Analysis of Low Brominated DD/F
description
Transcript of Analysis of Low Brominated DD/F
-
Analysis of Low Brominated DD/F Takeshi Nakano(Hyogo Pref. Inst. of Pub. Health and Env.Sci.)PCDD/DF/PCB in environment
-
,,,,PeCDF,,,,Co-PCB,,,TCDD,,,,,HxCN congeners congenerscongeners congeners
-
Trend of PCB Use in JapanTotal 58,000tAmount of PCB use (t)
-
PCB product use in JapanAr-1242 1248 1254 12601969-1971KC-300 400 500 600
-
KC300KC400KC500KC600JapanJapanHomologue patternreflects product use
Graph1
0
8.0308016321
26.7672437811
26.8077485563
22.4548453783
12.1968409665
2.9985865653
0.6297989168
0.0514895281
0.0014413042
Sheet1
1962196319641965196619671968196919701971
KC300KC400KC500KC600KC300KC400KC500KC600KC300KC400KC500KC600%KC300KC400KC500KC600
0000000010001001000100100010200.10300030
1001010204040030200501603010020050302001004301.121090500350
570480730850910710890720400590301,7401,0904001,050602,600420470500301,4209,160242,2301,2702,1401205,760
10010102050130208040014090260300380902107003709802.62005501400890
9060100160230340560790120650501,6101,0803808101802,45064040660701,4105,400142,5105402,1203005,470
1,3901,1601,7701,7002,5602,3202,6502,420620400903,5303,0104704501004,0301,620390440502,50020,080537,0501,4801,29024010,060
0009070140280508080021070501100230802010002001,0102.72001502900640
000010150200500050090009002000202900.8016000160
201010201010200000014010000240108000904301.115018000330
2,0901,7102,6302,8403,8303,7604,5904,0001,3901,7801707,3405,6401,7902,46034010,2302,9101,2701,7901506,12037,80012,5504,4506,03066023,690
KC300KC400KC500KC600
010000
60.025.714.30
38.722.037.22.1
22.561.815.70
45.99.938.85.5
70.114.712.82.4
31.323.445.30
010000
45.554.500
53.018.8253
Sheet1
Sheet2
Sheet3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
()
%
PCB1969-1971
(t)
(1969-1971)
(t)
JapanHokkaidoTohokuKantoHokurikuTokaiKinkiChugokuShikokuKyusyu
D2CBs8.03080163211.23671482289.11303390696.01701449854.08351104596.919662701710.44666837154.96266241611.23671482287.3111572594
T3CBs26.767243781115.993511406530.83911308321.117657744820.019426338222.375062767433.530618987318.127786109815.993511406528.8398391406
T4CBs26.807748556347.588828633331.1654805225.199091247837.420030585921.676616672428.77958565124.375912625247.588828633339.3359573952
P5CBs22.454845378326.90772438419.012861957127.973982199426.372837922326.422234682316.375677518331.632689258526.90772438418.4014963762
H6CBs12.19684096655.77681562447.776407753515.60768959839.39065690617.17378725077.997129915117.27125075195.77681562444.3045587663
H7CBs2.99858656531.82265567541.63797506483.31329181362.09802288334.40210969162.26037288492.98354133071.82265567541.3235181246
O8CBs0.62979891680.58666708920.3494473020.66492593360.52185460220.9083879030.49148272140.550805080.58666708920.3818963792
N9CBs0.05148952810.07295376250.03723158050.05568429310.05858138630.06522542190.04128062410.05072437270.07295376250.0469271417
D10CB0.00144130420.00501763430.00148002270.00171999090.00330974970.00132643810.00104608710.0017779470.00501763430.0027368915
MCB0000000000
D2CBs8.01.29.16.04.16.910.45.01.27.3
T3CBs26.816.030.821.120.022.433.518.116.028.8
T4CBs26.847.631.225.237.421.728.824.447.639.3
P5CBs22.526.919.028.026.426.416.431.626.918.4
H6CBs12.25.87.815.69.417.28.017.35.84.3
H7CBs3.01.81.63.32.14.42.33.01.81.3
O8CBs0.60.60.30.70.50.90.50.60.60.4
N9CBs0.10.10.00.10.10.10.00.10.10.0
D10CB0.00.00.00.00.00.00.00.00.00.0
-
PCBHomologue DistributionandSource Estimation
-
Source estimationKCKCKCKCSediment ASediment BShip paintN.C.P.InsulatorInsulatorcapacitorcapacitor
-
To evaluate environmental risk
-
Daily variation of PCDD/Fsand PCBs in ambient air
-
Daily variation of Dioxin Concentration
-
Time trend of PCDD/F levels in ambient air
-
Time trend of PCDDs/PCDFsTEQMatsumura et al, symposium of J.Env.Chem, 2003.6Dioxin Emission Reduction Plan
-
0.000.100.200.300.400.50010002000300040005000600070008000Emission inventry (g-TEQ/yearPCDDs/PCDFspg-TEQ/m3)19971998199920002001Emission inventry vs Level in airMatsumura et al, symposium of J.Env.Chem, 2003.6
-
Matsumura et al, symposium of J.Env.Chem, 2003.6Time trend of Co-PCBsTEQ
-
Time trend of Co-PCBsTEQ
-
Time trend of PCB levels in ambient air
(log scale)
-
Ambient air
-
Low volume air sampler
-
Time trend of PCB levels in breast milk
-
Time trend of breast milk levels DioxinsPCBpg TEQ/g-fatg g-fat
60
40
20
0
Year (1973-2000)Konishi et al. (2003)Konishi et al (2003) Organohalogen compdspg TEQ/g-fatg / g-fatYear (1973-2000)
60
40
20
0
0.3
0.2
0.1
0
-
Development of congener specific analysis for PCBs using HT8-PCB
-
Congener number number of isomerof peakmono 3 3di 12 10tri 24 23tetra 42 39penta 46 38hexa 42 40hepta 24 23octa 12 12nona 3 3deca 1 1 total 209 192
-
Matsumura et al, J. Env. Chem. (2002)GC/MS-SIM chromatogram of TrCB (HT8-PCB)PCB product13C-TrCB
-
Matsumura et al, J. Env. Chem. (2002)GC/MS-SIM chromatogram of PeCB (HT8-PCB)13C-PeCBPCB product
-
Congener profiles of PCBsin environmental and human samples
-
Congener profiles of PCBs(Hexa-) in environmental and human samples
-
Congener profiles of PCBs(Hepta-) in environmental and human samples
-
Congener profiles of PCBsin human samples(pooled blood)
-
2831748099118153138163/164187180170Tri-CBsTetra-CBsPenta-CBsHexa-CBsHepta-CBsChromatogram of PCB in human blood 3~7ClHirai et al, (2003) Organohalogen compounds#187#180#153#138#74#99#118#28245-2345245-245245-234245-34245-2356245-4245-2424-4
-
Levels of the predominant PCB congeners in human bloodHirai et al, (2003) Organohalogen compounds245-23452345-234245-245245-234245-4245-24245-34245-2356245-2352345-34
22.334.142.449.054.559.663.467.070.373.375.6cumulative(%)
-
human milk/adipose tissue #74 (2,4,4',5-)#99 (2,2,4,4',5-)#118 (2,3,4,4',5-)#153(2,2',4,4',5,5'-)#138(2,2',3,4,4',5'-)#187(2,2',3,4,5,5,6-)PCB congeners predominant in human samples
-
Analysis of Low Brominated DD/F
ANALYSIS of MBDD/MBDF to T3BDD/T3BDF on a SP2331 - COLUMN
-
Introduction In the last two decades the increased use of brominated organic compounds especially brominated flame retardants (BFR) resulted in the presence of brominated compounds indoor, in the waste stream and in the environment.
-
IntroductionSome of the BFR, in particular the PeBDE, are associated with the presence and the formation potential of brominated dibenzo-p-dioxins and furans (PBDD/PBDF). Therefore the congener specific analysis of PBDD/PBDF received more attention in recent time.
-
IntroductionIn this respect also the analysis of low brominated DD/F homologues might be interesting in some processes and samples: Brominated aromatic compounds are subjected to debromination reaction under various conditions are dehalogenated more rapidly compared with chlorinated aromatic compounds.
-
IntroductionUnder UV or exposure to sunlight, brominated aromatic compounds can undergo rapid debromination . photo degradation
Debromination reactions are also observed during thermal degradation of polybrominated aromatics . thermal degradation
-
IntroductionTherefore it might be interesting to have selected samples analysed for low brominated DD/DF.
For this study we synthesised a low brominated DD and DF mixture and optimised a temperature program on a SP2331 column.
-
IntroductionWe have been reported complete assignment of M1CDD/F to T3CDD/F on SP-2331 (Dioxin 2000) DB5MS (Dioxin 2001) DB-Dioxin (Dioxin 2002)In this study, as the first step of complete assignment of M1BDD/F-T3BDD/F (74congeners)
-
Materials and MethodsStandards. (synthesised)The PBDD standards were synthesized by pyrolysis of bromophenols in Pyrex ampoules.The PBDD was synthesized by condensation of 2-monobromophenol, 2,4- and 2,6- dibromophenol(DBP) 2,4,6-tribromophenol (TBP) at 350C (30 min).
-
Standards PBDD by condensation2-BP + 2,4- DBP 2-M1BDD2-BP + 2,6- DBP 1-M1BDD2,4-DBP + 2,4- DBP 2,7/2,8-D2BDD2,4-DBP + 2,6- DBP 1,7/1,8-D2BDD2,6-DBP + 2,6- DBP 1,6/1,9-D2BDD2-BP + 2,4,6-TBP 1,3-D2BDD2,4- DBP + 2,4,6-TBP 1,3,7/1,3,8-T3BDD 2,6- DBP + 2,4,6-TBP 1,3,6/1,3,9-T3BDD 2,4,6- TBP + 2,4,6-TBP 1,3,6,8/1,3,7,9-T4BDD
-
Materials and MethodsStandards. (synthesised)For the PBDF mixture all three 2-/3-/4- bromophenol isomers, phenol, 2,4-DBP
were pyrolysed at 370C (15 minutes) in the presence of trace amounts of CuBr2
-
Standards PBDF4-BP + phenol 2-M1BDF3-BP + phenol 1-/3-M1BDF2-BP + phenol 4-M1BDF2,4-DBP + phenol 2,4-D2BDF4-BP + 4-BP 2,8-D2BDF3-BP + 3-BP 1,7-/3,7-/1,9-D2BDF2-BP + 2-BP 4,6-D2BDF------------------------------------------------------- 2,4-DBP + 4-BP 2,4,8-T3BDF-------------------------------------------------------2,4-DBP + 2,4-DBP 2,4,6,8-T4BDF
-
Materials and MethodsStandards. (commercially available )We obtained commercially available standards 2,7/2,8-D2BDD, 2,3,7-T3BDD 1,2,3,4-, 1,3,6,8-, 1,3,7,9-, 1,3,7,8-, 2,3,7,8-T4BDD 2,7-D2BDF, 2,8-D2BDF, 2,3,8-T3BDFEBC-2500 8-Br-2,3-CDF, 8-Br-2,3,4-CDF, 7-Br-2,3-CDD, 2-Br-3,7,8-CDD, EDF-2046: 13C-2,3,7,8-TeBrDF, 13C-2,3,7,8-TeBrDD (TeHxBrDD/DF)
-
GC/MS AnalysisThe analysis was carried out using HP 5890 II gas chromatograph connected to JMS-700 mass spectrometer (JEOL Ltd. Japan) operating at a resolution >10,000.
-
Temperature programTemperature program used for congener specific separation of the MBDD/F-T3BDD/F on SP2331 column (60m, 0.32mm i.d., 0.20um,): 120C, 1 min. isothermal; 20C/min. to 200C, 2C /min. to 260C, 30min. isothermal. Carrier gas flow rate: He 1.2mL/min.
-
Table.1Monitoring ionM1BrDD 261.9629263.9610D2BrDD 339.8735341.8715T3BrDD 419.7820421.7800T4BrDD 497.6925499.6904M1BrDF 245.9680247.9661D2BrDF 323.8785325.8765T3BrDF 403.7870405.7850T4BrDF 481.6975483.6955
-
Results and DiscussionThe use of the 2,4-DBP (resulting in 2- and 3- (7- and 8-) PBDD substitution) and 2,6-DBP (resulting in 1- and 4- (6- and 9-) PBDD substitution) produced a wide range of congeners within the D2BDD.
-
GC/MS-SIM chromatogram of M1BrDDT3BrDDSP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.
-
Reliable assignment (blue color) Confirmation by authentic standards
Progressing assignment red color Estimation from -formation ratio (major/minor) -regularity of elution order -comparison of RRT for PXDD/F (Cl and Br)
-
Brominated DD Mixture (Synthesis)
Major component
DiBrDD 13-, 27/28- , 16-/19-, 17/18-
TrBrDD 137-, 138-, 136-, 139-
TeBrDD 1368-, 1379-
-
2-MBP2,6-DBP2,4-DBP2,4,6-TBP1,3-DBDD2,8-DBDD2,7-DBDD1,3,6-D1,3,7-D1,3,8-D1,3,9-D
-
GC/MS-SIM chromatogram of M1BrDDT3BrDDSP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.
-
Results and Discussion
The use of all three monobromophenols produced a wide range of congeners within the D2BDF. Due to the higher pyrolysis temperature and the addition of CuBr2 the isomerisation/bromination reactions had a significant impact and hence a broad range of T3BDF were formed .
-
GC/MS-SIM chromatogram of M1BrDFT3BrDFSP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.
-
Reliable assignment (blue color) Confirmation by authentic standards
Progressing assignment red color Estimation from -formation ratio (major/minor) -regularity of elution order -comparison of RRT for PXDD/F (Cl and Br)
-
Brominated DF Mixture (Synthesis)
Major component M1BDF 2-, 1-, 3- , 4- (4:2:2:1) D2BDF 24-, 28- , 18-, 27-, 17-, 19-, 26-, 37- 16-, 26-, 46- T3BDF 248-, 247-, 246-, 249-(168-) T4BDF 2468-
-
2,8-DBDF2-MBDF1-MBDF3-MBDF4-MBDF2,4-DBDF2,4-DBP2-MBP3-MBP4-MBP
-
GC/MS-SIM chromatogram of M1BrDFT3BrDFSP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.
-
PCDFPBDFMCDFDCDFTCDFMBDFDBDFTBDF
-
On the high polar SP2331-column, all 4 M1BDF were separated and also for D2BDF and T3BDF a reasonable selectivity was achieved. However on the less polar DB5 column even the 4 brominated M1BDF were not completely separated while the 4 chlorinated M1CDF isomers could be separated also on this low polar column. This demonstrates that the selectivity for brominated congeners is smaller compared with the chlorinated congeners.
-
Separation of low chlorinated DD/F (Dioxin 2000, 2001, 2002) congener ULTRA-2 DB-5MS SP-2331 DB-DIOXINMCDF 4 4 4 4 4D2CDF16 8 10 15 16T3CDF28 8 10 23 21 congener ULTRA-2 DB-5MS SP-2331 DB-DIOXINMCDD 2 2 2 2 2D2CDD10 5 4 8 9T3CDD14 6 5 12 12
-
Separation of low brominated DD/F on BPX35 & SP-2331 congener BPX35 SP-2331MBDF 4 4 4D2BDF16 8 13T3BDF28 16 15 congener BPX35 SP-2331MBDD 2 2 2D2BDD10 5 7T3BDD14 6 9
-
Comparison of Separation for PXDD/F on SP-2331 (Cl/Br)congenerClBrMXDF 4 4 4D2XDF161513T3XDF282315congenerClBrMXDD 2 2 2D2XDD10 8 7T3XDD1412 9the selectivity for brominated congeners is smaller compared with the chlorinated congeners.
-
Comparison of Separation D2CDF and D2BDF 1,9-D2CDF 1,9-D2BDF
-
Low Brominated DD/F in Stack Gas Samples
-
GC/MS-SIM chromatogram(D2BrDF)SP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.PeCB(323.8834,325.8805)DiBrDF(323.8785, 325.8765)#126
-
GC/MS-SIM chromatogram(BrClDF)SP2331 ; 60m x 0.32mmid. 0.20um; 120C (1 min.), 20C/min. to 200C, 2C /min. to 260C (30min).; He 1.2mL/min.BrClDFBrCl2DF, BrClDDBrCl2DD
-
Thank you for your attention
-
Low Chlorinated DD/F in Environmental Samples
-
Ambient air
-
(MCDFTrCDF)Ambient airIncineration (flyash)Isomer distribution of ambient air(MCDF-TrCDF)
-
(MCDDTrCDD)Isomer distribution of ambient air(MCDD-TrCDD)Incineration (flyash)Ambient air
-
(MCDFTrCDF)28-23-27-37-2-238-128-237-1278-TCDF2378-TCDF238-TrCDF237-TrCDF128-TrCDF37-DiCDF27-DiCDF23-DiCDF28-DiCDFIsomer distribution of bleaching process(MCDF-TrCDF)
-
(MCDFTrCDF)(MCDFTrCDF)28-27-238-128-237-2-124-24-Isomer distribution of ambient air(MCDF-TrCDF)Isomer distribution of bleaching process(MCDF-TrCDF)Ambient air
-
CNP(MCDFTrCDF)(MCDFTrCDF)248-246-124-24-24-Isomer distribution of ambient air(MCDF-TrCDF)Isomer distribution of pesticide CNP (MCDF-TrCDF)pesticide CNPAmbient air
-
4-MCP3,4-DCP2,3,8-TrCDF1,2,8-TrCDF
-
Synthesis of 1,4,X-T3CDF isomers from chlorophenol Authentic standard (1,4,7- : NMR)2,5-DCP4-MCP3-MCP2-MCPO-m-p-1,4,6-TrCDF1,4,8-TrCDF1,4,9-TrCDF1,4,7-TrCDF
-
NMR 1,4,7-TrCDFAuthentic standardH9H6H8H2 ; H3
-
PCB levels andHomologue profiles in Environmental samples
-
PCB levels in air, water, sediment and biota (2002, MOE Japan)AirSedimentWaterBiota0.1-10ng/m30.1-10ng/L0.05-800ng/g-dry0.1-800ng/g-wet
-
Homologue profiles of PCBsin human samples
-
AirWaterBirdHuman bloodBreast milk
-
Congener profiles of TrCB,TeCBin human and combustion sample (A)
-
PCB congeners predominant in human samples (TrCB, TeCB)PCB productCombustionBreast milkCombustionPCB productBreast milk
Graph12
0.2521362922
0
3.8553943236
1.1804652803
1.1188671759
0.9913795665
3.090930818
2.2161453055
1.0284836765
0
0.0989663006
1.2892687915
0.3956011163
1.3119141826
7.5799999604
4.7246340261
3.4849474171
5.4313946986
3.7206443439
2.0699075764
4.3878581091
2.9854283841
0
0
0.0084507582
0.0740101554
KC400
KC
KC300KC400KC500KC600
_10.100.010.020.00
_20.000.000.000.00
_30.000.000.000.00
_100.120.000.000.00
_45.990.390.080.05
_90.280.020.010.00
_70.070.010.000.00
_61.040.090.020.01
_8_57.070.700.130.05
_140.000.000.000.00
_110.000.000.000.00
_13_120.000.000.000.00
_150.030.020.010.00
_191.750.250.030.02
_300.010.000.000.00
_1814.253.860.280.16
_175.501.180.110.09
_240.210.030.000.00
_270.880.170.020.01
_323.881.120.080.04
_164.490.990.100.06
_230.010.000.000.00
_340.020.010.000.00
_290.030.010.000.00
_260.730.290.030.02
_250.310.090.010.00
_313.903.090.190.06
_283.542.220.150.07
_210.020.010.000.00
_20_332.751.560.130.04
_221.931.030.070.03
_360.000.000.000.00
_390.000.000.000.00
_380.000.000.000.00
_350.000.000.000.00
_370.040.100.010.00
_540.040.020.000.00
_500.030.020.000.00
_531.061.290.070.03
_510.370.400.010.00
_451.181.310.040.03
_460.490.500.020.01
_52_694.417.584.280.42
_730.000.000.000.00
_43_493.514.720.600.10
_650.000.000.000.00
_750.000.000.000.00
_48_472.913.480.120.05
_620.000.000.000.00
_443.455.431.120.09
_590.450.450.020.01
_421.411.720.060.02
_642.243.720.300.04
_720.000.000.000.00
_711.341.970.080.02
_410.810.810.020.02
_680.010.000.020.00
_400.760.900.050.01
_570.010.020.000.00
_670.070.120.010.00
_630.110.220.020.00
_580.000.000.000.00
_610.000.000.000.00
_740.682.070.250.02
_701.394.391.220.05
_760.040.060.010.00
_800.000.000.000.00
_661.072.990.260.02
_550.060.090.070.03
_600.561.150.070.00
_560.962.070.160.01
_790.000.000.000.00
_780.000.000.000.00
_810.000.010.010.00
_770.010.070.010.00
_1040.000.000.000.00
_960.040.200.040.00
_1030.010.040.030.00
_1000.000.030.010.00
_940.010.050.020.00
_102_930.110.280.120.00
_98_951.313.909.776.80
_880.010.030.000.00
_910.281.030.930.07
_1210.000.000.000.00
_920.290.461.560.51
_840.471.862.670.25
_890.060.210.030.00
_90_1011.373.469.816.20
_1130.010.020.000.01
_990.652.302.610.18
_112_1190.050.130.080.00
_830.080.220.320.02
_1080.000.000.000.00
_86_117_970.521.732.330.16
_125_1160.000.000.000.00
_87_1150.692.003.860.52
_1110.000.000.000.00
_850.341.190.810.07
_120_1101.164.059.001.76
_820.260.790.490.03
_1240.020.070.200.00
_109_1070.030.180.290.06
_1230.010.040.040.00
_1060.000.000.000.00
_1180.241.523.840.24
_1140.030.100.120.05
_1220.000.040.020.00
_105_1270.140.981.230.04
_1260.000.000.010.01
_1550.000.000.000.00
_1500.000.010.020.00
_1520.000.000.020.00
_1450.000.000.000.00
_1360.120.271.706.31
_1480.000.000.000.00
_1540.000.010.060.01
_1510.090.271.347.67
_1350.060.130.942.35
_1440.030.060.421.65
_1470.020.040.170.00
_149_1390.420.995.6920.32
_1400.000.000.030.00
_1430.000.010.030.00
_1340.030.080.550.61
_1420.000.000.000.00
_1310.010.040.160.08
_1330.000.010.100.09
_1650.000.000.000.00
_1460.050.150.811.40
_1320.250.513.305.09
_1610.000.000.000.00
_1530.400.865.5016.33
_1680.000.000.000.07
_1410.090.191.173.20
_1370.030.080.400.03
_1300.030.080.420.21
_164_1630.160.351.943.98
_1380.430.925.347.10
_1600.000.000.000.00
_1580.090.150.890.87
_1290.040.100.390.07
_1660.010.020.040.10
_1590.000.000.000.09
_1280.130.261.140.06
_1620.000.010.010.09
_1670.010.020.180.13
_1560.030.100.520.07
_1570.000.020.100.09
_1690.000.000.000.11
_1880.000.000.000.07
_1840.000.000.000.11
_1790.060.110.370.10
_1760.020.040.130.11
_1860.000.000.000.10
_1780.020.030.110.06
_1750.010.010.030.05
_182_1870.100.230.640.16
_1830.040.140.380.10
_1850.010.020.060.05
_1740.100.210.630.06
_1810.000.000.020.06
_1770.060.110.360.07
_1710.040.060.240.08
_1730.000.010.030.05
_1720.010.040.110.07
_1920.000.000.000.07
_1800.120.471.120.10
_1930.000.020.030.05
_1910.010.010.040.08
_1700.090.230.660.06
_1900.030.070.160.10
_1890.000.010.030.12
_2020.010.020.030.08
_2010.000.020.030.10
_2040.000.000.000.09
_1970.000.000.010.09
_2000.000.020.030.07
_198_1990.040.150.200.14
_1960.010.060.100.05
_2030.020.100.130.07
_1950.020.070.100.06
_1940.030.130.190.07
_2050.000.000.010.07
_2080.000.010.010.10
_2070.000.010.010.08
_2060.020.050.050.07
_2090.000.010.000.09
BZ38M41M25F37F31M25F37M36M31M25F43F37M32F41F33F25M42F29M48M28F35M44M40F38M41M25F37F31M25F37M36M31M25F43F37M32F41F33F25M42F29M48M28F35M44M40F
_1100000.36000.14000000000.2400.8200.140000000.101545752000.0222388131000000000.023637635100.073312472100.011141529300
_2815.49.21.64.24.94.34.36.87.64.51.98.55.83.84.726.27.17.36.61484.61.03565616220.899201470.4894313420.33106057621.38215051340.7782805431.0721855131.08017092121.07226501881.3548095740.27935425061.28552199750.67083820080.68796958451.13337673930.56175041430.61063890561.7796716380.65265981221.25709496781.11415292540.52735662490.4674369214
_310.650.420000.1700.180.130.160.160.2100.160.1400.160.160.170.470.160.1500.04371276010.04105050190000.030769230800.02859275970.01834137530.04817100710.02352456850.031759955200.02896714040.033760158200.01575842340.04010527640.01519892710.08952039920.01273317630.00988793670
_441.71.10.250.320.280.370.220.860.410.750.160.460.240.560.360.220.271.20.550.50.620.440.190.11432568020.10751321920.07647364720.02522366290.07898002930.06696832580.0548560030.13660985180.0578458760.22580159570.02352456850.06956942570.02775882210.10138499140.08681183530.06179254560.02659233940.30078957260.04917299960.09523446730.04934105810.02900461440.0193071772
_52_6911110.590.8311.50.624.61.54.70.41.60.754.71.10.70.68.21.43.22.11.30.620.73975440151.07513219240.18047780730.06542387580.28207153330.27149321270.15459419030.73070385840.21163125371.41502333280.05881142120.24198061130.08674631910.85090974930.26525838580.1966126450.05909408762.0553954130.12516763520.60950059050.16712293880.08569545150.0630023677
_47_4842.11.21.710.740.631.81.90.910.430.8110.921.50.790.8111.50.912.21.90.510.26900160060.20525250950.36707350650.13400070940.28207153330.13393665160.15708764490.28592759680.26806625470.27397260270.06322227780.12250268450.11566175880.16656105730.36171598060.22189141360.07977701830.25065797720.13410818060.17332673040.1750811740.12524719840.0518245282
_605.32.70.631.41.31.20.862.22.110.62.22.511.30.52.11.92.81.8031.40.35642712070.26389608360.19271359090.11035352540.36669299330.21719457010.21443710260.34946706270.29628375520.30106879420.08821713180.33272334050.28915439690.18104462750.31348718320.14043760360.20682930670.47625015670.25033527050.342844082100.19775873430.1422634109
_631.120.76000000000000.33000.250.420.350.340.970.530.280.07532044820.0742818606000000000000.0597447271000.02462253650.10527635040.03129190880.06475943770.07719488130.03493737640.0284526822
_700.850.500.180.160.170.190.320.260.20.140.350.190.160.20.150.310.230.340.20.360.250.220.05716284010.048869645100.01418831040.04513144530.03076923080.04737563890.05083157280.03668275060.06021375880.02058399740.05293325870.02197573420.02896714040.04822879740.04213128110.03053194530.05765133480.03039785430.03809378690.02864964670.01647989450.0223556789
_721.10.50.1300000.10000000000000000.07397544020.04886964510.039766296500000.0158848665000000000000000
_681.10.7400.280.260.220.20.440.30.3600.340.310.30.240.210.310.310.30.340.670.440.220.07397544020.072327074800.02207070510.07333859870.03981900450.04986909360.06989341250.04232625070.108384765900.05142087990.03585514520.05431338830.05787455690.05898379350.03053194530.07770397290.02682163610.06475943770.05332017570.02900461440.0223556789
_743830153211191319151031264218128.9411753295040532.55551520532.93217870654.58841883092.52236629493.10278686673.43891402713.24149108593.01812463272.1163125373.01068794224.55788514133.93218493374.85779386763.2588032952.89372784492.49978934364.03809598854.26118561224.73848904785.5235991013.97911759092.63678312465.3856862685
_6620122.15.59.44.23.188.43.11.686.445.827.55.57.1717114.21.34500800281.17287148260.64237863630.43353170692.65147241340.76018099550.77297095131.2707893191.18513502070.93331326210.23524568471.20990305650.7402352560.724178511.3986351250.56175041430.73867609551.37861887450.63477872151.33328254161.35289998090.72511535930.4267902326
_10521133.49.36.1124.79.19.293.810.710.55.65.23.19.85.217816168.21.41225840291.27061077281.04004160170.73306270441.72063635342.17194570141.17192370031.44552285041.29800502272.7096191480.55870850121.61824533811.21444846691.0138499141.25394873280.87071314220.96520343141.30342148141.51989271351.52375147611.27331762911.05471324980.8332571208
_1146.544.41.751.44.22.42.63.134.93.83.72.91.81.75.81.87.246.97.25.90.43981761690.4300528770.52002080080.39411973360.39490014670.76018099550.59842912360.41300652870.43737125770.90320638270.72043990940.57470395180.42794850740.52502941980.43405917670.47748785210.57124284720.45118435890.64371926690.76187573810.54911822750.47462096240.5995386601
_11886531647225120353534234847242313622777347765485.7835344125.18018238154.89431341963.70472549566.20557373359.23076923084.98690936295.55970327074.938062586410.23633900353.38165671777.25941833915.43610266144.345071065.54631170273.65137769296.10638905586.76776538416.88421993746.47594377366.127841094.28477257754.8776026583
_1231.410.240.640.460.930.390.630.590.580.350.750.730.330.450.210.431.030.641.41.30.760.09415056020.09773929020.07341470130.05044732590.12975290530.16832579190.09724473260.10007465890.08324162650.17461990060.05145999350.11342841150.08443308390.05974472710.10851479420.05617504140.09849014610.10778293020.09208761730.12190011810.11141529250.08569545150.0772287088
_1260.780.440.120.260.180.410.20.340.260.2500.40.40.170.300.30.220.390.220.370.660.190.05245531210.04300528770.03670735060.02049422610.0507728760.07420814480.04986909360.05400854610.03668275060.075267198600.06049515280.04626470350.03077758670.072343196100.02954704380.0551447550.0348681270.04190316560.02944547020.04350692160.0193071772
_84_927.550.761.11.310.733.321.80.191.61.21.91.20.540.912.92.12.52.81.90.70.5043780010.48869645110.23247988740.08670634140.36669299330.18099547510.18202219170.52420059410.28217500490.54192382960.02793542510.24198061130.13879411050.34398479230.28937278450.15167261190.08962603290.72690813390.18775145280.47617233630.22283058510.12524719840.0711317054
_851.90.720.470.480.430.310.220.710.710.2900.310.360.30.490.20.330.450.780.370.650.740.230.12777576030.0703722890.14377045670.03783549440.12129075930.05610859730.0548560030.11278255210.10017212680.087309950300.04688374340.04163823320.05431338830.11816055370.05617504140.03250174820.11279608970.06973625390.07047350580.05172852870.04878048780.0233718461
_86_97_1174.34.40.751.50.81.40.82.21.51.20.541.322.20.90.561.11.82.62.52.92.72.20.28917672060.4300528770.22942094150.11823592010.22565722670.25339366520.19947637450.34946706270.21163125370.36128255310.07939541860.19660924670.23132351750.39829818050.21702958840.1572901160.10833916070.45118435890.23245417970.47617233630.23078882030.17798286090.2235567885
_87_1152.71.20.760.860.670.520.380.980.980.660.390.610.940.470.710.390.5711.91.11.11.20.690.18157608040.11728714830.23247988740.06778859420.18898792730.09411764710.09475127790.15567169160.13826575240.19870540420.05734113560.09225510810.10872205320.08509097490.17121223080.10954133080.05613938330.25065797720.16987036210.2095158280.0875405870.07910349370.0701155382
_957.24.811.41.51.20.783.52.220.511.71.22.11.51142.62.52.720.80.4842028810.4691485930.30589458870.11035352540.42310730.21719457010.19448946520.55597032710.31039250540.60213758840.0749845620.25710439950.13879411050.38019371780.36171598060.28087520710.09849014611.00263190880.23245417970.47617233630.21487234990.13183915620.0812933776
_9962422050131613282714162139191912241649244660264.16952480874.10505018916.11789177453.94119733583.66692993342.89592760183.24149108594.44776261663.80936256674.21496311912.35245684713.17599552344.51080859143.43984792254.58173575443.37050248572.36376350554.0105276354.38086723294.57125442843.66078818363.95517468692.6420347732
_10123152.22.83.82.51.89.16.150.884.43.43.13.91.82.48.86.46.286.41.31.54675920321.46608935330.67296809520.22070705081.07187182670.45248868780.44882184271.44552285040.86063376511.50534397110.12938512660.66544668110.39324997980.56123834530.94046154960.50557537290.23637635052.20579019930.57219490391.1809073940.63665881450.42188529990.1321017387
_107_1086.74.20.662.16.31.312.62.60.870.492.72.91.31.60.682.51.43.41.754.21.40.45057768090.41050501890.20189042860.16553028811.777050660.23529411760.24934546810.41300652870.36682750640.2619298510.07204399090.40834228160.33541910040.23535801580.38583037930.19099514090.24622536520.35092116810.30397854270.32379718870.39791175910.27686222810.1422634109
_110_1205.52.61.21.71.410.591.92.210.451.51.30.871.80.641.31.72.11.22.62.50.620.36987720080.25412215460.36707350650.13400070940.39490014670.18099547510.14711382620.30181246330.31039250540.30106879420.06616284880.22685682310.15036028640.15750882590.43405917670.17976013260.12803718990.42611856120.18775145280.22856272140.20691411470.16479894530.0630023677
_1190.640.3600.3100.1200.230.260.15000.1400.32000.160.1600.390.4100.04304025610.035186144500.024435423500.02171945700.03653519290.03668275060.0451603191000.016192646200.0771660759000.04010527640.014304872600.03103711720.0270270270
_1130.310.200.1700000.15000000000000.270.2100.0208476240.01954785800.013400070900000.0211631254000000000000.0214872350.01384311140
_1210.570.580.210.2500.130.130.30.24000.170.2700.18000.170.380.260.40.60.140.03833272810.05668878830.06423786360.019705986700.02352941180.03241491090.04765459950.0338610006000.025710440.031228674900.0434059177000.04261185610.03397407240.0495219230.03183294070.03955174690.0142263411
_1110.420.6500.570.160.260.20.310.330.180.260.290.440.260.280.220.590.270.4700.780.810.340.02824516810.063530538600.04492964960.04513144530.04705882350.04986909360.04924308610.04655887580.0541923830.03822742380.04385898580.05089117390.04707160320.06752031640.06179254560.05810918620.06767765380.042020563300.06207423440.05339485830.0345496855
_1550.140.150000000000.23000000000000.0094150560.01466089350000000000.034784712900000000000
_15629207.8256.8111213135.1241518137.29266.725142837231.95026160411.95478580432.38597779211.97059866791.91808642671.99095022622.99214561782.06503264341.83413753211.53545085053.52868527072.2685682312.08191165752.35358015751.73623670692.52787686432.56074379761.67940844722.23513634332.66656508322.22830585092.43902439022.3371846071
_1576.74.92.161.832.83.33.21.45.73.84.93.11.82.371.963.66.885.30.45057768090.47892252210.64237863630.47294368030.507728760.54298642530.69816731080.52420059410.45148000790.42149631190.83806275180.57470395180.56674261790.56123834530.43405917670.64601297640.68943102240.47625015670.53643272240.68568816430.54115999240.52735662490.5385686269
_1679.56.92.48.72.84.13.44.34.32.35.569.13.62.92.3113.293.7109.27.80.63887880130.67440110250.73414701290.68576833640.78980029340.7420814480.84777459170.6830492590.60667626060.69245822670.80865704120.90742729241.05252200460.6517606590.69931756250.64601297641.08339160670.8021055270.80464908360.70473505770.79582351820.60646011870.792610432
_1690.40.280.110.510.160.170.160.390.2400.30.260.320.20.170.180.440.170.320.260.510.640.320.02690016010.02736700130.03364840480.04020021280.04513144530.03076923080.03989527490.06195097930.033861000600.04410856590.03932184930.03701176280.03620892550.04099447780.05055753730.04333566430.04261185610.02860974520.0495219230.04058699940.042188530.0325173511
_1285.22.11.21.51.10.680.6521.40.570.311.10.610.930.490.680.681.70.751.51.90.430.34970208070.20525250950.36707350650.11823592010.31027868670.12307692310.16207455430.31769732980.19752250350.17160921270.04410856590.15123788210.12722793460.11043722280.2242639080.13762885150.06697329930.17044742450.15198927130.14285170090.11937352770.12524719840.0436951905
_1307.161.33.61.62.51.83.82.71.81.63.14.23.71.51.32.72.25.23.25.25.24.40.4774778410.58643574130.39766296530.28376620820.45131445330.45248868780.44882184270.60362492650.38093625670.54192382960.23524568470.46883743440.48577938680.66986512180.36171598060.36513776930.26592339440.55144754980.46490835940.60950059050.41382822950.34278180620.447113577
_1335.14.314.21.21.91.72.32.51.12.82.532.41.31.541.341.95.163.20.34297704070.42027894790.30589458870.33106057620.338485840.34389140270.42388729580.36535192920.35271875620.33117567360.41167994820.37809470520.34698527630.4345071060.31348718320.42131281070.39396058420.32585537030.35762181490.36189097560.40586999430.39551746870.3251735106
_1352.41.10.471.10.760.440.371.10.970.480.240.670.730.510.720.360.680.791.70.581.41.50.470.16140096030.10751321920.14377045670.08670634140.21437436530.0796380090.09225782320.17473353140.13685487740.14451302120.03528685270.1013293810.08443308390.092332760.17362367070.10111507460.06697329930.1980198020.15198927130.1104719820.11141529250.09887936720.0477598594
_1378.15.12.76.32.232.63.43.31.75.53.65.53.42.22.25.527.13.96.596.10.54472824110.49847038010.82591538960.49659086430.62055737330.54298642530.64829821720.54008546060.46558875810.51181695020.80865704120.54445637540.63613967310.61555173350.53051677160.61792545570.54169580330.50131595440.63477872150.74282884460.51728528680.5932762030.6198620045
_138124753810832443455522757538940332870311074791122818.33904961737.330446766311.62399437158.51298624529.02628906697.9638009058.4777459178.73667656827.33655012848.12885744398.38062751798.015607749410.2938965297.24178517.95775157357.86450580016.89431022437.77039729299.56638354948.95203992237.24199401548.042188538.2309544859
_1321.200.27000000000000000000000.080700480200.08259153900000000000000000000
_1541.10.690.220.770.220.190.110.480.50.2300.190.240.240.460.20.190.310.420.190.750.670.120.07397544020.06744011020.06729680950.0606944390.06205573730.03438914030.02742800150.07624735910.07054375120.069245822700.02873519760.02775882210.04345071060.11092623410.05617504140.01871312780.07770397290.03755029060.03618909760.05968676390.04416611730.0121940066
_1360.60.3600.250.220.1100.360.310.1900.170.130.160.2300.120.31000.420.340.110.04035024010.035186144500.01970598670.06205573730.019909502300.05718551940.04373712580.057203070900.025710440.01503602860.02896714040.05546311700.01181881750.0777039729000.03342458780.02241265660.0111778394
_1293.400.5240.721.41.11.52.20.761.81.621.91.312.812.913.74.530.228651360500.15906518610.31529578690.2030915040.25339366520.2742800150.23827299730.31039250540.22881228360.26465139530.24198061130.23132351750.34398479230.31348718320.28087520710.2757724090.25065797720.25927581580.19046893450.29445470170.29663810150.3048501661
_1650.580.6900.5900.3100.250.370.180.220.220.260.320.190.20.40.110.260.180.710.670.180.03900523210.067440110200.046506128600.056108597300.03971216620.05220237590.0541923830.03234628160.03327233410.03007205730.05793428080.04581735750.05617504140.03939605840.02757237750.0232454180.03428440820.05650346980.04416611730.01829101
_14120.960.260.490.630.360.270.80.840.380.150.620.510.250.480.150.330.710.940.370.920.970.220.13450080030.09382971860.07953259310.03862373390.1777050660.0651583710.06732327640.12707893190.11851350210.11440614180.02205428290.09376748690.0589874970.04526115690.11574911380.04213128110.03250174820.17796716380.08404112650.07047350580.07321576370.06394199080.0223556789
_1472.92.70.351.40.510.730.361.51.10.910.310.70.841.30.710.40.611.11.60.891.91.60.720.19502616040.26389608360.10706310610.11035352540.1438564820.13212669680.08976436850.23827299730.15519625270.27397260270.04557885140.10586651740.09715587740.23535801580.17121223080.11235008290.06007898910.27572377490.1430487260.16951735170.15120646850.1054713250.0731640399
_14646418.7409.61913222411202128211312301335174450313.09351840644.00731089892.66128292193.15295786862.70788672013.43891402713.24149108593.49467062733.38610005933.31175673642.94057105893.17599552343.23852924513.80193717753.1348718323.37050248572.95470438183.25855370353.12919088063.23797188683.501623483.29597890573.1501183835
_1495.52.91321.50.90.62.221.20.461.51.30.91.80.650.912.32.30.92.52.50.70.36987720080.28344394163.97662965340.15764789340.42310730.16289592760.14960728090.34946706270.28217500490.36128255310.06763313440.22685682310.15036028640.16294016480.43405917670.18256888460.08962603290.57651334750.20563254360.17142204110.19895587950.16479894530.0711317054
_1517.94.70.92.31.91.41.14.13.32.20.612.42.51.81.80.951341.74.14.21.10.53127816110.4593746640.27530512990.18129507740.53593591330.25339366520.2742800150.6512795260.46558875810.66235134730.08968741730.3629709170.28915439690.32588032950.43405917670.26683144680.09849014610.75197393160.35762181490.32379718870.32628764250.27686222810.1117783943
_1533152227332069117901341466716413919211788822268325111028135023721.183876044121.698122428222.330304976925.223662948819.462935800521.176470588222.441092133221.285721093520.598775360520.171609212724.11268268321.02206560722.207057680521.182221417621.220670862623.031766985922.258773009820.804612106822.440768886920.951582796822.362640860823.071852340124.0831631253
_1584.21.61.42.31.20.850.81.71.70.870.491.11.50.81.10.640.9513.11.21.92.60.80.28245168060.15638286430.42825242420.18129507740.338485840.15384615380.19947637450.27004273030.23984875420.2619298510.07204399090.16636167030.17349263810.1448357020.26525838580.17976013260.09356563880.25065797720.27715690660.22856272140.15120646850.17139090310.0812933776
_163_16468561557153122333315343344321820511953287073614.57302720955.47340025224.58841883094.49296496284.23107300015.61085972855.48560029925.24200594094.65588758154.51603191334.99897080014.99085010815.08911738515.793428084.34059176735.61750414295.02299744914.76250156664.73848904785.33313016655.57076462724.81212920246.1986200449
_1661.70.690.490.80.280.440.570.440.380.210.850.480.620.450.240.270.930.2710.570.91.70.680.11432568020.06744011020.14988834850.06305915740.07898002930.0796380090.14212691680.06989341250.05361325090.06322444680.124974270.07259418340.07171029040.08147008240.05787455690.07583630590.09159583580.06767765380.08940545370.10856729270.07162411660.11206328280.069099371
_1893.52.60.6930.911.31.31.41.80.72.31.82.11.711.13.20.82.51.23.24.520.23537640050.25412215460.21106726620.23647184010.25668509530.23529411760.32414910860.22238813080.25395750440.2107481560.33816567180.27222818770.24288969340.30777586680.24114398710.30896272790.31516846740.20052638180.22351363430.22856272140.25466352580.29663810150.2032334441
_17043275.14310161417227.5262026171213378.931153852312.8917672062.63896083591.56006240253.38942970872.82071533342.89592760183.4908365542.70042730293.10392505432.25801595663.82274237663.02475764133.00720572763.07775866752.89372784493.65137769293.64413540432.2308559972.77156906572.85703401783.02412936913.4278180623.1501183835
_1715.83.71.35.91.62.41.62.23.31.13.52.53.22.31.61.43.81.24.11.94.46.14.60.39005232080.36163537380.39766296530.46506128560.45131445330.43438914030.3989527490.34946706270.46558875810.33117567360.51459993530.37809470520.3701176280.41640264330.38583037930.393225290.3742625550.30078957260.36656236030.36189097560.3501623480.40210942650.4674369214
_1728.56.11.58.32.23.52.53.55.51.55.144.73.52.22.46.71.86.12.57.3105.80.57162840120.59620967030.45884188310.65423875770.62055737330.63348416290.62336367040.55597032710.77598126360.45160319130.749845620.60495152830.54361026610.63365619630.53051677160.67410049710.65988397860.45118435890.54537326780.47617233630.58095116830.65919578110.5893769879
_1741.640.780.440.680.670.330.190.650.830.360.160.560.40.260.520.220.290.611.20.260.720.830.230.11029065620.07623664640.1345936190.05360028380.18898792730.05972850680.04737563890.10325163220.1171026270.10838476590.02352456850.0846932140.04626470350.04707160320.12539487330.06179254560.02856214240.15290136610.10728654450.0495219230.05729929330.05471324980.0233718461
_1751.250.760.281.40.350.480.310.620.750.260.540.550.850.430.380.280.590.331.30.3701.340.980.08406300020.07428186060.08565048480.11035352540.09872503670.08687782810.07729709510.09848617220.10581562690.07827788650.07939541860.08318083510.09831249490.07784918980.09163471510.0786450580.05810918620.08271713250.11622708990.070473505800.08833223470.0995843876
_17718133.1134.17.13.98.19.34.35.179.18.14.43.57.54134.81315141.21050720251.27061077280.9482732251.02471130731.15649328671.28506787330.97244732581.28667418551.3121137731.29459581510.749845621.05866517451.05252200461.46646148281.06103354310.9830632250.73867609551.00263190881.16227089850.91425088571.03457057360.98879367171.4226341087
_17816122.6163.87.25.27.1113.29.38.18.87.74.85.3143.8124.71721131.07600640221.17287148260.79532593071.26118314741.07187182671.30316742081.29659643441.12782552061.55196252720.96342014151.36736554241.22502684471.0178234771.39404363181.1574911381.48863859791.37886204490.95250031331.07286544480.89520399221.35289998091.38431114041.3210173866
_1810.250.2600.20000.110.1400.1300.160000.1100.26000.2400.01681260.025412215500.01576478930000.01747335310.019752250300.019113711900.01850588140000.010833916100.023245418000.01582069870
_1791.80.810.330.940.680.330.230.851.10.370.180.550.450.390.690.320.390.681.30.351.110.250.12105072030.07916882510.10094521430.07409450990.19180864270.05972850680.05734945770.13502136510.15519625270.11139545390.02646513950.08318083510.05204779140.07060740470.16638935110.08988006630.0384111570.17044742450.11622708990.06666412710.0875405870.06591957810.0254041805
_18016610730180416748619628977991644650149361135014519612411.163566423210.45810405329.176837661714.188310408711.56493286712.126696832611.9685824719.689768557513.5444002378.429926238114.261769635711.947792683110.525220046511.5868561611.092623405414.043760357314.67503176319.023687178810.10281627189.523446725811.539441013612.920237310512.6004735339
_182_187927415972139254060204539514328266722702584109706.18703681297.23270747614.58841883097.64592283145.92350220027.05882352946.23363670376.35394659518.46525014816.02137588446.61628488255.89827740055.89874969647.78491898256.75203163817.30275538586.59883978615.51447549826.25838176134.76172336296.68491755277.18523401457.1131705433
_18322135.1235.77.65.28.6124.68.98.8137.36.64.8114.7175.51523161.47950880311.27061077281.56006240251.81295077441.607807741.37556561091.29659643441.36609851791.69305002961.38491645341.30855412121.33089336221.50360286381.32162578081.59155031471.34820099431.08339160671.17809249281.51989271351.04757913981.19373527731.51615029661.6258675528
_190106.92.2112.43.73.44.35.126.64.96.74.13.339.22.37.73.99.5138.40.67250400140.67440110250.67296809520.86706341390.676971680.66968325790.84777459170.6830492590.71954626260.60213758840.97038844940.74106562210.77493378360.74228297280.79577515730.84262562140.90610934380.57651334750.68842199370.74282884460.75603234230.85695451550.8535804652
_1912.41.40.672.80.620.890.580.921.30.51.211.50.90.790.671.60.541.50.761.82.61.80.16140096030.13683500630.20494937440.22070705080.17488435070.16108597290.14462037150.14614077170.18341375320.15053439710.17643426350.15123788210.17349263810.16294016480.19050374980.18818638880.15758423370.13535530770.13410818060.14475639020.14324823330.17139090310.1829100997
_2028.76.81.28.21.72.62.63.35.21.54.945.94.42.92.67.71.762.18.9126.20.58507848120.66462717350.36707350650.64635636310.47952160670.47058823530.64829821720.52420059410.73365501280.45160319130.72043990940.60495152830.68240437660.7965963610.69931756250.73027553860.75837412470.42611856120.53643272240.39998476250.70828293120.79103493740.6300236767
_2050.940.880.2210.330.340.310.460.560.260.580.530.680.410.360.360.880.250.630.320.991.10.550.06321537610.08601057540.06729680950.07882394670.0930836060.06153846150.07729709510.07307038580.07900900140.07827788650.08527656070.08015607750.0786499960.07422829730.08681183530.10111507460.08667132850.06266449430.05632543590.0609500590.07878652830.07251153590.0558891971
_19423163.2234.45.96.67.3122.913910106.75.7214.3145.41829121.54675920321.56382864350.97886268391.81295077441.24111474671.06787330321.64568008981.15959525361.69305002960.87309950321.91137118831.36114093861.15661758751.8104462751.61566471341.60098868072.06829306731.07782930191.25167635231.02853224641.43248233271.91166776531.2194006646
_1954.81.10.914.90.791.11.521.90.952.81.92.821.81.24.113.31.54.35.93.40.32280192070.10751321920.27836407570.38623733890.22283651130.19909502260.37401820220.31769732980.26806625470.28601535450.41167994820.28735197590.32385292450.3620892550.43405917670.33705024860.40380959880.25065797720.29503799730.28570340180.34220411280.38892551090.345496855
_19924183.7223.867.59.4113.9141115110000000001.61400960341.75930722391.13180997831.73412682771.07187182671.08597285071.87009101111.49317744981.55196252721.17416829752.05839974121.66361670271.73492638131.9914909025000000000
_1970000.50.110.110.110.20.270.10.150.230.330.140.190.120.1400.370.1200.460.220000.03941197340.03102786870.01990950230.02742800150.0317697330.03809362570.03010687940.02205428290.03478471290.03816838040.02534624790.04581735750.03370502490.013788620400.03308001790.022856272100.03032300590.0223556789
_2011.81.20.371.70.360.430.380.90.890.420.480.611.20.557.77.4244.7166.12234170.12105072030.11728714830.11318099780.13400070940.1015457520.07782805430.09475127790.14296379840.12556787720.12644889360.07057370540.09225510810.13879411050.09957454511.85680870052.07847653292.36376350551.17809249281.43048725971.16186050061.750811742.24126565591.7274842748
_196_20323164233.756.48.29.23.612.39.1139.485.6194.515.29.318.729151.54675920321.56382864351.22357835491.81295077441.04366467340.90497737561.59581099611.3025590521.29800502271.08384765921.80845120121.37626472681.50360286381.70181949851.92915189661.572901161.87131277521.12796089741.35896289671.7713610911.4881899791.91166776531.5242508307
_2065.141.14.61.51.522.62.61.13.13.35.22.92.31.54.91.44.31.55.26.82.80.34297704070.39095716090.33648404760.36259015490.42310730.27149321270.49869093630.41300652870.36682750640.33117567360.45578851410.49908501080.60144114550.52502941980.55463117030.42131281070.48260171570.35092116810.38444345110.28570340180.41382822950.44825313120.2845268217
_2082.11.50.421.60.610.60.6911.10.391.31.32.31.20.850.61.90.471.80.5123.21.20.14122584030.14660893530.12847572730.12611831470.17206363530.10859728510.1720483730.15884866490.15519625270.11741682970.19113711880.19660924670.26602204510.2172535530.2049723890.16852512430.18713127750.11780924930.16092981670.09713915660.15916470360.210942650.1219400665
_2071.40.850.320.870.330.260.420.660.510.30.540.641.10.60.610.370.740.30.960.390.961.60.60.09415056020.08307839670.09788626840.06857683360.0930836060.04705882350.10472509660.10484011880.07195462630.09032063830.07939541860.09679224450.12722793460.10862677650.14709783210.10392382660.07288270810.07519739320.08582923560.07428288450.07639905770.1054713250.0609700332
_2093.62.812.41.51.21.312.11.1233.722131.31.31.13.24.31.70.24210144050.27367001260.30589458870.18917747210.42310730.21719457010.32414910860.15884866490.29628375520.33117567360.29405710590.45371364620.42794850740.3620892550.48228797410.28087520710.29547043820.32585537030.11622708990.2095158280.25466352580.28345418590.1727484275
1486.981023.13326.911268.65354.52552.5401.05629.53708.78332.15680.14661.21864.59552.35414.69356.031015.33398.951118.5525.021256.561517984.09100100100100100100100100100100100100100100100100100100100100100100100
Y-MWGeo-TOGeoPlsm-1PlsmVT-alklVT-trp-1VT-trp-2VTR
_1901666.2149.925.56.13.1661.4
_3006.400.50.70001.3
_183.9147.5626.2123.981.9204.476.975.4832.4
_172.5116.1246.445.935.774.828.426.9281.5
_241.711.6102.22.46.52.30.75.8
_271.41446.410.67.118.37.77.724.7
_323.149.6164.539.22659.326.631105.6
_162.247.6140.840.224.972.933.319.80
_231.513.63.91.51.40.80.70.40
_341.87.21.71.83.11.21.80
_292.916.69.42.71.85.93.81.90
_267.166.814928.919.665.656.380.51.8
_256.462.260.81311.424.122.633.30.7
_3114.6214.1495.5145.687159.4179.4269.65.6
_2815201.1381.9136.578.6107.8126.8203.94.3
_214.867.822.21.13.52.10.30
_20_3317.5168.2258.1114.463.9133.3163.7160.53
_2211.874.2118.359.433.455.384.495.11.9
_369.824.24.92.31.91.52.54.30
_390151.13.122.40.31.72.60
_3813.620.502.42.31.64.72.50
_3551.830.617.111.43.76.766.875.60
_3762.659.738.825.313.518.5168.1212.60.6
_548.52.50.60.6
_504.92.92.40.40.3
_534.4266.728.212.877.334.729.9
_51269.392.113.85.717.610.19.2
_453.4178.629.313.156.837.422
_461.474.314.15.627.817.214.3
_52_69222.61023.3168.961.3224.9209.2208.2
_73, _43_491.395.5676.4103.845123.5137.5135.9
_65, _751.1965.7508.91004581.1105.195.6
_441.714.2564.212346.6141.4222.3235.3
_590.85.575.541.711.232.581.7111.6
_421.19.418940.814.53768.874
_642.78306.172.231.961.3123.8134.1
_722.37.2230.346.227.1459390.9
_71, _4171.923.910.419.737.328.2
_682.7300.995.92.82.51.91.8
_401.32.569.421.68.223.556.944
_571.56.32.21.22.24.75.1
_672.21.832.55.557.12729.1
_632.5121.65.33.4515.117.8
_586.42.61.11.45.35.2
_615.47.9216.957.332.529.4156.1184.9
_74, _70918.2513.9124.266.788.2511.6475.2
_762.915.4293.8614.372.4
_808.930.8338.399.843.155.6291.4429.5
_668.9254.577.547.4276.8393.9
_554.11.29.13.82.71.718.221.9
_6014.14.962.733.716.519.9239.4233.9
_5612.78.5147.756.431.630.2290.9371.3
_7917.11.911.93.85.5
_7817.11.83.23.1
_8117.11.11.95.27.4
_7745.94.39.919.45.43.1132.5169.5
_2021.336.411.7
_20146.94.59.2
_2042.34.910.8
_1972.141.53.4
_2002.86.84.99
_198_1993.35.418.556.4
_19675.413.139.5
_2033.14.812.425.8
_1952.63.49.722.9
_1949.44.239.4143.4
_2057.76.75.97.3
_208137.996.30.61.98.5
_207178.394.52.50.78.8
_206234.278.32.11255.7
_209693.24224.53.418.6
ng/g-lipidStructurering-1ring-2
#190.0465517241
#300.0581896552
#180.3336206897
#170.2017241379
#16, #320.3413793103
#260.124137931
#280.19784482762,4',4-424
#311.0241379312,4',5-425
#220.1396551724
#350.0465517241
#370.0892241379
TrCB2.7
#530.0533216235
#510.0263471551
#450.1417727872
#73, #520.4755034189
#43, #490.3130292955
#47, #48, #750.6291951571
#440.3600777868
#59, #420.1486732325
#41, #64, #680.3745059908
#400.0677498275
#630.0784141522
#743.85734897432,4,4',5-4245
#70, #760.2659808042
#80, #661.9553352989
#56, #600.7508939213
#790.3883068816
#810.0815507183
#770.0319929741
TeCB10
#102, #98, #93, #95, #121, #880.3553240741
#920.3333333333
#84, #101, #90, #891.1851851852
#996.11805555562,2',4,4',5-24245
#97, #86, #125, #111, #87, #117, #116, #1150.5555555556
#120, #850.3310185185
#1100.400462963
#124, #107, #1090.6631944444
#1189.64351851852,3',4,4',5-34245
#114, #1220.5474537037
#105, #1271.7662037037
#1260.1006944444
PeCB22
#1510.6407624633
#135, #1440.2668621701
#1470.1730205279
#139, #149, #1400.4780058651
#143, #134, #133, #1310.5747800587
#142, #165, #146, #1614.1158357771
#15329.88563049852,2',4,4',5,5'-245245
#141, #1370.6818181818
#1300.6099706745
#13817.71700879772,2',3,4,4',5'-234245
#166, #1590.9882697947
#1620.3431085044
#128, #1671.4105571848
#1562.5527859238
#1570.5469208211
#1690.0146627566
HxCB61
#1790.2823889405
#186, #1781.7649308781
#1879.34167531832,2',3,4',5,5',6-2356245
#1832.3982296049
#1850.116277799
#174, #1810.564777881
#1771.7919239386
#1710.5938473307
#173, #192, #1721.0174307415
#18013.66887055352,2',3,4,4',5,5'-2345245
#193, #1910.905305721
#1705.11207037872,2',3,3',4,4',5-2345234
#1890.4422709142
HpCB38
#2020.5056674338
#2010.1099539701
#2040
#1970.0277905639
#2000.0181242808
#1980.0652474108
#1991.27232451092,2',3,3',4,5,5',6'-23452356
#196, #2031.11403912542,2',3,3',4,4',5',6-23452346
#1950.2543440736
#1940.8004890679
#2050.0320195627
OcCB4.2
#2080.0846428571
#2070.0664285714
#2060.14892857142,2',3,3',4,4',5,5',6-234562345
NoCB0.3
#2090.1
198219851986198719881992199319941995199619971998199920002001
18_1735.273358455751.011673274736.32386741611.78306860330.383363545610.54088424136.20637004498.978390570511.196043053811.70384529317.91126995365.92006824252.640150813750.8819286853.9234657556
31_2887.698293275273.070568976776.749610326134.662151285661.687985970335.994336741318.241597536627.47620441235.643555342424.079688918933.571665578133.084999451414.250569333474.341222528117.627689696
5286.6059563124106.631378212679.042468353339.295105974364.199947856528.527087543118.911456697525.8844012129.980653073520.839554109735.748812805845.545800818315.685781920546.704001903416.0429980157
4966.8471193417113.747279483770.275254047728.779785231341.199585977427.260529586212.738072745530.184519541423.314379318219.78828391739.852616505649.49769352112.006271632642.669988518515.8951139955
47_4852.528423856972.551450583947.01210473717.911244999625.496651508118.69792086849.188658039222.627067167616.750693060413.006998040126.577262587534.1037572978.401747193224.057261630710.6208657281
4448.317501921958.446640841642.746940912719.178999204929.787377777115.78396548889.454540300712.778910614213.233093100511.282428096515.443239310917.86683144357.897861773912.65771591446.9301351442
41_6453.902291282760.233278697242.548737468728.627204373428.959815267315.16271680869.35907117112.842230195317.707936364411.8882047817.551934504520.5286214969.27706890818.45980074639.2415971244
7457.490795530668.35435165548.163585900232.75274739334.161865771618.26454894610.873765481718.617492743519.062944764112.439443912827.109237566934.139818892711.305454770319.74828334211.8258659427
7080.00173148264.671966188260.288265855637.425737031649.099041615422.612547690613.460349534420.393060304824.444382318215.938427999930.033504341131.82206853713.70850767419.362699354612.2650423654
6696.896025867141.161492956775.289677868540.601354787950.642069971335.760300165917.406275076927.704407478730.45531620923.418524307452.292581357662.021394837818.073654563632.184562355122.2702794618
60_5644.188205328347.975592204129.868509976520.215825601624.961372385412.61940670367.56420415019.30003685814.66783598528.684687836116.890397651215.8128607528.173948727814.3107559297.8825999447
9581.1898141643105.416437080471.392545568543.447111499851.729393779230.546109667419.561010865525.825375645120.286935196919.599420489536.806880000541.474866789520.554548692719.517532004417.280885061
90_101158.5101892379239.4757139963168.936032509694.6942505853118.138004280364.451891858946.046881262573.845656510463.968042938751.1230589042105.2869514801106.311717448251.016100889851.280069036349.3601186706
9997.6871890622184.7764077691120.225627937966.693364708577.935043971850.427388597930.178966377373.098054124650.028428136342.035249889694.0612855968106.176457137936.588350338340.673857560444.2406531739
9728.426838054843.343222350627.66148933617.301897982822.149438956911.11015327757.879975442310.6192946199.08360774238.064689283715.211551665115.66891645647.6027333597.79257887487.8523007874
8753.55437161967.135303493150.444505514335.326787725543.488624665820.051677205515.306598619418.668350864116.935940786614.012887484624.73655086824.74021463215.57897658716.117454938613.6167867167
8525.234269542639.867788840125.99016021116.691429256720.05257039710.15505757887.218201528211.40730344119.84121179697.895368506215.175747397215.39272821227.979035238.92411174028.3431983388
110106.3890892576135.301229829899.477341839368.153960590576.148992499939.368711927328.795941634334.586507783234.536719046328.134718651353.217683360550.849133949728.995187250429.662882152128.2018316805
118149.71933967228.9042427392156.8716975056110.9127587537127.066344586366.319073150443.068000720174.952573927962.514837726651.867762121101.4179133087100.695715704851.266285538256.736570086256.1907559555
10548.109111362569.068851916446.438008350834.198799567639.089068034919.408631641313.162237308719.593703878618.306720377614.318375536125.526779649626.356969907614.739111277817.222205828717.4413326774
15144.48740113390.397303693649.89901618829.574425204834.786485639621.049295787611.194596679828.681865798724.861595419415.349022631336.864198559844.887749985716.952961391516.608156444216.2346073064
149132.8993018479231.4071114183152.792864479499.768421718699.886499104266.237490313938.955179440880.997398958270.518415506248.2966762988101.9686745416128.065844495554.875723423749.91685134454.7337602443
14635.943780605681.132292266147.017173474428.086286536929.796137127821.950327524712.049091268534.937692675427.145638357718.984262639444.437294392459.311591619919.811747739520.92661947221.1241681162
153263.1700790084444.1623450553313.9694477118198.8309019479215.2377332667140.686964895384.9465180345212.799208736177.8355067539122.9660483324269.5898704047351.3480654674130.3053099953135.4678934606137.037746695
132_16826.142809955833.747836406526.340515453819.064787756619.026658191310.43402678466.26127328269.97045911898.99118902837.071960053213.461284282213.4508917847.00375140567.73502652076.8490880404
138237.4564946731390.6038045655267.0538552447191.1866791885200.2973416697112.355544895575.1115394889141.2980829655129.018534504295.3137203376183.9231888756199.6430864461103.5034745505109.8129594232102.7357746498
128_16733.608421682350.727021868337.724887347428.990126100529.608847272616.044270821210.399301120918.903229984716.179099790212.673374799925.082951418725.01830512313.396664321515.580109965913.6362075097
18765.4859658407167.509759815681.231826205749.718777555949.932107356137.941818367219.230192512365.050928151661.376961897836.980138693977.3679607062129.68515751443.202470043937.550451998139.8901958292
18081.0148274028142.067468339182.460726440257.328350951663.32770360634.649590381521.956551049349.634300623764.639524095132.744813979272.637032075886.562650522144.6499961934.898617249733.3877266178
170_19034.623398584562.416678019138.178385981326.095250553628.713854726915.78952728699.819079517921.586745513427.027701759314.35517949630.951178640437.03879362520.032698664316.353064486315.0644067832
cement
UTSDCl
_1680250111201
_2930180009.115001
_339015005.93701
_10_430150.416.32
_9_7351300.51342
_627700.28272
_8_5481500.56172
_14172300.17252
_11442000.61282
_12_13426100.44562
_152.1210.0533.22
_19181.30.0592.13
_300.930.0140.333
_1857120.34133
_17256.90.114.53
_276.23.30.0231.23
_241.74.60.0180.693
_16_32369.40.168.83
_342.55.80.011.43
_232.5290.0161.53
_292.4280.0161.83
_2658.70.0394.53
_253120.0222.93
_3116120.12143
_28136.70.139.13
_33_20_2111580.12103
_224.690.0473.53
_361.5190.0111.43
_3907.70.0091.63
_381.2620.0123.23
_353.2610.0382.73
_371.1150.0291.43
_540.180.05400.114
_500.180.200.154
_533.60.910.0195.64
_511.50.440.011.94
_453.50.960.01554
_461.40.390.0071.64
_690.190.3700.224
_730.0750.4200.14
_529.24.90.065374
_430.490.720.0030.954
_497.83.60.048254
_47_48_755.93.90.055154
_650.111.1004
_620.11.700.0494
_447.53.40.056274
_590.781.10.0071.94
_422.11.40.0165.84
_71_720.320.5600.624
_41_682.42.60.0219.14
_643.84.60.043144
_400.850.630.0092.34
_570.111.50.0020.254
_670.262.20.0030.594
_580.0442050476100.124
_630.171.10.0020.754
_610.233.10.00724
_74120.0163.24
_760.45612050671.10.00914
_701.73.90.038.74
_66_801.54.60.038104
_550.09192487851.100.164
_560.844.50.0194.14
_600.370.740.0121.94
_790.05782901032.200.084
_780.01975921381.200.124
_810.0090.530.0010.0324
_770.0582.50.0050.144
_1040.0080.04005
_960.0760.1100.525
_1030.036000.185
_1000.0090.1100.15
_940.0070.06200.225
_102_980.120.2401.15
_95_93_1211.72.20.017145
_880.0210.0900.115
_910.280.3302.55
_920.170.33025
_840.290.390.0142.85
_900.0750.240.0050.385
_1011.22.10.025135
_89_1130.030.160.0060.385
_990.451.10.0116.25
_1190.0290.3500.255
_1120.0080.140.0060.0375
_83_1080.0650.350.0150.535
_970.260.530.0062.45
_86_1250.0350.2200.195
_111_1170.010.2500.135
_1160.0180.1200.0875
_87_1150.380.870.00883.85
_85_1200.110.4201.45
_1100.481.40.0145.35
_820.0590.1900.565
_1240.0080.1400.165
_107_1090.0230.6400.285
_1230.0110.1500.0925
_118_1060.111.10.0121.75
_114_12200.1900.065
_105_1270.0380.50.0060.495
_12600.20.00205
_1550.0010.0190.00220.0156
_1500.0080.036006
_1520.0040.01900.0186
_145_1480.0060.06600.0136
_136_1540.20.2600.726
_1510.140.250.00260.986
_1350.0650.1300.396
_1440.030.06400.196
_1470.0120.04900.0616
_149_1390.450.850.0082.86
_1400.0040.02200.0126
_134_133_1430.0280.07300.146
_131_1650.0090.04900.0366
_146_161_1420.0450.210.0030.326
_153_1680.20.550.0161.76
_1320.10.190.0050.426
_1410.0370.100.36
_1370.0120.05100.076
_1300.0110.0450.0010.0696
_164_1630.0510.190.0040.326
_1380.180.470.01416
_158_1600.0140.130.0020.0966
_1290.010.03500.0366
_16600.0200.0356
_15900.022006
_16200.042006
_128_1670.0220.110.0030.0996
_1560.0020.080.0020.0246
_15700.0300.0076
_16900.008006
_18800.007007
_18400.016007
_1790.0560.09700.437
_1760.0170.03600.147
_178_1860.0120.04500.137
_17500.01300.0277
_187_1820.0510.140.0040.587
_1830.0230.0760.00090.297
_1850.0040.01300.0457
_174_1810.0320.0650.0020.317
_17700.03400.147
_1710.0080.0290.00120.0737
_1730000.0047
_172_19200.01600.0377
_180_1930.0370.110.0070.417
_19100.01300.0097
_1700.0130.050.0040.127
_19000007
_18900.007007
_20200.00800.0358
_20100.0100.028
_20400008
_19700.00700.018
_20000.00700.0168
_19800008
_1990.0080.01700.0688
_196_2030.0080.02100.0818
_19500008
_19400.0080.0010.0288
_20500.005008
_20800.00700.0079
_20700.00800.0059
_2060.0040.01400.0149
_2090.0090.02300.01310
10-12
IUPAC10-198210-198510-198610-198710-198810-199210-199310-199410-199510-199610-199710-199810-199910-200010-200111-198211-198511-198611-198711-198811-199211-199311-199411-199511-199611-199711-199811-199911-200011-200112-198212-198512-198612-198712-198812-199212-199312-199412-199512-199612-199712-199812-199912-200012-200110-12_198210-12_198510-12_198610-12_198710-12_198810-12_199210-12_199310-12_199410-12_199510-12_199610-12_199710-12_199810-12_199910-12_200010-12_2001
190.631.931.130.390.860.150.000.100.220.320.000.000.002.950.190.000.000.000.070.000.000.000.000.000.000.000.000.000.000.000.070.040.030.000.030.000.020.000.000.000.000.000.000.000.000.711.961.170.460.890.150.020.100.220.320.000.000.002.950.19
18_1732.7849.6533.1511.2428.699.764.918.458.1210.847.355.511.7250.493.652.151.302.880.541.460.781.300.533.080.860.360.410.410.390.160.340.060.290.000.240.000.000.000.000.000.200.000.520.000.1135.2751.0136.3211.7830.3810.546.218.9811.2011.707.915.922.6450.883.92
24_271.833.252.390.731.740.650.270.540.630.710.310.210.002.970.160.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.020.030.000.000.000.000.000.000.000.000.030.000.060.000.001.853.282.390.731.740.650.270.540.630.710.340.210.062.970.16
16_3212.4820.3213.256.069.283.811.163.353.253.731.380.000.0013.620.130.980.611.450.210.720.420.470.361.740.420.140.150.210.160.170.000.000.000.000.000.000.000.000.000.000.000.000.000.000.0013.4620.9314.706.2710.004.221.633.715.004.151.520.150.2113.780.30
269.6510.439.263.088.823.301.572.622.493.023.083.660.8421.142.030.400.190.610.100.300.180.140.161.040.220.000.120.000.000.110.060.000.080.000.030.000.000.000.000.000.090.000.190.050.1110.1110.619.953.189.143.481.712.783.533.243.173.781.0321.192.24
254.645.673.761.303.761.510.690.980.911.141.701.530.6211.211.020.260.000.360.000.100.100.060.100.520.000.000.000.000.000.100.080.000.090.000.070.080.000.080.060.000.080.120.000.000.004.995.674.211.303.931.680.751.161.491.141.781.650.6211.211.12
31_2879.5968.4168.1032.3255.0431.9215.8224.2420.9321.5124.2330.508.9371.7814.437.754.667.942.346.654.072.433.2414.712.577.641.773.301.802.020.360.000.710.000.000.000.000.000.000.001.700.812.020.761.1887.7073.0776.7534.6661.6935.9918.2427.4835.6424.0833.5733.0814.2574.3417.63
3313.6014.8212.265.059.664.682.822.923.933.833.271.211.385.022.311.890.652.500.271.620.750.600.874.300.760.270.250.280.350.270.150.000.260.000.030.000.000.000.000.000.580.000.690.180.4415.6315.4715.025.3211.325.433.413.798.234.594.121.472.365.543.02
229.658.596.165.037.093.382.411.862.932.542.131.680.355.341.320.860.371.260.170.920.440.280.392.390.480.130.220.000.150.140.000.000.030.000.000.000.000.000.000.000.540.120.840.300.4210.518.967.445.208.013.822.692.255.323.012.802.021.195.781.88
372.943.482.042.352.150.650.230.450.220.240.490.380.000.640.001.010.321.070.150.720.500.230.402.890.470.760.220.350.180.110.090.040.250.070.030.000.000.000.000.000.180.000.340.210.264.043.843.362.572.911.150.460.843.110.711.430.600.691.040.37
540.000.150.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.150.000.000.000.000.000.000.000.000.000.000.000.000.00
501.281.491.190.190.680.690.240.820.000.240.160.090.000.140.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.281.491.190.190.680.690.240.820.000.240.160.090.000.140.00
534.318.345.312.273.331.980.862.051.391.431.712.000.823.061.170.000.000.190.080.070.000.080.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.004.318.345.502.353.401.980.942.051.391.431.712.000.823.061.17
512.946.353.842.041.651.330.472.171.051.211.401.720.792.221.320.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.030.000.000.000.000.000.000.000.000.000.000.000.000.000.002.976.353.842.041.651.330.472.171.051.211.401.720.792.221.32
453.935.073.561.732.621.060.650.890.730.820.860.970.521.070.510.170.000.140.000.000.000.000.000.000.000.000.000.000.000.000.040.000.000.000.000.000.030.000.000.000.000.000.000.000.004.145.073.701.732.621.060.680.890.730.820.860.970.521.070.51
69_460.101.030.180.320.310.090.030.120.150.150.000.150.140.210.140.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.101.030.180.320.310.090.030.120.150.150.000.150.140.210.14
5282.06104.5674.2435.5762.6227.7918.1225.0426.5419.7135.2644.7115.0646.2116.044.342.044.633.701.480.730.730.823.341.130.480.830.630.490.000.200.030.170.030.110.000.060.030.100.000.000.000.000.000.0086.61106.6379.0439.3064.2028.5318.9125.8829.9820.8435.7545.5515.6946.7016.04
4964.65112.9868.7327.7240.3326.8712.3129.7320.9819.1239.5148.7711.7442.2915.622.040.731.451.010.790.350.360.422.250.670.320.730.240.380.280.160.030.090.040.070.050.070.040.090.000.030.000.030.000.0066.85113.7570.2828.7841.2027.2612.7430.1823.3119.7939.8549.5012.0142.6715.90
47_4848.7670.2845.1516.2323.5817.828.2521.6614.3212.2025.3033.347.4923.039.583.262.031.621.451.700.690.790.802.280.741.180.690.810.890.970.510.240.250.230.210.200.140.170.160.070.100.080.100.140.0752.5372.5547.0117.9125.5018.709.1922.6316.7513.0126.5834.108.4024.0610.62
4445.8357.6841.1518.3128.9715.368.9812.0710.8010.3214.9817.467.2612.386.932.260.691.430.800.720.360.380.652.320.960.410.410.600.280.000.230.080.170.070.100.070.090.060.110.000.060.000.040.000.0048.3258.4542.7519.1829.7915.789.4512.7813.2311.2815.4417.877.9012.666.93
59_4217.9124.2915.917.689.915.253.114.603.933.506.218.002.925.432.600.500.000.420.090.150.000.000.190.800.000.000.000.000.000.000.090.030.060.040.050.040.040.040.050.000.050.050.030.000.0318.5024.3216.397.8110.115.293.164.834.783.506.268.052.955.432.63
72_711.852.672.150.921.240.880.401.030.680.651.471.580.400.850.510.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.852.672.150.921.240.880.401.030.680.651.471.580.400.850.51
41_6451.1959.1840.9227.9427.8114.568.7312.1614.6410.9116.9019.958.7117.978.742.450.991.470.651.050.510.550.622.930.970.510.490.460.410.440.260.070.150.040.100.090.080.070.140.000.140.080.110.070.0653.9060.2342.5528.6328.9615.169.3612.8417.7111.8917.5520.539.2818.469.24
406.338.015.492.203.141.720.781.431.010.941.631.650.551.110.610.170.000.270.000.000.000.000.000.000.000.000.000.000.000.000.030.000.020.000.000.000.000.000.000.000.000.000.000.000.006.548.015.782.203.141.720.781.431.010.941.631.650.551.110.61
634.598.445.041.833.011.881.002.291.701.282.193.791.081.551.030.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.004.598.445.041.833.011.881.002.291.701.282.193.791.081.551.03
7449.8362.8444.0528.8129.8616.399.2616.7215.3510.9824.2532.869.5417.9210.116.124.403.212.903.451.331.251.403.321.282.531.061.481.421.561.541.120.911.050.850.540.370.500.390.190.330.220.280.410.1657.4968.3548.1632.7534.1618.2610.8718.6219.0612.4427.1134.1411.3119.7511.83
7076.6063.2558.4536.6447.7621.7612.9419.4520.2815.0029.5031.1113.1218.9511.753.111.301.630.681.210.770.470.833.940.930.420.710.500.340.480.290.120.210.110.130.090.050.110.220.000.110.000.080.080.0480.0064.6760.2937.4349.1022.6113.4620.3924.4415.9430.0331.8213.7119.3612.27
6687.72134.8170.8937.3345.5433.6415.6325.7625.1521.8448.1460.4016.1730.0019.948.525.933.982.924.721.871.601.705.011.533.951.481.741.982.240.660.420.410.350.380.250.170.240.290.050.210.140.160.200.0996.90141.1675.2940.6050.6435.7617.4127.7030.4623.4252.2962.0218.0732.1822.27
60_5640.9445.6827.9419.3423.0911.696.958.3711.457.6715.3115.287.4713.697.222.942.151.750.791.730.840.560.823.050.971.440.430.610.530.580.310.140.170.090.130.090.060.100.170.040.140.110.100.090.0944.1947.9829.8720.2224.9612.627.569.3014.678.6816.8915.818.1714.317.88
811.692.041.501.271.430.600.460.520.270.390.780.730.420.610.330.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.692.041.501.271.430.600.460.520.270.390.780.730.420.610.33
772.785.353.112.022.081.650.802.261.731.413.194.691.331.341.700.520.480.310.280.380.210.240.280.520.270.580.180.000.280.370.020.000.000.000.000.000.000.000.000.000.000.000.000.000.003.325.833.422.302.451.871.042.542.251.683.764.871.331.622.07
674.352.712.591.841.842.021.090.941.250.941.911.901.652.281.870.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.004.352.712.591.841.842.021.090.941.250.941.911.901.652.281.87
1040.000.100.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.100.000.000.000.000.000.000.000.000.000.000.000.000.00
1031.414.342.330.711.021.040.241.690.850.712.142.850.580.840.880.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.414.342.330.711.021.040.241.690.850.712.142.850.580.840.88
1001.132.741.810.570.830.960.291.680.820.752.062.770.630.931.140.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.132.741.810.570.830.960.291.680.820.752.062.770.630.931.14
931.416.322.671.060.981.100.5419.9114.261.101.361.800.830.891.110.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.416.322.671.060.981.100.5419.9114.261.101.361.800.830.891.11
9577.53101.9666.3540.2050.6430.0519.0425.2118.7218.9835.9640.8719.8318.9216.883.533.424.973.251.050.470.480.621.490.620.850.610.730.580.400.130.040.070.000.040.030.030.000.080.000.000.000.000.020.0081.19105.4271.3943.4551.7330.5519.5625.8320.2919.6036.8141.4720.5519.5217.28
9213.1824.7215.508.939.106.333.707.425.274.409.6511.454.094.124.820.420.190.390.320.000.000.000.000.160.110.110.200.140.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.0013.6024.9115.899.259.106.333.707.425.424.519.7711.644.234.124.82
8421.1734.1623.4012.7517.829.175.7410.478.726.9715.3315.576.417.056.421.151.411.291.110.640.230.360.130.370.210.440.270.440.360.300.040.000.000.000.000.000.000.000.000.000.000.000.000.000.0022.3635.5724.6913.8618.479.406.1110.619.107.1915.7615.846.857.406.72
(90_)101153.37235.80163.2089.04116.4863.5945.0272.9461.5949.95104.30104.6549.6950.2048.784.833.505.565.521.540.760.970.832.211.150.941.671.271.030.580.310.170.170.130.120.100.060.070.170.030.050.000.050.040.00158.51239.48168.9494.69118.1464.4546.0573.8563.9751.12105.29106.3151.0251.2849.36
9982.09172.41111.7157.1668.5947.2726.0570.1345.5239.3190.18103.3031.6235.8738.7612.9110.356.997.567.572.263.492.253.922.293.402.524.604.225.202.692.021.521.971.780.900.640.720.590.430.480.350.370.590.2897.69184.78120.2366.6977.9450.4330.1873.1050.0342.0494.06106.1836.5940.6744.24
1193.538.065.211.932.722.081.093.242.772.455.205.041.671.761.740.290.280.000.180.000.000.000.000.170.070.150.140.200.450.140.070.050.040.050.040.000.000.000.000.000.000.000.000.000.003.908.405.252.162.772.081.093.242.942.525.355.181.872.221.88
109_834.448.554.982.643.172.041.202.281.581.293.013.121.141.221.200.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.004.448.554.982.643.172.041.202.281.581.293.013.121.141.221.20
9727.7743.1026.9816.7322.1511.117.8810.628.757.8515.0615.467.497.797.850.620.240.680.570.000.000.000.000.330.210.160.200.120.000.000.030.000.000.000.000.000.000.000.000.000.000.000.000.000.0028.4343.3427.6617.3022.1511.117.8810.629.088.0615.2115.677.607.797.85
8750.5164.8848.4032.8442.1819.3614.5918.1515.6413.3024.1924.2214.8815.4513.062.722.041.882.331.150.590.670.451.200.670.500.520.650.620.560.330.210.170.150.160.100.050.080.100.040.050.000.050.050.0053.5567.1450.4435.3343.4920.0515.3118.6716.9414.0124.7424.7415.5816.1213.62
8521.7037.0123.9114.3618.159.386.3610.808.837.2414.2414.857.077.947.322.752.261.651.771.420.530.690.410.860.550.800.450.800.820.960.790.600.430.570.470.250.170.200.150.100.130.090.100.170.0625.2339.8725.9916.6920.0510.167.2211.419.847.9015.1815.397.988.928.34
110102.74131.6096.2965.6174.4038.5728.0133.8632.7227.1652.2450.1328.2728.7627.713.463.623.082.491.680.730.740.671.680.970.980.720.690.900.500.190.080.100.050.070.070.040.050.130.000.000.000.030.000.00106.39135.3099.4868.1576.1539.3728.8034.5934.5428.1353.2250.8529.0029.6628.20
828.4212.807.584.556.093.111.862.962.641.953.904.322.172.262.050.230.250.000.000.000.000.000.000.150.000.000.080.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.008.6413.057.584.556.093.111.862.962.791.953.904.402.172.262.05
1245.466.094.953.604.362.201.291.981.991.553.022.861.541.481.220.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.005.466.094.953.604.362.201.291.981.991.553.022.861.541.481.22
10713.8330.6318.749.3411.478.794.6112.397.826.9214.3216.875.516.906.611.120.940.430.410.620.180.320.130.250.000.310.260.350.370.500.060.000.000.000.000.000.000.000.000.000.000.000.000.000.0015.0131.5619.179.7512.098.984.9312.528.076.9214.6417.135.877.287.11
1231.443.990.981.171.111.050.001.091.120.731.821.960.890.700.800.360.260.280.200.220.000.000.120.110.000.110.000.120.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.804.251.261.371.331.050.001.211.230.731.941.961.010.700.80
118123.25205.62139.0895.11108.7959.9236.4069.4454.8247.1793.8297.0444.3648.6847.3820.0217.9913.8311.2614.014.185.133.726.373.766.292.865.996.548.216.445.303.974.554.272.221.541.791.320.931.310.790.921.520.60149.72228.90156.87110.91127.0766.3243.0774.9562.5151.87101.42100.7051.2756.7456.19
1142.743.592.722.172.281.140.731.231.200.771.651.690.950.970.850.450.340.320.000.290.140.130.090.000.140.170.000.140.150.130.150.100.070.090.080.050.000.030.000.000.020.000.000.000.003.344.033.112.262.641.320.861.341.200.911.841.691.091.120.98
10540.9962.4941.3930.1834.0517.5511.3218.2716.2613.1623.2825.4613.0714.9514.995.665.354.223.074.161.351.510.911.750.961.940.731.481.882.341.451.230.830.950.880.510.340.410.290.200.310.170.200.390.1148.1169.0746.4434.2039.0919.4113.1619.5918.3114.3225.5326.3614.7417.2217.44
1261.745.032.031.331.561.170.581.791.721.082.263.411.361.021.030.310.390.370.180.180.090.130.140.110.000.120.090.160.160.120.000.000.000.000.000.000.000.000.000.000.000.000.000.000.002.055.432.401.521.731.260.711.931.831.082.383.501.521.181.15
1553.461.212.501.031.772.130.712.461.641.994.525.291.704.903.340.150.100.000.000.000.000.110.000.150.000.100.080.130.210.220.020.000.000.000.000.000.000.000.000.000.000.000.000.000.003.631.312.501.031.772.130.822.461.801.994.625.371.835.113.56
13613.8822.8916.928.9110.746.873.009.165.944.439.9013.114.404.395.310.290.340.890.490.120.060.000.000.120.000.100.170.080.080.070.000.000.000.000.000.000.000.000.000.000.000.000.000.000.0014.1623.2417.819.4110.866.933.009.166.064.4310.0013.284.484.475.38
1543.1910.966.202.552.703.351.136.604.203.248.2113.062.823.084.360.320.240.220.200.170.080.130.000.140.070.130.190.220.220.200.030.000.000.000.000.000.000.000.000.000.000.000.000.000.003.5411.206.422.752.873.441.266.604.333.318.3413.263.043.294.56
15142.3685.2045.8626.9833.5720.4710.0627.4323.1315.0035.6144.0215.8615.5915.492.105.204.042.601.220.581.131.251.730.351.260.871.091.010.740.030.000.000.000.000.000.000.000.000.000.000.000.000.000.0044.4990.4049.9029.5734.7921.0511.1928.6824.8615.3536.8644.8916.9516.6116.23
13223.0033.8923.0816.2118.3911.486.6511.6311.049.2316.6018.7011.349.719.800.561.921.621.040.400.210.390.300.360.120.500.280.380.370.220.020.000.000.000.000.000.000.000.000.000.000.000.000.000.0023.5835.8124.7017.2518.7911.697.0411.9311.409.3517.1018.9911.7210.0910.03
1473.188.985.522.632.622.891.085.242.892.115.449.031.822.192.870.200.000.180.230.140.060.080.000.080.000.090.110.110.170.120.000.000.000.000.000.000.000.000.000.000.000.000.000.000.003.378.985.702.862.762.951.165.242.972.115.539.141.932.362.99
149127.35220.64142.2092.8196.6065.0036.7379.1867.6147.5199.17126.0352.7747.3452.835.3010.6210.486.833.141.182.191.772.820.752.772.042.072.541.900.250.150.120.130.140.060.040.050.090.030.030.000.040.040.00132.90231.41152.7999.7799.8966.2438.9681.0070.5248.30101.97128.0754.8849.9254.73
134_7.6214.969.626.016.704.442.375.914.293.217.308.633.123.303.280.320.430.280.360.380.070.150.000.000.000.000.000.120.150.170.030.000.000.000.000.000.000.000.000.000.000.000.000.000.007.9715.409.906.377.084.502.525.914.293.217.308.633.243.453.45
14631.0575.8842.6424.3726.7620.9510.3333.8725.7218.2643.0358.1717.7418.6919.254.745.154.293.622.940.961.701.041.390.721.401.142.052.211.880.160.100.090.100.100.040.030.020.030.000.000.000.020.020.0035.9481.1347.0228.0929.8021.9512.0534.9427.1518.9844.4459.3119.8120.9321.12
153215.52393.20276.39167.52182.99130.2868.60200.81160.55114.67255.10341.96111.91115.63117.9940.7245.8233.0926.2026.928.1714.6810.2215.497.2813.228.5117.4018.4118.386.935.144.495.115.332.241.661.771.791.021.270.880.991.430.67263.17444.16313.97198.83215.24140.6984.95212.80177.84122.97269.59351.35130.31135.47137.04
(132_)16825.1931.8324.4317.7018.4410.205.919.608.576.8713.0313.156.597.316.700.951.921.911.370.580.230.350.370.420.200.430.300.420.430.150.000.000.000.000.000.000.000.000.000.000.000.000.000.000.0026.1433.7526.3419.0619.0310.436.269.978.997.0713.4613.457.007.746.85
14118.9727.2318.2212.9314.957.524.488.258.986.0412.1112.156.736.285.890.911.280.890.740.510.240.290.270.390.090.380.210.160.230.220.030.000.000.000.000.000.000.000.000.000.000.000.000.000.0019.9128.5119.1113.6715.467.764.778.529.376.1312.4912.366.896.506.11
1305.687.366.375.345.552.581.672.982.932.164.393.952.362.272.111.271.030.830.800.780.270.380.260.400.220.340.170.540.410.420.290.230.150.200.210.090.060.060.040.030.040.000.030.040.007.238.627.366.346.552.942.113.303.372.404.764.122.932.732.54
1377.1412.718.816.476.184.152.395.373.993.196.407.253.063.383.230.771.161.070.830.580.200.310.170.300.060.210.170.340.290.310.070.050.030.040.040.000.000.000.000.000.000.000.000.000.007.9813.929.927.336.804.352.715.544.293.256.607.423.403.673.54
138194.94341.15228.04161.31169.63101.7860.93130.55112.9587.15170.57192.3688.1592.8686.0435.6644.1334.5424.8125.528.3612.669.0414.427.1912.136.5614.3715.5016.066.865.334.475.065.142.211.521.701.650.971.230.720.981.450.63237.46390.60267.05191.19200.30112.3675.11141.30129.0295.31183.92199.64103.50109.81102.74
1587.9210.378.207.306.703.5445.943.994.043.127.035.333.463.373.222.403.262.461.321.530.520.690.680.800.630.770.340.710.780.810.720.570.420.530.520.210.130.140.150.070.110.040.070.120.0511.0514.2011.099.158.754.2746.764.815.003.837.915.724.244.284.08
1293.675.453.632.943.411.670.901.861.711.282.622.791.301.381.310.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.003.675.453.632.943.411.670.901.861.711.282.622.791.301.381.31
128_16727.7144.2132.7425.1025.2414.458.4317.5214.2911.6623.2724.1811.7013.4911.794.815.624.343.143.581.261.731.131.670.881.620.741.561.861.761.100.900.650.750.790.330.240.250.220.130.190.100.140.230.0833.6150.7337.7228.9929.6116.0410.4018.9016.1812.6725.0825.0213.4015.5813.64
15611.8217.9113.4811.0110.925.883.497.036.444.869.939.815.115.445.252.413.102.281.551.770.720.810.530.890.470.820.370.751.110.840.680.570.420.430.430.220.140.160.140.070.140.060.080.130.0414.9121.5816.1813.0013.126.824.447.727.475.4010.8910.245.946.686.13
1572.464.143.012.342.281.400.751.751.611.182.502.811.371.311.180.540.490.470.380.350.140.230.000.250.100.170.120.290.290.150.080.070.050.060.070.030.000.000.000.000.000.000.000.000.003.084.703.532.792.701.570.981.751.861.292.672.931.661.591.33
1690.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.00
1880.120.610.270.110.150.170.040.290.200.160.380.850.150.170.190.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.120.610.270.110.150.170.040.290.200.160.380.850.150.170.19
1840.691.031.000.630.680.700.250.660.610.712.501.631.765.942.180.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.691.031.000.630.680.700.250.660.610.712.501.631.765.942.18
17914.2029.3316.7710.3911.418.193.1512.6410.107.0514.3320.767.045.937.220.000.491.370.670.100.080.000.190.190.000.250.240.190.000.070.000.000.000.000.000.000.000.000.000.000.000.000.000.000.0014.2029.8218.1411.0611.518.273.1512.8310.297.0514.5821.007.235.937.29
1763.706.663.782.562.751.770.742.442.151.453.013.911.591.241.510.000.170.400.140.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.003.706.834.182.702.751.770.742.442.151.453.013.911.591.241.51
1788.7925.5011.017.077.555.772.679.489.035.7711.6218.226.155.365.501.331.681.660.920.950.280.600.530.710.150.370.300.660.640.570.050.030.030.030.030.000.000.000.000.000.000.000.000.000.0010.1627.2112.708.028.526.053.2710.019.745.9211.9918.526.816.006.07
1750.982.401.200.921.000.520.260.750.990.551.301.630.690.520.490.200.320.280.090.100.000.000.000.070.000.000.050.000.090.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.182.721.481.011.100.520.260.751.060.551.301.680.690.620.49
18756.36157.0970.8043.1944.5236.3215.8361.8156.4635.8074.49127.1738.8833.0735.938.9910.3510.366.465.331.593.383.244.881.182.882.514.324.463.960.130.070.070.060.080.040.020.000.040.000.000.000.000.020.0065.49167.5181.2349.7249.9337.9419.2365.0561.3836.9877.37129.6943.2037.5539.89
18318.8636.4219.2813.9314.698.824.6612.2315.198.9119.6124.4810.898.008.683.774.523.892.142.560.701.261.322.180.631.020.551.331.341.170.720.410.440.410.460.190.120.130.130.060.120.060.070.090.0523.3541.3523.6116.4817.719.716.0413.6817.509.6020.7525.0912.309.439.90
1851.883.411.661.191.280.710.290.881.070.601.471.810.780.610.540.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.000.001.883.411.661.191.280.710.290.881.070.601.471.810.780.610.54
17418.8731.3518.5212.3013.768.334.269.9911.839.2914.3117.888.526.426.820.952.642.301.150.660.250.650.721.140.170.630.280.450.550.270.040.000.030.000.000.000.000.000.000.000.000.000.000.000.0019.8533.9920.8413.4514.428.584.9110.7112.989.4514.9418.168.976.967.09
17716.8542.1020.6413.9613.2610.464.9115.1713.128.6918.8223.1710.278.509.662.373.713.501.721.670.501.011.351.820.350.900.601.061.000.980.090.050.060.040.050.000.000.000.000.000.000.000.000.000.0019.3145.8524.2115.7214.9810.965.9316.5214.949.0419.7223.7711.339.5010.64
1717.0113.377.575.225.503.501.714.765.523.227.749.624.023.083.321.161.731.330.620.950.230.340.620.640.230.380.210.420.440.360.260.140.150.1