Analytical Report 235651 3TM International Koppers ... · Analytical Report 235651 for 3TM...
173
Analytical Report 235651 for 3TM International Project Manager: Randy Horsak Koppers Creosote Facility 12-AUG-03 XENCO Láboratoric 11381 Meadowglen, Suite L Houston, TX 77082 Ph:(281) 589-0692 Fax:(281) 589-0695 Houston - Dallas - San Antonio - Austin Tampa - Miami - Latin America Page I
Transcript of Analytical Report 235651 3TM International Koppers ... · Analytical Report 235651 for 3TM...
Analytical Report 235651
for
3TM International
Project Manager: Randy Horsak
Koppers Creosote Facility
12-AUG-03
XENCOLáboratoric
11381 Meadowglen, Suite L Houston, TX 77082 Ph:(281) 589-0692 Fax:(281) 589-0695
Houston - Dallas - San Antonio - Austin Tampa - Miami - Latin America Page I
XENCOtnborateries
12-AUG-03
Project Manager: Randy Horank3TM International1500 South Dairy Ashford, Suite 225Houston , TX 77077
Reference: XENCO Report No: 235651Koppers Creoote FacilityProject Address: Grenada, Mississippi
Randy Horsak:
We are reporting to you the results of the analyses performed on the samples received under the project namereferenced above and identified with the XENCO Chain of Custody Numbered 235651. Afl results beingreported under this Chain of Custody apply to the samples analyzed and properly identified with a LaboratoryID number.
All the results for the quality control samples were reviewed. Also, all parameters for data reduction andvalidation were reviewed. In view of this, we are able to release the analytical data for this report withinacceptance criteria for accuracy, precision, completeness or properly flagged.
The validity and integrity of this report will remain intact as long as it is accompanied by this letter andreproduced in full, unless written approval is granted by XENCO Laboratories. This report will be filed for atleast 5 years in our archives after which time it will be destroyed without further notice, unless otherwisearranged with you. The samples received, and described as recorded in COC No. 235651 will be filed for 60days, and after that time they will be properly disposed without further notice, unless otherwise arranged withyou. We reserve the right to return to you any unused samples, extracts or solutions related to theni ifweconsider so necessary (e.g., samples identified as hazardous waste, sample sizes exceeding analytical standardpractices, controlled substances under regulated protocols, etc).
We thank you for selecting XENCO Laboratories to serve your analytical needs. If you have any questionsconcerning this report, please feel free to contact us at any time.
Respectfully,
Recrpient ofthe Prestigious Small Business Administration Award of Ezee(lence In 1994.CertUled and approved by numerous Stares andAgencies.
A Small Business and Minority Status Company that delivers SERVICE and QUALITYHouston - Dallas - San Antonio - Austin * Tampa - Miami - Latin America
2 3 4 5 S 7 l0
i1381
Meo
dow
gien
, Sit
eI.
Ho.
ston
IX77
082
281-
689-
0692
D53
09W
uach
Roo
dSu
Ite
104.
San
Ant
onio
.1X
7823
821
0-5b
9-33
340
1107
8M
orts
ontr
Sul
e0.
DoU
ce. I
X75
229
972-
481-
9999
Com
pany
CC
CNo
:
AN
ALY
SIS
REQU
EST
&CH
AIN
OF
CUST
OD
YRE
CORD
On-
LIN
EH
aIp
&T
echnlc
dS
oiv
lces
atw
ww
.X
NC
O.c
om
Wor
kO
rder
No:
3()
047
Pag
e/
of3
Com
pany
Phon
eL
obo
// —
//
Lob
On’
y37yJ
/i-
C.))
(9)f
f7
Add
ition
sP
roje
ctN
ame
CIPr
e.4o
usly
done
atX
ENC
OP
roje
ctED
TAT:
Sh12
h20
h24
h48
h3d
5d7d
14d
21d
and
TIs
10W
orkh
gD
ays
Cro
r’w
2’-
i9Y
_______
Loc
atio
n
——
Pro
ject
Man
oqer
(PM
)Pr
oJec
tD
irec
tor
(PD
)fii
t4ttj(
oFa
xR
esul
tsto
PM
Ior
Fax
>/-97-
/ó7
chw
olc.
toCI
Acc
ountn
gE
indude
Invo
ice
with
FIna
l Rep
ort A
ttnPM
CIIn
voic
eg
mus
t hav
ea
P.O
Bil t
o:-
EQ
uote
No.
P.O
NoCI
Cal
lfo
r ci P
.O.
Spe
cial
Dt
(FiR
IFi
RII
OW
QA
PPS
eeL
ctPM
Cal
lP
rc.
PM
)-
Sec
ific
atlo
ns4/.’
p,
I—
ES
arnple
rNam
e7:7
Am
,,d4P
Sr,a
turez...%
”—
Sam
pl.
g-
Som
plel
DT
im.
3nM
Lp..t3
ss-oI
1O
-5
(030
Z_
-1
‘—
——
——
—
——
—1rvr-tL
p-w
3oz_1_L
Z_.
3-r
rf(P
$’B
81
•____
--
-. -
3rI
2t-
h?--
7-o
l1.L
22j!__
-
--
——
——
—
-
—31’n
-ps.
-3o3-i
.’z
4’tIc\
Rek
quIs
hed
by(I
nlfla
and5i)
Dot
e&
flm
eR
elin
quis
hed
to(J
rttds
and
Sign
.)D
ate
&Ti
me
Total
Conta
ner
sper
CCC:ti
Zoole
rTonip
:‘
—/,
a1:7
f’-
/(g7O
Rus
bTA
TsF
axD
ue:
Fina
l Fox
Due
:/7
fC
)/
Fina
lRep
ort D
ata
Pac
kag
eD
ueD
ate:
cy’
-c.-(.--
74s/
bush
Cha
rges
ore
Pro-
App
rove
dup
onR
egue
stbg
them
. At T
erm
sA
ppt’
2 3 4 5 6 7 S 9 10 2 3
Pre
eivolt
v.s
-V
ario
us),
NC
!pl
-k2
(H).
H2S
D4
F*k
2(5
),H
N034-k
2(N
).N
ciO
ff+A
sbc
Aci
d(N
AA
).Z
nAc+
NaO
l-l (
ZA).
(Cod
.<4C
)(C
4),
Non
e(N
).S
eeL
abel
(SL)
,O
ther(
O)_
___________
5l:
4oz
(4),
Boz
(8),
32oz
(32)
,4ar
VO
A(V
),TL
(1),
&)O
rnl(
.5),
Ted
lor
Bag
(S).
Mpe
(W).
Oth
erTY
PEG
loss
Nnb
(GA
),G
lass
Cle
ar(G
C),
Plas
tic(P
),O
ther
(0)
2 3 4 5 6 7 8 9 10
011
381
Meo
dow
qlen
.&ilt
eL
Hou
ston
TX77
082
281$8992
________
053
09W
woch
Roa
d,te
104,
Son
Ant
onio
,DC782
210-
309-
3334
El
IlO
76M
orrt
sonL
n,&
iteD
,D
o$os
jX75
229
9724
81-9
99
AN
AL
YS
ISR
EQ
UE
ST
&C
HA
INO
FC
US
TO
DY
RE
CO
RD
On-
LIN
EH
elp
&T
echn
icci
Son’
Ices
ofw
ww
.ZE
NC
O.c
omC
ompa
nyC
OC
No:
Wor
kO
rder
No:
30046
Poge
ofj
Com
pan
yP
hone
LO
siy
*7
//
//
l.ob
Onl
y377—
7.t.14/.
/4’’-3a
-.—
-(!
7I—
7A
ddla
Pr*
ctN
cei
OP
re%
’lou
siyd
oria
tXE
NC
0P
roac
tlD
TAT:
5hl2
tiaR
i24
h48
h3d
Sd7d
Nd
21d1ls
10W
oddn
gD
ays
KQ
pper
sC
re.o
coi-e
0580
agre
eB
uto
ftenre
port
edln
5-7
Woii
dngD
ays_
_______
Loc
atio
n,
, ,0
—R
emar
ks—
Pit
j.ct
Mon
ogor
(PM
)P
roje
ctD
irec
tor
(PD
)(3
‘.
RQ.,-
L,/i
’o,-
stik
”0
Fax
Res
dts’
tom
’PM
(1or
Fax
‘>
,>
TY
Dt
4,,L
,A
pf’
/--/c;r
0.D
..0
hw
oc.
toE
lA
ccou
ntIn
gndude
Invo
ice
wIth
Ffr
Rep
ortA
ttn
PME
lIn
voic
e2
“‘m
zthaie
aP.
OBi
t to:
o—
-
0Q
uote
No.
P.O
lbE
lC
allb
raP.
O.
&‘
U)
Sp.c
ldD
b(R
RI
RRlI
DW
QA
PF
See
LcP
MC
atP
r,P
M)
2atiom
4/(’
PL
,,,
—
.8Sa
mpi
big
-C
Sam
plel
DT
hn.
E<
1
kP
S-q0-o
Z3S
..l(
i3_!1ic±
——
—. -.---
--—
,—
——
——
3fl7-kP
--I13,___L
k_..
—
-----
3rp1-i<
Pq-__.._._
—---_.
--—
——
——
—
.____
4’_’_
3-
Tfl
7-1
D-’
$j___.
-—
3W
-kP
-S-ô
)‘-‘‘
Re1
nqS
hedb
Cln
Iflc
Sl)
Dat
e&
flm
eR
Gfl
qUtih
edto
(In
itids
aid
SIgn
.)D
ote
&Ti
me
tota
l Ccn
tahl
ers
per
CO
C:
oolo
rT
emp:
,Ø
ój),
FJ
E.i
-/‘
OO
Rus
hTA
TsFa
xDue
:Fi
nalF
axD
ue:
Fed
E-
Fina
l Rep
ortD
ata
Pac
kage
Due
Dat
e:L
Rus
hC
harg
esar
ePr
e-A
ppro
ved
upon
Req
uest
ing
them
.A
lTer
ms
App
ly
2 3 4 5 6 7 S 9 10 2
pr,,.
qvol
lves
-V
c1ow
(V),
HC
Ip+
*2(H
),H
2V
4p1
1<2
(i),H
NO
3pH
<2
(N),
ND
OH
+Asb
cA
cid
(NM
),Z
nAc÷
NoO
H(Z
A).
(Coo
I..o
lC)
(Ca)
,N
one
(N),
See
Lab
el(S
L),
Oth
er(0
)32
E:4o
z(4
).8o
z(6
),32
oz(3
2),
4Oiil
VO
A(‘d
),1(1
),&
X)m
l(.5
),T
edla
rB
ag(S
)W
ipe
(N).
Oth
erTY
PEG
loss
Arn
b(G
A),
Glo
ssC
lear
(GC
),Pl
ostlc
(P),
Oth
er(O
)
2 3 4 5 6 7 8 9 10
1138
1M
eadoel
ea.S
teL
Houst
onT
X77082
281.
389-
0692
AN
AL
YSI
SR
EQ
UE
ST
&C
HA
INU
IU
UIU
iJY
KL
U1
LU
1-’a
geot
D83
09W
u,zb
ech
Rd.
St.
104,
San
Mto
n)o,
IX78
238
210-
509-
3334
DN
.W.1
58th
Str
e.
Mcm
lLak
e., F
l 330
1430
6-82
3-85
00[2
1107
8M
onte
enU
i,S
te0
,D
alla
s,TX
7622
997
2-43
1499
9[2
2818
Sout
hFe
tken
burg
Rd, R
lveM
e.l
3356
9•8
13
-0-2
00
0S
erla
I#14
002
0C
ompa
nyP
hone
t.ab
Onl
y:ç
/i—
’,i
3TA
7X
+1
4/3/-
V97-/i3
-/
—P
roje
ctN
ame-
Sta
teC
Prev
ious
lydon. a
tXE
NC
OP
roje
ctID
-T
AT
:5h
12h
24h
48h
3d5d
7d14
d21
d.hd
aA
Tis
Quo
teSp
ecifi
c,—
Kop
,,prc
er,p
’F
,/ii
-4,
plea
secl
rcle
yow
requ
lred
TA
t—
—-
SeiL
octl
on
,-
,/
fro
J.M
anag
er(P
M)
Rem
arks
nd
I7’t
s#i7
Fax
Res
ults
toP
Mq)r
orFa
xN
NV
——
—e-
mai
lFi
nal
Rep
ort t
o:-,
,-
qN
Invo
ice
to[2
Acc
ound
ng‘I
nvolc
ew
ithFi
nal
Rep
oit
[2In
voic
em
ust
have
aP.
O.
Bil
to:
°-
.Q
uote
No.
P.O
No.
CC
all f
ora
P.O
.x
-o13
o.O
I’R
agP
rogr
am:
CL
I’ft
FC
ES
TR
RP
13W
UST
Oth
er:
. NO
<z
Spe
cial
DL
s(G
W13
WT
RR
PQ
APP
MD
Ls
See
Lab
PMIn
clud
edC
all
PM
),
L0
aD
O£
-oS
pec
ific
atio
n.:
Lev
elI
IIIll
IVC
usto
mw
tthR
awD
ata
ED
DD
ryB
asis
,4/,h,
j-1,
.0
0-
5.L
$/L
A(
•r
/.i
+574/4
o0
-Sa
mpl
erN
ame7
Sig
n!
—
01
13
000
Sam
plin
g°-
Sam
ple
IDT
ime
<-
.‘
.-
o•g
12.
..l.
L£0
II.-
-—
3-t
m-k
P-s
—c-t
Z-.,io
:),‘
S-
I—
—X
——
——
m-P
--s-
--ô,
)-—
——
37-P
-&
SO
’-
--
p;gL
)fo,
-
--
—
‘1-
—
Pp/rea4
-i
NS
-—
EH
HH
LR
elin
quis
hed
by(i
niti
als
and
Sig
n)D
ate
&li
me
Rel
Inqu
Ishe
dto
(lni
tlaes
and
Sun
)D
ate
&T
ime
Tot
alC
onta
iner
spe
r COO
:C
oder
Ter
rp;
xi
%S
r/(t’
Fr/
E—
ØØ
’Sp
ecifi
cFa
xD
ueD
ate:
[2R
ush
Prel
imira
ryR
esul
tsC
oatA
ppro
vet
f-
CR
ish
Dat
aP
acka
geco
stpr
eapp
rove
dL
ab:
Rus
hC
narg
esar
ePr
e-A
ppro
ved
upon
Req
uest
ing
Ihem
. All
Ter
ms
App
ly
2 3 4 5 6 7 8 9 10 2 3
Pre
serv
ativ
es:
Var
ious
(V),
HC
Iç-
I<2
(H),
H2S
04pH
<2(S
),H
NO
3pH
<2(N
),A
sbc
AcI
d&N
aOH
(A),
ZnA
c&N
aOH
(Z),
(Coo
l,<4C
)(C
),N
one
(NA
),S
eeLa
bel
(L),
Oth
er(0
)C
ent.
Siz
e:4o
z(4
),B
oa(8
),32
oz(3
2),
4Orri
VO
A(V
),IL
(1),
500m
1(5
),T
edla
rB
ag(B
),W
ipe
(W),
Oth
er_
__
__
__
__
__
Con
t.T
ype:
Gla
ssA
mb
(A),
Gla
ssC
lear
(C),
Plas
tic(P
),O
ther
(0)
_________
Vdati
ixA
ir(A
),Pr
oduc
t(P)
,So
lid(S
),W
ater
V)
Com
mitt
edto
Exce
llenc
eIn
Serv
ice
and
Qua
lity
ww
w.x
enco
.com
XE
NC
OL
obor
ollo
rics
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atIo
n:G
rena
da,
Mis
siss
ippi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Dat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
epor
tD
ate:
12-A
UG
-03
Pro
ject
Mau
aer
Kar
enO
lson
Lab
Id:
2356
51-0
0123
5651
-002
2356
51-0
0323
5651
-004
2356
51-0
05235651.0
06
Fkld
Id:
3TM
-KP4
3-SS
-0l
3TM
-KP-
43-S
S-02
3TM
-KP-
SS-B
B-1
3TM
-KP-
SS-B
B-2
3TM
-KP-
SS-B
B-0
33T
M-K
P-SW
-BB
-01
Ana
lysi
sR
eque
sted
Dep
th:
2-ft
2.ft
1-ft
0-3
In0-
3In
ftM
atrt
xSO
ILSO
ILSO
ILSO
ILSO
ILW
AT
ER
Sam
pled
:Ju
l-21-
0310
:30
Jul-2
1-03
10:4
0Ju
l-21-
0311
:55
Jul-
21-0
312
:35
Jul-
21-0
312
:45
jul-
21-0
312
:55
Per
cent
Moi
stur
eE
xtra
cted
:
Ana
lyze
thJu
l-25-
031&
32Ju
l-25-
03l8
-.34
Jul-2
5-03
18:3
6Ju
l-25
-03
18:3
8Ju
l-25
-03
18:4
0U
niec
/RL
%R
L%
RL
%EL
%EL
%EL
Perc
ent M
oist
ure
24.4
1.00
22.3
100
20.1
100
20.5
1.09
22.8
1.00
—
SVO
As
byE
PA
8270
CE
xtra
cted
:Ju
l-28-
0310
:12
Jul-2
8-03
10:1
5Ju
l-28-
0310
:18
Jul-
28-0
310
:21
Jul-
28-0
310
:24
Jul-
29-0
310
:10
Ana
lyze
thA
ug-0
9-03
0125
Aug
-09-
0302
:16
Aug
-09-
0303
:07
Aug
-09-
0303
:57
Aug
-09-
0304
:48
Aug
-02-
0301
:51
UnU
sIR
L;m
g/kg
EL
mg/
kgE
Lm
g/kg
ELm
g/kg
ELm
g/kg
ELni
g/L
ELA
cena
phth
enc
BIlL
0.22
0B
RL
107
6.78
0.20
80.
561
0209
8.89
0216
0.40
80.
025
Aec
naph
thyl
ene
0.69
102
202.
1810
70.
394
0208
ER
L02
090.
393
0.21
6B
RL
0.02
5A
nthr
acen
c1.
0902
2038
61.
07€9
602
08—
.0.
744
0209
10.7
0216
—__0.2
01
0.02
5B
enzc
(a)a
nthr
accn
e1.
4402
2010
.61.
072.
370.
201
0358
0209
3.92
0.2)
60.
154
0.02
5B
cnzo
(a)p
yrcn
e2.
0302
208A
01.
0713
70.
200
0350
0.20
91.
690.
2)6
0.05
70.
025
Ben
zo(b
)flu
oran
thtie
5J0
0.22
021
.71.
072.
6002
080.
705
0.20
930
60.
216
0.09
700
25B
enzo
(g,h
,i)pc
syle
re0.
805
0220
3.07
1.07
0J4
l0.
208
BR
L0.
209
0388
02)6
BR
L00
25B
enu,
(k)f
1uor
anth
ai11
302
2062
01.
070.
955
0208
0.28
502
090.
919
0216
0.03
300
25C
hiys
ene
2.49
0220
142
1.07
2.64
0200
0.44
40.
209
3.68
0216
0259
0025
Dib
nz(a
.h)M
thra
cenc
DIlL
0.22
0ER
LL
07E
EL
0200
BR
L02
09E
EL
02)6
BR
L00
25Fl
uora
nthe
ne2.
900.
220
305
1.07
114
0.20
81.
4702
09_J
33.8
1)2.
16j
0.79
400
25El
uore
neB
IlL02
20B
IlL10
77.
4002
000.
679
0.20
911
.00.
216
0.49
100
25In
deno
(1,2
,3-c
,d)P
!rcn
e12
80.
220
4.46
1.07
0.47
602
08E
EL
0209
0.50
102
160.
026
0025
Nap
btha
lene
BIlL
0220
BIlL
1.07
4.47
0208
BR
!..02
092.
0502:6
BR
L00
25Ph
enan
thre
nc0.
784
0220
5.54
1.07
24.6
1)10
42.
220.
209
61.5
1)26
1.18
0025
pyrc
ne2.
1002
2024
.51.
077.
5802
080.
967
0.20
912
.60.
216
0.54
80.
025
‘Ott
.esl
ytis
airo
pott,
tad
the
ende
ada
tap.s
k,e
Itra
pesm
as.h
uhi
att
mad
ear
ycw
excl
uahe
tad
coa5
dest
Wm
e.T
hepM
MIC
nIan
dem
mlts
tapt
nmd
ehta
*Sk
itso
alyt
het ,
e,of
lrq
tem
m*
the
best
juda
ttias
tor
XE
NC
OL
aSot
.io,k
eX
EN
CO
t.abo
i.tor
ksae
mem
etm
ore
apon
othi
llly
and
mak
esta
tea
rtan
syto
the
atd
me
ofth
eda
teho
nky
petta
nota
d.O
s,fl
ehIt
tyI,
roaSte
dto
the
amoo
nttn
voki
dta
rIt
.w
orS
tee
dwoa
l.ett
shatw
he.
5retd
toI,
emiti
ngSi
nce
1990
Hou
ston
-D
alla
s.
San
AnI
ons,
-A
ustin
-Tam
pa-
Mia
mi
Latin
Am
eric
aB
rent
Bar
ron
Page
1
Lab
orat
oly
Man
ager
Thia
an.I
ytce
tro
poot
,nd
the
earl
,.da
tapa
ckag
eh
eopr
eoon
u,hi
sho
nem
ode
bryo
uron
ctud
veso
dco
oSdo
otld
non.
The
bmm
prna
.tnm
oan
deo
iohn
ispr
ea.o
dtb
tnag
haot
thti
mia
lyka
l.e,
o6
repe
o..o
tthe
hnot
udgm
ento
flCEN
CO
,bor
oto,
iis.
XE
NC
OLa
horo
turio
sbs
oam
oono
ripo
ndka
flty
and
mok
eono
wtm
oto
the
.,d
no. o
f the
d.ts
here
bypr
onon
ed.
Our
liabi
lIty
islim
bed
toth
eon
oom
tin
voiro
dSt
etft
li,no
ekce
dar m
id...
othe
rwbe
agre
edto
Inw
ettin
g.Si
nce
1990
Hou
ston
-D
alla
s-
San
Ant
onio
-A
ustin
-Tam
pa-
Mia
mi -
Latin
Am
eric
a
XEN
CO
tcbart
ori
cs
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3T
MIn
tern
atio
nal
,H
oust
on,T
XP
roje
ctId
:P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
eceI
ved
InL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e:12
-AU
G-0
3
Pro
ject
Man
agen
Kar
enO
lson
Lab
Id:
2356
51-0
0123
5651
-002
2356
51-0
0323
5651
-004
2356
51-0
0523
5651
-006
Fie
ldId
:3T
M-K
P-43
-SS-
013T
h0-K
P-43
-SS-
023T
h1-K
P-SS
-BB
-13T
M-K
P-SS
-BB
-23T
M-K
P-SS
-BB
-03
3TM
-KP-
SW-B
B.0
1A
na!y
srs
Req
uest
edD
epth
:2-
ft2-
ft1-
ft0-
3In
0-3
Inft
Maü
&SO
ILSO
ILSO
ILSO
ILSO
ILW
AT
ER
Sam
pled
:Ju
l-21-
0310
30Ju
l-21-
0310
:40
Jul-2
1-03
11:5
5Ju
l-21
-03
12:3
5Ju
l-21
-03
12:4
5Ju
l-21
-03
12:5
5V
OA
sby
SW-8
4682
6013
Ext
ract
ed:
Aug
-01-
0316
:12
Aug
-01-
0312
:06
Aug
-01-
0312
:08
Aug
-01-
0312
:10
Aug
-OI-
a312
:12
Ana
lyze
d:A
ug-0
1-03
16:2
7A
ug-0
1-03
14:0
8A
ug-0
1-03
14:3
0A
ug-0
1-03
14:5
1A
ug-0
1-03
15:1
4__________________________
UnI
isJR
L:m
g/kg
RL
mg/
kgR
Im
g/kg
RI
mg/
kgRL
mg/
kgEL
Een
zenc
BIlL
0.00
7B
Ill
0.00
6E
EL
0.00
6B
RL
0.00
6]
EE
L0.
006
Bro
mob
enzc
neB
IlL0.
007
BIlL
0.00
6E
EL
0.00
6B
RL
0.00
61
EE
L0.
006
Bm
moc
h1om
m1i
aie
EE
L0.
007
EEL
0.00
6E
EL
0.00
6B
RL
0.00
61E
EL
0.00
6B
rom
odic
hlor
omet
hane
BR
L0.
007
BIlL
0.00
6I3
RL0.
006
BIl
L0.
006
BR
L0.
006
Bro
mof
onn
BR
L0.
007
EE
L0.
006
EE
L0.
006
BR
L0.
006
ER
L0.
016
Bro
mom
etha
neB
IlL0.
007
BR
L0.
006
EE
L0.
006
EE
L0.
006
EE
L0.
066
MT
BE
EE
L0.
007
BIlL
0.00
6E
EL
0.00
6B
IlL
0.00
6E
EL
0.00
6te
rt-B
utyl
bcnz
ene
BIlL
0.00
7ER
L0.
006
EE
L0.
006
DE
L0.
006
EE
L0.
006
Sec-
But
ylbe
nsen
cB
IlL0.
007
BIlL
0.00
6E
EL
0.00
6E
EL
0.00
6E
RL
0.00
6n-
But
ylbc
nzen
eB
RL
0.00
7D
EL0.
006
BR
L0.
006
EE
L0.
006
EE
L0.
006
Car
bon
Tct
rach
lond
eB
IlL0.
007
EE
L0.
006
EE
L0.
006
BR
L0.
006
BR
L0.
006
Chl
orob
cnze
neE
EL
0.00
7EE
L0,
006
EE
L0.
006
EE
L0.
006
EE
L0.
006
Chl
oroe
tlian
cB
IlL
0.01
3EE
L0.
012
DEL
0.01
2B
RL
0.01
3E
EL
0.01
3C
hlor
ofor
mE
EL
0.00
7E
EL
0.00
6E
EL
0006
BR
L0.
006
BE
L0.
006
Chl
orom
etha
neB
IlL0.
013
BR
L0.
012
BR
L0.
012
BR
L0.
013
EE
L0.
013
2-C
hlor
otol
uene
BIlL
0.00
7E
EL
0.00
6E
EL
0.00
6B
RL
0.00
6E
EL
0.00
64-
Chl
orot
olue
noB
IlL0M
0713
RL0.
006
EE
L0.
006
EE
L0.
0(16
DE
L0.
006
p-C
ymen
e(p-
Isop
mpy
ltolu
cne)
BR
L0.
007
BIlL
0.00
6E
EL
0.00
6E
EL
0.00
60.
020
0.00
61,
2-D
ibro
mo-
3-C
horo
pcop
ene
BIlL
0.00
7E
EL
0.00
6B
IlL0.
006
DE
L0.
006
EE
L0.
006
Dib
rom
ochl
orom
elha
neB
IlL00
07EE
L0.
006
BEL
0.00
6E
EL
0.00
6B
IlL
0.00
6D
ibeo
mom
etha
neB
IlL0.
007
EE
L0.
006
EE
L0.
006
EE
L0.
006
BR
L00
061,
2-D
ichl
orob
cnze
acEE
L0.
007
EE
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
1,3-
Dic
hlor
oben
zeac
BIlL
0.00
7E
EL
0.00
6E
EL
0.00
6B
RL
0.00
6E
EL
0.00
61,
4-D
ichI
orol
nzen
eEE
L0.
007
EE
L0.
006
EE
L0.
006
EE
L0.
0(16
EE
Lo.
ooD
ichl
orod
iflu
orom
tthan
eB
IlL0.
007
BR
L0.
006
EE
L0.
006
BR
L0.
006
EE
L0.
006
Page
2B
rent
Bar
ron
Labo
rato
ryM
anag
er
Thu
osily
ticol
ropo
it,so
dth
eom
irs
dota
p.eb
get
setl
iLbo
obe
enm
ed.b
ryos
ee*
o!u,
Iv, s
odco
e5de
ndd
use.
The
istu
pmto
tlons
end
emub
seop
eese
edtb
oth
ou
tth
uan
sIy4
caie
epoe
t sop
som
eth
beaj
adgm
me
ofX
ENC
OL
abos
stoñ
to.
)cEN
UO
Labo
esto
ticts
enus
mso
resp
coiiN
fin
dm
oken
sow
erto
nty
toth
ee4
0,e
of I
kedn
tebe
echy
poes
cale
d.O
urflo
bOhy
jojI
o,jt
njto
the
amee
ntt
joco
josi
fxild
ow
ork
ordt
runl
mo
uth
aw
.ug
reed
toit,
wttt
lng.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi -
Latin
Am
eric
a
XEN
CO
Lab
ora
tori
esC
erti
fica
teof
Ana
lysi
sS
umm
ary
2356
513T
MIn
tern
atio
nal
,H
oust
on
,T
XP
roje
ctId
:P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
ecei
ved
InL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e:12
-AU
G-0
3
Pro
ject
Man
ager
Kar
enO
lson
Lab
lift
2356
51-0
0123
5651
-002
2356
51-0
0323
5651
-004
2356
51-0
0523
5651
-006
•F
kId
ld:
3TM
-KP-
43-S
S-01
3TM
-KP-
43-S
S-02
3TM
-KP-
SS-B
B-1
3TM
-KP-
SS-B
B-2
3TM
-KP-
SS-B
B-0
33T
M-K
P-SW
-BB
-01
Ana
lysi
sR
eque
lEed
Dep
th:
2-ft
2-ft
1-ft
0-3
In0-
3In
ftM
atri
x:SO
ILSO
ILSO
ILSO
IL.
SOIL
WA
TE
RSa
mpi
eth
Jul-2
1-03
10:3
0Ju
l-21-
0310
:40
Jul-2
1-03
11:5
5Ju
l-21
-03
12:3
5Ju
l-21
-03
12:4
5Ju
l-21
-03
12:5
5V
OA
sby
SW—
846
8260
BE
s*ac
ed:
Aug
-01-
0316
:12
Aug
-01-
0312
:06
Aug
-01-
0312
:08
Aug
-01-
0312
:10
Aug
-01-
0312
:12
Ana
lyze
d:A
ug-0
1-03
16:2
7A
ug-0
1-03
14:0
8A
ug-0
1-03
14:3
0A
ug-0
1-03
14:5
1A
ug-0
1-03
15:1
4j
1Fnl
LrJR
L.m
g/kg
RL
mg/
kgR
!.m
g/kg
RI
mg/
kgRL
mg/
kgil
l1,
2-D
ichi
omet
hane
BIt!
.0.
007
BIlL
0.00
6B
RL
0.00
6BI
LL0.
005
BIl
LDM
061,
1-D
lchl
oroe
than
eB
IlL0.
007
BIl
L0.
006
BIlL
0M06
BR
!.0.
006
BILL
0.00
6tr
ans-
I,2-d
ichl
oroe
uhen
eB
R!.
0.00
7BI
LL00
06B
R!.
0.00
6B
R!.
0.00
6B
R!.
0.00
6ci
s-1,
2-D
ichI
oroe
t1ne
Bill
.0.
007
BR
L0.
006
BR
!.0.
006
BILL
0.00
6BI
LL0.
006
1,1-
Dic
hlor
oeth
ene
BR
!.0.
007
BIlL
0.00
6B
R!.
0.00
6BI
LL0.
006
BR
L0.
006
2,2-
Dic
hlor
opro
pane
BR
L0.
007
BR
!.0.
006
BR
!.0.
006
BIl
L0.
006
BR
!.0.
006
I,3-D
ichi
orop
ropa
neBI
lL.
0.00
7B
IlL0.
006
BR
!.0.
006
BIl
L0.
006
BR
L0.
006
1,2-
Dic
hlor
opro
pane
BR.L
0.00
7B
R!.
0,00
6B
IlL0.
006
BR
L0.
006
BILL
0.00
6tr
ans-
I,3-
dich
loro
jiope
neB
IlL0M
07B
IlL0,
006
BR
!.0.
006
BIl
LDM
06B
IlL
0.00
61,
1-D
ichi
ompr
open
eB
IlL0M
07B
IlL0.
006
BR
!.0.
006
BIl
L0.
006
BR
!.0.
006
cis-
l,3.D
ichl
orop
rope
neB
IlLDM
07BI
LL0.
006
BR
!.0.
006
BR
!.0.
006
BR
I.0.
006
Eth
ylbe
nzen
eB
IlL0.
007
BIlL
0.00
6BI
LL0.
006
BR
!.DM
06B
R!.
0.00
6H
cxac
h]or
obut
adie
neB
IlLD
M07
BIlL
0.00
6B
R!.
0.00
6B
IlL
0.00
6B
IlL
DM06
isop
ropy
lben
zene
BilL
0.00
7BR
!..0.
006
BR
!.0.
006
BILL
0.00
60.
009
0.00
6M
ethy
lene
Chl
orid
eB
IlL0.
027
DILL
0.02
5B
R!.
0.02
5B
IlL
DM25
BR
!.DM
26N
apht
halc
ncB
IlL0.
013
BIlL
0.01
20.
197
I)0.
062
0.07
70.
013
—_10.4
D1.
30n-
Pmpy
lben
zenc
BIlL
0.00
7B
R!.
DM
06B
R!.
0.00
6B
IlL
0.00
6B
IlL
DM06
Styr
ene
BR
!.0.
007
BR
!.D
M06
BR
!.0.
006
BR
!.0.
006
BILL
0.00
61,
1,1,
2-T
etra
chlo
rcct
hane
BIlL
0.00
7BI
LL0.
006
BILL
DM06
BIl
L0.
006
BILL
DM06
1,1,
2,2-
Tet
rach
lors
ctha
neB
IlL0.
007
BIlL
0.00
6B
IlLDM
06B
IlL
0.00
6B
IlL
DM06
TTe
troch
loro
ethy
lene
BR
!.0.
007
BR
!.0.
006
BILL
0.00
6B
RL
DM06
BR
!.DM
06T
olue
neB
IlL0.
007
BILL
0.00
6B
RL
0M06
BR
!.0.
006
BIl
L._
_o.W
f_____________
l,2,4
-Tri
ehlo
eubc
nzen
eB
IlL0.
007
BR
!.0.
006
BIlL
0.00
6B
R!.
0.00
6BI
LL.
0.03
61,
2,3-
Tri
chlo
robe
nusn
eBR
L0.
007
BIlL
0.00
6BR
!.0.
006
BIl
L0.
006
BR
!.0.
036
l,1,2
-Tri
chlo
roct
hane
BR
!.D
M07
BR
!.0.
006
BIlL
DM06
BILL
DM06
BIl
LD
M06
Bre
ntB
arro
nL
abor
atoy
Man
ager
Page
3
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
y
This
anet
ytin
sin.
pafl
and
the
eetir
ada
tapo
ck.,a
Itre
pnnw
sti.h
ube
enm
ade
aryo
uren
clus
ive
and
conf
idno
ttaat
e.T
heI
reet
tiont
and
reeu
ttaes
qwee
ned
tbea
uhou
ttht
.aus
iytis
alro
pedrq
nd
the
bant
judm
ait
ofX
ENCO
Labo
rato
rine.
XEN
CO
Labo
rato
ries
usai
mes
itore
opon
iIity
and
mak
esno
wm
mM
ylo
the
end
use
ofth
eda
tahe
ruby
pres
ente
d.O
urfla
kitit
yIs
rant
edto
the
snow
sIn
edoe
dfin
tlds
wee
koru
ntc
ssae
heem
linar
oed
toin
wri
tsa
Sinc
e19
90H
ousl
on-
Dal
las
-Sa
nA
aton
b-
Aus
tin-
Tam
pa-
Mia
mi-
Lat
inA
mer
ica
Dat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
bat
e:12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
Bar
ron
Lab
ora
tory
Man
ager
XEN
CO
Lab
orc
tlore
s
Pro
ject
Id:
Conta
ctR
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
Id:
2356
51-0
0123
5651
-002
2356
51-0
0323
5651
-004
2356
51-0
0523
3651
-006
•F
ield
Id:
3TM
-KJ’
43-S
S-01
3TM
-KP-
43-S
S-02
3TM
-KP-
SS-B
B-I
3Th4
-KP-
SS-B
B-2
3TM
-KP-
SS-B
B-0
33T
M-K
P-SW
-BB
-ll
Ana
lysi
sR
eque
sted
Dep
tk2-
ft2.
ft1-
ft0-
3In
0-3
In11
MaO
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
WA
TER
Sam
pled
:Ju
l-21-
0310
:30
Jul-2
1-03
10:4
0Ju
l-21-
0311
:55
Jul-
21-0
312
:35
Jul-
21-0
312
:45
Jul-
21-0
312
:55
VO
As
SW-8
4682
60B
Exi
raci
ed:
Aug
-01-
0316
:12
Aug
-01-
0312
:06
Aug
-0.-0
312
:08
Aug
-01-
0312
:10
Aug
-01-
0312
:12
Ana
lyze
d:A
ug-0
1-03
16:2
7A
ug-0
1-03
14:0
8A
ug-0
1-03
14.3
0A
ug-0
1-03
14:5
1A
ug-0
1-03
15:1
4U
n/fr
/Ri:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RLm
g/kg
RL
1,1,
I-T
rich
loro
diia
neB
RL
0.00
7B
RL
0.00
6R
RL
0.00
6B
RL
0.00
6B
R].
0.06
6T
rich
loro
ethe
neB
RL
0.00
7BR
]..0.
006
BR!..
0.00
6BR
!..0.
006
BR
].0.
066
—.____________
Tri
vhlo
rofl
uoro
mct
hanc
-
BR
L0.
007
BR
L0.
006
BR
L0.
006
B9.
L0.
006
BR
]..0.
066
1,2,
3-T
rich
loro
prol
ane
RR
L0.
007
BR!..
0,00
6B
RL
0.00
6B
R].
0.00
6B
R].
0.00
6I,2
,4-T
rim
ethy
lbcn
zcne
BR
L0.
007
BR
L0.
006
0.01
40.
006
BR
].0.
006
0.14
50.
066
1,3,
5-tr
imet
hylb
enne
BR
L0.
007
881.
.0.
006
0.00
70.
006
BR
L0.
006
--
0.06
70.
006
Vin
ylC
hlor
ide
BR
L0.
003
BR]..
0.00
2B
R].
0.00
2B
RL
0,00
3B
R].
0.00
3o-
Xyl
ene
BR
L0.
007
BR!..
0.00
6B
R].
0.00
6B
RL
0.00
6B
RL
0.00
6m
,p-X
ylen
csB
RL
0.01
388
1..
0.01
2BR
!..0.
012
BR
L0.
013
BR!..
0.01
3
Page
4
Con
tact
:R
andy
Hor
ask
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Dat
eRe
ceiv
edin
Lab
:F
riJu
l-25
-03
10:3
0am
Rep
ort
Dat
e:12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
ml.
anal
ytin
dce
pact
. and
Ihan
tic, d
ata
p.c
kae
Itne
ptew
e., h
a.he
mm
id. f
rur
u,Iv
end
eoia
tdit
I.l.
isT
hele
tnep
enta
tlona
and
re,o
ttaan
peea
ned
thm
abo.
nfb
i..n
alyt
it.I
empo
atpre
wt
the
boat
loda
men
tofX
EN
CO
Lnb
ornt
odn.
,X
EN
CO
bbor.
todes
aant
mem
noro
apnn
tibU
ityan
dm
ako.
nowa
rrant
y to
the
ead
an. o
f the
data
here
bypr
enon
tid.
Oae
li.h
ltty
lalim
ited
totIr
em
eant
breo
lced
fcc
thi,
reac
ton
tono
lan,
ofbw
nhe
.,eed
tohr
o.i
tin
Sinc
e19
90H
oust
tn-D
alla
sSa
nA
nton
b-
Aus
tin-T
ampa
-M
iam
i-
Lat
inA
mer
ica
Page
5B
rent
Ban
-on
Lab
orat
ory
Man
ager
XE
NC
OL
nL,o
roL
orie
s
Pro
ject
Id:
Lab
Id:
2356
51-0
0723
5651
-008
2356
51-0
0923
5651
-010
2356
51-0
1123
5651
-012
•F
ield
Id:
3TM
-KP-
SS=7
-O1
3Th{
-KP-
SS-7
-02
3IN
-XP-
SS-3
03-(h
l3T
M-K
P-SS
-303
-02
3TM
.KP-
SS-6
90.U
l3T
M-)
P-SS
-690
-0A
naly
sIs
Req
uest
edD
epth
:6
In6
In6
In6
In1-
ftI-
ftM
atri
x:SO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Jul-2
2-03
08:1
5Ju
l-22-
0308
:25
Jul-2
2-03
12:0
5Ju
l-22
-03
12:1
5Ju
l-23
-03
09:5
0Ju
l-23
-03
10:0
5Pe
ro!e
ntM
oist
ure
ExU
aCte
th
Ana
lyze
d:Ju
l-25-
0318
:42
Jul-2
3-03
18:4
4Ju
l-25-
0318
:46
Jul-
25-0
318
:48
Jul-
25-0
318
:50
Jul-
25-0
318
:54
LJni
Is/R
L%
RL
%R
L%
RL
%R
L%
RL
%K
!.Pe
rcen
tMoi
stur
e14
.31.
0015
6L
0013
31.
0010
3L0
Oj
19.6
LW
13.6
1.00
SV
OA
sby
EP
A82
70C
Exf
ract
ed:
Jul-2
8-03
10:2
7Ju
l-28-
0310
:30
Jul-2
8-03
10:3
3Ju
l-28
-03
10:3
6Ju
l-28
-03
10:4
5Ju
l-28
-03
10:4
8A
naly
zed:
Aug
-09-
0305
:38
Aug
-07-
0306
:59
Aug
-0-0
306
:09
Aug
-07-
0305
:19
Aug
-07-
0304
:28
Aug
-07-
0301
:56
(Ini
xJR
Lm
g/kg
RL
mg/
kgRI
..m
g/kg
RL
mg/
kgR
I.m
g/kg
RL
mg/
kgK
!.A
ccna
phth
ene
BR
L0.
973
BR
!.0.
197
BR
!.0.
192
BR
L0.
185
BR
!..0.
207
BR
.L0.
193
Ace
naph
tbyl
cne
BIlL
0.97
303
680.
197
BR
L0.
192
BR
L03
85B
RL
0.20
7B
RL
0.19
3A
nthr
acen
eB
IlL0.
973
0374
0.19
7B
R!.
0.19
2B
R!.
0.18
5B
RL
0207
BR
L0.
193
Ben
zoça
)ant
hrac
ene
BR
L09
730.
927
0.19
7B
R!.
0.19
2B
IlL
0.18
5B
R!.
0.20
7B
RL
0.19
3B
cnm
(a)p
yren
eB
IlL0.
973
1.18
0.19
7B
RL
0.19
2B
R!.
0.18
5B
RL
0207
BR
!.0.
193
Ben
w(b
)flu
oran
then
eBR
U0.
973
2.92
0.19
7BR
!..0.
192
BIl
L0.
185
BR!..
0.2C
7B
IlL
0.19
3B
enzo
(g.h
i)pe
ryle
neB
IlL0.
973
0.37
40.
197
BIlL
0.19
2B
RL
0.18
5B
IlL
0.20
7B
RL
0.19
3B
enzo
(k)f
luor
nthe
ieB
IlL0.
973
0.91
50.
197
BR
L0.
192
BIl
L0.
185
BIl
L0.
207
BR
!.0.
193
Chi
’ysc
neB
RL
0,97
313
90.
197
BR
!.0.
192
SRI.
0.18
5B
R!.
0.20
7B
R!.
0.19
3D
ibcn
z(a,
h)A
nthr
acen
eB
IlL
0.97
3B
R!.
0.19
7B
RL
0.19
2B
R!.
0.18
5B
R!.
0207
[B
RL
0.19
3Fl
uora
nthe
neB
IlL0.
973
136
0.19
7B
R!.
0.19
2B
IlL
0.18
5B
RL
0207
BIl
L0.
193
Fluo
renc
BIlL
0.97
3B
RL
0.19
7B
IlL03
92B
R!.
0.18
5B
IlL
0.20
7B
R!.
0.19
3In
dcno
(1,2
.3-c
,d)P
3rcn
eB
IlL0.
973
0.53
60.
197
BIlL
0.19
2SR
I.0.
185
BIlL
0207
BR
!.0.
193
Nap
htha
lcnc
BIlL
0.97
3B
R!.
0.19
7B
IlL0.
192
BR
!.0.
185
BIlL
0.20
7B
R!.
0193
Pii
ithre
ne
BR
!..0.
973
0.27
50.
197
BIlL
0392J
BR
!.0.
185
BR
L0.
207
BIl
L0.
193
Pyre
neB
IlL0.
973
1.67
0.19
7B
IlL0.
192
BR
!.0.
185
BR
!.0.
207
BR
!.0.
193
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,
TX
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Faci
lity
Dat
eR
eceI
ved
InL
ab:
Fri
Jul-
25-0
310
:30
am
Rep
ort
Dat
e:12
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
on
EN
CO
Lco
borc
otor
ics
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
Id.
2356
51-0
0723
5651
-008
2356
51-0
0923
5651
-010
2356
51-0
1123
5651
-012
•F
Idd
lth
3TM
-KP-
SS-7
-0l
3TM
-KP-
SS-7
-02
3TM
-K?.S
S-30
3-O
13T
M-1
O-S
S-30
3-02
3TM
-K1’
-SS-
690-
0I3T
M-K
P-SS
-690
-0Z
Ana
lysi
sR
eque
sted
Dep
th:
6In
6In
6In
6In
1-ft
1-ft
Mat
rlx
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
Sam
pled
:Ju
l-22-
0308
:15
Jul-2
2.03
08:2
5Ju
l-22-
0312
:05
Jul-
22-0
312
:15
Jul-
23-0
309
:50
Jul-
23-0
310
:05
VO
As
hySW
-846
8260
flH
xira
sfed
:A
ug-0
1-03
17:0
4A
ug-0
1-03
12:1
6A
ug-0
4-03
16:0
4A
ug-0
1-03
1258
Aug
-01-
0312
00A
ug-0
4-03
11:4
0
Ana
lyze
&A
ug-0
1-03
19:5
2A
ug-0
1-03
15:5
7A
ug-0
4-03
17:2
8A
ug-0
1-03
18:4
8A
ug-0
1-03
12:4
3A
ug-0
4-03
12:0
7
Uni
1yiR
L.ru
g/kg
RI
mg/
kgR
Im
g/kg
RI
mg)
kgR
Im
g/kg
RI
mg/
kgRL
Ben
zene
BR
I0.
006
801
0.00
6I3
RL0.
006
BR
L0.
006
BR
L0.
006
TO
RL
0.00
6
Bro
mob
cnze
neB
IlL0.
006
BR
L0.
006
BIlL
0.00
6B
RL
0.00
6B
RL
__
0.0
06
JB
RL
0.00
6
Bro
moc
hlor
omet
haae
BilL
0.00
6B
RL
0.00
6BI
lL0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
Bro
mod
lchl
orom
e0an
eB
IlL0.
006
BR
L0.
006
BR
L0.
006
BR
J.0.
006
BIl
L0.
006
BR
L0.
006
Bro
mof
orm
BilL
0.00
6B
RL
0.00
6B
RL
0.00
6B
IlL
0.00
6U
RL
0.00
6B
RL
0.00
6
Bro
mom
etlia
ncB
IlL0.
006
BR
L0.
006
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6
MTB
EB
IlL0.
006
BR
L0.
006
BIl
L0.
006
BR
L0.
006
BR
L0.
006
BIl
L0.
006
tert
-But
ylbc
nzen
eB
R!.
0.00
6B
IlL0.
006
ERL
0.00
6B
RL
0.00
6B
R!.
__
0.0
06
JB
RL
0.00
6
Sec-
But
ylbe
ozen
eB
IlL0.
006
BR
L0.
006
BIlL
0.00
6B
IlL
0.00
6B
RL
0.00
6B
RL
0.00
6
n-B
utyl
benz
ene
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
6B
IlL
0.00
6B
RL
0.00
6B
IlL
0.00
6
Car
bon
Tetc
achl
orid
eB
IlL0.
006
BIlL
0.00
6B
RL
0.00
6B
R!.
0.00
6B
RL
0.00
6B
RL
0.00
6
Chk
,mbc
nzen
eB
IlL0.
006
BIlL
0.00
6B
IlL0.
006
BIl
L0.
006
BIl
L0.
006
BR
L0.
006
Chi
oroe
than
eB
IlL0.
012
BR!..
0.01
2B
IlL0.
012
BIl
L0.
011
BIl
L0.
012
BIl
L00
12
Chl
orof
orm
BR
!.0.
006
BIlL
0.00
6B
IlL0.
006
BIl
L0.
005
-B
RL
0.00
6B
RL
0.00
6
Chl
orom
etha
neB
IlL0.
012
BR
L0.
012
BIlL
0.01
2B
IlL
0.01
1B
IlL
0.01
2B
IlL
0.01
2
2-C
hior
otol
uene
BilL
0.00
6B
IlL0.
006
BIlL
0.00
6B
Ill.
0.00
6B
R!.
0.00
6B
IlL
0.00
6
4-C
hlor
otol
uenc
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
IlL
0.00
6B
IlL
0.00
6B
IlL
0.00
6
p-C
ymen
c(p
-Tso
prop
yllo
lucn
e)B
RL
0,00
6B
IlL0.
006
ilRL
0.00
6B
IlL
0.00
5B
IlL
0.00
6B
IlL
0.00
5
1,2-
Dib
rom
o-3-
Cla
brop
ropa
neB
RL
0.00
6BR
.L0.
006
BIlL
0.00
6B
RL
0.00
6B
IlL
0.00
6B
IlL
0.00
6
•Dib
rom
ochl
orom
etha
neB
IlL0.
006
BIlL
0.00
6B
IlL0.
006
BIl
L0.
006
BR.!.
0.00
6B
IlL
0.00
6
t)ib
rom
omct
hane
BIlL
0.00
6B
RL
0.00
6B
IlL0.
006
BIl
L0.
005
BR
L0.
006
BIl
L0.
006
I,2-D
ichl
orob
enze
me
BIlL
0.00
6B
IlL0.
006
BIl
L0.
006
BIl
L0.
006
BR
!.0.
006
BIl
L00
06
I,3-D
lchl
orob
enze
neB
IlL0.
006
BIlL
0.00
6B
IlL0.
006
BIl
L0.
006
,B
IlL
0.00
6B
IlL
0.00
6
1,4-
Dle
hlor
obcn
zenc
BilL
0.006
BRL
0.00
6B
IlL0,
006
BIl
L0.
005
BR
L0.
006
—B
IlL
0.00
6
Dic
hlor
odif
luor
omha
neB
IlL0.
006
BIlL
0.00
6BP
.L0.
006
BR
L0.
006
BIl
L0.
006
BR
L00
06
XE
NC
Obb
eest
onee
eatu
tneu
tore
spon
aibi
it3
and
milt
onno
vam
ety
toth
eed
use
ofth
eda
tahe
reby
pran
oute
d.
Our
liabi
lity
lilbi
tited
toth
eir
.ow
ein
voi
ikr
tide
wee
ke,
&tn
dneu
othe
rwk.
geee
dto
Inw
tili
r
Sinc
e19
90H
oust
n-
Dal
las
.Sa
nA
nton
k,-
Aus
tin-
Tam
pa-
Mia
mi-
Lat
inA
mer
ica
ent’rron
bo
rato
iyM
anag
erPa
ge6
Dat
eR
ecei
ved
inL
ab:
FriJ
ul-2
5-03
10:3
0am
Rep
ort
Dat
e:12
.AIJ
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
XEN
CO
LorQ
11cs
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,houst
on
,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
IP
roje
ct1d;
Con
tact
:R
andy
ITor
tak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
14:
2356
51-0
0723
5651
-008
2356
51-0
0923
5651
-010
2356
51-O
H23
5651
-012
Flel
dId
:3T
M-K
P-SS
-7-O
13T
h0-K
P-SS
.7.0
23T
M41
P-SS
-303
-01
3TM
4C1’
-SS-
303-
023T
M-R
P-SS
.690
-O1
3TM
-KP-
SS-6
90-0
2
Ana
lysi
sR
eque
sted
Dep
th:
61n
61n
61n
61n
1-f
tI-
ILM
airi
xSO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Jul-2
2-03
08:1
5Ju
l-22-
0308
:25
Jul-2
2-03
12:0
5Ju
l-22
-03
12:1
5Ju
l-23
-03
09:5
0ju
l-23
-03
10:0
5V
OA
sb3’
Sw
-846
826O
Exi
,-ad
ed:
Aug
-01.
0317
:04
Aug
-01-
0312
:16
Aug
-04-
0316
:04
Aug
-01-
0312
:58
Aug
-01-
0312
:00
Aug
-04-
0311
:40
Ana
lyze
d:A
ug-0
1-03
19:5
2A
ug-0
1-03
15:5
7A
ug-0
4-03
17:2
8A
ug-0
1-03
18:4
8A
ug-0
1-03
12:4
3A
ug-0
4-03
12:0
1U
nits
/RL
:m
g/kg
RL
mg/
kgR
Lm
g/hg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgRL
1,2-
Dic
hlor
oeth
ane
BIlL
0.00
6B
RL
0.00
6O
RL
0.00
6B
RL
0.00
5]
BR
L0.
006
BR
L0.
006
lj-D
ichl
oroe
than
cB
IlL0.
006
BR
L0.
006
IIR
L0.
006
BR
L0.
006
ER
L0.
006
BRL.
0.00
6
tran
s-l,2
-dic
h1or
ohen
eB
IlL0.
006
BR
L0.
006
VR
L0.
006
BR
L0.
006
jB
RL
0.00
6B
RL
0.00
6
cis-
I,2-
Dic
hlor
octlr
ne.
BIlL
0.00
6B
IlL0.
006
BR
L0.
006
BR
L0.
005
BR
L0.
006
BIl
L00
06
1,1-
Dic
hior
oeth
enc
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0006
2,2-
Dic
hior
opro
pace
BR
L0.
006
BIlL
0.00
6ER
L0.
006
BR
L0.
005
BR
L0.
006
ER
L00
06
13-D
ichl
orop
ropa
neB
IlL0.
006
BIlL
0.00
6B
RL
0.00
6B
IlL
0.00
6B
R].
0.00
6B
RL
0006
1.2-
Dic
hlor
opro
pane
BIlL
0.00
6B
IlL0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L00
06
tran
s-1,
3-di
ch1o
roxo
pene
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
IlL
0.00
6
i,1-D
ichl
orop
ropc
ecB
IlL0.
006
BR
L0.
006
BIlL
0.00
6B
IlL
0.00
6B
IlL
0.00
6B
IlL
0.00
6
cis-
1,3-
Dic
hlom
prop
cne
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
IlL
0,00
6B
IlL
0.00
6B
IlL
0.00
6
Eth
ylbe
azen
eB
IlL0.
006
BIlL
0.00
6B
IlL0.
006
BR
L0.
006
BIl
L0.
006
BIl
L0.
006
Hex
achi
orob
utad
iene
BR
L0.
006
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6B
R].
0.00
6B
IlL
0.00
6
isop
mpy
lbcn
zene
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
6B
RL
0.00
6B
IlL
0.00
6B
RL
0.00
6
Met
hyle
neC
hlor
ide
BIlL
0.02
3B
IlL0.
024
BIlL
0.02
3B
IlL
0.02
2B
IlL
0.02
5B
RL
0.02
3
Nap
htha
lene
BIlL
0.01
2B
IlL0.
012
ERL
0.01
2B
RL
0.01
1B
IlL
0.01
2B
IlL
0012
n-Pr
opyl
bcnz
ene
881.
0.00
6B
IlL0.
006
BR
L0.
006
BR
L0.
006
BIl
L0.
006
BIl
L0.
006
Styr
ene
BR
L0.
006
BIlL
0.00
6B
RL
0.00
6B
IlL
0.00
6B
IlL
0.00
6B
RL
0.00
6
1,1,
l,2-T
elra
chlo
rcct
hane
BIlL
0.00
6B
IlL0.
006
BR
].0.
006
BIl
L0.
006
BIl
L0.
006
BIl
L0.
006
t,1,2
,2-T
etra
chlo
roet
hane
BIlL
0.00
6B
R].
0.00
6B
IlL0.
006
BIl
L0.
006
BIl
L0.
006
BR
].0.
006
Tet
rach
loro
ethy
lene
BIlL
0.00
6B
IlL0.
006
BR
].0.
006
BIl
L0.
006
BIl
L0.
006
BR
].0,
006
Tol
uene
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
6B
IlL
0.00
6B
RL
0.00
6B
RL
(100
6
l,2.4
-Tri
chlo
robe
nzen
eB
IlL0.
006
ERL
0.00
6B
IlL0.
006
BIl
L0.
006
BIl
L0.
006
BE
L0.
006
1,2,
3-T
rich
loro
benz
ene
BIlL
0.0.
06BR
.L0.
006
BR
L0.
006
BIl
L0.
006
BIl
L0.
006
BP.
L00
06
1,12
-Tri
chlo
roct
hate
BR
L0.
006
BIlL
0.00
6B
IlL0.
006
BR
].0.
006
BIl
L0.
006
BR
L0.
006
The
tnt
,reta
tloos
and
eana
ltsa
pre,
,ed
thro
ehoo
t thi
nan
lyea
Inn
pmtr
aytm
eett
hebd5m
ent
ofN
CO
Lab
oeat
o.it
&X
EN
CO
L.b
m.t
o.ln
.ana
nmm
nore
apon
atbt
ilan
dm
akno
nova
inon
tyto
the
aid
use
ofth
eda
tahc
pnnw
end.
Our
liabi
lity
I,lim
ited
toth
em
ount
invo
iced
thrt
ld,w
anic
ced
anhi
n’ot
awit
e,gr
oed
tohi
wit
tln
Sinc
e19
90H
ousl
on-
Dal
las
.Sa
nA
nton
io-
Aus
tin-T
ampa
-M
iam
i-
Latin
Am
eric
aZ
rentB
arron
Lab
ora
tory
Man
ager
Page
7
Dat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
XEN
CO
oro
tor1
cs
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
31M
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctId
:P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Lab
Id:
2356
51-0
0723
5651
-008
2356
51-0
0923
5651
-010
2356
51-0
1123
5651
-012
.
Fie
JdI&
3TM
-K1-
SS-7
-0I
3TM
-XP-
SS-7
-02
JTM
-K’-S
S-30
3-0I
3Th4
-KP-
SS-3
03-0
23T
ht-K
P-SS
-690
-01
3Th4
-KP-
SS-6
90-0
2A
naly
sis
Req
uesf
edD
epth
:6
In6
In6
In6
In1-
ft1-
ftM
at,i:
cSO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Jul-2
2-03
08:1
53u
1-22
.03
08:2
5Ju
l-22-
0312
:05
Jul-
22-0
312
:15
Jul-
23-0
309
:50
Jul-
23-0
310
:05
VO
As
bySW
—84
6826O
E.zl
fade
d:A
ug-0
1-03
17:0
4A
ug-0
1-03
12:1
6A
ug-0
4-03
16:0
4A
ug-0
1-03
12:5
8A
ug-0
1-03
12:0
0A
ug-0
4-03
11:4
1A
naly
zed:
Aug
-01-
0319
:52
Aug
-01-
0315
:57
Aug
-04-
0317
28A
ug-0
1-03
18:4
8A
ug-0
1-03
12:4
3A
ug-0
4-03
12:W
•.U
niM
iL:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RI.
mg/
kgR
Lm
g/kg
RI.
1;1,
1-T
rich
1oro
ctha
eSR
I.0.
006
BR
L0.
006
SRI.
0.00
6B
RL
0.00
5U
RL
0.00
6B
RL
0006
Tri
chlo
roei
hcne
DIlL
0.00
6B
IlL0.
006
SRL
0.00
6B
RL
0.00
6B
RL
0.00
6SI
lL00
06T
rich
loro
fluo
rom
etha
ncD
EL0.
006
SRI.
0.00
6SR
L0.
006
SR
I.0.
006
jS
RI.
0.00
6SR
L0
006
l,2,3
.Tri
chlo
mpt
ppan
eB
IlL0,
006
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
6f
BR
L0.
006
SRI.
0006
l,2,4
-Tri
met
h)1b
ezcn
eB
RL
0.00
6B
IlL0.
006
BIlL
0.00
6B
RL
__0006j
BR
L0.
006_
[B
IlL
0006
1,3,
5-tr
imet
hylb
enze
neSR
I.0.
006
BIlL
0.00
6B
IlL0.
006
BIl
L0.
006
BIl
L0.
006
BIl
L0.
006
Vin
ylC
hlor
ide
SRI.
0.00
2SR
I.0.
002
SRI.
0.00
2B
RL
0.00
2B
IlL
0.00
2SR
I.0.
002
o-X
3jcn
eB
ilL0.
006
BIlL
0.00
6SR
I.0.
006
BR
L0.
006
BIl
L0.
006
BIl
L00
06m
,p-X
ylcn
es88
.1.
0.01
2B
IlL
0.01
2ER
L0.
012
BR
L0.
011
SR
I.0.
012
BR
L0,
012
Thi
..)
yla
lro
pont
. nod
the
notir
eda
tape
ekag
eIt
r,p
re.n
ot
tan
boa,
m.d
.f.
ryou
rno
dt.d
veno
doo
nfld
miti
dno
n.Th
ont
orpn
nt.tk
ne. n
otro
ailta
enpt
m.n
dth
rotb
ont
hi.a
n.Iy
tc.1
roort
rnpn
omlt
tho
boa
juda
tnet
uoC
XEP
ICO
Lab
onto
nl,L
XE
NC
OL
.bem
teri
uau
umm
noru
pon.a
dif
nod
nob..
noo.
mnL
yto
th.
end
no. a
ft).
.d.t
abm
aby
peno
erd.
Our
Hab
iIit
I.lim
ited
toth
e.r
mm
tin
voic
edSt
eti
nino
okde
ecod
nen
aebe
rwito
agen
edto
hro
vit
)oSi
nce
1990
Hou
ston
-D
alla
s-
San
An
ton
io-
Aus
tin-T
ampa
-M
iam
i -La
tinA
mer
ica
Bao
nLa
bora
tory
Man
ager
Pagc
8
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
lid
ssn
.lyttc
.Irq
sod,
sod
the
eat,
,da
tepadi,
Itro
çros
mui
hube
enm
ade
twya
sirn
xchs
ste
nod
co.d
tdoi
tldu
sT
hem
tupe
s..ti
on. s
odre
subs
anpe
usse
dtI
nout
hout
this
soat
yt.c
slre
poet
rqw
e.an
t the
bust
juda
mm
itof
XE
NC
OU
bo,e
iode
s.X
EN
CO
Lebo
esto
etes
smam
mso
resp
onal
bfltt
oan
dm
ubes
amw
inm
ayto
tttn
usd
usa
oflb
sda
tebe
eday
pesse
atosL
O,
itabi
Rty
I,lio
dlof
toth
e.a
aoon
tbo
toto
edlb
rthi
sw
ed, c
oWm
aim
ethe
awite
egr,
,das
isw
aitb
,Si
nce
1990
Hou
ston
-D
alla
s-S
anA
nton
io-
Aus
tin-T
ampa
-M
iam
i-
Latin
Mne
tica
Pag
t9
XEN
CO
Lobore
Dat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e;12
-AU
G-0
3P
roje
ctM
anag
erK
aren
Ols
on
Pro
ject
Id:
Con
tact
:R
andy
Hom
ak
Pro
ject
Loc
atio
n:G
rena
da, M
issi
ssip
pi
Lab
Id;
2356
51-0
1323
5651
-014
2356
51-0
1523
5651
-016
2356
51-0
1723
5651
-018
•F
ield
Id:
3Th(
-KJ’
-SS-
l137
-0)
3Th4
4C3’
.SS-
I13
7-02
3Th1
-1C
P-SS
-688
-01
3Th(
-KP-
SS-6
88-0
23T
h0-K
P-Bq
uipm
eiit
RIm
e!T
M-I
IP-H
eId
Rin
kA
naI
ys
Req
uest
edD
qJth
:6
In6
In6
In6
InIn
fiM
atri
x:SO
ILSO
ILSO
IL.
SOIL
WA
TE
RW
AT
ER
Sam
pled
:Ju
l-23-
0314
:40
Jul-
23.0
314
:50
Jul-2
3-03
16:5
0Ju
l-23
-03
17:0
0Ju
l-24
-03
08:5
0Ju
l-24
-03
08:5
5P
erce
ntM
âist
ure
Ana
lyze
d:Ju
l-25-
0318
:56
Jul-2
5-03
18:5
8Ju
l-25-
0319
:00
Jul-
25-0
319
:02
UIL
cIR
L-
%R
L%
RL
%R
L%
ELPe
rcen
tMoi
stur
e11
.51.
0011
.01.
006.
591.
0019
.21,
00SV
O.A
sby
EPA
8270
CE
xtru
ded:
Jul-2
8-03
10:5
1Ju
l-28-
0310
:54
Jul-2
8-03
10:5
7Ju
l-28
-03
11:0
0Ju
l-29
-03
10:1
5Ju
l-29
-03
10:2
0A
naly
zed:
Aug
-07-
0301
:04
Aug
-07-
0300
:12
Aug
-06-
0323
20A
ug-0
6-03
22:2
7A
ug-0
2-03
00:1
4A
ug-0
2-03
01:0
7U
nIEs
JRL-
mg/
kgR
Lm
g/kg
EL
mgl
lcg
RI
mg/
kgR
Im
g/L
ELm
g/L
ELA
cena
phth
enc
DEl
..0.
188
DR
L0.
187
ORL
0.17
8B
RL
0206
BR
L0.
005
JB
RL
0.00
5A
cena
phth
ylen
eB
IlL0.
188
DEL
0.18
7B
RL
0.17
8B
RL
0206
BR
L0.
005
JB
RL
0.00
5A
nthr
acen
eB
RL
0.18
8B
IlL
0.18
7B
IlL
0.17
8B
RL
0206
BIl
L0.
005
BIl
L0.
005
Bsn
zo(a
)ant
hrac
cnD
EL0.
188
BIlL
0.18
7D
IlL0.
170
BR
L0.
206
BR
L0.
005
BR
L0.
005
Bcr
izo(
a)py
renc
DEL
0.18
8B
IlL0.
187
OR
L0.
178
BIl
L02
06B
IlL
DM05
BR
L0.
005
b)f
Iuora
nth
pie
BIlL
0.18
8B
IlL0.
187
ORL
0.17
8B
RL
0.20
6B
IlL
0.00
5B
IlL
0,00
5B
enzo
(g,h
,i)pc
ryle
eeB
IlL0.
188
BR
L0.
187
DIlL
0.17
0B
IlL
0.20
6B
IlL
0.00
5B
RL
0.00
5B
enzo
(k)f
luor
anth
me
BIlL
0.18
8B
IlL
0.18
7B
IlL
0.17
8B
IlL
0.20
6B
RL
0.00
5B
IlL
0.00
5C
hrys
ene
BIlL
0.18
8B
IlL
0.18
7B
IlL0.
178
BIl
L0.
206
BIl
L0.
005
BR
L0.
005
Dib
enz(
a,h)
Ant
hrae
ene
BR!..
0.18
8B
RL
0.18
7B
IlL0.
178
BIl
L0.
205
BIl
L0.
005
ER
L00
05Fl
uora
nthe
neB
IlL
0.18
8BR
.L0.
187
BIl
L0.
178
BIl
L0.
206
BIl
L0.
005
BIl
L00
05Fl
uore
neD
EL0.
188
BIl
L0.
187
ERL
0.17
8B
IlL
0.20
6B
IlL
0.00
5B
R!..
0005
Inde
no(1
,Z3-
c,d)
Pren
eB
IlL0.
188
BIl
L0.
187
BIlL
0.17
8B
IlL
0205
BIl
L0.
005
BIl
L0.
005
Nap
htlia
lene
DIlL
0.18
8B
RL
0.18
7-
DIlL
0.17
8B
IlL
0.20
6B
IlL
DM05
BIl
L00
05.P
hena
nthr
ene
BIlL
0.18
8B
IlL
0.18
7B
RL
0.17
8B
RL
0.20
6B
IlL
0.00
5B
IlL
0.00
5Py
rene
BIlL
0.18
8B
RL
0.18
7ER
L0.
178
BR
L02
06B
R!..
0.00
5B
IlL
0.00
5
Bre
ntB
airo
nL
abor
atot
yM
anag
er
l3at
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e:12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
XE
NC
OL
aboro
tore
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctId
:P
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
yC
onta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atIo
n:G
rena
da,
Mis
siss
ippi
Lu
bId
2356
51-0
1323
5651
-014
2356
51-0
1523
5651
-016
2356
51-0
1723
5651
-018
Fie
ldId
:3T
h(-IC
P-SS
-113
7-0!
3TM
-KP.
SS-l
137-
023T
M-1
C1’-S
S-68
8-0!
3TM
-XP-
SS-6
88-0
23T
h(-K
P-Eq
uipm
ent R
inse
3Th-
KP-
Ficl
dB
lai*
Ana
lysi
sR
eque
sted
Dep
th:
61n
61n
tin
61n
Inft
Maf
rx.
SOIL
SOIL
SOIL
SOIL
WA
TE
RW
AT
ER
Sam
pled
:Ju
l-23-
0314
:40
Jul-2
3-03
14:5
0Ju
l-23-
0316
:50
Jul-
23-0
317
:00
Jul-2
4—03
08:5
0Ju
l-24
-03
08:5
5V
OA
sby
SW-8
4682
60B
Ext
ract
ed:
Aug
-05-
0316
:19
Aug
-05-
0316
:21
Aug
-05-
0316
:23
Aug
-05-
0316
:25
Ana
lyze
d:A
ug-0
5-03
18:0
7A
ug-0
5-03
1828
Ang
-O5-
0318
:50
Aug
-05-
0319
:12
Unl
iziR
L:
mg/
kgRI
..m
g/kg
Ri..
mg/
kgR
Im
g/kg
RLB
cnze
neB
RL
0.00
6BR
.L0.
006
BR
L0.
005
JB
RL
0.00
6L
Bro
mob
enzc
neBR
]..0.
006
BR!..
0.00
6B
R!.
.__o
.oo5
TB
RL
0.00
6B
rom
ochi
orom
etha
neBR
]..00
06BR
!..0.
006
BR
L0.
005
BR
L0.
006
Bro
mod
ichl
orom
etlia
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
5B
RL
0.00
6B
rom
ofom
iB
EL0.
006
BR
L0.
006
BR!..
0.00
5B
RL
0.00
6B
roni
omet
hane
BEL
0.00
6B
ilL0.
006
BR
L0.
005
JB
RL
0.00
6M
TBE
BR
L0.
006
BilL
0.00
6B
RL
O.0
O5J
BR
L0.
006
tert
-But
ylbe
nzen
eB
IlL
0.00
6B
RL
0.00
6B
RL
0.00
5B
RL
0.00
6Sc
c-B
utyl
benz
ene
BilL
0.00
6B
ilL0.
006
BilL
0.00
5B
RL
0.00
6n-
But
ylbc
nzcn
eB
IlL0.
006
BilL
0.00
6B
RL
0.00
5B
ilL0.
006
Car
bon
Tet
rach
iori
deB
IlL0.
006
BilL
0.00
6B
ilL0.
005
BR.L
0.00
6C
hlor
oben
zene
BIlL
0.00
6BR
.L0.
006
BilL
0.00
5B
ilL0.
006
Chl
oroe
than
cB
ilL0.
011
BilL
0.01
1B
ilL0
Oil
BilL
0.01
2C
hlor
ofor
mL
BilL
0.00
6B
IlL0.
006
BilL
0.00
5B
ilL0.
005
Chl
oron
ieth
ane
BilL
0.0]
]B
IlL0.
011
BilL
0.01
1B
ilL0.
012
2-C
hior
otol
uenc
BR
L0.
006
BIlL
0.00
6B
ilL0.
005
BilL
0.00
54-
Chl
orot
olue
ncB
ilL0.
006
BIlL
0.00
6ER
L0.
005
BR
L0.
006
p-C
ymen
c(p-
lsop
rspy
ltolu
ene)
BilL
0.00
6B
IlL0.
006
Bill
.0.
005
BR
L0.
005
l,2-D
ibro
mo-
3-C
hbro
prop
ane
BilL
0.00
6B
ilL0.0
06B
ilL0.
005
BR
L0.
006
Dib
roni
ochi
orom
etha
neB
ilL0.
006
BR
L0.
006
BilL
0.00
5B
ilL0.
006
Dib
rom
omet
hanc
BR
L0.
006
BIlL
0006
BilL
0.00
5B
ilL0.
006
l,2-D
ichl
orob
enze
acBR
]..0.
006
BIlL
0.00
6B
ilL0.
005
BR
L0.
006
-—
1,3-
Dic
hlor
oben
zcec
BilL
0.00
6B
RL
0.00
6B
ilL0.
005
BR
L0.
006
1,4-
Dic
hlor
oben
zcae
BilL
0.00
6BR
I.0.
006
BilL
0.005
BilL
0.00
6D
ichl
orod
itluo
rom
ttlia
neB
ilL0.
006
BR!..
0.00
6ER
L0.
005
BilL
0.00
6lt
d.
aa.l
ical
ropo
rt,ai
dth
eaim
. dat
ap
.ásm
r.eem
ij.b
abe
enm
ode
bryo
urai
dual
vean
dco
efid
entid
OIL
The
intu
prnt
.dnn
sm
drn
mN
aenp
rnsa
edth
rout
hout
thu.e
etyt
uai
r.p.m
repo
uent
the
bem
tadg
moo
tofC
OLm
bora
Lo,tI
LX
EN
CO
Lab
orat
oden
amai
mes
nora
ipom
oibi
ltuan
d.m
ak..
noam
nly
toll
....d
ui.
oflit
.da
tabi
raby
pres
meu
tO
urtu
btut
yI,
timiti
dto
the
amou
ntIn
voic
edfa
rthi
nw
ork
d.r.m
Ioon
athen
a.ag
reed
toI.
nntti
ng.
Sinc
e19
90fl
ousl
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-T
ampa
-M
iam
i -La
tinA
mer
ica
rent
Bar
ron
Lab
orat
ory
Man
ager
Page
10
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
yD
ate
Rec
ehre
dIn
Lab
:F
riJu
l-25
-03
10:3
0am
Rep
ort
Dat
e:12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
Lab
ld:
2356
51-0
1323
5651
-014
2356
51-0
1523
5651
-016
2356
51-0
1723
5651
-018
FkJ
dId.
3TM
-IG’-S
S-I 1
37.0
13T
M-K
P.SS
-113
7-02
3TM
-XP-
SS-6
88-0
13T
M-K
P-SS
-688
-02
3M-K
P-Eq
uipm
ene
Rim
e3T
M-K
P-r:o
ldBi
onic
Ana
lysi
sR
equ&
edl)
epth
:6
In6
In6
In6
InIn
ftM
afti
r.SO
IL)I
LSO
ILSO
ILW
AT
ER
WA
TE
RSa
mpl
ed:
Jul-2
3-03
14:4
0Je
el-2
3.03
14:5
0Ju
l-23-
0316
:50
Jul-
23-0
317
:00
Jul-
24-0
308
:50
Jul-
24-0
308
:55
VO
As
bySW
-846
8260
13F.
xfra
cfed
Aug
-05-
0316
:19
Aug
-05-
031&
21A
ug-0
5-03
16:2
3A
ug-0
5-03
1625
Ana
lyze
d:A
ug-0
5-03
18:0
7A
ug-0
5-03
18:2
9A
ug-0
5-03
18:5
0A
ug-0
5-03
19:1
2U
nIte
JRL
mg/
kgR
I.m
g/kg
IlL
mg/
kgIlL
mg/
kgRL
[,2-D
icbl
oroe
than
eB
RL
0.00
6B
RL
0.00
6SR
I.0.
005
BR
]..0.
006
1j-D
ichl
oroe
than
eSR
I.0.
006
BR
I.0.
006
SRL
0.00
5S
RI.
0.00
6tm
ns-1
,2-d
1chI
oro1
iene
BIlL
0.00
6SR
I.0.
006
SRI.
0.00
5S
RI.
0.00
6ci
s-1,
2-D
ichl
oroc
then
cBR
]..0.
006
BR
L0.
006
SRI.
0.00
5B
RL
0.00
61,
1-D
ichl
oroe
then
oSR
I.0.
006
BIlL
0.00
6SI
lL0.
005
BR
L0.
006
2,2.
Dic
hlor
opro
pone
BIlL
0.00
6B
RI.
0.00
6SR
I.0.
005
BR
L0.
006
13-D
ichl
orop
ropa
ecB
IlL0.
006
SRI.
0.00
6ER
L0.
003
BIl
L0.
006
1,2-
Dic
hior
opro
pane
BIlL
0.00
6B
IlL0.
006
ERL
0,00
5B
RL
0.00
6
-_____________
tran
s-l,3
-dic
hlor
opc,
pcne
BR
L0.
006
BR]..
0.00
6B
IlL0.
003
BIl
L0.
006
1.1-
Dic
hlor
opro
peec
BIlL
0.00
6SR
I..0.
006
SRI.
0.00
5B
IlL
0.00
6ci
s-l,3
-Dic
hlor
opro
penc
SRI.
0.00
6B
IlL0.
006
BIlL
0.00
5B
IlL
0.00
6E
thyl
benz
ene
BR
L0.
006
BIlL
0.00
6SR
I.0.
005
8111
.0.
006
Hex
acitl
orob
utad
leac
BIlL
0.00
6SR
I.0.
006
BR
L0,
005
BR
L0.
006
isop
ropy
lbcn
zcne
BIlL
0.00
6B
IlL0.
006
BIlL
0.00
5B
IlL
0.00
6—
-—
Met
hyle
neC
hlor
ide
SRI.
0.02
3B
IlL0.
022
BIl
L0.
023
BIl
L0.
025
--
Nap
htha
lcne
BR].,
0.01
1SR
I.0.
011
SIlL
0.01
1B
IlL
0.01
2n-
Pmop
ylbe
nzen
eB
IlL0.
006
-B
IlL0.
006
BIlL
0.00
5B
RL
0.00
6St
yrcn
eB
IlL0.
006
SIlL
0.00
6SR
I.0.
003
BR
L0.
006
1.1,
1,2-
Teh
achl
orce
than
eB
IlL0.
006
BIlL
0.00
6SR
I.0.
005
BIl
L0.
006
1.1,
2,2-
Tet
rach
loro
etha
neB
IlL0.
006
BIlL
0.00
6B
IlL0.
005
BIl
L0.
006
Tet
rach
ioro
ethy
lene
BR
L0.
006
BIlL
0.00
6B
IlL0.
005
BIl
L0.
006
Tolu
ene
SRI.
0.00
6SI
lL0.
006
ERL
0.00
5B
IlL
0.00
6t,2
,4-T
rich
loro
benz
eno
BIl
L0.
006
BIl
L0.
006
BIl
L0.
005
BIl
L0.
006
12,3
-Tric
hlom
bent
ene
RL
0.00
6SI
lL0.
006
BIlL
0.00
3B
RL
0.00
61,
1,2-
Tri
chlo
roet
henc
BIl
L0.
006
SRL
0.00
6B
IlL0.
005
BIl
L0.
006
XE
NC
Otc
kbor
c%L
oric
s
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,M
issi
ssip
pi
Thin
.o.t
lcal
repo
on.e
ndtin
. ent
irede
e.po
ckeg
eit r
epre
ennd
s,kn
t kno
t ore
dehr
yreo
r cck
etiy
.and
eneS
dont
ides
Tho
totn
opre
tatio
men
dre
oolti
tnpn
oeeo
lth
roah
oet
thin
eeel
yden
lro
per?
repr
eete
t the
beatj
ned
8mnrnt
efC
Oi.
.boro
ton3
XE
NC
Oeb
orot
odee
etee
mne
ore
poos
ihili
tyno
doo
eke.
no.x
mnt
ylo
the
e,d
flee
ofth
eda
tohe
emky
poom
eend
.O
tor t
iohi
lity
Iilim
ited
toth
em
ount
kwoi
red
Err I
N.w
ork
ord.
runb
noot
heeo
4n. i
groe
dto
inw
nitk
oSi
nce
1990
Hou
sion
-D
alla
s-
San
Ant
onio
-A
ustin
-Tam
pa-
Mia
mi
-La
tinA
mer
ica
tZ
nL
abora
toiy
Man
ager
Page
II
XEN
CO
Lc6
orc
Lorc
s
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da. M
issi
ssip
pi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Dat
eR
ecei
ved
InL
ab:
Fri
Jul-
25-0
310
:30
amR
epo
rtD
ate:
12-A
UG
-03
Pro
ject
Man
ager
:K
aren
Ols
onL
abId
:23
5651
-013
2356
51-0
1423
5651
-015
2356
51-0
1623
5651
-017
2356
51-0
18•
Fl e
ldId
:3T
M-I
CP-
SS-1
137-
el3T
h4-K
P-SS
-l13
7-02
3Th4
-KF$
s-68
8-0l
3TM
-IC
P-SS
-680
-02
3TM
-IC
P-E
quip
men
tR
i-ac
3TM
-XP-
FeL
dB
ledc
Ana
lysi
sR
eque
sted
Dep
th:
6In
6In
6In
6In
Inft
Maf
rlx
SOIL
SOIL
SOIL
SOIL
WA
TER
WA
TE
RSa
mpl
ed:
Jul-2
3-03
14:4
0Ju
l-23-
0314
:50
Jul-2
3-03
1630
Jul-
23-0
317
:00
Jul-
24-0
308
30Ju
l-24
-03
08:5
5V
OA
sby
SW—
846
82O
BE
xtra
cted
:A
ug-0
5-03
16:1
9A
ug-0
5-03
16:2
1A
ug-0
5-03
16:2
3A
ug-0
5-03
16:2
5A
naly
zed:
Aug
-05-
0318
:07
Aug
-05-
0318
:28
Aug
-OS-
0318
:50
Aug
-05-
0319
:12
Unl
Lc,
iL:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Im
g/kg
RL
I,1,1
-Tri
chlo
met
hane
BIlL
0.00
6BR
L0.
006
L0.
005
BR
L0.
006
Tri
chlo
roct
hene
BR
L0.
006
BR
L0.
006
BR
L0.
005
BR
L0.
006
Tri
chlo
rofl
uoro
met
ane
BIlL
0.00
6B
RL
0.00
6B
RL
0.00
5B
RL
0.00
61,
2.3-
Tri
ch1o
ropr
oane
BIl
L0.
006
BR
L0.
006
BR
L0.
005
BIl
L0.
006
1,2,
4-T
rini
ethy
lbcn
zene
BilL
0.00
6B
RL
0.00
6B
R!.
0.00
5B
ilL0,
006
1,3,
5-tr
imet
hylb
enne
BIlL
OA)0
6B
RL
0.00
6B
RL
0005
BR
L0.
006
Vin
ylC
hlor
ide
[B
IlL0.
002
BR
L0.
002
BIl
L00
02B
RL
0.00
!o-
Xyl
neB
IlL0.
006
BR
L0.
006
BIlL
0.00
5B
RL
0.00
6m
,p-X
ylen
esL
BIlL
0.01
1B
IlL0.
011
BIlL
0.01
1B
IlL
0.01
!
moo.t
oI
repo
rt..
edth
eo.
tlre
dolt
p.e
ke
Itre
p.o.
e,ts
.hoe
boe.
inod
efh
ryo.
r ecI
ooin
een
dconid
endw
The
hacp.t
Iool
and
rnm
ib.tp
enas
odtI
lro.
4hoo
tthI
no.
oIyt
Itai
repo
nro
pro
tth
ebo
atju
dm
eof
XEN
CO
Lab
orat
orie
.X
EN
CO
Lah
orite
tIno
untm
no
ron,a
fld
7an
dm
ake.
no‘n
nlne
yto
the
e.d
noa
ofth
edot
aboo
rby
ce.n
otol
.
Bar
ron
Ott
liabi
lity
InlIm
bed
toIh
een
e.o0
j,wol
cod
fort
hl, w
o.*
ordu
nIee
.otb
erw
ioag
reed
to1..
wnt
cbtg
.Si
nce
1990
Hou
strn
-D
alla
s.Sa
nA
nton
b-
Aus
tin-
Tam
pa-
Mia
mi
-La
tinA
mer
ica
Page
12L
abor
atoo
yM
anag
er
Proj
ect I
d:
Con
tact
:R
nndyH
oak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Pag
el3
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
iona
l,H
oust
on,T
X
XE
NC
O
______
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Facil
ity
Dat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e:12
-AU
G-0
3P
roje
ctM
anag
er:
Kar
enO
lson
.
Lab
Id;
2356
51-0
1923
5651
-020
2356
51-0
2123
5631
-022
2356
51.0
2323
5651
-024
•.F
7eW
Id3T
h1-K
P-SS
-5-O
13T
h1-K
P-SS
-5-0
23T
M-K
P-SS
-5-0
33T
M-K
P-O
-5-0
13T
M-K
P-SS
-444
13T
M-K
Y-S
S-44
-02
:A
naiy
sos
Req
uef
edD
epth
:6
In6
In6
in6
In6
InM
afri
xSO
IL)I
LSO
ILSO
ILSO
Il.
SOIL
Sam
ple&
Jul-2
4-03
09:5
0Ju
l-24.
0310
:00
Jul-2
4-03
10:1
5Ju
l-24
-03
10:2
0Ju
l-24
-03
10:3
5Ju
l-24
-03
10:4
5Pe
rcen
tMotu
reE
.irac
ted:
.
Ana
lyze
d:Ju
I-25
.03
19:0
4Ju
l-25.
0319
:06
Jul-
2-03
19:0
8Ju
l-25
-03
19:1
0Ju
l-25
-03
19:1
6Ju
l-25
-03
19:1
2U
nIW
1L:
%R
L%
RL
%R
L%
RL
¾IlL
%IlL
Perc
ànt M
oist
ure
5.56
1.00
5.77
1.00
12.1
1.00
13.2
1.00
19.1
1.00
16.6
1.00
SVO
As
byE
PA82
70C
Jul-3
0-03
09:3
9Ju
l-30-
0309
:42
Jul-3
0-03
09:4
5Ju
l-30
-03
09:4
8Ju
l-30
-03
09:5
1Ju
l-30
-03
09:5
4A
naly
zed:
Aug
-07-
0313
:42
Aug
-01-
0315
:41
Aug
-07-
0316
:45
Aug
-12-
0304
34A
ug-0
8-03
21:1
0A
ug-0
8-03
23:4
3U
nIW
RL
:m
g/kg
RL
mg/
kgR
Lm
gJl
RI
mg/
kgR
Lm
g/kg
IlLm
g/kg
RI.
Ace
naph
tl,en
eB
RL
0.17
6B
IlL0.
177
RR
L0.
190
BIl
L1.
15B
IlL
0.20
6B
IlL
0199
Acc
naph
thyl
ene
BIlL
0.17
6B
IlL
0.17
7BR
.L0.
190
BIl
L1.
15B
R].
0.20
6B
IlL
0.19
9A
nthr
acen
eB
IlL0.
176
BIlL
0.17
7B
R].
0.19
0B
R].
1.15
BR
L0.
206
BIl
L0.
199
Bcn
zo(s
)ant
hrac
enc
BIlL
0.17
6B
RL
0.17
7B
RL
0.19
0B
IlL
1.15
BIl
L0.
206
BIl
L0.
199
Bcn
zd(a
)pyr
cnc
BIlL
0.17
6B
IlL0.
177
BIlL
0.19
0U
RL
1.15
BR
L02
06B
RL
0.19
9&
ns,(
b)fl
uora
nthc
neD
IlL0,
176
BIlL
0.17
7B
RL
0.19
0B
RL
1.15
BR
]..0.
206
BR
].0.
199
Bcn
zo(g
.h,fl
pcry
leae
BR]..
0.17
6B
RL
0.17
7B
R].
,0.
190
BIl
L1.
15B
IlL
0.20
6B
IlL
0.19
9nz(
k)f
luora
nth
me
BR
].0.
176
BR
].0.
177
BR
L0.
190
BR
L1.
15B
RL
0.20
6B
IlL
0.19
9C
lnys
çne
BIl
L0.
176
BIlL
0.17
7B
RL
0.19
0B
IlL
1.15
BIl
L02
06B
RL
0,19
9D
iben
aJi)
Ant
hrac
cne
BIl
l.0.
176
BR
L0.
177
BR
].0.
190
BR
L1.
15B
R].
0.20
6B
IlL
0.19
9Fl
üora
nthe
neB
IlL0.
176
BR
L0.
177
BR
L0.
190
BR
L1.
15B
R].
0.20
6B
IlL
0.19
9Fl
uore
neB
Ill.
0.17
6B
IlL0.
177
BIlL
0.19
0B
IlL
1.15
Bil
L02
06B
IlL
0.19
9In
deno
(l,2
,3-c
,d)P
7ren
eB
R].
0.17
6B
R].
0.17
7B
ilL0.
190
BR
]..1.
15B
R].
0206
Bil
L0.
199
Nap
htlia
lcnc
BR
].0.
176
BIlL
0.17
7B
IlL0.
190
BilL
1.15
BR
].0.
206
BR
L0.
199
Phen
anth
rene
BR].,
0.17
6B
IlL0.
177
BIlL
0.19
0B
R].
1.15
BR
].0.
206
BR
].0.
199
Pyre
neB
R].
0.17
6B
R].
0.17
7B
IlL0.
190
BIl
L1.
15B
IlL
0206
BIl
L0.
199
The
enei
ytle
dre
poet
ted
the
.ñtir
edet
epeo
kie
itte
i,ees
ente
hubo
com
edel
bryo
urae
heel
y.an
dto
nfid
eeth
i ue
The
hete
tpre
tntle
otte
dre
mdt
opra
nare
ldm
ouho
eldd
eea
njyt
hal
eopo
elre
eim
eth
ebe
etju
dsom
oter
XB
24C
OZ
abo,
atot
i‘C
ENC
0Le
bore
tmie
nen
amom
nopo
oe*5
ted
mak
eeoo
olna
nty
tothe
etdse
ecu
beda
tebe
rthyp
etoe
etto
d.O
urlie
toitt
yI,
Smile
dto
the
emou
ettI
nvoi
ced
fert
il,w
eek
erde
unic
eaci
tterm
lteie
eedte
hiw
dih
Sinc
e19
90H
ousb
,n-
Dal
las.
San
Ant
onb
-A
ustin
-Tam
pa-
Mia
mi -
Lat
inA
mer
ica
Bre
nt
Bar
ron
Lab
ora
tory
Man
ager
XEN
CO
Lab
orc6
tori
es
Pro
ject
16:
Conta
ct:
Ran
dyN
oraa
kP
roje
ctL
ocat
ion:
Gre
nada
,M
issi
ssip
pi
Cer
tific
ate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
I)at
eR
ece!
ved
InL
ab:
Fri
Jul-2
5-03
10:3
0am
Rep
ort
Dat
e:12
-AU
G-0
3P
role
ctM
anae
er:
Kar
enO
lson
Lab
Id:
2356
5141
923
5651
-020
2356
51-0
2123
5651
-022
2356
51-0
2323
5651
-024
F7eI
dId:
3Th1
-KP-
SS-5
-Ol
3TM
-KP-
SS-5
-02
3TM
-KP-
SS-5
-03
3TM
-KP-
G-5
-01
3TM
-KP-
SS-4
4-0
3TM
-IC
P-SS
-44-
02
Ana
lysi
sR
eque
sted
Dep
th:
6In
6In
6In
6In
6In
Maf
rlx
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
Sam
pled
:Ju
l-24-
0309
:50
Jul-2
4-()
310
:00
Jul-2
4-03
10:1
5Ju
l-24
-03
1020
Jul-
24-0
310
:35
Jul-
24-0
310
:45
VO
As
bysw
-846
8260
J]E
xtra
cted
:A
ug-0
6-03
13:0
5A
ug-0
5-03
16:2
9A
ug-0
4-03
16:1
2A
ug-0
5-03
1&27
Aug
-05-
0316
:31
Aug
-05-
0316
:33
Ana
lyze
d:A
ug-0
6-03
14:0
9A
ug-0
5-03
19:5
5A
ug-0
4-03
18:5
5A
ug-0
5-03
19:3
3A
ug-0
5-03
20:1
6A
ug-0
5-03
20:3
7U
nIr4
fLm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
I.m
g/kg
ELm
g/kg
RL
Ben
zenc
BR
L0.
005
ERL
0.00
5ER
L0.
006
ER
L0.
029
BR
L0.
006
BR
L0.
006
Bro
mob
enzc
ncB
IlL0.
005
BIlL
0.00
5B
RL
0.00
6B
RL
0.02
9B
R]..
0.00
6B
RL
0.00
6B
rom
oebl
orom
etba
neB
IlL
0.00
5B
IlL0.
005
EE
L0.
006
BR
L0.
029
BR
L0.
006
BR
L0.
006
Bm
mod
ichl
orom
ctha
neB
IlL00
05B
RL
0.00
5B
RL
0.00
6O
RL
0.02
9E
EL
0.00
6B
RL
0.00
6B
rom
ofon
nB
RL
0.00
5—
BR
L0.
005
BIlL
0.00
6U
RL
0.02
9B
RL
0.00
6B
IlL
0.00
6B
rom
omet
hane
BIlL
0.00
5B
IlL0.
005
EE
L0.
006
BR
L0.
029
BR
L0.
006
BR
L0.
006
MTB
EB
IlL0.
005
BIl
L__
0.00
5_-J
EE
L0.
006
BR
L0.
029
BR
I.0.
006
BIl
L0.
006
tert
-But
ylbe
nzcn
cB
IlL
0.00
5B
IlL0.
005
EE
L0.
006
BR
L0.
029
EE
L0.
006
BR
L0.
006
Scc-
Bul
ylbe
nzen
eBR
]..0.
005
BIlL
0.00
5B
IlL0.
006
BR
L0.
029
BR
]..0.
006
BR
L0.
006
n-B
utyl
benz
ene
BIlL
0.00
5B
RL
0.00
5B
RL
0.00
6B
R!.
0.02
9B
RL
0.00
6BR
L.0.
006
Car
bon
Teu
nchi
orid
eB
IlL0.
005
BIll
..0.
005
EEL
0.00
6B
RL
0.02
9B
IlL
0.00
6B
RL
0.00
6C
hlor
oben
zene
BIlL
0.00
5B
IlL0.
005
ERL
0.00
6B
IlL
0.02
9B
IlL
0.00
6B
RL
0.00
6C
hlor
oeth
ane
BIl
L0.
011
BIlL
0.01
!B
IlL0.
011
BR
L0.
058
BR
!.00
12B
IlL
0.01
2C
hlor
ofbr
mB
IlL0.
005
BIlL
0.00
5B
IlL0.
006
BR
!.(0
29B
IlL
0.00
6L
BIl
L0,
006
Chl
orom
etha
neB
IlL0.
011
BR
L0.
011
EE
L0.
011
BR
L0.
050
EE
L0.
012
BR
]..0.
012
2-C
hior
otol
uene
BIl
l.0.
005
SIlL
0.00
5B
IlL0.
006
BR
L0.
029
EE
L0.
006
BIl
L0.
006
4-C
hlor
otol
uenc
BIlL
0.00
5B
IlL0.
005
BR
!.0.
006
BR
L0.
029
BR
!..0.
006
BIl
L00
06p-
Cyn
iene
(p-T
sopr
opyl
tolu
ene)
JB
RL
0.00
5B
IlL0.
005
EEL
0.00
6E
EL
0.02
?B
R!.
0.00
6B
IlL
0006
1,2-
Dib
rom
o-3-
Chb
ropr
opan
eI
BIlL
0.00
5B
R!.
0.00
5B
IlL0.
006
BR
L0.
029
EE
L0.
006
BR.L
000
6D
ibm
moc
blor
omet
hane
BIlL
0.00
5B
IlL0.
005
BIlL
0.00
6B
IlL
0.02
?B
IlL
0.00
6B
IlL
0006
Dib
rom
omet
hanc
BR
L0.
005
BIlL
0.00
5B
IlL00
06B
IlL
0.02
9B
IlL
0.00
6B
RL
0.00
61,
2-D
ichl
orob
enze
aoB
R!.
0.00
5B
IlL0.
005
EEL
0.00
6B
RL
0.02
9B
R!.
0.00
6B
IlL
0006
1,3-
Dic
hlor
obcn
zcae
BIlL
0.00
5B
IlL0.
005
ER
!.0.
006
BIl
L0.
029
BIl
L0.
006
BR
!.0.
006
1,4-
Dic
hlor
obcn
zcae
BRL
0,00
5BR
L0.
005
BR!.
0.00
6BI
lL0.0
29B
R!.
0.00
6E
EL
0006
Dic
hlor
odif
luor
omct
hanc
BIlL
0.00
5E
EL
0.00
5E
EL
0.00
6BR
]..0.
029
BR
!.0.
006
BIl
L0.
006
Tide
.o.I
ytlm
Ire
port
, .nd
the
ettf
rodo
tep.c
k.
Itre
ptue
uot..
h..b
ootm
ed.t
bryo
urud
utit
emrd
fido
ttilt
use.
The
heer
ptud
otoo
aan
dpo
uted
ihsta
nt
thiti
.nit
ea1
repo
rtrq
woe
uti t
hebuti
dgm
eoto
fXE
NC
OL
iboo
ttori
es.
XE
NC
OL
ebur
elor
ian
.s,r
mm
oor
,utn
ltulit
,en
dm
akot
ooan
*M
yto
the
md
use
ofrh
odo
t.)o
teth
ypre
sottt
d.O
arIl.
bflh
tyle
limite
dto
the
m.o
uu(
iiw
ked
f.rth
!,w
ork
onkr
ante
.,ot
heov
.tto
.Ve.
dto
k,w
rlti
n
Baro
n
Sinc
e19
90H
ousl
on-
Dal
las
-Sa
nA
nton
k-
Aus
tin-T
ampa
-M
iam
i -La
tinA
mer
ica
Pags
14
Lab
orat
oiy
Man
ager
Thin
enel
ytie
niee
pot
end
the
toth
. dot
epn
ckte
Iirn
pre
w,u
,hu
been
wid
ebe
yone
.ndr
nlon
end
eool
idon
tidw
11w
Inin
eyrn
ialio
nean
drn
enits
espr
neee
dth
ront
)oul
this
anily
licel
repo
rt,ep
ttoen
t the
bnet
dnon
tof X
ENC
O.o
boea
tade
a.X
E14C
OL
thom
taci
coam
muno
roap
on.I
bilir
and
mak
e.no
wan
tonl
yto
the
erd
use
a(th
edo
t.Ir
nedr
yps
nsen
insi
One
lIab
ilit
y.lin
dtad
toth
ean
otrn
tlmw
lced
far t
his
woe
koa
dwun
l.ea
nthe
nwb.
aim
edto
lnw
rith
ii.Si
nce
1990
Hou
ston
-D
alla
s-Sa
nA
nton
io-
Aus
tin-T
ampa
-M
iam
i-La
tinA
mer
ica
XEN
CO
Lth
erø
ori
cs
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctId
:P
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
yC
onta
ct:
Ran
dyH
orsa
kP
roje
ctL
ocat
ion:
Gre
nada
,M
issi
ssip
piD
ate
Rec
eive
din
Lab
:Fr
iJu
l-25
-03
10:3
0am
Rep
ort
Dat
e:12
-AU
G-0
3P
roje
ctM
anag
er;
Kar
enO
lson
Lab
Id:
2356
51-0
1923
5651
-020
2356
51-0
2123
5651
-022
2356
51-0
2323
5651
-024
•Fi
eld
id:
3TM
-IC
P-SS
-5-0
l3T
M-K
P-SS
-5-0
23T
M-K
P-SS
-5.0
33T
M-K
P-C
I-5-
013T
M-K
P-SS
-44-
OI
3TM
-KP-
SS-4
4-G
2A
naly
sis
Req
uesE
edD
epth
:6
In6
In6
in6
In6
InM
atri
x:SO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Jul-2
4-03
09:5
0ju
l-24
-03
10:0
0Ju
l-24-
0310
:15
Jul-
24-0
310
:20
Jul-
24-0
310
:35
Jul-
24-0
310
:45
VO
As
byS
w-8
4682
60F
E.x
t,aet
ed:
Aug
-06-
0313
:05
Aug
-05-
0316
:29
Aug
-04-
0316
:12
Aug
-05-
0316
27A
ug-0
5-03
16.3
1A
ug-0
5-03
16:3
3A
naly
zed:
Aug
-06-
0314
:09
Aug
-05-
0319
:55
Aug
-04-
0318
:55
Aug
-05-
0319
:33
Aug
-05-
0320
:16
Aug
-05-
0320
:37
Uni
tc’R
L:
mg/
kgR
Lm
g/kg
RL
mg/
Jig
ELm
g/kg
RLm
g/kg
ELm
g/kg
RL
1,2-
Dic
hlor
oeth
anc
BIlL
0.00
5B
RL
0.00
5B
RL
0.00
6E
EL
0.02
9B
RL
0.00
6B
RL
0.00
61,
1-D
ichl
oroe
than
eB
RL
0.00
5B
RL
0.00
5D
EL0.
006
I3R
L0.
029
EE
L0.
006
BR
!.0.
006
tran
s-I,2
-dlc
hlor
octh
ene
EE
L0.
005
BR
!.0.
005
DEL
0.00
6E
EL
0.02
9B
RL
0.00
6BR
.L00
06ci
s-l,2
-Dic
h1or
octln
cB
IlL0.
005
EE
L0.
005
DEL
0.00
6E
EL
0.02
9B
RL
0.00
6B
RL
0.00
6l,l
-Dic
hlor
oeth
e.ne
BE!
.0.
005
BR
L0.
005
BIlL
0.00
6E
EL
0.02
9E
RL
0.00
6B
R!.
0.00
62,
2-D
ichl
orop
ropa
ncB
IlL0.
005
BIlL
0.00
5D
EL0.
006
BR
L0.
029
BR
L0.
006
BR
L0.
006
1,3-
Dic
hlor
opro
pane
B1U.
.0.
005
BR
L0.
005
ER
!.0.
006
BR
L0.
029
ER
L0.
006
BIl
L00
061,
2-D
ichl
orop
ropa
tieB
IlL0.
005
BET.
.(1
005
BIlL
0.00
6E
RL
0.02
9B
IlL
0.00
6B
IlL
0006
tran
s-1,
3-di
chlo
rolx
open
eD
EL0.
005
BR
L0.
005
DEL
0.00
6D
EL
0.112
9E
RL
0.00
6D
ilL00
06l,l
-Dic
hlor
opro
pene
BIlL
0.00
5ER
L0.
005
DEL
0.00
6I3
RL
0.02
9B
IlL
0.00
6E
EL
0.00
6ci
s-1,
3-D
ichl
orop
rope
neB
IlL0.
005
EE
L0.
005
DIlL
0.00
6B
RL
0.02
9E
EL
(100
6E
RL
0006
Elh
ylbc
nzen
eB
R!.
0.00
5E
EL
0.00
5B
IlL0,
006
BIl
L0.
029
BR
L0.
006
BIl
L0,
006
Hex
achl
orob
utad
iene
BR
!.0.
005
BR
!.0.
005
ERL
0.00
6B
IlL
0.02
9B
IlL
0.00
6_L
BIl
L0.
006
Nap
htha
lene
BIlL
0.01
1E
EL
0.01
1B
IlL0.
011
BIl
L0.
058
BR
L0.0
12j
BIl
L0.
012
isop
ropy
lben
zenc
BIlL
0.00
5B
IlL0.
005
ERL
0.00
6B
ilL0.
029
BE
L0.
006
BIl
L0.
006
Met
hyle
neC
hlor
ide
BR
!.0.
021
DEL
0.02
1D
EL(1
023
0.19
2(1
116
0.03
00.
025
BIl
L0.
024
n-Pr
opyl
benz
ene
BIlL
0.00
5D
EL0.
005
BEL
0.00
6B
IlL
(102
9E
EL
0.00
6B
EL
1100
6St
yren
eB
RL
0.00
5B
IlL0.
005
BIlL
0006
DIl
L0.
029
BIl
L0.
006
BE
L0.
006
1,l,l
,2-T
etra
chlo
roet
bane
DEL
0.00
5B
IlL0.
005
BIlL
0.00
6B
R]..
0.02
9E
RL
0.00
6B
IlL
(100
6I,
I,2,
2-T
ctra
chlo
rcct
hane
BR
!.(1
005
BR
L0.
005
EE
L0.
006
BIl
L0.
029
BR
!.0.
006
DE
L0.
006
Tet
rach
loro
cthy
lcne
DEL
0.00
5B
RL
0.00
5B
IlL0.
006
BIl
L00
29B
IlL
0.00
6D
EL
(100
6T
olue
neB
IlL00
05B
IlL0.
005
BilL
(100
6B
IlL
0.02
9E
EL
0.00
6B
R!.
(100
6L
2.4-
Tri
chlo
robe
nzcn
eB
IlL0.
005
EE
L0.
005
BIlL
0006
DE
L0.
029
BE
L0.
006
BIl
L0.
006
1,2,
3-T
rich
loro
bcnz
cne
BIlL
0.005
BRL
0.005
BRL
0.006
BRL
0.02
9BR
!.0.
006
BIl
L(1
006
1,1,
2-T
rich
loro
etha
ncB
RL
0.00
5B
IlL0.
005
BR
!.0.
006
BIl
L.
0.029
_LB
R!.
0.00
6B
R!.
1100
6
Page
15L
abor
ator
yM
anag
er
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
iongi,
Hou
ston
,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
y
ml,
eeaiw
ite
poni
. ten
dth
een
tire
data
pec
bl.
Itre
peea
erat
hubo
wm
ode
bry
urc,
dath
-oen
doo
olid
ennt
idre
The
Ipr
etet
l000
and
rono
ltnot
tpne
ated
thnn
ubou
ath
iaen
ilyan
tire
peat
repe
osan
tthe
beit
Judm
onto
fXEN
CO
.ibo
nato
aIxaii
co
1.ab
onat
ocle
oas
ium
e,on
rnop
smib
huiy
and
mik
e,no
nonl
nty
toth
een
don
eof
lino
dii
ibm
n6ry
ptiit
ente
d.O
urlia
bilit
yI.
limite
dto
the
inan
e,hw
olce
dFm
thin
umtk
o,d.
rurd
cnn
athw
eha
agre
edto
m.a
itin
g.Si
nce
1990
Hou
ston
-D
alla
s.
San
Ant
onio
-A
ustin
-Tam
pa-
Mia
mi -
Lat
inA
mer
ica
Pngs
16
Dat
eR
ecei
ved
InL
ab:
Fri
Jul-
25-0
310
:30
amR
eport
Dat
e:12
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
on
-
Bre
ntB
arro
nL
abora
tory
Man
ager
XE
NC
OL
ceort
1orc
s
Pro
ject
Id:
Conta
ct:
Ran
dyH
orse
kP
roje
ctL
ocat
ion:
Gre
nada
,M
issi
ssip
pi
Lab
Id:
2356
31-0
1923
5651
.020
2356
51-0
2123
5651
-022
2356
51-0
2323
5651
-024
Flei
dIt
t3T
M-K
i’-SS
-5-0
13T
h4-K
l’-SS
-5-0
23T
M-K
P-SS
-5-0
33T
h1-K
P-(-
5-0l
3TM
-KP-
SS-4
4-01
3TM
-IC
P-SS
-44-
12A
na1
ys
Req
uest
edD
epth
:6
In6
Tn6
In6
In6
InM
atrL
nSO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Jul-2
4-03
09:5
0Ju
l-24.
0310
:00
Jul-2
4-03
10:1
5Ju
l-24
-03
1020
Jul-
24-0
310
:35
Jul-
24-0
310
:45
VO
As
bysw
-846
8260
13E
xt,a
cte&
Aug
-06.
0313
:05
Aug
-05-
0316
:29
Aug
-04-
0316
:12
Aug
-05.
.03
1627
Aug
-05-
0316
31A
ug-0
5-03
16:3
2A
naly
zed:
Aug
-06-
0314
:09
Aug
-05-
0319
:55
Aug
-04-
0318
:55
Aug
-05-
0319
33A
ug-0
5-03
20:1
6A
ug-0
5-03
2037
Unl
WR
L.
mg/
kgR
Lm
g/kg
RL
mg/
kgR.
Lm
g/kg
Ri
mg/
kgp1
mg/
kgRL
l,l,1
-Tri
chlo
roet
hane
BR
L0.
005
BIlL
0.00
5B
IlL0.
006
BIl
L0.
029
BIl
L0.
006
BIl
l.0.
006
Tri
chio
roet
hene
BIlL
0.00
5B
RL
0.00
5B
IlL0.
006
BR
L0.
029
BIl
L0.
006
BIl
L0.
006
Tri
ehlo
rofl
uoru
met
hane
BR
L0.
005
BR
L0.
005
BR
L0.
006
BIl
L0.
029
BR
L0.
006
BIl
LO
.006
1,2,
3-T
rich
loro
prop
ane
BIlL
0.00
5B
RL
0.00
5B
IlL
0.00
6B
IlL
0.02
9B
RL
0.00
6B
IlL
0.00
61,
2,4-
Trim
ethy
lben
r.cnc
BIlL
0.00
5B
IlL0.
005
BR
L0.
006
BIl
L0.
029
BIl
L0.
006
BR
L0.
006
135-
trim
ethy
lben
200e
BIlL
0.00
5B
IlL0.
005
IIR
L0.
006
BIl
L0.
029
BIl
L0.
006
BIl
L0.
006
Vin
ylC
hlor
ide
BR
L0.
002
BIlL
0.00
2B
IlL0.
002
BR
L0.
012
BIl
L0.
002
BR
L0.
002
o-X
ylen
eBF
.L0.
005
BR
L0.
005
BIlL
0.00
6B
RL
0.02
9B
RL
0.00
6B
IlL
0.00
6m
,p-X
ylen
esB
IlL0.
011
BIlL
0.01
1ER
L0.
011
BR
L0.
053
BIl
L0.
012
BIl
L00
12
XE
NC
OL
nborc
iorc
s
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Luc
atlo
n:G
rena
da, M
issi
ssip
pi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctN
ame:
Kop
pers
Cre
osot
eFa
cilit
yD
ate
Rec
eive
dIn
Lab
:F
riJu
l-25
-03
10:3
0am
Rep
ort
Dat
e12
-AU
G-0
3
Pro
ject
Man
aeet
Kar
enO
lson
Lab
Id:
2356
51-0
25.
Fia
ldId
:D
uplic
ate
IA
naly
sts
Req
uest
edDe
pm:
Mat
rix.
SOIL
Sam
pled
:Ju
l-24-
1300
:00
Per
cent
Motu
reE
xUac
ted:
Ana
lyze
d:Ju
l-25-
0319
:20
:Jn
itvR
L:
%R
LtM
oist
ure
8.64
1.0
0
SVO
As
byE
PA82
70C
Ext
ract
ed:
Jul-3
0-03
09:5
7A
naly
zed:
Aug
-09-
0300
:34
tTni
tr/R
L:
mg/
ksR
LA
ccna
phth
ene
BR.L
0.18
2A
ccna
phth
ylen
eB
RL
0.18
2—
Ant
hrac
ene
BIlL
0.18
2B
enzo
(a)a
nthr
accn
eB
IlL0.
182
Ben
zo(a
)pyr
ene
BIlL
0.18
2B
cnzo
(b)f
iuor
anth
cnc
BR
L0.
182
Ben
zo(g
,h,l)
pery
leae
BIlL
0.18
2B
enzo
(k)f
luor
anth
ene
BIlL
0.18
2C
hrys
cne
BIlL
0.18
2D
iben
z(a,
h)A
nthr
acen
eB
IlL0.
182
Fluo
rant
hene
BR.L
0.18
2Fl
uort
neB
IlL0.
182
Inde
no(1
,2,3
-c.d
)Pyr
ene
BIlL
0.18
2N
npht
hale
neB
IlL0.
182
Phen
anth
rene
BIlL
0.18
2Py
rene
BIlL
0.18
2
Ths
anal
ilceJ
repo
,t.an
dth
e,n
tlre
data
pack
tpIt
repr
eaen
t.h
nabe
atm
ade
Itry
nur
encl
ujlw
end
nont
dent
idu
nT
bht
terp
retit
iont
and
rete
espe
mau
dth
roag
hoal
thin
ana)
yd
lrq
tort
tepe
eton
t(b
ebe
atju
dgm
ento
fXEP
1CO
tjbo
mto
,iet.
XE
NC
OL
ahoe
ttode
nan
nim
enno
retp
oeai
bflk
and
mak
nno
eam
eny
toth
em
dua
. nit
hada
taha
nby
pman
ned.
On,
ilebl
ihy
I.lim
ited
totim
amou
nttt
wot
red
ar
thit
enor
tcart
.,m
deta
othe
rwhe
agre
edto
aw
iltin
g.Si
nce
1990
Hou
ston
-D
alla
s-
San
Ant
ona
Aus
tin-T
ampa
-M
iam
i -La
tinA
mer
ica
Bre
nt
Bar
ron
Page
17
Lab
ora
toty
Man
ager
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3TM
Inte
rnat
ional
,H
oust
on,
TX
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Faci
lity
flat
eR
ecei
ved
inL
ab:
Fri
Jul-
25-0
310
:30
am
Rep
ort D
ate:
12-A
UG
-03
Pro
lect
Man
a2er
;K
aren
Ols
onL
abId
:23
561-
025
Ana
lysi
sR
eque
sted
Fie
ldId
:D
uplic
ate
1D
epth
:
Mat
rix:
SOIL
Sam
pled
:Ju
l-24-
0300
:00
VO
As
bySW
-846
8260
BE
xtra
cted
:A
ug-0
5-03
16:3
5
Ana
lyze
d:A
ug-0
5-03
20:5
9
V_________________________
_U
nIV
sIRL
:m
g/kg
RI
Ben
zcne
BR
L0.
005
-_
__
__
__
__
__
__
__
__
_
Bro
mob
enze
neB
RL
0.00
5B
rom
ochi
orom
etha
seS
RI
0.00
5B
rom
odic
hlor
omet
lran
eV
BilL
0.00
5B
rom
ofor
mB
ilL0.
005
Bro
mom
etha
neB
RL
0.00
5M
TB
EB
ilL0.
005
tert
-But
ylbe
nzcn
cB
ilL0.
005
Scc-
But
ylbe
nzen
eB
ilL0.
005
n-B
utyl
bcnz
ene
BilL
0.00
5—
Car
bon
Tet
rach
iori
deB
ilL0.
005
roh
en
zcn
eB
ilL0.
005
Chi
oroe
than
eB
ilLö
iTC
hlor
ofor
mB
ilL0.
005
ChIo
rom
han
BilL
0.01
1-._
__
__
__
2-C
hlor
otol
uene
BR
L0.
005
4-C
hior
otol
uene
BilL
0.00
5p-
Cym
ene
(p-l
sopr
opyl
tolu
ene)
BilL
0.00
51,
2-D
ibro
mo-
3-C
hkro
prop
ane
BR
L0.
005
Dib
rom
ochi
orom
esita
ncV
BilL
0.00
5V
Dib
rom
omet
hane
81W
0.00
51,
2-D
ichl
orob
enze
aeSR
I.0.
005
I,3-D
ichl
orob
enze
neB
ilL0.
005
l,4-D
ichl
oroh
cnze
jcB
RL
0.00
5D
iohl
orod
fflu
orom
etjm
neB
ilL0.
005
This
nusl
ytis
olro
ped,
and
the
met
redi
t.pa
ckag
eit
rnpr
eeoo
tojr
ssbo
onm
edet
hur
oodn
aive
and
cn,d
ld,rr
ntd
use
The
inte
rpro
tatto
naan
dre
sulls
eupr
nsas
dth
ntaa
thou
tthi
san
atyt
ical
rope
dre
pron
eot t
hebe
anju
dgm
ent o
CX
ENC
OL
nbor
.tn,
teX
EN
CO
Lab
orat
orie
sal
oanr
elno
roep
omib
ifl
and
mak
esno
wnr
rnnt
yto
theet
dus
eof
the
data
hern
Lpr
osnt
rtrd.
Our
tiabi
thyt
atb
ntte
dto
the
atro
une
hwot
ced
fart
his
wor
kon
tsre
nisn
aot
herw
taes
gree
dto
tow
ritin
g.V
Sinc
e19
90H
oust
on-D
aIla
-Sa
nA
nton
io-
Aus
tin-T
ampa
-M
iam
i -La
tinA
mer
ica
Page
18
XEN
CO
Lcb
ora
torc
s
Pro
ject
Id:
Con
tact
:R
andy
Hor
nok
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
orat
ory
Man
ager
The
anal
ytic
alre
pent
.and
the
aitir
eda
tapa
dcip
Itre
pren
ente
.hen
been
mad
eth
ryou
rocc
lusiv
ean
dco
n6de
edcc
c.Th
eet
eepr
etut
lons
and
resc
dcae
npee
iaed
tbnc
uihn
,ctl
td. .
n.Iy
tlcal
repe
ntre
pres
m*
the
best
Judm
ecn
o(X
ENC
Ora
tatie
LX
ENC
Oab
orat
teic
, aao
cmen
ooro
npon
eidl
it’an
dm
akea
now
arra
nty
toth
een
dus
eof
the
dali
here
bype
eaen
tnd.
Our
liabi
lity,
limite
dto
the
min
uetI
nvoi
ced
fart
Ntw
ork
orde
eut
dera
atho
wbe
aend
toIn
wilt
ing.
Sinc
e19
90H
oust
on-
Dall
as.
San
Ant
onio
-A
ustin
—T
am
pa
-M
iam
i-L
ati
nM
neri
caPa
ge19
XEN
CO
Lcilbo
rclL
Qre
Pro
ject
Id:
Contacb
Randy
Ho
rk
Pro
ject
Loc
atio
n:G
rena
da, M
issi
ssip
pi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
3T
MInternational,
Houston
,T
X
Project
Nam
e:
Ko
pp
ers
Creo
so
teF
acil
ity
Dat
eR
eceiv
ed
inL
ab:
Rep
ort D
ate:
Pro
ject
Man
aeer
:
Fri J
ul-25-03
10
:30
am
12
-A
UG
-0
3
Kar
enO
lson
,L
abId
:23
56fl
-025
Ana
lysi
sR
eque
sted
Fie
IdI&
Duplk
ate
I
Dep
ik
Mat
rix:
SOIL
Sam
pled
:Ju
l-24-
0300
:00
VO
As
by
SW
-846
8260B
Ext
rude
d:A
ug-0
5-03
16:3
5
Asu
lyze
thA
ug-0
5-03
20:5
9
UnI
ts/R
i:m
g/kg
ilL1,
2-D
ichi
oroe
than
eB
RL
0.00
5l,l
-Dic
hlor
oeth
ane
BilL
0.00
5tr
ans-
1,2-
dich
loru
ethe
neB
ilL0.
005
cis-
1,2-
Djc
hlom
ethe
neB
ilL00
051,
1-D
ichl
oroe
ther
teB
ilL0.
005
2.2-
Dic
hiom
prop
are
BilL
0.00
513
-Dic
hlor
opro
pare
BilL
0.00
51,
2-D
ichi
orop
ropa
reB
ilL0.
005
tran
s-l,3
-dic
hlor
opro
pcne
BilL
0.00
51,
1-D
ichi
orop
rope
reB
ilL0.
005
cis-
1.3-
Dic
hlor
opro
pene
Bill
.0.
005
Eth
ylbc
nzen
eB
ilL0.
005
—_______________
Hex
achl
orob
utac
licje
BilL
0.00
5is
opro
pylb
enze
neB
ilL0.
005
Met
hyle
neC
hloi
ide
BilL
0.02
2N
apht
hale
neB
IlL0.
011
n-Pr
opyl
benz
ene
BilL
0.00
5St
yren
eB
IlL0.
005
I,1,1
,2-T
etra
chlo
roet
hane
BIlL
0.00
5t,1
,2.2
-Tct
raoh
lorr
etha
neB
ilL0.
005
Tet
rack
loro
ethy
lent
BIlL
oö
Tol
uenc
BilL
0.00
51.
2,4-
Tri
chlo
robe
ncen
eB
IlL0.
005
l,2,3
-Tri
chlo
robe
nzcn
cBI
lL0.0
051,
1,2-
Ti
chlo
roct
itme
BIl
l.0.
005
Bre
ntB
arro
nL
abor
ator
yM
anager
XEN
CO
Lab
orn
orc
s
Pro
ject
Id:
Con
tact
:R
andy
Hor
sak
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
5651
31M
Inte
rnat
iona
l,H
oust
on,T
XPr
ojcc
tNam
e:K
oppe
rsC
reos
ote
Faci
lity
Dat
eR
ecei
ved
InL
ab:
Fri
Jul-
25-0
310
:30
amR
epor
t Dat
e:12
-AU
G-0
3P
roje
ctM
anag
erK
aren
Olso
nL
abld
.23
5651
-025
Ana
lysi
sR
eque
sted
Fiel
dId
.D
uplic
aLe
ID
epth
:
Mat
rlr.
SOIL
Sam
pled
:Ju
l-24-
0300
:00
VO
As
bySW
-846
8260
BK
tl:
Aug
-05-
0316
:35
—________
—___________
Ana
lyze
d:A
ug-0
5-03
20:5
9U
nitc
/RL
:m
g/kg
RL
1,lj-
Tri
chio
roet
hane
BEL
0.00
5T
rich
loro
ethe
noB
RL
0.00
5T
tichl
orof
luor
omct
hanc
BilL
0.00
51,
2,3-
Tri
chlo
ropr
opan
eB
ilL0.
005
I,2,4
-Tri
mct
hylb
cnrc
rte
BIlL
0.00
51,
3,5.
teim
cthy
lbcn
2cne
BR
L0.
005
Vin
ylC
hlor
ide
BIl
L00
02o-
Xyl
ene
BIlL
0.00
5m
,p-X
ylen
esB
IlL00
l1
The
an.I
ytk,
Irn
port
and
the
aide
, dat
ep.d
reIt
rere
aaea
t.h.s
been
mad
efo
r yea
r atcc
boatv
ean
dco
nfid
cntJ
utT
hehr
teep
reU
tIooI
and
reau
hocr
iprc
uad
thro
aghn
uttid
ean
.tytb
etre
pent
reye
eiur
tthe
bant
juda
mea
ter
XE
NC
OL
.bom
todm
.
Baon
XE
NC
OL
abor
etod
eees
eem
0000
reap
nndh
tlkr a
ndoa
ken
nos.
erre
nty
toth
ean
don
eof
the
date
here
bypr
enee
tud.
Ore
Subt
ilty
I,D
o,fto
dto
the
enoi
mt
bren
tred
tert
id,
wor
kor
der u
rdea
not
berr
eb. a
eree
dto
hiw
,irlti
g.Si
nce
1990
Hou
sttn
-D
alla
s-S
anA
nton
io-
Aus
tin-T
ampa
.Mia
mi -
Latin
Am
eric
aPo
gc20
Labo
rato
ryM
anag
er
XEN
CO
Lcb
orc
itori
es
Work
Ord
er#:
2356
51
Lab
Bat
chID
:64
0955
Rep
ort
ing
Uni
ts:
mg/
kg
(F
orm
3-
MS
IMSD
Rec
over
ies
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ilit
y Pro
ject
ID:
QC
-Sa
mpl
eID
:23
5651
-011
Bat
ch:
IM
atri
x:So
lidM
AT
RIX
SP
IKE
IM
AT
RIX
SP
IKE
DU
PL
ICA
TE
RE
CO
VE
RY
ST
UD
Y
Mat
rix
Spik
ePe
rcen
t Rec
ovcy
ID]—
lo0’
(C-A
)/BM
thix
Spik
eD
uplic
ate
Perc
ent R
ecov
ery
[GI=
100(
F-A
)1t
Rel
ativ
ePe
rcen
t Dif
fere
nce
RPI
)20
0(D
-43Y
(D4{
)N
)N
otD
etec
ted.
3Pr
esen
tBel
owR
eest
ing
Lim
it,S-
Pres
ent
inB
lank
. NP.
-Not
Requ
este
d,1-
Inte
rfem
ice,
NA
-N
otA
pplic
eble
N=
See
Nar
rativ
e.EQ
L-
Est
imite
dQ
usnt
istt
rnU
ntil
SV
OA
sL
wE
PA82
70C
Pare
nt—
pike
dSa
mpl
eSp
iked
—D
uplic
ate
Spik
ed—
Con
trol
cont
rol
—.‘
Sam
ple
Spik
eR
esul
tSa
mpl
eSp
ike
Spik
edSa
mpl
eD
op.
RPD
Lim
itsL
imits
Flag
Rea
ukA
dded
q%
RA
dded
Res
ult[
19%
R%
%R
%R
PDA
naly
tes
(A)
(B)
[D)
lEl
IGI
Ace
naph
then
e<0
.201
2.07
1.80
872.
171.
7685
241
-134
19A
cena
phth
ylee
te<0
.207
2.07
1.75
852.
071.
7283
265
-135
25A
nthr
acen
e<0
.207
2.07
1.79
862.
071.
7786
065
.435
25B
enzo
(a)a
nthr
acen
e<0
.207
2.07
1.75
852.
071.
7082
444
-126
25—
Ben
zo(a
)pyr
ene
<0.2
072.
071.8
187
2.07
1.76
852
65.1
3525
Bcn
zo(b
)flu
oran
then
e<0
.201
2.07
1.89
912.
071.
8991
065
..135
25B
enzo
(g,h
,i)pe
ryle
ne<0
.207
2.07
1.15
562.
071.
1154
465
.135
25X
Ben
zo(k
)tlu
oran
then
e<0
207
2.07
2.07
100
2.07
191
928
25-1
2525
Chr
yscn
e<0
207
2.07
1.80
872.
071.
7685
265
-135
25D
iben
z(a,
h)M
thra
cene
<0.2
072.
0713
264
2.07
124
606
65-1
3525
XFl
uora
nthe
ne<0
.207
2.07
1.82
882.
071.
7585
365
-135
25Fi
uore
ne<0
.207
2.07
1.83
882.
071.
7786
265
-135
25—
lnde
no(1
,2,3
-c,d
)Pyr
ene
<020
72.
0712
862
2.07
1.20
587
65-1
3525
X)J
apht
hale
ne<0
207
2.07
1.81
872.
071.
7283
565
-135
25Ph
enan
thre
ne<0
.207
2.07
1.83
882.
071.
7886
265
-135
25Py
renc
<020
72.
071.
8589
2.07
1.79
863
41-1
4436
Pag
e1
of
4
XEN
CO
Lcb
ora
tori
c$
Work
Ord
er#:
2356
5)
Lab
Bat
chID
:M
1309
Rep
ort
ing
Uni
ts:
mg/
kg
For
m3-
MS
I MSD
Rec
over
ies
3P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ily Pro
ject
iD:
QC
-S
ampl
eID
:23
5651
-023
SB
atch
#:I
Mat
rix
:S
olid
IM
AT
EIX
SPIK
EI
MA
TR
JXS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YS
TU
DY
SVO
As
byE
PA
8270
CP
aree
t—
ipik
edSa
mpl
eSp
iked
Dup
licat
eSp
iked
Con
trol
Con
trol
Sam
ple
Spik
eR
esul
tSa
mpl
eSp
ike
Spik
edSa
mpl
eD
up.
RPD
Lim
itsL
imits
Flag
Res
ult
Add
edIC
I%
RA
dded
Res
ult
[19
%R
%%
R%
RPT
)A
naytc
sIA
]IB
J[D
l[J
IGI
Ace
naph
then
e<0
.206
2.05
1.86
912.
061.
8288
341
-134
19—
Acc
naph
thyl
ene
<0.2
062.
051.
8188
2.1)6
1.82
880
65-1
35-
25A
nthr
acen
e<0
.206
2.05
1.83
892.
061.
8389
065
-135
25—
Ben
zo(a
)ant
hrac
ene
<020
62.
051.
7786
2.06
1.78
860
44-1
2625
—B
enzo
(a)p
yren
e<0
.206
2.05
1.87
912.
061.
8891
065
-135
25—
Bct
szo(
h)tlu
oran
thcn
c<
0206
2.05
192
942.
1)6
1.88
913
65-1
3525
Ben
zo(g
,h,i)
pcry
lcne
<020
62.
051.
6781
2.06
.1.7
083
265
-135
25B
enzo
{k)t
luor
anth
enc
<020
62.
051.
9595
2.06
2.07
100
52.
5-12
525
Cln
ysen
e<0
206
2.05
1.83
892.
061.
8288
165
-135
25D
ibon
z(a,
h)A
nthr
accf
le<0
206
2.05
1.85
902.
061.
8791
165
-135
25Fl
uora
nthe
ne<0
.205
2.05
191
932.
061.
9193
065
-135
25Fl
uore
ne<0
.205
2.05
1.88
922.
061.
8590
265
-135
25—
lnde
no(1
,2,3
.c,d
)Pyr
ene
<0.2
052.
051.
7485
2.06
1.78
861
65-1
3525
—)l
apht
hale
ne<0
.205
2.05
1.79
8729
61.
8791
465
-135
25P
heni
nthr
enc
<020
62.
051.
9093
2.06
1.90
921
65-1
3525
Pyre
ne<
0.20
52.
0517
887
2.06
1.79
870
41-1
4436
Nat
tixSp
ike
Perc
entR
ecov
eyID
]l0
0’(C
-A)/
BM
attix
Spik
eD
uplic
ate
Perc
entR
ecov
esy
tG)-
Rel
ativ
ePe
rcen
tDitY
ereo
ceR
PD-
200(
D-G
Y(D
+G)
Pag
e2
of
4—
Not
Det
ecte
d.,T
—Pr
esen
tBel
owR
.ert
ing
Lim
it,B
Pres
ent i
nBl
ank,
NP,
-Not
Req
uest
ed.I
Inte
rfer
ence
,NA
Not
,pti
cabl
eN-
See
Nan
ativ
eEQ
LRs
timste
dQ
uant
itatic
oLi
mit
XEN
CO
Lbrorie
CF
orm
3-
MS
IMSD
Rec
over
ies
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ilit
y
Matr
ixSp
ikeP
erce
itRe
cove
ry[D
)-10
0’(C
-A)lB
Mat
rixSp
ike
Dup
lierte
Perc
entik
ecov
ery
fG] -
100(
F.A
yER
nlat
ivel
’uce
ntD
iffe
renc
eR
PD
-o0(D
-Gy(D
+Q
)N
O-N
otD
etec
ted,
3Pr
esen
tBel
owR
epof
ling
Lim
It, B
-Pr
esen
tIn
Ola
nk, N
R-
Not
Req
uest
ed,1
Inte
rfer
ence
, NA
-N
otA
rplic
able
N-
See
Nar
rativ
e,EQ
L-
Ert
inot
edQ
uant
itatio
nLi
mit
Work
Ord
er#
:235
651
Lab
Bat
chID
:64
0960
Rep
ort
ing
Unit
s:tu
g/kg
QC
-Sam
plel
D:
2356
51-O
IlS
Pro
ject
ID:
Bat
ch#:
IM
atri
x:
Sol
id
MA
TR
IXS
PIK
EI
MA
TR
IXS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YS
TU
DY
Par
ent
pike
dSam
ple
Spik
ed—
Dup
licat
eSp
iked
—C
ontr
olC
ontr
ol—
VO
As
bySW
-846
8260
BSa
mpl
esp
ike
Rem
itS
impl
eSp
lice
Spik
edSa
mpl
eD
up.
RPD
Lim
itsL
imiL
Flag
Res
ult
Add
ed[C
)%
RA
dded
Rei
it[19
%R
%%
R%
RPD
Ana)
yte
sIA
](B
i[D
l[E
ljG
)B
enze
nc<0
.006
0.06
00.
052
870.
061
0.05
285
266
.142
21C
hlor
oben
zene
<0.0
060.
060
0.05
795
0.06
10.
056
923
60-1
3321
—1,
1-D
ichl
oroe
then
e<0
.001
0.06
00.
045
750.
061
0.04
980
659
-172
22To
luen
e<0
.006
0.06
00.
051
850.
061
0052
850
59-1
3921
Tri
chlo
roet
hene
<0.0
060.
060
0.05
490
0.06
100
5489
162
437
24L
abB
atch
lfl:
6410
81Q
C-S
arnp)e
ID:
2356
51-0
12S
Bat
ch%
:1
Mat
rix:
Sol
idR
epor
ting
Uni
ts:
mg/
kgM
AT
RIX
SP
IKE
/MA
flU
XS
PiK
ED
uP
UcA
rER
EC
OV
ER
YST
UD
YP
ares
tpi
ked
Sam
ple
Spik
ed—
Dup
licat
eSp
iked
Con
trol
Con
trol
—
VO
As
bySW
-846
8260
BSa
mpl
eSp
ike
Res
uft
Sam
ple
Spik
eSp
iked
Sim
ple
Drip
.RJ
’DL
imits
Lim
Its
Flag
Res
ult
Add
ed[C
i%
RA
dded
Rea
slt
[19
%R
%%
R%
RPD
Analy
tes
IAJ
(U)
(Dl
(El
Den
zene
<0.0
060.
058
0.05
810
00.
058
0.05
798
266
-142
21.
Chl
orob
enze
ne<0
.006
0.05
80.
057
980.
058
0.05
810
02
60-1
3321
1,1-
Dic
hior
oeth
ene
<0.0
060.
058
0.05
810
00.
058
(105
910
22
59-1
7222
lolu
ene
<0.0
060.
058
0.05
595
O;0
580,
056
912
59-1
3921
Tnc
hlor
oeth
ene
<0.0
060.
058
0.06
010
30.
058
0.06
l10
52
62-1
3724
Page
3of
4
(F
orm
3-
MS
/MSD
Rec
over
ies
Pare
ntip
iked
Sim
ple
Spik
ed—
Dup
licat
eSp
iked
Con
trol
Cun
trol
—
VO
As
by
S’SV
-846
8260
13Sa
mpl
eSp
ike
Res
ult
Sim
ple
Spik
eSp
iked
Sam
ple
Dup
.li
’DL
imits
Lim
itsFl
agR
csuk
Add
ed[C
l%
RA
dded
Res
ult [
9%
R%
%R
%R
PDA
nal
yte
s[A
l(D
l[D
J[E
l[G
JB
enze
ne<0
.005
0.05
00.
052
104
0.05
000
5110
22
66-1
4221
Chl
orob
enze
ne<0
.005
0.05
00.
053
106
0.05
00.
052
104
260
-133
211,
1-D
ivhl
oroc
then
e<0
.005
0.05
00.
051
102
0.05
00.
048
966
59-1
7222
—To
luen
e<0
.003
0.05
00.
051
102
0.05
000
5010
02
59-1
3921
Tri
chlo
roet
hcnc
<0.0
030.
050
0.05
310
60.
050
0,05
410
82
62-1
3724
QC
-Ssm
pleI
D:
2356
51-0
19S
Bat
ch:
IM
atri
x:S
olid
MA
TR
IXSP
IKE
IMA
TR
IXSP
IKE
DU
PLIC
AT
ER
EC
OV
ER
YST
UD
YPa
rest
—pi
ked
Sim
ple
Spik
ed—
Dup
lIcat
e1S
pike
dC
ontr
olC
ontro
l—
VO
As
bySW
-846
8260
BSi
mpl
eSp
ike
Res
ult
Sim
ple
Spik
eSp
iked
Sam
plel
Dup
.R
PDL
imits
Lim
itsFl
agR
esul
tA
dded
(C(
%R
Add
edR
esul
t (9
%R
%%
R%
RPD
Ana
lyte
s[A
l[E
l(D
J[E
lI
(GN
spht
hale
ne<0
.011
0.05
30.
051
960.
053
0053
100
475
425
F
XEN
CO
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Faci
lity
QC
-S
ampl
eID
2358
01-0
01S
Pro
ject
ID:
Bat
ch8:
1M
atri
x:So
lidM
AT
IIIX
SPIK
EIM
AT
RIX
SP
IKE
DU
PL
ICA
TE
RE
CO
VE
RY
ST
UD
Y
Work
Ord
er23
5651
Lab
Bat
chU
):64
1150
Rep
ort
ing
Uni
ja:
tngl
kg
Lab
Bat
chID
:64
1186
Rep
ort
ing
Uni
ts:
mg/
kg
Mat
rixSp
ike
Perc
entR
ecov
my
[1)1
l0O
’(C
-A)’
BM
atri
xSp
Ice
Dup
titat
ePe
rcen
tRec
over
y[G
J-
IOO
’(F.
A)/
ER
elat
ive
Perc
entD
iffe
renc
eIt
?!)-
200a
(D.G
y(D
+O
)M
)N
otD
etec
ted,
I-‘
Pres
entB
elow
Rep
ortin
gL
imit.
B-
Pres
ent
inB
lank
, NR-
Not
Req
uest
ed.!
Inte
rfer
ence
,NA
-N
otA
pplic
ab1N
—Se
eNar
rativ
e,EQ
L=
Est
imit
edQ
usnt
itat
boLi
mit
Pag
e4
of4
XENCOLctborcitorcs
Work Order #: 235651Lab Batch #: 640960
Reporting Units: mg/kg
( Blank Spike Recovery
Project Name: Koppers Creosote Facility
Blank Spike Recovery [1)] l00*LC]/[B]All resuix are based on MDL and validated for QC purposes.
Sample: 461664-1-BKS
Batch H: I
Project ID:Matrix: Solid
BLANK (BLANK SPIKE RECOVERY STUDYVOAs by SW-846 8260B Blank SPike Blank Blank Control
Result Added Spike Spike Limits FlagsIA! (B! Result %R %RAnalytesID!
Bcnzene <0005 0.050 0.044 88 66.142Chlombenzcne <0.005 0.050 0.047
- 94 - 60.1331,1-Dichloroethenc <0.005 0.050 0.042 84 59-172Toluene <0.005 0.050 0.044 88 59-139Thehloroctheno <0.005 0.050 0.047 04 62.137
Lab Batch H: 641081 Sample: 461734-1-BKS Matrix: SolidReporting Units: mg/kg Batch N: I BLANK /BLANK SPIKE RECOVERY STUDY
VOAs by SW-846 8260B Blank Spike Blank Blank ControlResult Added Spike Spike Umits flapJAJ (B) Result %R %ItAnalytcs
l1Bcnzenc <0.005 0.050 0.048 96 66-142Ch1orobcnne <0.005 0.050 0.049 98 60-1331,1-Dichloroctliene <0.005 0.050 0.049 98 59-172Toluene <0.005 0.050 0.048 96 59-139Trichlorocthenc <0.005 0.050 0.051 102 62-137
Lab Batch H: 641150 Sample: 461780-l-BKS Matrix: SolidReporting Units: mg/kg Batch #: I__J_BLANK (BLANK SPIKE RECOVERY STUDY
VOAs by SW-846 8260B Blank Spike Blank Blank ControlResult Added Spike Spike UmHa flagsIAI II Result %R %RAnalytes IC! ID)Bcnzcn <0.005 0.050 0.049 98 66-142Chlorobcnzcne <0.005 0.050 0.049 98 60-1331,1.Dichlorocthaie <0.005 0.050 0.048 96 59-lflToluenc <0.005 0.050 0.047 94 59-139Trichlerocthcnc <0.005 0.050 0.052 104 62-137
Lab Batch H: 641186 Sample: 46l800-i-BKS Matrix: SolidReporting Units: mg/kg Batch H: I BLANK (BLANK SPIKE RECOVERY STUDY
VOAs by SW-846 8260B Blank Spike Blank Blank ControlResult Added Spike Spike Limits FlagsIA) lBI Result %R %RAnalytes
IC!Naphthalenc <0.005 0.050 0.053 106 65-135
Page 1 of I
elat
ivc
Perc
entD
iffe
retc
eR
PD20
0KD
-G)I
(D+G
)lB
lank
Spik
eR
ecov
ety
[fli
100(
C]/
[B]
Bla
nkSp
ike
Dup
licat
eR
ecov
eiy
[G]
100(
F)/
(E]
MI
resu
ltsar
eba
sed
onM
DL
and
Vdi
dnte
dfb
r(C
Purp
oses
[NC
OL
thorc
tori
cs
Work
Ord
er
#:23
5651
Lb
Bat
chID
:64
0955
Uni
ts:
mg/
kg
CB
S/ B
SDR
ecov
erie
s
Sam
ple:
4616
60-1
-BK
S
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ilit
y
Bat
chH
:1
BL
AN
KIE
LA
NK
SPIK
EIB
LA
NK
SPIK
ED
UP
LIC
A1t
RE
CV
ER
Ysn
rr)y
Pro
ject
ID:
Mat
rk:
Sol
id
SVO
As
byE
PA
8270
CB
lank
Spik
eB
lank
Bla
nkSp
ike
Bla
nkB
ik. S
pkC
ontr
olC
oatr
ol—
Sam
ple
Res
ult
Add
edSp
ike
Spik
eA
dded
Sp&
eP
up.
RPD
Um
its
Lim
itsFl
ag(A
l(B
]R
esul
t%
R(E
lD
uplic
ate
%R
%%
R%
RPD
Ana
lyte
sIC
](‘N
Res
ult
[F]
[G]
Arc
naph
then
e<0
.167
1.67
1.37
821.
671.
2877
641
-134
19—
Ace
naph
thyl
ene
<0.1
671.
6713
581
1.67
1.24
749
65-1
3525
Ant
hrac
ene
<0.1
671.
671.
3279
1.67
1.25
755
65-1
3525
—B
cnzo
{a)a
nthr
accn
c<0
.167
1.67
132
791.
671.
3078
144
-126
25B
enzo
(a)p
yren
c<0
.167
1.67
1.25
751.
671.
1770
765
-135
25—
Ben
zo(b
)flu
oran
then
e<0
.167
1.67
1.35
811.
671.
2474
965
-135
25B
enzo
(g,h
,i)pc
iyle
ne<0
.167
1.67
1.30
781.
671.
1971
965
-135
25—
Ben
zo(k
)flu
oran
then
c<0
.167
1.67
121
721.
67L
iS71
125
-125
25C
luys
ene
<0.1
671.
671.
3782
1.67
1.29
776
65-1
3525
Di,e
ñz(a
,h)A
nthr
acen
e<0
.167
T1.
671.
3883
1.67
1.29
778
65-1
35•F
kiór
anth
ene
<0.1
671.
671.
3681
1.67
129
775
65-1
3525
Fbor
ene
<0.1
67[
1.67
1.38
831.
671.
2977
865
-135
251m
leno
(1.2
3-c,
d)Py
icne
<0.1
67[
1.67
137
821.
6712
575
96$
..135
25N
apht
hale
ne<0
.167
1.67
1.31
781.
671.
2375
465
-135
25Pb
enan
thre
ne<0
.167
1.67
133
801.
6712
776
565
-135
25P
rene
<0.1
671.
6713
883
1.67
1.31
786
41-1
4436
Page
1of
3
Lab
Bat
chID
:64
1024
Uni
ts:
mg/
L
Rel
ativ
ePe
rcen
t Difi
bren
ceR
PD20
01(D
-G)/
(t)+
G)I
Bla
nkSp
ike
Rec
ovuy
[Dl=
100(
CY
tB]
Bla
nkSp
ike
Dup
licat
eR
ecov
ay[(3
] =10
0(F
)/[E
]A
llre
sults
are
base
don
MD
Lan
dV
alid
ated
for
QC
Purp
oses
XE
NC
Oort,
res
Wo
rkO
rder
#:
2356
51
(B
S/B
SDR
ecov
erie
s
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Faci
lity
Sam
ple:
4617
00-1
-BK
SB
atch
#:I
Mat
rix:
Wat
er
Pro
ject
ID:
IB
LA
NK
/BL
AN
KS
PIK
EI
BL
AN
KS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YST
UD
YS
VO
As
byE
PA
8270
CB
link
Spik
eB
lank
Bla
nkSp
ike
Bla
nk11
1k. S
pkC
ontr
olC
ontr
ol—
Sam
ple
Res
ult
Add
edSp
ike
Spik
eA
dded
Spik
eD
up.
RPI
3L
imits
Lin
tits
Flag
IAI
[BJ
Res
ult
%R
[EJ
Dup
licat
e%
R%
%R
%R
PDA
naly
tes
[CI
[D]
Res
ult
IFIG
]A
cena
phth
ene
<0.0
051
0.05
00.
056
112
0.05
00.
056
112
027
-132
31A
crna
phth
ylcn
c41
.005
111
050
0.05
611
20.
050
0.05
611
20
46.1
0825
HA
xttir
acen
e<0
.005
0.05
00.
055
110
0.05
00.
056
112
247
-145
25B
eizo
(a)a
nt1i
race
ne<0
.005
0050
[0.
059
118
0.05
00.
060
120
233
-143
25—
.,H
eszo
(a)p
yren
e<0
.005
0.05
0[
0.05
511
00.
050
0.05
511
00
65-1
3525
Ben
zo(b
)flu
oran
thcn
e<0
.005
0.05
0r
0.05
811
60.
050
0.05
711
42
24-1
5925
Ben
zo(g
,h,i)
peiy
lene
<0.0
05-
0.05
00.
056
112
0.05
00.
057
114
265
-135
25B
aizo
(k)t
luor
anth
esie
<0.0
050.
050
0.05
110
20.
050
0.05
210
42
25-1
2525
tlry
sene
<0.0
050.
050
r0.
059
118
0.05
00.
059
118
0-
65-1
3525
—D
i,enz
(a,h
)Mth
race
ne<o
.oos
T0.
050
0.05
310
60.
050
0.05
410
82
50-1
2525
—E
laor
anth
cne
<0.0
05[
0.05
00.
057
114
0.05
00.
057
114
047
-125
25—
.Fl
iore
nc<0
.005
[0.
050
T0.
056
112
0.05
00.
057
114
248
-139
25In
deno
(1,2
,3-v
,d)P
yren
e<0
.005
0.05
00.
051
102
0.05
00.
052
104
227
-160
25N
epht
hale
ne41
.005
0.05
00.
052
104
0.05
00.
051
102
226
-175
25P
lnan
thre
ne.
<0.0
05T0
.050
0.05
511
00.
050
0.05
611
22
65-1
3525
Pcc
ne<0
.005
0.05
00.
059
118
0.05
00.
060
120
223
-152
31
Page
2of
3
.jW
j)rder#:
2356
51‘!
L4L
abfl
tch
U):
6413
09S
ampl
e:-t
lnit
a:-m
g/kg
xco
CE
SIB
SDR
ecov
erie
s
4618
85-1
-BIc
S
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ifit
y
Bat
ch#:
I
-3 Pro
ject
ID:
Mat
rix:
Solid
BL
AN
KIB
LA
NK
SP
IKE
IB
LA
NK
SPIK
ED
UP
UC
AT
ER
EC
OV
ER
YST
UD
YS
VO
As
byE
PA
8270
CB
lank
Spik
eB
lank
Bla
nkSp
ike
Bla
nkE
lk. S
pkC
ontr
olC
ontr
ol—
Sam
ple
Res
ult
Add
edSp
ike
Spik
eA
dded
Spik
eD
up.
RPD
Lim
itsL
imits
Flag
IAI
[BI
Res
ult
%R
[El
DuplI
ca%
R%
%R
%R
PI)
LA
naly
tes
[CID
IR
esul
t[1
1[C
IA
cenn
phth
ene
<0.1
671.
671.
6297
1.67
1.56
934
41-1
3419
nnphth
vle
ne
<0.1
671.
671.
5794
1.67
1.52
913
65-1
3525
•
-.b
race
ne
<0.1
671.
671.
6196
1.67
1.55
933
6543
525
‘13
tnjo
anth
race
ne<0
.167
1.67
1.56
931.
671.
4989
444
-126
25.
n)1in
c<0
.167
1.67
1.60
961.
671.
5693
365
-135
25•
nzO
(bltl
uorn
then
e<0
.167
1.67
1.60
961.
671.
5794
265
-135
25•B
cnzo
(g,li
i)pc
ryle
ne<0
.167
1,67
1.68
101
1.67
1.63
983
65-1
3525
cnzo
(k)f
luor
anth
ene
-<0
.167
1.67
1.64
981.
671.
6096
225
-125
25::-
:.h’
<0.1
671.
671.
6398
1.67
1.56
935
6543
525
‘:s
aa,h
)Anth
race
ne
<0.1
671.
671
1.63
981.
6715
794
465
-L35
25I,
Etl
ien
<0.1
671.
671
1.64
981.
671.
6297
165
-135
35—
Lior
ent
<0.1
671.
67I.
698
1.67
1.60
962
65-1
3525
nden
o(1.
2.3,
c.d)
Pyre
ne<0
.167
1.67
11.
6096
1.67
1.53
924
65-1
3535
•aj
,lith
altn
e<0
.167
1.67
11.
5492
1.67
1.51
902
65-1
3525
•nsh
cnc
<0.1
671.
671
1.64
981.
6715
995
365
-135
25P
nrne
<0.1
671
1.67
11.
5995
1.67
1.52
914
41-1
4436
•
cntD
re
RPD
2o09
(D-G
)1+
G)I
Elà
kS1,
lke
Rcc
very
[D]-
100(
Cy[
B]
Bla
nkSp
ike
Dup
licat
eR
xove
iy[U
]—10
0(F)
/[E
J• )
lte
sults
tre
base
don
MD
Lan
dV
thda
tcd
for Q
CPu
rpos
esP
age
3of
3
XENCOLcbborcltoricg
Work Order#; 235651Lab Batch #: 640955
Units: mg/kg
( Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates conflnncd by reanalysis** Poor resoveries due to dilutionSurrogateRecovoy [D] 100 • A/BAll results are based an MDL and validated for QC purposes.
Page I of 24
Sample: 235651-001 /SMP
Project ID:Batch: I Matrix: SolidSURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amouct True Control. Found Amount Recovery Llndta FlagsIAI IBI %R
Analytes IDI2-Fluorobipbcnyl
1.17 1.67 70 30-1152-Fluorophenol0.948 1.67 57 25-121Nitrobcnzenc-d51.11 1.67 66 23-120Plicsaol-d63.03 1.67 62 24—113Terphcnyl-D141.14 1.67 68 18-1372.4,6-Tribroniophenol1.34 1.67 80 19-122
Lab Batch #: 640955 Sample: 235651-002! SMP Batch: I Matrix: Solidlinks: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 5270C AmounC True ControlFound Amount Recovery Umits FlagsIA) IF) %R %RAnalytes Ph
2.Fluombipbcnyl128 1.67 77 30-1152-Fluorophenol
0.747 1.67 45 25-121Nitrohenzne.d51.02 1.67 61 23-120Plrcnokl6
0.873 1.67 52 24-113Tcrphenyl-D141.30 1.67 78 18-1372,4,6-Tribromophenol1.08 1.67 65 19-122
Lab Batch 11: 640955 Sample: 235651-003 I DL Batch: I Matrix: SolidUnits: mg/kg
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True Control
Found Amount Recovely Umits ElageIAI (Dl %RAnalytes (Dl
2-Fluorobipbcnyl1.56 1.66 94 30-I 152-Fluorophcnol1.19 1.66 72 25-121Nitrobcnzcnc-d51.40 1.66 84 23-120Phenokl61.12 1.66 67 24-113Terpheny!DI41.45 166 89 18-1372,4,6-Tribeomopbcnol1.58 1.66 95 19-122
XENCOLoborcitorics
Work Order #: 235651Lab Batch #: 640955
Units: mg/kg
Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
‘ Swrogatm outside limits; data and suilogates confinned by reanalysisPoor recoveries due to dilution
Swrogatc Recovery ID] 100 * Al BAll icsuhs are based on MDL and validated for QC purposes.
Sample: 235651-003 / SMP
Project ID:Batch: I Matrix: Solid
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits FlagsA) In)Analytes IDI
2-Fluorobiphenyl1.45 1.66 87 30-1152-Fluorophenol1.17 1.66 70 25-121Nitrobenzcne-dS1.39 1.66 84 23-120Pbenol-d61.29 1.66 78 24-113Tctphcnyl-D141.52 1.66 92 18-1372,4,6-Tribromophenol1.77 1.66 107 19-122
Lab Batch #: 640955 Sample: 235651-004 I SMP Batch: I Matrix SolidUnits: mg/kg
SURROGATE RECOVERY SEUDYSVOAs by EPA 8270C A.uuunt True ControlFound Amount Recovery Umits FlagsIAI IBI %RAnalytes ID)
2-Fluorobiphenyl1.47
- 1.66 89 30-1152-Fluorophenol1.39 1.66 72 25-121Nitmbensene-d51.38 1.66 83 23-120Phcnol-d61.29 1.66 78 24-113Terphcnyl-D141.48 1.66 89 18-1372,4,6-Thbromophcnol169 1.66 102 19-122
Lab Batch #: 640955 Sample: 235651-005 / DL Hatch: I Matrix: SolidUnits: mg/kgSURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits FlagsIAJ IB] %RAnalytes V
2-Fluorobiphenyl1.46 V 1.67 87 30-1152-Fluorophenol
V
1.30 1.67 66 25-121Nftrobcnzcnc-d51.40 1.67 84 23-120Thenol-d61.09 1.67 65 24-1 13TetpbenylD14 V
133 1V67 92 SR-1372,4,6-Tribromophenol118 1.67 71 19-122
Page 2 of 24
XENCOLcberateric
Work Order # 235651Lab Batch : 640955
Units: mg/kg
C Form 2 - Surrogate RecoveriesProject Namer Koppers Creosote Facility
ProjectlD:Sasupl.: 2’i6cl-on5 / SMP Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
• Suriogates outside limits; data and surrogat confirmed by reanalysisPoor rccoveries due to dilution
SurrogatcRecovmy[DJ 100A/BAll jesuIts are based on MDL and validatcd for QC purposes.
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IAI (BJ %RAnalytes JDJ
2-Fluorobph.nyl 1.07 1 67 64 30-I 152-Fluorophcnol 0.813 1.67
- 49 25-121Nit,obenrcne-d5 1.07 1.67 64 23-120Ptienol-d6 0.943 1.67 56 24-113Teephenyl-D14 1.16 1.67 69 18-1372.4,6-Tribromophenol 1.48 1.67 89 19-122
Lab Batch #: 640955 Sample: 235651007 / SMJ’ Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
JAI BJAnalytes 11)1
2-Fluorobiphenyl 0.969 1.67 58 30-1152-Fluorophenol 0.704 1.67 42 25-121Nitrobcnscne-dS 0.919 1.67 55 23—170Phenol-d6 0.646 1.67 39 24-113Tcrphenyl-D14 1.05 1.67 63 18-137Z4,6-Tribromophcnol 0.966 1.67 58 19-122
Lab Batch 8: 640955 Sample: 235651-008! SMP Batch: 1 Matrix: SolidUntti tog/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True CoatrolFound Amount Recovery Limits Fligs
IAJ ml %RAnlllytes mill
2-Fluorobiphenyl 1.18 1.67 71 30-1152-liluorophenol
0.943 [67 56 25-121Nitrobcnzenc-dS 1.14 1.67 68 23-120Phenol-46
0.984 1.67 59 24-1 13Tcrphenyl-D14 1.26 1.67 75 18-1372.4,6-Tribromophenol 1.12 1.67 67 19-122
Page 3 of 24
XENCOLcborctorie
Work Order #: 235651Lab Batch #: 640955
Units: mg/kg
Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Project ID:Sample: 235651..009/SMP Batch: I Matrix:Solid
SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IAI IBI %R VaRAnalytes tIN
2-Fluorobiphenyl 1.46 1,66 88 30-1 IS2-Fluorophenol 1.21 1.66 73 23-121Nitrobenzcne-d5 1.43 1.66 86 23-120Phcnol-d6 1.26 1.66 76 24-113Tethenyl-D14 1.53 1.66 92 18.1372,46-Tribromophcno1 1.33 1.66 80 19-122
Lab Batch #: 640955 Sample: 235651-010/ SMP Batch: I MatHs: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount Truc ControlFound Amount Recovery Limits Flags
tAt I) %R %RAnalytes ID)
2-Fluorobiphenyl 1.44 1.66 87 30-1152-Fluorophenol 1.16 1.66 70 25.121Nitrobenzenc-d5 1.39 1.66 84 23-120Phenol-d6 1.19 1.66 72 24-1 13Terphenyl-D14 1.53 1.66 92 18-1372,4,6-Tribromophenol 1.29 1.66 78 19-122
Lab Batch #: 640955 Sample: 235651-011 / MS Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) fB) %RAnalytes ID]
2-Fluorobiphenyl 1.50 1.66 90 30-1152-Fluomphcnol 1.34 1.66 81 25-121Nitrobcnsene-dS 1.50 1.66 90 23-120Pheaol-d6 1.46 1.66 88 24-113Tasphrnyl-014 160 1.66 96 18-1372,4,6-Tribromophenol 1.77 1.66 107 19-122
° Suaogatm outside limits; data and sunogatm confirmed by reanalysis“ Poor recoveries due to dilutionSunogsteRecovay[D] l00’A/BAll results are based on MDL and validated for QC purposec.
Page4of 24
XENCOLcthorntorics
Work Order #: 235651Lab Batch #: 640955
Units: mg/kg
C Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates conflrrne.jl by reanalysisPoor recovuries due to dilution
Surrogate Recovay [D] = 100 * Al BAll results are based on MDL and validated for QC purposes.
Sample: 235651-011 /MSD
Project ID:Batch: 1 Matrix: Solid
SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) IBI %RAnalytes ID)
2-Fluorobiphenyl 1.49 1.66 90 30-) 152-Fluorophenol 126 1.66 76 25-121Nitrobcnzene-dS 1.43 166 86 23-120Pbenol-d6 1.35 1.66 81 24-113Tcapheayl-D14 1.56 1.66 94 18-1372,4,6-Tribromopbenol 1.74 1.66 105 19-122
Lab Batch #: 640955 Sample: 235651-011 / SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amoant Trc ControlFound Amount Recovery Limits Flags
IAI (B)Analytes ID)
2-Fluorobiphenyl 1.45 1.67 87 30-1152-Fluorophenol 1.21 1.67 72 25-121Nitrohenwie.d5 1.40 1.67 84 23-120pbcnol-d6 1.22 1.67 73 - 24—113Terphcnyl-D14 1.51 1.67 90 18-1372,4,6-Tribroznophcnol 1.32 1.67 79 19-122
Lab Batch #: 640955 Sample: 23565 1-012 / SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) %RAnalytes ID)
2-Fluorobiphcnyl 1.38 1.67 83 30-115 —
2-Fluorophcnol 1.14 1.67 68 25-121Nitrobenzcne-d5 1.35 1.67 81 23-120Phcnol-d6 1.15 1.67 69 24-113T.rphanyl-D14 1.49 1.67 89 18-1372,46-Tribmmophcnol
- 1.17 1.67 70 - 19-122 1
Page 5 of 24
XENCOLcberatories
Work Order #: 235651lab Batch #: 640955
UnIts: mg/kg
I Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates confirmed by reanalysis“‘ Poor rurovcsies due to dilutionSurmgateRecovuryjD] 100 AIBAll results are based on MDL and validated for QC purposes.
Sample: 235651-013 I SMP
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True Control
Found Amount Recovery Limits FlagsA1 IBI %R
Analytes 1012-Fluorobiphenyl 1A6 1.67 87 30-I 152-Fluorophenol 1.09 1.67 65 25-121 -
Nitmbenzcnc.d5 1.35 1.67 8) 23-120Phenol-d6 1.16 1.6? 69 24-113Terpbcnyl-D14 1.53 1.67 92 18.1372,4,6-Tribromophenol 1.37 1.67 82 19-122
Lab Batch #: 640955 Sample: 235651-014 / SMP Hatch: I Matrix: SolidUnits: mg/kg SURROGATE RItCOVERY STUDY
SVOAs by EPA -8270C Amount True ControlFound Amount Recovery Limits Flags
IAJ FBI %RAnalytes 101
2-Fluorobiphenyl 1.38 1.66 83 30-1152-Fluorophenol 1.09 1.66 66 25-121Nitmhen,ane-dS
1.33 1,66 80 23-120Phenol-d6 1.14 24-113Terphcnyl-014 1.48 “i• 18-1372,46-Tn’bromophenol 1.25 ] 1.66 1 75 19-122
Lab Batch #: 640955 Sample: 235651-015 / SM? Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
[AJ lBl %RAnalytes 101
2-Fluorobiphcnyl 1.06 1.67 63 30-1152-Fluorophenol 0.777 1.67 47 25-121Nitrobcnzenc-d5 1.00 1.67 60 23-120Phenol-d6 0.835 1.67 50 24-1 13TrphenyI..D14
5.2$ I 67 75 18-1372,4,6-Tribromophenol 0.937 1.67 56 19-122
Page 6 of 24
XENCOLciboratorics
Work Order#: 23565]Lab Batch #: 640955
Units: mg/kg
C Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
• Surrogates outside limits; data and surrogates con6nned by reanalysisPoor recoveries due to dilution
Surrogate Recovery ED] 1004/BAll results arc based on MDL and validated for QC purposes.
Sample: 23565 1.016 I SMP
Project ID:Batch: 1 MatrIx: Solid
SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IAI [ill %R %RAnalytes IDI
2-Fluorobipbeaiyl 138 1.66 83 30-1152-Fiuorophcnol 111 1.66 67 25-121Nitrobenznc-d5 1.32 1.66 80 23-120Phenol-d6 1.14 1.66 69 24-113Tcrpbenyl-D14 141 1.66 85 18-1372,4.6-Tribromopbcnol 137 1.66 83 19-122
Lab Batch It: 640955 Sample: 461660-1BKS /BKS batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA H270CFound Amount Recovery Limits flags
IA) BJ %RAnalytes ID)
2-Fiuorobiphcnyl 1.41 1.67 84 30-1152-Fluorophcnol 128 1.67 77 25-121Nitmbcn,ene-d5 138 1.67 83 23-120Pbenoi-d6 132 1.67 79 24-113Tcrphenyt-1314 1.46 1.67 87 18-1372,4,6-Tribromopbenol 136 f 1.67 81 19-122
Lab Batch #: 640955 Sample: 461660-1-BLK/ BLK Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) If) %RAnalytes II))
2-Fhlorobipheoyt 1.47 1.67 88 30-1152-Fluorophenol 128 1.67 77 25-121Nitrobenzcne.d5 1.44 1.67 86 23-120Phenol-d6 129 1.67 77 24-1 13Teaphenyt.D14 1.43 1.67 - 86 18-1372,4,6-Tribromophenol 130 1.67 78 [ 19-122
Page 7 of 24
XENCOLoborcitorics
Work Order #: 235651I .ah Hatch g: 640955
Units: mg/kg
[ Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
‘Ssrrogates outside limits data and surrogates confirmed by reanalysisPoor recovaics due to dilution
Surrogate Recovery [DJ =100 Al BAll results are based on MDL and validated for QC purposes.
Sample: 461660-l.ESD / BSD
Project ID:Batch: I Matrix: Solid
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C True Control
Found Amount Recovery Limits Flags)4) in)
Analytes (B)2-Fluorobiphenyl 1.38 167 83 30-1152-Fluorophenol 127 1.67 76 25-121Nitrobcnzene-dS 1.36 1.67 81 23-120Phenol-d6 127 1.67 76 24-1 13Tcrphcnyl-D14 1.44 1.67 86 18-1372,4,6-Tribromophenol 137 [67 82 19-122
Lab Batch U: 641024 Sample: 235651-006/ SMP Batch: I Matrix: WaterUnits: mg/L SURROGATE RECOVERY s FUDY
SVOAs by EPA 5270C Amount Tone ControlFound Amount Recovery LImits Flags
IA) f B) %RAnalytes I1N
2-Fluorobiphenyl 0.060 0.050 120 43-116 “2-Fluorophenol 0.025 0.050 50 21400Nitmbenrent-d5 0.055 0.050 110 35-114Phcnol-d6 0,018 0.050 36 10-94Tcephcnyl-D14 0.065 0.050 130 33-1412,4,6-Tdbiomophenol 0.061 0.050 122 10-123
Lab Batch U: 641024 Sample: 235651-017/SMP Batch: I Matrix: WaterUnits: mg/L SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) (B)Ana3ytes (D)
2-Fluorobiphcnyl 0.054 0.050 108 43-1162-Fluorophenol 0.024 0.050 48 21-100Nitrobcnsmic-d5 0.052 0.050 [ 104 35-1 14Phenol-d6 0.015 0.050 30 10-94TerphenylD14 0.061 00fl 122 33-1412,4,6-Tribromophcnol 0.061 0,050 [ 122 10-123
PageS of 24
XENCOLclborotorics
Work Order#: 235651Lab flatrh 641024
C Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogatm outside limits; data and surrogatm confirmed by reanalysis‘ Poor recoveries due to dilutionSurrogate Recovery [Dj 100 • Al BAll results are based on MDL and validated for QC purposes.
Units: mg/LSamplat 235651-018! SMP
Project ID:Batch: I Matrix: Water
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount Thie Control
Found Amount Recovery Limits FlagsIAI In) %RAnalytes ID)
2-Fluombiphenyl0.053 0.050 106 43-1162-Fluorophenol0.024 0.050 48 21-I 00Nitrobcnzcne-dS0.051 0.050 102 35-114Pbcnol-d60.015 0.050 30 10-94Terphenyl-D]40.061 0.050 122 33-1412,4,6-Tribromophenol0.061 0.050 122 10-123
Lab Batch #: 641024 Sample: 461700-1-BKS I BKS Batch: I Matrix: WaterUnits: mg”L SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits flagsIA) IBI %R %RAnalytes IDl
2-Fluorobiphenyl0.056 0.050 112 43-1162-Fluomphenol0.027 0.050 54 21-100Njleobensene-d50.055 0.050 I 10 35-114Phenol-460.018 0.050 36 10-94Tczphcnyl.D140.064 0.050 128 33-1412,4,6-Tribromophenol0.061 0.050 122 10-123
Lab Batch 4: 641024 Sample: 461700-1-BLK / BLK Batch: 1 Matrix: WaterUnits: mg/L SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount Thic ControlFound Amount Recovery Limits Flags
LA) IBIAnalytes ID)
2-Fluorobiphenyi0.052 0.050 104 43-1162-Fluorophenol0.025 0.050 50 21-100Nit,obcnzene-dS0.050 0.050 100 35-114Phenol-d60.016 0.050 32 10-94Tcephenyt-D140.058 0.050 116 l-l4I2,4,6-Tribromophenol0.057 0.050 114 I 0-123
F’age 9 of 24
XENCOLaboratories
Work Order #: 235651Lab Batch #: 641024
C Form 2 - Surrogate Recoveries 3Project Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates conlinned by reanalysis‘“Poor resoveries due to dilutionSurrogate Recovy (DJ = 100 ‘A lBAll results are based on MDL and validated for QC purposes.
Units: mglL
Sample: 461700-1-BSD IBSD
Project ID:Batch: I Matrix: Water
SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount Trae ControlFound Amount Recovery LAmits Nags
tAl IBIAnalytes
2_)hrnmbipbenyl 0.056 0.050 112 43-1162-Fluoropbenol 0.026 0,050 52 21-100Nitrobcnzene-dS 0.054 0.050 108 35-1 14Phenol-d6 0.018 0.050 36 10-94Terphcnyl-D14 0.065 0.050 130 33-1412,4,6-Tribromophenol 0.061 0.050 122 10423
Lab Batch #: 641309 Sample: 235651.019/ SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Auiuuut True ControlFound Amount Recovery Limits Nags
IAI IBI %RAnalytes 11)1
2-Fluorobiphenyl 1.58 1.67 95 30-1 152-Fluorophenol 0.902 1.67 54 25-121N1t,obensene.4S 1.55 1.67 93 23-120Phcnol-d6 1.06 1.67 63 24-113Terphenyl-D14 1.60 1.67 96 18.1372,4,6-Tribromophcnol 1.15 1.67 69 19-122
Lab Batch 8’: 641309 Sample: 23565 1-020 / SMP Batch: 1 Matrix: SolidUNits: tog/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Nags
IAI IBIAnalytes
2-Fluorobiphenyl 1.62 1.67 97 30-1152-Fluorophenol 0.715 1.67 43 25-121Nitrobcnzene-d5 1.55 1.67 93 23-120Phenol-d6 0.866 1.67 52 24-113Thrphenyl-D11 1.62 1.67 Q7 18.1372,4,6-Tribxomopbcnol 0.862 1.67 52 19-122
Page lOof 24
XENCOLnboratorics
Work Order #: 235651Lab Batch d 641309
Units: mg/kg
E Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates confirmed by reanalysis‘ Poor resovcries due to dilution
SurrogateRccovcry[D]= 100 A/BAll results are based on MDL and validated for QC pulposes.
Sample: 235651-021 /SMP
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amouat Trite ControlFound Amount Recovery Limits Flaga
IA! IBI %R %RAnalytes (Dl
2-Fluoroblphenyl 1.65 1.67 99 30-115 -________
2-Fluorophonol 1.33 1.67 80 25-121
Nitrobenantc-dS 1.58 1.67 95 23-120Phenol-d6 1.46 1.67 87 24-113Tcrphcnyl-D14 1.75 1.67 105 18-1372,4,6-Tribromophenol 1.71 1.67 102 19-122
Lab Batch #: 641309 Sample: 235651-022 I SMP Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Auauuut Tnac ControlFound Amount Recovery Limits Flags
(Al If) %RAnalytes ID)
2-Fluorobiphenyl 5.62 5.00 112 30-1152-Fluorophenol 4.40 5.00 88 25-121Niobnnarne-dS 543 5.00 109 23-120Phenol-d6 4.82 5.00 96 24-113Terphcnyi.D14 5.93 5.00 119 18-1372,4,6-Tribromophenol 5.22 5.00 104 19.122
Lab Batch #: 641309 Sample: 23565 1-023 I SMP Batch: 1 Matrix: Solid
Units: mg/ku SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA] 101Analytes [Dl
2-Fhtoiobiphcnyl 1.59 1.67 95 30-1152-Fluorophenol 1.33 1.67 80 25-121Nilsobcnzcnc-d5 1.54 1.67 92 23-120Pbenol-d6 1.43 1.67 86 24-113T.ephonyl-D14 1.65 1.67 99 18-137Z4,6-Tiibromophcnol 1.66 1.67 99 19-122
Page II of 24
XENCOLctborctorics
Work Order #: 235651
( Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Lab Batch v. 641309 Sample: 235651-023 SIMSUnits: mg/kg
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
“Suirogates outside limits; data, and surmgates confirmed by reanalysisPoor sesoverics due to dilution
Surmgate Recovmy [DJ 100 A / BAll results arc based on MDL and validated for QC purposes.
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Umits FlagsIA] IBI %R %RAnalytes (‘N2-Flunrohiphenyl
1.60 1.66 96 304152-Fluorophenol136 1.66 82 25-121Nitrobenzenc-d51.58 1.66 95 23-120Phcnol-d61.49 1.66 90 24-I 13Tcrphenyl-D141.60 1.66 96 18-1372,4,6-Tribromophenol1.90 1.66 114 19-122
Lab Batch N: 641309 Sample: 235651-023 SD /MSD Batch: I Matrix: SolidUnits: mg/kg
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits FlapJA( IBI %RAnalytes (D)
2.Fluorobiphcnyl1.63 1.66 98 304152-Fluorophcnol1.38 1.66 83 25-121Nitrobenzene..d5162 1.66 98 23-120Phsnol-d61.51 166 91 24-113Tcrpbenyl-D141.64 1.66 99 18-137Z4,6.Tribmmoplscnol1.92 1.66 116 19-122
Lab Batch N: 641309 Sample: 235651-024! SMP Batch: I Matrix: SolidUnits: mg/kg
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags(A] (B] %RAnalytes
2-Fluorobiphenyl1.57 1.66 95 30-1152-Fluomphenol121 1.66 73 25-121Nitrobcnzene-d51.51 1.66 91 23-120Phenol-d6132 1.66 80 24-113Terphnnyl_D141.57 1.66 95 1R-17Z4,6-Tribromàpbcnol1.55 1.66 93 19-122
Page 12 of 24
XENCOLcboraLorics
Work Order#: 235651Lab Batch 641309
Units: mg/kg
I Form 2 - Surrogate RecoveriesProject Name: ICoppers Creosote Facility
** Surrogates outside limits; data and surrogates confirmed by reanalysis“ Poor resoverIcs due to dilution
Surrogate Recovery D] 100 * Al BAll results arc based on MDL and validated for QC purposes.
Page 13 of 24
Sample: 23565 1-025 / SMP
Project ID:Batch: I Matrix: SolidSURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery LImits Flags
IAJ IBI %RAnaiytes
2-Fluorobiphensi1.52 1.66 92 30-1152-Pluorophcnol 124 1.66 75 25-121
Nitrobcnzcne-dS1.43 1.66 86 23-120
Phenol-d61.34 1.66 81 24-113
Terphcnyl-D141.50 1.66 90 18-137
2,4,6-Thbmmophenol 1.48 1.66 89 19-1 22Lab Batch II: 641309 Sample: 461885-1-BKS / EKS Batch: I Matrix: Solid
UnIts: mg/kg SURROGATE RECOVERY STUDY• SVOAs by EPA 8270C Amobnt Trac Cuntrol
round Amount Recovery Limits FlagsIA) %R
Analytes ID)2-Fluorobiphenyl
1.67 1.67 100 30-1152-Fluotophenol1.41 1.67 84 25-121
Ngrobenzene-d51.64 1.67 98 23-120Phcnol-d61.60 1.67 96 24-113Terphcnyl-D141.75 1.67 105 18-13724,6-Tribromophenol2.04 1.67 122 19-122
Lab Batch #: 641309 Sample: 461 885-1-BLK I ELK Batch: 1 Matrix: SolidUnits: ma/kg SURROGATE RECOVERY STUDY
SVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IA) IBI %R. Analytes ID)
2-Fluorobiphenyl 1.64 1.67 98 30-1152-Fluoropbcnol
1.41 1.67 84 25-121Nitrobcnzcne-d5- 1.65 1.67 99 23-120Phenol-d6
. 1.52 1.67 91 24113Terplsanyl-D141.69 1.67 101 18-1372,4,6-Tsibromopbcnol1.74 1.67 104 19-122
XENCOLoboratorics
Work Order II: 235651Lob Bntch th 641309
Units: mg/kg
C Form 2 - Surrogate Recoveries 3Project Name: Koppers Creosote Facility
“Surrogates outside limits; data and surrogates confirmed by reanalysisS* Poor rccøveries due to dilutionSurrogate Recovery [1)] 100 A F BAll results are based on MDL and validated for QC purposes.
ampl.o 461885-1-BSD I BSD
Project ED:Batch: I Matrix: Solid
SURROGATE RECOVERY STUDYSVOAs by EPA 8270C Amount True ControlFound Amount Recovery Limits Flags
IAI 11 %RAnalytes 11)1-F)uorobipbcnyl
1.64 1.67 98 30-1152-Fluomphenol1.44 1.67 86 25-121Nitrobenzene-d51.61 1.67 96 23420
Phcnol-d61.61 1.67 96 24-113
Tesphenyl-D141.67 1.67 100 18-1372,4,6-Tiibromopbenol1.96 1.67 117 19-122
Lab Batch l: 640960 Sample: 235651-001 I SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amuuu True ControlFound Amount Recovery limits lOngsIA) )B) %RAnalytes
4-Bromofluoroben.zene 0.0622 0.0500 124 74-121 ‘Dibromofluorome*hane 0.0531 0.0500 106 80-120l,2-Diohloro.tlian.-D4&0519 0.0500 104 80-120Tolucnc-D80.0537 0.0500 107 81-117
Lab Bitch #: 640960 Sample: 23565 1-002 / SMP Batch: 1 Matrix: SolidUnits: mg/kg
SURROGATE RECOVERY STUDYVOAs by SW-846 8260B Amount True Control
Found Amount Recovery Limits Flags)A) (U YuRAnalytes DJ4-Bromofluorobenzene 0.0607 0.0500 121 74.121Dibromofluoromethane 0.0547 0.0500 109 80-1201,2-Diclilorocthanc-04
0.0536 0.0500 107. 80-120Tnluene-D80.0532 0.0500 106 81-117
Page 14 of 24
XENCOLcdorcttorics
Work Order #: 235651Lab Batch #: 640961)
Units: mg/kg
L Form 2 - Surrogate Recoveries 3Project Name: Koppers Creosote Facility
Project ID:Sample: 235651-003/ SMP Batch: I Matrix: Solid
SURROGATE RECOVERY STUDYVOAs by SW-846 8260B Amount True Control
Fomd Amount Recovery Limits flagsIAI (Dl %R %R
Analytes ID(4-9mmofhiorobenzene
0.0567 0.0500 113 74-123Dibmmofluoromntane 0.0560 0.0500 112 80-1201.2-Dichlorocthans-D4 0.0525 0.0500 105 80-120Tolucne.D8
0.0510 0.0500 102 81-1 17Lab Hatch #: 640960 Sample: 235651-004 / SMP Batch: I Matrix: Solid
IJnits: inrlkg SUkROGATE RECOVERY STUDYVOA.s by SW-846 8260B Amount True Control
Found Amount Recovery Umitu Flags(AJ IB) %RAnalytes 101
4-Byomofluorobenzcne 0.0533 0.0500 107 74-121Dibromofiuoromethanc0.0556 0.0500 lii 80-1 20l,2-Dichlorocthane-D40.0531 0.0500 106 80-120
Tolucne-D80.0490 0.0500 98 81-117
Lab Batch #: 640960 Sample: 235651-005! SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW846 8260B Amount True ControlFound Amount Recovery limits flags
(Al IBI %RAnalytes (DI
4-Bromofluorobcnzcne0.0627 0.0500 125 74-12 IDibromotiuoromcthane0.0587 0.0500 117 80-120l,2-Dichioroethanc-D40.0533 0.0500 107 80-120Tolucne-D80.0533 0.0500 107 81-117
Lab Batch #: 640960 Sample: 235651-007/ SMP Batch: I Matrix: SolidUnits: mg/kg
SURROGATE RECOVERY STUDYVOAs by SW-846 826013 Amount True Control
Found Amount Recovery Limits Fiaga(Al (B] %R
Analytes IDJ4-Bromofluorobcorxne
0.0754 0.0500 151 74-121 ‘Pibromotluoromcsnane
0.0512 0.0500 102 80-1201,2-Dichloroethanc-D40.0589 0.0500 118 80-120
Toiucne-D80.0648 0.0500 130 81-117
“Surrogates outside limits; data and surrogates confirmed by reanalysis“ Poor recovenes due to dilutionSusmgateRecovay[D)= 100 A/DAU results are based on M1)L and validated for QC purposes.
Page 15 of 24
XENCOLcborotories
Work Order#: 235651Lab Batch lli 640960
Units: mg/kg
I Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
‘ Surrogates oulside limits; data and surrogates confinned by reanalysis‘ Poor recoveries due to dilutionSurrogate Recovery [D] IOOAIBAll results are based on MDL and validated for QC purposes.
ampIe 235651-008 / SMP
Project ID:Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
JAJ IBI %R %RAnalytes ID1
4-Bromofluorobenzene 00654 0.0500 131 74-121Dibroinofluoromethane 0.0549 0.0500 110 80-120l,2-Dichlorocthane-D4 p.0590 0.0500 118 80-120Tolucne-D8 0.0566 0.0500 113 81-117
Lab Batch N: 640960 Sample: 235651-010 I SMP Batch: 1 Matrix: SolidUnits: mg/kg SURROGATE RkCOVERY ,rUDY
VOAs by SW-846 8260B Amount True ControlV Found Amount Recovery Limits Flags
IAI IBI %RAnalytes P1
4-Bromofluorobcnzene 0.0573 0.0500 115 74-121Dibromofluososncthane 0.0528 0.0500 106 80-1201,2-Dichlorocthune-D4 0.0509 0.0500 102 80-120Toluenc-D8 0.0505 0.0500 101 81-117
Lab Batch N: 640960 Sample: 235651-011 I SMP Batch: i Matrix: SolIdUnits: mgñcg SURROGATE RECOVERY STUDY
VOAs by SW-84( 826013 Amount True ControlFound Amount Recovery Limits Flags
IAI JBJ %RAnalytes IDI
4-Bromofluoroboizene 0.0533 0.0500 107 74-121Dibroinof)uoromdbanc 0.0541 0.0500 108 80-120l,2-Dichloroetbane-D4 0.0520 0.0500 104 80-120Toluene-D8 0.0499 0.0500 100 81-117
Lab Bateb 8: 640960 Sample: 235651-011 SI MS Batch: I Matrix: SolidUnits: fl1kg SURROGATE RCOVERY 3UDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
IAI P1 4R hRAnalytes 101
4-Bromofluorobenzcne 0.0532 0.0500 106 74-121Dibromolluoeomethanc 0.0065 0.0500 115 80-12012-Dicti1orodhane-D4 0.0569 0.0500 114 80-120Toluene-D8
- 0.0503 0.0500 101 81-117
Page 16 of’ 24
XENCOLaborcttorics
Work Order #: 235651Lab Batch #: 640960
Units: mg/kg
( Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
“Surrogates outside limits; data and surrogates confinned by reanalysis“ Poor recova es due to dOutionSurrogateRecovesy[D] 100 A10All results arc based on MDL and validated for QC purposes.
Sample: 235651-011 SD/MSD
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW.846 8260B Amount True ControlFouad Amount Recovery Limita Flags
IA) JB) %R %RAnalytes lot
4-Bmmofiuinmhcnsene 0.0527 0.0500 105 74-121Dibromofluoromethane 0.0551 0.0500 110 80-120l,2-Dichlorocthanc-D4 0.0528 0.0500 106 T 80-120Toluene-D8 0.0510 0.0500 102 J 81-117
Lab Batch 8: 640960 Sample: 461664-J-BKS !BKS Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW446 8260B Amount True Controlround Amount Recovery Umits Flags
IA] IBI %R %RAnalytes DJ
4.Bromofluoiohcnzcne 0.0511 0,0500 102 74-121Dibromolluoromethane 0.0502 0.0500 100 80-120I2-Dichloeodbanc-D4 0.0512 0.0500 102 80-120Tolucnc-D8 0.0506 0.0500 101 81-117
Lab Batch #: 640960 Sample: 461664- I .BLK / BLK Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Nags
IA) ID) %R %RAnalytes ID)
4-Bromofiuorobcnzcne 0.0526 0.0500 105 74-121
Dibromofluoromethane 0.0511 0.0500 102 80-12012-Dichloroethanc-D4 0.0509 0.0500 102 80-120__-Toluene-D8 0.0504 0.0500 101 81-117
Lab Batch 8: 641081 Sample: 235651-009 / SMP Batch: 1 Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery L.lmlts Flags
IA) till %RAnalytes ID!
4-Brosnofluoiobcnzene 0.0638 0.0500 128 74-121 “
DlbsomofluoeomcUsanc 0.0541 0.0500 108 80.120
1.2-Dichlorocthano-D4 0.0517 0,0500 103 [ 80-120Tolucnc-D8 0.0579 0.0500 116 [ 81-117
Page 17 of 24
XENCOLcborctorics
Work Order#: 235651LabBatcb#: 641081
Units: mg/kg
C Form 2- Surrogate Recoveries JProject Name: Koppers Creosote Facility
Project ID:Sample: 235651-012/SM? Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amonat True ControlFound Amount Recovery Limits Flags
IA1 (DIAnalytes 101
4-Bsomofiuorobcozene 0.0524 0.0500 105 74-121Dibromotluoromdbanc 0.0550 0.0500 110 80-12012-Dicidosocthune-D4 0.0512 0.0500 102 80-120Tolucc-D8 0.0497 0.0500 99 81-117
Lab Batch W: 641081 Sample: 235651-012 S / MS Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
IA) ID) %R %RAnalytes ID)
4-Bromofluombcnzene 0.0519 0.0500 104 74-121Dibromofluoromdhane 0.0551 0.0500 110 80-1201,2-Dichloancthanc-D4 0.0520 0.0500 104 80-120Toluene-D8 0.0502 0.0500 100
- 81-117
Lab Batch #: 641081 Sample: 235631-012 SDIMSD Batch: I MatrIx: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amomit Recovery Limits Flags
(A) ID) %R %RAnalytes IDl
4-Bromofluorobenzcnc 0.0524 0.0500 105 74-121Dibromofiuoromethane 0,0552 0.0500 110 80-1201,2-Dlchlocodbane-D4 0.0548 0.0500 110 80-120Toluene-08 0.0500 0.0500 100 81-117
Lab Batch U: 641081 Sample: 235651-021 ISMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Umlts Flags
(A) IB) %R %RAnalytes ID)
4—Bromofluombcnzcoe 0.0559 0.0500 112 74-121DibromutluoTomdbanc 0.0537 0.0500
- 107 80-120l,2-Dichlorocthsne-D4 0.0527 0.0500 105 80-120Toluene-OS 0.0514 0.0500 103 81-117
“Surrogatm outside limits data and surrogates confinned by reanalysis“ Poor recovoics due to dilution
Sumogate Recovery [D]=100 A/BAll results are based on MDL and validated for QC purposes.
Page 18 of 24
XENCOLcborQLories
Work Order #: 235651
Lab Batchi MIORJ
Units: me/kg
Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Project ID:Sample: 461734-1-BKS IRKS Batch: I Matrix: Solid
SURROGATE RECOVERY STUI
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
(Al I B %R %RAnalytes (Dl
‘l-Dromoftuorobensene 0.0519 — 0.0500 104 74-121Dibromofinoromethanc 0.0533 0.0500 107 80420l,2-Dichlorodhanc-D4 0.0529 0.0500 106 80-120Tolucnc-D8 0.0510 0.0500 102 81-117
Lab Batch #: 641081 Sample: 461734-l-BLK/BLK Batch: 1 Matrix: Solid
units: mg/leg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B 1.inouiit True ControlFound Amount Recovery Limits Flags
(AJ (RI %R %RAnalytes (DJ
4-Bromofluorobeazene 0.0540 0.0500 108 74-121Dibtomofluorome*bane 0.0516 0.0500 103 80-12012-Dichlorocthanc-D4 0.0504 0.0500 101 80-120Tolucnc-D8 0.0512 0.0500 102 81-117
Lab Batch 1 641150 Sample: 235651-005/ UL Batch: 1 MatrIx: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True Control. Found Amount Recovery Limits Flags
(A) (81 %RAnalytes (Dl
4-Bromofluorobensene 0.0511 0.0500 102 74-121
Dibmmofkroxomcthanc 0.0528 0.0500 T 106 80-1201,2-Dicblorocthnne-D4 0.0496 0.0500 99 80-120Tolucnc-D8 0.0477 0.0500 95 81-117
Lab Batch #: 641150 Sample: 235651-013 / SMP Batch: I Matrix: SolidUnits: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
1A1 ID) hRAnalytes
4-Bromofluorobenienc 0.0634 0.0500 127- 74-121 - **
Djbromothjoiomhanc 0.0559 0.0500 112 80-1201,2-Dichloroethane-D4 0.0537 ] 0.0500 107 80-120 1Toiuene-U8 0.0525 f 0.0500 105 81-117 1
Stnrogates outside limits; data and surrogates confinned by reanalysis• Poor recovecies due to dilutionSurrogate Recovery LI)] = 100 * Al BAll results are based on MDL and validated for QC purposes.
Page 19o1 24
XENCOLcborcitorics
Work Order#: 235651Lab Batch 8’: 641150
Units: mg/kg
C Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Project ID:
Sampi.: 235651-fll4 / SM? Butch: I Mutrix: Solid
SURROGATE RECOVERY STUDY
Sunogates outside limits; data and surrogates confirmed by reanalysisPoor recoveries due to dilution
Surrogate Recovery ED] = 100 ‘ A / BAll results arc based on MDL and validated for QC purposes.
VOAs by SW-846 8260B Amount True ControlPound Amount Recovery limits Flags
IAI IBl %RAnalytes
4-Dmmofluorobonzanc 00616 00500 123 74-121Dibromofiuoromcthanc 0.0547 0.0500 109 80-1201,2-Dicbloroethane-D4 0.0534 0.0500 107 80-120Toluene-D8 0.0524 0.0500 105 81-117
Labflaich#: 641150 Sample: 235651-015/SMP Batch: I Matrix:Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True CoatrolFouad Amount Recovery limits Flags
IAI 1BI %RAnalytes ID)
4-Bromofluombcnzene 0.0639 0.0500 128 74-121 •‘
Dibromofluoromedsanc 0.0586 0.0500 117 80-120l,2-Dichloroctbanc-D4 0.0562 0.0500 112 80.120Tolucne-D8 0.0501 0.0500 100 81-117
Lab Batch 8’: 641150 Sample: 235651-016/SMP Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
JAI IBI %RAnalytes jDJ
4-Bromofluorobeazene-- 0.0590 0.0500 1111 74-121
Dibmmofluoromcthane 0.0556 0.0500 111 80-1201,2-Dicbloroethane-D4 0.0539 0.0500 108 80-120Toluene-D8 0.0481 0.0500 96 81-117
Labflatchh: 641150 Sample: 235651-020/SM? Batch: I Matrix:Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-$46 8260B Amount True ControlFound Amount Recovery limits Flags
IA) llAnalytes [Dl
4-Bromofluorobcnz.cnc 0.0669 0.0500 134 74-121 “
Dibronsofluotomeihane 0.0565 0.0300 113 80-120
I,2-Dichlorocthanc-D4 0.0549 0.0500 110 80-120Toluene-D8 0.0534 0.0500 107 81-117
Page 20 of 24
XENCOLcberotorics
Work Order tl/: 235651
Lab Ratch: 641150
Units: mg/kg
( Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
•* Surrogates outside limits; data and surrogates confirmed by reanalysis•S Poor recoveriet due to dilutionSurrogate Recovesy [D] 100 • Al BAll results sic based on MDL and validated for QC purposes.
Sample: 235651-022 / SMP
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flap
IAI IBI %RAnalytes ID)
4-Bmmofluorobenzcne 0.0693 0.0500 139 74-121Dibiomofluoromethane 0.0528 0.0500 106 80-120l,2-Dichloroctbane-D4 0.0521 0.0500 104 80-120Toluene-D8 0.0601 0.0500 120 81-117 •‘
Lab Batch #: 641150 Sample: 235651423/ SMP Batch: I Matrix: Solid
Units: mg/kg SURROGATE RiCOVERY ,IUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Umuti Flags
IAI IBI %R %RAnalytes ml
4-Bromofluorobenzene 0.0601 0.0500 120 74-121Dibromofhioromethane 0.0566 0.0500 113 80-12012-Dichlorocthant-D4 0.0551 0.0500 110 80-120Tolucne-D8 0.0514 0.0500 103 81-117
Lab Batch k 641150 Sample: 235651-024/ SM? Batch: 1 MatrIx: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
IA) JBJ %RAnalytes . IDI
4-Bmmotluorobenunc o.osas o.osoo 117 74-121Dibroinofluoromdltanc 0.0574 0.0500 115 80-1 201,2-Dichlorocthane-D4 0,0541 0.0500 108 80-120Toluene-D8 0.0510 0.0500 102 81-117
Lab Batch 8: 641150 Sample: 235651425/ SMP Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
lAl WIAnalytes [DI
4-Bmmofluorobenzanc 0.0611 0.0500 122 74-121 “
Dlbromolluormnaliauc 0.0570 0.0500 114 tO-1201.2-Dichloroethane-D4 0.0520 0.0500 104 80-120Toluenc-D8 0.0512 0.0500 102 81-117
Page 21 of 24
XENCOLcbarotories
Work Order #: 235651l.sibflatch#: 641150
Units: mg/kg
( Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Surrogates outside limits; data and surrogates confirmed by reanalysis‘ Poor resoveries due to dilutionSurrogate Recovery [DJ 100 *A/BAll results arc based on MDL and validated for QC purposes.
Sample: 235801-001 S/MS
Project IDBatch: 1 Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 82608 AmoUnt True ControlFound Amount Recovery Umita Flags
IAI (BJAnalytes IDI
4-Bromofluorobenzcnc 0.0529 0.0500 106 74123Dibromofluoromctlrane 0.0518 0.0500 104 80-1201,2-Dichlorocthanc-D4 0.0523 0.0500 105 80-120
Toluene-D8 0.0500 0.0500 100 81-117
Lab Batch N: 641150 Sample: 235801-001 SD! MSD Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 82608 Amount True ControlFound Amount Recovery Limits Flags
IAI IBI %RAnalytes 381
4-Bromofluorobcnzene 0.0532 0,0500 106 74423Dibromofluoromethanc 0.0522 0.0500 104 80-1201,2-Dichloroethanc-D4 0.0514 0.0500 103 80-120Toluene-D8 0.0490 0.0500 98 81-317
Lab Batch N: 641 ISO Sample: 461780-1 ‘BKS / OKS BatCh: 1 MatrIx: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Umits Flags
(Al 181 %RAnalytes 3D)
4-Bromotluorobenzene 0.0517 0.0500 103 74-121
Dibromofluoromethanc 0.0545 0.0500 109 80-1201,2-Dicblorocthane-D4 0.0532 0.0500 106 80-120Tolucne-D8 0.0490 0.0500 98 81-117
Lab Batch N: 641150 Sample: 461 780-1-BLK I BLK Batch: 1 Matrix: Solid
Units: tug/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 82608 ‘ Amount True ControlFound Amount Recovery Limits Flags
IAI (RI %R %RAnalytes (Dl
4-&omofluorobcnzcnc 0.0530 0.0500 106 74-121DtbTomufluururrrObauc 0.0535 0.0500 107 80-120
1,2-l)icliloroethane.D4 0.0504 0.0500 301 80-120Tolucne-D8 0.0487 0,0500 97 81-137
rsge 22 of 24
XENCOLcbcratorics
Work Order#: 235651Lab Batch H, 641186
Units: mg/kg
C Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
** Surrogaim outside limits; data and surrogates cordinned by reanalysis
Poor recoveries due to dilutionSurrogateRecovery [I)]= 100 AIBAll results are based on Ml)L and validated for QC purposes.
Sample: 235651-003 /DL
Project ID:
Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
IAI IBI
Analytcs D)
4-Bromofluorobenzene 0.0542 0.0500 - 108 74-121
Dibmmoiluo,omethane 0.0568 0.0500 114 80-120
l.2-Dichloroetbane-D4 0.0519 0.0500 104 80-120
Tolucne-D8 0.0487 0.0500 97 81-117
Lab Batch II: 641186 Sample: 235651.019/ SMP Bitch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
IM ID)Anaiytes - IDI
4.Bromolluorobenzcne 0.0586 0.0500 117 74-121
Dibromotluoromctbane 0.0515 0.0500 103 80-120
l,2-Dichlorocthane-D4 0.0523 0.0500 105 80-120
Tolucne-08 0.0524 0.0500 105 81.117
Lab Batch /I: 641186 Sample: 235651-019 S/MS Bitch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY SfUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Limits Flags
JAI IBI
Analytes ID)
4-Brornofluorobcnzcne 0,0567 0.0500 113 74-121
Dibromofluorotnethane 0.0539 0.0500 108 80-120
1,2-Dichlorocthanc-D4 0.0553 0.0500 111 80-1 20
Toluene-t)8 0.0537 0.0500 107 81-117
Lab Batch 4: 641186 Sample: 235651-019 SI) / MSD Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOM by SW-846 8260B Amoum True CmilroiFonid Amount Recovery limits Flags
IAI [B ‘AR
Analytes ID]
4-Bromofiuorobcnzcne 0.0581 0.0500 116 74-121
DIbsomOfluOjoIflethafle 0.0335 0.0300 107 80-120
1,2-Dichlorocthane-D4 0.0547 0.0500 109 80-120
Toh,cnc-D8 0.0537 0.0500 107 1 81-117 1
Page 23 of 24
XENCOLc%borotorics
Work Order #: 235651LabBatchtl: 641186
Units: tog/kg
Form 2 - Surrogate RecoveriesProject Name: Koppers Creosote Facility
Sirrogates outside limits; data and surrogates confirmcd by reanalysis‘ Poor resovesies due to dilutionSurn,gacReiy[D 30O A/BAiresu1i are based on MDL and validated lbr QC purposes.
l’age 24 of 24
Sample: 461800-l--BKS / BKS
Project ID:Batch: I Matrix: Solid
SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Umita Flags
IAI 11 %RAnalytes 11)1
4-Bromoiluorobcnzcnc 0.0507 0.0500 101 74-121Dibromofluoromcthanc 0.0529 0.0500 106 80-120l,2-Dicbloroethanc-D4 0.0557 0.0500 Ill 80-120Tolucne-D8 0.0501 0.0500 100 81-117
Lab Batcb*: 641186 Sample: 461800-l-BLK/BLK Batch: I Matrix: Solid
Units: mg/kg SURROGATE RECOVERY STUDY
VOAs by SW-846 8260B Amount True ControlFound Amount Recovery Umita Flaga
IAI IBIAnalytes P1
4-BromoThiorobcnzcne 0.0522 0.0500 104 74-121Dibromofluoromethane 0.0531 0.0500 106 80-1201,2.Dlchloroethane-04 0.0503 0.0500 101 80-120Tolucne-D8 0.0503 0.0500 101 81-117
SUM
MA
RY
OF
SAM
PLiN
GA
ND
AN
AL
YSIS
—PR
EL
IMIN
AR
Y,
SU
BJE
CT
TO
CH
AN
GE
K0P
PE
Rs
WO
OD
PRE
SER
VIN
GFA
CIL
ITY
GR
EN
AD
A,
MISSISSIPPI
CA
SE
FIELDCA
MPA
IGN
No.
1M
AY
29.2
003
VE
RsIoN
Site
Nam
eI
Location
-K
oppersw
oodtreating
facilityG
renada,M
ississippi
Environm
entalM
ediato
beS
ampled
Indoordust
Stream
andditch
sediments
Groundw
ater(possible
futurefield
campaign)
IndoorD
ustS
ampling
Collect1
composite
sample
of indoordustfromeach
residenceto
betested.
Sam
pleto
becollected
fromattic,air and
heatingvents,
behindappliances, bookshelves, and
other areasthatare
notroutinelycleaned.
This
willbe
representativeof
“olddust.”
Use
HV
S-3forensic
vacuumsystem
tocollectsam
plesA
STMStandard
D-5438
tobe
usedas
aguideline
Fieldblanks
andother
QA
IQC
samples
tobe
tested-
Sam
plesof
indoordust
willbe
collectedat
approximately
20-30residences
inor
nearG
renada;addresses
tobe
sampled
aresum
marized
inT
able1
Sam
plesof
indoordust willbe
collectedat the
Grenada
Elem
entarySchool
(dust+
filters)S
amples
ofindoor
dustwillbe
collectedat the
Grenada
Middle
School(dust
+filters)
Sam
plesof
indoordust w
illbe
collectedatthe
Baptist
Church
(dust+
filters)S
amples
ofrepresentative
creosotem
aterialwillbe
collectedfor forensic
identificationT
estabout
10sam
plesfor
Dioxins,and
therem
ainder forPA
Hs
Sam
plingand
Analysis
Sum
mary
-P
reliminary,
Subject to
Change
Field
Cam
paignN
o.1
Page
1
Stream
andD
itchS
ampling
Use
conventionaltechniques
(grab,hand
auguring)for
sample
retrievaland
preservationS
amples
willbecollected
fromthe
centralIupgradientditch
atthesouthw
estcornerofthe
Koppers
plantS
amples
willbe
collectedin
Batupan
Bogue
Creek
nearthe
intersectionofT
iePlant
Road
andthe
Creek.
Sam
pleswill
becollected
inthe
northditch
atthenorth
cornerof
theK
oppersplant
Approxim
ately6
locationswillbe
sampled
at eachof the
ditchesI creek
areas.C
ollectdiscretesedim
entsamples
at0.5,1.0,and
2.0feetbgs
usinghand
augersorsim
ilarsam
plingdevices
ateachsam
plingpoint.
-D
itcheswill
besam
pledusing
hipw
aders,to
theextent
practical.C
reekarea
willrequirea
boatorsim
ilarm
eansto
support thesam
plingcrew
.S
ampling
ofC
ontrolG
roupN
ocontrol
groupsam
plingwillbe
performed
aspart of
thisphase
of work.
Sam
plesof
thefollow
ingm
aterialswill
beobtained
fromK
oppersfor
futureforensic
identification:currentproductioncreosote
oil,currentproductioncreosote
impregnated
cross-tie,currentproduction
creosoteim
pregnatedpow
erpole, heavilycontam
inatedI w
eatheredcreosote
soil.
Sam
pleC
ollectionD
ocumentation
Standard3TM
InternationalS
ample
Collection
LogI
FieldN
otesC
hain-of-custodyand
sample
preservationPhotographs
ofsampling
locationsb
GPS
readingsof
sampling
locations
Sam
pihigand
Analysis
Sununary
-P
reliminary,
Subject
toC
hangeF
ieldC
ampaign
No.
1P
age2
Analytical
Testing
Sam
plesto
besubm
ittedto
AX
YS
Analytical
inSidney,
BC
Canada
fortesting
Sam
plesto
betested
forcreosote
PAH
susing
Method
8270mod
lowresolution
GC
/MS.
Sam
plesto
betested
forchlorinatedphenols
usingM
ethod1653m
odlow
resolutionG
CIM
SIfsufficient
sample
aliquotis
available,then
severalsam
plesm
aybe
forensicallytested
usinglightI
lRand/or
electronm
icroscopyIftesting
forPAH
sindicates
positiveresults,then
samples
willbetested
for Dioxins
IFurans
usingM
ethods161
3bhigh
resolutionG
CIM
S;iftesting
forPA
Hs
doesnotindicate
positiveresults,
thensam
pleswillnot
betested
forD
ioxinsI
Furans
Laboratory
touse
highlevel
QA
/QC
Laboratory
datato
besubm
ittedto
3TMin
hardcopy,
pdfformat,
andE
xcel format
Forsam
plesw
ithpositive
PAH
results,forensic
fingerprintingwill
beconducted
ona
representativenum
berof
samples
topositively
identifythe
material
ascreosote,
andnot
some
otherm
aterialIf
sufficientsam
pleextract
isavailable,
aportion
ofthe
sample
willbe
archivedby
thelaboratory
foruse
bythe
defendant,ifrequested
Data
Report
Upon
receiptoftheanalyticaltesting
data,3TM
will preparea
formal
Sum
mary
Reportthat
includesthe
following:
—O
verviewofthe
fieldprogram
—S
ample
collectionlogs
andfield
notes—
Photographs—
Sitesketches
—G
PSreadings
—Sum
mary
ofanalyticaltesting
results—
Summ
aryofforensic
fingerprintingofselected
samples
—O
therfindings
Work
Schedule
Kick
offfieldcam
paignin
lateJune
orearly
July2003
Sam
plecollection
fieldw
orkwill
requireapproxim
ately_____field
daysA
nalyticaltesting
turnaroundtim
ewill
beapproxim
ately4-6
weeks
-Sum
mary
Report
willbe
submitted
approximately
2-4w
eeksafter
receiptof
thefinal
analyticaldata
Sam
plingand
Analysis
Sum
mary
-P
reliminary,
Subjectto
Change
Field
Cam
paignN
o.1
Page
3
Table
1N
ames
and
Addresses
ofResidences
toB
eS
ampled
(IndoorD
ust)
#A
ddressR
esident Nam
eL
ongitudeL
atitudeP
Ails
Dioxins
1Steve
Cole
tofillin
234567891011121314151617
Sampling
andA
nalyeisS
umm
ary- P
reliminary,
Subject toC
hangeF
ieldC
ampaign
No.
1P
age4
18192021222324252627282930
Sam
plingand
Analysis
Sum
mary
-P
reliminary,
Subject
toC
hangeF
ieldC
ampaign
No.
1P
ageS
S:\3TM
litat1oual_N
eMcliits\L
awdy
&D
aiL
&D
.KoppeiiW
oodP
irvngW
IeIdC
anipilgaflSam
pllngS
ununalyMayZ92003.wpd
Sam
plingand
Analysis
Sum
mary
-P
reliminary,
Subject
toC
hangeF
ieldC
ampaign
No.
1P
age6
Analytical Report 236028
for
3TM International
Project Manager: Randy Horsak
Koppers Creosote Facility
3TM-LD-022003-02
19-AUG-03
XENCOLciboratorics
11381 Meaciowglen, Suite L Houston, TX 77082 Ph:(281) 589-0692 Fax:(281) 589-0695
Houston - Dallas- San Antonio - Austin - Tampa - Miami - Latin America Page 1
XENCOLciborcltoric5 I1 9-AUG-03
Project Manager: Randy Horsak3TM International1500 South Dairy Ashford, Suite 225Houston, TX 77077
Reference: XENCO Report No: 236028Koppers Creosote FacilityProject Address: Grenada, Mississippi
Randy Horsak:
We are reporting to you the results of the analyses performed on the samples received under the project namereferenced above and identified with the XENCO Chain of Custody Numbered 236028. All results beingreported under this Chain of Custody apply to the samples analyzed and properly identified with a LaboratoryID number.
All the results for the quality control samples were reviewed. Also, all parameters for data reduction andvalidation were reviewed. In view of this, we are able to release the analytical data for this report withinacceptance criteria for accuracy, precision, completeness or properly flagged.
The validity and integrity of this report will remain intact as long as it is accompanied by this letter andreproduced in full, unless written approval is granted by XENCO Laboratories. This report will be filed for atleast 5 years in our archives after which time it will be destroyed without further notice, unless otherwisearranged with you. The samples received, and described as recorded in COC No. 236028 will be filed for 60days, and after that time they will be properly disposed without further notice, unless otherwise arranged withyou. We reserve the right to return to you any unused samples, extracts or solutions related to them if weconsider so necessary (e.g., samples identified as hazardous waste, sample sizes exceeding analytical standardpractices, controlled substances under regulated protocols, etc).
We thank you for selecting XENCO Laboratories to serve your analytical needs. If you have any questionsconcerning this report, please feel free to contact us at any time.
Respectfully,
Recipient of the Prestigious Small Business Administration A ward ofExcellence in 1994.Cent/led and approved by numerous States andAgencies.
A Small Business and Minority Status Company that delivers SER VICE and QUALITY
Laboratory Manager
Houston - Dallas - San Antonio - Austin - Tampa - Miami - Latin America
2 3 4 5 6 7 8 9 10
I’
1138
1M
eado
wgl
en,S
uite L
Hou
ston
TX77
082
281.
589-
0692
-•
k0
5309
Wur
zbac
hR
oad,
Suite
104.
Sar
iA
nton
io.
TX78
238
21
0-5
Ct.
.-3
4
011
078
Mor
rison
hi,
Suite
D,
Dal
las,
TX75
229
972-
481-
9999
AN
AL
YS
ISR
EQ
UE
ST
&C
HA
INO
FC
US
TO
DY
RE
CO
RD
On
-L
IN
EH
elp
&T
echnicalS
ervices
at
ww
w.
XE
NC
O.c
on
.
Com
pan
yC
OC
No:
Wor
kO
rder
No:
I0S
ISO
Pag
e/of
2 A 6
Com
pany
Pho
neL
abO
nly:
7‘2
’7
//
lab
Onl
y
3TiY
l(/)
‘t9
7/a
30
(_..
/A
dditi
ons
Pro
ject
Nam
ePr
evio
usly
done
”at X
ENC
OP
roje
ctID
TAT:
5h12
h20
h24
h48
h3d
5d7d
14d
21d
Sta
ndar
dTA
T)v
orl
dn
gD
ays
VJp
p.o
r5(‘
rrc,c
r,f
IJ):
t,3
T4
Lb
•-O
po(3
unle
ssot
herw
ise
agre
edin
wri
fln
But
ofte
nre
port
ecN
n5-
7W
orki
ngD
ay
s_
__
__
__
Loc
1ton
rP
ifrr
‘
Rem
arks
Pro
ject
Man
ager
(PM
)P
roje
ctD
irec
tor
(PD
)-
8i?
Qf7
df.
1rg
YFa
xR
esult
so1’M
and
/or
Fax
>.
,.>
.
-rJ
()
u.
invo
ice
toC
Acc
ount
ing
Incl
ude
Invo
ice
with
Fina
lR
epor
tA
ttnPM
Cin
voic
e2
mus
th
ave
aP.O
Bill
to:
.ö
Quo
teN
o.P.
ON
oC
Cal
lfo
ra
P.O
.
Spe
cial
Dis
cRR
IRR
IiD
WQ
APP
See
Lab
PMC
oil
Proj
.P
M)
‘0Q
I)
I...
Spe
cifi
cati
ons
QA,i(
iC_
4r’L
r-c
7c*jtii
7g
2i
..
-
Sam
pler
Nam
e7TD1
4%
’y
’g
natu
re..,..—
——
-S
‘0.0
>
—
sam
plin
ge
>‘
Sam
ple
IDD
ate
lim
eE
<>
.
Tfl1
-K
P5
!-r-ø
i//ôJ3”S
XIç
--
I—
----—
-—
-—
‘.77Y
)-K
P-9
jZ.-
E33
‘13L
’OV
-—
i41
!ZP
•-5
AfL
)-7
.g
//
03
3T
h1-K
-5F
iD’Q
I
r,ii
-icp
s-A
m..
3
3r/
11
KP
5T
A-O
i_T
lr
:T
.-K
prh_
-—
--—
--—
---—
——
--—
—
II15
3TY
”l-k
p55
tI)
O“1
bl(
)\i
V‘4’
‘/V
‘/
Rel
inqu
ishe
dby
(ln
ltIoi
san
dS
ign.
)D
ate
&T
ime
Rel
inqu
ishe
dro
”?T
nuii
and
sign.)
—L
)ate
Icfi
iie
aië
orii
rsr
ocT
7C
oole
rT
emp:3
2.
7JDz-’-
ff2
Rus
hTA
TsFa
xD
ue:
Fina
lFa
xD
ue:
/‘7
(Th
-
Rno
iR
epor
tD
ata
Pac
kage
Due
Dot
e:
Lab
ç,,>
IC/21b
(fv
ush
Ch
arg
esar
ePre
-Ap
pro
ved
upon
Req
uest
ing
them
.Al
lTer
ms
App
ly
7 S 9 1C
Pre
sew
atlv
es-
Var
ious
(V).
HCI
pH.c
2(H
),H
2S04
pH<2
(S),
HN
Q3
pH
2(N
),N
aOH
+A
sbc
Aci
d(N
M),
ZnA
c+N
aOH
(ZA
),(C
ool,
<40
)(C
4).
Non
e(N
),Se
eL
abel
(Si)
,O
ther
(0)_
__
__
__
__
__
__
__
_
SIZE
:4oz
(4),
Boz
(8),
32oz
(32)
,40
m1
VO
A(V
),1L
(1),
SOOr
nI(.5
),T
edla
rB
ag(B
),W
ipe
(W),
Oth
er
__
__
__
__
__
TYPE
Gla
ssA
mb
(GA
).G
lass
Cle
ar(G
C),
Plas
tic(P
).O
ther
(0)_
__
__
__
__
__
__
__
_
2 3 4 5 6 7 8 9 10 2 3
2 3 4 5 6 7 8 9 10
1138
1M
eado
wgl
en,
Suite
LH
oust
onTX
7708
228
1-58
9-06
92
053
09W
urzb
ach
Roo
d.Su
ite10
4Sa
nA
nton
io, T
X78
238
210-
5Ct
..,.s3
4
011
078
Mor
rIso
nLn
,Sui
teD.
Dal
las,
TX75
229
972-
481-
9999
AN
AL
YS
ISR
EQ
UE
ST
&C
HA
INO
FC
US
TO
DY
RE
CO
RD
On-
LIN
EH
elp
&T
echn
ical
Ser
iice
sat
ww
w.X
EM
CO
.CO
tb.
Com
pan
yC
OC
No;
Wor
kO
rder
No:
j05
161
Pag
eof
aC
ompa
nyP
hone
Lab
Onl
y:7f
7(7
lob
Onl
y14r,1
j;:1
:g
c.
(g
C..—
...}
)L
-’-
3(
JA
dditi
ons
Pro
ject
Nam
eR
’Pre
vlou
sly
done
atX
ENC
OPr
ojC
fID
TAT:
5h12
h20
h24
h48
h3d
5d7d
14d
21d
Sta
ndar
dT
AT
,yor1
dng
Day
s
Kop
p-c
F(;
3rA
-Lb
unle
ss0t
hrw
lse
agre
edh
wri
ting
But
ofte
nre
port
ecH
n5-
7W
orkI
ngD
ays_______
Loc
atio
n—
Rem
arks
Pro
ject
Man
ager
(PM
)P
roje
ctD
irec
tor
(PD
)8
?c4
t4H
o’k
Fax
Res
ults
toPM
and
Ior
Fax
..
I)‘
,>
,
i.Y1
igi)
c9’
-U
-(n
Invo
ice
to0
Acc
ount
ing
,‘ln
clu
do
Invo
ice
with
Fina
lR
epor
tA
ttnPM
0In
voic
em
usthav
ea
P.O
Bill
to:
0o
Ee
‘9
Quo
teN
o.P.
ON
oC
Cal
lfo
ra
P.O
.L
J’0Q
O.
Spec
ial
DLs
CPP
IP
R)
DW
QA
PPS
eeL
abPM
Cal
lPr
oj.
PM
),
3S
peci
flca
tlon
sA
/aC
.4
,/
r-t’
ñ
Sam
ple
rNam
e••
J.•.
S‘0
‘0
.,.
Sam
plin
g-
e—
Sam
ple
IDD
ate
Tim
eE
<.S
.0
c)
fr4-kp.j-,.
3R
/7/3
c#-
xX
——
—-
7-i
p8Ic
tP)K
L.L
c±
___
elln
quIs
hed
by(
Initi
als
and
Sig
n.)
Dot
e&
lim
eR
elin
quis
hed
to(i
niti
als
and
sig
n.)
Dat
e&
lim
eT
otal
Con
tain
ers
per
CC
C:
Coo
ler
Tem
p:
7zy
’f2
-,!-
/T
/3
,‘S
Z)
Rus
hTA
TsFa
xD
ue:
Fina
lFa
xD
ue:
‘,(‘
-L
,Fi
nal R
epor
tD
ata
Pac
kag
eD
ueD
ate:
Lab—
€)-’s
/j
Vhu
shC
har
ges
are
Pre
-App
rove
dup
onR
eque
stin
gth
em.
All T
erm
sA
pply
Pre
serv
ativ
es-
Var
ious
(V).
HC1
pH<2
(H),
H2S
04pH
<2(S
).H
NO
3,,p
W<2
(N),
NaO
H÷
Asb
cA
cid
(NA
A),
ZnA
c+N
aOH
(ZA
),(C
ool,<
4C)
(C4)
,N
one
(N),
See
Lab
el(S
L),
Oth
er(0
)
__
__
__
__
__
__
__
__
SIZE
:4oz
(4),
8oz
(8).
32oz
(32)
,sI
Om
l VO
A(V
),11
.(1)
.50
0ml
(.5),
Ted
lar
Bag
(8),
Wlp
e(‘#
1),
Oth
er
___________
TYPE
Gla
ssA
rnb
(GA
),G
lass
Cle
ar(G
C),
Plas
tic(P
),O
ther
(0)
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3TM
Inte
rnat
ional
,H
oust
on,T
XP
roje
ctId
:3T
M-L
D-0
2200
3-02
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ilit
y
Thin
anal
ytic
alre
port
,an
dth
eee
ttre
data
pack
age
itre
pres
ents
. has
been
mad
er
your
excl
uoiv
ean
dco
nfid
entia
l use
.Th
ein
terp
reta
tions
and
resu
ltsex
pres
sed
thro
ugho
uttid
ean
alyt
ical
repo
rtre
pres
ent t
hebe
ntju
dgm
ent o
f XE
NC
OL
abor
ater
iei
XEN
CO
Lab
orat
orie
sas
sum
esno
reup
onoi
bilit
yan
dm
akes
now
arra
nty
totir
een
dus
eof
the
data
here
bypr
esen
ted.
Our
liabi
lity
Ialim
ited
toth
eam
ount
invo
iced
for t
his
wor
kor
der u
nite
sot
herw
iuc
agre
edto
inw
ritin
g.
Sinc
e19
90H
oust
on-
Dal
las
-S
anA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-L
atin
Am
eric
a‘it
Bar
ron
Lab
ora
tory
Man
ager
XEN
cOL
oboro
ori
cs
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
ecei
ved
inL
ab:
Fri
Aug
-08-
0303
:00
pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
onL
abId
:23
6028
-001
2360
28-0
0223
6028
-003
2360
28-0
0423
6028
-005
2360
28-0
06•
Fie
ldid
:3T
M-K
P-SS
-JC
-O1
3TM
-KP-
SS-J
C-0
23T
M-K
P-SS
-JC
-03
3TM
-KP-
SS-N
D-0
l3T
M-K
P-SS
-ND
-02
3TM
-KP-
SS-N
D.0
3A
naly
sis
Req
uest
edD
epth
:6-
In6-
In6-
In1-
ft1-
ft1-
ftM
atri
x:SO
ILSO
ILSO
ILSO
ILSO
ILSO
IL—
__
___________________________
Sam
pled
:A
ug-0
6-03
12:3
0A
ug-0
6-03
12:4
0A
ug-0
6-03
13:0
0A
ug-0
7-03
08:1
0A
ug-0
7-03
08:4
5A
ug-0
7-03
09:3
0
Per
cent
Moi
stur
eE
xtra
cted
:
Ana
lyze
d:A
ug-1
1-03
15:2
4A
ug-1
1-03
15:2
8A
ug-1
1-03
15:3
0A
ug-1
1-03
l5:3
2A
ug-1
1-03
15:3
4A
ug-1
1-03
15:3
6U
nitc
/RL
:%
RI..
%RI
..%
RI
%R
L%
RL
%R
LPe
rcen
tMoi
stur
e20
.51.
00J
19.7
1.00
17.3
1.00
21.3
1.00
26.7
1.00
16.4
1.00
SVO
AP
AR
sL
ist
byE
PA
8270
CE
xtra
cted
:A
ug-1
1-03
10:0
9A
ug-1
1-03
10:1
2A
ug-1
1-03
10:1
5A
ug-I
1-03
10:1
8A
ug-1
1-03
10:2
1A
ug-1
1-03
10:2
4A
naly
zed:
Aug
-14-
0319
:52
Aug
-14-
0320
:35
Aug
-15-
0302
:24
Aug
-16-
0300
:53
Aug
-15-
0303
:06
Aug
-15-
0303
:49
Uni
ts/R
L:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RI
Ace
naph
ihen
eB
RL
0.20
9B
RL
0.20
7B
RL
0.20
1B
R!..
0.21
1B
RL
0.22
7B
RL
0.19
9A
cena
phth
ytne
BR
L02
09B
RL
0207
BR
!..0.
201
BR
L0.
211
BR
L0.
227
BR
L0.
199
Ant
hrac
ene
—BR
!..0.
209
BR
L0.
207
BR
!..02
01B
RL
0.21
1B
R!..
0.22
7B
RL
0.19
9B
enzo
(a)a
nthr
acen
e—
BR
L0.
209
BR
L0.2
0r
BR
L02
0102
930.
211
BR
L02
27B
RL
0.19
9B
enzo
(a)p
yrsn
eB
RL
0.20
9B
R!..
0.20
7B
R!..
0.20
10.
266
0.21
1B
RL
0.22
7B
RL
0.19
9B
enzo
(b)t
luor
anth
ene
BR
I..0.
209
BR
!..0.
207
BR
L0.
201
0.59
20.
211
BR
L0.
227
0.29
50.
199
Ben
zo(g
,h,i)
pery
lert
eB
RL
0.20
9B
RL
0207
BR
L0.
201
BR
L0.
211
BR
L0.
227
BR
]..0.
199
Ben
zo(k
)flu
oran
then
e—
BR
L0.
209
BR
L0.
207
BR
L0.
201
0.70
90.
211
BR
L0.
227
BR
L0.
199
Chr
ysen
eB
RL
0209
BR
L02
07B
R!..
0201
0404
02
11
jB
RL
0227
0230
0199
Dib
enz(
a,h)
Ant
hrac
ene
BR
L02
09B
RL
0.20
7B
RL
0.20
1B
RL
0.21
1L
BR
L0.
227
BR
L0.
199
Fluo
rant
henc
BR
L0.
209
BR
L0.
207
BR
L0.
201
-0.
495
0.21
1B
RL
0.22
70.
326
0.19
9Fl
uore
neB
RL
0.20
9B
RL
0.20
7B
RL
0.20
1B
RL
0.21
1B
RL
0.22
7B
RL
0.19
9In
deno
(l,2
,3-c
,d)P
yren
eB
RL
0.20
9B
RL
0.20
7B
RL
0.20
1B
RL
0.21
1B
RL
0.22
7B
RL
0.19
9N
apht
hale
neB
RL
0.20
9B
RL
0.20
7B
RL
0201
BR
!..0.
211
BR
!..0.
227
BR
L0.
199
Phen
anth
rene
BR!..
0.20
9B
RL
0.20
7B
RL
0.20
1B
R]..
0.21
1B
R!..
0.22
7B
RL
0.19
9Py
rene
BR
L0.
209
BR
L0.
207
BR
L0.
201
0.60
80.
211
BR
L0.
227
0.28
80.
199
Page
1
Dat
eR
ecei
ved
inL
ab:
Fri
Aug
-08-
0303
:00
pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
on
Lab
kb23
6028
-001
2360
28-0
0223
6028
-003
2360
28-0
0423
6028
-005
2360
28-0
06
Fie
ldId
:3T
M-K
P-SS
-JC
-01
3TM
-KP-
SS-J
C-0
23T
M-K
P-SS
-JC
-03
3TM
-KP-
SS-N
D-0
13T
M-K
P-SS
-ND
-02
3TM
-KP-
SS-N
D-0
3A
naly
sis
Req
uesl
edD
epth
:6-
In6-
In6-
In1-
ft1-
ft1-
ft
Mat
rir
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
Sam
pled
:A
ug-0
6-03
12:3
0A
ug-0
6-03
12:4
0A
ug-0
6-03
13:0
0A
ug-0
7-03
08:1
0A
ug-0
7-03
08:4
5A
ug-0
7-03
09:3
0
VO
Asb
ySW
—84
682
60B
Exi.r
acge
d:A
ug-1
4-03
17:1
0A
ug-1
4-03
17:1
6A
ug-1
4-03
17:1
8A
ug-1
4-03
17:2
0A
ug-1
4-03
17:2
2A
ug-1
4-03
17:2
4
Ana
lyze
d:A
ug-1
4-03
18:2
3A
ug-1
4-03
19:2
7A
ug-1
4-03
19:4
9A
ug-1
4-03
20:1
0A
ug-1
4-03
20:3
2A
ug-1
4-03
20:5
4
Um
a/R
L:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
Bcn
zene
BR
L0.
006
BR
L0.
006
BR
L0.
006
SR
I.0.
006
BR
L0.
007
BR
L0.
006
Bro
mob
enze
ne-—
BR
L0.
006
SR
I.0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Bro
moc
lilor
omet
hane
——
__
__
__
_______
—B
RL
0.00
6SR
I.0.
006
SRI.
0.00
6U
RL
0.00
6B
RL
0.00
7B
RL
0.00
6B
rom
odic
hior
omet
hane
—B
RL
0.00
6BR
.L0.
006
BR
.L0.
006
BR
I0.
006
BR
L0.
007
BR
L0.
006
Bro
mof
orm
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Bro
mom
etha
neB
RL
0.00
6S
RI
0.00
6SR
I.0.
006
BR
L0.
006
BR
L0.
007
jB
RL
0.00
6—
—-
BR
L0.
006
BR
L0.
006
BR
L0.
006
SRL
0.00
6B
RL
0.00
7—
ER
L0.
006
tert
-But
ylbe
nzen
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6—
BR
L0.
007
1B
RL
0.00
6Se
c-B
utyl
benz
ene
——
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0,
007
jB
RL
0.00
6n-
But
ylbe
nzer
ie—
.B
RL
0.00
6—
—B
RL
0.00
6[
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Car
bon
Tet
rach
iori
de—
-B
RL
0.00
6—
BR
L0.
006
BR
L0.
006
BR
L0.
006
SR
I0.
007
L._..
BR
L0,
006
Chl
orob
enze
neB
RL
0.00
6S
RI
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
6C
hior
oeth
ane
—B
RI.
0.01
2B
RL
0.01
2B
RL
0.01
2B
RL
0.01
3B
RL
0.01
3B
RL
0.01
2C
hlor
ofor
m—
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
-—
.B
RL
O.0
06
Chi
orom
etha
ne—
—S
RI
0.01
2S
RI
0.01
2B
RL
0.01
2B
RL
0.01
3B
RI.
0.01
3B
RL
0.01
22-
Chl
orot
olue
neB
RL
0.00
6B
RI
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7j
BR
I.0.
006
4-C
hlor
otol
uene
—______
BR
I0.
006
BRI.,
0.00
6B
RI
0.00
6B
RL
0.00
6B
RL
0.00
7j
BR
L0.
006
p-C
ymen
e(p-
Isop
ropy
ltolu
ene)
-B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
R!..
0.00
6B
RL
0.00
7j
BR
I.0.
006
l.2-D
ibro
mo-
3-C
hlor
opro
pane
——
BR
L0.
006
BR
I.0.
006
SR
I.0,
006
BR
L0.
006
BR
L0.
007
BR
I.0.
006
Dib
rom
ochi
orom
etha
ne—
—B
RI.
0.00
6B
RL
0.00
6S
RI.
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
6D
ibro
mor
neth
ane
——
__
__
__
BR
L0.
006
BR
L0.
006
BR
L0,
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
I,2-D
ichl
orob
enze
ne—
BR
J.0.
006
SRI.
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
6I.3
-Dic
hlor
oben
zene
—B
RI.
0.00
6B
RL
0.00
6B
RL
0.00
6SR
I.0.
006
—S
RI.
0.00
7B
RL
0.00
61,
4-D
ichl
orob
enze
neS
RI
0.00
6B
RL
0.00
6S
RI,
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
6D
ichi
orod
iflu
orom
etha
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
6S
RI.
0,00
6B
RL
0.00
7B
RL
0.00
6
XE
I CO
Lob
orci
tori
es
Pro
ject
Id:
3TM
-LD
-022
003-
02
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3TM
Inte
rnat
iona
l,H
oust
on,T
XP
roje
ctN
ame:
Kopper
sC
reos
ote
Fac
ilit
y
This
anal
ytic
alre
putt,
and
the
entir
eda
tapa
ckag
eit
repr
esen
ts, h
asbe
enm
ade
thry
our s
eclu
sive
and
conf
iden
tial u
se.
The
inte
rpre
tati
ons
and
resu
ltsae
prea
sed
thro
ugho
utth
isan
alyt
ical
repo
rtre
pres
ent t
hebe
ntju
dgm
ento
fXEN
CO
Lab
orat
orie
s.X
Ey4C
OLa
bora
torie
sas
sum
esno
resp
onsi
bilit
yan
dm
akes
now
arra
nty
toth
een
dus
eoft
heda
tahe
reby
pres
ente
d.O
urliu
bilu
tyIs
limite
dto
thu
amou
ntin
voic
edfo
rthi
sw
ork
orde
run
less
othe
rwis
eag
reed
loin
writi
ng.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-La
tinA
mer
ica
iiron
Labo
rato
ryM
anag
erPa
ge2
This
anel
ytic
ilre
port
,an
dth
een
tire
data
pack
age
itre
prew
tts,
has
been
mad
efo
ryou
rsx
chss
ive
sad
conf
iden
tial u
se.
The
inte
rpre
tatio
nsan
dre
sults
enpr
eusa
dth
roug
hout
this
anal
ytic
alre
port
repr
esen
t the
beat
judg
men
tof
XE
NC
OL
abor
stot
lee.
XE
NC
OL
abor
ator
ies
aoau
mes
nore
spon
sibi
lity
and
mak
esno
war
rant
yto
the
end
use
ofth
eda
tahe
reby
pres
ente
d.O
urlia
bilit
yis
limite
dto
the
amou
ntin
voic
edfo
r thi
sw
ork
orde
r unl
ess
othe
rwis
eag
reed
toin
writ
ing.
Lob
orci
tori
csC
erti
fica
teof
Ana
lysi
sS
umm
ary
2360
283T
MIn
tern
atio
nal,
Hou
ston
,T
XP
roje
ctId
:3T
M-L
D-0
2200
3-02
Pro
ject
Nam
e:K
oppe
rsC
reos
ote
Fac
ilit
yC
onta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
ecei
ved
inL
ab:
FriA
ug-0
8-03
03:0
0pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
onL
abId
:23
6028
-001
2360
28-0
0223
6028
-003
2360
28-0
0423
6028
-005
2360
28-0
06F
leld
Id:
3TM
-KP-
SS-J
C-0
13T
M-K
P-SS
-JC
-02
3TM
-KP-
SS-J
C-0
33T
M-K
P-SS
-ND
-01
3TM
-KP-
SS-N
D-0
23T
MK
PS
SN
DO
3A
naly
sis
Req
uest
edD
epth
:6-
In6-
In6-
In1-
ft1-
ft1
ftM
atri
x:SO
ILSO
ILSO
ILSO
ILSO
ILSO
ILSa
mpl
ed:
Aug
-06-
0312
:30
Aug
-06-
0312
:40
Aug
-06-
0313
:00
Aug
-07-
0308
:10
Aug
-07-
0308
:45
Aug
-07-
0309
:30
VO
As
bySw
—84
682
60B
Ext
ract
ed:
Aug
-14-
0317
:10
Aug
-14-
0317
:16
Aug
-14-
0317
:18
Aug
-14-
0317
:20
Aug
-14-
0317
:22
Aug
-14-
0317
:24
Ana
lyze
d:A
ug-1
4-03
18:2
3A
ug-1
4-03
19:2
7A
ug-1
4-03
19:4
9A
ug-1
4-03
20:1
0A
ug-1
4-03
20:3
2A
ug-1
4-03
20:5
4U
nits
iRL
:m
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Im
g/kg
RL
mg/
kgR
L1,
2-D
ichi
oroe
than
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
61,
1-D
ichl
oroe
than
e-____________________
__
__
_-
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.0
071
BR
L0.
006
tran
s-I
,2-d
ichl
oroe
then
e—
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
cis-
1,2-
Dic
hlor
oeth
ene
BR
L0.
006
—B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6—
BR
L0.
007
BR
L0.
006
1,1-
Dic
hior
oeth
ene
—B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0,00
7B
RL
0.00
62.
2-D
ichi
orop
ropa
neB
RL
0.00
6B
RL
0.00
6B
RI
0.00
6B
RL
0.00
6B
RL
0.00
7-
—_
_B
RL
0.00
61,
3-D
ichi
orop
ropa
ne—
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
LO
.006
1,2-
Dic
hior
opro
pane
[B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
OM
O7I
BR
L0.
006
tran
s-I ,
3-di
chlo
ropr
open
e-
OR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
‘
BR
L0.
006
IID
ichl
orop
rope
ne-
—B
RL
000
6B
RL
000
6B
RL
000
6B
RL
000
6B
RL
000
7B
RL
000
6ci
s-I,
3-D
ichl
orop
rope
neB
RL
0,00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
6E
thyl
benz
ene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
—B
RL
0.00
6H
exac
hlor
obut
adie
ne—
BR
L0.
006
BR
I0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
isop
ropy
iben
zene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
-B
RL
0.00
7B
RL
0.00
6M
ethy
lene
Clil
orid
eB
RL
0.02
5U
RL
0.02
5B
RL
0.02
4—
BR
L0.
025
BR
L0.
027
BR
LO
.024
Nap
htha
lene
BR
L0.
012
BR
L0.
012
BR
L0.
012
BR
L0.
013
BR
L0.
013
BR
L0.
012
n-Pr
opyl
benz
ene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Styr
ene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
1,1,
1,2-
Tet
rach
loro
etha
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
61,
1,2,
2-T
etra
chio
roet
hane
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Tet
rach
loro
ethy
lene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Tol
uene
BR
L0.
006
BR
L0,
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
1,2,
4-T
rich
loro
benz
ene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
l,2,3
-Tri
chlo
robe
nzen
eB
RL
0.00
6B
RI
0.00
6B
RL
0.00
6B
RI
0.00
6B
RL
0.00
7B
RL
0.00
6L
1,2-
Trw
hlor
oeth
ane
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
1.0.
006
BR
L0.
007
BR
L0.
006
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-L
atin
Am
eric
a/-7
C,
7Pa
ge3
Labo
rato
ryM
anag
er
This
anal
ytic
alre
port
.an
dth
een
tire
data
pack
ego
itre
pres
ents
.ha
sbe
enm
ade
fory
our
excl
usiv
ean
dco
nfid
entia
lus
e.T
hein
terp
reta
tions
and
resu
ltsex
pres
sed
thro
ugho
utth
isan
alyt
ical
repo
rtre
pres
ent
the
best
judg
meo
tof
XE
NC
OL
obor
stot
ics.
XEN
CO
Lob
orat
mie
sas
sum
esno
resp
onsi
bilit
yan
dm
akes
now
arra
nty
toth
een
dus
eof
the
data
here
bypr
esen
ted.
Our
liabi
lity
inlim
ited
toth
eam
ount
invo
iced
for t
his
wor
kor
der
unle
ssot
herw
ise
agre
edto
inw
nitie
g.
Sinc
e19
90H
oust
on-
Dal
las
=Sa
nA
nton
io-
Aus
tinT
ampa
-M
iam
i-
Lat
inA
mer
ica
Page
4
Dat
eR
ecei
ved
inL
ab:
FriA
ug-0
8-03
03:0
0pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
on
XEN
COL
aborcbte
rós
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3T
MInternational,
Housto
n,T
X
Pro
ject
Id:
3TM
-LD
-022
003-
02P
roje
ct
Nam
e:
Koppers
Creosote
Facil
ity
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
Id:
2360
28-0
0123
6028
-002
2360
28-0
0323
6028
-004
2360
28-0
0523
6028
006
•F
ield
Id:
3TM
-KP-
SS-)
C-0
13T
M-K
P-S5
-JC
-02
3TM
-KP-
5S-J
C-0
33T
M-K
P-SS
-ND
-OI
3TM
=KP-
SS-N
D-0
23T
M-K
P-SS
-ND
-03
Ana
lysi
sR
eque
sted
Dep
th:
6-In
6-In
6-In
1-ft
1-ft
1-ft
Mat
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
-—
Sam
pled
:A
ug-0
6-03
12:3
0A
ug-0
6-03
12:4
0A
ug-0
6-03
13:0
0A
ug-0
7-03
08:1
0A
ug-0
7-03
08:4
5A
ug-0
7-03
09:3
0
VO
As
bySW
—84
682
60B
Ext
,act
ed:
Aug
-14-
0317
:10
Aug
-14-
0317
:16
Aug
-14-
0317
:18
Aug
-14-
0317
:20
Aug
-14-
0317
:22
Aug
-14-
0317
:24
Ana
lyze
d:A
ug-1
4-03
18:2
3A
ug-1
4-03
19:2
7A
ug-1
4-03
19:4
9A
ug-1
4-03
20:1
0A
ug-1
4-03
20:3
2A
ug-1
4-03
20:5
4
Uni
ts/R
L:
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
11,1
-Trt
chlo
roet
hane
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0,
007
BR
L0.
006
Tnc
hlor
oeth
ene
BR
E0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
—.
BR
L0.
006
Tri
chlo
rofl
uoro
met
hane
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
I,2,
3-T
rich
loro
prop
ane
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
l.2.4
-Tri
met
hylb
enze
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RI_
0.00
6I.3
,5-t
rim
ethy
lben
zene
BR
.L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
006
Vin
ylC
hlor
ide
BR
L0.
002
BR
L0.
002
BR
L0.
002
BR
L0.
003
BR
L0.
003
1B
RL
0.00
2o-
Xyi
ene
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
006
BR
L0.
007jB
RL
0.00
6m
,p-X
ylen
esB
RL
0.01
2B
RL
0.01
2B
RL
0.01
2B
RL
0.01
3B
RL
0.01
3B
RL
0.01
2
Lab
orat
ory
Man
ager
This
anat
ytic
alre
port
.and
the
entir
eda
tapa
ckag
eit
ropr
esni
tta.h
asbe
enm
ade
bar y
our
exdu
sive
anti
eant
iden
tialu
sa.
The
inta
rpre
taso
naen
dre
sults
expr
esse
dth
roug
hout
this
anal
ytic
alre
port
repr
esen
tth
ebe
stju
dgm
ento
fXE
NC
OL
abor
ator
ies.
XEN
CO
Leh
orat
orie
sas
sum
esno
resp
onsi
bilit
yan
dm
akes
now
alm
nty
toth
eco
dus
eof
tbe
data
here
bypr
esen
ted.
Our
liabi
lity
islim
ited
Wth
eum
oant
invo
iced
for
this
wor
kor
der
wilm
aot
herw
ise
agre
edto
isw
ritin
g.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-L
atin
Am
eric
a
Dat
eR
ecei
ved
InL
ab:
Fri
Aug
-08-
0303
:00
pmR
epo
rtD
ate:
19-A
UG
-03
Pro
ject
Man
a2er
:K
aren
Ols
on
XEt
ICO
Loborcdorie
sC
erti
fica
teof
Ana
lysi
sS
umm
ary
2360
283
TM
Inte
rnati
onal,
Ho
usto
n,T
X
Pro
ject
Id:
3TM
-LD
-022
003-
02P
roje
ct
Nam
e:
Koppers
Creosote
Facil
ity
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Lab
Id:
2360
28-0
071
2360
28-0
0823
6028
-009
2360
28-0
1023
6028
-011
2360
28-0
12•
Fie
ldId
:3T
M-K
P-SS
-TA
-01
3TM
-KP-
SS-T
A-0
23T
M-K
P-SS
-CD
-01
3TM
-KP-
SS-C
D-0
2I
3TM
-KP-
SS-C
D-0
3T
rip
Bla
nkA
naly
sis
Req
uesk
dD
epth
:1-
ft6-
In6-
In6-
In6-
InIn
Mat
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
WA
TE
RSa
mpl
ed:
Aug
-07-
0310
:45_
_-A
ug-0
7-03
11:0
0A
ug-0
7-03
11:4
5A
ug-0
7-03
12:4
0A
ug-0
7-03
13:4
5A
ug-0
7-03
00:0
0
Percent
Mo
istu
re
Ext
ract
ed:
Ana
lyze
d:A
ug-1
1-03
15:3
8A
ug-1
1-03
15:4
0A
ug-1
1-03
15:4
2A
ug-1
1-03
15:4
4A
ug-1
1-03
16:1
0U
nlts
/RL
:%
_____
RL
%R
I%
RL
%R
I%
RL
Perc
entM
oist
ure
19.7
1.00
17.6
1.00
23.8
1.00
23.8
1.00
23.0
1.00
—
SV
OA
PA
Rs
Lis
tby
EP
A8270C
Ext
ract
ed:
Aug
-i1-
0310
:33
Aug
-11-
0310
:36
Aug
-11-
0310
:39
Aug
-11-
0310
:42
Aug
-11-
0310
:45
Aug
-12-
0310
:10
Ana
lyze
d:A
ug-1
5-03
05:5
7A
ug-1
5-03
06:3
9A
ug-1
6-03
01:3
7A
ug-1
5-03
07:2
3A
ug-1
5-03
08:0
7A
ug-1
4-03
17:4
0U
nils
iRL
:m
g/kg
RL
mg/
kgR
Im
g/kg
RI
mg/
kgR
Lm
g/kg
RL
mg/
LR
LA
cena
phth
ene
BR
L0.
207
TT
hR
L0.
202
BR
L0.
218
BR
L0.
219
BR
L0.
216
BR
L0.
006
Ace
naph
thyl
ene
BR
L0.
207
‘rB
RL
0.20
2B
RL
0.21
8B
RL
0.21
9B
R.L
0.21
6B
RL
0.00
6A
nthr
acen
e—
.-
-B
RL
0.20
7B
R!.
0.20
20.
253
0.21
8B
RL
0.21
9—
BR
L0.
216
BR
L0.
006
Ben
zo(a
)ant
lirac
ene
BR
L0.
207
BR
L0.
202
0.42
80.
218
BR
L0.
219
BR
!.0.
216
BR
L0.
006
Ben
zo(a
)pyr
ene
—B
RL
0.20
7B
RL
0.20
20.
342
0.21
8B
RL
0.21
9B
RL
0.21
6B
RL
0.00
6B
enzo
(b)f
luor
anth
ene
BR
L0.
207
BR
L0.
202
0.79
00.
218
BR
L0.
219
BR
L0.
216
BR
]..0.
006
Ben
zo(g
,h,i)
pery
lene
BR
L0.
207
BR
!.02
02B
RL
0.21
8B
RL
0.21
9B
RL
0.21
6B
RL
0.00
6B
enzo
(k)f
luor
anth
ene
BR
L0.
207
BR
L0.
202
—02
890.
218
—B
RL
0.21
9B
RL
0.21
6—
BR
L0,
006
Chr
ysen
eB
RL
0.20
7B
R!.
0.20
2—
0.53
50.
218
BR
L0.
219
—B
R!.
0.21
6B
R!.
0.00
6D
iben
z(a,
h)A
nthr
acen
eB
RL
0.20
7B
RL
0.20
2B
R!.
0.21
8B
RL
0.21
9—
BR
L0.
216
BR
!.0.
006
Fluo
rant
liene
—-
BR
!.0.
207
BR
!.0.
202
1,48
0.21
8—
BR
L0.
219
BR
!.0.
216
-—
BR
]..0.
006
Fluo
rene
—B
R!.
0.20
7B
R!.
0.20
2B
RL
0.21
8B
R!.
0.21
9B
R!.
0.21
6B
R!.
0,00
6In
deno
(1,2
,3-c
,d)P
yren
e___
____
——
__
__
__
__
__
_BR
!..0.
207
BR
!.0.
202
BR
L0.
218
BR
!.0.
219
BR
!.0.
216
BR
L0.
006
Nap
htha
lene
[B
RL
0.20
7B
RL
0.20
2B
RL
0.21
8B
R!.
0.21
9B
RL
0.21
6B
R!.
0.00
6Ph
enan
thre
neB
R!.
0.20
7B
R!.
0.20
20,
545
0.21
8B
R!.
0.21
9B
R!.
0,21
6B
R!.
0.00
6Py
rene
jB
R!.
0.20
7B
R!.
0.20
21.
850.
218
BR
!.0.
219
BR
L0.
216
UR
L0.
006
Bre
ntB
arro
nL
abor
ator
yM
anag
erPa
ge5
This
anal
ytic
alre
port
,an
dth
een
tire
data
pack
age
itre
pres
ents
. has
been
mad
efo
ryou
rexc
lusi
vean
dco
nfid
entia
l eec
.Th
ein
terp
reta
tions
and
resu
ltsm
cpre
ssed
thro
ugho
utth
isan
alyt
ical
repo
rtre
pres
ent
the
best
judg
mot
uof
XE
NC
OL
abor
siot
ieX
EN
CO
t.abo
rato
rits
assu
mes
nore
spon
sibi
lity
and
mak
esno
wam
nty
toth
een
dus
eof
the
data
here
bypr
esen
ted.
Our
liabi
lity
Islim
ited
toth
eam
ount
Invo
iced
for
this
wor
kor
deru
nles
sot
herw
ise
agre
edto
inw
ritin
g.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-L
atin
Am
eric
a
XEN
COL
ctb
ero
to
ries
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3T
MInternational,
Ho
usto
n,T
X
Pro
ject
Id:
3TM
-LD
-022
003-
02P
roject
Nam
e:
Koppers
Creosote
Facil
ity
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
ecei
ved
inL
ab:
Fri
Aug
-08-
0303
:00
pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
:K
aren
Ols
onL
abIth
2360
28-0
0723
6028
-008
2360
28-0
0923
6028
-010
{23
02S
-011
123
6028
-012
•F
l eld
Id:
3TM
-KP-
SS-T
A-0
13T
M-K
P-SS
-TA
-02
3TM
-KP-
SS-C
D-0
13T
M-K
P-SS
-CD
-02
3TM
-KP-
SS-C
D-0
3T
rip
Bla
nkA
naly
sis
Req
uest
edD
epth
:1-
ft6-
In6-
In6-
In6-
InIn
Mat
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
WA
TE
R
Sam
pled
:A
ug-0
7-03
10:4
5A
ug-0
7-03
11:0
0A
ug-0
7-03
11:4
5A
ug-0
7-03
12:4
0A
ug-0
7-03
13:4
5A
ug-0
7-03
00:0
0
VO
As
by
SW
-846
82
60
BE
xtra
cted
:A
ug-1
4-03
17:2
6A
ug-1
4-03
17:2
8A
ug-1
5-03
15:3
6A
ug-1
5-03
15:3
8A
ug-1
5-03
15:4
0A
ug-1
2-03
18:1
5A
naly
zed:
Aug
-14-
0321
:15
Aug
-14-
0321
:37
Aug
-15-
0317
:53
Aug
-15-
0318
:15
Aug
-15-
0318
:36
Aug
-13-
0300
:25
Un1
WR
L:
mg/
kgR
I.m
g/kg
RI.
mg/
kgR
Lm
g/kg
RL
mg/
kgP
1m
gfL
RI.
Ben
zene
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
I.0.
005
Bro
mob
enze
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5B
rom
ochi
orom
etha
ne—
.—
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
—B
RL
0.00
5B
rom
odic
hior
omet
hane
BR
L0.
006
BR
L0.
006
BR
!.,0.
007
BR
L0.
007
BR
I0.
006
BR
L0.
005
Bro
mof
orm
BR
L0.
006
BR!..
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6—
BR
].,0.
005
Bro
mom
etha
ne-
SRL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RI.
0.00
5M
TB
EB
RL
0.00
6.
BR
L0.
006
0.00
80.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
tert
-But
ylbe
nzen
e—
——
SRI.
0.00
6—
BR
I0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
I.0.
005
Sec-
But
ylbe
nzcn
e—
——
ThR
L0.
006
SRI.
0.00
6B
RL
0.00
7‘“R
L0.
007
BR
L0.
006
BR
I.0.
005
n-B
utyl
benz
ene
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
I.0.
006
BR
L0.
005
Car
bon
Tet
rach
iori
deB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RI.
0.00
7B
RL
0.00
6B
RI.
0.00
5C
hlor
oben
zene
——
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
Chl
oroe
than
eB
RL
0.01
3B
RL
0.01
2B
RL
0.01
3B
R]..
0.01
3B
R]..
0.01
3B
RL
0.01
0C
hlor
ofor
m—
——
—SR
I..0.
006
BR
L0.
006
SR
I,0.
007
BR
L0.
007
—B
RI.
0.00
6B
RL
0.00
5C
hior
omet
hane
-—
_______
—.
BR
L0.
013
—SR
I.0.
012
BR
!.,0.
013
BR
L0.
013
—B
RL
0.01
3—
-B
RL
0.01
02-
Chi
orot
olue
neB
RI.
0.00
6B
RL
0.00
6B
RL
0.00
7B
R.L
0.00
7B
RL
0.00
6B
RL
0.00
54-
Chi
orot
olue
ne-
—.
BR
L0.
006
BR
L0.
006
BR
L0.
007
SR
I.0.
007
BR
L0.
006
BR
L0.
005
p-C
ymen
e(p-
lsop
ropy
ltolu
ene)
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
—B
RL
0.00
6B
RL
0.00
51,
2-D
ibro
mo-
3-C
hior
opro
pane
—B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RI.
0.00
6—
BR
L0.
005
Dbr
omoc
hlor
omet
hane
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
SRI.
0.00
6B
RL
0.00
5D
ibro
rnor
neth
ane
—.
SRL
0.00
6B
RL
0.00
6B
RL
0.00
7—
BR
I.0.
007
BR
L0.
006
SRI.
0.00
51,2
-Dic
hlo
roben
zene_
_._
________________
__
__
_B
RI.
0.00
6B
RI.
0.00
6B
RI
0.00
7B
RL
0.00
7B
R!..
0.00
6—
—B
RL
0.00
51,
3-D
ichl
orob
enze
neB
RI.
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RI.
0.00
5l,4
-Dic
hlor
oben
zene
SRL
0.00
6B
RL
0.00
6B
RI,
0.00
7B
RL
0.00
7B
RL
0.00
6B
RI.
0.00
5D
ichl
orod
iflu
orom
etha
neBR
.L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
I.0.
006
BR
L0.
005
///
Bar
ron
Page
6L
abor
ator
yM
anag
er
This
onal
ytic
alre
port
.an
dth
een
tire
data
pack
age
itre
pres
ents
,ha
sbe
enm
ade
fary
our
excl
usiv
ean
dco
nfid
entia
l us
The
inte
rpre
tatio
nsan
dre
sults
expr
esse
dth
roug
hout
this
anal
ytic
alre
port
repr
esen
tth
ebo
utju
dgm
ent o
f XEN
CO
Lab
orat
orie
s.X
ENC
OL
abor
ator
ies
assu
mes
nore
spon
sibi
lity
and
mak
esno
wsr
oant
yto
the
end
usa
ofth
edo
tahe
reby
pecu
enta
d.O
urlia
bilit
yis
limite
dto
the
amou
ntin
voic
edts
rth
isw
ork
orde
r uul
esa
othe
rwis
eag
reed
toin
writ
ing.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nto
nio
-A
ustin
-T
ampa
-M
iam
i-
Latin
Am
eric
a
XEN
cOL
nbar
ator
Ecs
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3TM
Inte
rnat
ional
,H
ou
sto
n,T
X
Pro
ject
Id:
3TM
-LD
-022
003-
02P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
Conta
ct:
Ran
dyH
orsa
k
Pro
ject
Loc
atio
n:G
rena
da,
Mis
siss
ippi
Dat
eR
ecei
ved
inL
ab:
Fri
Aug
-08-
0303
:00
pm
Rep
ort
Dat
e:19
-AU
G-0
3
Pro
ject
Man
ager
;K
aren
Ols
onL
abId
:23
6028
-007
2360
28-0
0823
6028
-009
2360
28-0
1023
6028
-01
123
6028
012
•F
leld
Id:
3TM
-KP-
SS-T
A-0
13T
M-K
P-SS
-TA
-02
3TM
-KP-
SS-C
D-0
13T
M-K
P-S
S-C
D-0
23T
M-K
P-S
S-C
D-0
3T
rip
Bla
nkA
naly
sis
Req
uest
edD
epth
:1-
ft6-
In6-
In6-
Tn6-
InIn
Mat
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
WA
TE
R
—-
—_
_______________________
Sam
plet
hA
ug-0
7-03
10:4
5A
ug-0
7-03
11:0
0A
ug-0
7-03
11:4
5A
ug-0
7-03
12:4
0A
ug-0
7-03
13:4
5A
ug-0
7-03
00:0
0
VO
As
bySW
—84
682
60B
Ext
ract
ed:
Aug
-14-
0317
:26
Aug
-14-
0317
:28
Aug
-15-
0315
:36
Aug
-15-
0315
:38
Aug
-15-
0315
:40
Aug
-12-
0318
:15
Ana
lyze
d:A
ug-1
4-03
21:1
5A
ug-1
4-03
21:3
7A
ug-1
5-03
17:5
3A
ug-1
5-03
18:1
5A
ug-1
5-03
18:3
6A
ug-1
3-03
00:2
5IJ
nIIs
JRL
:m
g/kg
RL
mg/
kgR
Im
g/kg
91
mg/
kgR
Lm
g/kg
RL
mg/
LR
L1,
2-D
ichi
oroe
than
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
51,
1-D
ichl
oroe
than
eB
RL
0.00
6B
RL
0.00
6B
R1.
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5tr
ans-
I,2-
dich
loro
ethe
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6—
BR
L0.
005
ois-
I,2-
Dic
hlor
oeth
ene_
_—B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6—
BR
L0.
005
1.1-
Dic
hior
oeth
ene
BR
L0.
006
BR
I0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
2,2-
Dic
lilor
opro
pane
BR
L0.
006
BR
I0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
1,3-
Dic
hior
opro
pane
—-
—B
RL
0.00
6BR
.L0.
006
BR
L0.
007
BR
I.0.
007
BR
L0.
006
BR
L0.
005
1,2-
Dic
hlor
opro
pane
——
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
tran
s-I,
3-di
chlo
ropr
open
e—
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
l,t-D
ichl
orop
rope
ne—
.B
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
O.0
05
cis-
1,3-
Dic
hlor
opro
pene
BR
L0.
006
BR
L0.
006
BR
L0.
007
—B
RL
0,00
7B
RL
0.00
6B
RL
0.00
5E
thyl
benz
ene
—B
RL
0.00
6-
BR
L0.
006
BK
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
Hex
achl
orob
utad
iene
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
——
BR
L0.
006
BR
L0.
005
isop
ropy
lben
zene
BR
L00
06B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5M
etily
lene
Chl
orid
eB
RL
0.02
5B
RL
0.02
4B
RI.
0.02
6B
RL
0.02
6B
RL
0.02
6B
RL
0.00
5N
apht
hale
neB
RL
0.01
3B
RL
0.01
2B
RL
0.01
3B
RL
0.01
3B
RL
0.01
3B
RL
0.01
0n-
Prop
ylbe
nzen
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5St
yren
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
51,
1,1,
2-T
etra
chlo
roet
hane
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
1,1,
2,2-
Tet
rach
loro
etha
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5T
etra
chlo
roet
hyle
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0,00
6B
RL
0.00
5T
olue
neB
RL
0.00
6B
RL
0.00
6]
BR
L0.
007
ER
L0.
007
BR
L0.
006
BR
L0.
005
1,2,
4-T
rjch
loro
benz
ene
——
—B
RL
0.00
6B
RL
0.00
6j
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
L0.
005
l,2,3
-Tri
chlo
robe
nzen
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
51,
1,2-
Tri
chlo
roet
hane
BR
L0.
006
BR
L0.
006
jB
RI.
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5
Bre
ntB
arro
nL
abor
ator
yM
anag
erPa
ge7
Cer
tifi
cate
ofA
naly
sis
Sum
mar
y23
6028
3T
MIn
tern
atio
nal
,H
oust
on
,T
XP
roje
ctId
:3T
M-L
D-0
22003-0
2P
roje
ctN
ame:
Kop
pers
Cre
osot
eF
acil
ity
This
onal
ytic
alre
port,
end
the
entir
eda
tapa
ckag
eit
repr
esen
ts, h
asbe
enm
ade
Ilsry
ear
excl
usiv
ean
dco
nade
ntie
luse
.Th
ein
terp
reta
tions
and
resu
ltsex
pres
sed
thro
ugho
utth
isan
olyt
ical
repo
rtre
pres
ent t
hebe
stju
dgm
ento
fXE
NC
OL
abor
ator
ies.
)CEN
CO
Lab
orat
orie
sas
sum
esno
resp
onsi
bilit
yan
dm
okes
now
snon
tyto
the
end
use
ofth
eda
tahe
reby
pres
ente
d.O
urlia
bilit
yis
limite
dto
the
omos
etIn
voic
edfis
rth
isw
ork
orde
run
less
oche
rwis
cag
reed
tois
writ
ing.
Sinc
e19
90H
oust
on-
Dal
las
-Sa
nA
nton
io-
Aus
tin-
Tam
pa-
Mia
mi
-L
atin
Am
eric
aPa
ge8
Dat
eR
ecei
ved
inL
ab:
Fri
Au
g-0
8-0
30
3:0
0pm
Rep
ort
Date
:19-A
UG
-03
Pro
ject
Manager:
Kar
enO
lson
XENC
Lnberc
orc
s
Conta
ct:
Ran
dy
Hor
sak
Pro
ject
Locati
on
:G
ren
ad
a.
Mis
siss
ippi
Lab
Id:-
2360
28-0
0723
6028
-008
2360
28-0
0923
6028
-010
.236
028-
011
2360
28-0
12•
Fie
ldId
3TM
-KP-
SS-T
A-0
13T
M-K
P-SS
-TA
-02
3TM
-KP-
SS-C
D-O
l3T
M-K
P-SS
-CD
-02
3TM
-KP-
SS-C
D-0
3T
rip
Bla
nkA
naly
sis
Req
uest
edD
epth
:1-
ft6-
In6-
In6-
In6-
InIn
Mat
rix:
SOIL
SOIL
SOIL
SOIL
SOIL
WA
TE
R—
Sam
pled
:A
ug-0
7-03
10:4
5A
ug-0
7-03
11:0
0A
ug-0
7-03
11:4
5A
ug-0
7-03
12:4
0A
ug-0
7-03
13:4
5A
ug-0
7-03
00:0
0—
VO
As
bySW
—84
682
60B
Ext
ract
ed:
Aug
-14-
0317
:26
Aug
-14-
0317
:28
Aug
-15-
0315
:36
Aug
-15-
0315
:38
Aug
-15-
0315
:40
Aug
-12-
0318
:15
Ana
lyze
d:A
ug-1
4-03
21:1
5A
ug-1
4-03
21:3
7A
ug-1
5-03
17:5
3A
ug-1
5-03
18:1
5A
ug-1
5-03
18:3
6A
ug-1
3-03
00:2
5U
nilr
/RL
:m
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mg/
kgR
Lm
g/kg
RL
mgf
LP
11,
1,1-
Tri
chlo
roet
liane
BR
L0.
006
BR
L0.
006
BR
L0.
007
BR
L0
.00
7B
RL
0.00
6B
RL
0.00
5T
rich
ioro
ethe
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7-—
BR
L0.
006
BR
L0.
005
Tri
chio
rofl
uoro
met
hane
——
___________
__
__
_B
RL
0006
BR
L0
006
BR
L0
007
BR
L0
007
BR
L0
006
-—
BR
L0
005
1.2,
3-T
rich
ioro
prop
ane
UR
L0.
006
BR..!
..0.
006
BR
L0.
007
BR
L0.
007
BR
L0.
006
BR
!..0.
005
i,2,4
-Tri
met
hylb
enze
neB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7—
BR
L0.
006
—B
RL
0.00
51,
3,S-
trim
ethy
lbcn
zene
—B
R.L
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6B
RL
0.00
5V
inyl
Chl
orid
e—
BR
L0.
002
BR
L0.
002
BR
L0.
003
BR
L0.
003
BR
L0.
003
BR
L0.
002
o-X
ylen
eB
RL
0.00
6B
RL
0.00
6B
RL
0.00
7B
RL
0.00
7B
RL
0.00
6—
BR
L0.
005
m,p
-Xyl
enes
BR
L0.
013
BR
L0.
012
BR.!.
.0.
013
BR
L0.
013
.B
RL
0.01
3B
RL
0.01
0
Bre
nt
Bar
ron
Lab
ora
tory
Man
yw
er
XEN
CO
Lab
orc
tori
cs
Vork
Ord
er#:
2360
28
(F
orm
3-M
S/M
SD
Recoveri
eE
jP
roje
ctN
ame:
Kopper
sC
reoso
teF
acil
ity
Lab
Batc
hID
:64
1520
QC
-Sam
ple
ID:
2360
28-0
06S
Rep
ort
ing
Uni
ts:
mg/
kg
Pro
ject
ID:
3TM
-LD
-022
003-
02
Bat
ch#:
IM
atrix
:So
lidM
AT
RIX
SP
IKE
IM
AT
RIX
SP
IKE
DU
PL
ICA
TE
RE
CO
VE
RY
ST
UD
Y
Mat
rixSp
ike
Perc
entR
ecov
ery
CD]
IOO
*(C
_A)I
BM
atri
xSp
ike
Dup
licat
ePe
rcen
tRec
over
y[G
]10
0(F-
A)/
ER
elat
ive
Perc
ent
Diff
eren
ceR
P1) =
200(
D-G
)/(D
+G)
ND
Not
Det
ecte
d,.1
=Pr
esen
t Bel
owR
epor
ting
Lim
it,B
—Pr
esen
t in
Bla
nk, N
RN
otR
eque
sted
,I=
Inte
rfer
ence
,NA
Not
App
licab
leN
See
Nar
rativ
e,EQ
LEs
timat
edQ
uant
itatio
nLi
mit
SV
OA
PA
Rs
Lis
tby
EP
A82
70C
Par
ent
Spik
edSa
mpl
eSp
iked
Dup
lica
teSp
iked
Con
trol
Con
trol
Sam
ple
Spik
eR
esul
tSa
mpl
eSp
ike
Spik
edSa
mpl
eD
up.
RPD
Lim
itsL
imits
Fla
gR
esul
tA
dded
[Cl
%R
Add
edR
esul
t[F
l%
R%
%R
%R
PD
Ana
lyte
s[A
l[B
][D
J[E
l[G
I
Ace
naph
tlien
e<0
.199
1.99
1.65
831.
991.
7588
641
-134
19A
cena
phth
ylen
e<0
.199
1.99
1.68
841.
991.
7688
565
-135
25A
nthr
acen
e<0
.199
1.99
1.84
921.
991.
6985
865
-135
25B
enzo
(a)a
nthr
acen
e<0
.199
1.99
1.96
981.
991.
7588
1144
-126
25B
enzo
(a)p
yren
e<0
.199
1.99
1.90
951.
991.
7286
1065
-135
25B
enzo
(b)f
luor
anth
ene
0.29
51.
992.
1794
1.99
1.80
7621
65-1
3525
Ben
zo(g
,h,i)
pery
lene
<0.1
991.
991.
8693
1.99
1.81
912
65-1
3525
Ben
zo(k
)flu
oran
then
e<0
.199
1.99
1.85
931.
991.
7186
825
-125
25C
hrys
ene
0.23
01.
992.
1094
1.99
1.81
7917
65-1
3525
Dib
enz(
a,h)
Ant
hrac
ene
<0.1
991.
991.
7889
1.99
1.78
890
65-1
3525
Fluo
rant
hene
0.32
61.
992.
0486
1.99
1.81
7514
65-1
3525
Fluo
rene
<0.1
991.
991.
7186
1.99
1.77
893
65-1
3525
lnde
no(1
,2,3
-c,d
)Pyr
ene
<0.1
991.
991.
8894
1.99
1.86
931
65-1
3525
Nap
htha
lene
<0.1
991.
991.
6080
1.99
1.6!
811
65-1
3525
Phen
anth
renc
<0.1
991.
991.
7487
1.99
1.65
835
65-1
3525
Pyre
ne0.
288
1.99
2.17
951.
991.
9081
1641
-144
136
Page
1of
3
XEN
CO
Lab
ora
tori
es
Wor
kO
rder
#:
2360
28
ES
es1
Pro
ject
Nam
e:K
op
per
sC
reoso
teF
acil
ity
Lab
Bat
chID
:64
1408
QC
-Sam
ple
ID:
2360
87-0
03S
Rep
ort
ing
Uni
ts:
mg!
LI
Pro
ject
ID:
3TM
-LD
-022
003-
02
Bat
ch#:
IM
atri
x:
Wat
er
MA
TR
IXS
PIK
EI
MA
TR
IXS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YS
TU
DY
Mam
xSp
ike
Perc
ent
Rec
over
y[D
]=
100
(C.A
)fB
Mat
rixSp
ike
Dup
licat
ePe
rcen
tRec
over
y[G
]lO
O(F
-A)/
ER
elat
ive
Perc
ent
Dif
fere
nce
RPD
=20
0*(D
_G)I
(D+G
)
ND
Not
Det
ecte
d,3
=Pr
esen
tB
etow
Rep
ortin
gLi
mit,
BPr
esen
tin
Bla
nk,N
RN
otR
eque
sted
,T—
Inte
rfer
ence
, NA
Not
App
licab
leN
=Se
eNar
rativ
e,EQ
L=
Estim
ated
Qua
ntita
tion
Lim
it
Par
ent
Spik
edSa
mpl
eSp
iked
Dup
lica
teSp
iked
Con
trol
Con
trol
—V
OA
sby
SW
-846
8260
BSa
mpl
eSp
ike
Res
ult
Sam
ple
Spik
eSp
iked
Sam
ple
Dup
.R
PDL
imits
Lim
itsFl
agR
esul
tA
dded
[CJ
%R
Add
edR
esul
t[1
9%
R%
%R
%R
PD
Ana
lyte
sIA
I[D
JtE
lIG
I
Ben
zene
<0.0
050,
050
0.05
310
60.
050
0.05
210
42
66-1
4221
Chl
orob
enze
ne<0
.005
0.05
00.
052
104
0.05
00.
052
104
060
-133
21
1,1-
Dic
hlor
oeth
ene
<0.0
050.
050
0.05
110
20.
050
0.05
210
42
59-1
7222
Tol
uene
<0.0
050.
050
0.05
110
20.
050
0.05
110
20
59-1
3921
Tri
chlo
roet
hene
<0.0
050.
050
0.05
210
40.
050
0.05
010
04
62-1
3724
Lab
Bat
chID
:64
1504
ØC
-S
ampl
eID
:23
6028
-001
SB
atch
#:I
Mat
rix
:S
olid
Rep
ort
ing
Uni
ts:
mg/
kgI
MA
TR
IXS
PIK
EI
MA
TR
IXS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YS
TU
DY
Par
ent
Spik
edSa
mpl
eSp
iked
Dup
lica
teSp
iked
Con
trol
Con
trol
—V
OA
sby
SW
-846
8260
BSa
mpl
eSp
ike
Res
ult
Sam
ple
Spik
eSp
iked
Sam
ple
Dup
.R
PDL
imits
Lim
itsF
lag
Res
ult
Add
edIC
)%
RA
dded
Res
ult
[19
%R
%%
R%
RP
DA
naly
tes
IA)
[B]
[Dl
[E]
IG)
Ben
zene
<0.0
060.
062
0.06
310
20,
063
0.06
095
766
-142
21
Chl
orob
enze
ne<0
.006
0.06
20.
060
970.
063
0.06
197
060
-133
21
1,l-
Dic
hlor
oeth
ene
<0.0
060.
062
0.06
198
0.06
30.
059
944
59-1
7222
Tol
uene
<0.0
060.
062
0.05
894
0.06
30.
058
922
59-1
3921
Tri
chlo
roet
henc
<0.0
060.
062
0.05
995
[0.06
30.
054
8610
62-1
3724
Page
2o
f3
Mat
rixSp
ike
Perc
entR
ecov
ery
[1)]
100(
C-A
)IB
Mat
rix
Spik
eD
uplic
ate
Perc
entR
ecov
ery
[0]
1OO
*(F_
A)lE
Rel
ativ
ePe
rcen
tDiff
eren
ceR
PD=
2OO
*(D
Gy(
D+G
)
ND
Not
Det
ecte
d.3
=Pr
euen
tBel
owR
epor
ting
Lim
it.B
Pres
ent i
nB
lank
,NR
=N
otR
eque
sted
, IIn
terf
eren
ce, N
AN
otA
pplic
able
NSe
eN
arra
tive,
EQL
Estim
ated
Qua
ntita
tion
Lim
it
XEN
CO
Lth
orc
itori
cs
Wor
kO
rder
#:
2360
28
Lab
Bat
chID
:64
1529
Rep
orti
ngU
nits
:m
g/kg
CF
orm
3-
MS
IMSD
Rec
over
ies
Pro
ject
Nam
e:K
opper
sC
reoso
teF
acil
ity
QC
-Sa
mpe
ID:
2360
68-0
01
S
Pro
ject
ID:
3TM
-LD
-022
003-
02
Bat
ch#:
IM
atri
x:S
olid
MA
TR
IXS
PIK
E/M
AT
RIX
SP
IKE
DU
PL
ICA
TE
RE
CO
VE
RY
ST
UD
YPa
rent
Spik
edSa
mpl
eSp
iked
Dup
licat
eSp
iked
Con
trol
Con
trol
VO
As
byS
W-8
4682
60B
Sam
ple
Spik
eR
esul
tSa
mpl
eSp
ike
Spik
edSa
mpl
eD
up.
RP1
)L
imits
Lim
its
Flag
Res
ult
Add
ed[C
J%
RA
dded
Res
ult
[19
%R
%%
R%
RPD
Ana
lyte
sIA
][D
)[E
J
Ben
zene
<0.0
070.
066
0.05
786
0.06
60.
059
893
66-1
4221
Chl
orob
enze
ne<
0.00
70.
066
0.06
294
0.06
60.
062
940
60
13
321
1,1-
Dic
hlor
oeth
ene
<0.0
070.
066
0.06
294
0.06
60.
059
895
59-1
7222
Tol
uene
<0.0
070.
066
0.06
497
0.06
60.
064
970
59-1
391
21T
rich
lóro
ethe
ne<
0.00
70.
066
0.06
091
0.06
60.
063
954
62-1
371
24
Pag
e3
of3
XENCOLnborøtoric
Work Order #: 236028Lab Batch /: 641408
Reporting Units: rng/L
-—-
Blank Spike Recovery
Blank Spike Recovesy [D] = l004[C]/[B]All results are based on MDL and validated for QC purposes.
Project Name: Koppers Creosote Facility
Project ID:Matrix: WaterSample: 461937-l-BKS
Batch #: I
3TM-LD-022003-02
BLANK IBLANK SPIKE RECOVERY STUDY
VO.As by SW-846 826013 Blank Spike - Blank Blank ControlResult Added Spike Spike Limits Flags
IAI IBI Result %R %R
Analytes ICI LDI
Benzcne <0.005 0.050 0.053 106 66.442
Chlorobenzene <0.005 0.050 0.054 108 60-133
1,1-Dichldroethene <0.005 0.050 0.052 104 59-172
Toluene <0.005 0.050 0.053 106 59-139
Triebloroethene <0.005 0.050 0.052 104 62-137
Lab Batch #: 641504 Sample: 462000-1-BKS Matrix: Solid
Reporting Units: mg/kg Batch #: I BLANK /BLANK SPIKE RECOVERY STUDY
VOAs by SW-846 8260B Blank Spike Blank Blank ControlResult Added Spike Spike Limits Flags
IAI IB) Result %R %R
Analytes . IC] iui
Benzene <0.005 0.050 0.049 98 66-142
Chlorobenzene <0.005 0.050 0.048 96 60J
1,1-Dichloroethene <0.005 0.050 0.048 96 59-172
Toluene <0.005 0.050 j 0.048 96 59-139
Trichloroethene <0.005 0.050 0.047 94 62-137
Lab Batch #: 641529 Sample: 46201 9-1-BKS Matrix: Solid
Reporting Units: mg/kg Batch #: I__[_BLANK/BLANK SPIKE RECOVERY STUDY
VOAs by SW-846 8260B Blank Spike Blank Blank ControlResult Added Spike Spike Limits Flags
IAI IBI Result %R %R
Analytes IC] ID]
Benzenc <0.005 0.050 0.046 92 66.442
Chlorobenzene <0.005 0.050 0.048 96 60-133
1,1-Dichloroethene <0.005 0.050 1 0.043 f 86 59-172
Toluene <0.005 0.050 0.046__J 92 59-139
Trichloroethene <0.005 0.050 0.045 90 62-137
Page 1 of I
XEN
CO
Lnb
orct
orie
sB
S/B
SDR
ecov
erie
s
Pro
ject
Nam
e:K
opper
sC
reos
ote
Fac
ilit
y
Work
Ord
er
#:236028
Uni
ts:
mg/
L
Sam
ple:
4619
62-1
-BK
S
Rel
ativ
ePe
rcen
t Dif
fere
nce
RPD
=20
0*(D
G)/
(D+
G)
Bla
nkSp
ike
Rec
over
y[D
JIO
0*(C
)/[B
]B
lank
Spik
eD
uplic
ate
Rec
over
y(G
]=
100(
F)/
[E]
All
resu
ltsar
eba
sed
onM
DL
and
Val
idat
edfo
rQ
CPu
rpos
es
Pro
ject
ID:
3TM
-LD
-022
0030
2
Mat
rix:
Wat
er
BL
AN
KIB
LA
NK
SP
IKE
IBL
AN
KS
PIK
ED
UP
LIC
AT
ER
EC
OV
ER
YST
UD
Y
Lab
Bat
chID
:64
1612
Bat
ch#:
I
SV
OA
PA
ils
Lis
tby
EP
A82
70C
Bla
nkSp
ike
Bla
nkB
lank
Spik
eB
lank
Blk
. Spi
tC
ontr
olC
ontr
olSa
mpl
eR
esul
tA
dded
Spik
eSp
ike
Add
edSp
ike
Dup
.R
PD
Lim
its
Lim
its
Fla
g[A
l[B
IR
esul
t%
R[E
lD
upli
cate
%R
%%
R%
RP
DA
nal
yte
s[C
l[D
lR
esul
t[F
l[G
I
Ace
naph
then
e<0
.005
0.05
00.
054
108
0.05
00.
053
106
227
-132
31A
cena
phth
ylen
e<0
.005
0.05
00.
050
100
0.05
00.
050
100
046
108
25A
nthr
acen
e<0
.005
0.05
01
0.05
410
80.
050
0.05
611
24
47-1
4525
Ben
zo(a
)ant
hrac
ene
<0.0
050.
050
0.05
110
20.
050
0.05
210
42
33-1
4325
Ben
zo(a
)pyr
ene
<0.0
050.
050
]0.
052
104
0.05
00.
052
104
065
-135
25B
enzo
(b)f
luor
anth
ene
<0.0
050.
050
0.05
4lo
g0.
050
0.05
611
24
2415
925
Ben
zo(g
,h,i)
pery
lene
<0.0
050.
050
0.03
978
0.05
00.
040
803
65-1
3525
Ben
zo(k
)flu
oran
then
e<0
.005
0.05
00.
056
112
0.05
00.
056
112
025
125
25C
hiys
ene
<0.0
050.
050
f0.
053
106
0.05
00.
054
108
265
-135
25D
iben
z(a,
h)A
nthr
acen
c<0
.005
0.05
00.
041
820.
050
0.04
284
250
-125
25Fl
nora
nthe
ne<0
.005
0.05
00.
054
108
0.05
00.
056
112
447
-125
25Fl
uore
ne<0
.005
0.05
00.
054
108
0.05
00.
053
106
248
-139
25ln
deno
(l,2
,3-c
,d)P
yren
e<0
.005
0.05
0f
0.04
182
0.05
00.
041
820
2746
025
Nap
litha
lene
<0.0
050.
050
0.04
896
0.05
00.
050
100
426
175
25Ph
enan
thre
ne<0
.005
0.05
00.
054
108
0.05
00.
057
114
565
135
25Py
rene
<0.0
050,
050
0.04
998
0.05
00.
049
980
23-1
5231
Page
1of
2
XEN
CO
LnborL
ori
c1’
BS
/BSD
Rec
over
ies
)P
roje
ctN
ame:
Kopper
sC
reo
sote
Fac
ilit
y
Wo
rkO
rder
#;
2360
28
Uni
ts;
mg/
kg
Sam
ple:
4620
12-
1-B
KS
Pro
ject
ID:
3T
M-L
D-0
22
00
3-0
2
Mat
rix
:S
olid
BL
AN
K/B
LA
NK
SP
IKE
IB
LA
NK
SP
IKE
DU
PL
ICA
TE
RE
CO
VE
RY
STU
DY
Rel
ativ
ePe
rcen
t Dif
fere
nce
RPD
=20
0*I(
D_G
)f(D
+G)I
Bla
nkSp
ike
Rec
over
y[D
]=
I00*
(C)/
[B]
Bla
nkSp
ike
Dup
licat
eR
ecov
ery
[GI
=l0
0*(F
)/[E
]A
llre
sults
are
base
don
MD
Lan
dV
alid
ated
for
QC
Purp
oses
Lab
Bat
chID
:64
1520
Bat
ch#:
I
SV
OA
PA
ils
Lis
tby
EP
A82
70C
Bla
nkSp
ike
Bla
nkB
lank
Spik
eB
lank
Bik
.Spk
Con
trol
Con
trol
•Sa
mpl
eR
esul
tA
dded
Spik
eSp
ike
Add
edSp
ike
Dup
.R
PDL
imits
Lim
itsF
lag
IAI
181
Res
ult
%R
(El
Dup
licat
e%
R%
%R
%R
PI)
Azi
alyt
esrc
i[D
lR
esul
t(F
J[G
I
Ace
naph
then
e<0
.167
1.67
1.50
901.
671.
5895
541
-134
19
Ace
naph
thyl
ene
<0.1
671.
671.
5190
1.67
1.53
922
65-1
3525
Ant
hrac
ene
<0.1
671.
671.
4989
1.67
1.43
863
65-1
3525
Ben
zo(a
)ant
hrac
ene
<0.1
671.
671.
4989
1.67
1.49
890
4412
625
Bcn
zo(a
)pyr
ene
<0.1
671.
671.
4687
1.67
1.48
892
65-1
3525
Ben
zo(b
)flu
oran
then
e,
<0.1
671.
671.
4184
1.67
1.47
885
65-1
3525
Ben
zo(g
,hi)
pery
lene
<0.1
671
1.67
T1.
4184
1.67
1.55
9310
65-1
3525
Ben
zo(k
)flu
oran
then
e<0
.167
11.
671.
5190
1.67
1.56
933
25-1
2525
Chr
ysen
e<0
.167
11.
67[
1.53
921.
671.
5190
265
-135
25D
ibcn
z(a,
h)A
nthr
acen
e<0
.167
1.67
1.49
891.
671.
5291
265
-135
25
Fluo
rant
hene
<0.1
671.
671.
4788
1.67
1.53
924
65-1
3525
Fluo
rene
<0.1
671.
671.
5090
1.67
1.60
966
65-1
3525
lnde
no(1
,2,3
-c,d
)Pyr
ene
<0.1
671.
671.
5593
1.67
1.61
963
65-1
3525
Nap
htha
lene
<0.1
671.
67T
1.43
861.
671.
3581
665
-135
25Ph
enan
thre
ne<0
.167
1.67
1.45
871.
671.
4889
265
-135
25Py
rene
<0,1
671.
67(
1.55
931.
671.
5190
341
-144
36
Page
2of
2
STATE OF MISSISSIPPIDAVID RONALD MUSOROVE, GOVERNOR
MIssissiPPi DEPARmCENT OF ENvIRoNMENTAl QUALITYCHARLES H. CHI5OLM, ExEarrivE DIRECTOR
July 8, 2002
Mr. Steve Holsenback1002 Lakeview DriveGrenada, MS 38901
Dear Mr. Holsenback:Re: Sample Well No. H997043
Sample LD. No. SW01043
As you may remember, in May, 2002, I collected a re-sample ofyour well and also collected asample from Batupan Bogue underneath the bridge ofHighway S. The purpose of this letter is toadvise you of the results which have just been received from the Mississippi State UniversityChemical Laboratory.
The laboratory analyses of the re-sample of your well did not indicate the presence of any of thecompounds detected in the original samples. These included ACIFLUORF.EN, CADMIUM andBIS(2-ETHYLHEXYL)PHTHALATE. Also, the analyses of the surface water sample fromBatupan Bogue did not detect any semi-volatile compound. I was not surprised that CADMIUMwas not detected in the re-sample since this inorganic compound is rarely found in groundwater. Ihad suspected the first detect was the result of external contamination ofthe collected sampleor a reporting error of some kind from the laboratory. However, I felt the other two compoundswould proba1iiU1l b present.
I am relieved that the second set of analyses did not indicate any areas of concern. However, sincethe first analyses did indicate the presence of the three compounds, I would like to sample yourwell one more time in order to verifS’ these last results. If there is a problem of any kind with yourwell we certainly would like to find it.
OFFICE OF P0111 mow CONmOI
For your information, I have enclosed copies of the laboratory analyses of these latest samples.You will notice that the semi-volatile analyses on your well and also Batupan Bogue indicate thepresence ofDI-N-BUTYLPHTHALATE. However, you will also notice in the footnotes that thiscompound was detected in the laboratory blank on both samples. This blank is de-mineralized orpurified water and the analyses are conducted along with your collected samples as part of thelaboratory Quality Control Procedure. The presence of this compound in the blank indicates thatit was somehow introduced at the laboratory and was not in the submitted sample. I spoke withMrs. Reba Ingram at the laboratory about this, and she said she would be happy to discuss thiswith you if there are concerns of any kind. Her telephone number is (662) 325-7808.
I am not sure what my schedule will be, but I would like to re-sample your well sometime withinthe next few weeks. If it is O.K. with you, I will just stop by and collect the samples the next timeI am in the area. In the meantime, please do not hesitate to contact me ifyou have any questions.
Sincerely,
Shedd Landreth, P.E.AgChem Unit CoordinatorGroundwater Planning Branch
TARGET COMPOUND LIST OF SEMI-VOLATILE ORGANIC COMPOUNDS
ISCL No. 24,741 Sample ID: Batupan 043-SWOI
CONC. MQL CONG. MQL
COMPOUND COMPOUNDugfl ugh ugh ugh
henoI ND 1.0 3-Nitroanhllne ND 1.0
1s (2-Chloroethyh)etber ND 1.0 Acenaphthene ND 1.0
a-Chlorophenol ND 1.0 2,4-Dlnhtrophenol ND 1.0
I3-Dhchlorobenzene ND 1.0 4-Nifrophenol ND 1.0
I .4-Dichlorobenzene ND 1.0 Dibenzofuran ND 1.0
3enzyl Alcohol ND 1.0 2,4-Dinitrotoluene ND 1.0
: ,2-Dichlorobenzene ND 1.0 Dihphthalate ND 1.0
-Methylphenol ND 1.0 Fluorene ND 1.0
,is (2-Chlorohsopropyl)ether ND 1.0 4-Chlorophenyl-phenyl ether ND 1.0
1-Methyiphenol ND 1.0 4Nhtroanhlhne ND 1.0
l-nitroso-dI-n-propylamlne ND 1.0 4,6-Dinitro-2-methylphenol ND 1.0
1echloroethane ND 1.0 N-nhtrosodlptienytamhne ND 1.0
Jitrobenzene ND 1.0 4-Bromophenyl phenyl ether ND 1.0
sophorone ND 1.0 Hexachlorobenzene . ND 1.0
-Nitrophenol ND 1.0 Pentachlorophenol ND 1.0
,4-Dlmethylphend ND 1.0 Phenanthrene ND 1.0
lenzoic Acid ND 1.0 Arithracene ND 1.0
Is (2-Chhomethoxy)methane ND 1.0 Di-n-butylphthalate 1.0
,4-Dhchlorophenol ND 1.0 Fluoranthene ND 1.0
,2,4-Trichlorobenzene ND 1.0 Pyrene ND 1.0
laphthalene ND 1.0 Benzidlne ND 1.0
-Chioroaniflne ND 1.0 Butylbenzylphthalate NO 1.0
lexachiorobutadhene ND 1.0 Benzo(a)anthracene NO 1.0
-Chloro-3-methylphenol ND 1.0 Chrysene ND 1.0
-Methylnaphthalene ND 1.0 3,3DIcNorobenzidhne ND 1.0
exachiorocyclopentadlene ND 1.0 bls (2-Ethylhexyl)phthalate ND 1.0
,4,6-Trlchlorophenol ND 1.0 DI-n-octylptithalate ND 1.0
4,5-Trichiorophenol ND 1.0 Benzo(b)fluoranthene ND 1.0
.Chloronaphthalene ND 1.0 Benzo(k)fluoranthene ND 1.0
•Nitroariihhne ND 1.0 Benzo(a)pyrene ND 1.0
hinethylphthalate ND 1.0 ldeno(1,2,3-cd)pyrene ND 1.0
ceriaphihylene ND 1.0 Diberiz(a,h)anthracene — ND 1.0
&-Dinitrotoluene ND 1.0 Benzo(g,h.I)peryhene ND 1.0
= None Detected= Minimum Quantifiable Level
esent in the blank at 3.0 ppb
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
CHLORINATED ACIDS AND PHENOLSMETHOD 3
WELL ID: H997043 COLLECTION DATE: 05/17/2002 MSCL#: 24740
ANALYSIS RESULTS*
Acifluorfen 0.000Bentazon 0.0002,4—D 0.0002,4-DB 0.000Dalapon 0.000Dicarnba 0.000Dichioroprop 0.000Dinoseb 0.0004-Nitrophenol 0.000Pentachiorophenol 0.000Picloram 0.0002,4,5-T 0.0002,4,5-TP 0.000
Comment: RESAMPLE-.ANALYZED FOR PESTICIDE METHOD 3 ONLY
*RESULTS IN PARTS PER BILLION (ug/1)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
INORGANICS (MINERALS, RESIDUES, NUTRIENTS & METALS)METHOD 9
WELL ID: H997043 COLLECTION DATE: 05/17/2002 MSCL#: 24740
ANALYS IS RESULTS *
Calcium, Total 0.000Chlorides, Total 0.000Hardness (CA, MG) 0.000Sulfates 0.000Total Kjeldahl Nitrogen 0.000Ammonia Nitrogen 0.000Nitrate-Nitrite Nitrogen 0.000Phosphates, Total 0.000Phosphates, Ortho 0.000Total Solids © 180 C 0.000Dissolved Solids © 180 C 0.000Suspended Solids 0.000Magnesium 0.000Manganese 0.000Sodium 0.000Potassium 0.000Chromium 0.000Iron 0.000Arsenic 0.000Barium 0.000Cadmium 0.000Lead 0.000Mercury 0.000Silver 0.000Selenium 0.000Beryllium 0.000Cyanide 0.000Fluoride 0.000Nickel 0.000Antimony 0.000Thallium 0.000Copper 0.000Zinc 0.000Aluminum 0.000
Conductivity 0.000Ph 0.00Temperature 0.00
Comment: RESAMPLE-CADMIUN ANALYSIS ONLY
*RESULTS IN PARTS PER MILLION (mg/i)
TARGET COMPOUND LIST OF SEMI-VOLATILE ORGANIC COMPOUNDS
ND None DetectedMQL = Minimum Quantifiable Level
*Preserlt in the blank at 3.0 ppb
MSCL No. 24,740 Sample ID: Holsenback 04341997
GONG. MQL CONG. MQL
COMPOUND COMPOUNDugh ugh ugh ugh
Phenol ND 1.0 3-Nitroanlline ND 1.0 —
bis (2-Chloroethyl)ether ND 1.0 Acenaphthene NO 1.0
2-Chlorophenol ND 1.0 Z4-Dlnitrophenol ND 1.0
. 1,3-Djchlorobenzene ND 1.0 4-Nitrophenol NO 1.0
l.4-Dlchlorobenzene ND 1.0 Dibenzofuran ND 1.0
Benzyl Alcohol ND 1.0 2,4-Dinitrotoluene ND 1.0
1.2-Dlchlorobenzene ND 1.0 Diethylphthalate ND 1.0
2-Methytphenol ND 1.0 Fluorene ND 1.0
bis (2-Chloroisopropyl)ether ND 1.0 4-Chlorophenyl-phenyl ether ND 1.0
4-Methyipheriol ND 1.0 4-Nitroaniilne .Nt) 1.0
N-nltroso-di-n-propylamine ND 1.0 4,6-Dinitro-2-methylphenol ND 1.0
HecNoroethane ND 1.0 N-nitroscdiphenytamine ND 1.0
Nftrobenzen ND 1.0 4Bromophenyl phenyl ether ND 1.0
Isophorone ND 1.0 HeacNorobenzene ND 1.0
2-Nitrophenol ND 1.0 Pentachlorophenol ND 1.0
2,4-Dime hyiphenol ND 1.0 Phenanthrene ND 1.0
Benzoic Acid ND 1.0 Anthracene ND 1.0
bis (2-Chloroethoxy)methane ND 1.0 Dl-n-butytptlthatate 2.6w’ 1.0
2,4-Dichiorophenol ND 1.0 muoranthene ND 1.0
1,2,4-Thchlorobenzene ND 1.0 Pyrene ND 1.0
Naphthalene ND 1.0 Benzidine ND 1.0
4-Chioroeniline ND 1.0 Butylbenzytphthalate ND 1.0
HechIorobutadlene ND 1.0 Benzo(a)anthracene ND 1.0
4-Chloro-3-methylphenol — ND 1.0 Chiysene ND 1.0
2-Methylnaphthalene ND 1.0 3,3-Dlchlorobenzldine ND 1.0
HecNorocyclcpentadiene ND ID bis (2-Ethylhexyl)phthalate ND 1.0
2,4,6-Trichlorophenol ND 1.0 Di-n-octyiphthalate ND 1.0
2,4,5-Trichiorophenol ND 1.0 Benzo(b)fluoranthene ND 1.0
2-Chloronaphthalene ND 1.0 Benzo(k)fluoranthene ND 1.0
2-Nitroaniline ND 1.0 Benzo(a)pyrene ND 1.0
Dimethylphthalate ND 1.0 ldeno(12,3-cd)pyrene ND 1.0
Acenaphthylene ND 1.0 Dibenz(a,h)anthracena ND 1.0
2,6-Dlnitrotoluene ND 1.0 Benzo(g,hJ)per)4ene ND 1.0
STATE OF MISSISSIPPIDAVID RONALD MUSOROVE, GOVERNOR
MississiPPi DEPARTMENT OF ENVIRONMENTAL QUALITYCHARLES H. CHISOIM, EXECUTIVE DIRECTOR
May 9, 2002
Mr. Steve Holseriback
1002 Lakeview Drive
Grenada, MS 38901
Dear Mr. Holsenback:
Re: Sample of Well No. H997043
The purpose of this letter is to advise you of the results wediscussed of the laboratory analyses of your well which was sampledin March, 2002.
The Mississippi Office of Pollution Control determines groundwaterquality using standards and guidelines established for drinkingwater by the United States Environmental Protection Agency (USEPA).These national drinking water standards have been divided intoPrimary arid Secondary Regulations. Primary Regulations are based onhealth considerations and are the most important. SecondaryRegulations are guidelines relating to other qualities such ascolor, taste, odor, staining, etc. and are lesser in importance. Inaddition, the State of Mississippi has established groundwaterstandards which are also utilized in determining groundwaterquality. Maximum Contaminant Levels (MCL’S) have been establishedfor many items considered to be the most important in both Primaryand Secondary Regulations, and Mississippi Groundwater Standards.
As we discussed, there was one semi—volatile compound that wasindicated at a level exceeding Primary Drinking Water Standards,and this was:
BIS(2-ETHYLHEXYL)PHTHALATE at 14 Parts Per Billion (current MCL is6 Parts Per Billion)
This compound is not normally a part of our AgChem Program analysesand I am not completely familiar with its uses or probable source.I have been advised that it is not likely to be associated withwood treating operations, but is used as a plasticizer in rubberand resins: associated with some chemical plants: and is commonlyfound in analytical laboratories.
OFFICE OF POLLUTION CONTROL
There was also one compound which slightly exceeded SecondaryGuidelines, and this was:
MANGANESE at 0.26 Parts Per Million (current MCL is 0.05 PPM)
While this constituent may cause a slight metallic taste and buildup on fixtures, it does not present any health concerns.
In addition to these two compounds there was one herbicideindicated at an extremely low level, and this was:
ACIFLUORFEN at 0.800 Parts Per Billion
There are presently no drinking water standards on this compound,but there is an advisory level of 9.0 Parts Per Billion which waspublished several years ago. Since we have no established drinkingwater standards and the advisory level is more than 10 timesgreater than the indicated amount in your sample, there should notbe any concerns regarding this compound. With the exception ofBIS(2-ETHYLHEXYL)PHTHALATE mentioned above, the overall quality ofyour water would appear to be good at this time.
As we discussed by telephone, I would like to re—sample your wellon Friday, May 17., in order to verify these initial results. Inaddition, even though I an not equipped for surface water sampling,I hope to collect a sample from the creek near your property forsemi-volatile analyses. It would be interesting to see if thecompound detected in your well is also present in the creek.Normally, any contaminants are more likely to be found in surfacewater rather than groundwater, so these analyses may be of someimportance.
Attached you will find a copy of the laboratory analyses on yourwell. Please feel free to contact me at any time if you have anyquestions or if you wish additional information. I will be happy tohelp in any way that’ I can.
Sincerely,
AShedd Landreth, PE. ‘
AgChem Unit CoordinatorGroundwater Planning Branch
MISSISSIPPI DEPARTMENT OF ENVIRONMENTAL QUALITYOFFICE OF POLLUTION CONTROL
AGCHEM GISGENERAL REPORT
Weilcode: H997043County: GRENADALatitude (NAD 83) : 33 46 23.07Longitude (NAD 83) : 89 47 28.83Quad:Section,Township,Range: S17 T22N ROSE V
Quarter-Quarter:Owner: STEVE HOLSENBACKAddress 1: 1002 LAKEVIEW DRIVEAddress 2:City: GRENADAState: MSZip Code: 38901Phone: 662-294-0646Fax:Aquifer:Well Depth: 80
Comment 1: GPS ELEVATION - 187 FEETComment 2: OWNER CONCERNED WITH WOOD TREATING CHEMICALS CONTAMINATION
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
NITROGEN/PHOSPHORUS PESTICIDESMETHOD 1
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYSIS RESULTS*
Alachior 0.000Ametryn 0.000Atrazine 0.000Bromacil 0.000Butylate 0.000Carboxin 0.000Chiorpyrifos 0.000Curacron 0.000Cycloate 0.000DEF (TribufOs) 0.000Diazinon 0.000Diphenamid 0.000Disulfoton 0.000Disulfoton Sulfone 0.000Disulfoton Suifoxide 0.000EPN 0.000Hexazinone 0.000Iprodione 0.000Methazole 0.000Methyl Paraoxon 0.000Metolachior 0.000Metribuzin 0.000Molinate (Ordram) 0.000Prometon 0.000Pronamide 0.000Propazine 0.000Sirnazine 0.000Tebuthiuron 0.000Terbacil
___
0.000Terbufos 0.000Zorial 0.000
Comment:
*REStJITS IN PARTS PER BILLION (ugh)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
CHLORINATED PESTICIDESMETHOD 2
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217 --
ANALYSIS . RESULTS*
Aidrin 0.000Basalin 0.000Captan 0.000Chiordane-Gamma 0.000Chiordane -Alpha 0.000Chiorothalonil 0.. 0004,4-DDD 0.0004,4-DDE 0.0004,4-DDT 0.000Dacthal (DCPA) 0.000Dicofol 0.000Dieldrin 0.000Endosuifan 0.000Endosuifan II 0.000Endosuifan Sulfate . 0.000Endrin 0.000HCH-Alpha 0.000HCH-Beta 0.000HCH-Gamma 0.000HCH-Delta 0.000Heptachior 0.000Heptachlor Epoxide 0.000Hexachlorobenzene 0 .000Methoxychlor 0.000PCB’s •0.000PCNB . 0.000Pendamethalin 0.000CIS-Permethrin 0.000TRANS-Permethri’-— 0.000Toxaphene 0.000Trifluralin 0.000
Comment:
*RESULTS IN PARTS PER BILLION (ugh)
MISSISSIPPI STATE CHEMICAL LABORZTORYGROUNDWATER ANALYSIS
CHLORINATED ACIDS AIJD PHENOLSMETHOD 3
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYS IS RESULTS * - -
Acifluorfen 0.800Bentazon 0.0002,4-B 0.0002,4-DB 0.000Balapon 0.000Dicamba 0.000Dichioroprop 0 .000Dinoseb 0.0004-Nitrophenol 0.000Pentachiorophenol 0.000Picloram 0.0002,4,5-T 0.0002,4,5-TP 0.000
Comment:
*RESULTS IN PARTS PER BILLION (ug/1)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYSIS
HERBICIDESMETHOD 4
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYSIS RESULTS*
Atrazine Dealkylated 0.000Barban 0.000Carbofuran Phenol 0.000Carbofuran Phenol 3-KETO 0.000Cyanazine 0.000Diuron 0.000Fenamiphos 0.000Fenamiphos Sulfone 0.000Fenamiphos Sulfoxide 0.000Fluometuron 0.000Linuron 0.000Metribuzin DA 0.000Metribuzin DADK 0.000Metribuzin OK 0.000Neburon 0.000Pronamide Metabolite 0.000Propanil 0.000Propham 0.000SWEP 0.000
Comment:
*RESIJLTS IN PARTS PER BILLION (ug/l)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
CARBAMATESMETHOD 5
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYSIS RESULTS *
Aldicarb 0.000Aldicarb Sulfone 0.000Aldicarb Suifoxide 0.000Baygon 0.000Carbaryl 0.000Carbofuran 0.000Carbofuran 3-OH 0.000Methomyl 0.000Napthol-Gamma 0 .000Oxamyl 0.000
Comment:
*SULTS IN PARTS PER BILLION (ug/1)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
VOLATILE ORGANICSMETHOD 8(a)
WELL ID: H997043 COLLECTION DATE; 03/21/2002 MSCL#: 24217
ANALYSIS RESULTS*
Acrolein o.ooo
Acrylonitrile 0.000
Benzene 0.000
Bromobenzene 0.000
Bromochioromethane 0 . 000
Bromodichioromethane 0 .000
Bromoform 0.000
Bromornethane 0 .000
Carbon Tetrachioride 0.000
Chlorobenzene 0. 000
Chioroethane 0 .000
2-Chioroethylvinyl Ether 0.000
Chloroform 0.000
Chioromethane 0.000
2-Chiorotoluene 0.000
4-Chiorotoluene 0.000
Dibromochioromethane 0 . 000
1, 2-D±brombethane 0.000
Dibromomethane 0 .000
1, 2—Dichlorobenzene 0.000
1,3—Dichlorobenzene 0.000
1, 4-Dichlorobenzene 0.000Dichiorodifluoromethane 0 . 000
1, 1-Dichioroethane 0 .000
1, 2-Dichioroethane 0.000
1,1-Dichioroethene 0.000
Comment:
*RESULTS IN PARTS PE BILLION (ugh)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
INORGANICS (MINERALS, RESIDUES, NUTRIENTS & METALS)METHOD 9
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYSIS RESULTS*
Calcium, Total 26.000Chlorides, Total 4.600Hardness (CA, MG) 100.000Sulfates 43.000Total Kjeldahl Nitrogen 0.450Ammonia Nitrogen 0.270Nitrate-Nitrite Nitrogen 0.000Phosphates, Total 2.410Phosphates, Ortho 0.230Total Solids © 180 C 212.000Dissolved Solids © 180 C 197.000Suspended Solids 15.000Magnesium 9.000Manganese 0.260Sodium 19.000Potassium 5.800Chromium 0.000Iron 1.300Arsenic 0.000Barium 0.014Cadmium 0.003Lead 0.000Mercury 0.000Silver 0.000Selenium 0.000Beryllium 0.000Cyanide 0.000Fluoride 0.000Nickel 0.004Antimony 0.000Thallium 0.000Copper 0.001Zinc 0.001Aluminum 0.038
Conductivity 260.000Ph 6.49Temperature 17.80
Comment:
*R.E5ULTS IN PARTS PER MILLION (mg/l)
MISSISSIPPI STATE CHEMICAL LABORATORYGROUNDWATER ANALYS IS
VOLATILE ORGANICSMETHOD 8(b)
WELL ID: H997043 COLLECTION DATE: 03/21/2002 MSCL#: 24217
ANALYS IS RESULTS *
CIS-1, 2-Dichioroethene 0.000
TRANS-i, 2-Dichioroethene 0.000
1, 2-Dichioropropane 0.000
1, 3-Dichioropropane 0.000
2, 2-Dichioropropane 0.000
1, 1-Dichioropropene 0.000
CIS-1, 3-Dichioropropene 0.000
TRANS-i, 3-Dichioropropene 0.000
Ethyibenzene 0 . 000
Hexachloro-1, 3-Butadiene 0.000
Methylene Chloride 0.000
Naphthalene 0.000
Styrene 0.000
1,1,1, 2-Tetrachloroeethane 0.000
1,1,2, 2-Tetrachioroethane 0.000
Tetrachioroethene 0.000
Toluene 0.000
Trichioroethene 0.000
Trichiorofluoromethane 0.000
1,2, 3-Trichioropropane 0.000
Vinyl Chloride 0.000
O-Xylene 0.000
M-Xylene 0.000
P—Xylene 0.000
Comment:
*RESULTS IN PARTS PER BILLION (ugh)
TARGET COMPOUND LIST OF SEMIVOLATILE ORGANIC COMPOUNDS
MSCL#: 24217
Analysis of Drinking well WaterMarked: Holsenback (O43-H997
. Con3pounds-Cone. MQL Cone. MQLugfL ugfL ugfL ugfL
Phenol- ND- 1.0- 3-Noani1ine. -. ND 1Obis2C1x1l3roethyl)ether ND 1:0- Acenaphthue ND 1.02-Chiorophenol ND 1.0 2,4-Dinitrophenol ND 1.01,.3-Dichlorobenzeiie. ND 1A) 4-Nitrophenol ND 1.014ehlerobenaene ND- ho- Dibenzofuran ND 1.0BtnzyrAkolibr ND- to- Z1iitrorrnene - ND 1.01,2-Dichlorobenzene ND 1.0 Thethy1pht1ilfe ND 1.02.MethyIphiin1. . Nfl ... IlL Thioreue.. ND 1.0bis(-2-CMoroisopropyl)ether NB- - hO- 4-€Merophphenylether ND-- 1.04-MèthyrpEeuor ND to- 4-Nitroanilulië ND - 1.0N-nitroso-di-n-propyamine ND 1.0 4,6-Dinitro-2-methylphenol NDHexacb1oroethan. - ND 1 N..ni1rosodiphenyamine.. ND 1.0Nitrobemene- ND l.0 Biuiuuphcuy1 pheny[ether ND- 1.0Isophorone ND 1.0 Hexachlorobenzene ND 1.02-Nitrophenol . ND 1.0 entach1orophenol ND 1.0-2,4-Dimethylphenol - ND-- hO- Phenanth’ene ND 1.0rnnzoic AbidE ND- 1.0- Anfracene
V
ND 1.0bis(2-Chloroethoxy)methane - ND 1.0 Di-n-butvlphthnlate - ND V 1.02.4-Dichlnrnphennl. V - V Nil L(L F1norinthne - ND 1.91-24-Tñe1ilofobenefie-- NDV
V
Picnc ND 1.0hplithIne ND LCJ ffnzfhe - ND 1.0
4-Chloroaniline Ni) 1.0 Butylbenzylphthalate NDV
1.0Rexach1orohofAiene- . ND- tO Benzo(a)anthracene- V
V ND 1.0o-iuiUlpiiaiol V
- ND 1.02-Methylnaphthalene
V•
NDV
1.0 3,3’-Dichlorobenzidine ND 1.0exach1orocyc1opentadiene V
ND 1.0 bisQ-Ethylhexyl)phthalate V 14 1.02146-Tr4ch1oropheao1.__ — V ND- . tO- Dlt1i14e- . ND 1.045-Trich1rophenoI V 1.0- Benzo(b)fkiranthene V ND 1.02-Chloronaphthakne
V
ND 1.0 Berizo(k)fluoranthene ND 1.02-Nitroanilinc. - ND . tO Benzo(a)pyrene ND 1.0E)imethylphthalate- ND- V 1ndcno(1,2,3ed)pyreue. V 1.0
V
Acenaphthylene ND to- 3inz(á,h)anthracene N]) 1.02,6-Dinitrotciluene
V
- ND 1.0 Benzo(g,hj)peiylene ND 1.0
Surrogates Recovery, %2-fluorophenol 33
phenol-d5 26.
nitrobenzene-dS 952-fluorobipheityl 100 V
2,4,6-tribromophenol V62
Dterphenykfl4
ND = None Detected
MQL Minimum Quantifiable Level
AXYS METHOD DX-S.l6l3Ner,3 CLIENT ID:
16130B6.-5Ci05-D1 Form 1A 3TM4(P-DS..BB-IICPcbD/PcoF ANALYSIS REPORT
Sample Collection: 10-Jan.2004 10:50
Lab Name: AXYS ANALVTICAL SERVICES
Contract No.: 4182 Lab Sample ID: L6466-1 1 (A)
Matrix: DITCH SEDIMENT Sample SIze: 10.1 g (dry)
Sample Receipt Date: 21-Jan-2004 Initial Calibration Date: 03-Feb-2004
ExtractIon Date: 27-Jan.2004 Instrument ID: HR GC/MS
Analysis Date: 09-Feb.2004 Time: 2:05:29 GC Column ID: DB-5
Extract Volume (iJL): 20 Sample DataBle: DX42j157 S:8
InjectIon Volume (1L): 1.0 Blank Data Filename: DX42 056 S:5
Dilution Factor: N/A Cal. Ver. Data Filename: DX42_057 S: 1
Concentration Units: pg/g (dry weight basis) % MoIsture: 19.0
COMPOUND LAB CONG. DETECTION ION ABUND. RRT2FLA& FOUND LlMT RATIO2
2,3,7,8-TCDD 0.542 0.0500 0.68 1.001
1,2,3,7,8-PeCDD3 0.449 0.0500 0.64 1.0001,2,3,4,7,8-HxCDD 2.13 0.510 1.16 1.000
1,2,3,6,7,B4IxCDD 10.3 0.510 1.21 1.000
1,2,37,8,9-HxCDD 17.6 0.510 1.28 1.0101,2,3,4,6,7,8-HpCDD 728 0.560 1.05 1.000
OCDD E
2,3,7,8-TCDF 0.472 0.0500 0.86 1.0031,2,3,7,8-PeCDF 0.163 0.0500 1.49 1.0012,3,4,7,8-PeCDF 0.370 0.0500 1.54 1.0001,2,3,4,7,8-HxCDF 2.33 0.0600 1.22 1.0001,2,3,6,7,8.HxCDF 0.718 0.0600 1.32 1.0001,2,3,7,8,9-FIxCDF 0.107 0.0600 1.14 1.0002,3,4,6,7.8.HxCDF 0.572 0.0600 1.30 1.0001,2,3,4,6,7,8-l-IpCDF 47.1 0.120 1.06 1.0001,2,3,4,7,8.9.HpCDF 3.52 0.120 1.01 1.000OCDF 229 0.0500 0,90 1.002
Total Tetra.Dioxlns 36.4 0.0500Total Penta-Dloxins 28.6 0.0500Total Hexa-Dloxins 372 0.510Total Hepta-Oloxlns 5600 0.560Total Tetra-Furans 3.97 0.0500Total Penta-Furans 4.99 0.0500Total 1-lexa-Furans 37.4 0.0600Total Hepta-Furans 232 0.120
(1) U = not detected; K = peak detected, but did not meet quantification criteria; E = exceeds calibrated linear range, see dilution data; D = dilution
data; Z compound not requested; X = results reported separately
(2) Contract-requIred limits for RRTs and Ion abundance ratios are specified In Tables 2 and 9, respectively, Method 1613.(3) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
_____________
10-02-20041 1004003_lids, S6 Approved by: GA/CC Chemist dd-mm-
0131][C A’..)C’v’S iJ—.1A.L’y1IcEi\L SEF”...’lc:ES L’FL P.O. BOX 2219, 2045 MILI.5 RD. WEST, SIDNEY, B.C., CANADA 981 358 TEl (250) 655S800 FAX (250) 655-5811
AXYS METHOD OX-S-i 6i3Ner3 CLIENT ID:
1613DB5-S0054J1 Form IA 3TM-KP-DS-BB-1 1C
PCDDIPCDF ANALXSIS REPORT
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANP.L’IflCPL SERVICES
Contract No.: 4182 Lab Sample ID: L6466-1 I W (A)
Matrix: DITCH SEDiMENT Sample Size: 10.1 g (dry)
Sample Receipt Date: 21-Jan-2004 Initial Calibration Date: 03-Feb-2004
Extraction Data: 27-Jan-2004 Instrument ID: HR GCIMS
Analysis Date: 10-Feb.2004 TIme: 3:55: 12 GO Column ID; DB-5
Extract Volume ftlL): 200 Sample Detafile: DX42_059 S:iO
Injection Volume (giL): 1.0 Blank Data Filename: DX42_056 S:5
DIlution Factor: 10 Cal. VeF. Data FIlename: 0X42_059 S:1
Concentration Units: pg/g (dry werght basis)
COMPOUND fiB CONC. DETECTION ION ABUND. RRT2
FLAG1 FOUND LlM RATIO2
2,3,7,8-TCDDI,2,3,7,8-PeCDDI ,2,3,4,7.8-HxCDDI ,2,3,6,7,8-HxCDD1,2,3,7,6,9-HxCDDI ,2,3,4,6,7,64-IpCDDDODD D 7060 0.484 0.89 1.000
2,3,7,8-TCDFI,2,3,7,8-PeCDF2,3,4,7,8-PeCDFI ,2,3,4,7,B-HxCDFI ,2,3,6,7,8-HxCDFI ,2,3,7,8,9-HxODF2,3,4,6,7,8-HxCDFI ,2,3,4,6,7,8-HpCDFI ,2,3,4,7,B9-HpCDF000F
Total Tetra.DloxInsTotal Penta-I3loxlnsTotal Hexa-OloxlnsTotal Hepta-DioxlnsTotal Tetra.FuransTotal Penta-FuransTotal Hexa-furansTotal Hepta-Furans
(1) U = not detected; K = peak detected, but did not meet quantification criteria; E = exceeds calibrated linear range, see dilution data; D = dilution
data; Z compound not requested; X = results reported separately
(2) Contract-required limits for RRTs and Ion abundance ratios are specified In Tables 2 and 9, respectively, Method 1613.
(3) Alternate Ions used for native and labeled P5CDD for confirmation and quantitation.
11 004004_I ., as Approved by: 4,1JS’Z4444l%AJ( QA/OC Chemist
0133
€)X( ‘X”t’S 1\rsji\L’Y1icD.e,.L SER.\flc:ES LrE3 r.a. IOo 2219, 2045 MILlS RD. WEST, SIDNEY, IC., CANADA VII 358 TEL (250) 6S55800 FA)1 (2501 655-5811
AXYS METHOD DX-S-l6l3IVer.3 CLIENT ID:16130B5-S005-D1 Form 2 3TM.KP-DS-BB-1 IC
PCDDIPCDF ANALYSIS REPORT
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: L6466-1 I W (A)
Matrix: DITCH SEDIMENT Sample Size: 10.1 g (dry)
Sample Receipt Data: 21-Jan-2004 Initial Calibration Date: 03-Feb.2004
Extraction Date: 27-Jan-2004 Instrument ID: HR GC/MS
Maiysis Date: 10-Feb-2004 TIme: 3:55:12 GC Column ID: DB-5
Extract Volume (jiL): 200 Sample Dataflie: DX42_059 S:10
Injection Volume (pL): 1.0 Blank Data Filename: DX42_056 S:5
Dilution Factor: 10 Cal. Ver. Data Filename: DX42_059 S:1
Concentration Units: pg absolute
LABELED COMPOUND LAB SPIKE CONC. R(%)2 ION ABUND. RRT3FLAG1 CONC. FOUND RATIO3
13C-2,3,7,8-TCDD13C-1,2,3,7,8.PeCDD13C.1 ,2,3,4,7,8-HXCDD13C-1 ,Z3,6,7,8-HxCDD13C-1 ,2,3,4,6,7,8.HpCDD13C-OCDD D 4000 2310 57.8 0.87 1.177
I 3C-2,3,7,8-TCDF13C-1 ,2,3,7,8-PeCDF13C-2,3,4,7,8-PeCDF13C-1,2,3,4,7,8-HxCDFI 3C-1 ,2,3,6,7,8-HxCDF13C-I ,2,3,7,8,9.HxCDF13C-2,3,4,6,7,8-HxCDF13C-I,2,3,4,6,7,8-HpCDF13C-1 ,2,3,4,7,8,9-HpCDF
CLEANUP STANDARD
37C1-2,3,7,8-TCDD
(1) E = exceeds calibrated linear range, see dilution data; D = dilution data; Z = compound not requested; X = results reported separately(2) Contract-required limits for percent recovery (R) are specified in Section 9.3.3, Method 1613.(3) Contract-required limits for RRTs and ion abundance ratios are specified in Tables 2 and 9, respectively,
Method 1613. NOTE: There is no ion abundance ratio for 37C14-2378-TCDD (cleanup standard).(4) Alternate ions used for native and labeled P5CDD fbr confirmation and quantitation.
18-02-2004llOO4DD4jids, sa Approved by: QA/QC Chemist dd-mm-
0134e)][( A.)<VS I .l”—4i\L’y’1lC.,’\L SER’..’lcES LrE) EQ. BOX 2219, 2045 MJU.S RD. WEST, SIDNEY, BC, CANADA VOL 358 TEL (250) 055.5800 fAX 1250) 655-501 1
AXYS METHOD DX-S-l6l3Ner.3 CLIENT ID:1613DB225-0B004-Dl Form 18 3TM-KP-DS-BB-1 IC
2,3,7,8 - TCDF CONFIRMATION ANALYSIS REPORT
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: L6466-11 (A)
Matrix: DITCH SEDIMENT Sample Size: 10.1 g (dry)
Sample ReceIpt Date: 21-Jan-2004 Initial Calibration Date: 14-Jan-2004
Extraction Date: 27-Jan.2004 Instrument ID: HR CC/MS
Analysis Date: 07-Feb.2004 Time: 4:01:51 CC Column ID: DB-225
Extract Volume (IlL): 20 Sample Detaflle: D843 042 S:16
InjectIon Volume (l.iL): 2.0 Blank Data Filename: 0843042 S:5
Dilution Factor N/A Cal. Ver. Data Filename: D843 042 S:2
Concentration UnIts: pg/g (dry weight basis)
COMPOUND LAB CONC. DETECTION ION ABUND. RRT2FLA& FOUND LIMIT RATIO2
2,3,7,B-TCDF 0.146 0.0362 0.69 1.001
(1) U = not detected; K = peak detected, but did not meet quantification criteila; D = dilution data
(2) Contract-requIred limits for RRTs and ion abundance ratios are specified In Tables 2 and 9, respectively, Method 1613.
l1OO4cDO1_l. S13 Approved b ONQC Chemist dm
0135r( A.1 ----—-. DAY ., .
AXYS METHOD OX-S-i 6l3IVer.3 CLIENT ID:
D)CTEQ-n1 3TM-KP-DS-BB-1 ICPCDDIPCDF ANALYSIS TEQ DATA REPORT
Lab Name: AXYS ANALYTICAL SERVICES Sample Collection: 10-Jan.2004 10:50
Contract No.: 4182
Matrix: DITCH SEDIMENT Lab Sample ID: L6466-1 1(A)
Sample Size: 10.1 9 (dry) GC Column ID(s): DB—5DB-225
Concentration Units: pglg (dry weight basis) Sample Datafile(s): DX42 057 5:8DX42_059 5:100B43 042 S:16
TEQ
COMPOUND LAB CONG. DETECTION WHO U=1!2 DL U0
FLAGS FOUND UMIT 1998 TEF
2,3,78-TCDD 0;542 0.0500 1 5.42E-01 5.42E-01
1,2,3,7,8-PeCDD 0.449 0.0500 1 4.49E-01 4.49E-01
1,2,3,4,7,8-HxCDD 2.13 0.510 0.1 2.13E-01 2.13E-01
1,2,3,6,7,8-HXCDD 10.3 0.510 0.1 1.03E+00 1.03E÷00
1,2,3,7,8,9-HxCDD 17.6 0.510 0.1 i.76E+00 1.76E+00
I ,2,3,4,6,7,8-HpCDD 728 0.560 0.01 7.28E+00 7.28E+00
OCDD 7060 0.464 0.0001 7.06E-01 7.06E-01
23,7,8-TCDF 0.148 0.0362 0.1 1.48E-02 1.48E-02
1,2,3,7,8-PeCDF 0.163 0.0500 0.05 8.15E-03 8.15E-032,3,4,7,8-PeCDF 0.370 0.0500 0.5 1.85E-01 1.85E-0112,3,4,7,8-HxCDF 2.33 0.0600 0.1 2.33E-01 2.33E-011,2,3,6,7,8-HxCDF 0.718 0.0600 0.1 7.18E-02 7.18E-021,2,3,7,8,9-HxCDF 0.107 0.0600 0.1 1.07E-02 1.07E-022,3,4,6,7,8-HxCDF 0.572 0.0600 0.1 5.72E-02 5.72E-021,2,3,4,6,7,8-HpCDF 47.1 0.120 0.01 4.71E-01 4.71E-011,2,3,4,7,8,9-HpCDF 3.52 0.120 0.01 3.52E-02 3.52E-02OCDF 229 0.0500 0.0001 2.29E-02 2.29E-02
TOTAL TEQ 13.1 13.1
(1) U = not detected(2) Concentrations that do not meet quantification criteria are not included In the TEQ calculations.
llOO4OXTEQIjds, S14 (tEQ) Appmved by: QAIQC Chemist
0136-][( A.)C’YS JJ’.JJ\LY’Ti1A.L SEI ‘‘IZES LTE P0. lOX 2219, 2045 MIlLS RD. WEST, SIDNEY OX., CANADA VII 3S8 TEL (250) 655-5600 FAX (250) 655-581 1
. .•‘b S..
-CS
_:‘1
:‘
r
I
I’ •.. ..
Z. ...• •••. : 4;
:
1; :‘/:X,
• s•i>.. t . ••:••
is •‘c. ••• ••1•
t
.• A
• . 1_•
••i
• •.• .. I %.•••_i.. • • ,.... ? —: . .• Ir(.’..i. .•
bJ..:.. .r •... •. . . -
• .. ‘j ‘.—. ;•I’
• 4.Y •.
• . . rt.. tCY;. ‘J I •
‘-.• • • •. t.s .r.;.’1. • I.. —.
• •1•_• I. V r•..%.• .......
£ 11’.’r •‘i4I •: . • ..
— ‘ t 5,, 1— 3
3
•1 ‘I... i. •. • • • L• •• •••
•.•. ‘4t t L. .n %‘ : •; •: •• . .•• — ••;. •1
I I -
1
, 1 ‘ •)\•• ••
— _..l•
ri:C. I• •.• •.• •6 •5 • • •.-.
•‘:• •• .‘ ... ‘S
C3
wt_
•,_tS .—. I
:
‘. - %•I —t-
II .• Ii
• •.1• %.t -.
•. •• :‘.: • • : . ....:: —
, — — —•
S •• 3 a. t, II
•41 • . • • •••• . . . ..I •iI.1.•• • — .1.
i, I.• p..’
......
•fl? •t•I...•••p.. ..4. . .. . ., A.. P
‘I
In •.•‘•.• •• . • •
I.•••• .• ... ..
• • •. . —.... •. .. t1 . •. I.
— S I.
—
S.• •I
•.• S.. . . ; — . •. •. —: ••
1— — I.Si
•%_ S•
— _
—
— —,
a —
.. ••• •• tT’ø —
••• •• a.
.3. . .. •1 . • . •:.
.5 . . . • I. •• • . S • •• ••I..
iI• • • . . ... •..•. •- •• •.4.1
.:.—.. . ••‘••
• ...... . .
—
tI)
.51 C t
__ ,
..
:.. •• . •
‘,, S ..“ t’ — . —‘ ,: •
r — • •3 — 4••
5 ‘ k I V‘ 01 37 ‘
AXYS METHOD DX-S-lBl3Ner.3 CUENT ID:
isisosa-soos-oi Form 1A 3TM4(P4JS-BB.11C.PCDDIPCEJF ANALYSIS REPORT (DUPLICATE)
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG11004-103(CUP L646&-l1)
Matrix: DITCH SEDIMENT Sample SIze: 10.9 g (dry)
Sample Receipt Date: 21-Jan-2004 Initial Calibration Date: 03-Feb2004
ExtractIon Date: 27-Jan-2004 Instrument ID: HR GC/MS
Analysis Date: 09-Feb2004 Time: 3:00:15 GC Column ID: DB-5
Extract Volume (JL): 20 Sample Datafile: DX4Z_057 S:9
Injection Volume (zL): 1.0 Blank Data Filename: 0X42_056 S:5
Dilution Factor: N/A Cal. Var. Date Filename: DX42_057 S:1
Concentration Units: pg/g (dry weight basis) % MoIsture: 12.8
COMPOUND LAB CONC. DETECTION ION ABUND. RRT2
FLAG1 FOUND LIMIT RATK$
2,3,7,8-TCDD 0.530 0.0500 0.81 1.001
1,2,3,7,8-PeCOD 0.410 0.0500 0.59 1.000
1,2,3,4,7,8-I-IxCDD 1.80 0.340 1.21 1.000
1,2,3,6,7,8-HxCDD 9.64 0.340 1.28 1.000
1,2,3,7,8,94IxCDD 16.5 0.340 1,23 1.009
1,2,3,4,6,7,8-HpCDD 703 0.410 1.06 1.000
OCDD E
2,3,7,8-TCDF 0.429 0.0500 0.80 1.002
1,2,3,7,8-PeCDF 0.113 0.0500 1.59 1.001
2,3,4,T,B-PeCDF 0.256 00500 1.76 1.000
1,2,3,4.7,8.HxCDF 1.87 0.0500 1.32 1.000
1,2,3,6,7,8-HxCDF 0.503 0.0500 1.40 1.001
1,2,3,7,8,9-HxCDF 0.075 0.0500 138 1.000
2,3,4,6,7,8.HxCDF 0.492 0.0500 1.34 1.000
1,2,3,4,6,7,8-HpCDF 39.3 0.100 1.05 1.000
1,2,3,4,7,8,9-HpCDF 2.99 0.100 1.03 1.000
OCDF 210 0.0500 0.90 1.002
Total Tetra-I3loxlns 30.3 0.0500
Total Penta-Dloxlns 23.1 0.0500Total Hexa-Oloxlns 342 0.340Total Hepta-Dloxins 5320 0.410Total Tetre.Furens 3.53 0.0500Total Penta-Furans 3.69 0.0500Total Hexa.Furans 31.2 0.0500Total Hepta-Furans 203 0.100
• (1) U = not detected; K = peak detected, but dld not meet quantification ciiteria; E = exceeds calibrated linear range, see dilution data; 0 = dilution
data; Z = compound not requested: X = results reported separately
(2) Contract-requIred limits for RRT5 and Ion abundance ratios are specified In Tables 2 and 9, respectively, Method 1613.
(3) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
18-O22OO4
11004003_ljds,S7 Approved by: j 1 QA/OC Chemist dd-mm
0138ø))[( ,.X’Y’S SEIZ’/ICZES LT”[) P.O. DCX 2219, 2045 MIU.S RD. WEST, SIDNEY, D.C., CANADA VtL 358 TEl (250) A55580 FAX (250) 655811
AXYS METHOD DX.S-lGl3Ner.3 CLIENT ID:1813DB5-S005-D1 Form 1A 3TM4(P-DS-BB-1IC
PCDD/PCDF ANALYSIS REPORT (DUPUCATE)
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG1IOO4-l03 W(DUP L6466-11)
Matrix: DITCH SEDIMENT Sample Size: 10.9 g (dry)
Sample Receipt Date: 21-Jan-2004 Initial Calibration Date: Q3-Feb-2004
Extrection Date: 27’-Jan-2004 Instrument ID: HR GC/MS
Analysis Date: 10-Feb-2004 Time; 4:49:58 GO Column ID: DB-5
Extract Volume (IlL): 200 Sample Dataflie: DX42_059 S:11
Injection Volume (IlL): 1.0 Blank Data Filename: DX42 056 8:5
Dilution Factor: 10 Cal. Ver. Data FIlename: DX42 059 SI
ConcentratIon Units: pg/g (dry weight basis)
COMPOUND LAB CONC. DETECTION ION ABUND. RRT2FLAG1 FOUND LIMIT RATIO2
2,3,7,B-TCDD1,2,37,B-PeCDD1 ,2,3,4,7,8-HxCDD1,2,3,6,7,8-HxCDD1,23,7,89-HxCDDI ,2,3,4,6,7,8-HpCDDOCDD D 6590 0.378 0.90 1.000
2,3,7,8-TCDFI,2,3,7,8.PeCDF2,3,4,7,8-PeCDFI ,2,3,4,7,B-FIxCDFI,2,3,6,7,8-HxCLJF1 ,2,3,7,8,9-HxCDF2,3,4,6,7,8-HxCDF1 ,Z3,4,6,7,8-HpCDF1 ,2,3,47,B,941pCDFOCDF
Total Tetra-DioxlnsTotal Pente-DioxlnsTotal Hexa-DioxlnsTotal Hepta-DloxlnsTotal TetraFuransTotal Penta-FuransTotal Hexa-FuransTotal Hepta-Furans
(1) U = not detected; K = peak detected, but did not meet quantification criteria; E = exceeds calibrated linear range, see dilution data; D = dilutiondata; Z = compound not requested; X = results reported separately
(2) Contract-requIred limits for RRTs and Ion abundance ratios are specified in Tables 2 and 9, respectively, Method 1613.(3) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
171 iJ 18-02-200411004004_1.dsS9 Appmvedby f/(j LV QA/QC Chemist
0140)] A.)(’YS , .F’JAL’YTicZA.L SEF\.qcES LiE3 O. BOX 2219, 2045 MIlLS RD. WEST, SIDNEY, Lt., CAHtBA VOL 3S8 TEL 1250) 655-5800 FAX (250) 655-5811
AXYS METHOD DX-S.1 6l3IVer.3 CLIENT ID:161 3D65-S005-D1 Form 2 3TM.KP-DS-BB-1 IC
PCDDIPCDF ANALYSIS REPORT (DUPLICATE)
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG11004-103 W(CUP L6466-1l)
Matrix: DITCH SEDIMENT Sample Size: 10.9 g (dry)
Sample Receipt Date: 21-Jan-2004 InitIal Calibration Date: 03-Feb-2004
Extraction Date: 27Jan-2004 Instrument ID: HR GC/MS
Analysis Date: 10-Feb-2004 Time: 4:45:58 GC Column ID: DB-5
Extract Volume (aL): 200 Sample Datafile: DX42 059 S:l 1
InjectIon Volume 4iL): 1.0 Blank Data Filename: DX42 056 5:5
DilutIon Factor: 10 Cal. Var. Data Filename: DX42 059 S:1
Concentration Units: pg absolute
LABELED COMPOUND LAB SPIKE CONC. R(%)2 ION ABUNO. RRTFLAG1 CONC. FOUND
I 3C-2,3,7,8-TCDD13C-1,2,3,7,B-PeCDD1 3C-1 ,2,3,4,7,8-HxCDDI 3C-1 2,3,6,7,84-ixCDD13C-1 ,2,3,4,6,7,8-i-IpCDD13C-OCDD D 4000 3010 75.2 0.88 1.177
13C-2,3,7,8-TCDF13C..1 ,2,3,7,8-PeCDF13C-2,3,4,7,8-PeCDFI 3C-1,2,3,4,7,8-l-ixCDFI 3C-I ,2,3.6,7,8-HXCDF1 3C-1 ,2,3,7,8,9-HxCDF13C-2,3,4.6,7,8-HxCDF13C-1 ,2,3,4,6,7,8-HpCDFI 3C-1 ,2,3,4,7,8,9-HpCDF
CLEANUP STANDARD
37CI.2,3,7,8-TCDD
(1) E = exceeds calibrated linear range, see dilution data: D = dilution data; Z = compound not requested; X = results reported separately(2) Contract-required limits for percent recovery (R) are specified in Section 9.3.3, Method 1613.(3) Contract-required limits for RRTs and ion abundance ratios are specified in Tables 2 and 9, respectively,
Method 1613. NOTE: There is no ion abundance ratio for 37C14-2378-TCDD (cleanup standard).(4) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
11004004 lis,S9 Approved by:_______
______________OA/QC
Chemist
0141)X( A..)CYS .i’—i1.LVFIcEft.L SEI’\,qcES LrE3 0. BOX 2219, 2045 MIU.S tO. WEST, SiDNE1 BC, CANADA VOL 3S8 TEL (2501 65558OO FAX (250) 655581 I
AXYS METHOD DX-S-l6l3Ner.3 CUENT ID:1813oe225.08004-o1 Form lB 3TM-KP.DS-BB-IIC2,3,7,8 - TCDF CONFIRMATION ANALYSIS REPORT (DUPUCATE)
Sample Collection: 10-Jan-2004 10:50
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG1IOO4-103(DUP L6466-11)Matrix: DITCH SEDIMENT Sample SIze: 10.9 g (dry)
Sample Receipt Date: 21-Jan-2004 Initial Calibration Date: 14-Jan-2004
Extraction Date: 27-Jan-2004 Instrument ID: HR DC/MS
Analysis Date: 07-Feb-2004 TIme: 4:37:29 DC Column ID: DB-225
Extract Volume (pL): 20 Sample Dataflle: D843_042 5:17
Injection Volume (iiL): 2.0 Blank Data Filename: 13843 042 S:5
DIlution Factor: N/A Cal. Ver. Data Filename: D843 042 S:2
Concentration Units: pg/g (dry weight basis)
COMPOUND LAB CONC. DETECTION (ON ABUND. RRT2FLAG1 FOUND LIMIT RATIO2
2,3,7,8-TCDF 0.136 00344 0.88 1.001
(1) U = not detected; K = peak detected, but did not meet quantification cliteria; D = dilution data(2) Contract-required limits for RRTs and ion abundance ratios are specified in Tables 2 and 9, respectively, Method 1613.
11004c001_lids, S14 Approved by Chemist
01+2--)J( ...)CvS A.L’y’TI,L SEF\fIcES L1E P.O. 008 2219, 2045 MILLS RD. WEST, SIDNEY, B.C., CANADA V81 350 lEt (250) 655-5000 FAX (250)6555811
AXYS METHOD DX-S-l6l3Ner.3 CUENT ID:DxrEo-ol 3TM-KP-DS-BB-1 IC
PCDDIPCDF ANALYSIS TEQ DATA REPORT (DUPLICATE)
Lab Name: AXYS ANALYTICAL SERVICES Sample Collection: 10-Jan-2004 10:50
Contract No.: 4182
Matrix: DITCH SEDIMENT Lab Sample ID: WG1 1004-103(DUP L6466-11)
Sample Size: 10.9 g (dry) GC Column ID(S): D8-5DB-225
Concentration Units: pglg (dry ight basis) Sample Oatafile(s): DX42_057 S:90X42_059 S:110B43 042 S:1 7
TEQCOMPOUND LAB CONC. DETECTION WHO U=112 DL U=0
FLAG1 FOUND LiMIT 1998 TEF
23,7,6-TCDD 0.530 0.0500 1 5.30E-01 5,30E-011,2,3j,8-PeCDD 0.410 0.0500 1 4.1OE-01 4.IOE-0112,3,4,7,84ixCDD 1.80 0.340 0.1 1.80E-01 1.80E-011,2,3,6,7,8-HxCDD 9.64 0.340 0.1 9.64E-01 9.64E-0112,3,7,8,9-HxCDD 16.5 0.340 0.1 1.65E+00 1.65E+00I ,2,3,4,6,7,8-HpCDD 703 0.410 0.01 7.03E+00 7.03 E+00OCDD 6590 0.378 0.0001 6.59E-01 6.59E-01
2,3,7,8-TCDF 0.136 0.0344 0.1 1.36E•02 1.36E-02I,2,3,7,8.PeCDF 0.113 0.0500 0.05 5.65E-03 5.65E-032,3,4,7,8-PeCDF 0.256 0.0500 0.5 1 .28E-01 I .26E-011,2,3,4,7,8-HxCDF 1.87 0.0500 0.1 1.87E-01 1.87E-011,2,3,6,7,8-HxCDF 0.503 0.0500 0.1 5.03E-02 5.03E-02I,2,3,7,8,9-HxCDF 0.075 0.0500 0.1 7.50E-03 7.50E-032,3,4,6,7,8-HxCDF 0.492 0.0500 0.1 4.92E-02 4.92E-021,2,3,4,6,7,8.HpCDF 39.3 0.100 0.01 3.93E-01 3.93E-01I,2,3,47,8,9-HpCDF 299 0.100 0.01 2.99E-02 2.99E-02OCDF 210 0.0500 0.0001 2.1OE-02 2.IOE-02
TOTAL TEQ 12.3 12.3
(1) U = not detected(2) Concentrations that do not meet quantification criteria are not Included In the TEQ calculations.
11DEO1s, S3 fIEQ) Approved by: l1.- QA!QC Chemist
0143€)][( /..)(‘YS I .r’—.J, LrTIC,.L SER’\/ICES LTL3 RB. BOX 2219, 2045 MILLS RD. WEST, SIDNEY, B.C., CANADA VOL 358 TEL (250) 655-56O FAX (250) 655.5811
• ‘IV,,.‘
•
1. ‘•.j ••
ci’
• - -- - -‘,-
-_‘‘‘‘_•:•,,_,I_—
1 ‘
/ ‘II
I.
‘—-I
I’,’—
I’,
--
‘i. t
• ,
,
—
‘I•
•
AXYS METHOD DX-S-1 6l3Ner.3 CUENT ID:16150B5-S005-D1 Form IA LAB BLANK
PCDDIPCDF ANALYSIS REPORT
Sample Collection: N/A
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG1IOO4-101
Matrix: N/A Sample Size: 10.0 g
Sample Receipt Date: N/A Initial CalibratIon Date: 03-Feb-2004
Extraction Date: 27-Jan2004 Instrument ID: HR GC/MS
Analysis Date: 08-Feb-2004 Time: 11:24:32 CC Column ID: DB-5
Extract Volume (.iL): 20 Sample Datafile: DX42_056 S:5
injection Volume (pL): 1.0 Blank Data Filename: DX42_056 S:5
Dilution Factor: N/A Cal. Var. Data Filename: DX42 056 S:1
Concentration Units: pg/g
COMPOUND LAB CONC. DETECTION ION ABUND. RRT2FLAG1 FOUND UMf RATIO2
2,3,7,8-TCDD U 0.05001,2,3,7,8-PeCDD’ U 0.05001,2,3,4,7,8-fIxCDD U 0.05001,2,3,6,7,B-HxCDD 0.053 0.0500 1.06 1.0011,Z3,7,89-HxCDD 0.062 0.0500 1.29 1.0111,2,3,46,7,841pCDD K 0.139 0.0500 0.69 1.000OCDD 0.674 0.0500 0.93 1.000
2,3,7,8.TCDF U 0.0500I 2,3,7,8-PeCDF U 0.05002,3,4,7,8.PeCDF 0.068 0.0500 1.43 1.0011,2,3,4,7,8-HxCDF K 0.061 0.0500 1.57 1.0001,2,3,6,7,8-HxCDF 0.060 0.0500 1.33 1.0001,2,3,7,8,9-HxCDF 0.072 0.0500 1.26 1.0002,3,4,6,7,8-HxCDF K 0.070 0.0500 2.15 1.0001,2,3,4,6,T,B-HpCDF K 0.128 0.0500 1.37 1.001I,2,3,4,7,8,9-HpCDF K 0.101 0.0500 0.76 1.000OCDF 0.225 0.0500 0.94 1.002
Total Tetre-Dloxlns U 0.0500Total Penta-Dloxlns U 0.0500Total Hexa-Dloxins 0.115 0.0500Total Hepta-Dloxlns U 0.0500Total Tetra-Furans U 0.0500Total Penta-Furans 0.068 0.0500Total Hexa-Furans 0.132 0.0500Total Hepta-Furans 0.058 0.0500
(1) U = not detected; K peak detected, but did not meet quantification criteria; E = exceeds calibrated linear ran9e, see dilution data; C = dilutiondata; Z compound not requested; X = results reported separately
(2) Contract-requIred limits for RRTs and Ion abundance ratios are specified in Tables 2 and 9, respectively, Method 1613.(3) Alternate loris used for native and labeled P5CDD for confirmation and quantitation.
I 1004001_lids, S2 Approved by: \C2t41tV/t7’1A-_C CA/CC Chemist
fl 1 4 4€)J[( A)’CYS LYTiC1.L SEE\/ICES LTL) o. Box 2219, 2045 M;Ll.S RD. WEST, SIDNEY, B.C.. CANADA VBL 358 TEL (250) A555800 FAX (250) 655.51
PXYS METHOD DX-S-1 61 3Ner.3 CLIENT ID:16130B5-S005-Dl Form 2 LAB BLANK
PCDDIPCDF ANALYSIS REPORT
Sample Collection: N/A
Lab Name: AXYS ANALYTiCAL SERVICES
Contract No.: 4182 Lab Sample ID: W011004—I01
Matrix: N/A Sample Size: 10.0 g
Sample Receipt Date: N/A Initial CalIbration Data: 03-Feb.2004
Extraction Date: 27-Jan-2004 Instrument ID: HR GC/MS
Analysis Date: 08-Feb.2004 Time: 11:24:32 GC Column ID: DB-5
Extract Volume (iJL): 20 Sample Datafile: DX42 056 S:5
Injection Volume (jiL): 1.0 Blank Data Filename: DX42_056 S:5
Dilution Facto: N)A Cal. Var. Data Filename: DX42_056 S:1
Concentration Units: pg absolute
LABELED COMPOUND LAB SPIKE CONC. R(%)2 ION ABIJND. RRT3FLAG1 CONC. FOUND RATIO3
13C-2,3,7,8-TCDD 2000 1280 63.8 0.81 1.01313C-1,2,3,7,8-PeCDD4 2000 1730 86.3 0.63 1.38213C-12,3,4,7,8-HxCDD 2000 1460 72.9 1.27 0.98613C-1,2,3,6,7,8-HxCDD 2000 1400 70.2 1.25 0.98913C-1,2,3,4,6,7,8-HpCDD 2000 1390 69.3 1.08 1.09413C.OCDD 4000 2280 57.0 0.90 1.178
13C-2,3,7,8-TCDF 2000 1430 71.6 0.80 0.96613C-1,2,3,7,8-PeCDF 2000 1480 74.1 1.68 1.28313C-2,3,4.7,8-PeCDF 2000 1420 71.2 1.60 1.35113C-1,2,3,4,7,8-HxCDF 2000 1360 68.0 0.53 0,95313C-1,2,3,6,7,8-HxCDF 2000 1360 68.2 0.53 0.95813C-1,2,3,7,8,9-HxCDF 2000 1390 69.6 0.55 1.00513C-2,3,4,6,7,8-HxCDF 2000 1470 73,3 0.63 0.98013C-1,2,3,4,6,7,B-HpCDF 2000 1410 70.6 0.46 1.06213C-1,2,3,4,7,8,9.HpCDF 2000 1350 67.7 0.46 1.104
CLEANUP STANDARD
37Cl-2,3,7,8-TCDD 200 124 61.9 1.014
(1) E = exceeds calibrated linear range, sea dilution data; D = dilution data; Z = compound not requested; X = results reported separately(2) Contract-required limits for percent recovery (R) are specified in Section 9.3.3, Method 1613.(3) Contract-required limits for RRTs and ion abundance ratios are specified in Tables 2 and 9, respectively,
Method 1613. NOTE: There is no ion abundance ratio for 37C14-2378-TCDD (cleanup standard),(4) Alternate loris used for native and labeled P5CDD for confirmation and quantitation.
1B-02-200411004901_lAs, S2 Approved by: .. QA/QC Chemist
0145•][c@ As)<’V’S L SER’%./IcEES LTE P.O. BOX 22)9, 2045 MiLLS RD. WEST, SIDNEY, B.C, CANADA 981 3S8 TEL (258) 655-5800 FAX (250) 655-5811
AXYS METHOD OX-Si 61Ner.3 CLIENT ID:I613o225-DBQo4-O1 Form lB LAB 8L.ANK
2,3,7,8 - TCDF CONFIRMATION ANALYSIS REPORT
Sample Collection: N/A
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182 Lab Sample ID: WG1IOO4-101
Matrix: N/A Sample SIze: 10.0 g
Sample Receipt Date: N/A Initial CalibratIon Date: 14-.Jan-2004
ExtractIon Date: 27-Jan-2004 Instrument ID: HR CC/MS
Analysis Date: 06-Feb-2004 TIme: 21:29:46 GC Column ID: DB-225
Extract Volume (iL): 20 Sample DatafIle: DB43_042 S:5
Injection Volume (iL): 2.0 Blank Date Filename: DB43_042 S:5
Dilution Factor: N/A Cal. Var. Data Filename: 0B43 042 S:2
Concentration Units: pg/g
COMPOUND LAB CONG. DETECTION ION ABUND. RRT2FLAG1 FOUND UM1 RATIO2
2,3,7r8TCOF U 0.0500
(1) U = not detected; K = peak detected, but did not meet quantification criteria; D = dilution data
(2) Contract-required limits for RRTs arid ion abundance ratios are specified fri Tables 2 and 9, respectively, Method 1613.
IIOO4cDD1_1.ds,S2 Approved by: t4i 4t14(QA/oC Chemist
0146))[ A..)(YS J-4A.L’’1ic:1.L SEI’ icLS LTE O. BOX 2219, 2045 MILLS RD. WEST, SIDNEY, DL, CANADA VOL ISO TEL (250) 655-5800 FAX (250) 655-5811
AXYS METHOD OX-S-i 61 3Ner.3 CUENT ID:OXTEQ-O1 LAB BLANK
PCDDIPCDF ANALYSIS TEQ DATA REPORT
Lab Name: AXYS ANALYTICAL SERVICES Sample Collection: N/A
Contract No.: 4182
Matrix: N/A Lab Sample ID: WGI 1004-101
Sample Size: 10.0 g GC Column ID(S): 08-508-225
Concentration Units: pglg Sample Dataflle(s): DX42_056 S:5DB43_042 S:5
TEQCOMPOUND LAB CONC. DETECTiON WHO U=112 DL U=O
FLAG1 FOUND LIMIT 1998 TEF
2,3,7,8-TCDD U 0.0500 1 2.50E-02 0.OOE+001,2,3,7,8-PeCOD U 0.0500 1 2.50E-02 0.OOE÷001,2,3;4,7,8-HxCDD U 0.0500 0.1 2.50E-03 0.OOE+00i,2,3,6,7,8-HxCDD 0.053 0.0500 0.1 5.30E-03 5.30E-031,2,3,7,8,9-HxCDO 0.062 0.0500 0.1 6.20E-03 6.20E-031,2,3,4,6,7,8-HpCOD U 0.0500 0.01 2.50E-04 0.OOE÷00OCDD 0.674 0.0500 0.0001 6.74E-05 6.74E-05
2,3,7,8-TCDF U 0.0500 0.1 2.50E-03 0.OOE+001,2,3,7,8-PeCDF U 0.0500 0.05 t.25E-03 0.OOE+002,3,4,7,8-PeCOF 0.068 0.0500 0.5 3.40E-02 3.40E-021,23,4,7,8-HxCDF U 0.0500 0.1 2.SOE-03 0.OOE+001,2,3,6,7,8-HxCDF 0.060 0.0500 0.1 6.OOE-03 6.OOE-031,2,3,7,8,9-HxCDF 0.072 0.0500 0.1 7.20E-03 7.20E-032,3,4,6,7,8-HxCDF U 0.0500 0.1 2.50E-03 0.OOE+001,2,3,4,6,7,8-HpCDF U 0.0500 0.01 2.50E-04 0.OOE+001,2,3,4,7,8,9-HpCDF U 0.0500 0.01 2.50E-04 0.OOE+00OCDF 0.225 0.0500 0.0001 2.25E-.05 2.25E-05
TOTAL TEQ 0.121 0.0588
(1) U = not detected(2) ConcentratIons that do not meet quantification criteria are not induded in the TEQ calculations.
11OO4DXTEQ_1.ds, S2 (TEQ) Approved by: Q,AJQC Chemist
Q147
][( AXVS .r—.J\L’ VKC,’\L SE’\7IcES LTE3 tO. BOX 2219, 2t45 MillS RB. WEST, SIDNEY, B.C., CANADA VOl 358 tEL (250) 655-5800 FAX (250) 655.511
[——,.—
-
GNV
AXYS METHOD DX-S-l6l3IVer.31613085-S005-D1
Form 8APCDDIPCDF ONGOING PRECISION AND RECOVERY (OPR)
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: 4182
Matrix: SOLID OPR Data Filename: DX42_056 S:2
Extraction Date: 27-Jan-2004 Lab Sample LD.: WGI1004-102
Analysis Date: 08-Feb-2004 Time: 8:38:45
CONCENTRATIONS REPORTED ARE CONCENTRATIONS IN EXTRACT, BASED ON A 20-tiL EXTRACT VOLUME
LAB ION ABUND. SPIKE CONG. OPR CONG. R(%)4FLAG’ RATIO2 CONG. FOUND LIMITS3
(ng!mL) (nglmL)COMPOUND
2,3,7,8-TCDD 0.78 11.0 11.4 7.4 - 17.4 1031,2,3,7,8-PeCDD5 0.63 50.0 50.9 35 - 71 1021,2,3,4,7,8-HxCDD 1.26 50.0 46.7 35 - 82 93.51,2,3,6,7,8-HxCDD 1.27 50.0 49.9 38 - 67 99.81,2,3,7,8,9-HxCDD 1.27 50.0 47.8 32 - 81 95.51,2,3,4,6,7,8HpCDD 1.04 50.0 47.5 35 - 70 95.0OCDD 0.89 100 95.1 78 - 144 95.1
2,3,7,8-TCDF 0.80 10.0 10.2 7.5 - 15.8 1021,2,3,7,8-PeCDF 1.55 50.0 48.5 40 - 67 96.92,3,4,7,8-PeCDF 1.55 50.0 48.6 34 - 80 97.21,2,3,4,7,8-HxCDF 1.24 50.0 47.3 36 - 67 94.61,2,3,6,7,8-HxCDF 1.24 50.0 48.4 42 - 65 96.91.2,3,7,8,9-HxCDF 1.24 50.0 47.9 39 - 65 95.92,3,4,6,7,8-HxCDF 1.25 50.0 47.8 35 - 78 95.61,2,3,4,6,7,8-HpCDF 1.04 50.0 49.3 41 - 61 98.61,2,3,4,7,8,9-HpCDF 1.04 50.0 47.1 39 - 69 94.1OCDF 0.90 100 95.4 63 - 170 95.4
(1) E = exceeds calibrated linear range, see dilution data; 0 = dilution data; Z = compound not requested; X = resultsreported separately(2) Contract-required Ion Abundance Ratios are specified In Table 9. Method 1613.(3) Contraci-required concentration lImits for OPR as specified In Table 6, Method 1613.(4) R% = percent recovery(5) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
1 1004DDI 1.>ds, 8A,a Approved by: QAIOC Cherr6st
0148e)J[(@ ?)C’yS ..,!-_._1i.LY1icZ,e..L SEI\’IcES L—rE P.O. BOX 2219, 2045 MiLLS RD. WEST. 5IDNRY B.C., CANADA V8L 358 TEL (250) 655-5800 FAX (250) 655-5811
AXYS METHOD DX-S-l6l3Ner.3I 613DB5-S005-fl I
Form 88PCDDIPCDF ONGOING PRECISION AND RECOVERY (OPR)
Lab Name: AXYS ANALYTICAL SERV(CES
Contract No.: 4182
Matrix: SOLID OPR Data Filename: DX42_056 S:2
Extraction Date: 27-Jan-2004 Lab Sample 1.1).: WG1IOO4-102
Analysis Date: 08-Feb-2004 Time: 8:38:45
CONCENTRATIONS REPORTED ARE CONCENTRATIONS IN EXTRACT, BASED ON A 20-liL EXTRACT VOLUME
LAB ION ABUND. SPIKE CONC. OPRCONC. R(%)4FLA& RATIO2 CONC. FOUND LIMITS3
(nglmL) (ng!mL)LABELED COMPOUND
13C-2,3,7,8-TCDD 0.79 100 47.7 20 - 175 47,713C-1,2,3,7.8-PeCDD 0.64 100 71.9 21 - 227 71.913C-1,2,3,4,7,8-HxCDD 1.28 100 62.3 21 - 193 62.313C-1,2,3,6,7,8-HxCDD 1.24 100 59.0 25 - 163 59.013C-1,2,3,4,6,7,8-.HpCDD 1.06 100 68.8 26 - 166 68.813C-OCDD 0.90 200 117 26 - 397 58.3
13C-2,3,7,8-TCDF 0.79 100 54.3 22 - 152 54.313C-1,2,3,7,8-PeCDF 1.57 100 60.2 21 - 192 60.213C-2,3,4,7,8-PeCDF 1.59 100 61.1 13 - 328 61.113C-1,2,3,4,7,8-HxCDF 0.53 100 63.1 19 - 202 63.113C-1,2,3,6,7,8-HxCDF 0.54 100 62.2 21 - 169 62.213C-1,2,3,7,8,9-HxCDF 0.53 100 56.8 17 - 205 56.813C-2,3,4,6,7,8-HxCDF 0.53 100 59.6 22 - 176 59.613C-1,2,3,4,6,7,8-HpCDF 0,46 100 70.1 21 - 158 70.113C-1,2,3,4,7,8,9-HpCDF 0.46 100 65.7 20 - 186 65.7
CLEANUP STANDARD37C1-2,3,7,8-TCDD 10.0 5.25 3.1 - 19.1 52.5
(1) 5 = exceeds calibrated linear range, see dilution data; D = dilution data; Z = compound not requested; X = resultsreported separately(2) Contract-required ion Abundance Ratios are specified In Table 9, Method 1613.(3) Contract-required concentration limits for OPR as specified in Table 6, Method 1613. Labelled
compound concentrations limits are based on required percent recovery (Section 15.5, Method 1613).(4) R% = percent recovery(5) Alternate Ions used for native and labeled P5CDD for confirmation and quantitation.
184)2-20041 IOO4001_1.xls,. QA/QC Chemist dd-rnm-yyyy
O149-€)][(13 i\)CY’S . %r”—,LrTicZAL SEF”/IcZES LEF[ P.O. BOX 2219, 2045 MILLS RD. WEST, SIDNEY, D.C., CANADA VOL 358 TEL (250) 6554800 FAX 12501 6555811
S —
PageloftDX-D2225-1_02 Teuips -source: 240 Tune : OW Data -list : 14—JAN-2004
-i résv: 160 Lint : OW -lit 13re_ent: 220 check : -I 3
,• q I— t-
PPM — Volts
200 0.4927
1’ \ LP
V
PPM - Volts
200 0.1740
380.97604
fl i I
J.Q7cioLf.
peak Locate Examination;14-JT-2004 ;1718 Fi1e:DB43_011BCALExperitnent:DX-DB225-1_02 Function:l Refereace:PFK
PPM
200
Vo1t
0.1480
PPM
200
A.
Volta
—. 0.076
I
J292.98245 304.98245 318.97925
PPM Volta PPM Volts PPM Volts200 0.3338 200 0.1218 200 0.0787
:______
.
330.97925 354.97925 366.97925
Psak tocat
PM Volts
200 0.5368
!I- wfi “xauiination:14-J.N-20O4:21:34 3’ils:DS43011CAIa2/_012CAL1
5xperiment :DX-DB225-102 ‘unctioa:1 Reference:K
PPM Volts PPM Volts -
200 0.1664 200 0.0835
A.
I\292.98245 — 304.98245 33.8.97925
PPM Volts PM Volts PPM Volts
200 0.3744 200 0.1318 200 0 0930-
/Ar Pr’
330.97925 354.97925
:)__
366. 97925
PPM Vo1t
200 — 0.1880
J:380.97604
tQ
#3
a-i
OP
US
quan
15—
JN—
2004
Pag
e1
Pag
e1
of
1
AX
YS
Ana
lytic
alS
ervi
ces
Ltd.
POB
ox22
19,2
045
Mill
sR
oad
Sidn
ey,B
ritis
hC
olum
bia
Can
ada
V8L
3S8
Phon
e:2S
0-65
5-58
00Fa
x:25
0-65
5-58
11
clq
Data
Are
aD
ata
Fil
eS
IIm
aly
teT
abie
Factr
#1F
aczt
r#2
Siz
eH
CS
anple
Tex
tC
oxri
rnen
tsD
one
2C
STE
M—
DE
FAU
LT
DB
43_O
11B
61
16
l3b
-3b004
1.0
000
1.0
00
01.0
00000
yD
XO
23B
-CA
L,,
l,,2
.OuL
CS—
iy
3C
STEM
—D
EFA
ULT
DB
43_O
11B
51
1613b-d
bO
O4
4.0
000
1.0
000
1.0
00
00
0y
DX
O23
C—
CA
L,,
1,,
2.O
uL
CS—
2y
4c
STEM
—D
EFA
ULT
DB
43_O
l1B
41
1613
b—db
OO
420.0
000
1.0
00
01
.00
00
00
yD
X023D
-CM
,,,
1,,
2.O
uL
CS—
3y
5c
STEM
—D
EFA
ULT
DB
43_O
11B
31
16i3
b—db
OO
48
0.0
00
01
.00
00
1.0
00
00
0y
DX
O23
E—
CA
L,,
l,,2
.OuL
CS—
4y
6c
STEM
—D
EFA
ULT
DB
43_O
11B
21
i613
b—db
OO
44
00
.00
00
1.0
00
01.0
00000
yD
X02
3F—
CA
L,,
1,,
2.O
uL
CS—
Sy
AXYS METHOD DX-S-l6l3IVer.3161308225-0B004-D1
Form 3PCDD/PCDF INITIAL CALIBRATION RELATIVE RESPONSES AND ION ABUNDANCE RATIOS
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 14-Jan-2004
Instrument ID: HR GC/MS GC Column ID: 08-225
CSI Data Filename: DB43_011B S: 6 CS4 Data Filename: DB43_OIIB S: 3CS2 Data Filename: D843_O1IB S: 5 CS5 Data Filename: 0843 0118 S: 2CS3 Data Filename: 0843 0118 S: 4
RELATIVE RESPONSE (RR)LAB CSI CS2 CS3 CS4 CS5 MEAN RR CV
FLAG1(%RSD)2COMPOUND
2,3,7,8-TCDF 0.86 0.91 0.91 0.94 0.96 0.92 4.04
MIZ’SLABFORMING ION ABUNDANCE RATIO QC
FLAGRATIO3 UMITS
CSI CS2 CS3 CS4 CS5COMPOUND
2,3,7,8-TCDF MIM+2 0.67 0.72 0.74 0.73 0.77 0.65-0.89
(1) Z = compound not requested; X results reported separately(2) For contract CVspeclfications, see Section 10.5.4, Method 1613.(3) See Table 8, Method 1613, for rrVz specifications.(4) Ion Abundance Ratio Control Linuts from Table 9, Method 1613.
18.02-2004llOO4cDDlljds, Form 3 (51 Approved byj QA)QC Cherrst dd-mm-,
AXYS METHOD DX-S.l6l3Ner.31613D5225-D9004-D1
Form 5PCDDIPCDF RT WINDOW AND ISOMER SPECIFICITY STANDARDS
Lab Name: AXYS ANALYTICAL SERVICES
Instrument ID: HR GC/MS Initial Calibration Date: 14-Jan-2004
RT Window Data FIlename: Analysis Date: Time:
0B5 IS Data Filename: Analysis Date: Time:
DB-225 IS Data Filename: DB43_O1IB S:1 Analysis Date: 14-Jan-2004 Time: 17:21:52
DB..5 RT WINDOW DEFINING STANDARDS RESULT
ISOMERS ABSOLUTE RT ISOMERS ABSOLUTE RT
1,3,6,B-TCDO (F) NA 1,3,6,8.TCDF (F) NA1,2,8,9-TCDD (L) NA 1,2,89.TCDF (L) NA
1,2,4,79-PeCDD (F) NA 1,3,4,6,8-PeCOF (F) NA1,2,3,8,9-PeCDD (L) NA 1,2,3,8,9-PeCDF (L) NA
1,2,4,6,7,9-HxCDD (F) NA 1,2,3,4,6,8-HxCDF (F) NA1,2,3,4,6,7-HxCDD (L) NA 1,2,3,4,8,94IxCDF (L) NA
1,2,3,4,6,7,9.HpCDD (F) NA 1,2,3,4,6,7,8-HpCDF(9 NA1,2.3,4,6,7,84-IpCDD (L) NA 1,2,3,4,7,8,9-HpCDF (U NA
(F) = First eluting isomer (DB-5); (L) = Last elutirig isomer (DB-5)
ISOMER SPECIFICITY (IS) TEST STANDARDS RESULTS
% Valley% Valley Height Height
Isomers Between Isomers BetweenCompared Peaks Compared
Peaks
1,2,3,4-TCDD 1,2,3,8-TCDD1,2,7,8-TCDD 0 2,3,7,8-TCDD NA
1,2,7,8-TCDD 2,3,4,7-TCDF1,4,7,8-TCDD 0 2,3,7,8-TCDF 16
1,4,7,8-TCDD 2,3,7,8-TCDF1,2,3,7-TCDD 0 1,2,3,9-TCDF 19
I ,2,3,7-TCDDI.2,3,8-TCDD 0
llOO4cDDl_1.xls, Form 5(2) Approved by: QNOC Chemist
O155.8. ‘.tN’ .a. t%I a. N’riKa I Cif’. ,iec i rim pp pnv nun ,n,r putt on wee, empty or titian, you era ye. term
• 8E
6
•7E
6
•5E
6
•4E
6
3E
6
•1E
6
2.0E
6
.l..8
E6
.1•7
E6
.1.
6E6
•4E
6
.l.3
E6
.l.1
E6
.9.9
E5
.8.
5E
5
7.
OE
S
.5.
6E5
4.2
E5
.2.8E
5
.1.
4E
5
• OEO T
ime
IS-sct-ô
•e:D
B4
3_
Oll
B#
1-1
223
Acq:1
4-J
.AN
-2004
17
:21
:52
GC
EI+
Volt
age
SIR
Au
tospec-U
ltir
na
.89
87
SM
O(1
,3
)B
SU
B(2
56
,15
,—3
.0)
PK
D(3
,2,1
,0.1
0%
,87
24
.O,5
.0O
%,F
,T)
Ex
p:]
JX—
]JB
225—
1_02
Nois
e:>
>ip
leT
ext:
DX
000
1A
-RS
N,,
Ol-
05
Fil
eT
ext:
Al.
01E
7
A9
.27
E6
i’(1 C
k€cl
iz’d
167
ri
1636
ihstrtiijent Icq9isi•tiaEk Runlog Axys AnaLyticaL
03 Temps -source: 300 Time : AL Date-List :-s RT/AL Liner : 02-FES-2004
-: -septtan: 02FEg-2ao4
• •e-J•-.;c•; ••-•
•••
••-••
••
• •
_•••%• ••
••
• 0157
4p2v1L 20L
Peak Locate Examination: 3-FEB-2fJ04:19:O1 File:DX42O4BCAL1Experiment:DX-D85-1_03 Function:3 Reference:PfK
PPM VoLts200 0.0119
I.
318.97925
W 4 i r.
Peak locate Examination: 3-FEB-2004:19:01 File:0X42_O4BCAL1Experiment:DX-D85-103 Function:4 Refecerice:PFK
/I.
T\
330.97925
J__
PPM VoLts PPM VoLts200 0.0503 200 0.0156
1
354.97925
PPM Volts200 0.0205
I_Ii
PPM VoLts200 0.0367
ft. -
380.97604
PPM VoLts200 0.0195
liii
_____
392.97604 404.97604
Peak Locate Examination: 3-FEB-2004:19:02 File:0X42048CAL1
Experiment:OX-0B5-1_03 Function:5 Reference:PFK
36&97925
.J,,380.97604
PPM Volts
200 — 0.0099
A
PPM
200
VoLts
0.0124
PPM
200Volts
0.0356
PPM VoLts
200 — 0.0194
392.97604
PPM Volts
200 — 0.0156
“
404.97604
EPM Volts
200 0.0231
A1..I P
u416.97604 430.97284
-,______
t - — ,-‘
peak Locate Examination: 3-FEB-2006:19:02 FiteDX42048CAL1Experirnent:DX-D65-1_03 Function:6 Reference:PFK
____
.11
I I
, &.
PPM VoLts
200 — 0.0200
PPM
200
VoIts
0.0176
PPM
0D
Va L ta
0.0089
1:442.97284
II
454.97284
J .1
AA P466.97284
fl I %Z I
Peak Locate Examination: 3-FEB--2004:19:03 FiLe:DX42O48CAL1
Experiment:DX-DB5-1_03 Function:7 Reference:PFK
PPM VoLts
200 0.0244
430.97284
0162
J QFe.o9.
Peak Locate Examination: 4-FEB-2004:07:02 FiLe;0X42_049CA1/_048CAL2Experinient:DX-DB5-103 Function:3 Reference:PFK
j.\”330.97925
PPM Volts200 0.0363
380.97604
PPM Volts PPM Volts200 0.0484 200 0.01 69
-
A.. 4 1
292.98245 304.98245
PPM - Volts PPM Volts200 0.0571 200 0.0191
PPM Volts200 0.0138
jI318.97925
PPM Volts200 0.0117
366.97925
‘H
. ..__J
354.97925
Peak Locate Examination: 4-FEB-2004:07:03 FILe:0X42049CAL1048CA12
Experiment:DX-0B5-1_03 Function:4 Reference:PFK
PM Volts PPM VoLts200 0.0513 200 0.0159
I
330.97925
PPM Volts
200 0.0380
380.97604
354.97925
II I1I i1
PPM Volts
200 0.0099
366.97925
Peak Locate Examination: 4-FEB2OO:O7:O3 FILe;X42O49CAL/_O48CALaExperiment:DX-085-1a3 Function:5 Refei-ence:PFK
PPM VoLts200 0.0377
tA
PPM VoLts200 0.0201
380.97604 392.97604
Peak Locate Examination: 4-EEB-2004:07:03 FiLe:DX42JJ49CALJ_048CAL2Expeciment:DX-DB5-103 Function:6 Reference:PFK
PPM Volts
200 0.0160
.di404.97604
PPM Volts200 0.0144
iTMIc...t442.97284
PPM Volts200 0.0066
416.97604
ni
Peak Locate Examination: 4-FEB-2004:0?’:04 Fl le:DX42049CAL/_048CAL.2
Experiment:DX-0B5-1_03 Function:? Reference:PFK
PPM Volts200 0.009?
466.97284
PPM Volts200 0.0177
\442.97284
PPM Volts200 — 0.0145
454.97284
flhi7
pxqôcc3
OP
tTS
quan
4-F
EB
-2004
Pag
e1
Page
1of
1
AS
I
ctv
h,o
c/q
Data
Are
aD
ata
Fil
eS
IA
xia
lyte
Table
Factr
#1F
actr
#2S
ize
MC
Saii
1e
Tex
tC
om
men
tsD
one
1c
STE
M—
DE
FAU
LT
DX
42
_0
48
10
11
61
3b
—c0
05
1.0
000
1.0
00
01
.00
00
00
yD
XO
23B
-CA
L,,
l,,1
.OuL
CS
1Y
2c
STE
M—
DR
FAU
L.T
DX
42
_0
48
31
16
13
b—
a00
54.0
000
1.0
00
01
.00
00
00
yD
X023C
—C
AL
1.*
1,,
1.O
uL
CS
-2y
3c
STEM
—D
EFA
ULT
DX
42_0
486
116
13b—
c005
20.0
000
1.00
001.
0000
00y
DX
023D
—C
AL,
,1,,
1.O
uL
Cal
Win
’y
4c
ST
EM
-DE
FA
UL
T1J
X42
_048
51
1613
b—cO
Q5
80
.00
00
1.0
000
1.0
00
00
0y
DX
023E
—C
AI,
,,l,
,l.O
uL
CS
-4y
5c
STEM
—D
EFA
ULT
DX
42_0
484
11613b—
c005
40
0.0
00
01.0
000
1.0
00
00
0y
DX
O23
F—
CA
L,,*
l,,l
.Ou
LC
S—5
y
) D
pv9
AXYS METHOD DX-S-l6l3Ner.3161 3D85-S005-D1
Form 3APCDDIPCDF INmAL. CALIBRATION RELATIVE RESPONSES
Lab Name: AXYS ANALYTICAL SERVICES
InItial Calibration Date: 03-Feb.2004
Instrument ID: HR GC/MS GC Column ID: DB-5
CSI Data Filename: DX42_048 S:10 CS4 Data Filename: DX42_048 S:5CS2 Data Filename: DX42_048 S:3 CS5 Data Filename: DX42_048 S:4CS3 Data Filename: DX42_048 S:6
RELATIVE RESPONSE (RRJLAB CSI CS2 CS3 CS4 CS5 MEAN RR CV
FLAG1(%RSD)2COMPOUND
2,3,7,8-TCDD 0.91 0.94 0.95 0.94 0.92 0.93 1.831,2,3,7,8-PeCDD3 1.00 1.04 1.09 1.08 1.03 1.05 3.541,2,3.4,7,8-HxCDD 1.10 1.10 1.15 1.15 1.05 1.11 3.811,2,3,6,7,8-HxCDD 0.86 0.86 0.98 0.92 0.88 0.90 5.751,2,3,7,8,9-HxCDD4 0.99 0.99 1.09 1.04 0.97 1.02 4.981,2,3.4,6,7.8-HpCDD 1.05 0.98 1.10 1.05 0.97 1.03 5.28OCDD 1.16 1.05 1.20 1.12 1.04 1.11 6.502,3,7,8-TCDF 0.92 1.01 1.04 1.01 0.98 0.99 4.591,2,3,7,8-PeCDF 0.95 1.01 1.08 1.04 1.01 1.02 4.692,3,4,7,8-PeCDF 0.97 1.00 1.08 1.05 1.01 1.03 4.291,2,34,7,8-HxCDF 1.21 1.21 1.36 1.27 1.21 1.25 5.251,2,3,6,7,8-HxCDF 1.13 1.14 1.24 1.20 1.13 1.17 4.321,2,3,7,8,9-HxCDF 1.11 1.09 1.16 1.16 1.08 1.12 3.702,3,4,6,7,8-HxCDF 1.09 1.06 1.19 1.12 1.06 1.10 4.871,2,3,4,6,7,B.HpCDF 1.31 1.27 1.42 1.34 1.26 1.32 4.971,2,3,4,7,8,9-HpCDF 1.26 1.16 1.32 1.23 1.15 1.23 5.65OCDF5 1.55 1.36 1.62 1.55 1.43 1.50 7.16
(1) Z corqound not requested; X = results reported separately(2) For contract CV specifications, see Section 10.5.4, Method 1613.(3) Alternate Ions used for native and labeled P5CDD for confirmation and quantitation.(4) Response Ratios are calculated relative to the labeled analogs of the othert HxCDDs (Section 17.1.2, Method 1613).(5) Response Ratios are calculated relative to the labeled analog of OCDD (Section 17.1.1, Method 1613).
11004001_isis, 3A-0 Approved by: QA/QC Chenist
0169
AXYS METHOD DX-S-l6l3Ner.31613085-S005-fl1
Form 3BPCDDIPCI3F INITIAL CALIBRATION RELATIVE RESPONSES
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004
Instrument ID: HR GC/MS GC Column ID: DB-5
CS1 Data Filename: DX42_048 S:10 CS4 Data Filename: DX42_048 S:5
CS2 Data Filename: DX42_048 S;3 CS5 Data Filename: DK42_048 S:4
CS3 Data Filename: DX42 048 S:6
RELATIVE RESPONSE (RR)LAB CSI CS2 CS3 CS4 CS5 MEAN RR CV
FLAG1 (%RSD)2LABELED COMPOUND
13C.2,37,8-TCDD 1.09 1.05 1.07 1.11 1.17 1.10 4.1113C-1,2,3,7,8-PeCDD3 0.69 0.67 0.66 0.74 0.84 0.72 9.7713C-1,2,3,47,8.NxCDD 0.97 0.95 0.96 0.93 0.98 0.96 2.0313C-1,2,3,6,7,8-HxCDO 1.15 1.09 1.04 1.12 1.08 1.10 3.6713C-1,2,3.4,6,7,8-HpCDD 0.73 0.76 0.72 0.74 0.77 0.75 2.8213C-OCDD 0.61 0.65 0.61 0.68 0.75 0.66 8.43
13C-2,3,7,8-TCDF 1.72 1.64 1.63 1.72 1.75 1.69 3.1813C-1,2,3,7,8-PeCDF 1.20 1.16 1.15 1.27 1.40 1.24 8.1513C-2,3,4,7,8-PeCDF 1.15 1.12 1.09 1.21 1.33 1.18 8.3113C-1,2,3,4,7,8-HxCDF 1.37 1.30 1.30 1.32 1.29 1.31 2.4113C-12,3,6,78-HxCDF 1.56 1.46 1.48 1.52 1.51 1.51 2.6713C-1,2,3j,8.944xCDF 1.21 1.18 1.15 1.20 121 1.19 2.1113C-2,3,4,6,7,8-HxCDF 1.40 1.39 1.33 1.35 1.35 1.37 2.2313C.1,2,3,4,6,7,B44pCDF 1.03 1.03 0.98 1.01 1.01 1.01 2.0513C-1,2,3,4,78,9-HpCDF 0.89 0.90 0.86 0.91 0.94 0.90 3.13
CLEANUP
37C1-2,3,7,8-TCDD 1.18 1.12 1.09 1.14 1.18 1.14 3.27
(1) Z = compound not requested; X = results reported separately(2) For assignment of labeled compounds to Internal standards, see Table 2. For contract CV specifIcations,
see Section 10,6.3, Method 1613.(3) Alternate ions used for native and labeled P5CDD for confirmation and quantitation.
18-02-2004110O4DD1,j.xs, 3A-D (5) Approved byr QA/QC Chemist dd-em-y,
0170
AXYS METHOD DX-S-l6l3Ner.316130B5-S005-D1
Form 3CPCDDIPCDF INITIAL CALIBRATION ION ABUNDANCE RATIOS
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004
Instrument ID: HR GC!MS GC Column ID: DB-5
CSI Data Filename: DX42_048 S:10 CS4 Data Filename: DX42_048 S:5
CS2 Data Filename: DX42_048 S:3 CS5 Data Filename: DX42 048 S:4
CS3 Data Filename: DX42 048 S:6
MIZSIAR
FORMING ION ABUNDANCE RATIOFLAGRATIO2 LIMITS
CS1 CS2 CS3 CS4 CS5COMPOUND
23,7,8-TCDD MIM+2 0.76 0.78 0.79 0.78 0,78 0.65-0.891,23,7,8-PeCDD4 MIM+2 0.59 0.63 0.63 0.63 0.63 0.51-0.701,2,3,4J,8-HxCDD M+21M+4 1.30 1.27 1.26 1.31 1.27 1.05-1.431,2,3,6,7,8-HxCDD M+21M+4 1.26 1.28 1.27 1.22 1.27 1.05-1.431,23,7,8,9-HxCDD M+21M+4 123 1.29 1.27 1.26 1.24 1.05-1.431,2,3,4,6,7,8-HpCDD M+21M+4 1.11 1.04 1.05 1.06 1.05 0.88-1.20OCDD M+21M+4 0.89 0.90 0.90 0.90 0.90 0.76-1.02
2,3,7,8-TCDF M/M+2 0.80 0.78 0.78 0.78 0.78 0.65-0.891.2,3,7,8-PeCDF M+21M+4 1.56 1.55 1.58 1.56 1.56 1.32-1.782,34,7,8-PeCDF M+21M+4 1.56 1.54 1.56 1.56 1.56 1.32-1.781,2.3,4,7,8.+IxCDF M+21M+4 1.24 1.25 1.25 1.25 1.24 1.05-1.431,2,3,67,8-HxCDF M+21M+4 1.23 1.25 1.24 1.25 1.25 1.05-1.431,2,3,7,B,9.44xCDF M+21M+4 1.25 1.26 1.25 1.25 1.24 1.05-1.432,3,4,6,7,8-HxCDF M+21M+4 1.25 1.23 1.25 1.24 1.25 1.05-1.431,2,3,4,6,7,8-HpCDF M+Z1M+4 1.00 1.05 1.03 1.04 1.04 0.88-1.201,2,3,4.7,8,9-HpCDF M+21M+4 1.06 1.03 1.04 1.04 1.04 0.88-1.20OCDF M+21M+4 0.90 0.90 0.91 0.91 0.91 0.76-1.02
(1) Z = compound not requested; X = results reported separately(2) See Table 8, Method 1613, for m(z specifications.(3) Ion Abundance Ratio Control Limits from Table 9, Method 1613.(4) Alternate Ions used for native and labeled P5CDD for confirmation and quantitation.
18-02-200411004001 1xts, 3A-D Approved by: QNQC Chemist dd-rnm-
- fl171
AXYS METHOD DX-S-1613!Ver.31613DB5-S005-D1
Form 3DPCDDIPCDF INITIAL CALIBRATION ION ABUNDANCE RATIOS
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004
Instrument ID: HR GC)MS GC Column ID: DB-5
CS1 Data Filename: DX42_048 S:10 CS4 Data FIlename: DX42 048 S:5
CS2 Data Filename: DX42_048 S:3 CS5 Data Filename: DX42_048 S:4
CS3 Data Filename: DX42 048 S:6
IAR MIZ’SQCFORMING ION ABUNDANCE RATIO
3FLAGRATIO2 LIMITS
CSI CS2 CS3 CS4 CS5LABELED COMPOUND
13C-2,3,7,8-TCDD MITvl+2 0.79 0.77 0.78 0.80 0.79 0.65-0.8913C-1,2,3,7,8-PeCDD4 MIM+2 0.64 0.63 0.63 0.63 0.63 0.51-0.7013C-1,2,3,4,7,8-HxCDD M+21M+4 1.27 1.27 1.27 1.29 1.27 1.06-1.4313C-1,2,3,6,7,8-HxCDD M+21M+4 1.24 1.26 1.24 1.25 1.24 1.05-1.4313C-1,2,3,4,6,7,8-HpCDD M+2M+4 1.05 1.04 1.05 1.03 1.05 0.88-1.2013C-OCOD M+21M+4 0.90 0.90 0.89 0.89 0.89 0.76-1.02
13C-2,3,7,8-TCDF MRvI+2 0.79 0.79 0.79 0.79 0.79 0.65-0.8913C-1,2,3,7,8-PeCDF Mi’21M+4 1.58 1.57 1.58 1.56 1.57 1.32-1,7813C-2,3,4,7,8-PeCDF M+21M+4 1.58 1.58 1.58 1.58 1.58 1.32-1.7813C-1,2,3,4,7,8-HxCDF MIM+2 0.53 0.52 0.53 0.52 0.53 0.43-0.5913C-1,2,3,6,7,8-HxCDF MIM+2 0.53 0.53 0.53 0,63 0.53 0.43-0.5913C-1,2,3,7,8,9-HxCDF Ms’M+2 0.52 0.54 0.53 0.54 0.53 0.43-0.5913C-2,3,4,6,7,8-HxCDF MJNI+2 0.53 0.53 0.53 0.54 0.53 0.43-0.5913C-1,2,3,4,6,7,8-HpCDF M1M+2 0.46 0.46 0.46 0.46 0.46 0.37-0.5113C-1,2,3,4,7.8,9-HpCDF M/M+2 0.46 0.46 0.46 0.47 0.46 0.37-0.51
(1) Z = compound not requested; X = results reported separately(2)See Table 8, Method 1613, for rrVz specifications.(3)lon Abundance Ratio Control Lirruts from Table 9, Method 1613.(4) Alternate ions used for native and labeled P5CDD and quantitatlon.
18-02-20041 1QO4DD1_1.xs, 3A-0 (5) Approved by
________________________________________QAJQC
Chemist
0172
AXYS METHOD DX-S-l6l3Ner.31613D55-S005-D1 Form 5
PCDDIPCDF RT WiNDOW AND ISOMER SPECIFICITY STANDARDS
Lab Name: AXYS ANALYTICAL SERVICES
Instrument ID: HR GC/MS initial Calibration Date: 03-Feb-2004
RT Window Data Filename: DX42048 S:6 Analysis Date: 03-Feb-2004 Time: 23:41:32
DB5 IS Data Filename: 0X42_048 S:6 Analysis Date: 03-Feb-2004 Time: 23:41:32
DB-225 IS Data Filename: Analysis Date: Time:
08-5 RT WINDOW DEFINING STANDARDS RESULT
ISOMERS ABSOLUTE RT ISOMERS ABSOLUTE RT
1,3,6,8-TCDD (9 22:58 1,3,6,8-TCDF (F) 21:271,2,8,9-TCDD (L) 28:19 1,2,8,9-TCDF(L) 28:10
1,2,4,7,9-PeCDD (F) 32:01 1,3,4,6,8-PeCDF (9 28:521,2,3,8,9-PeCOD (L) 37:0 1 1,2,3,8,9-PeCDF (L) 37:06
1,2,4,6,7,9-HxCDD (F) 39:59 1,2,3,4,6,8-HxCDF (F) 38:571,2,3,4,6,74-IxCDD (L) 42:38 1,2,3,4,8,9-l-IxCDF (L) 42:59
I ,2,3,4,6,7,9-HpCDD (F) 45:43 1 ,2,3,4,6,7,B4IpCDF(9 45:161,2,3,4,6,7,8-HpCDD (L) 46:39 1,2,3,4,7,8,9.HpCDF (L) 47:04
(F) = FLrst eluting Isomer (DB-5); (L) = Last eluting Isomer (DB-5)
ISOMER SPECIFICITY (IS) TEST STANDARDS RESULTS
% Valley Height % Valley HeightIsomers Between Compared Isomers Between Compared
Peaks Peaks
1,2,3,4-TCDD 1,2,3,8-TCDD1,2,7,8-TCDD 0 2,3,7,8-TCDD 11
1,2,7,8-TCDD 2,3,4,7-TCDF1,4,7,8.TCDD 0 2,3,7,8-TCDF NIA
1,4,7,8-TCDD 2.3,7,8-TCDF1,2,3,7-TCDD 0 1,2,3,9-TCDF N/A
1,2,3,7-TCDD DB-5 column;1,2,3,8-TCDD co-stub as per
Figure 6 in Method
18-02-20041IOO4DiD1_ljds Form 5(2) Approved by: QA)QC Cherrst dd-mm-
0173
I?V
mc
W I.4
a
I I N
pmm
U
l..
• La LV
ID ID ID ID ID ID ID ID LC ID ID
0
0174
C
--
--
-00
--
.
-.:
--.
..-,
-
00
04
g.
-‘IL
.0
-0
0b
P1S
NN
NI
I0.
-.40
F-’C
’13
.10-
U)
IAC
l‘49
vi’
00
t’IA
Cl
-ri.C
lID
.
E.R
.4
’i-O
’4
.V
4.O
.C
.Q
4;0.’4rfIflC
ldJfl,S
.O
N4
4-
Uii
tC
t’4’’#C
I’.I
fl-r4.I
3n.N
-0-C
lN
‘S0
19,-
IL
Cl
Ia.k
i,u
OL
IO
’4
riJO
Ci0
’S
rt74i1D
r0P
VrI1F
ir40C
lrl’
13.4.400
Cl
rvqrn.oo-IN
NC
I--ori--.”N
:n-n.4’4u
PC
CN
Cl
.4N
ai-i.
C4
.NN
-N,C
t‘r
IN-0
.0
.0
.00
00
-‘
-0•
.-,
..
..
..
S4)
4)4
-‘S
..4
..4.4
‘S-:’S
‘Sp’4
‘S‘4
..4
.4..
‘St
.4:.
.4Ii
‘da
g0
..J
.•Q
,0
00-0..0.0
O9
_:O
,0
-Q
-O
;.O
000.
I-
....
CII0
0-P
.O
0-00---0
00.0O
0-
N*4.
P4P4
C4
..N’tf
..NN
t-4N
.N-N
N
I)IL
.U
Vs
‘%
C)
00
00
0.0
.00
00
00
0C
l
NN
NflN
NC
iC
IN
NN
NN
-Ø
4’S
.4’S
4‘S
‘S
’S
‘4fl
m.1
1,-1
.0
00
.0O
hS
Q_
0C
C0
00:’O
.-0
__0.0
00
411.
rl,0.Q
00
0k
9:.0
00
0-0
00
’‘S
ID1W
NN
.:5
0.
00
0ri
p4-ri
ri’.v
-1.ri.
.-4.4
.4.-I
.4rI
0-
NtiN
f4f4
,-
4).•
r1
.rt:rV
rI
.-L
rbrlrI’r4
4rI.r
4v
i
gN1
--U
r1.1
.4itr
.4.4
-rl.i-
ftl.tl
rip4
.4.4
4rI
v-I
--.
‘:.
.o
4)14
0CI
‘S.
-.-
.S
.’I.
I7-
..
0-
-
.-a
.:..-
-.
ijI..:oJ1
-II
NN
‘S
rI
N-I’)
.4.f
l;13
F—o
ci
v-I.—
I-’S4):
‘Q
ZZ
01
II
I’I
4I
II
110.fl
•ri
rU
ClN
N0
cC
%O
.Iw
ID
ID
D-3
D1
DW
13
13
0C
l.
IL0:N
-D
P-rI.-
W€%
1313
13
..4-ID
13.IQ
,10.1
W.I’c
4.
.4).0
0-fl,j
4‘S
.I..’
S.W
r’S
..4
‘S‘S
‘S1
-4
-0
14-M
40
00
10W
w:w
.C41
..
rI
1rI
N-
--:
..-
-.
II
F-
.-----
:.
.-
-:
mm
..
..
.-
Nfl
Cl
....
....
-.
.N
NID
..
.--
--.0--IN
Cl.’4U
lW
C--C
,-,
QflQ
)riN
s.-
0.-4N
ClqlflID
C’.
-.
-.,
,Ci)
v-Lst
.c-
Ifl.40
C-
ci
.4ri-
ri
rt
p4H
p4-d
:-i
U’-
I).
..
--.--:-
4)4)
IIi—
IN
NN
.N
-N
NN
-Ct
NN
NN
NN
N.
Pt
N.-
çi
LI
bj
‘4-s’S
’S
’S
.s’S
’S
’S
.4
.4
.I’S
”S
-’S
.tI-.4
-.4
.-q
-.
Sic>
,04)
144000.00000
00
00
90
0t.Q
_
ii14
4)4
41.41I
II-
4I
II
II
I-I
I(rI
..I.-_t:.-1.I
15D
ip4
4)P
)I’)
(9(9
Cl
Cl
Cl
Cl
Cl
I’)C
iP
i’fl
Cl.IP
V.-fl.P
i..I’I.-‘-4
0ii
.44)
0.4]
91
‘S‘S
’S
41
‘S‘S
41
‘4‘S
‘S‘S
fl’S
‘Sc-?&
--.:’S-,’S
0r4
IlIIrIIi
cfreog &j 4Peak Locate Examination: 6-FEB-2004 :19 :05 File:fl943041kCAL2/_042CAL1
Experiment :DX-DB225-1_02 Function: 1 Reference: PEK
PPM Volts PPM Volts
200 ,_ 0.1525 200,_,
0.0465
A A..._.292.98245 304.98245
PPM Volts PPM Volts
200 0.1127 200 ,, 0.0363
l”-wJ
330.97925 354.97925
PPM Volts
200 ‘S:-’ 0.0547
380.97604
PPM Volts
200 — 0.0221
I
318.97925
PM Volts
200 0.0236
/ciJnsq.•
366.97925
fll7iZ
6%)
Peak Locate Examination: 7-FEB-2004 06:56 File:JDB43_D4:3cAL0/042CAL2
Experiment :1)X-D3225-1_02 Function: 1 Referenàe:PFK
PPM Volts
200 0.1486
A292. 98245
PPM Volts
200 0.0992
330.97925
PPM Volta
200 0.0489
380.97604
PPM Volta PPM Volts
200 0.0479 200 0.0233
A. .
304.98245 318.97925
PPM Volts PPM Volts
200 0.0358 200 0.0232
- I —“ -
354.97925 366.97925
Pag
e1
OP
uS
quan
18—
FE
B-2
004
Pag
e1
of
1
e/q
Data
Are
aD
ata
Fil
eS
IA
naly
teT
able
Faotr
#1F
actr
#2S
ize
HC
Sam
ple
Text
Co
zmn
ents
Don
e
1C
STE
M—
DE
FAU
LT
DB
43_O
11B
61
1613b
—d
00
41.0
000
1.0
00
01.0
00000
yD
XO
23B
—C
AL
,,1,
,2.O
uL
CS—
iy
2C
STEM
—D
EFA
ULT
DD
43_O
11B
51
1613
b—db
OO
44.0
000
1.0
00
01
.00
00
00
yD
XO
23C
—C
AL
,,1
,,2
.Ou
LC
S—2
y3
cST
EM—
DEF
AU
LTD
B43
_011
B4
116
13b—
db00
420.0
000
1.0
00
01
.00
00
00
yD
X02
3D—
CA
L,,
1,,2
.Ou
LCS
—3
y4
cST
EM—
DEF
AU
LTD
B43
_011
B3
11613b—
004
80
.00
00
1.0
00
01.0
00000
yD
XO
23E
—C
AL
,,1,.2.O
i.IL
CS—
4y
5c
STEM
—D
EFA
ULT
DB
43O
11B
21
1613
b—db
OO
44
00
.00
00
1.0
000
1.0
00000
yD
XO
23F—
CA
L,,
1,,2
.Ou
LC
S—5
y6
qST
EM
—D
EFA
UL
TD
B4
30
42
21
1613
b—db
OO
42
0.0
00
01.0
000
1.0
00000
yD
XO
23D
—C
AL
,,,b
1,,2
.Ou
LC
S—3
y7
qST
EM
—D
EFA
UL
TD
543_042
181
1613
b—db
OO
420.0
000
1.0
00
01.0
00000
yD
X02
3D—
CA
L,,D
1,,
2.O
UL
CS—
3y
8q
STEM
—D
EFA
ULT
DB
43_0
423
116
13b—
dbO
O4
1.0
000
1.0
000
1.0
00000
yT
Ot.U
EN
E,,
1,,2
.Ou
Ly
9q
STEM
—D
EFA
ULT
DB
43._
042
41
1613
b—db
OO
41
.00
00
1.0
000
1.0
00000
yT
OL
UE
NE
,,1
,,2
.Ou
Ly
10q
STEM
—D
EFA
ULT
DB
43_0
425
116
13b—
dbO
O4
1.0
000
20.0
000
10
.00
00
00
yW
G11
004—
101,
,11W
G11004,2
.0/2
Dy
11q
STEM
—D
EFA
ULT
DB
43_0
426
116
13b—
dbO
O4
1.0
000
20
.00
00
9.7
60000
yL
64
66
—1
,,1,W
G11004,2
.0/2
0c.
y12
qST
EM—
DEF
AU
LT0B
43_042
71
1613
b—db
OO
41
.00
00
20.0
000
9.7
90
00
0y
L6466—
2,,
i,W
Gl1
004,2
.O/2
0’
y13
qST
EM—
DEF
AU
LTD
B43
_042
81
1613
b—db
OO
41.0
000
20
.00
00
9.8
10000
yL
64
66
—3
,,1,w
G1
10
04
,2.O
/20
y14
qST
EM—
DEF
AU
LTD
B43
_042
91
1613b
—&
00
41.0
000
20.0
000
6.2
10
00
0y
1,64
66—
4,,
1,w
G1l0
04,2
.D/2
0y
15q
STEM
—D
EFA
ULT
DB
43_0
4210
116
13b—
dbO
O4
1.0
000
20
.00
00
9.1
70000
yL
64
66
—5
,,1
,WG
11
00
4,2
.0/2
0y
16q
STEM
—D
EFA
ULT
DB
43_0
4211
116
13b—
dbO
O4
1.0
00
02
0.0
00
01
0.0
50
00
0y
L6
46
6—
6,,
l,W
Gl1
004,2
.0/2
0y
17q
STEM
—D
EFA
ULT
DB
43_0
4212
116
13b—
dbO
O4
1.0
000
20.0
000
9.8
30000
yL
64
66
—7
,,1
,wG
11004,2
.0/2
0*
y18
qST
EM—
DEF
AU
LTD
B43
_042
131
1613
b—db
OO
41.0
000
20.0
000
9.9
80000
yL
64
66
—8
,,1,W
Gll
004,2
.0/2
0y
19q
STEM
—D
EFA
ULT
DB
43_0
4214
1l6
l3b
—d
00
41.0
000
20
.00
00
10.0
50000
yL
6466—
9,,
1,W
G1
10
04
,2.0
/20
y20
qS
TE
W-D
EF
AU
LT
DB
43
04
215
116
13b—
dbO
O4
1.0
000
20
.00
00
9.7
60000
yL
6466—
l0,,
1,W
G1
10
04
,2.O
/20
x.
y21
gST
EM—
DEF
AU
LTD
B43
_042
161
1613
b—db
OO
41.0
000
20.0
000
10.1
40000
yL
6466—
l1,,
1,W
G1
10
04
,2.0
/20
y22
qST
EM—
DEF
AU
LTD
843_042
171
1613
b—db
OO
41.0
000
20
.00
00
10.8
90000
yW
G11
004—
103,
,1,W
C1
10
04
,2.0
/20
y23
qST
EM
—D
EFA
UL
TD
B43
_042
11
1613b
—o
00
41.0
000
20.0
000
1.0
00000
yD
XO
O1A
—R
SN,,
1,
,2.O
uL
WIN
/RE
Sy
AXYS METHOD DX-S-l6l3Ner.3161308225•D6004-D1
Form 4 & 6PCDDIPCDF CALIBRATION VERIFICATION & RELATIVE RETENTION TIMES
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 14-Jan-2004 GC Column ID: DB-225
Instrument ID: HR GCIMS Analysis Date: 06-Feb-2004
VER Data Filename: 0B43_042 S:2 Time: 19:42:47
LAB M/Z’S ION QC CONC. CONCFLA& FORMING ABIJND. UMIT& FOUND RANGE4
RATIO2 RATIO (nglmL) (ng!mL)COMPOUND
2,3,7,8-TCDF MIM÷2 0.74 0.65-0.89 10.3 8.4 - 12.0
Compounds using 13C-1234-TCDD as Internal Standard
LAB RETENTION TIME REFERENCE RRT RRT QC LIMITS5FLAG1
COMPOUND
2,3,7,8-TCDF 13C-2,3,7,8-TCDF 1.000 0.999 - 1.003
(1) Z compound not requested; X = results reported separately(2) See Table 8, Method 1613, for m!z specIfications.(3) Ion Abundance Ratio Control LImits as specified In Table 9, Method 1613.(4) Contract-required concentration range as determined from the percent of the test concentration in Table 6,Method 1613, under VER.(5) Contract-requIred limits for Relative Retention Times (RRT) as specified In Table 2, Method 1613.
I’ ) 18-02-200411004c001_1.xls, Form 4 & 6 Approved by Li QAIQC Chemist dd-mm-y
Ui 79. “.f’..fC .& P. I I I FIdZ I T’G nn finn nn,n .,nr ,,n.r nn ,nrrfl nn,nnr ,, n.. nfl,,,n,r, ,n,fl,.,.-r fiflfir.fi
AXYS METHOD DX-S-l6l3fVer.31613DB225DBOO4-D1
Form 5PCDDIPCDF RT WINDOW AND ISOMER SPECIFICITY STANDARDS
Lab Name: AXYS ANALYTICAL SERVICES
Instrument ID: HR GCIMS
RT Window Data Filename:
DB5 IS Data FIlename:
DB-225 IS Data Filename:
Initial Calibration Date: 14-Jan-2004
Analysis Date:
Analysis Date:
Analysis Date:
ISOMERS
1,36,8-TCDD (F)1,2,8,9-TCDD (L)
12,4,7,9-PeCDD (F)1,2,3,8,9-PeCDD (L)
1,2,4,6,7,9-HxCDD (F)1,2,3,46,74-IxCDD (L)
1,2,3,4,6,79-HpCDD (F)1,2,3,4.6,7,8-HpCDD (L)
(F) = First eluUng isomer (DB-5); (L) = Last eluting isomer (DB-5)
Time:
Time:
Time: 19:07:08
ABSOLUTE RT
NANA
NANA
NANA
NANA
llOO4cODl_1.xls, Form 5 Approved by: QA/QC Chen-st18-O22OO4dd-rnm-,
06-Feb-2004DB43_042 S:1
DB-5 RT WINDOW DEFINING STANDARDS RESULT
ABSOLUTE RT ISOMERS
NA 1,3,6,8.TCDF (F)NA 1,2,8,9-TCDF (L)
NA 1,3,4,6,8.PeCDF (F)NA 1,2,3,8,9-PeCDF (L)
NA 1,2,3,4,6,8-HxCDF (F)NA 1,2,3,4.8,9-1-IxCOF (L)
NA 1,2,3,4,6,7,8-HpCDF(F)NA 1,2,3,4,7,B,9-HpCDF (L)
ISOMER SPECIFICITY (IS) TEST STANDARDS RESULTS
% Valley Heightisomers Between Isomers
Compared Peeks
1,2,3,4-TCDD 1,2,3,8-TCDD1,2,7,8-TCDD 0 2,3,7,8-TCDD
1,2,7,8-TCDD( 2,3,4,7-TCDF
1,4,7,8-TCDD 0 2,3,7,8-TCDF
1,4,7,8-TCDD 2,3,7,8-TCDF1,2,3,7.TCDD 0 1,2,3,9-TCDF
1,2,3,7-TCDD1,2,3,8-TCDD 0
% ValleyHeight
BetweenCompared
Peaks
NA
20
22
0180c1rr . A. g,. A. I ‘,..1I A. I I ——.•:: I ..—,-. ..,‘.,.‘. —.,
3.2
E6
•0
E6
.2.9
E6
2.7
E6
• 5E
6
2.4
E6
2.2
E6
1E
6
1.9
E6
l.7E
6
1.
6E
6
1.4
E6
.1.3E
6
.1.1E
6
.9.5
E5
.S.
DE
S
.6.4
E5
.4.8E
5
.3.2
E5
.1.6
E5
OEO T
ime 4
2
;,,—M
Igz;1
‘‘
Al.
04
E7
Lle
:DB
43042
#1
-1224
Acq:
6-F
EB
-20
U4
l9:U
’/:U
(3C
EI+
V0
J.ta
ge
iR
Auto
spec-U
.Ltl
ma
)5.8
987
SM
O(l
,3)
BS
UB
(256,1
5,—
3.O
)P
KD
(3,2
,l,
O.1
O%
,19
84
.O,5
.OO
%,F
,T)
Exp:D
X—
DB
225-l
_02
Nois
e:>
>m
p1e
Text:
DX
OO
1A
-RS
N,,
Fil
eT
ex
t:A
146E
7
35-
3 7 5_
7 D_ 5_ 0-
9)U
O(.
i4-
99/
16:1
81620
16:2
216:2
41
6:2
616:2
81
6:3
01632
16
34
l636
16:3
81
64
0
•LOL-saa-.cj.‘.*Joi
£0b8a)a;Uaiatj 9dx
6o)urpat4oLtSIflboyuaunJ3scij
npp,wT 1,7
Peak Locate Examination: 8-FEB-2004:07:41 Fl Le:0X42_O56CAL(055CAL2)
Experiment:LJX-085-1_03 Function:3 Reference:PFK
-4/.
PPM
200
Volts
0.3044PM Volts
200 0.1274
PPM Volts200 0.0521
318.97925
;- VoLts200 — 0.0883
—,366.97925
A
33b.97925 354.97925
Peak Locate Examination: 8FEB-2004:07:41 Fi Le:DX42O56CAL(055CAL2)Experiment:DX-D85-1_03 Function:4 Reference:PFK
PPM Volts200 0.3357
330.97925
PPM Volts200 0.1914
A
____380.97604
PPM VoLts200 0.0688
i 416.97604
I
PPM VoLts PPM Volts200 0.1301 200 0.1329
A._____
392.97604 404. 97604
1 4
Peak Locate Examination: 8FEB-2004:07:42 Fi l.e:0X42_056CAL(055CAL2)Experiment:DX-D85-1_03 Function:5 Reference:PFK
PPM VoLts
200 0.1464
404.97604
PPM Volts
200 0.1205
1,\
L1t\442.97284
PPM Volts200 0.2131
380.97604
PPM Volts200 0.0674
J•
416.97604
454.97284
PPM VoLts200 0.1271
zI.
fl ‘1 0
Peak Locate Examination: 8-FEB-2004:07:42 File:0X42_056CAL(055CAL2)Experiment:VX-DB5-103 Fiinction;6 Reference:PFK
PPM Volts200 0.0767
Mb’
416.97604
PPM Volts200 0.1420
-
454.97284
PPM Volts200 0.0643
I-__
42.96967
Peak Locate Examination: 8-FE6-2004:07:43 Fi (e:DX42056CAL(055CAL2
Experiment:DX-DB5-1_03 Function:? Refererice:PFK
/J
430.97284
PPM Volts
200 0.0853
\
504.96967
J\J442.97284
PPM Volts
200 — 0.0607
-.
480.96967
PPM • Volts
200 — 0.0880
/516.96967
rPPM Volts PPM VoLts
200 0.1114 200 0.1151
JL A
fllQl7
Peak Iocate Examination 8-FEB-2004:19:39 FiLe:DX42_O57CAL(056CAL2)Experiment:DX-D85-103 Furiction:3 Reference:PFK
PPM Volts PPM VoLts200 — 0.2533 200 0.1022
1\
PPM Volts200 0.0490
j318.97925
PPM Volts200 0.0670
1.
366.97925
?
____
330.97925 354.97925
Peak Locate Examination: 8-FEB2004:19:39 Fl le:DX42_O57CAL(056CAL2)Experiment:DX-DB5-1j3 Function:4 Reference:PFK
PPM Volts200 0.2874
f\330.97925
PPM Volts200 0.1536
..J.380.97604
PPM Volts200 0.0549
L
416.97604
PPM Volts200 0.0752
366.97925
PPM Volts200 0.1062
-
404.97604
Peak Locate Examinatofl: 8-FEB-2004:19:40 Fi le:DX42_OSTCAL(056CAL2)Experment:DX-DB5-1_03 Functiori:5 Reference:PFK
J___366.97925
PPM Volts200 0.0893
L A___
*.
PPM VoLts PPM Volts200 0.0825 200 0.1862
A1p ‘N
PPM Volts200 0.1174
,j.
392.97604380.97604
PPM Volts200 0.0609
..
416.97604
PPM Volts200 0.1064
—
442.97284 454.97284
Peak Locate xamination 8-FEB-2004:19:40 Ffle:DX42_057’CAL(O56CALZ)ExperimenflDX-D85-1_03 Function:6 Reference:PFK
Peak Locate Examination: 8-FEB-2004:19:41 FiLe:DX4205?CAL(056CAL2)
Experiment:DX-D85-1_03 Function:7 Reference:PF)
PPM Votts
200 0.0786
504.96967
PPM VoLts
200 — 01139
442.97284
PPM Votts
200 0.0637
A
480.96967
PPM VoLts
200 — 0.0919
516.96967
PPM VoLts
200 — 0.1308
454.97284
PPM Volts
200 0.0681
Wk
J\492.96967
OP
uS
quan
l1-F
B-2
004
Pag
e1
Pag
e1
of
1
c/q
Data
Are
aD
ata
Fil
eS
Inaly
teT
able
Factr
#1F
actr
#2S
ize
HC
Sam
ple
Text
Com
men
tsD
one
1c
STEM
—D
EFA
ULT
DX
42.0
48
101
lSl3
b—
c00
51.0
000
1.0
000
1.0
00000
yD
X02
3B—
CA
L,,.
.l,
,l.O
uI.
CS—
ly
2c
STEM
—D
EFA
ULT
DX
42_0
483
116
13b—
c005
4.0
00
01.0
000
1.0
00000
yD
X02
3C—
CA
L,,
l,,l
.Ou
LC
S—2
y3
aST
EM—
DEF
AU
LTD
X42.0
48
61
1613
b—c0
0520.0
000
1.0
00
01.0
00000
yD
X02
3D—
CA
L,,.
l,,l
.Ou
LC
alW
in.
y4
cST
EM—
DEF
AU
LTD
X4
20
48
51
1613
b—c0
058
0.0
00
01
.00
00
1.0
00000
yD
X02
3E—
CA
1,,,
l,,l
.Ou
LC
S—4
y5
aST
EM—
DEF
AU
LTD
X4
20
48
41
1613
b—a0
05400.0
000
1.0
00
01.0
00000
yD
XO
23F—
CA
L,,
1,
,l.O
uL
CS—
Sy
6q
STEM
—D
EFA
ULT
DX
42_0
561
116
13b—
cOO
S2
0.0
00
01
.00
00
1.0
00000
yD
XO
23D
—C
AL
,,l,
,l.O
uL
Cal
y7
qST
EM—
DEF
AU
LTD
X4
20
56
131
1613
b—c0
0520.0
000
1.0
000
1.0
00000
yD
XO
23D
—C
AL
,,l,
,l.O
uL
Cal
y8
qST
EM—
DEF
AU
LTD
X42
..056
21
1613
b—s0
051
.00
00
1.0
00
020.0
00000
yW
G11
004—
102,
,l,
WG
ll0
04
,1.0
/20
y9
qST
EM—
DEF
AU
LTD
X42
_056
31
1613
b—s0
051
.00
00
0.1
000
1.0
00000
yD
XO
2OB
—SU
R,,
l,,l
.OuL
.y
10q
STEM
—D
EFA
ULT
DX
42_0
564
116
13b—
s005
1.0
000
0.1
000
1.0
00000
yD
XO
2OB
—SU
R,,
l,,1
.OuL
y11
qST
EM—
DEF
AU
LTD
X42
056
51
1613
b—s0
051
.00
00
1.0
00
010.0
00000
yW
G11
004—
101,
,1
,WG
11
00
4,1
.0/2
0*
y12
qST
EM—
DEF
AU
LTD
X42
._05
66
116
13b—
s005
1.0
000
1.0
00
09.7
60000—
yL
64
66
—1
,,1,W
511004,1
.0/2
0*
y13
qST
EM—
DEF
AU
LTD
X42
_056
71
1613
b—s0
051
.00
00
1.0
000
1.0
00000
yT
OL
UE
NE
,,l,
,l.O
uL
y14
qST
EM—
DEF
AU
LTD
X42
...05
68
116
13b—
s005
1.0
000
1.0
000
9.7
90000
y1.
6466
—2,
,l,
WG
11
00
4,l
.0/2
0*
y15
qST
EM—
DEF
AU
LTD
X42
_056
91
1613
b—s0
051.0
000
1.0
00
09
.81
00
00
y1.
6466
—3,
,l,
WG
1l0
D4,l
.0/2
0y
16q
STEM
—D
EFA
ULT
DX
42_0
5610
116
13b—
s005
1.0
000
1.0
00
06.2
10000
y1.
6466
—4,
,1,W
G1l0
04,1
.0/2
0y
17q
STEM
—D
EFA
ULT
DX
42_0
5611
116
13b—
s005
1.0
00
01
.00
00
9.1
70000
y1.
6466
—5,
,l,
WG
l10
04
,l.0
/20
y18
qST
EM—
DEF
AU
LTD
X42
_056
121
1613
b—s0
051.0
000
1.0
000
10.0
50000.-
y1.
6466
—6,
,1
,WC
1l0
04
,1.0
/20
yV
\L)
(N
AXYS METHOD DX-S-l6l3Ner.31613DB5-S005-D1
Form 4APCDDIPCDF CALIBRATION VERIFICATION
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004 GC Column ID: 09-5
Instrument ID: HR GC/MS Analysis Date: 08-Feb-2004
VER Data Filename: DX42_056 S:1 TIme: 7:43:57
LAB MIZ’S ION ABUND. QC CONC. CONC
FLAG1 FORMING RATIO LIMITS3 FOUND RANGE4RATIO2 (ng!mL) (nglmL)
COMPOUND
2,3,7,8-TCDD MIM+2 0.79 0.65-0.89 11.6 8.6 - 14.2
1,2,3,7,8-PeCDD5 MIM+2 0.63 0.51-0.70 49.5 39 - 651,2,3,4,7,8-HxCDD M+21M+4 1.26 1.05-1.43 48.6 39 - 64
1,2,3,6,7,8-HxCDD M+2JM+4 1.28 1.05-1.43 47.2 39 - 64
1,2,3,7,8,9-HxCDD M+21M+4 1.25 1.05-1.43 48.3 41 - 611,2,3,4,6,7,8-HpCDD M+21M+4 1.05 0.88-1.20 47.6 43 - 58OCDD M+21M+4 0.90 0.76-1.02 94.0 79 - 126
2,3,7,8-TCDF M!M+2 0.79 0.65-0.89 10.3 8.4 - 121,2,3,7,8.PeCDF M+21M+4 1.55 1.32-1.78 49.2 41 - 602,3,4,7,8-PeCOF M+21M+4 1.56 1.32-1.78 48.5 41 - 611,2,3,4,7,8-HxCDF M+21M+4 1.25 1.05-1.43 48.7 45 - 561,2,3,6,7,8-HxCDF M+21M+4 1.25 1.05-1.43 48.0 44 - 571,2,3,7,8,9-HxCDF M+21M+4 1.26 1.05-1.43 45.6 45 - 562,3,4,6,7,8-HxCDF M÷21M+4 1.25 1.05-1.43 47.6 44 - 571,2,3,4,6,7,8-HpCDF M+2)M+4 1.04 0.88-1.20 47.2 45 - 551,2,3,4,7,B,9-HpCDF M+21M+4 1.04 0.88-1.20 46.5 43 - 56OCDF M÷21M+4 0.91 0.76-1,02 89.6 63 - 159
(1) Z = compound not requested; X = results reported separately(2) See Table 8, Method 1613, for rnz specifications.(3) Ion Abundance Ratio Control Limits as specified In Table 9, Method 1613.(4) Contract-requIred concentration range as determined from the percent of the test concentration in Table 6, Method 1613, underVER.(5) Alternate Ions used for native and labeled P5CDD for confim’iation and quantitation.
if 18-02-2004IIOO4DDI_1,ds,4A,B Approved by: \1(AA/t l’’ QAIQC Chemist dd-mm-F
€)] .A..)CY’S I\r—i1 ..LY1i(Z...L SE1\’lcES LTE) IO. lOX 2219, 2045 MillS RD. WEST, SIDNEY, D.C., CANADA 081 3S8 TEl (250) 655’5800 FAX (250) 655-5811
AXYS METHOD DX-S-l6l3Ner.31613DB5-S005-D1
Form 48PCDDIPCDF CALIBRATION VERIFICATION
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004 GC Column ID: 08-5
Instrument ID: HR GC/MS Analysis Date: 08-Feb-2004
VER Data Filename: DX42_056 S:1 Time: 7:43:57
LAB MIZ’S ION ABUND. QC CONC. CONCFLAG1 FORMING RATIO UMITS3 FOUND RANGE4
RATiO2 (nglmL) (nglrnL)
LABELED COMPOUND
13C-2,3,7,8-TCDD MIM+2 0.80 0.65-0.89 96.6 82 - 12113C-1,2,3,7,8-PeCDD5 MIM+2 0.64 0.51-0.70 98.5 62 - 16013C-1,2,3.4,7,8-HxCDD M+21M+4 1.26 1.05-1.43 94.0 85 - 11713C-1,2,3,6,7,8-HxCDD M+21M+4 1.26 1.05-1.43 95.2 85 - 11813C-1,2,3,4,6j,84IpCDD M+21M+4 1.07 0.88-1.20 115 72 - 13813C-OCDD M+21M+4 0.90 0.76-1.02 217 96 415
13C-2,3,7,8-TCDF MIM+2 0.80 0.65-0.89 105 71 - 14013C-1,2,3,7,8-PeCDF M+21M+4 1.59 1.32-1.78 103 76 - 13013C-2,3,4,7,8-PeCDF M+VM+4 1.59 1.32-1.78 102 77 - 13013C-1,2,3,4,7,8-HxCDF MIM+2 0.52 0.43-0.59 101 76 - 13113C-1,2,3,6,7,8-HxCDF MIM+2 0.53 0.43-0.59 98.2 70 - 14313C-1,2,3,7,8,9-HxCDF MIM+2 0.53 0.43-0.59 94.8 74 - 13513C-2,3,4,6,7,8-HxCDF M)M+2 0.53 0.43-0.59 97.5 73 - 13713C-1,2,3,4,6,7,8.HpCDF MIM+2 0.45 0.37-0.51 104 78 - 12913C-1,2,3,4,7,8,9-HpCDF M!M+2 0.45 0.37-0.51 114 77 - 129
CLEANUP STANDARD37C1-2,3,7,8-TCDD6 9.26 7.9 - 12.7
(1) Z compound not requested; X = results reported separately(2) See Table 8, Method 1613, for m/z specifications.(3) Ion Abundance Ratio Control Limits as specified In Table 9, Method 1613.(4) Contract-required concentration range as determined from the percent of the test concentration in Table 6, Method 1613, underVER.(5) Alternate loris used for native and labeled P5CDD for confirmation and quantitation.(6) No ion abundance ratio; concentration reported.
18-02-200411004DD11.xs,4A,B Approved by: QNQC Chemist dd-mm-
0195€J[( A>C’v’S ,i._!ie.L’yiic,\L SEI?\/1c:ES LIID Pu. BOX 2219, 2045 MIlLS RD. WEST, SIDNEY, B.C., CAN000 VOL 358 TEL (250) 65S5B00 FOX (250) 6555811
AXYS METHOD DX-S-l6l3IVer.31613DB5.S005-D1
Form 6APCDDIPCDF RELATIVE RETENTION TIMES
Lab Name: AXYS ANALYTICAL SERVICES
Initial Calibration Date: 03-Feb-2004 GC Column ID: DB-5
Instrument ID: HR GC/MS Analysis Date: 08-Feb-2004
CS3NER Data Filename: DX42_056 S:1 Time: 7:43:57
Compounds using 13C-1234-TCDD as internal Standard
COMPOUNDFLAG1
RETENTION TIMERRT RRT QC LIMITS2
2,3,7,8-TCDF 13C-2,3,78-TCDF 1.001 0.999 - 1.0032,3,7,8-TCDD 13C-2,3,7,8-TCDD 1.001 0.999 - 1.0021,2,37,8-PeCDF 13C-1,2,3,7,8-PeCDF 1.000 0.999 1.0022,3,4,78-PeCDF 13C-2,3,4,7,8-PeCDF 1.000 0.999 - 1.0021,23,7,8-PeCDD3 13C-1,2,3.7,8-PeCDD 1.001 0.999 - 1.002
LABELED COMPOUND
13C-2,3,78-TCDF 13C-1,23,4-TCDD 0.966 0.923 .. 1.10313C-2,3,78-TCDD 13C-1,2,3,4-TCDD 1.013 0.976 - 1.04337C1-2,3,7,8-TCDD 13C-1,2,3,4-TCDD 1.013 0.989 - 1.05213C-1,2,3,7,8-PaCDF 13C-1,2,3,4-TCDD 1.284 1.000 - 1.42513C-2,3,4,7,8-PeCDF 13C-12,3,4-TCOD 1.351 1.011 - 1.52613C-1,2,3,7,8-PeCDD3 13C-1,2,3,4-TCDD 1.382 1.000 - 1.567
(1) Z = compound not requested; X = results reported separately(2> Contract-required limits for Relative Retention Times (RRT) as specified In Table 2, Method 1613.(3) Alternate Ions used for native and labeled P5CDD for confirmation and quantitation.
11004DD1.ljds, 6A,B Approved QAIQC Chemist
01 )6[( ,\.)C’Y’S i\r.I..L’yTic:\L SEt\/ICES LrE) P.O. BOX 2219, 2045 MILLS RB. WEST, SIDNEY, B.C., CANADA VOL 358 TEL 1250) 655-5800 FAX (250) 655-5011
AXYS METHOD DX-S-l6l3Ner.31613DB5-S005-D1
Form 68PCDD!PCD F RELATIVE RETENTION TIMES
Lab Name: AXYS ANALYTICAL SERVICES
InItial Calibration Date: 03-Feb-2004 GC Column ID: DB-5
Instrument ID: HR GC!MS Analysis Date: 08-Feb-2004
CS3NER Data Filename: DX42_056 S:1 TIme: 7:43:57
Compounds using 13C-123789-HxCDD as Internal Standard
COMPOUNDFLAG1
RETENTION TIMERRT RRT QC LIMITS2
1,2,3,4,7,8-HxCDF 13C-12,34,78-HxCDF 1.001 0.999 - 1.0011,2,3,6,7,8-HxCDF 13C-12,3,6,7,8-HxCDF 1.000 0.997 - 1.005i,2,378,9-HxCDF 13C-12,3,789-HxCDF 1.000 0.999 - 1.00123,4,6,7,8-HxCDF 13C-2,3,4,6,7,8-HxCDF 1.001 0.999 - 1.0011,23,4,7,8-HxCDD 13C-1,2,3,4,7,8-HxCDD 1.000 0.999 - 1.0011,2,3,6,7,8-HxCDD 13C-12,3,6,7,8-HxCDD 1.000 0.998 - 1.0041,2,3,7,8,9-HxCDD 13C-1 23,6,7,8-HxCDD 1.011 1.000 - 1.0191,2,3,4,6,7,8-HpCDF 13C-1,2,3,4,6,7,8-HpCDF 1.000 0.999 - 1.0011,2,3,4,67,8-HpCDD 13C-1,2,3,4,6,7,8-HpCDD 1.000 0.999 - 1.0011,2,3,4,7,89-HpCDF I 3C-1 ,2,3,4,7,89-HpCDF 1.000 0.999 - 1.001OCDD 13C-OCDD 1.000 0.999 - 1.001OCDF 13C-OCDD 1.002 0.999 - 1.008
LABELED COMPOUND
13C-1,2,3,4,7,8-HxCDF 13C-1 2,3,7,8,9-HxCDD 0.954 0.944 - 0.97013C-1,2,3,6,7,8-HxCDF 1 3C-1 ,2,3,7,8,9-HxCDD 0.958 0.949 - 0.97513C-1,2,3,78,9-HxCDF 13C-1,2,3,7,8,9-HxCDD 1.005 0.977 - 1.04713C-23,4,6,7,8-HxCDF 13C-1 ,2,3,7,8,9-HxCDD 0.980 0.959 - 1.02113C.1,2,3,4,7,8-HxCDD 13C-1,23,7,8,9-HxCDD 0.987 0.977 - 1.00013C-1,2,3,6,7,8-HxCDD 13C-1,2,3,7,8,9-HxCDD 0.990 0.981 - 1.00313C-1,2,3,4,6,7,8-HpCDF 13C-1,2,3,7,8,9-HxCDD 1.062 1.043 - 1.08513C-1,2,3,4,67,8-HpCDD 13C-1 2,3,7,89-HxCDD 1.094 1.086 - 1.11013C.1,2,3,4,7,8,9-lIpCDF 13C-1 ,2,3,7,8,9-HxCDD 1.104 1.057 1.15113C-OCDD 13C-1,2,37,8,9-HxCDD 1.178 1.032 - 1.311
(1) Z = compound not requested; X = results reported separately(2) Contract-required limits for Relative Retention Times (RRT) as specified In Table 2, Method 1613.
I B-02-20041IOO4DDI_ljds, 6A,B Approved by: QA/OC Chemist dd-mm.y
0197€)][( ...>c’S , t—-4 %LVTlc.L SEI/IcES LTiZ p.o. lOX 2219, 2045 MILlS RI. WEST, SIDNY, B.C., CANADA VII 358 TEl 250) 655-5800FA 1250) 655-5011
AXYS METHOD DX-S-l6l3Ner.31613065-S005-D1 Form 5
PCDDIPCDF RT WINDOW AND ISOMER SPECIFICITY STANDARDS
Lab Name: AXYS ANALYTICAL SERVICES
ISOMERS
1,3,6,8-TCDD (F)1,2,89-TCDD (L)
1,24,7,9-PeCDD (F) 31:591,23,8,9-PeCDD (L) 36:59
1,24,6,7,941xCDD (F) 39:591,2,3,4,6,7.HxCDD (L) 42:37
1,2,3,46,7,9-HpCDD (F) 45:431,2,34,6,7,B-HpCDD (L) 46:38
(F) = First eluting Isomer (DB-5); (L) = Last eluting Isomer (DB-5)
1,2,3,4TCDD1,2,7,8-TCDD
1,2,7,8.TCDD1,4,7,8-TCDD
14,7,8-TCDD1,2,3,7-TCDD
1,2,3,7-TCDDI,2,3,8-TCDD
ISOMER SPECIFICITY (IS) TEST STANDARDS RESULTS
% Valley HeightBetween Compared Isomers
Peaks
D6-5 column;co-etute as per
Figure 6 in Method
I 2,3,8-TCDD2,3,7,8-TCDD
23,4,7-TCDF2,3,7,8-TCDF
2,3,7,8.TCDF1,2,3,9-TCDF
% Valley HeightBetween Compared
Peaks
11004001_I xis, Form 5 Approved by: \.E6f,(AWJiiuI\A( OA1QC Cherrst18-02-2004dd-mm-y
instrument ID: HR GCIMS Initial Calibration Date: 03-Feb-2004
RTWindowData Filename: DX42 056 S:1 Analysis Date: 08-Feb-2004 Time: 7:43:57
D85 IS Data Filename: DX42 056 S:1 AnalysIs Date: 08-Feb-2004 Time: 7:43:57
DB-225 IS Data Filename: Analysis Date: Time:
DB-5 RT WiNDOW DEFINING STANDARDS RESULT
ABSOLUTE RT ISOMERS
22:56 1,3,6,8-TCDF (F)28:17 1289-TCDF (L)
1,3,4,6,8-PeCOF (F)I,2,3,8,9-PeCDF (L)
1,2,3,4,6,8+IxCDF (F)1,2,3,4,8,9-HxCDF (L)
1,2,3,4,6,7,8-HpCDF(F)1,2,3,4,7,8,9-HpCDF (L)
ABSOLUTE RT
21:2428:08
28:5037:04
38:5642:57
45:1547:03
isomers
0
0
0
12
N/A
N/A
019&))[( A..)(’yS, , .r A.L9I( .L SEL’/KES LTL P.O. BOX 2219, 2045 MIU.S RD. WEST, SIDNEY, B.C., CANAUt VOL 350 tEL (250) A55-5600 FAX (2501 655-58fl
.e:D
4_U
5b
ffi4
AC
—U
U4
UI44l
L8ax
p1e*
1F
i1T
exts
Tex
tDX
O23D
—C
kt,
Exp
,DX
—D
B5—
1..0
33
21
.89
36
P’3
5310(1
,3)
BS
UB
(256.1
5,—
3.O
)P
KD
(3,2
,1,O
.10%
,1252.Q
,5.D
O%
.F,T
)N
0X
S5
31
31
o 91
C#tf7
L
•856
756
•656
•556
• 556
-4
56
263O
2636
(b
j!
CC04C
1—
‘-‘
—,
—
-‘
--
,,-,;-:“
,‘,
--‘
-
‘t%
t%
t-t
oa.0jnz;;-
----_
Ct,00t4b
w.w.-c
--‘r
--
çg
(1.JflJ
Jt
tIL.C
j4...
,.
,n
s,
—t
‘t4t-
1KV
.‘0
-4flO
aIfl.0
.,N
-.ttQ
ain
nn
sa
,r_
tN
rr.so
ill-<
t<
L,,0-
-‘
CL
f44’
nN
00q.’stn
-1’.‘O
r0
oC
t-’GI
-Q
i,rN
jq;5
.ajk
Jn
’ttfl_).4
.flfls,0
.O
09j’r
t.
Np5
fl
R°
°o
p-
-“-F
’a1”i:t
4’
t$
rE
Em
C—
—-s
am
--.
mw
a-w
—’w
cm
-as.
a3sn4tW
.-,
r-r
Cfl-
Z--O
’--
-0.
1.--
uqus
‘w
arut
us.
us’.,
Iuru
s-?
u.tw
.uJ
us
‘-us.,-
‘r
-‘
-
4.1‘
0—
“-‘-‘,
----‘‘.t
..’,-
---’--t:
a-,--,,-.
,-‘--:-.,.l-
•—
.—
-
—.—
.r—
-
I,
-,-“‘
-t-
-y
t;tJ
t-
a—
-a--
-
—nJrn(474in4.c*aa.
N0
1
J-.40-&
/‘
--
-in
‘—I
—5-
.-.Joaoi?
:oii5’o
-1’0
4,n
-a’,P
Int
._2.-.,
--
--
—-0
(0
--u
t:atsv
:-
-.4
-‘—
‘Q-O
kO
,Os
O’W
0%
41
4r’
--
--.
-C
jo--a-.o
Dnr:o
--
‘--c
-:Q
.0$
Qa-’
in-.
Sa
‘-r4-a
E-
->.--C
?()--4
.1,,,
-.0
’-
-—
-—-f
-r-
-,,
-,
uc
4b
-rr
r“
rr-w
---
rrr
L,
JD
.Q.
-.
oosa
-in.
i,u
roC
s.;,
-,-
,C’
t---
-‘--
“‘,-i.,”s,-’
4,
A’4+
.-
.‘‘
-t
---re-5
--.
—5
,------
t41
——
-._-_—
:--“‘
_-.—
.s’_
--
-‘
--.
,-
-c-E
-.’ti
[*
H-.
-i1
1is.
,‘‘4--’
—-I.-,-
-.-
----
-jS
-;
-.€-
-,-is
-.,,-,
-c,;7
n:,-—
---ns
-in-
-,-,.
--
--,‘X
,‘-
;..J,
&0
1--O
OC
:o
-,
4s.-
-<
.-a-.
--e
-fr.,,f
l-
--
.,-ii.----“a
rn-
rn
-t-‘;-
.—
‘.
-ts
’-fla
(fts
c,a
,(n-vok-
‘‘
---
-,Tht97-,
-1
-a’,,:
’T
aa
0--
‘rfr--
--:
--
,-
“-
-:
---
---
.‘-
--.
--,-r’j,u
v-
-,(
--
-‘-:
---
-
t
--!
-‘-Z
&-.;-
<-r-.
-it”;
-.
--
5,
—
-4
’4
”-4
’-’.-C5
--t
itiin
in
iin
in
In
15%
ifl2in
frn
rm
.’.in
In,.
cg
-E,‘
4t”
r:
-‘--“-
-t
¶7
5-
itit
.&°“
‘a—
ri—
ff
99’
-
.j
aA
-4s-
-
