Analysis and Solution for Iit Jee 2012

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    SOLUTIONS

    forforforforfor

    IIT-JEE 2012

    Time : 3 hrs. Max. Marks: 210

    Regd. Office: Aakash Tower, Plot No.-4, Sec-11, MLU, Dwarka, New Delhi-110075Ph.: 011-47623456 Fax : 011-47623472

    INSTRUCTIONS

    1. The question paper consists of 3 parts (Physics, Chemistry and Mathematics). Each part consists

    of three sections.

    2. Section I contains 10 multiple choice questions. Each question has four choices (A), (B), (C) and

    (D) out of which ONLY ONE is correct.3. Section II contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and

    (D) out of which ONE or MORE are correct.

    4. Section III contains 5 questions. The answer to each question is a single digit integer, ranging

    from 0 to 9 (both inclusive).

    DATE : 08/04/2012

    PAPER - 1 (Code - 0)

    PARTI : PHYSICS

    SECTION - I(Single Correct Answer Type)

    This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D)

    out of which ONLY ONE is correct.

    1. Three very large plates of same area are kept parallel and close to each other. They are considered

    as ideal black surfaces and have very high thermal conductivity. The first and third plates are

    maintained at temperatures 2Tand 3Trespectively. The temperature of the middle (i.e. second) plate

    under steady state condition is

    (A)

    1

    465

    2T (B)

    1

    497

    4T (C)

    1

    497

    2T (D)

    1

    497 T

    Answer (C)

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    Hints : At equilibrium,

    Heat absorbed = Heat radiated

    A(3T)4 +A(2T)4 = 2AT04

    1/4

    0

    97

    2

    T T

    2. Consider a thin spherical shell of radius R with its centre at the origin, carrying uniform positive surface

    charge density. The variation of the magnitude of the electric field

    | ( )|E r and the electric potential V(r) with

    the distance r from the centre, is best represented by whcih graph?

    (A)

    | ( )|E r V r( )

    0R r

    (B)

    | ( )|E r V r( )

    0R r

    (C)

    | ( )|E r V r( )

    0R r

    (D)

    | ( )|E r V r( )

    0R r

    Answer (D)

    Hints : Inside, E(r) = 0, outside 2

    1( )E r

    r

    Inside V(r) = constant, outside 1

    ( )V rr

    3. Young's double slit experiment is carried out by using green, red and blue light, one color at a time. The fringe

    widths recorded are G,

    Rand

    B, respectively. Then,

    (A) G

    > B

    > R

    (B) B

    > G

    > R

    (C) R

    > B

    > G

    (D) R

    > G

    > B

    Answer (D)

    Hints : As R > G > B

    R>

    G>

    Bas

    4. Two large vertical and parallel metal plates having a separation of 1 cm are connected to a DC voltage source

    of potential differenceX. A proton is released at rest midway between the two plates. It is found to move at

    45 to the vertical JUST after release. ThenXis nearly

    (A) 1 105 V (B) 1 107 V (C) 1 109 V (D) 1 1010 V

    Answer (C)

    Hints : Here, qE= mg

    19 27

    21.6 10 1.6 10 10

    (1 10 )

    X

    X= 109 V

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    5. A bi-convex lens is formed with two thin plano convex lenses as shown in the figure. Refractive index n of

    the first lens is 1.5 and that of the second lens is 1.2. Both the curved surfaces are of the same radius of

    curvature R = 14 cm. For this bi-convex lens, for an object distance of 40 cm, the image distance will be

    n = 1.5n = 1.2

    R = 14 cm

    (A) 280.0 cm (B) 40.0 cm (C) 21.5 cm (D) 13.3 cm

    Answer (B)

    Hints :

    1 1 1 1 11.5 1 1.2 1

    14 14f

    f= 20 cm

    As object distance = 40 cm Image distance = 40 cm

    6. A small mass m is attached to a massless string whose other end is fixed at P as shown in the figure. The

    mass is undergoing circular motion in the x-y plane with centre at O and constant angular speed . If the

    angular momentum of the system, calculated about O andPare denoted by

    OL and

    PL respectively, then

    P

    (A)

    OL and

    PL do not vary with time

    (B)

    OL varies with time while

    PL remains constant

    (C)

    OL remains constant while

    PL varies with time

    (D)

    OL and

    PL both vary with time

    Answer (C)

    Hints : The torque about O is zero, but aboutPis non-zero.

    AsdL

    dt

    thus PL

    must be a variable.

    7. A mixture of 2 moles of helium gas (atomic mass = 4 amu) and 1 mole of argon gas (atomic mass = 40 amu)

    is kept at 300 K in a container. The ratio of the rms speeds

    rms

    rms

    (helium)

    (argon)

    v

    vis

    (A) 0.32 (B) 0.45 (C) 2.24 (D) 3.16

    Answer (D)

    Hints :

    He Ar

    Ar He

    10 3.16M

    M

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    8. A thin uniform rod, pivoted at O, is rotating in the horizontal plane with constant angular speed , as shownin the figure. At time t = 0, a small insect starts from O and moves with constant speed v with respect to

    the rod towards the other end. It reaches the end of the rod at t = Tand stops. The angular speed of the

    system remains throughout. The magnitude of the torque

    (| |) on the system about O, as a function of

    time is best represented by which plot?

    z

    Ov

    (A)

    O Tt

    (B)

    O Tt

    (C)

    O Tt

    (D)

    O Tt

    Answer (B)

    Hints : ( )d

    Idt

    22

    3

    d MLmx

    dt

    2dx

    mxdt

    Now, x= vt

    t

    Finally torque becomes zero.

    9. In the determination of Youngs modulus

    2

    4MLgY

    ldby using Searles method, a wire of length L= 2 m

    and diameter d = 0.5 mm is used. For a load M = 2.5 kg, an extension l = 0.25 mm in the length of the

    wire is observed. Quantities d and l are measured using a screw gauge and a micrometer, respectively. They

    have the same pitch of 0.5 mm. The number of divisions on their circular scale is 100. The contributions to

    the maximum probable error of the Ymeasurement

    (A) Due to the errors in the measurements ofd and l are the same

    (B) Due to the error in the measurement ofd is twice that due to the error in the measurement of l

    (C) Due to the error in the measurement ofl is twice that due to the error in the measurement of d

    (D) Due to the error in the measurement ofd is four times that due to the error in the measurement of l

    Answer (A)

    Hints :

    2y l d

    y l d

    2l dy y

    l d

    =

    2y l y d

    l d

    The two quantities are equal.

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    10. A small block is connected to one end of a massless spring of un-stretched length 4.9 m. The other end of

    the spring (see the figure) is fixed. The system lies on a horizontal frictionless surface. The block is stretched

    by 0.2 m and released from rest at t = 0. It then executes simple harmonic motion with angular frequency

    3rad/s. Simultaneously at t = 0, a small pebble is projected with speed v from point Pat an angle of

    45 as shown in the figure. PointPis at a horizontal distance of 10 m from O. If the pebble hits the blockat t = 1 s, the value of vis (takeg= 10 m/s2)

    z

    10 m

    xP

    45O

    v

    (A) 50 m/s (B) 51 m/s (C) 52 m/s (D) 53 m/s

    Answer (A)

    Hints : For the block,

    2

    T = 6 seconds.

    For block, the position in 1 second will be

    x= 0.2 cost

    At t =1 s, x= 0.1 m

    At t = 1 s, block will be at a distance 4.9 m + 0.1 m = 5 m from wall.

    Range of pebble is also 5 mNow, for pebble, vcos45 (1 sec) = 5 m

    v = 5 2 = 50 m/s

    SECTION - II

    (Multiple Correct Answer(s) Type)

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of

    which ONE OR MORE are correct.

    11. For the resistance network shown in the figure, choose the correct option(s).

    I1 QT

    P SI2

    2 2

    4 4

    1 1

    2

    4

    12 V

    (A) The current throughPQis zero (B) I1

    = 3 A

    (C) The potential at Sis less than that at Q (D) I2 = 2 A

    Answer (A, B, C, D)

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    Hints : The network is an extension of balanced Wheatstone bridge, thus current PQand STis zero.

    Req

    =

    11 1

    +6 12

    = 4

    I1

    = 3A

    Also, I2

    =12

    6= 2 A

    Now, VS

    + 2I2

    + 2I2

    4I3

    = VQ

    VS

    VQ

    = 4I3

    2I2

    2I2

    = 4 1 2 2 2 2

    = 4 V

    12. A person blows into open-end of a long pipe. As a result, a high-pressure pulse of air travels down the pipe.

    When this pulse reaches the other end of the pipe

    (A) A high-pressure pulse starts traveling up the pipe, if the other end of the pipe is open

    (B) A low-pressure pulse starts traveling up the pipe, if the other end of the pipe is open

    (C) A low-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed

    (D) A high-pressure pulse starts traveling up the pipe, if the other end of the pipe is closed

    Answer (B, D)

    Hints : At open end, a compression is reflected as a rarefaction

    At closed end, a compression is reflected as a compression

    13. Consider the motion of a positive point charge in a region where there are simultaneous uniform electric and

    magnetic fields

    0 0 and .E E j B B j At time t = 0, this charge has velocity

    v in the x-y plane, making an

    angle with the x-axis. Which of the following option(s) is/are correct for time t > 0?(A) If = 0, the charge moves in a circular path in the x-z plane

    (B) If = 0, the charge undergoes helical motion with constant pitch along they-axis

    (C) If = 10, the charge undergoes helical motion with its pitch increasing with time, along the y-axis

    (D) If = 90, the charge undergoes linear but accelerated motion along they-axis

    Answer (C, D)

    Hints : For = 10, path is helical.

    Since there is an electric field, pitch is increasing.

    For = 90, path is straight line as

    B will not exert any force.

    14. A cubical region of side a has its centre at the origin. It encloses three fixed point charges, q at 0, , 04

    a,

    +3q at (0, 0, 0) and q at

    0, , 04a

    . Choose the correct option(s).

    a

    z

    y3qq

    x

    q

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    (A) The net electric flux crossing the plane x= 2

    ais equal to the net electric flux crossing the plane x=

    2

    a

    (B) The net electric flux crossing the planey = 2

    ais more than the net electric flux crossing the plane

    y =

    2

    a

    (C) The net electric flux crossing the entire region is0

    q

    (D) The net electric flux crossing the plane z = 2

    ais equal to the net electric flux crossing the plane x=

    2

    a

    Answer (A, C, D)

    Hints : Due to symmetry.

    15. A small block of mass of 0.1 kg lies on a fixed inclined planePQwhich makes an angle with the horizontal.

    A horizontal force of 1 N acts on the block through its centre of mass as shown in the figure. The blockremains stationary if (takeg=10 m/s2)

    Q

    O

    P

    1 N

    (A) = 45

    (B) > 45 and a frictional force acts on the block towards P.

    (C) > 45 and a frictional force acts on the block towards Q.

    (D) < 45 and a frictional force acts on the block towards Q.

    Answer (A, C)

    Hints : If 1 cos = 1 sin

    Q= 45, Fnet

    = 0

    If 1 cos > 1 sin

    i.e., < 45, friction must be towards P.

    If 1 cos < 1 sin

    > 45, friction must be towards Q.

    1sin

    1cos

    P

    Q

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    SECTION - III

    (Integer Answer Type)

    This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging from

    0 to 9 (both inclusive).

    16. A cylindrical cavity of diameter a exists inside a cylinder of diameter 2a as shown in the figure. Both thecylinder and the cavity are infinitely long. A uniform current density J flows along the length. If the

    magnitude of the magnetic field at the pointPis given by 0 ,12

    NaJ then the value ofNis

    aP

    2a

    O

    Answer (5)

    Hints : B =B1

    B2

    Here,B1

    is0

    2

    Ja(field due to complete cylinder)

    B2

    =

    2

    0

    02

    3 122

    2

    aJ

    Ja

    a

    B = 0512

    aJ

    17. A proton is fired from very far away towards a nucleus with charge Q= 120 e, where e is the electronic

    charge. It makes a closest approach of 10 fm to the nucleus. The de Broglie wavelength (in units of fm) of

    the proton at its start is: (take the proton mass, mp

    =

    275 10 kg;3

    h/e = 4.2 1015 J.s/C;

    9 15

    0

    19 10 . m/F; 1 fm 10 m

    4)

    Answer (7)

    Hints :2 2

    15 2

    0

    12024 (10 10 ) 2

    e e p hm m

    1422 0

    2

    4 10

    2 120

    h

    m e

    4

    04 10

    2 120

    h

    e m

    =

    1415

    9 27

    10 34.2 10

    9 10 2 120 5 10

    = 7 1015 m

    = 7fm

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    18. A circular wire loop of radius R is placed in the x-y plane centered at the origin O. A square loop of side

    a(a

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    20. A lamina is made by removing a small disc of diameter 2R from a bigger disc of uniform mass density and

    radius 2R, as shown in the figure. The moment of inertia of this lamina about axes passing through O and

    Pis IO

    and IP

    , respectively. Both these axes are perpendicular to the plane of the lamina. The ratio P

    O

    I

    Ito

    the nearest integer is

    2R

    O2R P

    Answer (3)

    Hints : Let the mass density be .

    IO

    =

    2 2

    2 2(2 ) (2 ) 3 ( ) ( )2 2

    R RR R

    = 413

    2R

    IP

    =

    2 22 2 2 23 ( )(2 ) (2 ) ( 5 )

    2 2

    R RR R R R

    = 437

    2R

    RatioP

    O

    I

    I=

    373

    13

    PARTII : CHEMISTRY

    SECTION - I

    (Single Correct Answer Type)

    This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of which

    ONLY ONE is correct.

    21. For one mole of a van der Waals gas when b = 0 and T = 300 K, the PV vs. 1/V plot is shown below. The

    value of the van der Waals constant 'a' (atm. litre2 mol2) is

    24.6

    23.1

    21.6

    20.1

    2.0 3.00

    1

    V (mol litre )

    1

    PV(litre-a

    tmm

    ol)

    1[Graph not to scale]

    (A) 1.0 (B) 4.5 (C) 1.5 (D) 3.0

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    Answer (C)

    Hints :

    2

    aP

    VV = RT

    PV +a

    V = RT

    PV = RT a

    V

    So, Plot of (PV) vs

    1

    Vhas slope a.

    slope =

    20.1 24.6

    1.53

    a = 1.5 atm L2 mol2

    22. The number of optically active products obtained from the complete ozonolysis of the given compound is

    CH CH = CH C CH = CH C CH = CH CH33

    H CH3

    CH3 H

    (A) 0 (B) 1 (C) 2 (D) 4

    Answer (A)

    Hints :

    Ozonolysis produces CH3CHO and CH3CH(CHO)2

    23. The colour of light absorbed by an aqueous solution of CuSO4

    is

    (A) Orange-red (B) Blue-green (C) Yellow (D) Violet

    Answer (A)

    Hints :

    Complementary colour of blue is (Orange-red)

    24. Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen?

    (A) HNO3, NO, NH

    4Cl, N

    2(B) HNO

    3, NO, N

    2, NH

    4Cl

    (C) HNO3, NH4Cl, NO, N2 (D) NO, HNO3, NH4Cl, N2

    Answer (B)

    Hints :

    3 2 4

    ( 5) ( 2) (0) ( 3)

    H NO , NO , N , NH Cl

    25. As per IUPAC nomenclature, the name of the complex [Co(H2O)

    4(NH

    3)2]Cl

    3is

    (A) Tetraaquadiaminecobalt (III) chloride

    (B) Tetraaquadiamminecobalt (III) chloride

    (C) Diaminetetraaquacobalt(III) chloride

    (D) Diamminetetraaquacobalt (III) chloride

    Answer (D)

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    26. The carboxyl functional group (COOH) is present in

    (A) Picric acid (B) Barbituric acid (C) Ascorbic acid (D) Aspirin

    Answer (D)

    Hints :

    (Picric acid)

    (Barbituric acid)

    OH

    NO2O2N

    NO2

    ,

    NH

    O

    HN

    OO

    (Ascorbic acid) (Aspirin)

    COOH,

    OH

    O

    HO OH

    HOO

    H

    OCCH3

    O

    27. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a0

    is Bohr radius]

    (A)

    2

    2 2

    0

    h

    4 ma(B)

    2

    2 2

    0

    h

    16 ma(C)

    2

    2 2

    0

    h

    32 ma(D)

    2

    2 2

    0

    h

    64 ma

    Answer (C)

    Hints :

    Centripital force = Coulombic force of attraction

    2mV

    r=

    2

    2

    KZe

    r

    V2 =2KZe

    mr

    V =

    nh

    2 mr

    V2 =

    2 2

    2 2 2

    n h

    4 m r

    22 2 2 2 20

    2 2 2 2 2

    a nKZe n h h nr

    mr Z Z4 m r 4 mKe

    Vn

    = 0

    hZ

    2 ma n

    K.E. =

    2 22

    n 2 2 2

    0

    1 h Zmv

    2 8 ma n; K.E. (for x = 2 and Z = 1) =

    2

    2 2

    0

    h

    32 ma

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    28. In allene (C3H

    4), the type(s) of hybridisation of the carbon atoms is (are)

    (A) sp and sp3 (B) sp and sp2 (C) Only sp2 (D) sp2 and sp3

    Answer (B)

    Hints :

    C = C = CH

    ( )sp

    ( )sp2

    (Allene)

    H

    H

    H

    ( )sp2

    29. A compound MpX

    qhas cubic close packing (ccp) arrangement of X. Its unit cell structure is shown below. The

    empirical formula of the compound is

    M =

    X =

    (A) MX (B) MX2

    (C) M2X (D) M

    5X

    14

    Answer (B)

    Hints :

    Number of X atoms/ ions per unit cell =1 1

    8 6 48 2

    Number of M atoms/ions per unit cell =1

    1 4 24

    Empirical formula of the compound is MX2

    30. The number of aldol reaction(s) that occurs in the given transformation is

    CH3CHO + 4HCHOconc. aq. NaOH

    OH OH

    HO OH

    (A) 1 (B) 2 (C) 3 (D) 4

    Answer (C)

    Hints :

    OH + HCHO/OH3 2 2Aldol Aldol

    CH CHO + H CHO HOCH CH CHO HOCH CH CHO2

    CH OH

    |2

    + HCHO/OHAldol

    HOCH C CHO2

    CH OH

    |

    |

    CH OH

    2

    2

    + HCHO/OHCannizzaro

    HOCH C CH OH2 2

    CH OH

    |

    |

    CH OH

    2

    2

    Number of aldol reactions = 3

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    SECTION - II

    (Multiple Correct Answer(s) Type)

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of

    which ONE OR MORE are correct.

    31. Choose the correct reason(s) for the stability of the lyophobic colloidal particles.

    (A) Preferential adsorption of ions on their surface from the solution

    (B) Preferential absorption of solvent on their surface from the solution

    (C) Attraction between different particles having opposite charges on their surface

    (D) Potential difference between the fixed layer and the diffused layer of opposite charges around the colloidal

    particles

    Answer (A, D)

    Hints :

    Lyophobic colloids carry either +ve or ve charge. In order to acquire stability the colloidal particles attract

    oppositely charged ions forming a diffused layer. A potential is developed between fixed layer and diffused layer

    called zeta potential. Higher the value of zeta potential higher will be the stability of lyophobic colloid.

    32. For an ideal gas, consider only P-V work in going from an initial state X to the final state Z. The final state

    Z can be reached by either of the two paths shown in the figure. Which of the following choice(s) is (are)

    correct? [take S as change in entropy and w as work done]

    P(atmosphere)

    V(liter)

    YX

    Z

    (A) S S Sx z x y y z+ (B) w w wx z x y y z+

    (C) w wx y z x y (D) S Sx y z x y

    Answer (A, C)

    Hints :

    Entropy is a state function. In this diagram initial state is X and final state is Z.

    Therefore, SX Z = SX Y + SY Z

    Work is a path function. Therefore WX Y Z

    = WX Y

    33. Which of the following hydrogen halides react(s) with AgNO3

    (aq) to give a precipitate that dissolves in

    Na2S

    2O

    3(aq)?

    (A) HCl (B) HF

    (C) HBr (D) HI

    Answer (A, C, D)

    Hints :

    Na2S2O3 + AgX Ag2S2O32 2 32Na S O

    Na2[Ag(S2O3)3][X = Cl and Br]

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    34. Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction, as

    shown in the given scheme.

    Binary mixture containing

    Compound 1 and Compound 2

    NaOH(aq)

    NaHCO (aq)3

    Compund 1

    Compund 1

    + Compund 2

    Compund 2+

    (A) C6H

    5OH and C

    6H

    5COOH (B) C

    6H

    5COOH and C

    6H

    5CH

    2OH

    (C) C6H

    5CH

    2OH and C

    6H

    5OH (D) C

    6H

    5CH

    2OH and C

    6H

    5CH

    2COOH

    Answer (B, D)

    Hints :

    C6H

    5COOH + NaOH C

    6H

    5COONa + H

    2O ; C

    6H

    5COOH + NaHCO

    3 C

    6H

    5COONa + CO

    2+ H

    2O

    C6H

    5CH

    2 OH + NaOH No reaction ; C

    6H

    5CH

    2OH + NaHCO

    3 No reaction

    C6H5CH2COOH + NaOH C6H5CH2 COONa + H2O ; C6H5CH2COOH + NaHCO3 C6H5CH2COONa

    + CO2

    + H2O

    C6H

    5CH

    2OH + NaOH No reaction ; C

    6H

    5CH

    2OH + NaHCO

    3 No reaction

    35. Which of the following molecules, in pure form, is (are) unstable at room temperature?

    (A) (B)

    (C)

    O

    (D)

    O

    Answer (B, C)

    Hints :

    The compound is antiaromatic and hence unstable at room temperature. The other compound

    O O

    +

    is also unstable at room temperature due to partial positive charge at carbonyl C-atom

    SECTION - III(Integer Answer Type)

    This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging from

    0 to 9 (both inclusive).

    36. The periodic table consists of 18 groups. An isotope of copper, on bombardment with protons, undergoes a

    nuclear reaction yielding elementXas shown below. To which group, element Xbelongs in the periodic table?

    63 1 1 129 1 0 1

    Cu H 6 n 2 H X

    Answer (8)

    Hints :

    63 1 1 4 1 5229 1 0 2 1 26Cu H 6 n ( He) 2 H X( Fe)

    Fe belongs to group-8.

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    37. An organic compound undergoes first-order decomposition. The time taken for its decomposition to1

    8and

    1

    10

    of its initial concentration are 18

    tand 1

    10

    trespectively. What is the value of

    1

    8

    1

    10

    t

    10 ?

    t

    (take log10

    2 = 0.3)

    Answer (9)

    Hints :

    1/8 102.303 1

    t log ...(i)k 1 8

    1/10 102.303 1

    t log ...(ii)k 1 10

    1/8

    1/10

    [t ] log810 10 3 0.3 10 9

    [t ] log10

    38. 29.2% (w/w) HCl stock solution has a density of 1.25 g mL1. The molecular weight of HCl is 36.5 g mol1.

    The volume (mL) of stock solution required to prepare a 200 mL solution of 0.4 M HCl is

    Answer (8)

    Hints :

    Molarity of HCl =1.25 29.2 1000

    10(M)100 1 36.5

    V 10 = 200 0.4

    V = 8 mL

    39. The substituents R1

    and R2

    for nine peptides are listed in the table given below. How many of these peptides

    are positively charged at pH = 7.0?

    H N3 CH CO NH CH NH CH CO NH CH COOCO

    HR2

    R1

    H

    Peptide R1 R2

    I H H

    II H CH3

    III CH2COOH HIV CH2CONH2 (CH2)4NH2

    V CH2CONH2 CH2CONH2

    VI (CH2)4NH2 (CH2)4NH2

    VII CH2COOH CH2CONH2

    VIII CH2OH (CH2)4NH2

    IX (CH2)4NH2 CH3

    Answer (4)

    Hints :

    When any group in R1

    and R2

    is basic group then amino acid is positively charged at pH = 7.0. So, answers

    are peptide IV, VI, VIII and IX.

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    40. When the following aldohexose exists in its D-configuration, the total number of stereoisomers in its pyranose

    form is

    CHO

    CH2

    CHOH

    CHOH

    CHOH

    CH OH2

    Answer (8)

    Hints :

    Given

    CHO

    CH2

    CHOH

    CHOH

    CHOH

    CH OH2

    has D configuration

    H

    CH OH2

    O

    HH

    HO

    HO

    OH*

    *

    *C* are chiral carbon atoms. Hence total stereoisomers are 8.

    PARTIII : MATHEMATICS

    SECTION - I

    (Single Correct Answer Type)

    This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) out of whichONLY ONE is correct.

    41. Letf(x)

    2 cos , 0,

    0, 0

    x xxx

    x

    thenfis

    (A) Differentiable both at x= 0 and at x= 2

    (B) Differentiable at x= 0 but not differentiable at x= 2

    (C) Not differentiable at x= 0 but differentiable at x= 2

    (D) Differentiable neither at x= 0 nor at x= 2Answer (B)

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    Hints :

    2 cos , 0( )

    0 , 0

    x xf x xx

    x

    Letp(x) = x2 and ( ) cosg xx

    Nowg(x) is a continuous non-differentiable at x= 0, and 2 but sincep(0) = 0, so,p(x).g(x) is non-differentiable

    at x= 2.

    42. The functionf: [0, 3] [1, 29], defined byf(x) = 2x3 15x2 + 36x+1, is

    (A) One-one and onto

    (B) Onto but not one-one

    (C) One-one but not onto

    (D) Neither one-one nor onto

    Answer (B)Hints :

    3 2( ) 2 15 36 1f x x x x

    f(x) = 6x2 30x+ 36

    = 6(x2 5x+ 6)

    = 6(x 2) (x 3)

    Clearly the derivative changes sign in [0, 3] so, fis NOT one-one.

    Now the function is increasing in [0, 2] and decreasing in [2, 3]

    Also, f(0) = 1

    f(2) = 29

    f(3) = 8

    Hence the range is [1, 29] and so, the function is onto.

    43. The ellipse E1

    : 2 2

    19 4

    x yis inscribed in a rectangle R whose sides are parallel to the coordinate axes.

    Another ellipse E2

    passing through the point (0, 4) circumscribes the rectangle R. The eccentricity of the ellipse

    E2

    is

    (A)2

    2(B)

    3

    2(C)

    1

    2(D)

    3

    4

    Answer (C)Hints :

    Let the equation ofE2

    be

    2 2

    2 21

    x y

    a b

    Clearly the pointPhas coordinates (3, 2)

    (0,4)

    P

    E2

    E1

    So, (3, 2) and (0, 4) satisfy E2

    22

    161 16b

    b

    and 2 29 4

    1a b

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    22

    9 312

    4a

    a

    12 1

    116 2

    e

    44. The point Pis the intersection of the straight line joining the points Q(2, 3, 5) and R (1, 1, 4) with the

    plane 5x 4y z = 1. IfSis the foot of the perpendicular drwan from the point T(2, 1, 4) to QR, then the

    length of the line segmentPSis

    (A)1

    2(B) 2 (C) 2 (D) 2 2

    Answer (A)

    Hints :

    The equation of the line QR is

    2 3 51 4 1

    x y z k

    so any arbitrary point is ( 2, 4 3, 5)k k k

    Now this will satisfy the equation of the plane

    5( 2) 4( 4 3) ( 5) 1k k k

    2

    3k

    So, the point is4 1 13

    , ,3 3 3

    Now, let point Sbe (+2, 4+ 3, + 5)

    So, D.R's ofSTis (, 4+ 2, + 1)

    () (1) 4(4+ 2) 1(+ 1) = 0

    1

    2

    The point is3 9

    ,1,2 2

    So,PSis

    1

    2

    45. The locus of the mid-point of the chord of contact of tangents drawn from points lying on the straight line

    4x 5y = 20 to the circle x2 + y2 = 9 is

    (A) 20(x2 +y2) 36x+ 45y = 0

    (B) 20(x2 +y2) + 36x 45y = 0

    (C) 36(x2 +y2) 20x+ 45y = 0

    (D) 36(x2 +y2) + 20x 45y = 0

    Answer (A)

    Hints :Let,P(, ) be a point on the line 4x 5y = 20.

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    i.e., 4 5 = 20 ... (1)

    If (h, k) be the mid point of chord of contact, then T= S1, gives

    xh +yk 9 = h2 + k2 9

    xh + yk = h2 + k2. ... (2)

    Also, equation of chord of contact w.r.t.P(, ) isx+ y = 9 ... (3)

    as equations (2) & (3) are identical,

    (0, 0)P( , )

    ( , )h k

    So,

    2 29

    h k h k

    2 2 2 2

    9 9,

    h k

    h k h k

    Using equation (1), we get

    2 2 2 2

    9 94 5 20

    h k

    h k h k

    i.e., locus of (h, k) is given by

    20(x2 +y2) 36x+ 45y = 0

    46. LetP= [aij] be a 3 3 matrix and let Q= [b

    ij], where b

    ij= 2i+ja

    ijfor 1 i,j 3. If the determinant ofPis

    2, then the determinant of the matrix Qis

    (A) 210 (B) 211 (C) 212 (D) 213

    Answer (D)

    Hints :

    Given,

    11 12 13

    3 3 21 22 33

    31 32 33

    [ ]ij

    a a a

    P a a a a

    a a a

    Now, 2 [ ]i j ij ijQ a b

    11 12 13

    21 22 23

    31 32 33

    b b b

    Q b b b

    b b b

    =

    2 3 411 12 13

    3 4 521 22 23

    4 5 631 32 33

    2 2 2

    2 2 2

    2 2 2

    a a a

    a a a

    a a a

    So,

    11 12 13

    1221 22 23

    31 32 33

    2

    a a a

    Q a a a

    a a a

    = 213.

    (as |P| = 2)

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    47. The integral

    2

    92

    sec

    sec tan

    xdx

    x xequals (for some arbitrary constantK)

    (A)

    2

    112

    1 1 1 sec tan

    11 7sec tanx x K

    x x

    (B)

    2

    112

    1 1 1 sec tan

    11 7sec tanx x K

    x x

    (C)

    2

    112

    1 1 1 sec tan

    11 7sec tanx x K

    x x

    (D)

    2

    112

    1 1 1sec tan

    11 7sec tanx x K

    x x

    Answer (C)

    Hints :Let secx+ tanx= t

    secx(secx+ tanx) dx= dt

    dx= 22

    1dt

    t

    Now, I =

    2

    2

    9/2

    12

    2 1

    tt dt

    t

    t

    =

    9 13 2 21

    2t t dt

    =

    7 11

    2 21 2 2

    2 7 11

    t t K

    =

    11

    221 1

    7 11

    t t K

    =

    2

    11

    2

    1 1 1 sec tan

    11 7

    sec tan

    x x K

    x x

    48. The total number of ways in which 5 balls of different colours can be distributed among 3 persons so that

    each person gets at least one ball is

    (A) 75 (B) 150 (C) 210 (D) 243

    Answer (B)

    Hints :

    x y z

    3

    2

    1

    2

    1

    1

    3 = 605 2 1C C C3 1 1

    3 = 90

    5 3 1

    C C C2 2 1

    Total = 150

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    49. If 2 1

    41

    limx

    x xax b

    x, then

    (A) a = 1, b = 4 (B) a = 1, b = 4 (C) a = 2, b = 3 (D) a = 2, b = 3

    Answer (B)

    Hints :

    Here,

    2 1 1 1lim 4

    1x

    x x ax x b x

    x

    2 1 1 1 lim 4

    1x

    x a x a b b

    x

    This is possible iff

    1 a = 0 a = 1

    and 1 a b = 4 b = 4

    50. Let z be a complex number such that the imaginary part of z is nonzero and a = z2 + z +1 is real. Then a

    cannot take the value

    (A) 1 (B)1

    3(C)

    1

    2(D)

    3

    4

    Answer (D)

    Hints :

    As, a is real,

    So a a gives

    z2 + z + 1 = 2 1z z

    ( )( 1) 0z z z zAs, z z

    So, 1z z

    1

    {where }2

    x z x iy

    Now,

    a = z2 + z + 1

    21 1

    12 2

    iy iy

    23

    4 y

    As,y 0 so, 3

    4a

    SECTION - II

    (Multiple Correct Answer(s) Type)

    This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of

    which ONE OR MORE are correct.

    51. Let Sbe the area of the region enclosed by2 xy e , y = 0, x= 0, and x= 1. Then

    (A)1

    Se

    (B)1

    1 Se

    (C)1 1

    14

    S

    e(D)

    1 1 11

    2 2

    S

    e

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    Answer (A, B, D)

    Hints :

    x [0, 1] x2x x2 xex2ex

    21 1

    10

    0 0

    1[ ] 1x x xS e dx e dx e

    e

    i.e.,1

    1Se

    Option (B) is correct.

    (0, 1)

    1,1e

    x= 0 x= 1

    y = 0

    1

    A

    Q

    1e

    R

    y-axis

    x-axis0

    0,1e

    S

    1P(1, 0)

    y e=x2

    Sis the area under the curve y = ex2

    Hence, S area of the rectangle OPQS

    i.e., S 1 1 1

    e e

    Hence, option (A) is correct.

    B

    A

    y-axis

    (0, 1)

    0

    x= 1x= 0 x=1

    2

    1

    21

    e,

    1,1e

    x-axis

    21

    0

    x dxS e

    2 2

    1

    12

    10

    2

    x xe dx e dx

    AreaA + AreaB

    Now,

    1

    2

    0

    1Area 1

    2A = dx

    1

    1

    2

    1 1 1Area 1

    2B = dx

    e e

    Hence,1 1 1

    12 2

    Se

    Hence, option (D) is correct

    Now, consider the integral3/2

    1

    12 1

    edx

    x e

    Substitute t = lnx

    1/2

    3/21 0

    etdx e dt

    x

    Now, for 0 < x< 1

    2 /2x xe e

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    2

    1

    0

    12 1xe dx

    e

    Now,1 1 1 7 9

    2 1 14 4 4e e e

    7 9 0

    4

    e

    e

    So, option (C) is not correct.

    52. If y(x) satisfies the differential equationy y tan x= 2xsec xand y(0) = 0, then

    (A)

    2

    4 8 2

    y (B)

    2

    4 18

    y (C)

    2

    3 9

    y (D)

    24 2

    3 3 3 3

    y

    Answer (A, D)

    Hints :

    tan 2 secdy

    y x x xdx

    cos (sin ) 2dy

    x x y x dx

    d(y cosx) = d(x2)

    ycosx= x2 + c

    y(0) = c = 0

    y = x2secx

    also,y = 2xsecx+ x2secxtanx

    53. Tangents are drawn to the hyperbola2 2

    19 4

    x y

    , parallel to the straight line 2xy = 1. The point of contact

    of the tangents on the hyperbola are

    (A)9 1

    2 2 2

    , (B)9 1

    2 2 2

    , (C) 3 3 2 2( , ) (D) 3 3 2 2( , )

    Answer (A, B)

    Hints :

    As, points of contact

    2 2

    2 2 2 2 2 2,

    a m b

    a m b a m b

    Here, a2

    = 9, b2

    = 4, m = 2

    so, required points are

    9 1,

    2 2 2

    54. Let , [0, 2] be such that

    22cos (1 sin ) sin tan cot cos 1

    2 2,

    tan(2 ) 0 and 3

    1 sin2

    .

    Then cannot satisfy

    (A)

    02

    (B)

    4

    2 3(C)

    4 3

    3 2(D)

    32

    2

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    Answer (A, C, D)

    Hints :

    2 12cos 1 sin sin cos 1

    sin cos2 2

    2cos 1 sin 2sin cos 1

    2cos + 1 = 2sin( + )(i)

    Now,

    3

    tan 0 and 1 sin2

    gives

    3 5,

    2 3

    Using (i) ;

    1

    sin cos2

    1 sin( ) 12

    i.e.

    5 13 17

    or,6 6 6 6

    13 17

    6 6

    2 7

    3 6So, options (A), (C) and (D) are correct.

    55. A ship is fitted with three engines E1, E

    2and E

    3. The engines function independently of each other with

    respective probabilities 12

    , 14

    and 14

    . For the ship to be operational at least two of its engines must function.

    LetXdenote the event that the ship is operational and letX1,X

    2andX

    3denote respectively the events that

    the engines E1, E

    2and E

    3are functioning. Which of the following is (are) true?

    (A) 13

    [ | ]16

    cP X X

    (B) P [Exactly two engines of the ship are functioning |X] =7

    8

    (C) 25

    [ | ]16

    P X X

    (D) 17

    [ | ]16

    P X X

    Answer (B, D)

    Hints :

    (A) 1cP X X

    1

    P X X

    P X

    1 1 1

    2 4 4

    1 1 1 1 1 1 1 1 1 1 3

    2 4 4 2 4 4 2 4 4 2 4 4

    18

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    (B) Required probability =

    3 3 1

    2 4 4 2 4 4 2 4 4

    1 1 3 1 3 1 1 1 1 1 1 1

    2 4 4 2 4 4 2 4 4 2 4 4

    7

    8

    (C) 2P X X

    22

    ( )P X X

    P X

    1 1 1 1 3 1 1

    4 2 4 2 4 2 4

    1

    4

    1 5

    54 81 8

    4

    (D)

    1

    1

    P X X

    P X

    1 1 1 3 1 1 3

    2 4 4 4 4 4 4

    1

    2

    7

    16

    SECTION - III

    (Integer Answer Type)

    This section contains 5 questions. The answer to each of the questions is a single digit integer, ranging from

    0 to 9 (both inclusive).

    56. The value of

    3

    2

    1 1 1 16 log 4 4 4 ...

    3 2 3 2 3 2 3 2is

    Answer (4)

    Hints :

    As, 1

    43 2

    y y

    4

    9y (as y > 0)

    so,

    3

    2

    46 log 4

    9

    57. Let Sbe the focus of the parabola y2 = 8xand letPQbe the common chord of the circle x2 +y2 2x 4y =

    0 and the given parabola. The area of the triangle PQSis

    Answer (4)

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    Hints :

    ClearlyP(2t2, 4t) satisfies the equation of circle,

    x2 +y2 2x 4y = 0

    4t4 + 16t2 4t216t = 0

    t(t3 + 3t 4) = 0

    t(t 1) (t2 + t + 4) = 0

    Y

    P t t(2 ,4 )2

    S(2, 0)QX t = 0,1

    i.e.,Pbe (2, 4)

    So, area ofPQS= 1

    2 4 42

    units

    58. If

    ,a b andc are unit vectors satisfying

    2 2 2| | | | | | 9a b b c c a , then

    |2 5 5 |a b c is

    Answer (3)

    Hints :

    2 2 2| | | | | | 9a b b c c a

    2 2 22(| | | | | | . ) 9a b c a b b c c a (i)

    2(3 ) 9a b b c c a

    3

    2a b b c c a angle between each pair is 120.

    Now, 2 2 2 2|2 5 5 | 4| | 25| | 25| | 20 20 50a b c a b c a b a c a c

    =

    20 20 504 25 25

    2 2 2

    = 54 10 10 25

    = 9

    |2 5 5 | 3a b c

    59. Letf: be defined asf(x) = |x| + |x2 1|. The total number of points at which fattains either alocal maximum or a local minimum is

    Answer (5)

    Hints :

    f(x) = |x| + |x2 1|

    f(x) = |x| + |(x 1)(x+ 1)| 1 10

    2

    2

    2

    2

    1 , 1

    1 , 1 0( )

    1 , 0 1

    1 , 1

    x x x

    x x xf x

    x x x

    x x x

    2 1 , 1

    2 1 , 1 0( )

    2 1 , 0 1

    2 1 , 1

    x x

    x xf x

    x x

    x x

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    f(x) is not differentiable at x= 0, 1 andf(x) = 0 at 1 1

    ,2 2

    x

    Also sign scheme off(x)

    x= 1, 0, 1 are point of minima 1 1/2 0 1/2 1 + + +

    1 1,2 2

    x are point of maxima

    total number of point of maxima

    and minima = 5

    60. Letp(x) be a real polynomial of least degree which has a local maximum at x= 1 and a local minimum at

    x= 3. Ifp(1) = 6 andp(3) = 2, thenp(0) is

    Answer (9)

    Hints :

    p(x) will be of degree 31 3

    +

    p(x) = k(x 1) (x 3), k > 0 as 1 is point of maxima and 3 is point of minima

    = k(x2 4x+ 3)

    Now

    32( ) 2 3

    3

    xp x k x x c

    given,p(1) = 6

    4k + 3c = 18 (i)

    andp(3) = 2

    c = 2

    so, k = 3

    p(x) = 3(x 1) (x 3)

    p(0) = 3( 1) ( 3) = 9