceptableTerphenyl-d14 09/08/1564
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:37:5109/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 20 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-008
ug/Kg
Wet
L1651410-8 15-TILBURY-B-7
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15X0.63Acenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/151.3Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/150.56Fluoranthene
0.50 09/02/151 KWG150812309/08/15UXNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
18 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1579
39-111 AcceptableTerphenyl-d14 09/08/1564
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:37:5509/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 21 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-009
ug/Kg
Wet
L1651410-9 15-TILBURY-B-8
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.99 09/02/151 KWG150812309/08/15UNDNaphthalene
0.99 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/151.3Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/150.57Fluoranthene
0.50 09/02/151 KWG150812309/08/15UXNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
12 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1570
41-100 AcceptableFluoranthene-d10 09/08/1581
39-111 AcceptableTerphenyl-d14 09/08/1567
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:37:5909/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 22 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-010
ug/Kg
Wet
L1651410-10 15-TILBURY-B-8D
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.98 09/02/151 KWG150812309/08/15UNDNaphthalene
0.98 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.49 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.49 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.49 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.49 09/02/151 KWG150812309/08/15UNDFluorene
0.49 09/02/151 KWG150812309/08/151.3Phenanthrene
0.49 09/02/151 KWG150812309/08/15UNDAnthracene
0.49 09/02/151 KWG150812309/08/150.56Fluoranthene
0.49 09/02/151 KWG150812309/08/15UXNDPyrene
0.49 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.49 09/02/151 KWG150812309/08/15UNDChrysene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.49 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
20 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.49 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.49 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1581
39-111 AcceptableTerphenyl-d14 09/08/1566
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:0309/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 23 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-011
ug/Kg
Wet
L1651410-11 15-TILBURY-B-9
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/150.75Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/15UNDFluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
13 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1583
39-111 AcceptableTerphenyl-d14 09/08/1559
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:0709/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 24 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-012
ug/Kg
Wet
L1651410-12 15-TILBURY-B-10
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.98 09/02/151 KWG150812309/08/15UNDNaphthalene
0.98 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.49 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.49 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.49 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.49 09/02/151 KWG150812309/08/15UNDFluorene
0.49 09/02/151 KWG150812309/08/151.5Phenanthrene
0.49 09/02/151 KWG150812309/08/15UNDAnthracene
0.49 09/02/151 KWG150812309/08/150.58Fluoranthene
0.49 09/02/151 KWG150812309/08/15UNDPyrene
0.49 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.49 09/02/151 KWG150812309/08/15UNDChrysene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.49 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
15 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.49 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.49 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1561
41-100 AcceptableFluoranthene-d10 09/08/1574
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:1109/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 25 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-013
ug/Kg
Wet
L1651410-13 15-TILBURY-B-11
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.1 09/02/151 KWG150812309/08/15UNDNaphthalene
1.1 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.51 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.51 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.51 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.51 09/02/151 KWG150812309/08/15UNDFluorene
0.51 09/02/151 KWG150812309/08/152.4Phenanthrene
0.51 09/02/151 KWG150812309/08/15UNDAnthracene
0.51 09/02/151 KWG150812309/08/150.96Fluoranthene
0.51 09/02/151 KWG150812309/08/150.65Pyrene
0.51 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.51 09/02/151 KWG150812309/08/15UNDChrysene
0.51 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.51 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
21 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.51 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.51 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.51 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1561
41-100 AcceptableFluoranthene-d10 09/08/1573
39-111 AcceptableTerphenyl-d14 09/08/1552
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:1509/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 26 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-014
ug/Kg
Wet
L1651410-14 15-TILBURY-B-12
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.97 09/02/151 KWG150812309/08/15UNDNaphthalene
0.97 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.49 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.49 09/02/151 KWG150812309/08/150.71Acenaphthene
0.49 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.49 09/02/151 KWG150812309/08/150.86Fluorene
0.49 09/02/151 KWG150812309/08/153.9Phenanthrene
0.49 09/02/151 KWG150812309/08/15UNDAnthracene
0.49 09/02/151 KWG150812309/08/151.7Fluoranthene
0.49 09/02/151 KWG150812309/08/150.72Pyrene
0.49 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.49 09/02/151 KWG150812309/08/15UNDChrysene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.49 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
21 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.49 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.49 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1580
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:1909/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 27 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-015
ug/Kg
Wet
L1651410-15 15-TILBURY-B-13
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.99 09/02/151 KWG150812309/08/15UNDNaphthalene
0.99 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/15UNDFluorene
0.50 09/02/151 KWG150812309/08/151.2Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/15UNDFluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
15 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:2309/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 28 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-016
ug/Kg
Wet
L1651410-16 15-TILBURY-B-14
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
1.0 09/02/151 KWG150812309/08/15UNDNaphthalene
1.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.50 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.50 09/02/151 KWG150812309/08/15UXNDAcenaphthene
0.50 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.50 09/02/151 KWG150812309/08/150.63Fluorene
0.50 09/02/151 KWG150812309/08/153.5Phenanthrene
0.50 09/02/151 KWG150812309/08/15UNDAnthracene
0.50 09/02/151 KWG150812309/08/150.96Fluoranthene
0.50 09/02/151 KWG150812309/08/15UNDPyrene
0.50 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.50 09/02/151 KWG150812309/08/15UNDChrysene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.50 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
18 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.50 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.50 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.50 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1554
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:2709/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 29 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-017
ug/Kg
Wet
L1651410-17 15-TILBURY-B-15
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.97 09/02/151 KWG150812309/08/15UNDNaphthalene
0.97 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.49 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.49 09/02/151 KWG150812309/08/15X0.58Acenaphthene
0.49 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.49 09/02/151 KWG150812309/08/150.55Fluorene
0.49 09/02/151 KWG150812309/08/153.8Phenanthrene
0.49 09/02/151 KWG150812309/08/15UNDAnthracene
0.49 09/02/151 KWG150812309/08/151.8Fluoranthene
0.49 09/02/151 KWG150812309/08/150.77Pyrene
0.49 09/02/151 KWG150812309/08/15UXNDBenz(a)anthracene
0.49 09/02/151 KWG150812309/08/15UXNDChrysene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.49 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
17 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
0.49 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.49 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.49 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1576
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:3109/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 30 of 64
Analytical Results
ALS Environmental - Canada K1509391
KWG1508123-3
ug/Kg
Wet
Method Blank
NA
NA
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.96 09/02/151 KWG150812309/08/15UNDNaphthalene
0.96 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.48 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.48 09/02/151 KWG150812309/08/15UNDAcenaphthene
0.48 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.48 09/02/151 KWG150812309/08/15UNDFluorene
0.48 09/02/151 KWG150812309/08/15UNDPhenanthrene
0.48 09/02/151 KWG150812309/08/15UNDAnthracene
0.48 09/02/151 KWG150812309/08/15UNDFluoranthene
0.48 09/02/151 KWG150812309/08/15UNDPyrene
0.48 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.48 09/02/151 KWG150812309/08/15UNDChrysene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.48 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(a)pyrene
0.48 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.48 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1573
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page15:38:3509/14/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 31 of 64
ALS Group USA, Corp. dba ALS Environmental
Extraction Method:
QA/QC Report
Surrogate Recovery Summary
ALS Environmental - Canada K1509391
Low
Plant tissue
L1651410
Client:
Project:
Sample Matrix:
Service Request:
Units:
Level:
Sample Name Lab Code
Polynuclear Aromatic Hydrocarbons
EPA 3541
Analysis Method: 8270D SIM
Sur1 Sur2 Sur3
Percent
K1509391-001L1651410-1 15-TILBURY-B-1 63 75 56
K1509391-002L1651410-2 15-TILBURY-B-1D 63 74 61
K1509391-003L1651410-3 15-TILBURY-B-2 66 79 63
K1509391-004L1651410-4 15-TILBURY-B-3 67 77 59
K1509391-005L1651410-5 15-TILBURY-B-4 71 82 65
K1509391-006L1651410-6 15-TILBURY-B-5 60 71 56
K1509391-007L1651410-7 15-TILBURY-B-6 70 80 64
K1509391-008L1651410-8 15-TILBURY-B-7 66 79 64
K1509391-009L1651410-9 15-TILBURY-B-8 70 81 67
K1509391-010L1651410-10 15-TILBURY-B-8D 69 81 66
K1509391-011L1651410-11 15-TILBURY-B-9 69 83 59
K1509391-012L1651410-12 15-TILBURY-B-10 61 74 53
K1509391-013L1651410-13 15-TILBURY-B-11 61 73 52
K1509391-014L1651410-14 15-TILBURY-B-12 69 80 56
K1509391-015L1651410-15 15-TILBURY-B-13 66 77 53
K1509391-016L1651410-16 15-TILBURY-B-14 64 77 54
K1509391-017L1651410-17 15-TILBURY-B-15 64 76 53
KWG1508123-3Method Blank 64 73 56
KWG1508123-1Lab Control Sample D61 82 D D65
KWG1508123-2Duplicate Lab Control Sample D69 88 D D69
Form 2A - OrganicPrinted: 09/14/2015 15:38:40 1 of 1
Surrogate Recovery Control Limits (%)
39-96
41-100
39-111
Fluorene-d10
Fluoranthene-d10
Terphenyl-d14
Results flagged with an asterisk (*) indicate values outside control criteria.
Page
Results flagged with a pound (#) indicate the control criteria is not applicable.
RR181708SuperSet Reference:
Sur1
Sur2
Sur3
=
=
=
u:\Stealth\Crystal.rpt\Form2.rpt Page 32 of 64
QA/QC Report
Internal Standard Area and RT Summary
ALS Environmental - Canada K1509391
Polynuclear Aromatic Hydrocarbons
L1651410
MS14
8270D SIM
KWG1508744-2
09/08/2015
09:22
KWG1508744
J:\MS14\DATA\090815\0908F002.D
Client:
Project:
Instrument ID:
File ID:
Analysis Method:
Lab Code:
Analysis Lot:
Service Request:
Date Analyzed:
Time Analyzed:
ALS Group USA, Corp. dba ALS Environmental
Phenanthrene-d10
RTArea
Acenaphthene-d10Naphthalene-d8
RTAreaRTArea
7.51
8.01
7.01
173,034
346,068
86,517
152,646
6.25
6.75
5.75
91,160
182,320
45,580
80,633
4.60
5.10
4.10
163,486
326,972
81,743
132,922
Results ==>
Upper Limit ==>
Lower Limit ==>
ICAL Result ==> 4.70 6.29 7.53Associated Analyses
KWG1508123-3 98,345 6.25 183,896 7.51 170,370 4.59Method Blank
KWG1508123-1 80,893 6.25 151,457 7.51 147,100 4.59Lab Control Sample
KWG1508123-2 81,842 6.25 153,337 7.51 147,927 4.59Duplicate Lab Control Sample
K1509391-001 91,455 6.25 167,196 7.51 156,572 4.59L1651410-1 15-TILBURY-B-1
K1509391-002 89,378 6.25 163,094 7.51 153,578 4.59L1651410-2 15-TILBURY-B-1D
K1509391-003 90,013 6.26 163,732 7.52 153,999 4.60L1651410-3 15-TILBURY-B-2
K1509391-004 89,903 6.26 163,512 7.52 153,617 4.60L1651410-4 15-TILBURY-B-3
K1509391-005 91,402 6.26 166,038 7.52 157,440 4.60L1651410-5 15-TILBURY-B-4
K1509391-006 96,450 6.26 174,850 7.52 161,998 4.61L1651410-6 15-TILBURY-B-5
K1509391-007 92,211 6.27 169,041 7.52 155,852 4.61L1651410-7 15-TILBURY-B-6
K1509391-008 95,830 6.27 174,989 7.53 160,228 4.61L1651410-8 15-TILBURY-B-7
K1509391-009 95,062 6.27 177,174 7.53 161,687 4.61L1651410-9 15-TILBURY-B-8
K1509391-010 97,898 6.27 180,194 7.53 165,470 4.61L1651410-10 15-TILBURY-B-8D
K1509391-011 97,604 6.27 181,778 7.53 176,604 4.61L1651410-11 15-TILBURY-B-9
K1509391-012 98,713 6.27 185,018 7.53 184,428 4.61L1651410-12 15-TILBURY-B-10
K1509391-013 98,315 6.27 185,980 7.53 186,699 4.61L1651410-13 15-TILBURY-B-11
K1509391-014 97,354 6.27 184,891 7.53 183,852 4.61L1651410-14 15-TILBURY-B-12
K1509391-015 97,619 6.27 184,963 7.53 184,958 4.62L1651410-15 15-TILBURY-B-13
K1509391-016 98,253 6.27 183,990 7.53 182,356 4.61L1651410-16 15-TILBURY-B-14
K1509391-017 97,617 6.27 188,446 7.53 185,088 4.61L1651410-17 15-TILBURY-B-15
Form 2B - OrganicPrinted: 09/14/2015 15:39:00 1Page
Results flagged with an asterisk (*) indicate values outside control criteria.
of
RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form2IS3New.rpt
2
Page 33 of 64
QA/QC Report
Internal Standard Area and RT Summary
ALS Environmental - Canada K1509391
Polynuclear Aromatic Hydrocarbons
L1651410
MS14
8270D SIM
KWG1508744-2
09/08/2015
09:22
KWG1508744
J:\MS14\DATA\090815\0908F002.D
Client:
Project:
Instrument ID:
File ID:
Analysis Method:
Lab Code:
Analysis Lot:
Service Request:
Date Analyzed:
Time Analyzed:
ALS Group USA, Corp. dba ALS Environmental
Perylene-d12Chrysene-d12
RTAreaRTArea
13.10
13.60
12.60
199,020
398,040
99,510
160,772
10.03
10.53
9.53
210,965
421,930
105,483
164,618
Results ==>
Upper Limit ==>
Lower Limit ==>
ICAL Result ==> 10.05 13.06Associated Analyses
KWG1508123-3 201,228 13.09 219,975 10.03Method Blank
KWG1508123-1 173,657 13.09 182,742 10.03Lab Control Sample
KWG1508123-2 175,893 13.09 186,893 10.03Duplicate Lab Control Sample
K1509391-001 180,815 13.11 195,740 10.03L1651410-1 15-TILBURY-B-1
K1509391-002 175,195 13.14 175,168 10.04L1651410-2 15-TILBURY-B-1D
K1509391-003 176,503 13.16 181,423 10.05L1651410-3 15-TILBURY-B-2
K1509391-004 186,411 13.17 176,142 10.05L1651410-4 15-TILBURY-B-3
K1509391-005 185,965 13.19 179,750 10.06L1651410-5 15-TILBURY-B-4
K1509391-006 195,977 13.20 191,737 10.06L1651410-6 15-TILBURY-B-5
K1509391-007 188,691 13.21 184,820 10.07L1651410-7 15-TILBURY-B-6
K1509391-008 196,094 13.22 193,547 10.07L1651410-8 15-TILBURY-B-7
K1509391-009 196,754 13.22 194,961 10.07L1651410-9 15-TILBURY-B-8
K1509391-010 199,688 13.23 201,853 10.07L1651410-10 15-TILBURY-B-8D
K1509391-011 201,111 13.23 233,533 10.08L1651410-11 15-TILBURY-B-9
K1509391-012 202,203 13.23 239,370 10.07L1651410-12 15-TILBURY-B-10
K1509391-013 202,957 13.23 243,130 10.07L1651410-13 15-TILBURY-B-11
K1509391-014 209,032 13.23 241,659 10.08L1651410-14 15-TILBURY-B-12
K1509391-015 249,658 13.23 245,490 10.08L1651410-15 15-TILBURY-B-13
K1509391-016 245,516 13.24 242,371 10.08L1651410-16 15-TILBURY-B-14
K1509391-017 249,565 13.24 248,400 10.08L1651410-17 15-TILBURY-B-15
Form 2B - OrganicPrinted: 09/14/2015 15:39:00 2Page
Results flagged with an asterisk (*) indicate values outside control criteria.
of
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2
Page 34 of 64
Lab Control Spike/Duplicate Lab Control Spike Summary
%Rec
Lab Control Spike
%Rec
Limits
Duplicate Lab Control Spike
%Rec RPD
RPD
Limit
QA/QC Report
Duplicate Lab Control Sample
KWG1508123-2
ALS Environmental - Canada K1509391
8270D SIM
ug/Kg
Wet
Lab Control Sample
KWG1508123-1
Polynuclear Aromatic Hydrocarbons
KWG1508123
Plant tissue
Low
L1651410
Client:
Project:
Sample Matrix:
Service Request:
Extraction Method:
Analysis Method:
Units:
Basis:
Level:
Extraction Lot:
Analyte Name Result Result
ALS Group USA, Corp. dba ALS Environmental
Date Extracted:
Date Analyzed:
09/02/2015
09/08/2015
EPA 3541
Spike
Amount
Spike
Amount
43-102250 68 40Naphthalene 250 60 13150 171
43-114250 67 402-Methylnaphthalene 250 59 13148 168
53-100250 73 40Acenaphthylene 250 64 12161 181
52-101250 73 40Acenaphthene 250 64 12161 181
55-103250 73 40Dibenzofuran 250 63 15156 182
56-104250 74 40Fluorene 250 67 11167 186
54-100250 79 40Phenanthrene 250 71 10178 196
57-103250 85 40Anthracene 250 76 11189 211
55-108250 92 40Fluoranthene 250 85 8213 230
48-117250 81 40Pyrene 250 75 7188 202
55-105250 96 40Benz(a)anthracene 250 89 7223 240
58-112250 90 40Chrysene 250 83 8208 225
60-107250 106 40Benzo(b)fluoranthene 250 98 8246 265
58-115250 98 40Benzo(k)fluoranthene 250 89 9223 244
56-110250 97 40Benzo(a)pyrene 250 89 8223 243
50-117250 89 40Indeno(1,2,3-cd)pyrene 250 84 6209 222
52-112250 89 40Dibenz(a,h)anthracene 250 83 7208 223
56-117250 88 40Benzo(g,h,i)perylene 250 82 7204 219
Form 3C - OrganicPrinted: 09/14/2015 15:39:04 Page 1 of 1
Results flagged with an asterisk (*) indicate values outside control criteria.
RR181708SuperSet Reference:
Percent recoveries and relative percent differences (RPD) are determined by the software using values in the calculation which have not been rounded.
u:\Stealth\Crystal.rpt\Form3DLC.rpt Page 35 of 64
ALS Group USA, Corp. dba ALS Environmental
Instrument ID:
File ID: Lab Code:
Sample Name:
Time Analyzed:
Date Analyzed:
Date Extracted:
Service Request:
Sample Matrix:
Project:
Client:
J:\MS14\DATA\090815\0908F003.D
09:48
09/02/2015
MS14
Plant tissue
Method Blank
KWG1508123-3
09/08/2015
Polynuclear Aromatic Hydrocarbons
Method Blank Summary
K1509391
L1651410
QA/QC Report
ALS Environmental - Canada
This Method Blank applies to the following analyses:
EPA 3541
8270D SIM KWG1508123
LowExtraction Method:
Analysis Method:
Level:
Extraction Lot:
Sample Name Lab Code File ID
Date
Analyzed
Time
Analyzed
KWG1508123-1 10:13J:\MS14\DATA\090815\0908F004.DLab Control Sample 09/08/15
KWG1508123-2 10:39J:\MS14\DATA\090815\0908F005.DDuplicate Lab Control Sample 09/08/15
K1509391-001 11:56J:\MS14\DATA\090815\0908F008.DL1651410-1 15-TILBURY-B-1 09/08/15
K1509391-002 12:22J:\MS14\DATA\090815\0908F009.DL1651410-2 15-TILBURY-B-1D 09/08/15
K1509391-003 12:49J:\MS14\DATA\090815\0908F010.DL1651410-3 15-TILBURY-B-2 09/08/15
K1509391-004 13:15J:\MS14\DATA\090815\0908F011.DL1651410-4 15-TILBURY-B-3 09/08/15
K1509391-005 13:42J:\MS14\DATA\090815\0908F012.DL1651410-5 15-TILBURY-B-4 09/08/15
K1509391-006 14:09J:\MS14\DATA\090815\0908F013.DL1651410-6 15-TILBURY-B-5 09/08/15
K1509391-007 14:36J:\MS14\DATA\090815\0908F014.DL1651410-7 15-TILBURY-B-6 09/08/15
K1509391-008 15:03J:\MS14\DATA\090815\0908F015.DL1651410-8 15-TILBURY-B-7 09/08/15
K1509391-009 15:30J:\MS14\DATA\090815\0908F016.DL1651410-9 15-TILBURY-B-8 09/08/15
K1509391-010 15:57J:\MS14\DATA\090815\0908F017.DL1651410-10 15-TILBURY-B-8D 09/08/15
K1509391-011 16:24J:\MS14\DATA\090815\0908F018.DL1651410-11 15-TILBURY-B-9 09/08/15
K1509391-012 16:51J:\MS14\DATA\090815\0908F019.DL1651410-12 15-TILBURY-B-10 09/08/15
K1509391-013 17:18J:\MS14\DATA\090815\0908F020.DL1651410-13 15-TILBURY-B-11 09/08/15
K1509391-014 17:45J:\MS14\DATA\090815\0908F021.DL1651410-14 15-TILBURY-B-12 09/08/15
K1509391-015 18:12J:\MS14\DATA\090815\0908F022.DL1651410-15 15-TILBURY-B-13 09/08/15
K1509391-016 18:39J:\MS14\DATA\090815\0908F023.DL1651410-16 15-TILBURY-B-14 09/08/15
K1509391-017 19:06J:\MS14\DATA\090815\0908F024.DL1651410-17 15-TILBURY-B-15 09/08/15
Form 4A - Organic 1Printed: of 1Page15:39:1509/14/2015RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form4mb.rpt Page 36 of 64
09/08/2015
ALS Group USA, Corp. dba ALS Environmental
Instrument ID:
File ID: Lab Code:
Sample Name:
Time Analyzed:
Date Analyzed:
Date Extracted:
Service Request:
Sample Matrix:
Project:
Client:
J:\MS14\DATA\090815\0908F004.D
Lab Control Sample Summary
MS14
KWG1508123-1
Lab Control Sample
10:13
09/02/2015
Plant tissue
L1651410
K1509391ALS Environmental - Canada
Polynuclear Aromatic Hydrocarbons
QA/QC Report
This Lab Control Sample applies to the following analyses:
EPA 3541
8270D SIM
Low
KWG1508123
Extraction Method:
Analysis Method:
Level:
Extraction Lot:
Sample Name Lab Code File ID
Date
Analyzed
Time
Analyzed
KWG1508123-3 09:48J:\MS14\DATA\090815\0908F003.DMethod Blank 09/08/15
K1509391-001 11:56J:\MS14\DATA\090815\0908F008.DL1651410-1 15-TILBURY-B-1 09/08/15
K1509391-002 12:22J:\MS14\DATA\090815\0908F009.DL1651410-2 15-TILBURY-B-1D 09/08/15
K1509391-003 12:49J:\MS14\DATA\090815\0908F010.DL1651410-3 15-TILBURY-B-2 09/08/15
K1509391-004 13:15J:\MS14\DATA\090815\0908F011.DL1651410-4 15-TILBURY-B-3 09/08/15
K1509391-005 13:42J:\MS14\DATA\090815\0908F012.DL1651410-5 15-TILBURY-B-4 09/08/15
K1509391-006 14:09J:\MS14\DATA\090815\0908F013.DL1651410-6 15-TILBURY-B-5 09/08/15
K1509391-007 14:36J:\MS14\DATA\090815\0908F014.DL1651410-7 15-TILBURY-B-6 09/08/15
K1509391-008 15:03J:\MS14\DATA\090815\0908F015.DL1651410-8 15-TILBURY-B-7 09/08/15
K1509391-009 15:30J:\MS14\DATA\090815\0908F016.DL1651410-9 15-TILBURY-B-8 09/08/15
K1509391-010 15:57J:\MS14\DATA\090815\0908F017.DL1651410-10 15-TILBURY-B-8D 09/08/15
K1509391-011 16:24J:\MS14\DATA\090815\0908F018.DL1651410-11 15-TILBURY-B-9 09/08/15
K1509391-012 16:51J:\MS14\DATA\090815\0908F019.DL1651410-12 15-TILBURY-B-10 09/08/15
K1509391-013 17:18J:\MS14\DATA\090815\0908F020.DL1651410-13 15-TILBURY-B-11 09/08/15
K1509391-014 17:45J:\MS14\DATA\090815\0908F021.DL1651410-14 15-TILBURY-B-12 09/08/15
K1509391-015 18:12J:\MS14\DATA\090815\0908F022.DL1651410-15 15-TILBURY-B-13 09/08/15
K1509391-016 18:39J:\MS14\DATA\090815\0908F023.DL1651410-16 15-TILBURY-B-14 09/08/15
K1509391-017 19:06J:\MS14\DATA\090815\0908F024.DL1651410-17 15-TILBURY-B-15 09/08/15
Form 4B - Organic 1of1PagePrinted: 09/14/2015 15:39:20SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form4LCS.rpt Page 37 of 64
QA/QC Results
Tune Summary
ALS Environmental - Canada
L1651410
K1509391
08:57
J:\MS14\DATA\090815\0908F001.D
MS14
Target
Mass
Relative
to Mass
Lower
Limit%
Upper
Limit%
Relative
Abundance %
Raw
Abundance
Result
Pass/Fail
8270D SIM
KWG1508744
Polynuclear Aromatic Hydrocarbons
Client:
Project:
Service Request:
Date Analyzed:
Time Analyzed:
File ID:
Instrument ID: Analysis Method:
Analysis Lot: Column:
ALS Group USA, Corp. dba ALS Environmental
09/08/2015
198 PASS 10 80 30.5 4778451
69 PASS 0 2 1.0 44868
198 PASS 0 100 27.7 4334969
69 PASS 0 2 1.2 52070
198 PASS 10 80 40.2 62872127
198 PASS 0 2 0.5 806197
442 PASS 30 100 42.3 156445198
198 PASS 5 9 6.3 9869199
198 PASS 10 60 36.6 57326275
442 PASS 1 50 3.0 11082365
443 PASS 0 100 73.0 51599441
442 PASS 100 100 100.0 370226442
442 PASS 15 24 19.1 70638443
Sample Name Lab Code File ID
Date
Analyzed
Time
Analyzed Q
KWG1508744-2 J:\MS14\DATA\090815\0908F002.D 09:22Continuing Calibration Verification 09/08/2015
KWG1508123-3 J:\MS14\DATA\090815\0908F003.D 09:48Method Blank 09/08/2015
KWG1508123-1 J:\MS14\DATA\090815\0908F004.D 10:13Lab Control Sample 09/08/2015
KWG1508123-2 J:\MS14\DATA\090815\0908F005.D 10:39Duplicate Lab Control Sample 09/08/2015
K1509391-001 J:\MS14\DATA\090815\0908F008.D 11:56L1651410-1 15-TILBURY-B-1 09/08/2015
K1509391-002 J:\MS14\DATA\090815\0908F009.D 12:22L1651410-2 15-TILBURY-B-1D 09/08/2015
K1509391-003 J:\MS14\DATA\090815\0908F010.D 12:49L1651410-3 15-TILBURY-B-2 09/08/2015
K1509391-004 J:\MS14\DATA\090815\0908F011.D 13:15L1651410-4 15-TILBURY-B-3 09/08/2015
K1509391-005 J:\MS14\DATA\090815\0908F012.D 13:42L1651410-5 15-TILBURY-B-4 09/08/2015
K1509391-006 J:\MS14\DATA\090815\0908F013.D 14:09L1651410-6 15-TILBURY-B-5 09/08/2015
K1509391-007 J:\MS14\DATA\090815\0908F014.D 14:36L1651410-7 15-TILBURY-B-6 09/08/2015
K1509391-008 J:\MS14\DATA\090815\0908F015.D 15:03L1651410-8 15-TILBURY-B-7 09/08/2015
K1509391-009 J:\MS14\DATA\090815\0908F016.D 15:30L1651410-9 15-TILBURY-B-8 09/08/2015
K1509391-010 J:\MS14\DATA\090815\0908F017.D 15:57L1651410-10 15-TILBURY-B-8D 09/08/2015
K1509391-011 J:\MS14\DATA\090815\0908F018.D 16:24L1651410-11 15-TILBURY-B-9 09/08/2015
K1509391-012 J:\MS14\DATA\090815\0908F019.D 16:51L1651410-12 15-TILBURY-B-10 09/08/2015
K1509391-013 J:\MS14\DATA\090815\0908F020.D 17:18L1651410-13 15-TILBURY-B-11 09/08/2015
K1509391-014 J:\MS14\DATA\090815\0908F021.D 17:45L1651410-14 15-TILBURY-B-12 09/08/2015
K1509391-015 J:\MS14\DATA\090815\0908F022.D 18:12L1651410-15 15-TILBURY-B-13 09/08/2015
K1509391-016 J:\MS14\DATA\090815\0908F023.D 18:39L1651410-16 15-TILBURY-B-14 09/08/2015
K1509391-017 J:\MS14\DATA\090815\0908F024.D 19:06L1651410-17 15-TILBURY-B-15 09/08/2015
Form 5 - Organic 1of1PagePrinted: 09/14/2015 15:39:30
Results flagged with an asterisk (*) indicate the analysis performed outside specified tune window
RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form5.rpt Page 38 of 64
QA/QC Results
Initial Calibration Summary
ALS Environmental - Canada
L1651410
K1509391
06/18/2015
Polynuclear Aromatic Hydrocarbons
CAL14088
MS14
Client:
Project:
Calibration ID:
Instrument ID:
Service Request:
ALS Group USA, Corp. dba ALS Environmental
Calibration Date:
Column: MS
Level ID File ID
J:\MS14\DATA\061815\0618F003.DAJ:\MS14\DATA\061815\0618F004.DBJ:\MS14\DATA\061815\0618F005.DCJ:\MS14\DATA\061815\0618F006.DDJ:\MS14\DATA\061815\0618F007.DEJ:\MS14\DATA\061815\0618F008.DF
Level ID File ID
J:\MS14\DATA\061815\0618F009.DGJ:\MS14\DATA\061815\0618F010.DHJ:\MS14\DATA\061815\0618F011.DIJ:\MS14\DATA\061815\0618F012.DJ
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRFAnalyte Name
Naphthalene 4.0 8.0 202.0 1001.02 0.968 0.924 0.968 0.990A B C D E
400 1000 1600200 20000.991 1.01 0.929 0.948 0.942F G H I J
2-Methylnaphthalene 4.0 8.0 202.0 1000.724 0.769 0.709 0.743 0.741A B C D E
400 1000 1600200 20000.740 0.740 0.682 0.691 0.684F G H I J
Acenaphthylene 4.0 8.0 202.0 1001.84 1.84 1.75 1.76 1.85A B C D E
400 1000 1600200 20001.84 1.86 1.74 1.73 1.69F G H I J
Acenaphthene 4.0 8.0 202.0 1001.14 1.10 1.04 1.05 1.06A B C D E
400 1000 1600200 20001.05 1.06 0.998 1.00 0.981F G H I J
Dibenzofuran 4.0 8.0 202.0 1001.73 1.72 1.62 1.64 1.69A B C D E
400 1000 1600200 20001.68 1.68 1.57 1.58 1.53F G H I J
Fluorene 4.0 8.0 202.0 1001.31 1.33 1.26 1.28 1.32A B C D E
400 1000 1600200 20001.30 1.29 1.22 1.22 1.19F G H I J
Phenanthrene 4.0 8.0 202.0 1001.06 1.08 1.03 1.03 1.03A B C D E
400 1000 1600200 20001.01 1.02 0.947 0.938 0.922F G H I J
Anthracene 4.0 8.0 202.0 1001.04 0.976 0.934 0.969 1.01A B C D E
400 1000 1600200 20001.00 1.00 0.935 0.923 0.899F G H I J
Fluoranthene 4.0 8.0 202.0 1001.14 1.08 1.05 1.11 1.17A B C D E
400 1000 1600200 20001.15 1.17 1.08 1.07 1.05F G H I J
Pyrene 4.0 8.0 202.0 1001.20 1.10 1.07 1.11 1.13A B C D E
400 1000 1600200 20001.12 1.15 1.10 1.09 1.08F G H I J
Benz(a)anthracene 4.0 8.0 202.0 1001.23 1.04 0.953 0.927 0.965A B C D E
400 1000 1600200 20000.999 1.07 1.05 1.05 1.04F G H I J
Chrysene 4.0 8.0 202.0 1001.09 0.998 0.978 0.996 0.988A B C D E
400 1000 1600200 20000.976 0.990 0.945 0.949 0.942F G H I J
Benzo(b)fluoranthene 4.0 8.0 202.0 1001.17 1.04 1.00 1.02 1.12A B C D E
400 1000 1600200 20001.14 1.18 1.14 1.15 1.15F G H I J
Benzo(k)fluoranthene 4.0 8.0 202.0 1001.15 1.05 1.03 1.04 1.09A B C D E
400 1000 1600200 20001.11 1.14 1.10 1.12 1.12F G H I J
Form 6A - Organic 3of1PagePrinted: 09/14/2015 15:39:41RR181708SuperSet Reference:
Results flagged with an asterisk (*) indicate values outside control criteria.
† SPCC Compound ‡ CCC Compound
u:\Stealth\Crystal.rpt\Form6iNew.rpt Page 39 of 64
QA/QC Results
Initial Calibration Summary
ALS Environmental - Canada
L1651410
K1509391
06/18/2015
Polynuclear Aromatic Hydrocarbons
CAL14088
MS14
Client:
Project:
Calibration ID:
Instrument ID:
Service Request:
ALS Group USA, Corp. dba ALS Environmental
Calibration Date:
Column: MS
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRF
Level
ID Amt RRFAnalyte Name
Benzo(a)pyrene 4.0 8.0 202.0 1001.02 0.949 0.902 0.921 1.02A B C D E
400 1000 1600200 20001.05 1.10 1.07 1.09 1.09F G H I J
Indeno(1,2,3-cd)pyrene 4.0 8.0 202.0 1001.06 0.971 0.928 0.969 1.04A B C D E
400 1000 1600200 20001.04 1.05 0.978 0.974 0.962F G H I J
Dibenz(a,h)anthracene 4.0 8.0 202.0 1001.17 1.04 0.955 0.991 0.979A B C D E
400 1000 1600200 20000.960 0.953 0.870 0.852 0.844F G H I J
Benzo(g,h,i)perylene 4.0 8.0 202.0 1001.19 1.11 1.03 1.06 1.07A B C D E
400 1000 1600200 20001.06 1.06 0.963 0.945 0.932F G H I J
Fluorene-d10 4.0 8.0 20 1001.39 1.19 1.29 1.15B C D E
400 1000 1600200 20001.14 1.09 1.03 1.03 0.996F G H I J
Fluoranthene-d10 4.0 8.0 202.0 1001.06 0.982 0.920 1.18 1.08A B C D E
400 1000 1600200 20001.11 1.07 0.995 0.974 0.961F G H I J
Terphenyl-d14 4.0 8.0 202.0 1000.857 0.802 0.748 0.918 0.815A B C D E
400 1000 1600200 20000.817 0.782 0.695 0.672 0.662F G H I J
Form 6A - Organic 3of2PagePrinted: 09/14/2015 15:39:41RR181708SuperSet Reference:
Results flagged with an asterisk (*) indicate values outside control criteria.
† SPCC Compound ‡ CCC Compound
u:\Stealth\Crystal.rpt\Form6iNew.rpt Page 40 of 64
QA/QC Results
Initial Calibration Summary
ALS Environmental - Canada
L1651410
K1509391
06/18/2015
Polynuclear Aromatic Hydrocarbons
CAL14088
MS14
Client:
Project:
Calibration ID:
Instrument ID:
Service Request:
ALS Group USA, Corp. dba ALS Environmental
Calibration Date:
Column: MS
Analyte Name
Compound
Type Fit Type Eval.
Eval.
Result Q
Control
Criteria
Average
RRF Q
Minimum
RRF
Calibration Evaluation RRF Evaluation
Naphthalene MS AverageRF % RSD 3.3 £ 20 0.968 0.70
2-Methylnaphthalene MS AverageRF % RSD 4.1 £ 20 0.722 0.40
Acenaphthylene MS AverageRF % RSD 3.5 £ 20 1.79 0.90
Acenaphthene MS AverageRF % RSD 4.5 £ 20 1.05 0.90
Dibenzofuran MS AverageRF % RSD 4.1 £ 20 1.64 0.80
Fluorene MS AverageRF % RSD 3.8 £ 20 1.27 0.90
Phenanthrene MS AverageRF % RSD 5.3 £ 20 1.01 0.70
Anthracene MS AverageRF % RSD 4.7 £ 20 0.969 0.70
Fluoranthene MS AverageRF % RSD 4.2 £ 20 1.11 0.60
Pyrene MS AverageRF % RSD 3.4 £ 20 1.11 0.60
Benz(a)anthracene MS AverageRF % RSD 8.2 £ 20 1.03 0.80
Chrysene MS AverageRF % RSD 4.2 £ 20 0.985 0.70
Benzo(b)fluoranthene MS AverageRF % RSD 5.9 £ 20 1.11 0.70
Benzo(k)fluoranthene MS AverageRF % RSD 3.8 £ 20 1.09 0.70
Benzo(a)pyrene MS AverageRF % RSD 7.1 £ 20 1.02 0.70
Indeno(1,2,3-cd)pyrene MS AverageRF % RSD 4.7 £ 20 0.998 0.50
Dibenz(a,h)anthracene MS AverageRF % RSD 10.2 £ 20 0.962 0.40
Benzo(g,h,i)perylene MS AverageRF % RSD 7.5 £ 20 1.04 0.50
Fluorene-d10 SURR AverageRF % RSD 11.4 £ 20 1.14 0.01
Fluoranthene-d10 SURR AverageRF % RSD 7.8 £ 20 1.03 0.01
Terphenyl-d14 SURR AverageRF % RSD 10.7 £ 20 0.777 0.01
Form 6A - Organic 3of3PagePrinted: 09/14/2015 15:39:41RR181708SuperSet Reference:
Results flagged with an asterisk (*) indicate values outside control criteria.
† SPCC Compound ‡ CCC Compound
u:\Stealth\Crystal.rpt\Form6iNew.rpt Page 41 of 64
QA/QC Results
Second Source Calibration Verification
Internal Standard
L1651410
Client:
Project:
Service Request:
Date Analyzed:
Analysis Method:
Calibration Type:
Calibration Date:
Calibration ID:
Units:
ALS Group USA, Corp. dba ALS Environmental
ALS Environmental - Canada K1509391
06/18/2015
06/18/2015
Polynuclear Aromatic Hydrocarbons
8270D SIM
CAL14088
ng/ml
J:\MS14\DATA\061815\0618X013.DFile ID:
Analyte Name Expected Result
Average
RF
SSV
RF %D %Drift Criteria Curve Fit
AverageRF± 30 %NA-10.9600.968400400Naphthalene
AverageRF± 30 %NA-40.6950.7223904002-Methylnaphthalene
AverageRF± 30 %NA51.871.79420400Acenaphthylene
AverageRF± 30 %NA21.071.05410400Acenaphthene
AverageRF± 30 %NA11.661.64400400Dibenzofuran
AverageRF± 30 %NA31.311.27410400Fluorene
AverageRF± 30 %NA21.031.01410400Phenanthrene
AverageRF± 30 %NA71.030.969430400Anthracene
AverageRF± 30 %NA61.171.11420400Fluoranthene
AverageRF± 30 %NA61.181.11420400Pyrene
AverageRF± 30 %NA51.081.03420400Benz(a)anthracene
AverageRF± 30 %NA41.020.985420400Chrysene
AverageRF± 30 %NA41.151.11410400Benzo(b)fluoranthene
AverageRF± 30 %NA21.121.09410400Benzo(k)fluoranthene
AverageRF± 30 %NA01.021.02400400Benzo(a)pyrene
AverageRF± 30 %NA11.010.998400400Indeno(1,2,3-cd)pyrene
AverageRF± 30 %NA10.9730.962400400Dibenz(a,h)anthracene
AverageRF± 30 %NA01.041.04400400Benzo(g,h,i)perylene
1of1PagePrinted: 9/14/2015 15:39:55 Form 6B - Organic
Results flagged with an asterisk (*) indicate values outside control criteria.
SuperSet Reference:
† SPCC Compound ‡ CCC Compound
RR181708u:\Stealth\Crystal.rpt\Form6SS.rpt Page 42 of 64
QA/QC Results
Continuing Calibration Verification Summary
L1651410
Internal Standard
Client:
Project:
Service Request:
Date Analyzed:
Calibration Type:
Analysis Method:
Calibration Date:
Calibration ID:
Units:
Analysis Lot:
ALS Group USA, Corp. dba ALS Environmental
ALS Environmental - Canada K1509391
8270D SIM
06/18/2015
CAL14088
KWG1508744
ng/ml
Polynuclear Aromatic Hydrocarbons
09/08/2015
J:\MS14\DATA\090815\0908F002.DFile ID:
Curve FitCriteria%Drift%D
CCV
RF
Average
RFResultExpectedAnalyte Name
Min
RF
± 20NA-4380400Naphthalene 0.968 AverageRF0.9280.70
± 20NA-93604002-Methylnaphthalene 0.722 AverageRF0.6580.40
± 20NA-5380400Acenaphthylene 1.79 AverageRF1.700.90
± 20NA-3390400Acenaphthene 1.05 AverageRF1.020.90
± 20NA-3390400Dibenzofuran 1.64 AverageRF1.590.80
± 20NA-1400400Fluorene 1.27 AverageRF1.260.90
± 20NA0400400Phenanthrene 1.01 AverageRF1.000.70
± 20NA0400400Anthracene 0.969 AverageRF0.9720.70
± 20NA5420400Fluoranthene 1.11 AverageRF1.160.60
± 20NA-8370400Pyrene 1.11 AverageRF1.030.60
± 20NA2410400Benz(a)anthracene 1.03 AverageRF1.050.80
± 20NA-4380400Chrysene 0.985 AverageRF0.9450.70
± 20NA15460400Benzo(b)fluoranthene 1.11 AverageRF1.280.70
± 20NA7430400Benzo(k)fluoranthene 1.09 AverageRF1.180.70
± 20NA5420400Benzo(a)pyrene 1.02 AverageRF1.070.70
± 20NA2410400Indeno(1,2,3-cd)pyrene 0.998 AverageRF1.010.50
± 20NA-2390400Dibenz(a,h)anthracene 0.962 AverageRF0.9440.40
± 20NA-2390400Benzo(g,h,i)perylene 1.04 AverageRF1.020.50
± 20NA-4380400Fluorene-d10 1.14 AverageRF1.100.01
± 20NA6430400Fluoranthene-d10 1.03 AverageRF1.100.01
± 20NA4410400Terphenyl-d14 0.777 AverageRF0.8040.01
Printed: 9/14/2015 15:39:58 1of1PageForm 7 - Organic
Results flagged with an asterisk (*) indicate values outside control criteria.
SuperSet Reference: RR181708
† SPCC Compound ‡ CCC Compound
u:\Stealth\Crystal.rpt\Form7.rpt Page 43 of 64
QA/QC Results
Analysis Run Log
L1651410
Client:
Project:
Service Request:
Analysis Method: Analysis Lot:
Sample Name Lab Code
ALS Group USA, Corp. dba ALS Environmental
ALS Environmental - Canada K1509391
8270D SIM
File ID
Date
Analysis
Started
Start
Time
Date
Analysis
Finished
Finish
Time
Polynuclear Aromatic Hydrocarbons
KWG1508744
Q
MS14Instrument ID:
KWG1508744-1 9/8/2015 08:57 9/8/2015 09:160908F001.D GC/MS Tuning - Decafluorotriphenylphosph
KWG1508744-2 9/8/2015 09:22 9/8/2015 09:410908F002.D Continuing Calibration Verification
KWG1508123-3 9/8/2015 09:48 9/8/2015 10:070908F003.D Method Blank
KWG1508123-1 9/8/2015 10:13 9/8/2015 10:320908F004.D Lab Control Sample
KWG1508123-2 9/8/2015 10:39 9/8/2015 10:580908F005.D Duplicate Lab Control Sample
ZZZZZZ 9/8/2015 11:04 9/8/2015 11:230908F006.D ZZZZZZ
ZZZZZZ 9/8/2015 11:30 9/8/2015 11:490908F007.D ZZZZZZ
K1509391-001 9/8/2015 11:56 9/8/2015 12:150908F008.D L1651410-1 15-TILBURY-B-1
K1509391-002 9/8/2015 12:22 9/8/2015 12:410908F009.D L1651410-2 15-TILBURY-B-1D
K1509391-003 9/8/2015 12:49 9/8/2015 13:080908F010.D L1651410-3 15-TILBURY-B-2
K1509391-004 9/8/2015 13:15 9/8/2015 13:340908F011.D L1651410-4 15-TILBURY-B-3
K1509391-005 9/8/2015 13:42 9/8/2015 14:010908F012.D L1651410-5 15-TILBURY-B-4
K1509391-006 9/8/2015 14:09 9/8/2015 14:280908F013.D L1651410-6 15-TILBURY-B-5
K1509391-007 9/8/2015 14:36 9/8/2015 14:550908F014.D L1651410-7 15-TILBURY-B-6
K1509391-008 9/8/2015 15:03 9/8/2015 15:220908F015.D L1651410-8 15-TILBURY-B-7
K1509391-009 9/8/2015 15:30 9/8/2015 15:490908F016.D L1651410-9 15-TILBURY-B-8
K1509391-010 9/8/2015 15:57 9/8/2015 16:160908F017.D L1651410-10 15-TILBURY-B-8D
K1509391-011 9/8/2015 16:24 9/8/2015 16:430908F018.D L1651410-11 15-TILBURY-B-9
K1509391-012 9/8/2015 16:51 9/8/2015 17:100908F019.D L1651410-12 15-TILBURY-B-10
K1509391-013 9/8/2015 17:18 9/8/2015 17:370908F020.D L1651410-13 15-TILBURY-B-11
K1509391-014 9/8/2015 17:45 9/8/2015 18:040908F021.D L1651410-14 15-TILBURY-B-12
K1509391-015 9/8/2015 18:12 9/8/2015 18:310908F022.D L1651410-15 15-TILBURY-B-13
K1509391-016 9/8/2015 18:39 9/8/2015 18:580908F023.D L1651410-16 15-TILBURY-B-14
K1509391-017 9/8/2015 19:06 9/8/2015 19:250908F024.D L1651410-17 15-TILBURY-B-15
ZZZZZZ 9/8/2015 19:32 9/8/2015 19:510908F025.D ZZZZZZ
ZZZZZZ 9/8/2015 19:59 9/8/2015 20:180908F026.D ZZZZZZ
ZZZZZZ 9/8/2015 20:26 9/8/2015 20:450908F027.D ZZZZZZ
ZZZZZZ 9/8/2015 20:53 9/8/2015 21:120908F028.D ZZZZZZ
Form 8 - Organic 1of1PagePrinted: 09/14/2015 15:40:02
Results flagged with an asterisk (*) indicate the holding time was exceeded for the analysis
RR181708SuperSet Reference:u:\Stealth\Crystal.rpt\Form8.rpt Page 44 of 64
QA/QC Results
Extraction Prep Log
Polynuclear Aromatic Hydrocarbons
ALS Environmental - Canada
L1651410
K1509391
Final
Volume
KWG1508123
Plant tissue
Low
Client:
Project:
Sample Matrix:
Service Request:
Extraction Method: Extraction Lot:
Level:
Sample Name Lab Code
Date
Received
Sample
Amount % Solids Note
ALS Group USA, Corp. dba ALS Environmental
Date Extracted: 09/02/2015
EPA 3541
Analysis Method: 8270D SIM
Date
Collected
K1509391-001 10.052g 1ml NA08/26/15L1651410-1 15-TILBURY-B-1 07/31/15
K1509391-002 10.017g 1ml NA08/26/15L1651410-2 15-TILBURY-B-1D 07/31/15
K1509391-003 10.000g 1ml NA08/26/15L1651410-3 15-TILBURY-B-2 07/31/15
K1509391-004 10.438g 1ml NA08/26/15L1651410-4 15-TILBURY-B-3 07/31/15
K1509391-005 10.398g 1ml NA08/26/15L1651410-5 15-TILBURY-B-4 07/31/15
K1509391-006 10.091g 1ml NA08/26/15L1651410-6 15-TILBURY-B-5 07/31/15
K1509391-007 10.139g 1ml NA08/26/15L1651410-7 15-TILBURY-B-6 07/31/15
K1509391-008 10.099g 1ml NA08/26/15L1651410-8 15-TILBURY-B-7 07/31/15
K1509391-009 10.104g 1ml NA08/26/15L1651410-9 15-TILBURY-B-8 07/31/15
K1509391-010 10.253g 1ml NA08/26/15L1651410-10 15-TILBURY-B-8D 07/31/15
K1509391-011 10.068g 1ml NA08/26/15L1651410-11 15-TILBURY-B-9 07/31/15
K1509391-012 10.235g 1ml NA08/26/15L1651410-12 15-TILBURY-B-10 07/31/15
K1509391-013 9.856g 1ml NA08/26/15L1651410-13 15-TILBURY-B-11 07/31/15
K1509391-014 10.404g 1ml NA08/26/15L1651410-14 15-TILBURY-B-12 07/31/15
K1509391-015 10.116g 1ml NA08/26/15L1651410-15 15-TILBURY-B-13 07/31/15
K1509391-016 10.018g 1ml NA08/26/15L1651410-16 15-TILBURY-B-14 07/31/15
K1509391-017 10.311g 1ml NA08/26/15L1651410-17 15-TILBURY-B-15 07/31/15
KWG1508123-3 10.438g 1ml NANAMethod Blank NA
KWG1508123-1 10.000g 1ml NANALab Control Sample NA
KWG1508123-2 10.000g 1ml NANADuplicate Lab Control Sample NA
Form 9 - Organic 1of1PagePrinted: 09/14/2015 15:40:06
Results flagged with an asterisk (*) indicate the holding time was exceeded for the analysis
SuperSet Reference: RR181708u:\Stealth\Crystal.rpt\Form9L.rpt Page 45 of 64
Polynuclear Aromatic Hydrocarbons
ALS Environmental—Kelso Laboratory 1317 South 13th Avenue, Kelso, WA 98626 Phone (360)577-7222 Fax (360)636-1068 www.alsglobal.com
RIGHT SOLUTIONS | RIGHT PARTNER
Page 46 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-001
ug/Kg
Dry
L1651410-1 15-TILBURY-B-1
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.6 09/02/151 KWG150812309/08/15UNDNaphthalene
7.6 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.8 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.8 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.8 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.8 09/02/151 KWG150812309/08/15UNDFluorene
3.8 09/02/151 KWG150812309/08/155.9Phenanthrene
3.8 09/02/151 KWG150812309/08/15UNDAnthracene
3.8 09/02/151 KWG150812309/08/15UNDFluoranthene
3.8 09/02/151 KWG150812309/08/15UNDPyrene
3.8 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.8 09/02/151 KWG150812309/08/15UNDChrysene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.8 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
83 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.8 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.8 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1563
41-100 AcceptableFluoranthene-d10 09/08/1575
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:26:5009/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 47 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-002
ug/Kg
Dry
L1651410-2 15-TILBURY-B-1D
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.0 09/02/151 KWG150812309/08/15UNDNaphthalene
7.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.5 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.5 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.5 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.5 09/02/151 KWG150812309/08/15UNDFluorene
3.5 09/02/151 KWG150812309/08/155.6Phenanthrene
3.5 09/02/151 KWG150812309/08/15UNDAnthracene
3.5 09/02/151 KWG150812309/08/15UNDFluoranthene
3.5 09/02/151 KWG150812309/08/15UNDPyrene
3.5 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.5 09/02/151 KWG150812309/08/15UNDChrysene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.5 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
120 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.5 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.5 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1563
41-100 AcceptableFluoranthene-d10 09/08/1574
39-111 AcceptableTerphenyl-d14 09/08/1561
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:26:5409/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 48 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-003
ug/Kg
Dry
L1651410-3 15-TILBURY-B-2
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.5 09/02/151 KWG150812309/08/15UNDNaphthalene
6.5 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.3 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.3 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.3 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.3 09/02/151 KWG150812309/08/15UNDFluorene
3.3 09/02/151 KWG150812309/08/155.8Phenanthrene
3.3 09/02/151 KWG150812309/08/15UNDAnthracene
3.3 09/02/151 KWG150812309/08/15UNDFluoranthene
3.3 09/02/151 KWG150812309/08/15UNDPyrene
3.3 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.3 09/02/151 KWG150812309/08/15UNDChrysene
3.3 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.3 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
99 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.3 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.3 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.3 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1579
39-111 AcceptableTerphenyl-d14 09/08/1563
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:26:5809/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 49 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-004
ug/Kg
Dry
L1651410-4 15-TILBURY-B-3
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.7 09/02/151 KWG150812309/08/15UNDNaphthalene
7.7 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.9 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.9 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.9 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.9 09/02/151 KWG150812309/08/15UNDFluorene
3.9 09/02/151 KWG150812309/08/159.6Phenanthrene
3.9 09/02/151 KWG150812309/08/15UNDAnthracene
3.9 09/02/151 KWG150812309/08/15UNDFluoranthene
3.9 09/02/151 KWG150812309/08/15UNDPyrene
3.9 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.9 09/02/151 KWG150812309/08/15UNDChrysene
3.9 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.9 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
110 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.9 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.9 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.9 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1567
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1559
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:0209/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 50 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-005
ug/Kg
Dry
L1651410-5 15-TILBURY-B-4
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
5.7 09/02/151 KWG150812309/08/15UNDNaphthalene
5.7 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
2.9 09/02/151 KWG150812309/08/15UNDAcenaphthylene
2.9 09/02/151 KWG150812309/08/15UNDAcenaphthene
2.9 09/02/151 KWG150812309/08/15UNDDibenzofuran
2.9 09/02/151 KWG150812309/08/15UNDFluorene
2.9 09/02/151 KWG150812309/08/1512Phenanthrene
2.9 09/02/151 KWG150812309/08/15UNDAnthracene
2.9 09/02/151 KWG150812309/08/154.6Fluoranthene
2.9 09/02/151 KWG150812309/08/153.0Pyrene
2.9 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
2.9 09/02/151 KWG150812309/08/15UNDChrysene
2.9 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
2.9 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
120 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
2.9 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
2.9 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
2.9 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1571
41-100 AcceptableFluoranthene-d10 09/08/1582
39-111 AcceptableTerphenyl-d14 09/08/1565
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:0609/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 51 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-006
ug/Kg
Dry
L1651410-6 15-TILBURY-B-5
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.2 09/02/151 KWG150812309/08/15UNDNaphthalene
6.2 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.1 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.1 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.1 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.1 09/02/151 KWG150812309/08/15UNDFluorene
3.1 09/02/151 KWG150812309/08/1513Phenanthrene
3.1 09/02/151 KWG150812309/08/15UNDAnthracene
3.1 09/02/151 KWG150812309/08/155.5Fluoranthene
3.1 09/02/151 KWG150812309/08/154.6Pyrene
3.1 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.1 09/02/151 KWG150812309/08/15UNDChrysene
3.1 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.1 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
88 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.1 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.1 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.1 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1560
41-100 AcceptableFluoranthene-d10 09/08/1571
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:1009/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 52 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-007
ug/Kg
Dry
L1651410-7 15-TILBURY-B-6
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 09/02/151 KWG150812309/08/15UNDNaphthalene
6.9 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.5 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.5 09/02/151 KWG150812309/08/15X3.9Acenaphthene
3.5 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.5 09/02/151 KWG150812309/08/15UNDFluorene
3.5 09/02/151 KWG150812309/08/1512Phenanthrene
3.5 09/02/151 KWG150812309/08/15UNDAnthracene
3.5 09/02/151 KWG150812309/08/154.3Fluoranthene
3.5 09/02/151 KWG150812309/08/15UNDPyrene
3.5 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.5 09/02/151 KWG150812309/08/15UNDChrysene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.5 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
120 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.5 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.5 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1570
41-100 AcceptableFluoranthene-d10 09/08/1580
39-111 AcceptableTerphenyl-d14 09/08/1564
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:1409/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 53 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-008
ug/Kg
Dry
L1651410-8 15-TILBURY-B-7
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
5.8 09/02/151 KWG150812309/08/15UNDNaphthalene
5.8 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
2.9 09/02/151 KWG150812309/08/15UNDAcenaphthylene
2.9 09/02/151 KWG150812309/08/15X3.7Acenaphthene
2.9 09/02/151 KWG150812309/08/15UNDDibenzofuran
2.9 09/02/151 KWG150812309/08/15UNDFluorene
2.9 09/02/151 KWG150812309/08/157.8Phenanthrene
2.9 09/02/151 KWG150812309/08/15UNDAnthracene
2.9 09/02/151 KWG150812309/08/153.3Fluoranthene
2.9 09/02/151 KWG150812309/08/15UNDPyrene
2.9 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
2.9 09/02/151 KWG150812309/08/15UNDChrysene
2.9 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
2.9 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
110 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
2.9 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
2.9 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
2.9 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1579
39-111 AcceptableTerphenyl-d14 09/08/1564
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:1809/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 54 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-009
ug/Kg
Dry
L1651410-9 15-TILBURY-B-8
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
8.0 09/02/151 KWG150812309/08/15UNDNaphthalene
8.0 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
4.0 09/02/151 KWG150812309/08/15UNDAcenaphthylene
4.0 09/02/151 KWG150812309/08/15UNDAcenaphthene
4.0 09/02/151 KWG150812309/08/15UNDDibenzofuran
4.0 09/02/151 KWG150812309/08/15UNDFluorene
4.0 09/02/151 KWG150812309/08/1510Phenanthrene
4.0 09/02/151 KWG150812309/08/15UNDAnthracene
4.0 09/02/151 KWG150812309/08/154.6Fluoranthene
4.0 09/02/151 KWG150812309/08/15UNDPyrene
4.0 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
4.0 09/02/151 KWG150812309/08/15UNDChrysene
4.0 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
4.0 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
96 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
4.0 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
4.0 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
4.0 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1570
41-100 AcceptableFluoranthene-d10 09/08/1581
39-111 AcceptableTerphenyl-d14 09/08/1567
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:2209/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 55 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-010
ug/Kg
Dry
L1651410-10 15-TILBURY-B-8D
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.4 09/02/151 KWG150812309/08/15UNDNaphthalene
6.4 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.2 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.2 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.2 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.2 09/02/151 KWG150812309/08/15UNDFluorene
3.2 09/02/151 KWG150812309/08/158.7Phenanthrene
3.2 09/02/151 KWG150812309/08/15UNDAnthracene
3.2 09/02/151 KWG150812309/08/153.6Fluoranthene
3.2 09/02/151 KWG150812309/08/15UNDPyrene
3.2 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.2 09/02/151 KWG150812309/08/15UNDChrysene
3.2 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.2 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
130 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.2 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.2 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.2 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1581
39-111 AcceptableTerphenyl-d14 09/08/1566
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:2609/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 56 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-011
ug/Kg
Dry
L1651410-11 15-TILBURY-B-9
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.4 09/02/151 KWG150812309/08/15UNDNaphthalene
7.4 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.7 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.7 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.7 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.7 09/02/151 KWG150812309/08/15UNDFluorene
3.7 09/02/151 KWG150812309/08/155.5Phenanthrene
3.7 09/02/151 KWG150812309/08/15UNDAnthracene
3.7 09/02/151 KWG150812309/08/15UNDFluoranthene
3.7 09/02/151 KWG150812309/08/15UNDPyrene
3.7 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.7 09/02/151 KWG150812309/08/15UNDChrysene
3.7 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.7 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
96 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.7 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.7 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.7 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1583
39-111 AcceptableTerphenyl-d14 09/08/1559
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:3009/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 57 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-012
ug/Kg
Dry
L1651410-12 15-TILBURY-B-10
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.2 09/02/151 KWG150812309/08/15UNDNaphthalene
6.2 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.1 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.1 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.1 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.1 09/02/151 KWG150812309/08/15UNDFluorene
3.1 09/02/151 KWG150812309/08/159.4Phenanthrene
3.1 09/02/151 KWG150812309/08/15UNDAnthracene
3.1 09/02/151 KWG150812309/08/153.7Fluoranthene
3.1 09/02/151 KWG150812309/08/15UNDPyrene
3.1 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.1 09/02/151 KWG150812309/08/15UNDChrysene
3.1 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.1 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
94 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.1 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.1 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.1 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1561
41-100 AcceptableFluoranthene-d10 09/08/1574
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:3409/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 58 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-013
ug/Kg
Dry
L1651410-13 15-TILBURY-B-11
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
4.9 09/02/151 KWG150812309/08/15UNDNaphthalene
4.9 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
2.5 09/02/151 KWG150812309/08/15UNDAcenaphthylene
2.5 09/02/151 KWG150812309/08/15UNDAcenaphthene
2.5 09/02/151 KWG150812309/08/15UNDDibenzofuran
2.5 09/02/151 KWG150812309/08/15UNDFluorene
2.5 09/02/151 KWG150812309/08/1511Phenanthrene
2.5 09/02/151 KWG150812309/08/15UNDAnthracene
2.5 09/02/151 KWG150812309/08/154.6Fluoranthene
2.5 09/02/151 KWG150812309/08/153.1Pyrene
2.5 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
2.5 09/02/151 KWG150812309/08/15UNDChrysene
2.5 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
2.5 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
98 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
2.5 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
2.5 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
2.5 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1561
41-100 AcceptableFluoranthene-d10 09/08/1573
39-111 AcceptableTerphenyl-d14 09/08/1552
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:3809/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 59 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-014
ug/Kg
Dry
L1651410-14 15-TILBURY-B-12
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.6 09/02/151 KWG150812309/08/15UNDNaphthalene
7.6 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.8 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.8 09/02/151 KWG150812309/08/155.5Acenaphthene
3.8 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.8 09/02/151 KWG150812309/08/156.7Fluorene
3.8 09/02/151 KWG150812309/08/1531Phenanthrene
3.8 09/02/151 KWG150812309/08/15UNDAnthracene
3.8 09/02/151 KWG150812309/08/1513Fluoranthene
3.8 09/02/151 KWG150812309/08/155.6Pyrene
3.8 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.8 09/02/151 KWG150812309/08/15UNDChrysene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.8 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
160 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.8 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.8 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1569
41-100 AcceptableFluoranthene-d10 09/08/1580
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:4209/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 60 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-015
ug/Kg
Dry
L1651410-15 15-TILBURY-B-13
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
6.9 09/02/151 KWG150812309/08/15UNDNaphthalene
6.9 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.5 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.5 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.5 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.5 09/02/151 KWG150812309/08/15UNDFluorene
3.5 09/02/151 KWG150812309/08/158.5Phenanthrene
3.5 09/02/151 KWG150812309/08/15UNDAnthracene
3.5 09/02/151 KWG150812309/08/15UNDFluoranthene
3.5 09/02/151 KWG150812309/08/15UNDPyrene
3.5 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.5 09/02/151 KWG150812309/08/15UNDChrysene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.5 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
110 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.5 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.5 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.5 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1566
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:4609/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 61 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-016
ug/Kg
Dry
L1651410-16 15-TILBURY-B-14
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.3 09/02/151 KWG150812309/08/15UNDNaphthalene
7.3 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.7 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.7 09/02/151 KWG150812309/08/15UNDAcenaphthene
3.7 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.7 09/02/151 KWG150812309/08/154.6Fluorene
3.7 09/02/151 KWG150812309/08/1526Phenanthrene
3.7 09/02/151 KWG150812309/08/15UNDAnthracene
3.7 09/02/151 KWG150812309/08/156.9Fluoranthene
3.7 09/02/151 KWG150812309/08/15UNDPyrene
3.7 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.7 09/02/151 KWG150812309/08/15UNDChrysene
3.7 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.7 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
130 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.7 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.7 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.7 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1577
39-111 AcceptableTerphenyl-d14 09/08/1554
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:5009/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 62 of 64
Analytical Results
ALS Environmental - Canada K1509391
K1509391-017
ug/Kg
Dry
L1651410-17 15-TILBURY-B-15
07/31/2015
08/26/2015
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
7.5 09/02/151 KWG150812309/08/15UNDNaphthalene
7.5 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
3.8 09/02/151 KWG150812309/08/15UNDAcenaphthylene
3.8 09/02/151 KWG150812309/08/15X4.4Acenaphthene
3.8 09/02/151 KWG150812309/08/15UNDDibenzofuran
3.8 09/02/151 KWG150812309/08/154.2Fluorene
3.8 09/02/151 KWG150812309/08/1529Phenanthrene
3.8 09/02/151 KWG150812309/08/15UNDAnthracene
3.8 09/02/151 KWG150812309/08/1514Fluoranthene
3.8 09/02/151 KWG150812309/08/155.9Pyrene
3.8 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
3.8 09/02/151 KWG150812309/08/15UNDChrysene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
3.8 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
130 09/02/151 KWG150812309/08/15UiNDBenzo(a)pyrene
3.8 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
3.8 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
3.8 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1576
39-111 AcceptableTerphenyl-d14 09/08/1553
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:5409/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 63 of 64
Analytical Results
ALS Environmental - Canada K1509391
KWG1508123-3
ug/Kg
Dry
Method Blank
NA
NA
L1651410
Plant tissue
Client:
Project:
Sample Matrix:
Service Request:
Date Collected:
Date Received:
ALS Group USA, Corp. dba ALS Environmental
Units:
Basis:
Sample Name:
Polynuclear Aromatic Hydrocarbons
Lab Code:
Level: LowExtraction Method:
Analysis Method:
EPA 3541
8270D SIM
NoteMRLQResultAnalyte Name
Extraction
Lot
Date
Analyzed
Date
Extracted
Dilution
Factor
0.96 09/02/151 KWG150812309/08/15UNDNaphthalene
0.96 09/02/151 KWG150812309/08/15UND2-Methylnaphthalene
0.48 09/02/151 KWG150812309/08/15UNDAcenaphthylene
0.48 09/02/151 KWG150812309/08/15UNDAcenaphthene
0.48 09/02/151 KWG150812309/08/15UNDDibenzofuran
0.48 09/02/151 KWG150812309/08/15UNDFluorene
0.48 09/02/151 KWG150812309/08/15UNDPhenanthrene
0.48 09/02/151 KWG150812309/08/15UNDAnthracene
0.48 09/02/151 KWG150812309/08/15UNDFluoranthene
0.48 09/02/151 KWG150812309/08/15UNDPyrene
0.48 09/02/151 KWG150812309/08/15UNDBenz(a)anthracene
0.48 09/02/151 KWG150812309/08/15UNDChrysene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(b)fluoranthene†
0.48 09/02/151 KWG150812309/08/15UNDBenzo(k)fluoranthene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(a)pyrene
0.48 09/02/151 KWG150812309/08/15UNDIndeno(1,2,3-cd)pyrene
0.48 09/02/151 KWG150812309/08/15UNDDibenz(a,h)anthracene
0.48 09/02/151 KWG150812309/08/15UNDBenzo(g,h,i)perylene
Surrogate Name %Rec
Control
Limits NoteDate
Analyzed
39-96 AcceptableFluorene-d10 09/08/1564
41-100 AcceptableFluoranthene-d10 09/08/1573
39-111 AcceptableTerphenyl-d14 09/08/1556
† Analyte Comments
This analyte cannot be separated from Benzo(j)fluoranthene.Benzo(b)fluoranthene
Comments:
1of1Page10:27:5809/15/2015Printed: Form 1A - Organic
Merged SuperSet Reference: RR181709u:\Stealth\Crystal.rpt\Form1mNew.rpt Page 64 of 64