AMERCOR 5000_msds_en_111013

Page: 1 of 13 Revision Date: 13.10.2011

SAFETY DATA SHEET Print Date: 27.03.2012

Amercor™ 5000 CORROSION INHIBITOR ™ Trademark, Ashland or its subsidiaries, registered in various countries 797950

MSDS Number: 000000214999 Version: 1.0

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Conforms to EU Regulation 1907/2006/EC as amended. - SDSCLP_RO

1. Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Trade name : Amercor™ 5000 CORROSION INHIBITOR ™ Trademark, Ashland or its subsidiaries, registered in various countries

1.2 Relevant identified uses of the substance or mixture and uses advised against

Use of the Substance/Mixture : BOILER WATER TREATMENT, Corrosion inhibitor.

1.3 Details of the supplier of the safety data sheet

Ashland P.O. Box 8619 NL3009 AP, Rotterdam Netherlands [email protected]

Emergency telephone number +1-800-274-5263/+1-606-329-5701 , or contact your local emergency telephone number at 112 Product Information +31 10 497 5000 (in the Netherlands), or contact your local CSR contact person

2. Hazards identification

2.1 Classification of the substance or mixture

Classification (67/548/EEC, 1999/45/EC)

Corrosive R35: Causes severe burns. Harmful R21/22: Harmful in contact with skin and if swallowed.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Labelling according to EC Directives (1999/45/EC)

Hazard pictograms :

Corrosive

R-phrase(s) : R21/22 Harmful in contact with skin and if swallowed.

R35 Causes severe burns.

S-phrase(s) : S26 In case of contact with eyes, rinse





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immediately with plenty of water and seek medical advice.

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

S51 Use only in well-ventilated areas. S60 This material and its container must be

disposed of as hazardous waste.

Hazardous components which must be listed on the label: • 110-91-8 Morpholine • 100-37-8 2-Diethylaminoethanol • 108-91-8 Cyclohexylamine

2.3 Other hazards

3. Composition/information on ingredients

3.2 Mixtures

Aqueous solution of amines

Hazardous components

Chemical Name CAS-No. EC-No.

Registration number

Classification (67/548/EEC)

Classification (REGULATION (EC)

No 1272/2008)

Concentration [%]

Morpholine 110-91-8 203-815-1

R10 Xn; R20/21/22 C; R34

Flam. Liq. 3; H226 Acute Tox. 4; H302 Acute Tox. 4; H312 Acute Tox. 4; H332 Skin Corr. 1B; H314

>= 10 - < 15

2-Diethylaminoethanol

100-37-8 202-845-2

R10 Xn; R20/21/22 C; R34

Flam. Liq. 3; H226 Acute Tox. 4; H312 Acute Tox. 4; H332 Acute Tox. 4; H302 Skin Corr. 1B; H314

>= 10 - < 15

Cyclohexylamine 108-91-8 203-629-0

R10 Repr.Cat.3; R62 Xn; R21/22 C; R34

Flam. Liq. 3; H226 Acute Tox. 3; H301 Acute Tox. 3; H311 Repr. 2; H361 Skin Corr. 1B; H314

>= 2,5 - < 5

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.





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4. First aid measures

4.1 Description of first aid measures

General advice : Move out of dangerous area. Get medical attention immediately. Do not leave the victim unattended. Consult a physician. Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air. Call a physician or poison control centre immediately. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. Keep respiratory tract clear. If breathing is irregular or stopped, administer artificial respiration. In case of shortness of breath, give oxygen.

In case of skin contact : Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Wash contaminated clothing before re-use.

In case of eye contact : Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical attention. Remove contact lenses.

If swallowed : Do NOT induce vomiting. Rinse mouth with water. If conscious, drink plenty of water. Never give anything by mouth to an unconscious person. Obtain medical attention.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms : Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) thirst irritation (nose, throat, airways) Cough central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness) nervousness effects on blood pressure Abdominal pain chest pain halo vision (blurred vision around bright objects) loss of coordination Difficulty in breathing





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methemoglobinemia (blood abnormality which causes a blue coloring to the skin) lung edema (fluid buildup in the lung tissue) kidney damage liver damage lung damage

Risks : Pulmonary edema may be delayed.

4.3 Indication of any immediate medical attention and special treatment needed

5. Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : ABC powder Carbon dioxide (CO2) Dry chemical Water mist

Unsuitable extinguishing media

: Halons

5.2 Special hazards arising from the substance or mixture

Specific hazards during firefighting

: Do not allow run-off from fire fighting to enter drains or water courses.

5.3 Advice for firefighters

Special protective equipment for firefighters

: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment.

Further information : Keep containers and surroundings cool with water spray. Prevent fire extinguishing water from contaminating surface water or the ground water system. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

6. Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Ensure adequate ventilation. Pay attention to the spreading of gases especially at ground level (heavier than air) and to the direction of the wind. Evacuate personnel to safe areas.

6.2 Environmental precautions

Environmental precautions : Prevent further leakage or spillage if safe to do so.





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6.3 Methods and materials for containment and cleaning up

Methods for cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal.

6.4 Reference to other sections

Comply with all applicable federal, state, and local regulations.

7. Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Do not breathe vapours or spray mist. Avoid contact with skin and eyes. For personal protection see section 8. Provide sufficient air exchange and/or exhaust in work rooms. Avoid exceeding of the given occupational exposure limits (see section 8). When diluting, always add the product to water. Never add water to the product. When neutralising, always add the product to the neutralising agent. Never add neutralising agent to the product. Smoking, eating and drinking should be prohibited in the application area.

Advice on protection against fire and explosion

: Keep away from heat and sources of ignition.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

: Store in original container. Keep containers tightly closed in a dry, cool and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.

Other data : Stable under recommended storage conditions. Protect from frost.

7.3 Specific end uses

8. Exposure controls/personal protection

8.1 Control parameters

Components CAS-No. Value Control parameters

Update Basis





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Morpholine 110-91-8 TWA

10 ppm 36 mg/m3

10 2006

RO OEL

STEL

70 mg/m3

10 2006

RO OEL

STEL

20 ppm 72 mg/m3

10 2006

RO OEL

TWA

10 ppm 36 mg/m3

12 2009

ECTLV

STEL

20 ppm 72 mg/m3

12 2009

ECTLV

2-Diethylaminoethanol

100-37-8 TWA

6 ppm 30 mg/m3

10 2006

RO OEL

STEL

9 ppm 45 mg/m3

10 2006

RO OEL

Cyclohexylamine

108-91-8 TWA

5 ppm 20 mg/m3

10 2006

RO OEL

STEL

10 ppm 40 mg/m3

10 2006

RO OEL

8.2 Exposure controls

Engineering measures

Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure (from known, suspected or apparent adverse effects).

Personal protective equipment

Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. In the case of vapour formation use a respirator with an approved filter.

Hand protection : Nitrile rubber





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Eye protection : Face-shield

Skin and body protection : Wear as appropriate: Safety shoes impervious clothing Chemical resistant apron Discard contaminated shoes. Wear resistant gloves such as: Nitrile rubber

Hygiene measures : Keep away from food, drink and animal feedingstuffs. When using do not eat, drink or smoke. Ensure that eyewash stations and safety showers are close to the workstation location.

Environmental exposure controls

General advice : Prevent further leakage or spillage if safe to do so.

9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid

Colour : yellow

Odour : amine-like

Odour Threshold : no data available Flash point : 84 °C

Evaporation rate : no data available Ignition temperature : no data available Lower explosion limit : no data available Upper explosion limit : no data available Flammability (solid, gas) : no data available Oxidizing properties : no data available Autoignition temperature : Note: no data available

Burning number : no data available Molecular Weight : no data available pH : ca. 12,5

Freezing point : -10 °C

Boiling point : > 98 °C

Sublimation point : no data available Vapour pressure : no data available Density : ca.0,95 g/cm3

at 25 °C





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Relative density : ca.0,95

Bulk density : no data available Water solubility : Note: completely soluble

Partition coefficient: n-octanol/water

: no data available

Solubility in other solvents : no data available Viscosity, dynamic : no data available Viscosity, kinematic : no data available Flow time : no data available Impact Sensitivity : no data available Relative vapour density : no data available Surface tension : no data available

9.2 Other information

Conductivity : no data available Oxidising potential : no data available Refractive index : no data available Glowing Temperature : no data available

10. Stability and reactivity

10.1 Reactivity

Hazardous polymerisation does not occur.

10.2 Chemical stability

Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

Hazardous reactions : Note: Stable under recommended storage conditions.

: Hazardous polymerisation does not occur.

10.4 Conditions to avoid

Conditions to avoid : excessive heat Exposure to moisture.

10.5 Incompatible materials

Materials to avoid : Acids halogenated hydrocarbons Strong oxidizing agents nitrites and other nitrosating agents Metals organic anhydrides isocyanates acrylates Ketones Aldehydes





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Alcohols glycols phenols aluminum organic solvent nitrates peroxides Copper Copper alloys galvanized metals Reducing agents Zinc

10.6 Hazardous decomposition products

11. Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Acute oral toxicity 2-Diethylaminoethanol : LD 50: 1.300 mg/kg

Species: Rat

Cyclohexylamine : LD 50: 156 mg/kg Species: Rat

Acute inhalation toxicity Morpholine : LC 50: Exposure time: 8 h

Species: Rat

2-Diethylaminoethanol : LC 50: 4,6 mg/l Exposure time: 4 h Species: Rat

Cyclohexylamine : LC 50: 2,3 mg/l Exposure time: 4 h Species: Rat

Acute dermal toxicity Morpholine : LD 50: 500 mg/kg

Species: Rabbit

2-Diethylaminoethanol : LD 50: 1.124 mg/kg Species: Rabbit

Cyclohexylamine : LD 50: 277 mg/kg Species: Rabbit

Skin corrosion/irritation





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Skin irritation Morpholine : Result: Corrosive to skin

2-Diethylaminoethanol : Result: Irritating to skin

Cyclohexylamine : Result: Corrosive to skin

Serious eye damage/eye irritation

Eye irritation Morpholine : Result: Corrosive to eyes

2-Diethylaminoethanol : Result: Irritating to eyes

Cyclohexylamine : Result: Corrosive to eyes

Respiratory or skin sensitization

Target Organ Systemic Toxicant - Repeated exposure

Target Organs : Overexposure to this material (or its components) has been

suggested as a cause of the following effects in laboratory animals:, effects on male fertility, testis damage

Further information 2-Diethylaminoethanol : Central Nervous System

12. Ecological information

12.1 Toxicity

Toxicity to fish 2-Diethylaminoethanol : LC 50: 1.660 - 1.920 mg/l

Exposure time: 96 h Species: Fathead minnow (Pimephales promelas) flow-through test

Cyclohexylamine : LC 50: 470 mg/l Exposure time: 96 h Species: Danio rerio (zebra fish) Method: Static Remarks: Mortality

Toxicity to daphnia and other aquatic invertebrates. Cyclohexylamine : LC 50: 80 mg/l





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Exposure time: 24 h Species: Water flea (Daphnia magna) Method: Static Remarks: Mortality

12.2 Persistence and degradability

12.3 Bioaccumulative potential

12.4 Mobility in soil

12.5 Results of PBT and vPvB assessment

12.6 Other adverse effects

13. Disposal considerations

13.1 Waste treatment methods

Product : Dispose of in accordance with the European Directives on waste and hazardous waste.

: Do not contaminate ponds, waterways or ditches with chemical or used container. Container hazardous when empty. Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum.

14. Transport information

REGULATIONID NUMBER

PROPER SHIPPING NAME

*HAZARD CLASS

SUBSIDIARY HAZARDS

PACKING GROUP

MARINE POLLUTANT / LTD. QTY.

ADR UN 2735 AMINES, LIQUID,

CORROSIVE, N.O.S. (MORPHOLINE, DIETHYL ETHANOLAMINE)

8 II





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ADNR UN 2735 AMINES, LIQUID,


8 II

RID UN 2735 AMINES, LIQUID,


8 II

INTERNATIONAL MARITIME DANGEROUS GOODS UN 2735 AMINES, LIQUID,


8 II

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO UN 2735 Amines, liquid,

corrosive, n.o.s. (MORPHOLINE, DIETHYL ETHANOLAMINE)

8 II

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER UN 2735 Amines, liquid,

corrosive, n.o.s. (MORPHOLINE, DIETHYL ETHANOLAMINE)

8 II

*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment.

15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Notification statusUS. Toxic Substances Control Act y (positive listing)





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Canada. Canadian Environmental Protection Act (CEPA). Domestic Substances List (DSL). (Can. Gaz. Part II, Vol. 133)

y (positive listing)

Australia. Industrial Chemical (Notification and Assessment) Act y (positive listing) New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand


Japan. Kashin-Hou Law List y (positive listing) Korea. Toxic Chemical Control Law (TCCL) List y (positive listing) Philippines. The Toxic Substances and Hazardous and Nuclear Waste Control Act


China. Inventory of Existing Chemical Substances y (positive listing) 15.2 Chemical Safety Assessment

16. Other information

Full text of R-phrases referred to under sections 2 and 3

R10 Flammable. R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. R21/22 Harmful in contact with skin and if swallowed. R34 Causes burns. R35 Causes severe burns. R62 Possible risk of impaired fertility.

Full text of H-Statements referred to under sections 2 and 3.

H226 Flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H361 Suspected of damaging fertility or the unborn child.

Further information

Other information : The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Ashland's Environmental Health and Safety Department (+31 10 497 5000).

AMERCOR 5000_msds_en_111013

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