Antonio H. Castro Neto - FapespVisit: Antonio H. Castro Neto Centre for Advanced 2D materials and...
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Visit: www.graphenecenter.org
Antonio H. Castro Neto
Centre for Advanced 2D materials and Graphene Research Centre
Department of PhysicsDept. of Electrical and Computer Engineering
Dept. of Materials Science Engineering
National University of Singapore
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Universidade Presbiteriana Mackenzie (UPM) - NUS
January 20th, 2012
MackGraphe - Centre for Graphene and Advanced Nano-Materials
UPM is investing ~ US$ 20 million. FAPESP is investing US$ 5 million via the SPEC program.
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Two-dimensional crystals
K.S. Novoselov, D. Jiang, T. Booth, V.V. Khotkevich, S. V. Morozov, & A.K. Geim. Two Dimensional Atomic Crystals. PNAS 102, 10451-10453 (2005).
Not 2DEG: non-trivial orbital properties. Transparent: non-trivial optical properties. Soft: non-trivial structural properties. Strain: tailoring of electronic properties. Chemical functionalization: tailoring
chemical, structural and electronic properties.
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Manganites
In 2D: Doping = Field Effect
Non-trivial orbital properties
In 2D: Coulomb interactions are long range
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Linjun Li, Eoin C.T. O'Farrell, K. P. Loh, B. Oezyilmaz, A.H. Castro Neto
Controlling Many-Body States by Electric Field Effect in 2D Materials:
the case of TiSe2
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Physical Interpretation
Cooper Pairing
McMillan, W. L. Phys. Rev. B 12, 1197-1199 (1975)
The CDW discommensurations drive local pairing:
Pair density wave
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P4
Phosphorene
Pressure5 GPa 10 GPa
Orthorhombic Rhombohedral Simple Cubic
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8
Black Phosphorus: phosphorene Phys. Rev. Lett. 112, 176801
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50 µm
Electric field effect in few-layer black phosphorus Steven P. Koenig, Rostislav A. Doganov, Henrick Schmidt, A. H. Castro Neto, Barbaros Oezilmaz
Appl. Phys. Lett. 104, 103106 (2014)
~10 nm
It rusts !
µ=600 cm2/Vs
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Phys. Rev. Lett. 114, 046801 (2015)
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Phys. Rev. B 91, 085407 (2015)
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A New Route to Graphene Processing by Selective Laser AblationS. Dhar, A. Roy Barman1, G.X. Ni, X. Wang, X. F. Xu, Y. Zheng, S. Tripathy, Ariando, A. Rusydi1, K. P. Loh, M. Rubhausen, A. H. Castro Neto, B. Oezyilmaz and T. Venkatesan, AIP Advances 1, 022109 (2011).
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Colossal nonlinear optical response of PhosphoreneM. J. L. F. Rodrigues, Christiano J. S. de Matos, Hsin-Yu Wu, Ho Yi Wei, A. Carvalho, F.Hipolito, A. H. Castro Neto & J. Viana-Gomes
100 fs duration laser pulses at a 1560 nm wavelength (80MHz repetition rate)
Supported by FAPESP and NRF
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Artificial 3D Heterostructures
Graphene
WS2
Graphane
Fluorographene
MoS2
Boron Nitride
Courtesy: K. Novoselov
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Paving the way. Example 1: electronics
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Paving the way. Example 2: photovoltaics
Published in Science
BN
Graphene
WS2
Graphene
Au
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Conclusions
A new 2D material science and technology is emerging from the “graphene experience”. New 2D materials, such as TMDCs and phosphorene, have properties which are rather different the ones found in 3D materials. Artificial 3D heterostructures of 2D materials provide new opportunities which still remain unexplored. Computational science will play an important role in this exploration. Terra plana (2D) is a fertile terrain of open fields for growth and exploration !
Thank you !