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GENERAL ELECTRIC COMPANY Pittsfield Massachusetts

AMBIENT TREND MONITORING AND PCB FATE AND TRANSPORT MODEL

September 1991

LMSE-910611amp337041

bulloLAWLER MATUSKY amp SKELLY ENGINEERS wgt ini Environmental Science amp Engineering Consultants s i-b

One Blue Hill Plaza Pearl River New York 10965

TABLE OF CONTENTS

Page No

LIST OF FIGURES iii

LIST OF TABLES vi

SUMMARY S-l

51 Introduction S-l 52 Ambient Trend Monitoring S-l 53 PCB Fate and Transport Model S-2 54 Projections of PCB Concentrations S-2 55 Future Monitoring S-3

1 INTRODUCTION 1-1

11 General Background 1-1 12 Report Organization 1-2

2 AMBIENT TRENDS 2-1

21 Ambient Trend Monitoring 2-1

211 Sampling Methods and Quality AssuranceQuality Control 2-1 212 Results of Surveys at Great Barrington 2-3

22 Analysis of Ambient Trends in the Vicinity of Great Barrington 2-5

221 Introduction 2-5 222 Methods 2-5 223 Results 2-6

3 PCB FATE AND TRANSPORT MODEL 3-1

31 Description of WASTOX Model 3-1 32 Parameter Evaluation 3-7

321 River Segmentation and Hydrology 3-7 322 Bed Sediment Characteristics 3-7 323 Settling Resuspension and Burial 3-8 324 Sediment - Water Partitioning 3-10 325 Bed Sediment - Water Column Diffusion 3-11 326 Volatilization 3-12 327 Upstream Tributary Suspended Solids and PCBs 3-12

Lawler Matusky amp Skelly Engineers

TABLE OF CONTENTS (Continued)

Page No

33 Model Calibration 3-13

331 Solids 3-14 332 PCBs 3-15

34 Model Projections of PCBs 3-19

341 Long-Term Hydrological Period 3-20 342 Upstream and Tributary Inflows of PCBs 3-20 343 Projections of PCBs in Sediment and Water 3-22

4 CONCLUSIONS AND RECOMMENDATIONS 4-1

41 Conclusions 4-1 42 Recommendations 4-3

REFERENCES R-l

ATTACHMENTS

1 - Sampling and Quality AssuranceQuality Control Manual

2 - Statistical Parameters

3 - Model Input Files

4 - Example Calculation of Particulate and Dissolved PCB Concentrations

n Lawler Matusky amp Skelly Engineers

LIST OF FIGURES

Following Figure No Title Page No

1-1 Housatonic River and Watershed Area 1-2

Schematic

in Upper Housatonic River

Housatonic River

River

Harrington MA

River at Great Barrington MA

at Great Barrington MA

River Daily Flow at Great Barrington (1913-1988)

Housatonic River

2-1 Staff Gauge and Sample Location 2-1

2-2 DH-59 Depth Integrating Sediment Sampler 2-1

2-3 Row Records at Great Harrington MA 2-3

2-4 Temporal Trends in Total PCB Flow and TSS 2-6

2-5 Total PCB and TSS Dependence on Flow in Upper 2-6

2-6 Total PCB Dependence on TSS in Upper Housatonic 2-6

2-7 Housatonic River Average Monthly Flow at Great 2-8

2-8 Peak Daily Flows for March 1913-1991 in Housatonic 2-8

2-9 Daily Housatonic River Flow-Frequency Histograms 2-9

2-10 Cumulative Frequency Distributions of Housatonic 2-9

3-1 Fluxes of PCB Associated With the Bed Sediment 3-6

3-2 Schematic of Model Segments and River Flows of 3-7

3-3 Dependence of Resuspension Rate on Flow 3-9

3-4 Suspended Solids Calibration Segments 1-4 3-14

3-5 Suspended Solids Calibration Segments 5 and 6 3-14

iii

LIST OF FIGURES (Continued)


3-6 PCB Calibration Results in Water Column andSediment (Segments 112 and 213)

3-16


3-16


3-16

3-9 Housatonic River Average Monthly Flow atGreat Barrington MA

3-20

3-10 Decaying PCB Boundary and TributaryConcentrations

3-21

3-11 PCB Projection Under Scenario 1 (Segment112 and 213)

3-23

3-12 PCB Projection Under Scenario 1 (Segments314 and 415)

3-23


3-23


3-23


3-23

3-16 PCB Projection Under Scenario 1 (Segments1122)

3-23

3-17 PCB Projection Under Scenario 1 (Averageof Model Segments)

3-23


3-24


3-24

IV


Figure No TitleFollowing

Page No


3-24


3-24


3-24


3-24

3-24 PCB Projection Under Scenarios 1 and 3(Segments 112 and 213)

3-24


3-24


3-24


3-24


3-24

3-29 PCB Projection Under Scenarios 1 and 3(Segments 1122)

3-24

LIST OF TABLES

Table No Title Page No

2-1 Existing Suspended Sediment and PCB Data forthe Housatonic River Between Great Harrington and MACT Border

2-1A

2-2 Sample Types and Specifications 2-2A

2-3 First Ambient Monitoring Survey Results atDivision Street Bridge (Great Barrington)

2-4A

2-4 Water Column PCB Data Used in Statistical Analyses 2-5A1

3-1 Physical Characteristics of Model Segments 3-7A

3-2 Drainage Areas and Long-Term Average Flows 3-7B

3-3 Bed Sediment Characteristics of Model Segments 3-8A

3-4 Solids Settling Resuspension and Burial Rates forModel Calibration

3-10A

3-5 Model Input Flow Data For 18-Month Calibration Period 3-14A

3-6 PCB Concentrations Measured in Water Column ofHousatonic River in Massachusetts and Connecticut During Model Calibration Period

3-15A

3-7 Summary of the Fate of PCBs in the Housatonic Riverfor the Projection Period

3-25A

VI

SUMMARY

51 INTRODUCTION

The Housatonic River Cooperative Agreement between the Connecticut Department of

Environmental Protection (CDEP) and the General Electric Company (GE) specifies that

GE will conduct ambient monitoring of trends in sediment and PCB transport at Great

Barrington Massachusetts and will extend the sediment and PCB fate and transport model

upstream to the same location The objectives of these tasks are (1) sample and analyze for

PCBs at an upstream location where concentrations are above detection limits more

frequently than they are in Connecticut (2) analyze the historical and recent data at Great

Barrington for temporal trends in PCB transport and (3) project PCB concentrations in the

water and sediment in Connecticut by developing a better understanding of temporal trends

in PCB transport at the models upstream boundary

52 AMBIENT TREND MONITORING

Three high-flow surveys were proposed to obtain data needed to investigate temporal trends

in PCB transport at Great Barrington Two events with flows greater than or equal to 1000

cfs were sampled between late March and August of 1991 when weather conditions permitted

the deployment of a sampling crew This report includes only the results from the first survey

in March as the August survey samples have not yet been completely analyzed by ITAS Labs

but will be included in a subsequent report Nevertheless available data on PCBs and total

suspended solids (TSS) concentrations as well as river flow from October 1979 through

March 1991 were statistically analyzed Initial examination of the data indicated that PCB

concentrations which are significantly correlated with TSS and river flow decreased slightly

during this 12-year period However further analysis revealed that the apparent decrease may

be caused by a decreasing trend in river flow over this time period As flows during recent

monitoring at Great Barrington have been generally lower than those of the earliest

monitoring (circa 1979-1982) there is no clear trend in PCB concentrations when river flow

trends are accounted for Moreover differences in sampling methods analytical laboratories

and analytical methods over this period further hamper trend analysis Thus based on the

S-l Lawler Matusky amp Skelly Engineers

existing data firm conclusions cannot be reached regarding PCB trends at this site

Continued high-flow monitoring at Great Harrington as well as at downstream locations

using the same laboratory and consistent sampling and analytical procedures is necessary to

clarify the nature of any temporal trends in PCB transport

53 PCB FATE AND TRANSPORT MODEL

The model of the transport transformation and reactions of PCBs was extended upstream

from the Connecticut-Massachusetts border to Great Barrington The extension of the model

was calibrated by using TSS measurements at the models upstream boundary and at Falls

Village Connecticut over an 18-month period for comparison Although the relatively high

detection limit for PCB analyses of water column samples does not allow precise

quantification of PCB concentrations during the calibration period recent experimental low-

level PCB measurement data provide a check on the PCB transport simulated by the model

The output for the downstream segment of the model extension is consistent with the Falls

Village data which defined the upstream boundary conditions for the previously completed

Connecticut model

The calibration results presented herein are preliminary and will be refined and verified after

additional monitoring data are collected in 1992

54 PROJECTIONS OF PCB CONCENTRATIONS

The expanded Housatonic River model which extends from Great Barrington to the

Stevenson Dam at Lake Zoar was applied to project PCB concentrations in water and

sediment in this portion of the river over a 50-year period A critical input to this model

relates to the upstream source of PCB - ie whether and the extent to which there will be

a change in PCB concentrations at the models upstream boundary Unfortunately as noted

above the monitoring data from Great Barrington and the analysis of historical data do not

allow any firm conclusions regarding this issue Hence at the present time the modeling

projections have been carried out for three hypothetical scenarios

S-2 Lawler Matusky amp Skelly Engineers

bull Reduction in PCB Concentrations at Upstream Boundary This scenario assumes that PCB concentrations at the models upstream boundary will decrease over time Such an assumption is supported to some extent by the data showing that decreases in PCB concentrations in Housatonic River biota in Connecticut have already occurred as well as by regression results from the existing data collected at Great Barrington For this scenario a diminishing source of PCBs is assumed for the upstream boundary and a minimum background PCB concentration is set for upstream and tributary inflows Under this scenario the model projects that a 50 reduction in PCB concentrations in the portion of the river under study will occur in approximately 20 years from 1990 for the water and approximately 25 years for the sediment

bull Constant PCB Concentration at Upstream Boundary This scenario assumes for comparison a constant PCB loading at the models upstream boundary and tributaries over the 50-year period For this scenario the model projections show minimal reduction in the overall PCB concentrations of the water and sediment by the year 2040

bull Reduction in PCB Concentrations at Upstream Boundary and in River Sediments Between Great Barrington and the Connecticut Border This scenario is similar to the first one in that it assumes a diminishing source of PCB inflow at the models upstream boundary and tributaries However it also assumes a 50 reduction in the PCB concentrations of the river bed sediments between Great Barrington and the Connecticut border For this scenario the model projects that the average time to reach an overall 50 PCB reduction in the portion of the river under study would be approximately 20 years for the water and 25 years for the sediments Hence the reduction of PCB in the Massachusetts model bed segments does not have an appreciable effect on the recovery of the river which is predominantly affected by PCB transport at the models upstream boundary

After additional monitoring data are obtained to clarify the temporal trend in PCB

concentrations at the upstream boundary the model can be applied again using better-

supported data to project downstream PCB concentrations in water and sediment over the

50-year period

S5 FUTURE MONITORING

Additional sampling of the water and sediments is needed to verify the model and track the

rivers recovery High-flow sampling of TSS and PCBs should be continued at Great

Barrington as well as at downstream locations The additional monitoring of river sediments


in 1992 required by the Cooperative Agreement will provide additional data for trend analyses

and model verification A proposal for such monitoring is included in this report A data

report on this monitoring of sediment and PCB transport will be submitted to CDEP by midshy

1993 together with recommendations for further evaluation of model parameters and for

additional modeling projections


CHAPTER 1

INTRODUCTION

11 GENERAL BACKGROUND

The Housatonic River Cooperative Agreement between Connecticut Department of

Environmental Protection (CDEP) and the General Electric Company (GE) specifies

activities to be performed by GE to implement the recommendations of the report entitled

Chapter 6 of Housatonic River PCB Sediment Management Study - Program for Monitoring the

Natural Recovery of the River April 1988 as modified by CDEPs review letter of 28 April

1989 Two tasks in the Cooperative Agreement that were performed by Lawler Matusky amp

Skelly Engineers (LMS) are documented in this report

Task IIA Ambient Trend Monitoring - entails monitoring the river and analyzing trends in sediment and PCB transport at Great Harrington Massachusetts

Task III PCB Fate and Transport Model - entails extending LMS PCB fate and transport model of the Housatonic River from the ConnecticutMassachusetts border to Great Barrington Massachusetts

The proposed study plans for these tasks called for integrating the monitoring and modeling

results into a single report Sediment and PCB transport were measured at Great Barrington

Massachusetts during two high-flow events The results of the first survey only are included

in this report as the analytical results for the second survey have not been completed The

trend analysis includes the data collected during the March 1991 survey and prior surveys

dating back to 1979 The need for additional monitoring is addressed as part of our

recommendations

The WASTOX model previously applied to the Connecticut portion of the river has been

enhanced and superseded by a new version known as WASTOX 251 The new version of

the model was adopted for this study to take advantage of certain recent scientific

developments offered in the latter version The effect of changing from the previous to the

1-1 Lawler Matusky amp Skelly Engineers

current version of the model was investigated by comparing model simulations of the

Connecticut portion of the river

The extension of the model upstream to Great Harrington entailed the addition of model

segments that represent the physical and chemical characteristics of the river The model

extension was calibrated by simulating the sediment and PCB transport from the upstream

boundary at Great Harrington Massachusetts to Falls Village Connecticut which is just

downstream of the states border River sampling data collected during an 18-month period

at these two locations compared favorably to the model results The calibrated model was

then used to project PCB concentrations in the river water and bed sediments over the next

50 years The entire study area is shown in Figure 1-1

In addition to the foregoing tasks Task FVC of the Housantonic River Cooperative

Agreement requires GE to submit simultaneously with the report on the PCB fate and

transport modeling a proposal for additional monitoring of river sediments in 1992 for further

calibration and verification of the model This report contains a proposal for such additional

monitoring to obtain data that would assist in resolving modeling uncertainties and would

support the analysis of trends in PCB levels The extended model is a useful tool for tracking

the recovery of the Housatonic River attributable to natural processes as well as any sediment

remediation projects

12 REPORT ORGANIZATION

The three remaining chapters of this report describe the activities conducted under the

monitoring and modeling tasks Chapter 2 presents the data collected during the high-flow

survey at Great Harrington and discusses the analysis of trends in PCB transport Chapter

3 describes the PCB fate and transport model and its application to the extended area of the

Housatonic River Chapter 4 recommends additional monitoring to fulfill the requirements

of the Cooperative Agreement pertaining to model verification and recalibration


MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20

LAWLER MATUSKV A SKELLY ENGINEERS 1 1 fliW EnvtrltximraquonUI Sconce t Engineering Consultant HOUSATONIC RIVER AND WATERSHED AREA FIGURE 1-1

One Blue Hill Plaza bull Pearl River NY 10965

CHAPTER 2

AMBIENT TRENDS

The Housatonic River Cooperative Agreement (HRCA) requires GE to monitor trends in

sediment and PCB transport at Great Harrington Massachusetts Because historical PCB and

total suspended solids (TSS) data already exist at Great Barrington (Table 2-1) these data

have been included in the trend analysis along with data recently collected by LMS This

chapter is organized into two sections

21 - Ambient Trend Monitoring This section includes a description of sampling methods and quality assurance control The analytical results of LMS first survey at Great Barrington are also presented and discussed

22 - Analysis of Ambient Trends at Great Barrington Various trends of PCB vs time TSS and flow are evaluated and discussed


211 Sampling Methods and Quality AssuranceQuality Control

Because high river flow is generally the operative factor in riverine PCB transport LMS

proposed sample collection during three high-flow events (ie gt1000 cfs) During 1991 two

high-flow events were sampled The results for the first event are included in Section 212

The samples of the second survey are currently being analyzed Following is a brief discussion

of sampling methodology and analytical quality assurancequality control (QAQC)

Samples were obtained from the center of flow platform located on the Division Street Bridge

near Great Barrington This is the same platform used by USGS Figure 2-1 provides a

schematic of the sampling location

A Scientific Instruments Inc (SCI) Model 5250 DH-59 Sediment Sampler was deployed for

sample acquisition (Figure 2-2) This sampler is designed to take depth-integrated samples

and can be either manually deployed (hand-line) or deployed with a winch and cable The


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the stream using a hand-operated A-55 Sounding Reel On contacting the streambed the

direction of travel is immediately reversed and the sampler rises towards the surface The 1shy

pt sample bottle is filled to approximately two-thirds of its volume to prevent any collected

suspended sediment from moving out of the bottle when it is filled The sampler is deployed

several times to obtain the required volumes indicated in Table 2-2 which also presents

sample types and collectionpreservation specifications

All sampling equipment was subject to thorough cleaning as specified in LMS QAQC

Manual (see Attachment 1 for a copy of our QAQC manual) Chain-of-custody forms and

request-for-analysis forms are filled out during the survey and submitted along with the

samples to the analytical laboratory (International Technology Corporation Analytical Services

Labs [ITAS])

To evaluate potential contamination from sampling equipment one field blank was taken

from the DH-59 sampler The sampler was thoroughly rinsed with distilleddeionized water

A clean sampler bottle was filled with field blank water supplied by ITAS and inserted into

the sampler The sampler was then positioned so the water poured out through the nozzle

into a clean set of bottles This process was repeated until all the field blank sample bottles

were filled Field blank results are presented in Section 212

ITAS Quality Assurance Manual (QAM) and Standard Operating Procedures (SOPs) address

all of the laboratory QAQC aspects of this project A list of the pertinent portions of these

documents that pertain to this study is included in Attachment 1

Following is a summary of the key QAQC aspects of this project

bull Containers and Preservation All sample bottles are supplied to LMS by ITAS and are cleaned according to SOP No QA841214RO-2 Glassware Cleaning Procedure for Organic Prep All samples to be analyzed for PCBs are stored in amber glass bottles with Teflon-lined caps Storage is at 4degC and extraction must occur within seven days of sampling analysis is required within 40 days of extraction


DH-59 DEPTH INTEGRATING SEDIMENT SAMPLER

The Model 5250 DH-59 Sediment Sampler is a medium-sized sampler designed for use with a cable suspension system The 15-in bronze casting weighs approximately 24 Ibs and is made with a vertical and horizontal tail fin assembly to orient the intake toward the oncoming current An exhaust tube is cast into the body of the sampler and allows air in the sampler bottle to escape downstream as it is displaced by the accumulating sample The DH-59 Sediment Sampler is supplied with two 14 in two 316 in and one 18 in nozzles Shipped in a heavy-duty wood shipping box

Like the DH-48 Sediment Sampler the DH-59 Sediment Sampler is of the depth integrating type it samples the entire time it is submerged Requires 1 -pt bottles

15 in 35 in

LAWLER MATUSKY ft SKELLY ENGINEERS DH-59 DEPTH INTEGRATING I Environmental Science amp Engineering Consultants FIGURE 2-2

SEDIMENT SAMPLER SCHEMATIC One Blue Hill Plaza Pearl River NY 10965

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bull Duplicate Sample Evaluation Duplicate samples are used to determine the precision of the analytical method as well as the percent recovery for the sample matrix One matrix spikematrix spike duplicate (MSMSD) is required per 20 samples If LMS does not take 20 samples during a survey one MSMSD will be provided per survey

bull Spiked Blank Evaluations The observed recovery of the spiked blank vs the theoretical spike recovery is used to calculate the percent recovery value One spiked blank is being performed for each survey

bull Field Blank ITAS supplies LMS with one field blank per survey This blank is passed through the same sampling procedure as the regular water column samples and thus would indicate any sources of contamination from the field procedures

bull Gas Chromatograph Calibration is performed with five concentrations and a blank and is verified with one concentration Acceptable limits are within 10 of the calibration curve Calibration is performed initially and verification is performed on a daily basis

In addition to the above QAQC procedures ITAS uses rigorous data validation and data

reporting procedures Data validation is a systematic procedure in which a body of data must

meet a set of criteria to verify its validity prior to its intended use Checks are made for

internal consistency proper identification as well as transmittal calculation and transcription

errors Final review of the data is performed by the Operations Manager Draft data reports

are checked against the reviewed data to prevent transcription errors

212 Results of Survey(s) at Great Harrington

The surveys at the Division Street Bridge (DSB) in Great Barrington were performed on 5

to 6 March and 19 to 22 August 1991 during high-flow events Figure 2-3 shows the flow

hydrograph for 1991 and also shows the detailed 15-min flows during the two surveys The

first survey started just after the peak flow at approximately 2100 hrs on 5 March 1991 and

continued during the receding limb until 1200 hrs on 6 March The second survey was

conducted during the ascending and receding limbs of the rain event caused by hurricane

Bob For comparison purposes the long-term average flow at Great Barrington is 522 cfs


Survey 1

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LAWLER MATUSKY amp SKELLY ENGINEERS Environmental Scienc 1 Engineering Coraullants FLOW RECORDS AT GREAT BARRINGTON MA RGURE 2-3 One Blue Hill Plaza bull Pearl River NY 10965

Samples for total PCBs dissolved (filtered) PCBs total organic carbon (TOC) dissolved

organic carbon (DOC) and TSS were taken from the center-of-flow platform (DSB-P) which

is the same sampling station used by USGS Connecticut Agricultural Experiment Station

(CAES) and Blasland amp Bouck Results of these samples for the first survey are shown in

Table 2-3 The analytical results from the second survey performed between 19 and 22

August 1991 are not completed yet and will be submitted in a subsequent report Most of

the total PCB results were slightly above the 0065-ug1 detection limit and the two samples

analyzed for dissolved PCB were below the detection limit Comparisons of these total PCB

concentrations are made with historical data in Section 22 in order to identify any trends

related to time flow or suspended solids concentrations

As indicated in Table 2-3 TOC DOC and TSS were also measured The TOC range was

consistently between 2 and 3 mg1 throughout the survey Note that the single DOC value

of 3 mg1 is higher than the corresponding TOC of 2 mg1 As DOC is either a fraction or

all of TOC this single measurement is questionable TOC and DOC analyses will be

repeated in future surveys and we recommend that at least duplicate analyses be performed

for this parameter TOC and DOC measurements are important because their difference

(ie TOC minus DOC) yields the organic carbon of the suspended solids material The

weight fraction of organic carbon of the TSS is the fraction of organic carbon (f^) that is part

of the partitioning equation used in the WASTOX model (discussed in Chapter 3) This

fraction ranges from about 0001 to 01 (Thomann 1987) If the DOC is in fact in the 2 to

3 mg1 range (approximately the same as TOC) then f^ would be very low The TSS

concentrations are consistent with those observed historically at the indicated flows (ie

generally less than 10 mg1) Note the difference in TSS results for the split sample analyzed

by the LMS and ITAS laboratories (sampled at 1200 hrs on 6 March 1991) The reason for

this difference is unknown Also note the unexplained elevated TSS concentration in the

field blank Future sampling events will include some duplicates for TSS to confidently

measure this constituent

Appendix A (separate cover) is a complete copy of the above-referenced analytical results


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22 ANALYSIS OF AMBIENT TRENDS IN THE VICINITY OF GREAT HARRINGTON

221 Introduction

The main focus of Task IIA - Ambient Trend Monitoring is to collect PCB data at Great

Harrington to discern any possible trends in PCB transport with time To date much

information has been collected at Great Harrington and its vicinity The historical data as

well as the current data are evaluated in this section to ascertain whether there are

statistically supported trends that may prove useful in predicting future conditions

Kulp (1991) suggested that there was an apparent decrease in the transport rate of PCBs in

the Housatonic River near Great Harrington He postulated that the decrease may be related

to a decrease in the quantity of PCBs available for transport from upstream sources such as

Woods Pond alternatively the decrease could be due to inaccuracies in the estimate of the

transport rate He concluded that additional data were necessary to determine whether the

transport was actually decreasing The analysis represented in this report combines data from

Kulp (1991) Frink et al (1982) Stewart (1982) Blasland amp Bouck (unpubl data obtained

for GE) and LMS (unpubl data) to reexamine the question of PCB transport-rate changes

over time Table 2-1 (presented previously) summarizes the sources of available data

222 Methods

Statistical analyses were conducted using Number Cruncher Statistical System (NCSS)

Version 503 (Hintze 1990) Measures of total PCB (ug1) instantaneous streamflow (ft3s)

total suspended sediment (mg1) and location (river miles from Long Island Sound) as well

as collection date were used PCB values reported as nondetected (ND) were assumed to

be (Detection Limit)2 Only samples with instantaneous streamflow andor suspended

sediment values were used in the analysis (as opposed to replacing missing observations with

average daily flow values) (Table 2-4)


TABLE 2-4 ( of 3)

WATER COLUMN PCB DATA USED IN STATISTICAL ANALYSES

Date of Sample Time Site

RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB

Instantaneous Streamflow

Suspended Sediment Source1

Collection (bis) Number Sound) ltugl) (ugrt) (ug1) (cfe) (mgI) of Data

100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C

JA = Great Bamngton (Fnnk et al 1982) F = Ashley Falls (Kulp In Press) B = Great Bamngton (Kulp In Press) G = Canaan (Kulp In Press) C = Great Bamngton (Biasland amp Bouck unpubl) H = Falls Village (Kulp In Press) D = Great Bamngton (LMS unpubl) I = Ashley Falls (Stewart 1982) E = Great Bamngton (Stewart 1982)

221 jtg1 due to laboratory contamination Not used for statistical analyses

Note Numbers in ( ) are detection limit For Fnnk data (Source A) detection limit is assumed equal to 0 1 jig1 since no value given in source document

2-5A1

TABLE 2-4 (Page 2 of 3)



River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB



Collection (hrs) Number Sound) (ugfl) ltugi) (ugI) (cfs) (mgft) of Data

030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H

A = Great Bamngton (Fnnk et al 1982) F = Ashley Falls (Kulp In Press) B = Great Bamngton (Kulp In Press) G = Canaan (Kulp In Press) C = Great Bamngton (Blasland amp Bouck unpubl) H = Falls Village (Kulp In Press) D = Great Bamngton (LMS unpubl) I = Ashley Falls (Stewan 1982) E = Great Bamngton (Stewart 1982)

Filterable and nonfilterable PCB data are measured while Total PCB is calculated Total PCB (jjg1) = Filterable PCB (Mg1) + Nonfilterable PCB (jigI) All ND values were added as 0 to obtain Total PCB

Note Numbers in ( ) are detection limit For Fnnk data (Source A) detection limit is assumed equal to 0 1 (tgl since no value given in source document

2-5A2



Dale or River Mile Filtered ToUl Nonfiltered Instantaneous Suspended Sample Time Site (From LI PCB PCB PCB Streamflow Sediment Source1

Collection (hrs) Number Sound) ltugl) ltugl) (ug1) (cts) (mg1) of Data

I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350

A = Great Bamngton (Fnnk et a l 1982) F = Ashley Falls (Kulp In Press) B = Great Bamngton (Kulp In Press) G = Canaan (Kulp In Press) C = Great Bamngton (Blasland amp Bouck unpubl) H = Falls Village (Kulp In Press) D = Great Bamngton (LMS unpubl) I = Ashley Falls (Stewart 1982) E = Great Bamngton (Stewart 1982)

3Filterable and nonfilterable PCB data are measured while Total PCB is calculated Total PCB Filterable PCB (tg1) + Nonfilterable PCB (Mgl) All ND values were added as 0 to obtain total PCB

Note Numbers in ( ) are detection limit For Fnnk data (Source A) detection limit is assumed equal to 0 1 jigl since no value given in source document

2-5A3

223 Results

The first step in the data analysis was to plot total PCB concentration river flow and TSS

concentration vs collection date (Figure 2-4) Additionally plots of total PCB and TSS vs

flow (Figure 2-5) and total PCB vs TSS (Figure 2-6) were prepared

The next step was to test for significant changes in PCB levels over time The null

hypothesis

HQ- PCB concentrations have remained constant over the period 1979-1991

was tested using ordinary least squares regression analysis The analysis was conducted using

(1) data from only the Great Barrington location ( of samples [n] = 46) and (2) data from

all locations ie Great Barrington Ashley Falls Cannan Falls Village (n = 68) The

dependent variable was PCB concentration and the independent variable was the Julian date

(DAY) In the analysis using the entire data set the effects of location were removed by

including river mile (RM) in the statistical model as a second independent variable The

statistical parameter results are included in Attachment 2

These results suggest that the null hypothesis should be rejected and that PCB concentrations

apparently have declined over the period 1979 through 1991 In both analyses there was a

significant downward trend in PCB concentrations associated with DAY However in neither

case did DAY explain a great amount of the variance1 For the Great Barrington station

alone DAY explained only 1179 of the total variance for all stations (with location effect

removed) DAY explained only 892 of the total variance This suggests that although

DAY may be a statistically significant factor in explaining PCB concentrations it is not of

primary importance Other factors weigh more heavily in determining the observed PCB

concentration

Variance is a measure of dispersion or spread of data around the mean


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TSS Dependence on Flow

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E Agfaf

0 1000 2000 3000

Kay

A - Great Barrington (Frink et al 1982) B - Great Barrington (Kulp unpubl) C - Great Barrington (Blasland amp Bouck D - Great Barrington (IMS unpubl) E - Great Barrington (Stewart 1982)

LAWLER MATUSKY ft SKEUY ENGINEERS 1 1 1( H Environmental Science raquo Engineering Contuttam


H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)

F - Ashley Falls (Kulp unpubl) G - Canaan (Kulp unpubl)

unpubl) H Falls Village (Kulp unpubl) 1 - Ashley Falls (Stewart 1982)

See Figure 1-1 for station locations

TOTAL PCB AND TSS DEPENDENCE ON FLOW FIGURE 2-5 IN UPPER HOUSATONIC RIVER

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In an effort to isolate some of the other influences on PCB concentration stepwise multiple

regression analysis was used Included in this analysis were TSS and river flow (FLOW)

Because PCB is adsorbed by sediment particles samples with higher concentrations of TSS

may have higher levels of PCB Increased river flow may increase PCB concentrations by

several mechanisms it may uncover previously buried PCBs and resuspend them in the water

column or it can increase the incoming suspended sediment load which in turn may have

adsorbed PCBs

The statistical parameter results of the stepwise multiple regression analysis are included in

Attachment 2

Following are the regression equations that result from multiple regression analysis using the

Great Barrington data only

PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where

PCB = total PCB concentration (ug1)

TSS = total suspended solids concentration (mg1)

Day = Julian day referenced to Jan 1 1900

Equation 2-2 results in negative PCB concentrations when projected beyond 67 years from

1991 An attempt to rectify this obvious limitation as well as to reduce variance was made

by performing a natural log-transformation of the data Following is the natural log-

transformed regression equation

In (PCB) = 3147795 - 0000181 (Day) (23gt


Equation 2-3 does not predict negative concentrations in the future and as will be shown in

Chapter 3 gives reasonable estimates of the currently observed PCB concentration at Great

Harrington

This analysis also indicated that TSS (and RM in the all location data set) had a highly

significant effect on the regression In the Great Harrington only data set 6154 of the

variance in PCB concentrations can be explained by TSS alone In the total data set after

removing the effects of location (RM) TSS explained 2155 of the variance in PCB

concentration The remaining variance in both data sets is unexplained (ie it may be due

to combinations of variability in other parameters inter-laboratory differences and other

unknown influences) Importantly DAY was no longer a significant effect in both data sets

after removing the effect of TSS This indicates that the significant relationship between

DAY and PCB concentration that was apparent in the first analysis was likely due to

underlying differences in TSS Therefore based on current data we cannot conclude that

there has been any significant temporal trend in PCB levels over the period 1979 through

1991

As described above TSS may be influenced by river flow Using only the Great Harrington

data the simple correlation coefficient (r) between FLOW and TSS was 05156 (n=36

P=00013) and the partial correlation (removing RM effects) for all locations was 06707

(n=51 Plt00001) Because TSS levels (and subsequently PCB concentrations) in samples

are related to river flow it is worthwhile to investigate the extent to which river flows may

have influenced sampling TSS and PCB concentrations In other words could TSS have been

sampled nonrandomly over the period thereby giving the impression of PCB change over

time

To investigate the influence of river flow the average monthly flows were plotted for the

period 1913-1991 (Figure 2-7) the plot revealed no obvious long-term trends An expanded

view of the 1978 through 1991 period (also in Figure 2-7) suggests somewhat lower flows

after 1986 This is further confirmed by an examination of peak daily flows during high-flow

months March values were used for this analysis (Figure 2-8) Although April is the month

of highest flow complete data for April 1991 were not available Peak daily flows during


1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992

LAWLER MATUSKV laquo SKELLY ENGINEERS i Environmental Scianc Engineering Contulurrtt HOUSATONIC RIVER AVERAGE FIGURE 2-7 One Blue Hill Plaza bull Pearl River NV 10965 MONTHLY FLOW AT GREAT BARRINGTON MA

degP M UJ tr D O E

CC Ul gt CC o

1 o z lt

go$2 i-JL Otradez at pound

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bullfcCO lt

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March of eight of the last 11 years (1981-1991) were below the long-term average while the

1979 (6500 cfs) and 1980 (4060 cfs) peaks were among the highest flows on record Daily

flow-frequency histograms and cumulative frequency distributions by month for the period

1913 through 1988 (Figures 2-9 and 2-10) indicate that peak March flows from the most

recent years 1989 (1260 cfs) and 1991 (1330) are exceeded approximately 20 of the time

The 1979 March peak flow is exceeded less than 02 of the time This pattern of high flow

(with presumably higher TSS and PCB) in the late 1970s and early 1980s coupled with low

flows in the late 1980s could induce an apparent trend towards decreasing PCBs over time

Examination of Great Barrington data only in Figure 2-4 suggests that there may be a trend

for lower flows to be sampled during more recent times Flows sampled during 1979 through

1982 were higher on average than those sampled during 1988 through 1991 The relatively

few high flows sampled during the middle portion of the period (ie 1983-1987) do not

substantially influence this overall decreasing trend In view of these flow data firm

conclusions cannot be reached based on current information regarding the long-term trend

in PCB concentrations over the period analyzed

Another method for analyzing temporal trends in PCB transport is to separate the data base

into TSS or flow classes (eg ND to 2499 mg1 25 to 4999 mg1 etc or 100 to 299 cfs 300

to 500 cfs etc) The resulting trend analysis would then reflect the various flow regions (eg

low medium and high) within which PCB transport occurs Although data throughout the

period are not available for a full range of flows and TSS there are low TSS (ie lt 25 mg1)

data for 1979 through 1991 These data do not suggest a temporal trend in PCB

concentrations As high flows are the operative condition for PCB transport this method of

TSS or flow classes requires additional measurements during high flow and TSS conditions

As more data are collected during future monitoring efforts this analysis will be performed

Another source of potential error in long-term trend analyses of this type must also be

considered Over time analytical laboratories analytical methods and sampling methods

change In this study data presented by Frink et al (1982) were analyzed by the USGS

Central Laboratory the more recent samples by LMS and Blasland amp Bouck Engineers were

analyzed by IT AS laboratory A difference in PCB levels that could possibly arise over time

due to this change in laboratories cannot be disregarded In addition laboratory detection


January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)

LAWLER MATUSKY SKELLY ENGINEERS Environmental Science raquo Engineering Corautann DAILY HOUSATONIC RIVER FLOW-FREQUENCY RGURE 2-9 One Blue HW Plaza bull Pearl River NY 10965 HISTOGRAMS AT GREAT BARRINGTON MA

200 400 600 800 1000 12OO 1400 1600 1800 2OOO 2200 2400 2600 2600 3OOO 1OO 3OO 5OO 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)

-bull- JAN --t- KB bull- MAR

bullamp APR -X- MAY -A- JUN

0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)

bullm- JUL --f- AUG bulllaquo- SEP

-B- OCT -X- NOV -A- DEC

LAWLER MATUSKY t SKELLV ENGINEERS CUMULATIVE FREQUENCY DISTRIBUTIONS 11 k i W Envifanmnul Sdwm t EnglnMrlng ConcuKantt FIGURE 2-10 OF HOUSATONIC RIVER DAILY FLOW AT GREAT

One Blue Hill Plaza bull Peart River NY 10965 BARRINGTON (1913-1988)

limits of PCB may also limit the quantification of exact PCB concentrations and hamper the

trend analysis this was the case in the Connecticut portion of the Housatonic River (LMS

1988)

Thus any conclusions regarding PCB trends based on this historical data set would be of

questionable validity Continued monitoring at Great Barrington using consistent laboratories

and analytical procedures should help clarify the nature of any temporal trends in PCB

transport


CHAPTER 3

PCB FATE AND TRANSPORT MODEL

31 DESCRIPTION OF WASTOX MODEL

The model applied to this study of the Housatonic River WASTOX2 (Version 251) is a

revised version of the modeling framework WASTOX developed at Manhattan College for

the US Environmental Protection Agency (EPA) (Connolly and Winfield 1984) The

original Version 10 of WASTOX was used for the Chapter 6 report (LMS 1988)

The model was developed to (1) provide a tool for performing waste load allocations and

(2) evaluate how long it would take a contaminated water system to recover to some specified

level The models latter function is the primary application for this study The results of

these projections will be discussed in Section 34

The essential changes between WASTOX (Version 10) and the current WASTOX2

(Version 251) are as follows

bull Version 251 includes an option to force a constant bed solids concentration given the solids settling and resuspension rates specified in model input by internally computing the solids burial flux which can therefore vary with time Version 10 which required a constant burial rate as model input caused a bed solids concentration drift which is not generally realistic

bull Version 251 uses a partition coefficient calculation that conforms to the Particle Interaction Theory (Di Toro 1985) This empirically-deduced equation accounts for changing partitioning in the water column as a result of increased or decreased particle interactions a function of solids concentration

bull Version 251 uses step input functions as compared to linear interpolation in Version 10 This modification allows WASTOX2 to be executed more efficiently

The model is used to determine the fate of the contaminant by considering the processes of

transport transfer and reaction as defined below

3-1


bull Transport is the physical movement of the chemical caused by the net advective movement of water mixing and the scouring and deposition of solids to which the chemical may be adsorbed It is specified by the flow and dispersion characteristics of the natural water system and the settling velocity and resuspension rate of the solids in the system

bull Transfer is the movement of the chemical between the air water and solid phases of the system It includes the processes of volatilization adsorptiondesorption and diffusion

bull Reaction is the transformation or degradation of the chemical It includes biodegradation and the chemical reaction processes of photolysis hydrolysis and oxidation

The general expression for the mass balance equation about a specified volume V is

(31 V = J + ER + EJ + EWdt

where

c = concentration of chemical (eg PCBs)

t = time

J = transport through the volume

T = transfer from one phase to another

R = reactions within the volume

W = wasteload inputs

The model is assumed to be one-dimensional along the longitudinal axis of the Housatonic

River however it represents each water segment overlying a segment of active bed sediment

River flow advects water through the overlying water segments and is the driving force for

resuspension of solids from the bed segment We assume that there is no direct advection

from one bed sediment segment to another ie bedload is negligible

The total concentration of PCBs consists of the dissolved and paniculate components


(3-2) ct = 4gt cd + m cp

where

c = total concentration of PCBs (ML3)

4 = porosity [L3 wateiL

3 (sollds + waler)] (ie void space)

cd = water-specific concentration of dissolved PCBs (ML3)

m = solids concentration (ML3)

c = solid-specific concentration of particulate PCBs (MM) [eg ug of PCBg of solids]

Note that porosity (ltpound) is required to add these two forms (ie dissolved and particulate

concentration) to obtain the total concentration The subscripts t d and p refer to total

dissolved and particulate PCB respectively

For the water column where ltfgt is essentially equal to 1 no porosity correction is required

however for the sediment where ltpound is typically about 7 - 8 this correction is important

For PCBs in natural water systems the sorption isotherm is assumed to be linear and the

relationship between the particulate and dissolved components is governed by the partition

coefficient (If) with units (L3M)

f

The partition coefficient describing the linear isotherm at a fixed solids concentration has

been shown for numerous chemicals to depend on the concentration of adsorbing solids as

Units are denoted as M = mass L = length T = time


a result of interactions between the moving solid particles The following empirical equation

describes this effect (Di Toro 1985)

U = -i- (3-4)

where

m = concentration of solids (ML3)

flc = limiting partition coefficient at high solids concentration w)

vx = dimensionless reaction rate constant (ratio of adsorption reaction rate constant to particle interaction induced desorption rate constant) commonly equals 14

For organic chemicals 1fc has been shown to be approximately equal to the product of the

fraction organic carbon (f^) of the solids and the octanol-water partition coefficient

of the chemical

where

=foe Wpoundight fraction of organic carbon of the total solids concentration

The model uses this solids-dependent partitioning to compute the particulate and dissolved

components of PCBs in the water column In the sediment a constant partition coefficient

defined by f^ and K^ is used The previously applied WASTOX (Version 10) used an

equation for the partition coefficient as a function of the solids concentration in both the

water column as well as the bed As the current WASTOX2 version uses solids dependent

partitioning in the water column only the change in the partition coefficients between the

previous and current model applications is investigated in Section 33

The bulk fraction of PCBs in the dissolved phase fd is expressed as the water-specific

concentration of dissolved PCBs and the porosity based on the two previous equations


cd- _ 4gt d

c lt|gt + Urn

The bulk fraction of PCBs in the particulate phase f is similarly expressed as

cf _ Urn (3-6) = c

As the wasteload inputs are assumed to be zero at present the mass balance equation for

PCBs in a water column segment is then written as

+ v u bull

where

first subscripts t p or d denote total particulate or dissolved phase second subscripts w or b denote water or bed segment

V = segment volume (L3)

Q = river flow (L3T)

x = longitudinal distance (L)

E = dispersion coefficient (L2T)

vs = solids settling rate (LT)

A = surface area between water and sediment segments (L2)

vu = solids resuspension rate (LT)

kt w = transferreaction rate coefficient (1T)


The five terms of this equation represent advection dispersion settling resuspension and

transferreaction of PCBs respectively

The bed sediment is modeled explicitly as an active layer of sediment of some prescribed

depth (h) below which is the model boundary with the inactive bed The active layer is

assumed to be at equilibrium so that a solids mass balance states that the net settling and

resuspension flux at the sediment-water interface is equal to the burial flux of sediment from

the active to the inactive layer

0 1 m v w ) (3-8) = lty laquo - shy

where

vb = solids burial rate (LT)

Assuming the depth of the active sediment layer is constant and the long-term trend is an

accretion of bed sediments (at least in the lakes and impoundments) the solids burial rate

may be viewed as the rate at which the sediment water interface moves upward away from

a fixed datum such as bedrock

The fluxes of PCB associated with the active segment are shown schematically in Figure 3-1

and expressed by the equation

(V (39) V

dt

DA ff ~~T Vd

where

D = diffusion rate coefficient (L2T)


f Paniculate PCB flux Dissolved PCB flux

PROCESS

copy DEPOSITION OF SOLIDS

copySCOURING OF SOLIDS

copyNET SEDIMENTATION OR BURIAL

copyDFFUSION OF DISSOLVED CHEMICAL

WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw

h (f dbc tb -f dwc tw

LAWLER MATUSKV laquo SKEUY ENGINEERS Enyironnwiul Scmm laquo Engineering Contutantt FLUXES OF PCB ASSOCIATED RGURE 3-1 One Blue Hill Plaza bull Pearl River NY 10965 WITH THE BED SEDIMENT

32 PARAMETER EVALUATION

The model parameters defining the rates of physical transport chemical transfers and

reactions are evaluated specifically for the Housatonic River

321 River Segmentation and Hydrology

The model used for the Chapter 6 report extended from the ConnecticutMassachusetts

border (mile point [MP] 831) to the Stevenson Dam (MP 196) For the purposes of this

work the model was extended to Great Harrington Massachusetts (RM 1061) using four

additional segments Figure 3-2 shows the water column segmentation of the new model

The model divides the river into segments each with similar physical and hydrological

characteristics (Table 3-1) The water segments are numbered from 1 for the segment with

the Division Street Bridge (Great Harrington) at its upstream end to 11 for the segment with

the Stevenson Dam at its downstream end Active bed-sediment layer segments below the

water segments are numbered from 12 for the bed segment below water segment 1 to 22

for the bed segment below water segment 11 The physical characteristics of the model

segments were evaluated based on available data in Frink et al (1982) and QLM (1971)

Table 3-2 shows observed long-term average flows in the study area as well as those estimated

by the indicated upstream drainage areas Figure 3-2 also shows the average flows associated

with each segment as well as tributary and additional flows to segments not associated with

the named tributaries Tributary and drainage area flows to the Housatonic River are

modeled as inflows to the upstream end of the appropriate segments

322 Bed Sediment Characteristics

Model segments 12 through 22 represent the active bed sediment layers beneath the 11 water

segments Segments 12-15 are in Massachusetts and segments 16-22 are in Connecticut The

Milepoint system adopted from Frink et al (1982)


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TABLE 3-2

DRAINAGE AREAS AND LONG-TERM AVERAGE FLOWS

DRAINAGE AREA AVERAGE FLOW STATION MILE POINT (Sq miles) (cfs)

Great Harrington MA 1004 280 530 MA-CT state line 831 545 910

Blackberry River 820 48 74

Falls Village Res 812 580 990 Salmon Creek 790 294 485 Hollenbeck River 773 24 40

Falls Village Dam 759 635 1087

Bulls Bridge Res 577 745 1278 Bulls Bridge Dam 531 791 1353

Ten Mile River 521 203 303

Gaylordsville 506 993 1701 Still River 406 70 116

Lake Lillinonah 401 1224 1980 Shepaug River 318 133 236

Shepaug Dam 296 1392 2380 Pootatuck River 272 242 48 Pomperaug River 261 751 128

Stevenson Dam 195 1544 2620

USGS daily flow data available

3-7B

TOC sand content bulk density and PCB concentration data from Frink et al (1982) and

Stewart Labs (1982) are summarized in Table 3-3 The sediments in segment 12 (Great

Harrington) are most similar to the sediments in the Connecticut riverine segments and the

sediments in segments 14 and 15 (the last two sediment segments in Massachusetts prior to

Connecticut border) appear to be as fine as the Connecticut lake sediments A generally

decreasing trend in PCB concentrations from Great Harrington to the Connecticut lakes is

discernible

323 Settling Resuspension and Burial

The solids settling rate in the Massachusetts segments were assumed to be approximately the

same as that in the Connecticut riverine segments Settling rates in Connecticut were

originally based on Stokes relationship and were then adjusted slightly during the calibration

process Thus the settling rates in the extended riverine segments 1-4 in Massachusetts were

set to an average of the rates in Connecticut riverine segments 5 7 and 9 which equals 6

ftd

Initial estimates of resuspension in the four Massachusetts segments were made assuming a

long-term equilibrium between solids settling and bed sediment erosion such that the average

resuspension solids flux approximately equals the settling solids flux However these

estimates which were made using the same techniques used in Connecticut (LMS 1988) did

not attain the relatively high TSS values measured at Falls Village It was postulated that this

observed increase in solids loading between Great Barrington and Falls Village is due mainly

to the different river morphology in segments 3 and 4 as compared to the typically riverine

segments 1 and 2 within and just below Great Barrington As clearly indicated by the 75-min

USGS topographical maps of the study area the river changes in segments 1 through 4 from

straight steep-banked and fast to a more sinuous shallow river with significant oxbows

Increased flows in this area would tend to cover more of the shallow banks (ie flood plains)

causing the previously deposited solids to resuspend It is not uncommon for these types of

rivers (ie with shallow flood plains) to carry large sediment loads during storms The

following factors are supportive of this hypothesis


~ laquo fl C

o B v-

t ~ Q r ^ r ^ - H v o o o r ~ - v o w ^ r f )

- H - H O C J c s d d d o c J c J d

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tlaquo

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^H + ^^ CO o 5 H Z

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3-8A

1 The bed sediments in segments 3 and 4 have approximately half the average bulk density of those in segments 1 and 2 This implies a bed more prone to resuspension due to either less compaction of the sediment (ie greater porosity) or lower specific gravity of the solids

2 During our reconnaissance of the study area agricultural activity along the banks of the Housatonic was noted This type of activity can result in increased solids loads due to erosion from tilled fields

Thus at normal dry-weather flows resuspension rates are calculated in the same manner as

was done in Connecticut For flows above average for these segments (approximately greater

than 700 cfs) twice this resuspension rate is used as model input This adjustment was tested

during the calibration process Figure 3-3 shows the applicable flow vs resuspension rates for

Great Harrington (segments 1 and 2) and for segments 3 and 4

The net result of increasing resuspension in segments 14 and 15 is that the bed is subject to

long-term scour or negative deposition which is consistent with the observation of oxbows

and cutoffs in part of segment 3 and all of 4 That is the formation of an oxbow or cutoffs

requires the cutting of a new channel which in effect results in increased sediment loads

downstream

This event-specific resuspension behavior was not observed in Connecticut In fact

suspended solids concentrations attenuate as they move in a downstream direction toward

Connecticut A possible explanation for this is that the Housatonic River generally widens

and deepens in the downstream direction in Connecticut thus slowing the river velocity

which is the primary driving force behind resuspension Another possible explanation for the

noted attenuation in solids from the MassachusettsConnecticut line to Stevenson Dam as

opposed to the increase in solids load between Great Barrington and Falls Village is differing

land use As discussed above the increased solids load is postulated to occur in part due to

increased resuspension solids fluxes In addition to this mechanism increased solids loads can

also occur from tributaries as well as portions of the Housatonic directly which drain

agricultural land uses As is discussed further in Section 327 increased solids loads in the

two tributaries entering segments 3 and 4 is assumed (no tributary solids data are available

for these) during flow events greater than 700 cfs in the main stem of the Housatonic River


Great Barrington

2000 2500 9000

Midpoint of Flow Class (cfs)

Seg s 3 amp 4 based on Falls Village TSS

600 1SOO 2000 ylty) 3000 Midpoint of Flow Class (cfs)

LAWUER MATUSKY A SKELLY ENGINEERS l| f [1 Environmental Sctonc Engineering ContutanM DEPENDENCE OF RESUSPENSION FIGURE 3-3

RATE ON FLOW One Blue Hid Plaza bull Pearl River NY 10965

These tributary loads however contribute a relatively small loading to the main stem flow

because of their relatively small drainage areas

Because cores were not analyzed for radioactive tracers in the Massachusetts portion of the

Housatonic River no analytical data were available to evaluate sediment burial rates

Consequently it was postulated that segments 1 and 2 which are typically fast-moving riverine

segments had generally minimal deposition similar to riverine segments 5 7 and 9 in

Connecticut Thus in these segments the resuspension and settling rates as calculated

previously were slightly adjusted to yield minimal deposition rates In segments 3 and 4

which is a meandering and oxbowed section of the Housatonic River the bed sediment

depositional or scouring behavior is less known Consequently in these segments no

calibration adjustments were made to force deposition or scour to a known value The

model-calculated deposition or scour is based on the net solids flux balance between settling

and resuspension Table 3-4 shows the model input settling and resuspension rates as well

as the model-calculated sediment depositionscour rates and the intended estimated values

based on depositional trends evaluated for similar types of segments in the Connecticut

portion of the Housatonic River as discussed in the Chapter 6 report (LMS 1988)

324 Sediment-Water Partitioning

The transfer of PCBs between the particulate (sorbed) and dissolved phases is analyzed by

a partition (a phase distribution) coefficient as defined in Equation 3-3 The model assumes

that adsorption-desorption are reversible and instantaneous although PCBs may have a

resistant component that is not readily desorbed (Di Toro 1985) For hydrophobic organic

pollutants such as PCBs the partitioning can be estimated a priori based on the chemicals

affinity for water and the octanolwater partition coefficient (K^) In natural water bodies

organic matter is the dominant sorbent and partition coefficients indexed to carbon content

(K^) are relatively independent of other sediment characteristics (eg geographical origin

of soil) (Karickhoff 1984) Experimental data for a set of 22 hydrocarbons and chlorinated

hydrocarbons yield this relationship with r2 = 0986 (EPA 1983)


TABLE 3-4

SOLIDS SETTLING RESUSPENSION AND BURIAL RATES FOR MODEL CALIBRATION

MODEL ESTIMATED SURFACE SETTLING RESUSPENSION CALCULATED BURIAL DEPTH OF

SEGMENT AREA RATE RATE BURIAL RATE RATE ACTIVE BED NUMBER (acres) (fld) (InJyr) (injyr) (IHLJT) (In)

112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29

Estimated buna) rates for Connecticut segments are taken from LMS (1988) and were specified as model input Estimated bunal rates in Massachusetts segments indicated equilibrium of resuspension and settling in segments 12 and 13 and net erosion in segments 14 and 15 These estimates were not needed as model input but were calculated based on resuspension and settling rales

3-10A

Log KK = 0942 log K^ - 0144 (3-10)

Based on log K^ estimates for Aroclors 1254 (603 630 604) and 1260 (611 714 715)

respectively (EPA 1987) a log K^ of 65 was estimated for total PCBs in the Housatonic

River and a log K^ of 598 is computed The classical sediment-water partition coefficient

(11) is equal to the K^ times the fraction organic carbon content (f^)



a result of interactions between the moving solids particles (Connolly 1980 OConnor and

Connolly 1980)

The previously defined Equation 3-4 (Di Toro 1985) describes this effect which is applicable

only to the water column For TSS values ranging from approximately 1 to 50 mg1 and f^

of 3 the solids-dependent partition coefficient ranges from approximately 2 x 104 to 9 x 104

Ikg At the present time there is no general theory or empirical relationships that are

available to estimate stationary bed sediment partition coefficients at solids concentrations of

gt 100000 mg1 (Thomann 1987) Thus the WASTOX2 model uses a constant partition

coefficient for bed sediments of

IF11 = K f (3-11) c aw Joe ^

The resulting range of bed partition coefficients (Hc) for the f^ values ranging between 1 and

9 is 31 x 104 to 28 x 105 Ikg

325 Bed Sediment-Water Column Diffusion

The diffusion of dissolved PCBs between the bed sediment and water column depends on the

molecular diffusion coefficient of PCBs in water and the porosity of the bed sediment


According to Chapra and Reckhow (1983) the diffusion coefficient (the parameter D in

Equation 3-9) for PCBs in the Housatonic River is estimated at 6 x 106 cm2sec The

significance of diffusion as a flux of PCB is described in Section 33 in discussions on model

sensitivity

326 Volatilization

The two-phase resistance theory is used by WASTOX to simulate the volatilization of a

toxicant The value of Henrys constant for PCB is 71 x 10~3 atm m3mole (Mills et al 1982)

The transfer of PCBs is similar to dissolved oxygen gas transfer in that the liquid phase

resistance controls The model evaluates the PCB volatilization rate coefficient analogously

to the reaeration rate coefficient The volatilization rate coefficient averages about 52 ftday

The significance of volatilization as a flux of PCB is described in Section 33 in discussions

on model sensitivity

327 Upstream and Tributary Suspended Solids and PCBs

Suspended solids data collected by USGS at Great Barrington for the 18-month period from

April 1979 through September 1980 (presented in Frink et al 1982) were used to produce

the models upstream boundary for model calibration No data were available on the

suspended solids load in the tributaries of the Massachusetts segments The bed sediment

characteristics of segments 12 and 13 (shown in Table 3-3) are similar to those of Connecticut

segments 16 17 and 18 so the tributaries of segments 1 and 2 were assigned the same

suspended solids concentration (178 mg1) as that previously determined for segments 5 6

and 7 (LMS 1988) However the bulk densities calculated for segments 14 and 15 showed

that their bed sediments are finer than those of the upstream segments and a field

reconnaissance showed that the land around segments 14 and 15 is more agricultural than that

around segments 12 and 13 Based on this information an increase in suspended solids was

postulated during high-flow events and a TSS concentration of 70 mg1 was assigned to

tributaries into segments 3 and 4 when the Housatonic River flow exceeded 700 cpounds During

flows of less than 700 cfs those tributaries were assigned the base value of 178 mg1


The PCB concentration of the upstream boundary was calculated from Equation 2-1 which

relates PCBs to total suspended solids (TSS) The reason for not using only Frink et al

(1982) data for the model calibration period is that the analytical techniques have been

improved since 1979 and 1980 As no clear temporal trend in PCB concentrations were

found in our statistical analyses a PCB-solids relationship based on all data collected at Great

Barrington provides the most reliable means of evaluating the PCB concentration at the

upstream boundary The tributaries to the Massachusetts segments were assigned the same

PCB concentration (0008 ug1) as that estimated for the Connecticut tributaries in previous

work (LMS 1988) as no additional data were available

33 MODEL CALIBRATION

Model calibration is the process of testing the model for accuracy by adjusting parameters

within reasonable bounds to attain agreement with field data The parameters were

developed from available data on sediment and PCB transport in the study area as described

in Section 32 The model input file is included in Attachment 3 The model simulated the

18-month period from April 1979 through September 1980 as the most intensive sampling of

suspended solids and PCB concentrations was conducted then (Frink et al 1982) Model

results were compared with the available field data

The segments of the river in Connecticut were calibrated in previous work presented in the

Chapter 6 report (LMS 1988) The calibration of the extended model entailed tuning model

parameters for the four Massachusetts segments As TSS and PCB concentration data

collected at Falls Village are used for this calibration the first two Connecticut segments are

included in these simulations to terminate the model at the sampling location to ensure

consistency with the previously calibrated portion However all model parameters in these

two segments remain unchanged from the 1988 model Thus all parameter tables and

calibration figures in this section will make reference only to segments 1 to 6 in the water

column and segments 12 to 17 in the bed

Another aspect of the model testing performed is a comparison of the new version of

WASTOX with the original version applied previously The comparisons involved the


Connecticut model segments that constituted the 1988 model The changes in model

formulation that are described in Section 31 entailed two model parameters (1) sediment

burial rate and (2) PCB partition coefficient The effect of the first parameter is described

in Section 331 the effect of the second parameter is described in Section 332

River flows for the 18-month period were based on average 1979-1980 monthly flow data

from three USGS gaging stations at Great Harrington Salmon Creek and Falls Village Dam

(included in Table 3-2) Segment flow balances were calculated by estimating ungaged

tributary and mainstem flows from drainage areas and observed long-term average flows

(Table 3-5) All flow and upstream boundary data were input to the model at 30-day intervals

and were used in model computations as step functions with a constant value assigned to

each month

The model results presented graphically for all segments in an upstream to downstream

sequence are spatially continuous that is only the concentrations at the upstream boundary

of the first segment were set as input Concentrations of all other segments were computed

The displayed model results are the outcome of certain adjustments to the initial parameter

evaluations described in Section 32 Sensitivity analyses were performed to determine the

degree of influence that certain parameters have on resulting suspended solids and PCB

concentrations

331 Solids

Suspended solids concentrations measured during the 18-month period at Great Harrington

(MP 1061) and Falls Village Dam (MP 759) were used for comparison with model results

A depth-integrated sample was collected daily and analyzed for suspended solids

concentrations at those two locations Figures 3-4 and 3-5 present the suspended solids

calibration results for all segments The data points plotted in segments 1 (Great Harrington)

and 6 (Falls Village Dam) are monthly averages of the daily TSS measurements The

segment 1 graph shows the inputted upstream boundary labeled as observed at Great B and

the model result for segment 1 In segments 3 and 4 the increased suspended solids

concentrations at the peaks in May 1979 September to November 1979 and March to April


QuM

9S S

8

S 8

Q O

su

O H

e 9SE i i i i 8 Nshy

(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M

raquoshy CM to in ltD

1 = C CQ C S

c trade bull J sect S -1 c = a ^

CD O O iZ

0

Segment 5

BO

so

70

10

Apr-79 Jun-79 Aug-79 Oct-78 Dlaquoc-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-80 Date

bull Model Observed Andrus

Segment 6

100

90

I

laquo 50

Apf-79 Jun-79 Aug-79 Od-79 Dc-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-BO Date

bull Model Observed Falls V + Observed Canaan

LAWLER HATUSKV SKEUY ENGINEERS Envwonmwiul Scnnc t Englnaring Conturlanta SUSPENDED SOLIDS CALIBRATION FIGURE 3-5 One Blue Hill Plaza bull Pearl River NY 10965 SEGMENTS 5 AND 6

TABLE 3-6

PCB CONCENTRATIONS MEASURED IN WATER COLUMN OF HOUSATONIC RIVER IN MASSACHUSETTS AND CONNECTICUT DURING MODEL CALIBRATION PERIOD

PCB CONCENTRATION

STATION DATE TIME TOTAL

laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18

Falls Village (MP 759)

100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128

Source USGS (1987) Hartford CT

Note ND is non-detected The detection limit is 01

aSample water passing through a 045-fjm pore diameter filter

contradiction indicated that the particulatedissolved PCB concentration breakdown is

questionable and led to the consideration of the total PCB data alone

The total PCB concentration was above the detection limit in all of the samples taken at

Great Barrington and 43 of the samples taken at Falls Village These latter data are of

limited usefulness in precisely defining the total PCB concentration for model calibration

However the data do show a trend of decreasing PCB concentrations with distance

downstream which should be reflected in the model results

Figures 3-6 through 3-8 present the model results for total PCB concentration in water

segments and particulate PCB concentration in water and underlying bed segments The

reason for showing the particulate concentration of the overlying water and the bed segments

on the same plot is to illustrate how greater particulate concentrations in the water tend to

increase the beds PCB concentration through deposition The notation of water segmentbed

segment (eg 112) is used in each plot to indicate that the particulate concentrations are for

the water and underlying bed segments As a point of clarification the units of the total and

particulate PCB concentrations are not the same the relationship between total and

particulatedissolved PCB concentrations is expressed in Equation 3-2 and an example

calculation is included in Attachment 4

The extent to which the measurements can be used to calibrate the model is

bull Total PCB concentrations computed by the model at Falls Village (segment 6) fall into the below-detection-limit range that resulted from approximately 57 of the measurements during the period

bull The decrease in PCB concentrations from segment 1 to segment 6 agrees with the decrease in observed PCB concentration from Great Barrington to Falls Village

Unfortunately the PCB measurements at Falls Village were not performed at a sufficiently

low detection limit to allow for more rigorous comparisons

In addition to comparisons to field data the model results should also be compared to model

results generated previously in the Connecticut segments calibration The previous


Total PCB Segment 1 Total PCB Segment 2 02

018

0 16 016

012

004 004

002 002

Apr-79 Jun-79 Aug-79 Oct-79 Dec-79 Feb-80 Apr-80Date

Jun-SO Aug-80 Oct-80 0-1mdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashimdashr

Apr-79 Jun-79 Aug-79 Oct-79 Dec-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-80 Date

Particulate PCB Segments 112 50

Particulate PCB Segments 213

35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05

00 Apr-79 Jun-79 Aug-79 Oct-79 Dec-79 Feb-80 Apr-80

Date Jun-BO Aug-80 Oct-80

00 Apr-79 Jun-79 Aug-78 Oct-79 Dec-79 Feb-80 Apf-80

CM Jun-laquo0 Aug-80 Oct-80

Segment 1 (water) + Segment 12 (bed) I Slaquogmlaquont 2 (water) + Segment 13 (bed)

LAWLER MATUSKV A SKELLV ENGINEERS Enwoomwiul Scianc laquo EnglnMrlng Coraultant PCB CAUBRATION RESULTS IN WATER COLUMN RGURE 3-6 One Blue Hill Plaza bull Pearl River NY 10965 AND SEDIMENT (SEGMENTS 112 AND 213)

i

Total PCB Segment 3 Total PCB Segment 4

002

Apr-78 Jun-79 Aug-78 Oct-78 Oec-79 Feb-laquo0 Apr-80 Jun-80 Aug-80 Oct-80 Apr-79 Jun-78 Aug-78 Oct-79 Oec-78 Feb-80 Apf-80 Jun-80 Aug-80 Oct-80 Date Date

Partculale PCB Segments 314 Paniculate PCB Segments 415 50shy

45

25 25

1 5

05

00 00 Apr 78 Jun-78 Aug-78 Oct-79 Dec-78 Feb-80 Aplt-80 Jun-80 Aug-80 Oct-80 Apr-78 Jun-78 Aug-78 Oct-78 Dec-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-80

Date Dale

Segment 3 (water) 4shy Segment 14 (bed) I Segment 4 (water) + Segment 15 (bed)

LAWLER MATUSKY C SKELLY ENGINEERS Envtronmertal Science bull Engineering Coraulums PCB CAUBRATION RESULTS IN WATER COLUMN RGURE 3-7 One Blue Hill Plaza bull Pearl River NY 10965 AND SEDIMENT (SEGMENTS 314 AND 415)

Total PCB- Segment 5 Total PCB Segment 6

0 12

004

002

Apr-79 Jun-79 Aug-79 Oct-79 Oc-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-80 Date

Parfculate PCB Segments 516

35

25

|20

1 5shy

1 0

05

00 Apr 79 Jun-79 Aug-79 Oct-79 Dec-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct-80

Date

I Segment 5 (water) + Segment 16 (bed)

018

0 12

r 002

Apr-7B Jun-79 Aug-79 Oct-79 Oc-78 Fet-80 Apr-80 Jun-80 Aug-80 Oct-80 Dtraquo


35

25

20

1 5

Apr-79 Jun-79 Aug-79 Oct-79 Dec-79 Feb-80 Apr-80 Jun-80 Aug-80 Oct 80 Date

Segment 8 (water) + Segment 17 (bed)

LAWLER MATUSKY 1 SKELLY ENGINEERS Environmental Scanca 4 Engineering ConsuHantt PCB CAUBRATION RESULTS IN WATER COLUMN RGURE 3-8

AND SEDIMENT (SEGMENTS 516 AND 617) One Blue Hill Ptaza bull Pearl River NY 10965

calibration efforts consist of a calibration of the Connecticut segments using an estimated

PCB upstream boundary concentration of 005 ug1 (Apicella et al 1988) Note that this

boundary condition is revised from the 002-ugl boundary concentrations used in the Chapter

6 report (LMS 1988) as a result of subsequent sampling conducted in 1988-1989 which

indicated that a boundary of 002 ug1 was too low The Massachusetts calibration results in

segment 4 (at the Massachusetts-Connecticut state line) for total PCB concentrations is

approximately 004 to 005 ug1 which is consistent with the revised boundary of 005 ug1 used

in the Connecticut model

In addition the total PCB results at Falls Village (segment 6) are in agreement with the

Connecticut model results The model predicts that in segments 112 through 415 the

paniculate PCB concentration in the water column is approximately twice as high as that in

the underlying bed leading to a slight increase in bed PCB concentration over time Note

that this model-predicted trend has not been confirmed with actual data and may change after

additional data (eg PCB in bed sediment) is collected for model refinement and calibration

In segments 516 and 617 the paniculate PCB concentrations of the water column and

corresponding bed are in the same range so that the bed PCB concentrations remain

approximately constant over time The observations for segments 516 and 617 are consistent

with model results from previous Connecticut segment calibration efforts (LMS 1988 Apicella

et al 1989) This examination of particulate PCB concentration provides a glimpse of the

rates of change in sediment PCB concentrations for the upstream and downstream portions

of the river to be projected later

The model sensitivity to three parameters (partitioning volatilization and diffusion) that

affect transfers of PCBs was investigated individually to further test the models validity

Since the partition coefficient is calculated by the model from the user-input logarithm of the

octanol-water partition coefficient (log K^J and fraction organic carbon (f^) discussed in

Section 31 the models sensitivity to this parameter is tested by varying log K^ and f^ The

range of log K^ for the PCB Aroclors 1254 and 1260 was found in the literature to be 60

to 72 (EPA 1987) If the high value for log K^ were used to calculate partition coefficients

in the water column PCBs in the water column would be approximately 30 in the dissolved

phase as opposed to the 50 predicted by use of the average log K^ (65) value If the


low value for log K^ were used PCBs would be about 70 in the dissolved phase in the

water column Model sensitivity to partitioning was also tested by increasing and decreasing

foe by 50 This increase and decrease in f^ yielded a decrease and increase respectively

in dissolved PCB of about 10 No justification for using either extreme value of log K^

could be made so an average of all the Aroclor 1254 and 1260 log K^s was deemed

appropriate for the model As a relatively small variation in dissolved PCB was affected by

the 50 change in f^ values the original estimate of f^ based on the literature was also

deemed appropriate

If volatilization were zero through the system total PCB concentrations in the water column

would be approximately 35 greater The precision of PCB measurements does not permit

testing this hypothesis However not only is the inclusion of volatilization in PCB modeling

documented in the scientific literature (Chapra and Reckhow 1983) but the importance of

its impact on PCBs in the water column is also recognized (Thomann and DiToro 1983)

Given the effect of volatilization on water column PCBs shown in the sensitivity tests

volatilization will be further discussed in the model projections (Section 34) Finally the

elimination of diffusion of dissolved PCB from the bed to the water column has a negligible

effect on the computed results

The change in the partition coefficient between the previous WASTOX (LMS 1988) and the

present version was investigated by applying both models to the Connecticut portion of the

river The solids-dependent partition coefficient in the current model yields a lower partition

coefficient in the water column For example at a TSS concentration of 20 mg1 and an f^

of 003 the partition coefficient in the current model is approximately 30000 Ikg as

compared to 100000 Ikg in the previous model This change in partitioning increases the

dissolved portion of PCB in the water column from approximately 25 in the 1988 model to

50 in the current model There are no published data available for the Housatonic River

to check the ratio of dissolved to total PCB The change in partitioning for the bed segments

is from approximately 9000 Ikg in the previous model to a range of 30000 to 280000 Ikg in

the present WASTOX2 model While this appears to be a substantial change in partitioning

virtually all PCB in bed segments is in the particulate form according to both models

Diffusion of PCB from the bed to the water column had a negligible effect on the computed


results in the previous as well as the present model Thus the latest modeling of PCB

partitioning indicates that there is an approximately even split between the dissolved and

paniculate components in the Housatonic River

A special request was made by CDEP for a test of model sensitivity to suspended solids

entering the Housatonic River from the Ten Mile River which is modeled as a tributary

entering segment 9 The Connecticut segments previously calibrated (LMS 1988) were

executed on WASTOX Version 251 with the original Ten Mile River suspended solids

concentration (178 mg1) and with an increased concentration of 360 mg1 The increased

tributary sediment loading had little effect (lt10) on the total and particulate PCB

concentrations in the water column and the bed Hence refinement of Ten Mile Rivers

incoming sediment load does not appear to be necessary to improve the models reliability

A test of model sensitivity to upstream PCB boundary concentration is discussed in the model

projections Section 34

34 MODEL PROJECTIONS OF PCBs

The usefulness of the model as a tool for projecting PCB levels in Housatonic River sediment

and water hinges on setting reasonable conditions for the driving forces of the system Two

such important factors are the river flow and the upstream PCB concentration Evaluation

of the expected river flow and total PCB concentration of water influent to the study area

is discussed in Sections 341 and 342 The PCB concentrations of the bed segments for the

projections remained the same as those in the model calibration The fact that PCB

concentrations in recent sediment samples of the Housatonic River in Massachusetts are

comparable to those from previous samples (Mark Brown pers commun) supports this The

model projections of PCBs in sediment and water are presented Ln Section 343 An example

of the model projection input file is included in Attachment 3


341 Long-Term Hydrological Period

Because river flow affects the PCBs entering the Housatonic River study area and also

controls the resuspension of PCBs any cyclical trend in hydrology that might regulate longshy

term PCB levels must be incorporated into the modeling effort Statistical analyses of

Housatonic River flow data at Falls Village recorded by USGS from 1912 through 1986

showed no significant long-term periodicity (LMS 1988) No significant long-term periodicity

is then expected in flow data at Great Barrington (Figure 3-9) as there are no significant

climatological or hydrological differences between the Housatonic River at Great Barrington

and at Falls Village Thus the mean monthly flows at Great Barrington used for the

projections computed from 76 years of data are

FLOW FLOW MONTH (cfs) MONTH (cfs)

Jan 494 Jul 279 Feb 493 Aug 238 Mar 910 Sep 261 Apr 1250 Oct 288 May 688 Nov 454 Jun 419 Dec 514

Like the model calibration the upstream boundary and tributary flows for each month were

estimated on the basis of drainage area A 50-year period was selected for the modeling

projections as a reasonable time span to study the rivers natural recovery under the no action

plan Although the field data that established initial conditions for the model were collected

from 1979 through 1991 for simplicity time zero is assumed to be 1990

342 Upstream and Tributary Inflows of PCBs

Because the total PCB concentration of the Housatonic River at Great Barrington is

generally near the detection limit there is considerable uncertainty in estimating influent

concentrations for the future Nevertheless in order for modeling projections to be carried


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out an estimate must be made The approach to doing so entails (1) determining whether

the upstream source will be constant or will diminish with time (2) if the latter estimating

the rate of decrease and (3) estimating a minimum boundary PCB concentration that

upstream and tributary waters will not be below

It is difficult at the present time to establish whether the upstream PCB source is constant

or diminishing As discussed in Section 223 the analysis of ambient PCB trends in the

vicinity of Great Barrington does not allow any firm conclusions as to whether the PCB

concentration is declining or remaining relatively constant However the data on PCB

concentrations of the insects and fish in the Housatonic River in Connecticut show a

generally declining trend in such concentrations (summary of numerous studies found in LMS

[1988]) These data suggest that the upstream boundary PCB concentration has been

decreasing and will continue to decrease For present purposes the temporal trend in PCB

concentration at the upstream boundary is assumed to decrease exponentially with a time rate

coefficient of 005year the same rate used in the Chapter 6 modeling projections (LMS

1988) Figure 3-10 shows the assumed exponentially decaying boundary and also shows the

decay calculated using Equation 2-3 the log-transformed regression based on Great

Barrington data As discussed in Section 22 Equation 2-3 comprises a significant level of

statistical uncertainty Nevertheless reasonable agreement is shown between these two decay

functions Thus until more data are collected and the resulting trend becomes more

quantifiable we will consistently use the exponential decay rate constant of 005yr

According to the literature on background PCB levels (Section 62 of Chapter 6 report [LMS

1988]) the presence of PCB in remote nonindustrialized areas suggests that there is a

minimum concentration for influent surface water As PCBs in the environment become

more and more dispersed through fluvial and atmospheric transport the tributaries as well

as the upstream boundary are assumed to reach a minimum boundary PCB concentration

This minimum total PCB concentration (ct w) for the upstream and tributary inputs to the

model was set at 0005 ug1 and is reached in 28 years for the tributaries and in 46 years for

the upstream boundary (Figure 3-10)


Upstream PCB Boundary Conditions

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LAWLER MATUSKY C SKELLY ENGINEERS Envuoormnul Sdnc t Enjto4gtlaquonng Corauluntt DECAYING PCB BOUNDARY AND FIGURE 3-10 One Blue HID Plaza bull Peari River NY 10965 TRIBUTARY CONCENTRATIONS

The 1990 PCB concentration from which the exponential decrease starts was estimated to be

0066 ng1 based on PCB flow and suspended solids data collected in 1979-1991 The

statistical analyses and resulting equation (Equation 2-3) relating PCB concentration to time

are discussed in Section 23 The average 1990 PCB concentration computed using this

equation is 0061 igfl which compares favorably with an average of PCB data collected in

1990-1991 at Great Barrington yielding 0059 jigl (See Table 2-6) The exponential decrease

in PCB concentration was factored into the upstream boundary condition at intervals of 900

days or approximately 25 years Hence the total PCB concentration at the models upstream

boundary was input as decreasing in steps over the projection period (Figure 3-10)

The only other change in model input from the calibration was to use the average suspended

solids concentration of 126 mg1 for the upstream boundary rather than the monthly variation

in order to avoid lengthy input data files for the 50-year simulation Comparison of the

constant and time-varying solids boundary condition showed a negligible difference in the

results over several years

343 Projections of PCBs in Sediment and Water

The modeling projections can be viewed as an extension of the model calibration which was

a simulation of 18 months to a 50-year simulation The results are presented in terms of the

commonly measured forms of PCBs namely total PCBs in the water column and particulate

PCBs in the bed sediment Three hypothetical scenarios are assumed for the modeling

projections

bull Scenario 1 Reduction in PCB concentration at upstream boundary

bull Scenario 2 Constant PCB concentration at upstream boundary

bull Scenario 3 Reduction in PCB concentration at upstream boundary and in river sediments between Great Barrington and the Connecticut border

Each scenario is discussed below


Scenario 1 Reduction in PCB Concentrations at Upstream Boundary

These projections are based on the assumptions discussed above including the assumed

exponential decrease in PCB concentration at the upstream boundary and tributary inflows

The trends in PCB concentration projected for the Housatonic River from Great Barrington

(segments 112) through Lake Zoar (segments 1122) are presented graphically in Figures 3shy

11 through 3-16 Note that the sinusoidal variation in PCB concentration is attributable to

the variation in flow which affects scour and deposition Concentrations are projected to

decrease monotonically from year to year for all segments except the bed sediment in six

segments the four Massachusetts segments (12 through 15) the MassachusettsConnecticut

state line segment (16) and the Bulls Bridge impoundment (segment 19) In these segments

the particulate PCB concentration of the suspended sediment is initially greater than that of

the bed sediment Data on the change in bed sediment PCB concentrations over time are

scarce and limited to sediment sampling depths of 3 in which exceeds the depth of the active

sediment layer in most segments Hence this increase in PCB concentrations of the six

upstream bed segments cannot be documented However in view of the short time (less than

seven years) projected until these bed sediments reach their maximum overall declining PCB

concentrations are expected throughout the study area The percentage reductions in water

and bed PCB concentrations were arithmetically averaged for segments 1 through 11 and 12

through 22 to provide a riverwide outlook (Figure 3-17) A reduction of 50 of the total

PCB concentration in the water is projected for 20 years from 1990 and the same reduction

in the particulate PCB concentration of the bed is projected for 25 years The water column

will achieve about 10 greater reduction in PCB concentrations at the end of 50 years than

will the bed A combination of water and bed PCB reductions shows the decline in PCB

levels to which fish would be directly and indirectly (through the food chain) exposed

Scenario 2 Constant PCB Concentration at Upstream Boundary

In view of the lack of any clear finding at present on the trend in PCB concentrations at the

models upstream boundary a second set of model projections was carried out keeping the

PCB loadings at the upstream boundary and from the tributaries constant over the 50-year

period These projections also assist in demonstrating the relative importance of the external


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LAWLER UATUSKY ft SKELLY ENGINEERS 1 1 fliM Environment Sconce Engineering ConsuManfs PC B PROJECTION UNDER SCENARIO 1 FIGURE 3-11

One Blue Hill Plaza bull Peart River NY 10965 (SEGMENT 11 2 AND 21 3)


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Parbculate PCB Segments 14 Particulate PCB Segments 15

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LAWLER MATUSKY A SKELLY ENGINEERS I Environmental Science t Engineering Contuttant PCB PROJECTION UNDER SCENARIO 1 FIGURE 3-12 One Blue Hill Plaza bull Pearl River NY 10965 (SEGMENTS 314 AND 415)

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LAWLER UATUSKV ft SKELLV ENGINEERS Environmental Science laquo Engineering Consultants PCB PROJECTION UNDER SCENARIO 1 RGURE 3-13

(SEGMENTS 516 AND 617) One Blue Hill Plaza bull Pearl River NY 10965

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LAWLER UATUSKV amp SKELLY ENGINEERS 1 1flil^ Ertyiionnnnul Solaquoncraquo Engineering CootulUnU PCI3 PROJECTION UNDER SCENARIO 1 RGURE 3-14

One Blue Hill Plaza bull Peart Rhw NY 10965 (SEGMENTS 718 AND 819)


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LAWLER MATUSKV amp SKELLV ENGINEERS 1 1 1y Environmental Scraquonoraquo t Engineering Comuluntt PCB PROJECTION UNDER SCENARIO 1 FIGURE 3-1 5

One Blue HiH Plaza bull Pearl River NY 10965 (SEGMENTS 920 AND 1021)

Total PCB Segment 11

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0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980

LAWLER MATUSKY amp SKELLY ENGINEERS I Environmental Sonco t Engineering ConculUnti PCB PROJECTION UNDER SCENARIO 1 FIGURE 3-16 One Blue Hill Plaza bull Pearl River NY 10965 (SEGMENTS 1122)

Water Column

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LAWLER MATUSKY A SKELLY ENGINEERS Environmental Scant t EngtoMring ContuKantt PCB PROJECTION UNDER SCENARIO 1 FIGURE 3-17 One Blue HM Plaza bull Peart River NY 10965 (AVERAGE OF MODEL SEGMENTS)

(upstream and tributary) loadings vs the sedimentation and burial of PCBs in the rivers

recovery The results of these model projections are presented in Figures 3-18 to 3-23

Under this scenario a minimal change in PCB concentration of the water column is

projected and the only bed sediments showing a substantial decrease in PCB concentration

are those of Lakes Lillinonah and Zoar (due to sediment burial) These results demonstrate

that the projected recovery of the studied portion of the Housatonic River depends primarily

on the diminishing source of PCBs from upstream They show further that the recovery of

the two lakes also depends primarily on sediment burial

Scenario 3 Reduction in PCB Concentrations at Upstream Boundary and in River Sediments Between Great Harrington and the Connecticut Border

These projections assume not only a diminishing source of PCB inflow at the models

upstream boundary and tributaries (as in Scenario 1) but also a 50 reduction in the PCB

concentration of the bed sediments in the river segments between Great Barrington and the

Connecticut border (Scenario 3) The results of these projections are presented in Figures

3-24 to 3-29 These plots show Scenarios 1 and 3 superimposed for comparison purposes

Note that relatively small differences are seen for the first 10 years in the Massachusetts bed

segments (ie those bed segments subject to the assumed 50 decrease in PCB

concentration) The Connecticut segments are essentially unchanged as compared to Scenario

1 and after 10 years the Massachusetts segments are the same as in Scenario 1 The average

times to reach a 50 reduction in PCB concentrations in the entire study area are

approximately 20 years from 1990 for the water column and approximately 25 years for the

sediments essentially the same as Scenario 1 The reason for virtually no change between

these scenarios is that the fate of PCB is controlled mainly by PCBs at the upstream

boundary not PCBs in the bed sediment The Scenario 3 projections reveal that remediation

of the sediments in the Massachusetts segments of the river downstream of Great Barrington

would not have an appreciable beneficial effect in reducing PCB concentrations in the water

and sediments of the Housatonic River in Connecticut


0075 Total PCB Segment 1 Total PCB Segment 2

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LAWLER UATUSKV 1 SKELLY ENGINEERS Environmental Science i Engineering Corwulunts PCB PROJECTION UNDER SCENARIO 2 FIGURE 3-18 One Blue Hill Plaza bull Pearl River NY 10965 (SEGMENTS 112 AND 213)


0075

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LAWLER MATUSKY amp SKELLY ENGINEERS Environmental Science I Engineering Consultants PCB PROJECTION UNDER SCENARIO 2 RGURE3-19 One Blue Hill Plaza bull Peart River NY 10965 (SEGMENTS 314 AND 415)


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LAWLER HATUSKV 1 SKELLY ENGINEERS Environmental Science 1 Engineering Consultant PCB PROJECTION UNDER SCENARIO 2 FIGURE 3-20 One Blue Hill Plaza gt Pearl River NY 10965 (SEGMENTS 516 AND 617)

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The importance of volatilization in the rivers recovery was investigated by turning

volatilization off in the model Water column PCB concentrations were about 30 greater

with volatilization off rather than on However the change did not significantly alter the

projected percent reductions in PCB concentrations in the river

A mass balance of inflowing and outflowing PCBs (see Table 3-7) indicates that 57 of the

total PCBs in the entire study area (ie Great Barrington to Stevenson Dam) are lost to

sedimentation and burial over the 50-year projection period The remaining losses are due

to transport past the Stevenson Dam and volatilization


TABLE 3-7

SUMMARY OF THE FATE OF PCBs IN THE HOUSATONIC RIVER FOR THE PROJECTION PERIOD

CONTRIBUTING COMPONENT

INFLOWS

Housatonic River at Great Harrington

Tributaries

Total Inflow of PCBs

OUTFLOWS

Outflow at Stevenson Dam

Volatilization

Sedimentation and Burial

Total Outflow of PCBs

PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4

CONCLUSIONS AND RECOMMENDATIONS

41 CONCLUSIONS

This report addresses Task IIA (Ambient Monitoring) and Task III (Fate and Transport

Model) as required by the Housatonic River Cooperative Agreement

Two ambient monitoring surveys were performed at Great Harrington in March and August

1991 during high-flow events Results of the first survey consistently indicated total PCB

concentrations ranging from non-detectable (ie lt 0065 jig1) to 0087 xg1 in the water

column for flow ranging from approximately 1000 to 1300 cfs PCB concentrations in filtered

water samples were below the detection limit Because the fraction of dissolved PCB is

estimated at approximately 50 of total PCB concentration it is not surprising that dissolved

PCB is below detection (ie 50 of 0087 ig1 is less than 0065 jigI) Total organic carbon

(TOC) concentrations of 2 to 3 mg1 were measured The results of the August survey are

not included in this report as ITAS Labs has not yet completed the analyses LMS will

continue to monitor weather conditions and river flow in order to plan and execute the

remaining survey

A statistical trend analysis using a multiple linear regression technique was performed with

all data collected between Great Barrington and Falls Village between 1979 and 1991 PCB

was found to be most significantly correlated with total suspended solids (TSS) A correlation

between PCB and time was found but it was fairly low It is possible that the reason for the

apparent decrease in PCB concentration over time may be that river flow measurements in

general and specifically during sampling also show a declining trend over the past 12 years

However there is no reason to believe that there is a long-term decline in the river flow that

would cause an apparent decreasing trend in PCB Given these circumstances and the

existing data no clear conclusions can be reached presently regarding a trend in PCB

transport at Great Barrington


The WASTOX (Version 251) model was extended to Great Harrington as required in the

Cooperative Agreement Consistency with the CT model (LMS 1988) was demonstrated at

Falls Village where predicted TSS and PCB concentrations of the current model were very

similar to the previous model Model version 251 employs a constant bed sediment

concentration option and an updated formulation for the partitioning between particulate and

dissolved phases in the water column This new partitioning conforms with the Particle

Interaction Theory (DiToro 1985) and results in partition coefficients in the water column

approximately 30 of those used in the Connecticut WASTOX model Additionally version

251 assumes a constant partition coefficient in the bed as data does not exist to indicate a

dependence on solids concentration The updated bed partition coefficients are

approximately 10 to 30 times greater than those used in the previous WASTOX application

in Connecticut The effect of lower partitioning in the water column is to allow more PCB

to exist in the dissolved phase and thus be more subject to volatilization from the river system

The impact of higher partitioning in the bed is generally insignificant because the high solids

concentration (ie greater the 300000 mg1) result in virtually all of the PCB residing on

particulates even for partitioning coefficients differing by as much as 30 times from one

another

Although the relatively high detection limit for PCB analyses of water samples does not allow

precise quantification of PCB concentration during the calibration period recently collected

experimental low-level PCB measurement data provide a check on the PCB transport

simulated by the model Model projections are performed with both a constant and decaying

PCB boundary condition at Great Barrington as well as with a 50 reduction in PCB

concentration of the Massachusetts bed segments The upstream boundary condition is the

main determinant of PCB levels in downstream water and sediment and is thus very important

to accurately predict PCB concentrations in the future As will be discussed in the following

recommendations section continued monitoring at the upstream boundary is critical to the

accuracy of modeling projections


42 RECOMMENDATIONS

Tasks IV B and C of the Cooperative Agreement require that GE conduct additional

monitoring of river sediments in 1992 for further calibration and verification of the fate and

transport model and that a proposal for such additional monitoring be submitted at the same

time as the present modeling report

A general discussion of the types and amounts of samples that would be required for a

successful model verification follows Once this general plan is accepted a detailed work

scope for this proposed sampling plan would be developed

Sediments The Proposed Monitoring Program called for a comprehensive sediment survey

of the Housatonic River in Connecticut in 1992 when discernibly lower PCB concentrations

in surficial bed sediments are expected as compared to Frink data collected during 1979-1980

The recommended number of sediment samples in the river segments located in Connecticut

are shown below The current sediment sampling work in the Massachusetts portion of the

river being performed by Blasland amp Bouck for GE may also provide some information

useful for further model calibration and verification LMS in consultation with GE and

Blasland amp Bouck will evaluate the number of additional core samples necessary in the

Massachusetts segments

For consistency with Frink data collected during 1979-1980 as well as recent and current

Blasland amp Bouck data most sediment samples will be collected from the top 3 in of the bed

A gravity core sediment sampler (eg Ballchek sampler) will be used to get an even

representation of the top 3 in of sediment A select subset of core samples would be

analyzed in finer 1-in increments for the top 3 in of sediment to evaluate PCB

concentrations in the active layer of sediment (ie the layer that interacts with the water

column) The number of these samples would be specified in the detailed work scope

Additionally some deep core samples (approximately 24 to 30 in) would also be analyzed for

Cesium in selected 1-in increments to evaluate sediment depositional trends


The recommended number of sediment grab and core sampling stations by segment are as

follows

NUMBER OF NUMBER OF MODEL SURFICIAL DEEP CORE

LOCATION SEGMENT No SEDIMENT SAMPLES SAMPLES

Mass 1 thru 4 to be determined to be determined

Cannann 5 4 -

Falls Village 6 10 1

Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8

L Lillinonah 10 10 2

L Zoar 11 10 2

Core samples to be taken in the Connecticut lakes and impoundments would be located at

the same stations sampled by LMS in 1986 to provide a spatially consistent means of

evaluating trends in PCB concentration over time The number of samples shown above

should be sufficient for the purposes of model recalibration and verification

Water Monitoring for PCBs in the water column at Great Barrington is currently being

performed for GE by Blasland and Bouck as part of the Massachusetts Contingency Plan

requirements Additionally LMS will be sampling at Great Barrington during one additional

high-flow event We recommend that sampling at downstream stations also be incorporated

into the remaining sampling event and that additional samplings be performed during 1992

The number of samples taken would depend on the occurrence of appropriate high-flow

events A total of four sampling events are proposed at this time

The recommended stations for sampling river water are

bull Great Barrington

bull Falls Village


bull Lake Lillinonah (Rt 133 Bridge)

bull Lake Zoar (Rt 84 Bridge)

bull Massachusetts tributary (eg Williams or Green River)

All water column samples would be taken with a depth-integrated sampler and would be

analyzed for PCB TSS TOC and some percentage of samples will be filtered for analysis of

dissolved PCB and DOC Low-level PCB measurements may be considered if a suitable and

validated analytical method is available to attain quantifiable PCB concentrations for portions

of the Housatonic River system If low-level PCB measurements are made sample

compositing during high-flow events at stations in Connecticut is recommended One of the

tributaries in Massachusetts will be sampled during these events to assist in evaluating

sediment fluxes in model segments 314 and 415

The results of these proposed water and sediment surveys would be presented in a data

review and assessment report The data will be analyzed for trends through comparisons with

available data The updated data may also indicate that adjustments to the PCB fate and

transport model are warranted Recommendations for further evaluation of model

parameters and model recalibration or verification will be included in the data review and

assessment report which will be submitted to CDEP by mid-1993


REFERENCES

Academy of Natural Sciences of Philadelphia (ANSP) 1990 PCB Concentrations in Fishes From the Housatonic River Connecticut in 1984 1986 and 1988 Report No 89-30F Prepared for General Electric Company

Apicella G D Distante JP Lawler 1988 Fate and Transport Model of PCB in the Housatonic River

Blasland and Bouck Engineers PC 1991 Description of Field Activities Housatonic River MCP Phase II Water Column Sampling March 1991 Prepared for General Electric Company Unpublished

Chapra SC and KH Reckhow 1983 Engineering approaches for lake management Vol 2 Mechanistic modeling Butterworth Publishers

Connolly JP RP Winfield 1984 WASTOX a framework for modeling the fate of toxic chemicals in aquatic environments Part I Exposure concentration Performed for US Environmental Protection Agncy EPA-6001 3-84-007 (WASTOX2 Manual revised 1991)

Di Toro DM 1985 A Particle Interaction Model of Reversible Organic Chemical Sorption Chemosphere 14 101503

Frink CR BL Sawhney KP Kulp and CG Fredette 1982 Polychlorinated biphenyls in Housatonic River sediments in Massachusetts and Connecticut Determination distribution and transport A cooperative study by the Conn Agricultural Experiment Station the Conn Department of Environmental Protection and the US Geological Survey

Hintze JL 1990 Number Cruncher Statistical System Version 503 Survival Analysis Kaysville UT

Karickhoff SW 1984 Organic Pollutant Sorption in Aquatic Systems ASCE Journal of Hydraulic Engineering 110(6)

Kulp KP US Geological Survey (USGS) Water Resources Investigative Report 91-4014 In Press

Lawler Matusky amp Skelly Engineers (LMS) 1988 Housatonic River PCB Sediment Management Study Program for Monitoring the Natural Recovery of the River Chapter 6 Prepared for General Electic Company

Lawler Matusky amp Skelly Engineers (LMS) 1991 Housatonic River Water Column Sampling Data Analysis April 1991 Prepared for General Electric Company Unpublished

R-l Lawler Matusky amp Skelly Engineers

REFERENCES (Continued)

Mills WB JD Dean DB Porcella SA Gherini RJM Hudson WE Friek GL Rupp and GF Bowie 1982 Water quality assessment A screening procedure for toxic and conventional pollutants Prepared for EPA EPA-6006-82-004a

OConnor D J and JP Connolly 1980 The effect of concentration of adsorbing solids on the partition coefficients Water Research 141517

Quirk Lawler amp Matusky Engineers (QLM) 1971 Systems Applications for Water Pollution Control Prepared for Commonwealth of Massachusetts

Stewart Laboratories Inc 1982 Housatonic River Study 1980 and 1982 Investigations Final Report Prepared for General Electric Company

Thomann RV and DM Di Toro 1983 Physico-Chemical Model of Toxic Substances in the Great Lakes Journ of Great Lakes Res 9(4)474

Thomann RV and JA Mueller 1987 Principles of Surface Water Quality Modeling and Control Harper and Row Publishers NY

US Environmental Protection Agency (EPA) 1983 Environmental transport and transformation of polychlorinated biphenyls EPA5605-83025

US Environmental Protection Agency (EPA) 1987 Processes Coefficients and Models for Simulating Toxic Organics and Heavy Metals in Surface Waters EPA6003-87015

R-2 Lawler Matusky amp Skelly Engineers

ATTACHMENT 1

SAMPLING AND QUALITY ASSURANCEQUALITY CONTROL MANUAL

TASK 2 - AMBIENT TREND MONITORING

Sampling Methods and Quality Assurance Quality Control

General

As part of the Ambient Trend Monitoring requirement LMS will obtain water column

samples from the Division Street Bridge near Great Barrington The objective is to obtain

samples during three wet weather events when the discharge at Great Barrington is greater

than 1000 cfs to develop a relationship between river flow and PCB concentration Weather

conditions and flow recorded by the USGS are monitored by LMS to determine the

appropriate time to sample

Samples will be obtained from the platform located at the center-of-flow on the Division

Street Bridge near Great Barrington Samples taken from this position should be

representative of the whole cross-sectionally averaged flow This position was verified by

comparing cross-sectionally averaged total suspended solids (TSS) measurements with

measurements at the platform During the first survey TSS samples will be taken at four

stations evenly spaced over the main cross-section of flow to confirm that the sampling

platform is still representative of the whole cross section

Bottle Preparation

Since PCBs are one of the parameters of concern a glass sample bottle must be used The

bottles are cleaned as follows

bull Nonphosphate soap and tap water

bull Nitric acid rinse

bull Methanol rinse

bull Distilleddeionized water rinse

bull Hexane rinse


bull Air or over dry

Sampler Preparation

The above cleaning method is also employed to clean all parts of the DH59 sampler that

come into contact with sample The bailer which is used to collect TSS only is simply cleaned

with tap water prior to use and rinsed between stations with river water

Sampling Methodology

A Scientific Instruments Inc (SCI) Model 5250 DH-59 Sediment Sampler will be deployed

for sample acquisition This sampler is designed to take depth integrated samples and can be

either manually deployed (hand-line) or deployed with a winch and cable The sampler will

be lowered and raised at a uniform rate between the water surface and bottom of the stream

using a hand operated A-55 Sounding Reel On contacting the stream bed the direction of

travel is reversed and the sampler rises towards the surface The sampler comprises a streamshy

lined bronze casting 15 in long which partially encloses a pint-sized glass bottle The

sampler weighs 22 Ib and is equipped with a tail vane assembly to orient the intake nozzle

of the sampler upstream The glass bottle sampler container is sealed against a gasket in the

head cavity of the casting by pressure applied to the base of the bottle by a hand operated

spring tensioned pull rod assembly located at the tail of the sampler Sample water (including

suspended sediment) collected through the intake nozzle projecting horizontally upstream

from the head of the casting is discharged into the sample bottle The air in the bottle which

is continually displaced by the incoming volume of sample is ejected downstream through an

air exhaust tube which is permanently affixed to the body casting and protected by a

streamlined projection alongside the body of the sampler The sampler comes with several

nozzles of varying diameter that provide different inflow rates The 1-pt sample bottle should

only be filled to approximately two-thirds of its volume to prevent any collected suspended

sediment from moving out of the bottle when it is filled Thus the appropriate nozzle must

be chosen to ensure that for the given field condition this criteria is not exceeded The

nozzle choice and rate of sampler lowering and raising will be determined in the field prior

to actual sampling


Deployment of the DH-59 at the three stations other than the one located at the platform

is not feasible because of limited access to the edge of the bridge As discussed previously

these cross-sectional samples are required to confirm that water quality parameters taken at

the sampling platform location are reasonably representative of the full cross-sectional area

of flow Therefore to perform the one-time collection of the depth integrated suspended

sediment samples at these stations a stainless steel cylindrical bailer is used The 6-ft bailer

is deployed vertically at the mid-depth of the stream Since the stream is approximately 9 ft

deep during high flow events the bailer should be sufficiently representative of the water

depth to allow the analysis to confirm the horizontal center of discharge sampling point (ie

the platform)

When the sampler bottle is filled to the appropriate level it is carefully removed and the

sample water poured into the pre-cleaned sample bottles provided by International

Technology Corporation Analytical Services (ITAS) Labs This procedure is repeated until

all of the required sample bottles are filled for each collection period The sample bottles

are securely capped and labeled with the job number sample ID datetime and parameters

for analysis Preservatives are added in the field where applicable Sample containers are

placed in iced coolers to maintain a temperature of 4degC Collected samples are documented

on the proper field data sheet and chain-of-custody form A chain-of-custody record must be

filled out completely in order to establish the documentation necessary to trace sample

possession from time of collection through delivery to the analytical laboratory This record

must contain the following information

bull Sample container number(s)

bull Signature of collector

bull Date and time of collection

bull Sample type (eg surface water soil sediment)

bull Sample location identification

bull Number and type of containers

bull Signature of person(s) included in the chain of possession


bull Inclusive dates of possession

A request for analysis document will also accompany the samples to the analytical laboratory

clearly identifying which sample containers have been designated for each requested

parameter and the included sample volume preservative requested testing program and

special instructions if any This document must include the following information

bull Project name and contact

bull Laboratory contact

bull Sample container numbers

bull Sample type

bull Sample volume

bull Preservatives used in field

bull Analyses requested

The sample containers are shipped in iced coolers under the chain-of-custody protocols to the

analytical laboratory via an overnight carrier service Table 2-3 in Chapter 2 summarizes the

parameters measured during each survey and also indicates container materials and

preservation methods

Sampling Quality Assurance

To ensure no contamination from sampling equipment one field blank will be performed on

the DH-59 sampler The sampler is thoroughly rinsed with distilleddeionized water a clean

sampler bottle is filled with field blank water supplied by the analytical laboratory (ITAS) and

inserted into the sampler The sampler is then positioned so the water pours out through the

nozzle into a clean set of bottles This process is repeated un t i l all of the field blank sample

bottles are filled


Analytical Quality AssuranceQuality Control

IT AS Quality Assurance Manual (QAM) and Standard Operating Procedures (SOP) address

all of the QAQC aspects of this project The following portions of ITAS corporate QAM

Knoxville QAM and SOPs are included as attachments

bull ITAS Corporate QAM

- Section 50 - Container amp Preservation Requirements

- Section 60 - Operational Calibration Requirements

- Section 100 - Data Evaluation Validation amp Reporting

bull ITAS - Knoxville QAM

- Section K70 - Gas Chromatograph Operational Checklist

- Section K80 - Analysis of Quality Control Samples - Section K90 - Method Numbers and References

- Section K100 - Data Verification

- Section KllO - Data Reports

bull ITAS Standard Operating Procedures

- Organochlorine PesticidePCB Extraction for WaterEffluent Samples

- Extraction of PesticidesPCBs from SoilSediment Samples (Commercial Prep) - Sample Concentration Technique for GC Extracts

- Calibration and Linearity Procedure for GCEC Instruments

- GC Sample Analysis and Tracking

- Identification and Quantitation (Section 50)

These procedures and manuals will be made available upon request


bull Containers amp Preservation - All sample bottles are supplied to LMS by ITAS and are cleaned according to SOP No QA841214RO-2 Glassware Cleaning Procedure for Organic Prep All samples to be analyzed for PCB are stored in amber glass bottles with teflon-lined caps Storage is at 4 deg C and

5 Lawler Matusky amp Skelly Engineers

extraction must occur within 7 days of sampling analysis is required within 40 days of extraction

bull Duplicate Sample Evaluation - Duplicate samples are used to determine the precision of the analytical method for the sample matrix One Matrix SpikeMatrix Spike Duplicate (MSMSD) is required per 20 samples II LMS does not take 20 samples during a survey 1 MSMSD will be provided per survey

bull Matrix Blank Evaluations - The observed recovery of the matrix spike versus the theoretical spike recovery is used to calculate the percent recovery value 1 MSMSD is being performed for each survey

bull Field Blank - ITAS supplies LMS with one field blank per survey This blank is passed through the same sampling procedure as the regular water column samples and thus would indicate any sources of contamination from the field procedures

bull Gas Chromatograph - Calibration is performed with 5 concentrations and a blank and is verified with 1 concentration Acceptable limits are within 10 of the calibration curve Calibration is performed initially and verification is performed on a daily basis


reporting procedures Data validation is a systematic procedure of reviewing a body of data

against a set of criteria to verify its validity prior to its intended use Checks are made for

internal consistency proper identification transmittal errors calculation errors and

transcription errors Final review of the data is performed by the Operations Manager Draft

data reports are checked against the reviewed data to ensure no transcription errors

A copy of the QAQC results will be provided to GE with the Task 2 data submittal

Lavvler Matusky amp Skelly Engineers

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ATTACHMENT 2

STATISTICAL PARAMETERS

ORDINARY LEAST SQUARES REGRESSION RESULTS

GREAT BARRINGTON ONLY

Parameter SEof Prob Sequential Simple R2 R2Variable Estimate Estimate t-value Level

Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS

Variable Parameter Estimate

SEof Estimate t-value

Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887

STEPWISE MULTIPLE REGRESSION ANALYSIS RESULTS

GREAT HARRINGTON ONLY



Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp

1 1 2 1 1 24 12 3 File24Calib12Aug91NEUCAL23 w MA tnb base SS BC=178mgl neu 3amp4 vuseg4 d=1u 4 Time 5 10011 6 1 1 1 1 1 1 3 3 3 3 3 3 7 1 1 8 6 1 Interstitial Water Diffusion 9 10 2 10 1 7 1 11 0121 525 12 10 Million ft3day 13 2 8 1 14 0126 525 15 10 Million ft3day 16 3 9 1 17 0194 525 18 10 Million ft3day 19 4 10 1 20 0369 525 21 10 Million ft3day 22 5 11 1 23 0155 525 24 10 M i l l i o n ft3day 25 6 12 1 26 0280 525 27 10 Million ft3day 28 1 12 29 1618 1698 3531 6422 531 4943 015 016 30 024 046 019 043 31 10 Million ft3 32 3 33 12 2 0 Hydrodynamic Flow 34 10 2 1 0 3 35 1 0 18 36 1185 30 1083 60 465 90 244 120 37 218 150 599 180 883 210 632 240 38 582 270 331 300 160 330 1046 360 39 1333 390 463 420 229 450 214 480 40 138 510 134 525 41 10 ft3s 1 42 2 1 18 43 1185 30 1083 60 465 90 244 120 44 218 150 599 180 883 210 632 240 45 582 270 331 300 160 330 1046 360 46 1333 390 463 420 229 450 214 480 47 138 510 134 525 48 10 ft3s 49 2 0 18 50 51 30 47 60 20 90 11 120 51 9 150 26 180 38 210 27 240 52 25 270 14 300 7 330 45 360 53 58 390 20 420 10 450 9 480 54 6 510 6 525 55 10 ft3s 56 3 2 18 57 1236 30 1130 60 485 90 254 120

2 3 4 5 6 7 8

Note Bed segment numbers do not correspond to the numbering system used in the text since only 12 out of 22 segments were included in the model calibration WASTOX2 requires that bed segments be numbered consecutively after water column segments so bed segments 7 through 12 in this file correspond to bed segments 12 through 22 in the text

File newcal24inp 08-13-91 page 2 1 2 3 4 5 bull bull 7 8

58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8

File newcal24inp 08-13-91 page 3 1 bull 2 bull ^ 4 shyS bull 6 7 8

115 1037 270 622 300 288 330 1804 360 116 2274 390 789 420 377 450 349 480 117 220 510 216 525 118 10 ft3s 119 6 1 0 Resuspension Flow 120 10 3 121 1 7 18 122 000138 30 000138 60 0 000886 90 0 000886 120 123 0000886 150 0000886 180 000118 210 0 000886 240 124 0000886 270 0000886 300 0 000886 330 000138 360 125 000167 390 0000886 420 0 000886 450 0 000886 480 126 0000886 510 0000886 525 127 10 ft3s 1 128 2 8 18 129 000204 30 00018 60 00012 90 00012 120 130 00012 150 00012 180 000144 210 00012 240 131 00012 270 00012 300 00012 330 00018 360 132 00024 390 00012 420 00012 450 00012 480 133 00012 510 00012 525 134 10 ft3s 135 3 9 18 136 000847 30 001685 60 000270 90 000237 120 137 000229 150 001781 180 001922 210 000924 240 138 000319 270 000270 300 000229 330 002630 360 139 002667 390 000328 420 000237 450 000237 480 HO 000229 510 000229 525 141 10 ft3s 142 4 10 18 143 000847 30 001685 60 000270 90 000237 120 144 000229 150 001781 180 001922 210 000924 240 145 000319 270 000270 300 000229 330 002630 360 146 002667 390 000328 420 000237 450 000237 480 147 000229 510 000229 525 148 10 ft3s 149 5 11 18 150 000382 30 000356 60 000121 90 000104 120 151 000104 150 000121 180 000217 210 000147 240 152 000139 270 000113 300 0 000954 330 000312 360 153 000503 390 000121 420 000104 450 000104 480 154 0000954 510 0000868 525 155 10 ft3s 156 6 12 18 157 000161 30 000147 60 000063 90 000063 120 158 000063 150 000063 180 000105 210 000077 240 159 000070 270 000063 300 000063 330 000133 360 160 000224 390 000063 420 000063 450 000063 480 161 000063 510 000063 525 162 10 ft3s 163 6 1 0 Settling Flow 164 10 3 165 7 1 18 166 127 30 127 60 127 90 127 120 167 127 150 127 180 127 210 127 240 168 127 270 127 300 127 330 127 360 169 127 390 127 420 127 450 127 480 170 127 510 127 525 171 10 ft3s 1

File newcal24 inp 08-13-91 page 4 1 2 3 t S bull A bull 7 - 8

172 8 2 18 173 111 30 111 60 111 90 111 120 174 111 150 111 180 111 210 111 240 175 111 270 111 300 111 330 111 360 176 111 390 111 420 111 450 111 480 177 111 510 111 525 178 10 ft3s 179 9 3 18 180 153 30 153 60 153 90 153 120 181 153 150 153 180 153 210 153 240 182 153 270 153 300 153 330 153 360 183 153 390 153 420 153 450 153 480 184 153 510 153 525 185 10 ft3s 186 10 4 18 187 267 30 267 60 267 90 267 120 188 267 150 267 180 267 210 267 240 189 267 270 267 300 267 330 267 360 190 267 390 267 420 267 450 267 480 191 267 510 267 525 192 10 ft3s 193 11 5 18 194 166 30 166 60 166 90 166 120 195 166 150 166 180 166 210 166 240 196 166 270 166 300 166 330 166 360 197 166 390 166 420 166 450 166 480 198 166 510 166 525 199 10 ft3s 200 12 6 18 201 213 30 213 60 213 90 213 120 202 213 150 213 180 213 210 213 240 203 213 270 213 300 213 330 213 360 204 213 390 213 420 213 450 213 480 205 213 510 213 525 206 10 ft3s 207 12 PCB Boundary Conditions 208 1 18 209 000075 30 000094 60 000080 90 000088 120 000087 150 210 000073 180 000073 210 000072 240 000077 270 000070 300 211 000071 330 000120 360 000101 390 000080 420 000081 450 212 000081 480 000078 510 000078 525 213 1 mgl 1 214 2 18 215 0000080 30 0000080 60 0000080 90 0000080 120 0000080 150 216 0000080 180 0000080 210 0000080 240 0000080 270 0000080 300 217 0000080 330 0000080 360 0000080 390 0000080 420 0000080 450 218 0000080 480 0000080 510 0000080 525 219 1 mgt 220 3 18 221 0000080 30 0000080 60 0000080 90 0000080 120 0000080 150 222 0000080 180 0000080 210 0000080 240 0000080 270 0000080 300 223 0000080 330 0000080 360 0000080 390 0000080 420 0000080 450 224 0000080 480 0000080 510 0000080 525 225 1 mgl 226 4 18 227 0000080 30 0000080 60 0000080 90 0000080 120 0000080 150 228 0000080 180 0000080 210 0000080 240 0000080 270 0000080 300

Fi le neucal24inp 08-13-91 page 5 1 2 3 4 5 6 7 8

229 0000080 330 0000080 360 0000080 390 0000080 420 0000080 450 230 0000080 480 0000080 510 0000080 525 231 1 mgl 232 5 18 233 0000080 30 0000080 60 0000080 90 0000080 120 0000080 150 234 0000080 180 0000080 210 0000080 240 0000080 270 0000080 300 235 0000080 330 0000080 360 0000080 390 0000080 420 0000080 450 236 0000080 480 0000080 510 0000080 525 237 1 mgl 238 6 18 239 0000080 30 0000080 60 0000080 90 0000080 120 0000080 150 240 0000080 180 0000080 210 0000080 240 0000080 270 0000080 300 241 0000080 330 0000080 360 0000080 390 0000080 420 0000080 450 242 0000080 480 0000080 510 0000080 525 243 1 mgl 244 7 18 245 157 30 1 57 60 157 90 157 120 157 150 246 157 180 1 57 210 157 240 157 270 157 300 247 157 330 1 57 360 157 390 157 420 157 450 248 157 480 1 57 510 157 525 249 1 mgl 250 8 18 251 130 30 1 30 60 130 90 130 120 130 150 252 130 180 1 30 210 130 240 130 270 130 300 253 130 330 1 30 360 130 390 130 420 130 450 254 130 480 1 30 510 130 525 255 1 mgt 256 9 18 257 037 30 0 37 60 037 90 037 120 037 150 258 037 180 0 37 210 037 240 037 270 037 300 259 037 330 0 37 360 037 390 037 420 037 450 260 037 480 0 37 510 037 525 261 1 mgl 262 10 18 263 047 30 0 47 60 047 90 047 120 047 150 264 047 180 0 47 210 047 240 047 270 047 300 265 047 330 0 47 360 047 390 047 420 047 450 266 047 480 0 47 510 047 525 267bull 1 mgl 268 11 18 269 081 30 0 81 60 081 90 081 120 081 150 270 081 180 0 81 210 081 240 081 270 081 300 271 081 330 0 81 360 081 390 081 420 081 450 272 081 480 0 81 510 081 525 273 1 mgl 274 12 18 275 066 30 0 66 60 066 90 066 120 066 150 276 066 180 0 66 210 066 240 066 270 066 300 277 066 330 0 66 360 066 390 066 420 066 450 278 066 480 0 66 510 066 525 279 1 mgl 280 12 ss Boundary Conditions 281 1 18 282 63 30 13 8 60 81 90 115 120 112 150 283 54 180 53 210 50 240 68 270 42 300 284 44 330 24 4 360 167 390 83 420 87 450 285 87 480 75 510 72 525

23456 7

File newcal24inp 08-13-91 page 6

286 10 mgl 1 287 2 18 288 178 30 178 60 178 90 178 120 178 150 289 178 180 178 210 178 240 178 270 178 300 290 178 330 178 360 178 390 178 420 178 450 291 178 480 178 510 178 525 292 10 mgl 293 3 18 294 700 30 700 60 178 90 178 120 178 150 295 700 180 700 210 700 240 178 270 178 300 296 178 330 700 360 700 390 178 420 178 450 297 178 480 178 510 178 525 298 10 mgl 299 4 18 300 700 30 700 60 178 90 178 120 178 150 301 700 180 700 210 700 240 700 270 178 300 302 178 330 700 360 700 390 178 420 178 450 303 178 480 178 510 178 525 304 10 mgl 305 5 18 306 178 30 178 60 178 90 178 120 178 150 307 178 180 178 210 178 240 178 270 178 300 308 178 330 178 360 178 390 178 420 178 450 309 178 480 178 510 178 525 310 10 mgl 311 6 18 312 178 30 178 60 178 90 178 120 178 150 313 178 180 178 210 178 240 178 270 178 300 314 178 330 178 360 178 390 178 420 178 450 315 178 480 178 510 178 525 316 10 mgl 317 7 18 318 143E6 30 1 43E6 60 143E6 90 143E6 120 1 43E6 150 319 143E6 180 1 43E6 210 143E6 240 143E6 270 1 43E6 300 320 143E6 330 1 43E6 360 143E6 390 143E6 420 1 43E6 450 321 143E6 480 1 43E6 510 143E6 525 322 10 mgl 323 8 18 324 094E6 30 094E6 60 094E6 90 094E6 120 094E6 150 325 094E6 180 094E6 210 094E6 240 094E6 270 094E6 300 326 094E6 330 094E6 360 094E6 390 094E6 420 094E6 450 327 094E6 480 094E6 510 094E6 525 328 10 mgl 329 9 18 330 065E6 30 065E6 60 065E6 90 065E6 120 065E6 150 331 065E6 180 065E6 210 065E6 240 065E6 270 065E6 300 332 065E6 330 065E6 360 065E6 390 065E6 420 065E6 450 333 065E6 480 065E6 510 065E6 525 334 10 mgl 335 10 18 336 065E6 30 065E6 60 065E6 90 065E6 120 065E6 150 337 065E6 180 065E6 210 065E6 240 065E6 270 065E6 300 338 065E6 330 065E6 360 065E6 390 065E6 420 065E6 450 339 065E6 480 065E6 510 065E6 525 340 10 mgl 341 11 18 342 135E6 30 1 35E6 60 135E6 90 135E6 120 135E6 150

1 f 3 4 5 6 7 8

File ne wea1 24 inp 08-13-91 page 7 1 2 3 4 S 6 7

343 1 35E6 180 1 35E6 210 1 35E6 240 1 35E6 270 1 35E6 300 344 1 35E6 330 1 35E6 360 1 35E6 390 1 35E6 420 1 35E6 450 345 1 35E6 480 1 35E6 510 1 35E6 525 346 10 mgl 347 12 18 348 1 10E6 30 1 10E6 60 1 10E6 90 1 10E6 120 1 10E6 150 349 1 10E6 180 1 10E6 210 1 10E6 240 1 10E6 270 1 10E6 300 350 1 10E6 330 1 10E6 360 1 10E6 390 1 10E6 420 1 10E6 450 351 1 10E6 480 1 10E6 510 1 10E6 525

352 10 mgl 353 0 354 0 355 DPTH 274 TDPT 0 DSEG 7 AREA 180E6 VEL 022 356 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 357 BACU KL 0 BCS1 FOC1 003 358 DPTH 277 TDPT 0 DSEG 8 AREA 187E6 VEL 022 359 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 360 BACU KL 0 BCS1 FOCI 003 361 DPTH 372 TDPT 0 DSEG 9 AREA 289E6 VEL 020 362 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 363 BACW KL 0 BCS1 FOC1 003 364 DPTH 357 TDPT 0 DSEG 10 AREA 549E6 VEL 017 365 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 366 BACW KL 0 BCS1 FOC1 003 367 DPTH 070 TDPT 0 DSEG 11 AREA 231E6 VEL 052 368 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 369 BACU KL 0 BCS1 FOC1 003 370 DPTH 326 TDPT 0 DSEG 12 AREA 462E6 VEL 017 371 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 372 BACU KL 0 BCS1 FOC1 003 373 DPTH 025 TDPT 274 DSEG 0 AREA 180E6 VEL 0 374 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 375 BACU KL 0 BCS1 FOC1 0039 376 DPTH 025 TDPT 277 DSEG 0 AREA 1 87E6 VEL 0 377 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 378 BACU KL 0 BCS1 FOC1 0039 379 DPTH 025 TDPT 372 DSEG 0 AREA 289E6 VEL 0 380 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 381 BACU KL 0 BCS1 FOCI 0044 382 DPTH 025 TDPT 357 DSEG 0 AREA 549E6 VEL 0 383 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 384 BACU KL 0 BCS1 FOC1 0033 385 DPTH 025 TDPT 070 DSEG 0 AREA 231E6 VEL 0 386 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 387 BACU KL 0 BCS1 FOC1 0019 388 DPTH 028 TDPT 326 DSEG 0 AREA 462E6 VEL 0 389 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 390 BACU KL 0 BCS1 FOC1 0019 391 SOPT 1 K020 0 KDT 1 KP20 0 KPT 1 392 KHOH 0 KHN 0 KHH 0 KHT 1 USEG 6 393 HNRY 7188 MLUT 372 VOPT 4 KLT 1 ATMS 0 394 1FLU 0 ATMP 20 LKOU 65 NUX 14 ADOC 002 395 ADCS 002 K12 0 RH01 2 396 0 397 0 398 PCB1 1E-6 PCB2 1E-6 PCB3 1E-6 PCB4 1E-6 PCB5 1E-6 399 PCB6 1E-6 PCB7 157 PCB8 130 PCB9 037 10 047

File newcal24inp 1 2 3 4 bull 5 6 7

400 11 81 12 66 401 M1 1 M2 1 M3 1 M4 1 M5 1 402 M6 1 M7 143E6 M8 094E6 M9 065E6 10 065E6 403 11 135E6 12 110E6 404 1E9 1E9 1E9 405 15 406 1 407 05 525 408 525 409 0 410 TOT TOX DIS TOX PAR TOX DOC TOX 411 1 1 ALL 412 2 1 ALL 413 3 1 ALL 414 4 1 ALL 415 416 SOLIDS SED VEL 417 1 1 ALL 418 2 1 ALL 419 420 12345678901234567890123456789012345678901234567890123456789012345678901234567890

1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1

2 1 4 8 24 3 File08MA+ CTProj12Aug91ALLPR07wMA tnb SS base=178mgl new 3amp4 vuseg4 d=1in 4 Time 5 10011 6 1 1 1 1 1 1 1 1 1 1 1 1 3 3 3 7 3 3 3 3 3 3 3 3 3 8 1 1 9 12 1 Interstitial Water Diffusion

10 2 11 1 13 1

12 0121 360 13 10 Million ft3day 14 2 14 1 15 0126 360 16 10 Million ft3day

17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751

51 10 Million ft3 52 3 53 24 2 0 HydrooYnamic Flow

54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114

inp 08-13-91 page 2 1 2 3 It 5 bull A shy 7 8

295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8

File new8i np 1 2 3 4 5 bull 6 bull 7 bull 8

115 7 0 12 116 194 30 194 60 269 90 312 120 117 218 150 174 180 145 210 140 240 118 140 270 145 300 175 330 190 360 119 10 ft3s 120 8 7 12 121 1299 30 1295 60 2243 90 2775 120 122 1603 150 1066 180 716 210 645 240 123 653 270 714 300 1081 330 1268 360 124 10 ft3s 125 8 0 12 126 77 30 76 60 145 90 183 120 127 98 150 60 180 35 210 29 240 128 30 270 34 300 61 330 74 360 129 10 ft3s 130 9 8 12 131 1376 30 1371 60 2388 90 2958 120 132 1701 150 1126 180 751 210 674 240 133 683 270 748 300 1142 330 1342 360 134 10 ft3s 135 9 0 12 136 525 30 523 60 973 90 1225 120 137 670 150 413 180 251 210 217 240 138 221 270 250 300 421 330 513 360 139 10 ft3s 140 10 9 12 141 1901 30 1894 60 3361 90 4183 120 142 2371 150 1539 180 1002 210 891 240 143 904 270 998 300 1563 330 1855 360 144 10 ft3s 145 10 0 12 146 519 30 517 60 950 90 1191 120 147 662 150 419 180 260 210 227 240 148 231 270 259 300 421 330 506 360 149 10 ft3s 150 11 10 12 151 2420 30 2411 60 4311 90 5374 120 152 3033 150 1958 180 1262 210 1118 240 153 1135 270 1257 300 1984 330 2361 360 154 10 ft3s 155 11 0 12 156 243 30 242 60 441 90 553 120 157 305 150 192 180 120 210 105 240 158 107 270 120 300 199 330 237 360 159 10 ft3s 160 12 11 12 161 2663 30 2653 60 4752 90 5927 120 162 3338 150 2150 180 1382 210 1223 240 163 1242 270 1377 300 2183 330 2598 360 164 10 ft3s 165 12 0 12 166 10 30 10 60 10 90 10 120 167 10 150 10 180 10 210 10 240 168 10 270 10 300 10 330 10 360 169 10 ft3s 170 0 12 12 171 2673 30 2663 60 4762 90 5937 120

1 2 3 4 5 6 7 8

Fil e neu8 inp 08-13-91 page 4 bull i 2 3 4 5 6 7 8

172 3348 150 2160 180 1392 210 1233 240 173 1252 270 1387 300 2193 330 2608 360 174 10 ft3s 175 12 1 0 Resuspension Flow 176 10 3 177 1 13 12 178 00009 30 00009 60 00013 90 00019 120 179 00010 150 00009 180 00009 210 00009 240 180 00009 270 00009 300 00009 330 00009 360 181 1 0000 ft3s 182 2 14 12 183 00010 30 00010 60 00016 90 00022 120 184 00012 150 00010 180 00010 210 00010 240 185 00010 270 00010 300 00010 330 00010 360 186 1 0000 ft3s 187 3 15 12 188 00033 30 00033 60 00084 90 00122 120 189 00068 150 00028 180 00027 210 00026 240 190 00027 270 00027 300 00028 330 00030 360 191 1 0000 ft3s 192 4 16 12 193 00065 30 00065 60 00084 90 00122 120 194 00068 150 00028 180 00027 210 00026 240 195 00027 270 00027 300 00028 330 00059 360 196 1 0000 ft3s 197 5 17 12 198 000136 30 000136 60 000302 90 000504 120 199 000177 150 000111 180 000091 210 000091 240 200 000091 270 000091 300 000111 330 000136 360 201 1 0000 ft3s 202 6 18 12 203 000166 30 000166 60 000298 90 000497 120 204 000182 150 000166 180 000166 210 000166 240 205 000166 270 000166 300 000166 330 000166 360 206 1 0000 ft3s 207 7 19 12 208 035417 30 035417 60 051983 90 062836 120 209 042843 150 029133 180 021707 210 019993 240 210 019993 270 021707 300 029133 330 035131 360 211 1 0000 cfs 212 8 20 12 213 001436 30 001436 60 004168 90 006468 120 214 002012 150 001436 180 001436 210 001436 240 215 001436 270 001436 300 001436 330 001436 360 216 1 0000 cfs 217 9 21 12 218 012834 30 012647 60 022461 90 028878 120 219 015722 150 011872 180 010588 210 010588 240 220 010588 270 010588 300 011872 330 012834 360 221 1 0000 cfs 222 10 22 12 223 00 30 00 60 00 90 00 120 224 00 150 00 180 00 210 00 240 225 00 270 00 300 00 330 00 360 226 10 cfs 227 11 23 12 228 00 30 00 60 00 90 00 120

f 1 2 3 4 5 6 7 8

F i l e new8 inp 08-13-bull91 page 5 1 2 3 t 6 7 8

229 00 150 00 180 00 210 00 240 230 00 270 00 300 00 330 00 360 231 10 cfs 232 12 24 12 233 00 30 00 60 00 90 00 120 234 00 150 00 180 00 210 00 240 235 00 270 00 300 00 330 00 360 236 10 cfs 237 12 1 0 Settt ing Flow 238 10 3 239 13 1 12 240 123 30 123 60 123 90 123 120 241 123 150 123 180 123 210 123 240 242 123 270 123 300 123 330 123 360 243 1 0000 ft3s 244 14 2 12 245 98 30 98 60 98 90 98 120 246 98 150 98 180 98 210 98 240 247 98 270 98 300 98 330 98 360 248 1 0000 ft3s 249 15 3 12 250 129 30 129 60 129 90 129 120 251 129 150 129 180 129 210 129 240 252 129 270 129 300 129 330 129 360 253 1 0000 ft3s 254 16 4 12 255 267 30 267 60 267 90 267 120 256 267 150 267 180 267 210 267 240 257 267 270 267 300 267 330 267 360 258 10000 ft3s 259 17 5 12 260 178 30 178 60 178 90 178 120 261 178 150 178 180 178 210 178 240 262 178 270 178 300 178 330 178 360 263 1 0000 ft3s 264 18 6 12 265 140 30 140 60 140 90 140 120 266 140 150 140 180 140 210 140 240 267 140 270 140 300 140 330 140 360 268 1 0000 ft3s 269 19 7 12 270 2165 30 2165 60 2165 90 2165 120 271 2165 150 2165 180 2165 210 2165 240 272 2165 270 2165 300 2165 330 2165 360 273 1 0000 ft3s 274 20 8 12 275 478 30 478 60 478 90 478 120 276 478 150 478 180 478 210 478 240 277 478 270 478 300 478 330 478 360 278 1 0000 ft3s 279 21 9 12 280 916 30 916 60 916 90 916 120 281 916 150 916 180 916 210 916 240 282 916 270 916 300 916 330 916 360 283 1 0000 ft3s 284 22 10 12 285 2805 30 2805 60 2805 90 2805 120

5

1 2 3 4 5 6 7 8

neuS inp 08-13-91 page 6 3 8 1 bull 2 4 5 6 7

286 2805 150 2805 180 2805 210 2805 240 287 2805 270 2805 300 2805 330 2805 360 288 10000 ft3s 289 23 11 12 290 3450 30 3450 60 3450 90 3450 120 291 3450 150 3450 180 3450 210 3450 240 292 3450 270 3450 300 3450 330 3450 360 293 10000 ft3s 294 24 12 12 295 3450 30 3450 60 3450 90 3450 120 296 3450 150 3450 180 3450 210 3450 240 297 3450 270 3450 300 3450 330 3450 360 298 1000 ft3s 299 24 PCS Boundary Conditions 300 1 12 301 0066 900 0058 2700 0045 4500 0035 6300 0028 8100 302 0021 9900 001711700 001313500 001015300 000817100 303 000616000 000618000 304 1E-3 mgl 1 305 2 12 306 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 307 00050 9900 0 005011700 0005013500 0005015300 0005017100 308 0005016000 0 005018000 309 1E-3 mgl 310 3 12 311 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 312 00050 9900 0 005011700 0005013500 0005015300 0005017100 313 0005016000 0 005018000 314 1E-3 mgl 315 4 12 316 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 317 00050 9900 0 005011700 0005013500 0005015300 0005017100 318 0005016000 0 005018000 319 1E-3 mgl 320 5 12 321 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 322 00050 9900 0 005011700 0005013500 0005015300 0005017100 323 0005016000 0 005018000 324 1E-3 mgl 325 6 12 326 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 327 00050 9900 0 005011700 0005013500 0005015300 0005017100 328 0005016000 0 005018000 329 1E-3 mgl 330 7 12 331 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 332 00050 9900 0 005011700 0005013500 0005015300 0005017100 333 0005016000 0 005018000 334 1E-3 mgl 335 8 12 336 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 337 00050 9900 0 005011700 0005013500 0005015300 0005017100 338 0005016000 0 005018000 339 1E-3 mgl 340 9 12 341 00080 900 0 0062 2700 00050 4500 00050 6300 00050 8100 342 00050 9900 0 005011700 0005013500 0005015300 0005017100

gt newS inp 08-13-91 page 7 1 2 bull 3 4 5 6 7

343 0005016000 0005018000 344 1E-3 mgl 345 10 12 346 0085 900 0066 2700 0052 4500 0050 6300 0050 8100 347 0050 9900 005011700 005013500 005015300 005017100 348 005016000 005018000 349 1E-3 mgl 350 11 12 351 00080 900 00062 2700 00050 4500 00050 6300 00050 8100 352 00050 9900 0005011700 0005013500 0005015300 0005017100 353 0005016000 0005018000 354 1E-3 mgl 355 12 12 356 00080 900 00062 2700 00050 4500 00050 6300 00050 8100 357 00050 9900 0005011700 0005013500 0005015300 0005017100 358 0005016000 0005018000 359 1E-3 mgl 360 13 12 361 157 900 157 2700 157 4500 157 6300 157 8100 362 157 9900 15711700 15713500 15715300 15717100 363 15716000 15718000 364 1E-3 mgl 365 14 12 366 130 900 130 2700 130 4500 130 6300 130 8100 367 130 9900 13011700 13013500 13015300 13017100 368 13016000 13018000 369 1E-3 mgl 370 15 12 371 037 900 037 2700 037 4500 037 6300 037 8100 372 037 9900 03711700 03713500 03715300 03717100 373 03716000 03718000 374 1E-3 mgl 375 16 12 376 047 900 047 2700 047 4500 047 6300 047 8100 377 047 9900 04711700 04713500 04715300 04717100 378 04716000 04718000 379 1E-3 mgl 380 17 12 381 081 900 081 2700 081 4500 081 6300 081 8100 382 081 9900 08111700 08113500 08115300 08117100 383 08116000 08118000 384 1E-3 mgl 385 18 12 386 066 900 066 2700 066 4500 066 6300 066 8100 387 066 9900 06611700 06613500 06615300 06617100 388 06616000 06618000 389 1E-3 mgl 390 19 12 391 580 900 580 2700 580 4500 580 6300 580 8100

392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56

newS i np 08-13-91 page 8 1 bull bull U_ bull 7 _ bull _ 5 bull 6 7

400 21 12 401 360 900 360 2700 360 4500 360 6300 360 8100 402 360 9900 36011700 36013500 36015300 36017100 403 36016000 36018000 404 1000 mg1 405 22 12 406 550 900 550 2700 550 4500 550 6300 550 8100 407 550 9900 55011700 55013500 55015300 55017100 408 55016000 55018000 409 1000 mgl 410 23 12 411 630 900 630 2700 630 4500 630 6300 630 8100 412 630 9900 63011700 63013500 63015300 63017100 413 63016000 63018000 414 1000 mgl 415 24 12 416 630 900 630 2700 630 4500 630 6300 630 8100 417 630 9900 63011700 63013500 63015300 63017100 418 63016000 63018000 419 1000 mgl 420 24 SS Boundary Conditions 421 1 12 422 126 30 126 60 126 90 12 6 120 126 150 423 126 180 126 210 126 240 12 6 270 126 300 424 126 330 126 360 425 10 mgl 1 426 2 12 427 178 30 178 60 178 90 17 8 120 178 150 428 178 180 178 210 178 240 17 8 270 178 300 429 178 330 178 360 430 10 mgl 431 3 12 432 178 30 178 60 700 90 70 0 120 700 150 433 178 180 178 210 178 240 17 8 270 178 300 434 178 330 178 360 435 10 mgl 436 4 12 437 700 30 700 60 700 90 70 0 120 700 150 438 178 180 178 210 178 240 17 8 270 178 300 439 178 330 700 360 440 10 mgl 441 5 12 442 178 30 178 60 178 90 17 8 120 178 150 443 178 180 178 210 178 240 17 8 270 178 300 444 178 330 178 360 445 10 mgl 446 6 12 447 178 30 178 60 178 90 17 8 120 178 150 448 178 180 178 210 178 240 17 8 270 178 300 449 178 330 178 360 450 10 mgl 451 7 12 452 178 30 178 60 178 90 17 8 120 178 150 453 178 180 178 210 178 240 17 8 270 178 300 454 178 330 178 360 455 10 mgl 456 8 12

gt neu8 inp 08-13-91 page 9 1 2 3 bull 4 = bull _k shy 7 8

457 178 30 178 60 178 90 178 120 178 150 458 178 180 178 210 178 240 178 270 178 300 459 178 330 178 360 460 10 mgt 461 9 12 462 178 30 178 60 178 90 178 120 178 150 463 178 180 178 210 178 240 178 270 178 300 464 178 330 178 360 465 10 mgl 466 10 12 467 216 30 216 60 216 90 216 120 216 150 468 216 180 216 210 216 240 216 270 216 300 469 216 330 216 360 470 10 mgl 471 11 12 472 216 30 216 60 216 90 216 120 216 150 473 216 180 216 210 216 240 216 270 216 300 474 216 330 216 360 475 10 mgl 476 12 12 477 216 30 216 60 216 90 216 120 216 150 478 216 180 216 210 216 240 216 270 216 300 479 216 330 216 360 480 10 mgl 481 13 12 482 143E6 30 1 43E6 60 1 43E6 90 143E6 120 143E6 150 483 143E6 180 1 43E6 210 143E6 240 143E6 270 143E6 300 484 143E6 330 1 43E6 360 485 10 mgl 486 14 12 487 094E6 30 094E6 60 094E6 90 094E6 120 094E6 150 488 094E6 180 094E6 210 094E6 240 094E6 270 094E6 300 489 094E6 330 094E6 360 490 10 mgl 491 15 12 492 065E6 30 065E6 60 065E6 90 065E6 120 065E6 150 493 065E6 180 065E6 210 065E6 240 065E6 270 065E6 300 494 065E6 330 065E6 360 495 10 mgl 496 16 12 497 065E6 30 065E6 60 065E6 90 065E6 120 065E6 150 498 065E6 180 065E6 210 065E6 240 065E6 270 065E6 300 499 065E6 330 065E6 360 500 10 mgl 501 17 12 502 1349E6 30 1 349E6 60 1349E6 90 1349E6 120 1349E6 150 503 1349E6 180 1 349E6 210 1349E6 240 1349E6 270 1349E6 300 504 1349E6 330 1 349E6 360 505 10 mgl 506 18 12 507 1097E6 30 1 097E6 60 1097E6 90 1097E6 120 1097E6 150 508 1097E6 180 1 097E6 210 1097E6 240 1097E6 270 1097E6 300 509 1097E6 330 1 097E6 360 510 10 mgl 511 19 12 512 1349E6 30 1 349E6 60 1349E6 90 1349E6 120 1349E6 150 513 1349E6 180 1 349E6 210 1349E6 240 1349E6 270 1349E6 300

Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7

514 1 349E6 330 1 349E6 360 515 10 mgl 516 20 i 12 517 1 416E6 30 1 416E6 60 1416E6 90 1416E6 120 1416E6 150 518 1 416E6 180 1 416E6 210 1416E6 240 1416E6 270 1416E6 300 519 1 416E6 330 1 416E6 360 520 10 mgl 521 21 12 522 1 381E6 30 1 381E6 60 1381E6 90 1381E6 120 1381E6 150 523 1 381E6 180 1 381E6 210 1381E6 240 1381E6 270 1381E6 300 524 1 381E6 330 1 381E6 360 525 10 mgl 526 22 12 527 0 512E6 30 0 512E6 60 0512E6 90 0512E6 120 0512E6 150 528 0 512E6 180 0 512E6 210 0512E6 240 0512E6 270 0512E6 300 529 0 512E6 330 0 512E6 360 530 10 mgl 531 23 12 532 0 689E6 30 0 689E6 60 0689E6 90 0689E6 120 0689E6 150 533 0 689E6 180 0 689E6 210 0689E6 240 0689E6 270 0689E6 300 534 0 689E6 330 0 689E6 360 535 10 mgl 536 24 12 537 0 689E6 30 0 689E6 60 0689E6 90 0689E6 120 0689E6 150 538 0 689E6 180 0 689E6 210 0689E6 240 0689E6 270 0689E6 300 539 0 689E6 330 0 689E6 360 540 10 mgl 541 0 542 0 543 DPTH 274 TDPT 0 DSEG 13 AREA 1 80E6 VEL 022 544 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 545 BACU KL 0 BCS1 FOC1 003 546 DPTH 277 TDPT 0 DSEG 14 AREA 1 87E6 VEL 022 547 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 548 BACU KL 0 BCS1 FOCI 003 549 DPTH 372 TDPT 0 DSEG 15 AREA 289E6 VEL 020 550 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 551 BACU KL 0 BCS1 FOC1 003 552 DPTH 357 TDPT 0 DSEG 16 AREA 5 49E6 VEL 017 553 pH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 554 BACU KL 0 BCS1 FOC1 003 555 DPTH 070 TDPT 0 DSEG 17 AREA 231E6 VEL 057 556 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 557 BACU KL 0 BCS1 FOCI 003 558 DPTH 326 TDPT 0 DSEG 18 AREA 462E6 VEL 019 559 PH 7 TEMP 20 UVEL 0 DOC 0 PDOC 0 560 BACU KL 0 BCS1 FOC1 003 561 DPTH 73 TDPT 0 DSEG 19 AREA 23 -26E6 VEL 067 562 pH 7 TEMP 20 WVEL 0 DOC 00 PDOC 0 563 BACU KL 0 BCS1 FOC1 003 564 DPTH 472 TDPT 0 DSEG 20 AREA 5 05E6 VEL 013 565 pH 7 TEMP 20 UVEL 0 DOC 00 PDOC 0 566 BACU KL 0 BCS1 FOC1 003 567 DPTH 1 19 TDPT 0 DSEG 21 AREA 12 95E6 VEL 065 568 pH 7 TEMP 20 UVEL 0 DOC 00 PDOC 0 569 BACU KL 0 BCS1 FOC1 003 570 DPTH 11 86 TDPT 0 DSEG 22 AREA 58 47E6 VEL 002

1 2 3 4 5 6 7 8

File new8 i np 08-13-91 page 11

571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4

pH 7 TEMP 20 UVEL BACW KL 0 BCS1 DPTH 750 TDPT 0 DSEG PH 7 TEMP 20 UVEL BACU KL 0 SCSI DPTH 750 TDPT 0 DSEG pH 7 TEMP 20 UVEL BACU KL 0 SCSI DPTH 025 TDPT 274 DSEG pH 7 TEMP 20 WVEL BACW KL 0 BCS1 DPTH 025 TDPT 277 DSEG pH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 025 TDPT 372 DSEG PH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 025 TDPT 357 DSEG PH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 025 TDPT 070 DSEG pH 7 TEMP 20 WVEL BACU KL 0 BCS1 DPTH 028 TDPT 326 DSEG pH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 025 TDPT 73 DSEG pH 7 TEMP 20 WVEL BACU KL 0 BCS1 DPTH 053 TDPT 472 DSEG pH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 025 TDPT 119 DSEG pH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 122 TDPT 1186 DSEG pH 7 TEMP 20 WVEL BACU KL 0 BCS1 DPTH 074 TDPT 750 DSEG PH 7 TEMP 20 UVEL BACU KL 0 BCS1 DPTH 074 TDPT 750 DSEG PH 7 TEMP 20 WVEL BACU KL 0 BCS1 SOPT 1 KD20 0 KDT KHOH 0 KHN 0 KHH HNRY 7188 MLUT 372 VOPT 1FLU 0 ATMP 20 LKOW ADCS 002 K12 0 RH01

0 0

PCB1 1E-6 PCB2 1E-6 PCB3 PCB6 1E-6 PCB7 1E-6 PCB8

11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3

5 bull f 7 0 DOC 00 PDOC 0

FOC1 003 23 AREA 3101E6 VEL 004 0 DOC 00 PDOC 0



FOCI 0039 0 AREA 187E6 VEL 0 0 DOC 0 PDOC 0











FOC1 0081 1 KP20 0 KPT 1 0 KHT 1 WSEG 12 4 KLT 1 ATMS 0 65 NUX 14 ADOC 002 2

1E-6 PCB4 1E-6 PCB5 1E-6 1E-6 PCB9 1E-6 10 1E-6 157 14 130 15 037 66 19 058 20 037 63 24 63 1 M4 1 M5 1

File new8 i np 08-13-91 page 12 1 2 3 4 5 shy _ bull 7 8

628 H6 1 M7 1 H8 1 M9 1 H10 1 629 M11 1 M12 1 H13 143E6 MH 094E6 M15 065E6 630 M16 065E6 H17 135E6 M18 110E6 M19 135E6 M20 142E6 631 M21 1 38E6 M22 051E6 M23 069E6 M24 069E6 632 1E9 1E9 1E9 633 90 634 1 635 05 18000 636 18000 637 0 638 TOT TOX DIS TOX PAR TOX DOC TOX 639 1 1 ALL 640 2 1 ALL 641 3 1 ALL 642 4 1 ALL 643 644 SOLIDS SED VEL 645 1 1 ALL 646 2 1 ALL 647 648 12345678901234567890123456789012345678901234567890123456789012345678901234567890 649

12345678

ATTACHMENT 4

EXAMPLE CALCULATION OF PARTICULATE AND DISSOLVED PCB CONCENTRATIONS

EXAMPLE CALCULATIONS OF DISSOLVED AND PARTICULATE PHASES OF PCB

Assumptions cu w= 006 jig1 laquobdquo =10 cub = 10 mg1 0b = 07 m = 100 mg1 K = 32xl06

mb = falO5 mg1 f^ = 002 (bed amp water column)

auations

ct = $cd + me (3-2)

Partitioning bull Water column

H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)

Fraction of PCB in dissolved (fd) and paniculate phases (f )

Calculating the Partition Coefficient bull Water column

II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg

Calculating Fraction of PCB in Dissolved Phase (L) and Paniculate Phase (fp) bull Water column

fd = -mdash-= 069 1 + (00439 mdash )(10 ^pound)

mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed

fd = mdash = 000002 07 + (0064 mdashX6X105 ^pound)

mg I

(0064 mdash)(6xl05 -5S) - 5S-=- 099998 07 + (0064 mdash X6X105 -^)

w

Calculate Dissolved and Paniculate Phaaes of PCB bull Water column

= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed

Cj = ff^ = (000002X10 mgfl) = 2xlQ-5 mgfl = 002 igfl

(099998)(10 -^)(1000 M) = 167xlO-3 ngfmg = 167 raquoglg

6X105 -^

TABLE OF CONTENTS

Page No

LIST OF FIGURES iii

LIST OF TABLES vi

SUMMARY S-l

51 Introduction S-l 52 Ambient Trend Monitoring S-l 53 PCB Fate and Transport Model S-2 54 Projections of PCB Concentrations S-2 55 Future Monitoring S-3

1 INTRODUCTION 1-1

11 General Background 1-1 12 Report Organization 1-2

2 AMBIENT TRENDS 2-1

21 Ambient Trend Monitoring 2-1

211 Sampling Methods and Quality AssuranceQuality Control 2-1 212 Results of Surveys at Great Barrington 2-3

22 Analysis of Ambient Trends in the Vicinity of Great Barrington 2-5

221 Introduction 2-5 222 Methods 2-5 223 Results 2-6

3 PCB FATE AND TRANSPORT MODEL 3-1

31 Description of WASTOX Model 3-1 32 Parameter Evaluation 3-7

321 River Segmentation and Hydrology 3-7 322 Bed Sediment Characteristics 3-7 323 Settling Resuspension and Burial 3-8 324 Sediment - Water Partitioning 3-10 325 Bed Sediment - Water Column Diffusion 3-11 326 Volatilization 3-12 327 Upstream Tributary Suspended Solids and PCBs 3-12



Page No


331 Solids 3-14 332 PCBs 3-15





REFERENCES R-l

ATTACHMENTS






LIST OF FIGURES



Schematic


Housatonic River

River

Harrington MA




Housatonic River
















iii




3-16


3-16


3-16


3-20


3-21


3-23


3-23


3-23


3-23


3-23


3-23


3-23


3-24


3-24

IV



Page No


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































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50-year period












CHAPTER 1

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recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

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B Falls Village

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RJver MUe (From LI

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Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1

TABLE 2-4 ( of 3)



River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



JO





Re

turn

to C

liei


g 2 j c a 3

Q



E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

E H

A

No

n h

aza

rd _

SA

MP

LE

DIS

P

| II

5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^


Page No


331 Solids 3-14 332 PCBs 3-15





REFERENCES R-l

ATTACHMENTS






LIST OF FIGURES



Schematic


Housatonic River

River

Harrington MA




Housatonic River
















iii




3-16


3-16


3-16


3-20


3-21


3-23


3-23


3-23


3-23


3-23


3-23


3-23


3-24


3-24

IV



Page No


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




3


Ln

pound i-H uo





S


bull3 2 co c

k

w a g_y M

U 1

in

cludin

g

z Q c

i m

easu

red

1

irophyl

l T

S

r S

edim

ents i

lass

achu

set

thre

e ce

ntr

ed A

rocl

or

repr

esen

tat 3 u vgt s S

repr

esen

tat



I|o CO ^3 S EV



aco S

th in

tegra

ted

only

I1


SA

MP

LE


pound2 u 3

mea

sure

d



O 03

liH2


1n C^


laquo1 13

CJ bull

S ^S U98 oQ lt

tN OO

urre

nt

cj 0

aZ O

pCL

csi)00 u3^s0 raquo

j= bullsect



00 oo oo3 r^ 200 WJ

u-1 pound


C1 ~B S3

C



CO Ig_gt



|SIs


ONimdashi111 roE

3 k^x



pound f-H 23 W VO

Ibullg bullg bullo


X

2TT d bulla gt

E ^H 0) ^N

03 u O55 ow cLM

ltu o UM r laquo gt






tu

êso

urc


uIg

a

0

= bullS HbullM


z

Ste

war

t La

C

ompa

ny -

Pi

3 B

lasl

andamp

U

i IIOTU u

CO

O CO

D T

W u JO poundgt

J3 2 lt13 CQ g


U u

Com

pany

i bullgf

U-raquo


03 C 5bullcb

5^ X||


1

CM UJ cc

z o O Q o w cc

0

O

3 UJ

Q Z lt UJ 0

cc Q

d)CO o

LL O LL

h- 111Is sII

D lt0

c Ullit

gt

a

I












Labs [ITAS])
















15 in 35 in



11 claquo

Z mdash 3i U

CC CQ



aH

OLD

1Nlt

- 1 - 1 2 1 2 1


r5 W WM W ^gt ^gt ^


W O rt T3 (N

(N CN V V

pound H SBa S3 a

(N

CS

Cfl Z g


OS

W

03

0^ 0^

a ex S S

Jill 1 1

| 2 J jg

lt E shy5 E^

g P ^

g0 (N (N

S3 S3

| |

O O ^

CO m U H

bullIJSs

u c deg

3

I

t

Cd

U


$13 tt U9 U

-a

g

2 uO

u O

^J Û 4)E E


T3

M

U Jgt O U E E

_ 3 o

8

^ sect


CD mdash

|| P

AR

AM

ET

ER

sects 03U | f

V3 1

W 2 E -2 1 ri ushyu ^ ^ Sn 1c 8 E

Ue

3 ltlaquo





















Survey 1

joTW

S



Survey 2


Available 1991 Row































CQ u U



H J C^ Q Z U


wC5 2 gt QOf Z

CN BQ bulllt


k^ H o


etC352- u $ _2^ t5

re CS ro f fS f Q Q

o T3

Ed ^ s_^ Z Z

S0


HOr



Ui U9

03 U Z 523 Z Z o

CO 0 O

2 s g


au co 0 C

_] H 3

lt bullM T3 0 J X



pound^ 8 cgt 1 S

1 laquoOS

X




E vo deg CQ U

z gZ CU



AM

BIE

NT

M





lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2

TABLE 2-4 ( of 3)




I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

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ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

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Total PCB Segment 2

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mdash 0040shy

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45 50

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5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


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Water Column

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22


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t 08

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5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


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0065

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20

1 0

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Total PCB Segment 6

0070

0046

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20

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ll

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Total PCB Segment7

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mdash

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5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

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0075 0075

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0065 0085

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22 22

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0065

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10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

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0075shy

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0085shy

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0055shy

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1 O

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0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

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0040

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Total PCB Segment 7

0075

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Total PCB Segment 8

0020

0015

0010

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0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

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22


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20

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1 e

f 4

1 O

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Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

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0065

0095

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0015

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Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

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|pound

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1 8 1 8

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06

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Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

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0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































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ro 1J ^

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ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^

LIST OF FIGURES



Schematic


Housatonic River

River

Harrington MA




Housatonic River
















iii




3-16


3-16


3-16


3-20


3-21


3-23


3-23


3-23


3-23


3-23


3-23


3-23


3-24


3-24

IV



Page No


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















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bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



JO





Re

turn

to C

liei


g 2 j c a 3

Q



E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

E H

A

No

n h

aza

rd _

SA

MP

LE

DIS

P

| II

5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^




3-16


3-16


3-16


3-20


3-21


3-23


3-23


3-23


3-23


3-23


3-23


3-23


3-24


3-24

IV



Page No


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




3


Ln

pound i-H uo





S


bull3 2 co c

k

w a g_y M

U 1

in

cludin

g

z Q c

i m

easu

red

1

irophyl

l T

S

r S

edim

ents i

lass

achu

set

thre

e ce

ntr

ed A

rocl

or

repr

esen

tat 3 u vgt s S

repr

esen

tat



I|o CO ^3 S EV



aco S

th in

tegra

ted

only

I1


SA

MP

LE


pound2 u 3

mea

sure

d



O 03

liH2


1n C^


laquo1 13

CJ bull

S ^S U98 oQ lt

tN OO

urre

nt

cj 0

aZ O

pCL

csi)00 u3^s0 raquo

j= bullsect



00 oo oo3 r^ 200 WJ

u-1 pound


C1 ~B S3

C



CO Ig_gt



|SIs


ONimdashi111 roE

3 k^x



pound f-H 23 W VO

Ibullg bullg bullo


X

2TT d bulla gt

E ^H 0) ^N

03 u O55 ow cLM

ltu o UM r laquo gt






tu

êso

urc


uIg

a

0

= bullS HbullM


z

Ste

war

t La

C

ompa

ny -

Pi

3 B

lasl

andamp

U

i IIOTU u

CO

O CO

D T

W u JO poundgt

J3 2 lt13 CQ g


U u

Com

pany

i bullgf

U-raquo


03 C 5bullcb

5^ X||


1

CM UJ cc

z o O Q o w cc

0

O

3 UJ

Q Z lt UJ 0

cc Q

d)CO o

LL O LL

h- 111Is sII

D lt0

c Ullit

gt

a

I












Labs [ITAS])
















15 in 35 in



11 claquo

Z mdash 3i U

CC CQ



aH

OLD

1Nlt

- 1 - 1 2 1 2 1


r5 W WM W ^gt ^gt ^


W O rt T3 (N

(N CN V V

pound H SBa S3 a

(N

CS

Cfl Z g


OS

W

03

0^ 0^

a ex S S

Jill 1 1

| 2 J jg

lt E shy5 E^

g P ^

g0 (N (N

S3 S3

| |

O O ^

CO m U H

bullIJSs

u c deg

3

I

t

Cd

U


$13 tt U9 U

-a

g

2 uO

u O

^J Û 4)E E


T3

M

U Jgt O U E E

_ 3 o

8

^ sect


CD mdash

|| P

AR

AM

ET

ER

sects 03U | f

V3 1

W 2 E -2 1 ri ushyu ^ ^ Sn 1c 8 E

Ue

3 ltlaquo





















Survey 1

joTW

S



Survey 2


Available 1991 Row































CQ u U



H J C^ Q Z U


wC5 2 gt QOf Z

CN BQ bulllt


k^ H o


etC352- u $ _2^ t5

re CS ro f fS f Q Q

o T3

Ed ^ s_^ Z Z

S0


HOr



Ui U9

03 U Z 523 Z Z o

CO 0 O

2 s g


au co 0 C

_] H 3

lt bullM T3 0 J X



pound^ 8 cgt 1 S

1 laquoOS

X




E vo deg CQ U

z gZ CU



AM

BIE

NT

M





lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



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Re

turn

to C

liei


g 2 j c a 3

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E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

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No

n h

aza

rd _

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MP

LE

DIS

P

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5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^



Page No


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24


3-24

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




3


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pound i-H uo





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bull3 2 co c

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Survey 1

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CQ u U



H J C^ Q Z U


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pound^ 8 cgt 1 S

1 laquoOS

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E vo deg CQ U

z gZ CU



AM

BIE

NT

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lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



JO





Re

turn

to C

liei


g 2 j c a 3

Q



E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

E H

A

No

n h

aza

rd _

SA

MP

LE

DIS

P

| II

5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^

LIST OF TABLES



2-1A



2-4A






3-10A



3-15A


3-25A

VI

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




3


Ln

pound i-H uo





S


bull3 2 co c

k

w a g_y M

U 1

in

cludin

g

z Q c

i m

easu

red

1

irophyl

l T

S

r S

edim

ents i

lass

achu

set

thre

e ce

ntr

ed A

rocl

or

repr

esen

tat 3 u vgt s S

repr

esen

tat



I|o CO ^3 S EV



aco S

th in

tegra

ted

only

I1


SA

MP

LE


pound2 u 3

mea

sure

d



O 03

liH2


1n C^


laquo1 13

CJ bull

S ^S U98 oQ lt

tN OO

urre

nt

cj 0

aZ O

pCL

csi)00 u3^s0 raquo

j= bullsect



00 oo oo3 r^ 200 WJ

u-1 pound


C1 ~B S3

C



CO Ig_gt



|SIs


ONimdashi111 roE

3 k^x



pound f-H 23 W VO

Ibullg bullg bullo


X

2TT d bulla gt

E ^H 0) ^N

03 u O55 ow cLM

ltu o UM r laquo gt






tu

êso

urc


uIg

a

0

= bullS HbullM


z

Ste

war

t La

C

ompa

ny -

Pi

3 B

lasl

andamp

U

i IIOTU u

CO

O CO

D T

W u JO poundgt

J3 2 lt13 CQ g


U u

Com

pany

i bullgf

U-raquo


03 C 5bullcb

5^ X||


1

CM UJ cc

z o O Q o w cc

0

O

3 UJ

Q Z lt UJ 0

cc Q

d)CO o

LL O LL

h- 111Is sII

D lt0

c Ullit

gt

a

I












Labs [ITAS])
















15 in 35 in



11 claquo

Z mdash 3i U

CC CQ



aH

OLD

1Nlt

- 1 - 1 2 1 2 1


r5 W WM W ^gt ^gt ^


W O rt T3 (N

(N CN V V

pound H SBa S3 a

(N

CS

Cfl Z g


OS

W

03

0^ 0^

a ex S S

Jill 1 1

| 2 J jg

lt E shy5 E^

g P ^

g0 (N (N

S3 S3

| |

O O ^

CO m U H

bullIJSs

u c deg

3

I

t

Cd

U


$13 tt U9 U

-a

g

2 uO

u O

^J Û 4)E E


T3

M

U Jgt O U E E

_ 3 o

8

^ sect


CD mdash

|| P

AR

AM

ET

ER

sects 03U | f

V3 1

W 2 E -2 1 ri ushyu ^ ^ Sn 1c 8 E

Ue

3 ltlaquo





















Survey 1

joTW

S



Survey 2


Available 1991 Row































CQ u U



H J C^ Q Z U


wC5 2 gt QOf Z

CN BQ bulllt


k^ H o


etC352- u $ _2^ t5

re CS ro f fS f Q Q

o T3

Ed ^ s_^ Z Z

S0


HOr



Ui U9

03 U Z 523 Z Z o

CO 0 O

2 s g


au co 0 C

_] H 3

lt bullM T3 0 J X



pound^ 8 cgt 1 S

1 laquoOS

X




E vo deg CQ U

z gZ CU



AM

BIE

NT

M





lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



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Re

turn

to C

liei


g 2 j c a 3

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E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

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A

No

n h

aza

rd _

SA

MP

LE

DIS

P

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5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^

SUMMARY

51 INTRODUCTION










































Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




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pound i-H uo





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15 in 35 in



11 claquo

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CC CQ



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Survey 1

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Survey 2


Available 1991 Row































CQ u U



H J C^ Q Z U


wC5 2 gt QOf Z

CN BQ bulllt


k^ H o


etC352- u $ _2^ t5

re CS ro f fS f Q Q

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pound^ 8 cgt 1 S

1 laquoOS

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E vo deg CQ U

z gZ CU



AM

BIE

NT

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lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



JO





Re

turn

to C

liei


g 2 j c a 3

Q



E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

E H

A

No

n h

aza

rd _

SA

MP

LE

DIS

P

| II

5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^















Connecticut model



















50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















cS _o




3


Ln

pound i-H uo





S


bull3 2 co c

k

w a g_y M

U 1

in

cludin

g

z Q c

i m

easu

red

1

irophyl

l T

S

r S

edim

ents i

lass

achu

set

thre

e ce

ntr

ed A

rocl

or

repr

esen

tat 3 u vgt s S

repr

esen

tat



I|o CO ^3 S EV



aco S

th in

tegra

ted

only

I1


SA

MP

LE


pound2 u 3

mea

sure

d



O 03

liH2


1n C^


laquo1 13

CJ bull

S ^S U98 oQ lt

tN OO

urre

nt

cj 0

aZ O

pCL

csi)00 u3^s0 raquo

j= bullsect



00 oo oo3 r^ 200 WJ

u-1 pound


C1 ~B S3

C



CO Ig_gt



|SIs


ONimdashi111 roE

3 k^x



pound f-H 23 W VO

Ibullg bullg bullo


X

2TT d bulla gt

E ^H 0) ^N

03 u O55 ow cLM

ltu o UM r laquo gt






tu

êso

urc


uIg

a

0

= bullS HbullM


z

Ste

war

t La

C

ompa

ny -

Pi

3 B

lasl

andamp

U

i IIOTU u

CO

O CO

D T

W u JO poundgt

J3 2 lt13 CQ g


U u

Com

pany

i bullgf

U-raquo


03 C 5bullcb

5^ X||


1

CM UJ cc

z o O Q o w cc

0

O

3 UJ

Q Z lt UJ 0

cc Q

d)CO o

LL O LL

h- 111Is sII

D lt0

c Ullit

gt

a

I












Labs [ITAS])
















15 in 35 in



11 claquo

Z mdash 3i U

CC CQ



aH

OLD

1Nlt

- 1 - 1 2 1 2 1


r5 W WM W ^gt ^gt ^


W O rt T3 (N

(N CN V V

pound H SBa S3 a

(N

CS

Cfl Z g


OS

W

03

0^ 0^

a ex S S

Jill 1 1

| 2 J jg

lt E shy5 E^

g P ^

g0 (N (N

S3 S3

| |

O O ^

CO m U H

bullIJSs

u c deg

3

I

t

Cd

U


$13 tt U9 U

-a

g

2 uO

u O

^J Û 4)E E


T3

M

U Jgt O U E E

_ 3 o

8

^ sect


CD mdash

|| P

AR

AM

ET

ER

sects 03U | f

V3 1

W 2 E -2 1 ri ushyu ^ ^ Sn 1c 8 E

Ue

3 ltlaquo





















Survey 1

joTW

S



Survey 2


Available 1991 Row































CQ u U



H J C^ Q Z U


wC5 2 gt QOf Z

CN BQ bulllt


k^ H o


etC352- u $ _2^ t5

re CS ro f fS f Q Q

o T3

Ed ^ s_^ Z Z

S0


HOr



Ui U9

03 U Z 523 Z Z o

CO 0 O

2 s g


au co 0 C

_] H 3

lt bullM T3 0 J X



pound^ 8 cgt 1 S

1 laquoOS

X




E vo deg CQ U

z gZ CU



AM

BIE

NT

M





lt- ^ S u fe K


bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

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1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

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idic

ate

num


UJ Samp s _j UJ

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oc sectu ra

8 _ ltu C^^ in Ol



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turn

to C

liei


g 2 j c a 3

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E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

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No

n h

aza

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MP

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DIS

P

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5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^







50-year period












CHAPTER 1

INTRODUCTION

















recommendations
































MASSACHUSETTS

NEW YORK

CONNECTICUT

USGS GAGES

A Great Barnngton

B Falls Village

C Gaylordsville

^ O S 1 0 IS 20



CHAPTER 2

AMBIENT TRENDS






















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Available 1991 Row































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AM

BIE

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bulllaquo






221 Introduction















222 Methods












RJver MUe (From LI

Filtered PCB

Total PCB

NonfllleredPCB




100479 1630 01197500 1061 05 A

112779 11 00 01197500 1061 ND (0 1) 02 1280 22 A

031880 0900 01197500 1061 ND (01) 02 1000 63 A

03A880 1000 01197500 1061 ND (01) 01 A

031880 1100 01197500 1061 ND (01) 02 A

031880 1215 01197500 1061 ND(01) 02 A

031880 1330 01197500 1061 01 03 A

03 1 880 1515 01197500 1061 01 04 1820 76 A

032280 0700 01197500 1061 02 06 2980 226 A

040480 1330 01197500 1061 ND (0 1) 01 1060 20 A

041080 0830 01197500 1061 ND (0 1) 01 A

041080 11 45 01197500 1061 ND (0 1) 01 2410 124 A

041080 1455 01197500 1061 01 01 A

063080 1200 01197500 1061 01 04 631 18 A

060184 1730 01197500 1061 04 02 7650 67 B

012786 11 45 01197500 1061 ND(01) 0 2 2200 62 B

033187 1315 01197500 1061 ND(01) 02 1940 41 B

040587 1100 01197500 1061 01 05 5290 113 B

081988 0800 01197500 1061 02 02 153 12 B

100290 0955 01197500 1061 ND(OOT) ND (0 07) 259 ND(1) C

110590 11 40 01197500 1061 ND (003) ND (0 03) 461 4 C

120590 1200 01197500 1061 ND (006) 014 987 5 C

010291 1330 01197500 1061 ND (0 065) ND (0 065) 1412 ND(1) C

2691 1030 01197500 1061 ND (0 065) ND (0 065) 614 ND (1) C

31191 1400 01197500 1061 ND (0 065) 2 646 ND(1) C

4291 1345 01197500 1061 ND (0 065) ND (0 065) 825 ND(1) C




2-5A1




River MUe (From LI

Filtered PCB

Total PCB

NonfllteredPCB




030591 21 00 01197500 1061 -shy 0097 - 1310 3 D

030691 0030 01197500 1061 -shy 0068 -shy 1260 ND(1) D

030691 0305 01197500 1061 ND (0 065) 0086 - 1230 8 79 D

030691 0615 01197500 1061 -shy 0082 - 1190 5 D

030691 0900 01197500 1061 ND (0 065) 0086 -shy 1140 5 D

030691 1200 01197500 1061 -shy ND (0 065) -shy 1090 ND(1) D

022782 1445 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 510 24 E3

031382 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 686 52 E3

031482 1230 Wll 1061 ND(003) ND (0 03) ND (0 03) 952 62 E3

031582 1415 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 967 5 1 E3

031682 1400 Wll 1061 ND (0 03) ND (0 03) ND (0 03) 880 55 E3

042082 0900 Wll 1061 004 014 010 2960 190 E3

042082 11 00 Wll 1061 004 013 009 2890 170 E3

042182 1300 Wll 1061 004 010 006 2094 97 E3

042182 1600 Wll 1061 003 010 007 2046 110 E3

042282 1200 Wll 1061 002 007 005 1760 80 E3

042382 1200 Wll 1061 ND (0 03) 004 004 1460 56 E1

042382 1500 Wll 1061 ND (0 03) 004 004 1352 53 E3

042482 1800 Wll 1061 ND (0 03) 003 003 1101 50 E3

012786 1315 0119830 8485 ND (0 1) 01 - 123 F

033187 1410 0119830 8485 01 01 - 91 F

040587 1145 0119830 8485 ND (0 1) ND (0 1) - 47 F

081988 10-00 0119830 8485 ND (0 1) 01 - 3 F

012786 1400 01198550 791 ND (01) 01 186 G

033187 1445 01198550 791 ND (0 1) ND (0 1) -shy 104 G

040587 1215 01198550 791 ND (0 1) ND (0 1) -shy 129 G

012786 1430 01199105 739 ND (0 1) 01 mdash

4980 130 H

033187 1530 01199105 739 ND (0 1) ND (0 1) - 3770 92 H

040587 1300 01199105 739 ND (0 1) ND(01) - 9280 235 H

081988 12-00 01199105 739 ND (0 1) ND (0 1) -shy 985 10 H




2-5A2





I3022782 1310 Wl 8485 ND(003) -- ND (0 03) 820 75

I3031482 1400 Wl 8485 ND (0 03) 0045 0045 1320 540

I3031582 1530 Wl 8485 ND(003) 0048 0048 1500 460

I303A582 1630 Wl 8485 ND (0 03) 0048 0048 1525 440

031682 1320 Wl 8485 ND (0 03) 0048 0048 1440 340 I3

042082 1115 Wl 8485 ND (003) 007 007 4800 900 I3

I3042082 1420 Wl 8485 ND (003) 005 005 4800 910

I30421^2 1440 Wl 8485 ND (0 03) 004 004 3900 530

I3042282 1215 Wl 8485 ND (003) 004 004 2900 540

I3042382 1315 Wl 8485 ND (0 03) 005 005 2250 460

I3042482 1645 Wl 8485 ND (0 03) 004 004 1750 350




2-5A3

223 Results





hypothesis

















concentration



A g3



R I 3

(KM SSI

UJ cc 3 O c

en CO

Q z lt

g|


tu

1


CD

B 1 bdquodeg

0

c

c

pound c c M

01 E ICE

1000

t

2000

pound

3000

H

4000

i I

WOO


H

9000 100OO


A

H

A

A

A B

1 1

1 1 B

B

E Agfaf

0 1000 2000 3000

Kay




H

B

M 1

B

1

4000 6000 aOOO 7000 WOO 9000 10000

Flow (cfl)





ID c CSI

QS

S s pound 5 5

Ul CC 13 Oc

40

fc

I a

laquo C 1 LL 9

1 DC UJ

cc 0

C 3

o ~ ~ --W


f l1 S1

3j|

z 0lt CO

0 X cc UJQ Q3 Z

-8 1 oi -i

0

c ]

e

L

C

o

0

_ i

laquoUmdashr^

-8

3

c7 I CJ TJ CD 5


-121873 S S

2|15- it 5 S -J co

UJ u z UJ Q

UJ0 I l l

0 CO g_Jlt o


i t

J

I j~^



i 3

LL ~

-S Sill I

cshyc3

t C

33

li C 13

C

C

t3 c

C 73

t

t

C C

C

VI

3

0

I

T

C

_r-

C

Imdash I

p1 (mdash1 o (

3

o gt


5 laquo 29 of|Hi g

if bull

sect

5a (l6n) god 3 1

p^







adsorbed PCBs


Attachment 2



PCB = 006421 + 0002409 (TSS) f21)

PCB = 1044853 - 00000293(Day) (22gt

where








In (PCB) = 3147795 - 0000181 (Day) (23gt




Harrington












1991








time








1000O

1920 1930 1940 1950 I960 1970 1980 1990 2OOO

Year

2500

20OO

42 o

15OOshy

O

10OO

1976 1978 1992


degP M UJ tr D O E

CC Ul gt CC o

1 o z lt


o

CC DC 00

bullfcCO lt

o

UJ o

(sp) MOJJ Ajiea
































January - June

JAN

FEB

0 200 400 BOO 800 1000 1200 1400 1900 18OO 2000 2200 2400 2600 2800 3000 100 300 5OO 700 800 1100 1300 1500 1700 1900 2100 2300 2SOO 2700 2900 3500

Flow (cfs)

July - December

DEC 0 200 400 800 800 1000 12OO 1400 1600 1800 2000 2200 2400 2800 2800 3000

100 300 500 700 900 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900 3500

Flow (cfs)



Flow (cfs)



0 200 400 BOO 8OO 1000 12OO 1400 1600 1800 2000 2200 2400 2600 2800 3000 100 300 500 700 9OO 1100 1300 1500 1700 1900 2100 2300 2500 2700 2900

Flow (cfs)







1988)




transport


CHAPTER 3


















3-1






(31 V = J + ER + EJ + EWdt

where


t = time












(3-2) ct = 4gt cd + m cp

where















f







U = -i- (3-4)

where






of the chemical

where












cd- _ 4gt d

c lt|gt + Urn


cf _ Urn (3-6) = c



+ v u bull

where



















where








(V (39) V

dt

DA ff ~~T Vd

where




PROCESS





WATER COLUMN

ACTIVE SEDIMENT

INACTIVE SEDIMENT

MASS FLUX TERM ff

h f cpw tw




























DIT

ION

AL

FLO

CNi

FH N

AM

ED

TR

II CO

Ul oc



gt DC O z o

1 103 ngt lt CO

fS i =

a m t s i X

o LL

oc






bullJ


Q


IIILU




uj or -22 8 8 g g pound 8 8 S 8 8 5 O



-bull mdash~

1 LU


1 K 1 1S f CO


ui a Ul f sQ z J $

Ul o

a 2J i3gt 5 s


lt 3 CO

SE

GM

EN

T N

O

^ I Q - ^ R S 5 R 3 t 5 8 raquo- - fl r-

LAW

LER

MA

TUS

K

Envir

onm

enta

l Scie

nce

One

Blu

e H

ill P

laza

bull

Q O 5ltK e

1- ooVO

rgt O

90-

raquon bullmdasht

m (N(S

3 sO

^

deg wn O n

s s 00 0

0mo


ltN r-

BS-x

s00

3^ I

(Mr- r

1 ^ (sS

S a raquo 1

in or-shy

00

w^ S

i (N

^Xs Q 00ss

S 00 shy

s i

oo1

^ ^r O

CA H ZCxi s bl CA

U a oS

8 euroi f

s M Claquo

a

s

0 0

00 ^

raquo 0

(S

(N O

bullraquo n

r^S

m o deg

m fM

fl(S

SO 0

S

r^0

gj pound 0

S a

(S 0

0 bulln

inin

jn mdash

0

$ 2

rî O

P 5 S ec

raquo^

sect9 ^

S deg

5r

^C

s

0

pound

TT C-J

deg

o CA U HCA

s a 2 i

s S pound 2 ^^

9 ri sect T

ltS g(=5 Qlts S o

V

Cxi

HA

RA

CT

LE

NG

TH

(laquo)

00 Ô S in s 8 m in 1 r-- in i 1 1 I

U

t nu

mbe

rs u

slt

U

IIQ



^5 0 2 feshy 2

t

^Q H vO ^ ^ ^ O O ^ I 10 5 i I S

H

N 11

1- I O

SnC5 00 0- o ~ CJ S 2

B

bulls

mdashV


bull NE

W

EG

ME

NT

tlaquo

No

w-i u E

3-7A

c

TABLE 3-2














3-7B







discernible







ftd
















~ laquo fl C

o B v-



VO

P a o

H E Z U

ulaquo ltN

u Z o u f

~

gt_


tlaquo

03 a a S3

S C

cjt^ t^ Ed Jg

1 J

fc 35

g 55

fO ^^ V O IO ^J ^^ C 00 ^^ ^^

bullI laquo M2

bull COQ pound A Cj

so 122-P CO ^

It

aJ O e

^ 2ltu ca

a o Q

J C

^Hf^

^D ^p ^^ oo ^ ^

c i i ^J ^^

^jj^ rO

r-shy

^^ ON

^H O

U 1-u ^S

laquo shyS IM lt

1

S o

o as t 8 8 3 3 5 S 3 S 8 S 3 3 f1 pound

yfmdash 18

s _ laquo a


H

H Z ^^

8 Q

cn

0H ^~


0

w w bullraquo to




bullospoundgt

|deg

ltNS^

C shyH

O laquolaquol

1 1

c5

-amp

iioo y $ ^ o

fi 0 -322 _


I CO T3

r


^S CL


jg


C ^(I5 c ^

t8

s ^ e 1

^5 amplt

d

i ^ ^ v o ^ r o ^ ^ ^ v o r j


fraquo ^ T M O



2 to 00 y

^H + ^^ CO o 5 H Z

^ O |g


Q 1

w z


U 03 Z Z o TOf U O

3-8A












downstream















Great Barrington

2000 2500 9000


































TABLE 3-4




112 41 61 022 -0036 00 10

213 43 51 028 -0035 00 10 314 66 46 081 -0369 lt0 10

415 MA 126 42 075 -0254 lt0 10

516 CT 53 62 029 0055 00 10

617 106 40 007 0164 014 1 1 7A8 534 74 056 -0019 000 10

819 116 85 018 0299 026 21

920 297 57 039 -0033 000 10

1021 1342 41 000 0318 032 48

1122 712 95 000 0278 032 29


3-10A

Log KK = 0942 log K^ - 0144 (3-10)








Connolly 1980)








IF11 = K f (3-11) c aw Joe ^


9 is 31 x 104 to 28 x 105 Ikg








sensitivity

326 Volatilization































































each month







concentrations

331 Solids











QuM

9S S

8

S 8

Q O

su

O H


(D

CO (O

o trade

laquoo

| O

U oo

as gg a IU

CO ^H i K

^ a

O g 2raquo

ooCM

r^ cl

-J 2

aZ

1

a o

II poundpound

IU

sectpound

8

m0r^

raquoltfgt

hshyo^shy

en ggt

ft ft

c UUI

IS M


1 = C CQ C S


CD O O iZ

0

Segment 5

BO

so

70

10



Segment 6

100

90

I

laquo 50




TABLE 3-6


PCB CONCENTRATION


laquogl)

DISSOLVED FLOW

(cfs) TSS

(mg1)

Great Harrington

(MP 1061)

100479 112779 031880 031880 031880 031880 031880 031880 032280 040480 041080 041080 041080 063080

1630 1100 0900 1000 1100 1215 1330 1515 0700 1300 0830 1145 1455 1200

05 02 02 01 02 02 03 04 06 01 01 01 01 04

ND ND ND ND ND ND

01 01 02

ND ND ND

01 01

1280 1000

1820 2980 1060

2410

631

22 63

76 226 20

124

18


100479 112779 031880 031880 031880 031880 031880 032280 032280 040480 041080 041080 041080 063080

1230 0940 1115 1215 1315 1415 1515 0820 0930 1230 0930 1230 1550 1315

01 01

ND ND ND

01 ND

01 ND ND ND ND

02 02

ND ND

01 01 01

ND 01

ND ND ND

01 04 01

ND

3240 1850 2660 2820 2985 3150 3310 7550 6920 2180 4740 4740 5500 1110

24 100

210 242

19

128






























018

0 16 016

012

004 004

002 002






35 3 5

30

3

25

20-

1 5

25

44 44 -f + 4- + 4+ ++4++4-4 4

05







i


002



45

25 25

1 5

05


Date Dale




0 12

004

002



35

25

|20

1 5shy

1 0

05


Date


018

0 12

r 002



35

25

20

1 5











































deemed appropriate







































































en cgt ui tr D O c

I O


o

O

UJ O lt CC UI

lt OC UJ gt cc O

i O

(sp) MOIJ

































0070shy

0096shy

aoooshy

006shy

0060shy

0046shy

0040shy

OtO6shy

OOSOshy

0026shy

aososhy

aoisshy

0010shy

aooeshy

oooo






















projections




































00


Total PCB Segment 2

00 007

OOC ooe

ooe 10 111 ooe

00

oo mVl 005

005

_ 004

a OCM

o

^

^m

Lin

3 OK

OK

OK

OK

00

00

OOC

WAM

Iwu

1

LUWA LIvsAArt

Wvv^

3 deg03

003

ooz

002

001

001

OOC

10

10

0

Will

In

L raquoWM

VVMM KAV^

SM UA

OOC 0 5 10 15 20 25 30


OOC 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4

Years from 1 990 0 45 50

22


20

A r~ I

K V 1 10 10 3 1 0 O

1 0 V ^

^^





0005



22

20

1 8

1 8

1 2 1 2

r iftttt

06 06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0



0075

0070

0085

0080

0095

0050

_ 0045shy

mdash 0040shy

oooofshy

22

20

1 8

08

06

04

00


S 10 15 20 25 30 35 40Years from 1990


45 50

2 2

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


02





o flshy 007

ow ooe

OOi ooe

00 005

00 005

_ OOI 004

I

pound oo 1 I 0 0 3

OK 003

oo- 002

OOi o III 002

001

001

OCX

-II llllllll


001

ooc




20

K S

0

1Z

3 0 -f 100

Q Q

^^^^^-^ _ __

^-^^shy_





I O I 5 2 0 2 6 K 3 6 4 0 4 6 6 0




O


0 0 5 1 0 I S 2 0 Z S 3 0 M 4 0 4 S 5 0




0060

0046shy

0040shy

0036



0 5 1 0 1 S 2 0 2 6 3 0 3 6 4 0 4 6 6 0 YT torn 1980


Water Column

o a

20 26

Year from 1990

Bed Sediment

co g

1

20 2S Xgt

Year from 1990






























0070

0065

0035

0025

0015

0010

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

YMnfrom 1990


m 1 2shy

bulli 10




0075

0070

0065

0060

0055

0050

0045

0075shy

0070

0035

0030

0025

0020

0015

0010

0005

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMim from 1990 0

0015

0010

0000 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Yon tram 1800 0

22


20

08

t 08

04

02

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 Yews from 1990


0



0070

0065

0060

0055

0050

0045

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 0

04

02

00 0 5 10 15 20 25 30 35 40 45 50

YMnfnxn 1960

Total PCB Segment 6

0070

0046

mdash 004Oshy

2 2

20

1 6shy


ll

06

04

5 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 YMnfrom 1980

0


0075

0070

0065

0060

0055

0050

_ 0045shy

mdash 0040shy

2 -~ 0035shy

~ 0030shy

0025shy

0020

0015

0010

0005

0000 0 5

Total PCB Segment7

1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 YMtrade from 1980

_

mdash

0075

0070

0065

0060

0055

0050

0045

0040

0035

0005

OOOO-I 0

Total PCB Segment 8

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 9 Ywra from 1900

0

22


20

1 8

1 8

m

a 1 2 12shy

oe 08

06

04 04shy

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMfttrom 1980 0

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Ylaquoratrom 1990 0



0075 0075

0070 0070shy

0065 0085

0060 0080shy

0055 005

0050 OOSO

_ 0045 _ 0048shy

mdash 0040

8 a 0035

I 0030

mdash 004Oshy

0035

0025

002Oshy 0020

0015

0010 0010

0005 0005

OOOO 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

YMflfrofn 1090 0 0 5 1 0 1 5 2 0 2 S 3 0 3 S 4 0 4 S 5 0


22 22

20

06 06

04

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0




0075

0070

0069

0060

0055

0050

_ 0045

mdash 0040

5i003S

~ 0030

0029

0020

0015

0010

0006

0000 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0


20

1 8

16

ll

O S

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Yuratnxn1990



flUPI

1 m 004deg H)

KAM

L

WM

+M

UAAÂ

^gt^^raquo

c 5 10 15 20 25 30 35 40 45 50Years from 1990



S 27 ^ 03 1 o i_ o f shy

3

U euro

Ofl ~ pound

^ ^

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0Years from 1990


CD 004deg fffM

deg nnin MfMA

nm^ HA

l ^vv tVVAA

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990



_ ^~


2 1 10 bull ^1 v5 v

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 Years from 1990





0070

0065

0005

10 15 20 25 30 35Years from 1990

40 45 X 0000

5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990



1 8

1 6 1 8


1 0 I 1 O

06

04 04

02 02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 9 5 0





0075shy

0070shy

0085shy

0060

0055shy

0050

0045

0040shy

0035

0030

5 1 0 1 5 2 0 2 5 3 0 3 S 4 0 4 5 5 Years front 1990

0


2 2


1 O

08

18

|

R 12

10

4

04

02

5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 9 Years from 1990

0 0 5 1 0 1 5 2 0 2 9 3 0 3 9 4 0 4 5 5 Years from 1990

0



0075

0070

0085

ooeoshy

0055

0050

0045

0040

0035

0030

Total PCB Segment 7

0075

007O

0065

ooeoshy

0055

0050shy

004

0040shy

degshy 0035

0030

Total PCB Segment 8

0020

0015

0010

0005shy

0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5 0

Years from 1990


22


22


20

1 8 1 laquobull

1 e

f 4

1 O

08 08

00shy5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 0 5 1 0 1 S 2 0 2 5 3 O 3 5 4 O 4 5 5

Years from 1990

0



007ST

0065

0095

0045

0040

0035

pound 0 0 3 0

0025

0020

0015

0010

Total PCB Segment 9

1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 0

Yean from 1990

degshy

|pound

0070

0065

0090shy

0055

005O

0045

0040

0035shy

003Oshy

0025

0020

001

0005

0000



22


1 8 1 8

1 6

f4

1 2

i 10

08

06

02

00 0 5 1 0 1 5 2 0 2 5 3 0 3 5 4 0 4 5 5

Years from 1990

0 1 0 1 5 2 0 2 9 3 0 3 5 4 0 4 5 5 Years from 1990

0




0075shy

0070shy

0085shy

0090

0055shy

0080shy

5 0045shy

mdash 0040shy

0035shy

2 0030shy

OQ2S

0020


0010

OOO5


22


18

CD

2 i y

10














TABLE 3-7



INFLOWS


Tributaries


OUTFLOWS


Volatilization



PCB TRANSPORT

(lbyr)

324

222

546

134

101

311

546

PCB TRANSPORT

()

593

407

1000

245

185

570

1000

3-2 5 A

CHAPTER 4


41 CONCLUSIONS













remaining survey




























another












42 RECOMMENDATIONS




























follows




Cannann 5 4 -


Cornwall 7 8

Bulls Bridge 8 10 1

New Milford 9 8


L Zoar 11 10 2














bull Falls Village




















REFERENCES
























ATTACHMENT 1




General














Bottle Preparation





bull Methanol rinse


bull Hexane rinse



Sampler Preparation


























to actual sampling











the platform)




























bull Sample type

bull Sample volume













bottles are filled






































Z tJ

2 o o o o O

u lt^ ^ x


E- yjo|m 21 05


ro 1J ^

3 H

^Jgt i deg1

J rsi 1 _

uJ bull o gt UJ

S^ Imdash^ 1 lt

bull o n_

05 g co LU o


- lt O

vg UJ

Q 2 ^

^ -i [H

53

ltH O E

u

fe o

^ o

if ^ X

i ^ (ij i i M 1

2 05 0 tg 1 $i o 5 U(

U Q poundg

Q U 53 O

1 i ] 1 1 1 1 11

ogt

-o agt o


mdash




CD CT u0 0 a agt 11



0 O O C

lt O l|

fOJ

mdash 2w JD

QX Dr c3 1 0) sect

I

tn 01 5 ra CT o


1 01 U)jr o i o agt

= MSto~ JO







i 5 raquo o3

and

or

susp

ecl

i fo

r pa

ckin

g s

t

idic

ate

num


UJ Samp s _j UJ

UJ


oc sectu ra

8 _ ltu C^^ in Ol



JO





Re

turn

to C

liei


g 2 j c a 3

Q



E E S 0 gt

JC m V (J s s-






2 5 pound z DC 5Uj

a gtotrade gt



PO

SS

IBL

E H

A

No

n h

aza

rd _

SA

MP

LE

DIS

P

| II

5 deg^ 3 ô u^ a t a 0 ^ t O

3 S fe 3 g 1 rr 1 I


ATTACHMENT 2





Intercept 1044853 03783816 276 00084

DAY -0000029 00000122 -240 00209 01179 01179

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept 05238597 0326771 160 01138

DAY -0000022 00000094 -237 0207 00892 00892

RM 0002880 00012180 236 0211 01624 00887





Prob Level

Sequential R2

Simple R2

Intercept 0062085 03202042 019 08475

DAY -0000002 00000102 -001 09883 00700 00700

FLOW 00000056 00000129 044 06649 02389 01984

TSS 00023190 00004118 563 0000 06177 06154

ALL LOCATIONS



Prob Level

Sequential R2

Simple R2

Intercept -03957341 03089781 -128 02067

DAY -00000449 00000088 -051 06136 00372 00372

FLOW -00000135 00000109 -124 02202 00678 00361

TSS 0001971 00003816 516 00000 02726 02155

RM 0005980 00012580 476 00000 05123 00798

ATTACHMENT 3

MODEL INPUT FILES

File newcal24inp


2 3 4 5 6 7 8



58 227 150 625 180 922 210 659 240 59 607 270 345 300 167 330 1091 360 60 1390 390 483 420 239 450 224 480 61 144 510 140 525 62 10 ft3s 63 3 0 18 64 157 30 143 60 61 90 32 120 65 29 150 79 180 117 210 83 240 66 77 270 44 300 21 330 138 360 67 176 390 61 420 30 450 28 480 68 18 510 18 525 69 10 ft3s

70 4 3 18 71 1393 30 1273 60 546 90 286 120 72 256 150 704 180 1038 210 743 240 73 684 270 389 300 188 330 1229 360 74 1566 390 544 420 269 450 252 480 75 162 510 158 525 76 10 ft3s

77 4 0 18 78 100 30 92 60 39 90 21 120 79 18 150 51 180 75 210 54 240 80 49 270 28 300 14 330 89 360 81 113 390 39 420 19 450 18 480 82 12 510 11 525 83 10 ft3s

84 5 4 18 85 1493 30 1365 60 586 90 307 120 86 274 150 755 180 1113 210 796 240 87 734 270 417 300 202 330 1318 360 88 1679 390 583 420 289 450 270 480 89 173 510 169 525 90 10 ft3s

91 5 0 18 92 310 30 283 60 122 90 64 120 93 57 150 10 180 231 210 165 240 94 152 270 86 300 42 330 274 360 95 349 390 121 420 60 450 56 480 96 36 510 35 525 97 10 ft3s

98 6 5 18 99 1803 30 1648 60 707 90 371 120 100 331 150 765 180 1344 210 962 240 101 886 270 503 300 244 330 1592 360 102 2028 390 704 420 349 450 326 480 103 209 510 204 525 104 10 ft3s

105 6 0 18 106 130 30 159 60 78 90 5 120 107 27 150 33 180 102 210 157 240 108 151 270 119 300 44 330 213 360 109 246 390 85 420 28 450 23 480 110 11 510 11 525 111 10 ft3s

112 0 6 18 113 1933 30 1807 60 786 90 376 120 114 358 150 798 180 1447 210 1118 240

8







23456 7



1 f 3 4 5 6 7 8






1 2 3 4 5 6 7 8

10

20

30

40

50

F i1 e new8 i np 08-13-91 page 1 1 2 3 4 5 6 7 8

1 1


10 2 11 1 13 1


17 3 15 1

18 0194 360 19 10 Million ft3day

4 16 1

21 0369 360 22 10 Million ft3day 23 5 17 1

24 0155 360 25 10 Million ft3d

26 6 18 1 27 0281 360 28 10 Mill ion ft3d

29 7 19 1

1561 360 31

10 Million ft3d

32 8 20 1

33 0161 360 34 10 Million ft3d 35 9 21 1

36 0867 360 37 10 Million ft3d 38 10 22 1

39 0816 360 10 Million ft3d

41 11 23 1

42 0790 360

43 10 Million ft3d 44 12 24 1

45 0790 360

46 10 Million ft3d 47 1 24

48 1618 1698 3531 6422 531 4941 5581 7830

49 5050 267593 98200 98200 015 015 024 046

19 42 193 88 107 2339 751 751


54 10 2 1 0 3 55 1 0 12 56 558 30 557 60 1029 90 1413 120

57 778 150 474 180 315 210 269 240

s neuS

58 59

60 61 62 63 64

65 66 67 68 69

70 71 72 73 74

75 76 77 78 79

80 81 82 83 84

85 86 87 88 89

90 91 92 93 94

95 96 97 98 99 raquo

100 101 102 103 104

105 106 107 108 109

110 111 112 113 114


295 270 326 300 513 330 581 360 10 ft3s 1

2 1 12 558 30 557 60 1029 90 1413 120 778 150 474 180 315 210 269 240 295 270 326 300 513 330 581 360

10 ft3s

2 0 12 24 30 23 60 42 90 58 120 32 150 19 180 13 210 11 240 12 270 13 300 21 330 24 360

10 ft3s

3 2 12 582 30 580 60 1071 90 1471 120 810 150 493 180 328 210 280 240 307 270 339 300 534 330 605 360

10 ft3s

3 0 12 76 30 82 60 155 90 234 120 104 150 47 180 20 210 17 240 19 270 34 300 78 330 88 360

10 ft3s 4 3 12

658 30 662 60 1226 90 1705 120 914 150 540 180 348 210 297 240 326 270 373 300 612 330 693 360

10 ft3s

4 0 12 44 30 39 60 68 90 72 120 64 150 56 180 49 210 41 240 45 270 36 300 33 330 38 360

10 ft3s

5 4 12 702 30 701 60 1294 90 1777 120 978 150 596 180 397 210 338 240 371 270 409 300 645 330 731 360

10 ft3s

5 0 12 305 30 302 60 504 90 467 120 284 150 217 180 123 210 122 240 96 270 109 300 180 330 251 360

10 ft3s

6 5 12 1007 30 1003 60 1798 90 2244 120 1262 150 813 180 520 210 460 240 467 270 518 300 825 330 982 360

10 ft3s

6 0 12 98 30 98 60 176 90 219 120 123 150 79 180 51 210 45 240 46 270 51 300 81 330 96 360

10 ft3s 7 6 12

1105 30 1101 60 1974 90 2463 120 1385 150 892 180 571 210 505 240 513 270 569 300 906 330 1078 360

10 ft3s

3 4 5 7 8



1 2 3 4 5 6 7 8



f 1 2 3 4 5 6 7 8



5

1 2 3 4 5 6 7 8





392 580 9900 58011700 58013500 58015300 58017100

393 58016000 58018000 394 1000 mgl 395 20 12 396 370 900 370 2700 370 4500 370 6300 370 8100

397 370 9900 37011700 37013500 37015300 37017100

398 37016000 37018000 399 1000 mgl

56





Fi le new8inp 08-13-91 page 10 1 2 3 4 5 6 7


1 2 3 4 5 6 7 8


571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 589 590 591 592 593 594 595 596 597 598 599 600 601 602 603 604 605 606 607 608 609 610 611 612 613 614 615 616 617 618 619 620 621 622 623 624 625 626 627

1 2 3 4


0 0


11 1E-6 12 1E-6 13 16 047 17 81 18 21 036 22 55 23 H1 1 M2 1 M3




















12345678

ATTACHMENT 4





auations

ct = $cd + me (3-2)


H -- mdash (3-4)

14

bull Bed

=1 ltAw (3-11)



II = (32xlOlts)(002) = 64X104

64x10 mdash U = ^ = 43922 Ikg = 00439 lmg

1 + (10 -^)(64xl04 -^-X-rrK ^ ) 14 IxlO6

bull Bed

H = (002)(32xlO6) = 64000 Ikg = 0064 lmg



mg I

(00439 mdash )(10 ^) = -m-1mdash = 0 31 p i

(00439 mdash )(10 ) mg I

bull Bed


mg I


w


= (069)(006 jig) = 004 raquogfl

(031)(006 ) mdash = 00019 ^mlaquo = 19

m_

bull Bed



6X105 -^

AMBIENT TREND MONITORING AND PCB FATE AND TRANSPORT … · 2020. 12. 16. · 3.3 Mode Calibratiol n...

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Transcript of AMBIENT TREND MONITORING AND PCB FATE AND TRANSPORT … · 2020. 12. 16. · 3.3 Mode Calibratiol n...