Ans Mole
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Transcript of Ans Mole
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7/29/2019 Ans Mole
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Answer for Mole concept and Volumetric analysis
1. Number of moles of magnesium present= 0.450/24.31=0.0185Number of moles of nitrogen present = (0.623-0.450)/ 14.01 = 0.0123
Ratio of No of moles = Mg : N = 0.0185 : 0.0123
= 1.5/1 = 3:2
The empirical formula is Mg3N2
2. a) Mass of C in vitamin C = 0.2998 x 12/44.01 = 0.0818gMass of H in vitamin C = 0.0819 x 2/18.02 = 0.0092g
Mass of O in vitamin C = 0.2-0.0092-0.0818 = 0.109g
Relative mole ratio of atoms:
C : H : O = 1 : 1.33 : 1 = 3 : 4 : 3
Empirical formula = C3H4O3
b) molecular mass of empirical formula = 88
88n = 180
n = 2.045
n is an integer, n=2
Thus, molecular formula of vitamin C is C6H8O6
3. 2LiOH + CO2 Li2CO3 + H2ONo of moles of LiOH in 1.00kg = 1000 / 23.95 = 41.81mole CO2 : 2mole LiOH
No of moles of CO2 = 41.8 /2 = 20.9 mol
Mass of CO2 absorbed = 20.9 x 44 = 920g
4. (a) 2Mg + O2 2MgONo of moles of Mg = 2.43 / 24.3 = 0.1 mol
Since oxygen is in excess, all Mg will be converted to MgO
Mass of MgO formed = 0.10X 40.3 = 4.03g
(b) No of mole of oxygen = 1.28 / 32 = 0.04 mol
2 mole of Mg : 1 mole of O2
0.04 mole of O2 requires 0.08 mole Mg . Since there are 0.1 mole of Mg,
thus Mg is in excess (Oxygen is limiting).
All O2 will be reacted.
No of mole of MgO formed = 2 x 0.04 = 0.08
Mass of MgO formed = 0.08 x 40.3 = 3.22g
5. a) (CH3)3COH + HCl (CH3)3CCl + H2O
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7/29/2019 Ans Mole
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Answer for Mole concept and Volumetric analysis
b) No of moles of (CH3)3COH = 25/74 = 0.337
No of moles of HcL = 36/ 36.5 = 0.986
HCl is in excess , thus (CH3)3COH is limiting reagent.
c) (Experimental )No of moles of (CH3)3CCl = 28/92.5 = 0.303
% yield = Experimental / theoretical = 0.0303/ 0.337 X 100% = 89.9%
6. (a )2X(s ) + 6HCl(aq) 2XCl3(aq) + 3H2(g)X2O3(s) + 6HCl(aq) 2XCl3(aq) + 3H2O (l)
(b) In reaction I
No of mole of X= 0.5724/ 3 = 0.1908mol
Relative atomic mass = 16.5/ 0.1908 = 86.5
In reaction II
No of mole of X2O3 = 0.5724/6 = 0.954molLet the relative atomic mass of X be A , 16.5/ (2A+16x3) = 0.954
Relative atomic mass of X = 62.5
Thus the smallest relative atomic mass of X is 62.5 , the greatest relative
atomic mass of X is 86.5
(c) The only trivalent metal with relative atomic mass in the range of 62.5 to
86.5 is gallium (Ga).
7.
(a) The solution turns brown ( due to complex formation)I2 + I
- I3
-(aq)
(b) I2 is volatile, no accurate weighing of the mass of iodine solid.
(c) 78.5 cm3
(d) Starch indicator will form complex with I2 reversibly and turns blue black.
The end point can be observed easily.
(e) Near the end point. Starch indicator will combine irreversibly with iodine
when the concentration of iodine is high at start.
8 (a) Volume of CO2 produced = 100 cm3
Volume of unreacted O2 = 100 cm3
Volume of N2 = 250-100-100= 500 cm3
Using Avogadros law,
1/50 = x/100 = (y/2)/100
x = 2, y= 2
Formula is C2H2
(b) C2H2(g)+ 2O2 (g) 2CO2 (g) + N2 (g)
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7/29/2019 Ans Mole
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Answer for Mole concept and Volumetric analysis
9. (a) Mg + H2SO4MgSO4 + H2(b) Phenolphthalein changes from colourless to pink
(accept other indicators, showing colour change from acidic to basic
medium)
(ci) no of moles of NaOH used to neutralize the acid
= 21.50/1000 x 0.203 = 0.00436 g
(cii) no of moles of H+(aq) reacted with Mg
= (0.5x25) / 1000 X2 0.00436 = 0.02064
No of moles of H2SO4 used = 0.2064/2 = 0.01032
(ciii) Mass of Mg reacted with the acid = 24.3x 0.01032 = 0.2508g
Percentage purity of Mg= 0.2508/0.27 X 100% = 92.89%
(di) The Mg ribbon may be coated with an oxide layer dur to exposure to air.
(dii) Clean the surface of the magnesium ribbon with sand paper beforeWeighing.
10.For the pH 2 HCl (aq), [H+ (aq)] = 0.01MNo of mole of HCl required for the preparation = 0.01X1.0 = 0.01
Mass of constant boiling HCl (aq) = (0.01X 36.5 )/ 0.202
= 1.80g
11.Mass of HNO3 in 1dm
3
= 1420 x 0.68- 965.6Concentration of the acid = 965.6/ 63 = 15.3M
12.(a) Mole ratio of C : H : O = 5.88: 5.93 :1.47= 4 : 4 : 1
Empirical formula of A = C4H4O
(b) Suppose the formula of this acid is HA
HA + NaOH NaA + H2O
1 mole 1 mole
No of moles of HA= no of moles of NaOH
0.3200/ M = 0.1 x 23.5/1000
M = 136
Thus the molecular mass of A is 136 g
68n = 136
n = 2
Molecular formula of A is C8H8O2
13.1014.C4H10O