Alwa-mould d Component 2

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Safety data sheetaccording to 1907/2006/EC, Article 31

Printing date 16.12.2010 Revision: 14.12.2010

* 1Identification of the substance/mixture and of the company/undertaking

Product identifier

Trade name: ALWA-MOULD D, Komponente 2, Gieharz Article number: 6001 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation Tooling material

Details of the supplier of the safety data sheet Manufacturer/Supplier:ALWA Technische Produkte fr Kunststoff-verarbeitung, Modell- und Formbau GmbHRntgenstr.1, D-48599 Gronau

Further information obtainable from:Abteilung ProduktsicherheitTel.: +49 (0) 25 62 - 9 81 57

Fax: +49 (0) 25 62 - 9 81 59Email: [email protected]

Emergency telephone number:Giftinformationszentrum (GIZ) BonnTel.: 0228/19 240

* 2Hazards identification

Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008

GHS02 flame

Flam. Liq. 3 H226 Flammable liquid and vapour.

GHS07

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2 H319 Causes serious eye irritation.

Skin Sens. 1 H317 May cause an allergic skin reaction.

Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn; Harmful

R20: Harmful by inhalation.

Xi; Irritant

R36/38: Irritating to eyes and skin.

Xi; Sensitising

R43: May cause sensitisation by skin contact.

R10: Flammable. Information concerning particular hazards for human and environment:The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version.

Classification system:The classification is according to the latest editions of the EU-lists, and extended by company andliterature data.

(Contd. on page 2)GB


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Trade name: ALWA-MOULD D, Komponente 2, Gieharz

(Contd. of page 1)

Label elements Labelling according to EU guidelines:The product has been classified and marked in accordance with EU Directives / Ordinance onHazardous Materials.

Code letter and hazard designation of product:Xn Harmful

Hazard-determining components of labelling:methyl methacrylatestyrene

Risk phrases:10 Flammable.20 Harmful by inhalation.36/38 Irritating to eyes and skin.43 May cause sensitisation by skin contact.

Safety phrases:9 Keep container in a well-ventilated place.23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the

manufacturer).24 Avoid contact with skin.26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable.

3Composition/information on ingredients

Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions.

Dangerous components:

CAS: 100-42-5EINECS: 202-851-5

styreneXn R20; Xi R36/38

R10

Flam. Liq. 3, H226; Acute Tox. 4, H332; Skin Irrit. 2, H315;Eye Irrit. 2, H319

25-50%

CAS: 80-62-6

EINECS: 201-297-1

methyl methacrylate

Xi R37/38; Xi R43; F R11Flam. Liq. 2, H225; Skin Irrit. 2, H315; Skin Sens. 1, H317;

STOT SE 3, H335

2.5-10%

Additional information: For the wording of the listed risk phrases refer to section 16.

* 4First aid measures

Description of first aid measures General information:Take affected persons out into the fresh air.Take affected persons out of danger area and lay down.Keep quiet and cover.

Position and transport stably in side position.Symptoms of poisoning may even occur after several hours; therefore medical observation for atleast 48 hours after the accident.

(Contd. on page 3)

GB


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(Contd. of page 2)

After inhalation:

Supply fresh air and to be sure call for a doctor.In case of unconsciousness place patient stably in side position for transportation.

After skin contact:Call a doctor immediately.Immediately wash with water and soap and rinse thoroughly.

After eye contact:Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

After swallowing: Rinse out mouth and then drink plenty of water. Information for doctor: Most important symptoms and effects, both acute and delayedHeadacheDizzinessDizziness

UnconsciousnessNauseaCoughing

* 5Firefighting measures

Extinguishing media Suitable extinguishing agents:CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.

Advice for firefighters Protective equipment:Do not inhale explosion gases or combustion gases.

Wear fully protective suit.Mouth respiratory protective device. Additional informationCool endangered receptacles with water spray.Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.Collect contaminated fire fighting water separately. It must not enter the sewage system.

* 6Accidental release measures

Personal precautions, protective equipment and emergency proceduresEnsure adequate ventilationKeep away from ignition sources.Use respiratory protective device against the effects of fumes/dust/aerosol.

Wear protective equipment. Keep unprotected persons away. Environmental precautions:Prevent from spreading (e.g. by damming-in or oil barriers).Dilute with plenty of water.Do not allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.

Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

GB

(Contd. on page 4)


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(Contd. of page 3)

* 7Handling and storage

Handling: Precautions for safe handlingKeep receptacles tightly sealed.Keep away from heat and direct sunlight.Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.

Information about fire - and explosion protection:Fumes can combine with air to form an explosive mixture.Use explosion-proof apparatus / fittings and spark-proof tools.Use only in explosion protected area.Keep ignition sources away - Do not smoke.

Protect against electrostatic charges. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Not required. Further information about storage conditions:Store in a cool place. Heat will increase pressure and may lead to the receptacle bursting.Keep container tightly sealed.

* 8Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.

Control parameters

Ingredients with limit values that require monitoring at the workplace:

100-42-5 styrene

WEL Short-term value: 1080 mg/m, 250 ppmLong-term value: 430 mg/m, 100 ppm

80-62-6 methyl methacrylate

WEL Short-term value: 416 mg/m, 100 ppmLong-term value: 208 mg/m, 50 ppm

Additional information: The lists valid during the making were used as basis.

Exposure controls Personal protective equipment: General protective and hygienic measures:Do not eat, drink, smoke or sniff while working.Use skin protection cream for skin protection.Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes and skin.

Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longerexposure use self-contained respiratory protective device.

Recommended filter device for short term use: Combination filter A-P2(Contd. on page 5)

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(Contd. of page 4)

Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

Material of glovesButyl rubber, BRNitrile rubber, NBRPVA glovesThe selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application.

Penetration time of glove materialThe exact break trough time has to be found out by the manufacturer of the protective gloves andhas to be observed.

Eye protection:

Tightly sealed goggles

Body protection: Solvent resistant protective clothing

* 9Physical and chemical properties

Information on basic physical and chemical properties General Information Appearance:

Form: FluidColour: Yellow

Odour: Characteristic

Change in condition

Melting point/Melting range: Undetermined.Boiling point/Boiling range: 146C

Flash point: 21 - 55C (ISO 1523)

Ignition temperature: 480C

Self-igniting: Product is not selfigniting.

Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible.

Explosion limits:Lower: 1.2 Vol %Upper: 8.9 Vol %

Vapour pressure at 20C: 6 hPa(Contd. on page 6)

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(Contd. of page 5)

Density at 20C: 1.1 g/cm Solubility in / Miscibility with

water: Fully miscible.

Solvent content:Organic solvents: 36.3 %

10 Stability and reactivity

Reactivity Chemical stability Thermal decomposition / conditions to be avoided:

No decomposition if used according to specifications. Possibility of hazardous reactionsExothermic polymerization.Reacts with peroxides.

Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological information

Information on toxicological effects Acute toxicity:

LD/LC50 values relevant for classification:

100-42-5 styrene

Oral LD50 5000 mg/kg (rat)

Inhalative LC50/4 h 24 mg/l (rat)

Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information:The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:HarmfulIrritant

Sensitisation May cause sensitisation by skin contact.

* 12 Ecological information

Toxicity Acquatic toxicity: No further relevant information available. Additional ecological information: General notes:Water hazard class 2 (German Regulation) (Self-assessment): hazardous for waterDo not allow product to reach ground water, water course or sewage system.Danger to drinking water if even small quantities leak into the ground.

Results of PBT and vPvB assessment PBT: Not applicable.



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(Contd. of page 6)

vPvB: Not applicable.

* 13 Disposal considerations

Waste treatment methods RecommendationMust be specially treated adhering to official regulations.Must not be disposed together with household garbage. Do not allow product to reach sewagesystem.

Uncleaned packaging: Recommendation:Non contaminated packagings may be recycled.Packagings that may not be cleansed are to be disposed of in the same manner as the product.

Recommended cleansing agents: Water, if necessary together with cleansing agents.

* 14 Transport information

Land transport ADR/RID (cross-border)

ADR/RID class: 3 Flammable liquids. Danger code (Kemler): 30

UN-Number: 1866 Packaging group: III Hazard label: 3 UN proper shipping name: 1866 RESIN SOLUTION Tunnel restriction code D/E

Maritime transport IMDG:

IMDG Class: 3 UN Number: 1866

Label 3 Packaging group: III EMS Number: F-E,S-E Marine pollutant: No Proper shipping name: RESIN SOLUTION

Air transport ICAO-TI and IATA-DGR:

ICAO/IATA Class: 3 UN/ID Number: 1866

Label 3 Packaging group: III



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(Contd. of page 7)

Proper shipping name: RESIN SOLUTION UN "Model Regulation": UN1866, RESIN SOLUTION, 3, III Special precautions for user Warning: Flammable liquids.

* 15 Regulatory information

Safety, health and environmental regulations/legislation specific for the substance ormixture

National regulations:

Information about limitation of use:Employment restrictions concerning juveniles must be observed.

Employment restrictions concerning pregnant and lactating women must be observed. Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information

This information is based on our present knowledge. However, this shall not constitute a guaranteefor any specific product features and shall not establish a legally valid contractual relationship.

Relevant phrasesH225 Highly flammable liquid and vapour.H226 Flammable liquid and vapour.H315 Causes skin irritation.H317 May cause an allergic skin reaction.

H319 Causes serious eye irritation.H332 Harmful if inhaled.H335 May cause respiratory irritation.

R10 Flammable.R11 Highly flammable.R20 Harmful by inhalation.R36/38 Irritating to eyes and skin.R37/38 Irritating to respiratory system and skin.R43 May cause sensitisation by skin contact.

Department issuing MSDS: Abteilung Produktsicherheit Contact: Hr. Hazejager Abbreviations and acronyms:

ADR: Accord europen sur le transport des marchandises dangereuses par Route (European Agreement concerning the

International Carriage of Dangerous Goods by Road)RID: Rglement international concernant le transport des marchandises dangereuses par chemin de fer (RegulationsConcerning the International Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationIATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)ICAO: International Civil Aviation OrganizationICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)GHS: Globally Harmonized System of Classification and Labelling of ChemicalsLC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percent

* Data compared to the previous version altered. GB

Alwa-mould d Component 2

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