Annual Meeting, June 15-16 2015, Istanbul, Turkey EMODnet Chemistry Partner contribution: HCMR/HNODC...

Annual Meeting, June 15-16 2015, Istanbul, Turkey

EMODnet Chemistry

Partner contribution: HCMR/HNODC

WP1: Data collection and metadata

compilation in sea regions: current status


General overview of the HMCR’s contribution:

Current status (April 2015)

Seawater Sediment Biota

Number of CDIs at beginning: 3268 62

Number of CDIs at year 1: + 1324

Number of CDIs at year 2: + 900

Total number of CDIs (Mediter. & Black Sea)

5492 62

Note 1: For Seawater the number of CDIs is for bottles not CTDs or Buoys (oxygen)


Total number of stations(=CDIs) per parameter group per matrix:

Group Seawater Sediment Biota

Fertilizers 4339

Silicates 4332

Organic matter 1166

Chlorophyll 702

Partial pressure dissolved gases

4672

Acidity 193

Pesticides and biocides

Antifoulants

Pharmaceuticals

Heavy metals 783 62

Hydrocarbons

Radionuclides

Plastics

Current status

Current status vs Inventory

Seawater* Sediment Biota

Group Med.Sea Currentstatus

Med. Sea Inventory

Black Sea

Current status

Black sea Inventory

Med.Sea Currentstatus

Med. Sea Inventory

Black Sea

Current status

Black sea

Inventory

Med.Sea

Current

Med. Sea

Inventory

Fertilizers 4335 3400 4 4

Silicates 4328 3400 4 4

Organic matter 1148 960 18

Chlorophyll 684 1080 18 21


4672 3800 30

Acidity 193 172

Antifoulants

Pharmaceuticals

Heavy metals 783 130 39 62 400 39 4

Hydrocarbons 89125 58


Radionuclides 80 4 7 1

Plastics


Data quality control performed by the data center:

Type of QC: Seawater Sediment Biota Notes:

Position check Y Y Y

Date/time check Y Y Y

Missing value Y Y Y

Range check Y Y

Spike Y

Pre-existing statistics

Y* Y Y *for NTRA, PHOS,SLCA,DOXY

Visualization and manual checks

Y Y Y

Negative Values Check:

Y Y Y

Manual checks of zeros (but not part of the local software)


Difficulties encountered:

•Some datasets cannot be processed because the corresponding metadata are missing

•Missing P01 and P09 labels from the elements/compounds result in delay of data processing. Different methods of analysis along the decades demand different P01 and P09 labels increasing the time for processing

•Not uniform units among datasets for the same chemical elements/compounds increase the time of processing

•In some cases, there is a mismatch between the reported datasets and the actual scientist holdings (a time-consuming procedure to find these data)


Spatial distribution of HNODC’s CDIs uploaded during the 2nd yearSpatial distribution of HNODC’s CDIs uploaded during the 2nd year

2nd Year

Metals in Seawater

15 stations 783 CDIs from 1985 to 2009

Fertilizers, Silicates, Organic matter and Chlorophyll in Seawater

Spatial distribution of CDIs that will be uploaded by HNODC the last year

Spatial distribution of CDIs that will be uploaded by HNODC the last year


Planning for the last year


Total number of stations per parameter group per matrixGroup Seawater Sediment Biota

Fertilizers

Silicates

Organic matter +54 +37 (submitted on

May 2015)

Chlorophyll


Acidity

Antifoulants

Pharmaceuticals

Heavy metals +51 +69(submitted on

May 2015)

+34 ts

Hydrocarbons

+78 +17 tsPesticides and biocides

Radionuclides

Plastics

Planning for the last year

P01 and P09 new labels(some background info)

Group Seawater Sediment Biota

Fertilizers

Silicates

Organic matter 2 new labels in P012 new labels in P09

Chlorophyll


Acidity


Antifoulants

Pharmaceuticals

Heavy metals 4 new labels in P09 40 new labels in P0173 new labels in P09

77 new labels in P01

Hydrocarbons 8 new labels in P01 130 new labels in P01

Radionuclides

Plastics

TOTAL 4 in P09 50 in P0175 in P09

207 in P01

Some examples of new P01 parameters

New P01 parameters for Hydrocarbons in SedimentCODE GROUP

CODEUNITCODE

DUMMYVAL

MINPERMISS

VAL

MAXPERMISS

VAL

BEFOREDP

AFTERDP

SHORTTITLE

FULLTITLE

DEFINITION

HCMRAG06 SCAH KGUM -9 0 9 1 3 methyldibenzothiophenes_sed

not specified Quantity or mass of the sum of all isomers of the specified analyte per unit weight of dried unsieved sediment.

HCMRAG01 SCOC UUKG -9 0 999 3 1 aliphTPH_sed

not specified The combined mass of all aliphatic (no benzene rings) compounds that may be extracted per unit weight of dried unsieved sediment using an organic solvent. These are presumed to be sourced from crude oil.

New P01 parameters for Metals in Sediment

CODE GROUPCODE

UNITCODE

DUMMYVAL

MIN PERMISS

VAL

MAXPERMISS

VAL

BEFOREDP

AFTERDP

SIGFIG

SHORTTITLE

FULLTITLE

DEFINITION

HCMR0008 RMIN UMKG -9 0 999 3 2 - Lu_sed<63um

not specified

The quantity or mass of the specified analyte contained in a dried subsample of sediment that passes through a 63 micron sieve.

HCMR0028 RMIN UMKG -9 0 999 3 2 - Gd_sed notspecified

The quantity or mass of the specified analyte contained in a dried sample of sediment.

Examples of P01 mapping for contaminants in BiotaSubstance

NameName

QualifierSynonym Relationship Biological Entity P01 Code P01 Label

cadmium not specified Cd per unit dry weight of

Mytilus galloprovincialis (ITIS: 79456: WoRMS 140481) [Subcomponent: flesh]

MMUSCDXX Concentration of cadmium {Cd} per unit dry weight of biota {Mytilus galloprovincialis (ITIS: 79456: WoRMS 140481) [Subcomponent: flesh]}

alpha-hexachlorocyclohexane

not specified alpha-HCH CAS 319-84-6

per unit wet weight of

Boops boops (ITIS: 169218: WoRMS 127047)

W2931256 Concentration of alpha-hexachlorocyclohexane {alpha-HCH CAS 319-84-6} per unit wet weight of biota {Boops boops (ITIS: 169218: WoRMS 127047)}

In these new P01 codes method is not included, this information should be entered elsewhere in the metadata.

Seawater* Sediment Biota

Group Med.Sea Future Status

Med. Sea Inventory

Black Sea

Future status

Black sea

Inventory

Med.Sea Future Status

Med. Sea

Inventory

Black Sea

Future Status

Black sea

Inventory

Med.Sea

Future Status

Med. Sea

Inventory

Fertilizers 4335 3400 4 4

Silicates 4328 3400 4 4

Organic matter 1148 960 18 + 54 + 37

Chlorophyll 684 1080 18 21


4672 3800 30

Acidity 193 172

Antifoulants

Pharmaceuticals

Heavy metals 783 + 51 130 39 62 + 69 400 39 + 34 ts 4

Hydrocarbons 89 + 78125 58

Pesticides and biocides + 17 ts

Radionuclides 80 4 7 1

Plastics


Comparison of Inventory and future submissions

Annual Meeting, June 15-16 2015, Istanbul, Turkey EMODnet Chemistry Partner contribution: HCMR/HNODC...

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